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At least 127 records · Page 7Linked to original sources

Magmatic origin for sediment-hosted Au deposits, Guizhou Province, China: In situ chemistry and sulfur isotope composition of pyrites, Shuiyindong and Jinfeng deposits

The southwest Guizhou Province, China, contains numerous sediment-hosted Au deposits with Au reserves greater than 700 tonnes. To date, the source of ore fluids that formed the Guizhou sediment-hosted Au deposits is controversial, hampering the formulation of genetic models. In this study, we selected the Shuiyindong and Jinfeng Au deposits, the largest strata-bound and fault-controlled deposits in Guizhou, respectively, for detailed research on pyrite chemistry and S isotope composition using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) and laser ablation-multicollector-inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS), respectively. Petrography and pyrite chemistry studies distinguished five generations of pyrite. Among these, pre-ore pyrite 2 and ore pyrite are the most abundant types in the deposits. Pre-ore pyrite 2 is anhedral to euhedral and with ~2,639 ppm As and wider ranges of Cu, Sb, and Pb (<~22–4,837 ppm, <~6 to 532 ppm, and <~4 to 1,344 ppm, respectively). Gold in pre-ore pyrite 2 is below the detection limit of LA-ICP-MS (~2 ppm). Pre-ore pyrite 2 is interpreted to have a sedimentary (syngenetic or diagenetic) origin. Ore pyrite commonly rims the four identified pre-ore pyrites or occurs as individual, anhedral to euhedral crystals. Ore pyrite is enriched in Au (~641 ppm), As (~9,147 ppm), Cu (~1,043 ppm), Sb (~188 ppm), Hg (~43 ppm), and Tl (~22 ppm) in both deposits. Ore pyrite formed mainly by sulfidation of Fe in Fe-bearing host rocks, mainly Fe dolomite, and As, Cu, Sb, Hg, and Tl, also in ore fluids, were incorporated into ore pyrite. In situ δ 34 S isotope ratios for pre-ore pyrite 2 and ore pyrite were measured by LA-MC-ICP-MS. Pre-ore pyrite 2 from Shuiyindong and Jinfeng deposits resulted in δ 34 S values ranging from −0.8 to +3.4‰ and from 5.1 to 10.5‰, respectively. Analyses of ore pyrite from the Shuiyindong have δ 34 S values that vary from −3.3 to +2.5‰, with a median of 0.7‰; analyses of ore pyrite from the Jinfeng range from 8.9 to 11.2‰, with a median at 10.3‰. Available bulk and in situ δ 34 S data in the literature for pre-ore pyrites 1 and 2 and ore-related sulfide minerals including ore pyrite, arsenopyrite, and late ore-stage stibnite, realgar, orpiment, and cinnabar from several Guizhou sediment-hosted Au deposits were compiled for comparison. Pre-ore-stage pyrites from Guizhou sediment-hosted Au deposits have a broad range of δ 34 S values, from −33.8 to + 17.9‰ (including in situ and available bulk δ 34 S data). Ore-related sulfide minerals in all Guizhou sediment-hosted Au deposits, except Jinfeng, have very similar δ 34 S values, and most data plot between ~−5 and +5‰. In the Jinfeng deposit, the ore-related sulfide minerals exhibit δ 34 S values ranging from 1.9 to 18.1‰, with most data plotting between 6 and 12‰. The broad range of S isotope compositions for the sedimentary pyrites (pre-ore pyrites 1 and 2) indicate that S in these pre-ore pyrites was most likely generated by bacterial reduction from marine sulfate. The narrow range of δ 34 S values (~−5–+5‰) for ore-related sulfide minerals in all Guizhou sediment-hosted Au deposits, excepting the Jinfeng deposit, suggests that the deposits may have formed in response to a single widespread metallogenic event. As the S isotope fractionation between hydrothermal fluids and sulfide minerals in a sulfide-dominated system is small (<2‰) at ~250°C, the initial ore fluids that formed the Guizhou sediment-hosted Au deposits would have had δ 34 S values similar to the ore-related sulfide minerals, between ~−5 and +5‰. At Jinfeng, initial ore fluids may have mixed with local fluids with heavier δ 34 S, possibly basin brine ( δ 34 S basin brine >18‰), resulting in elevated δ 34 S values of ore-related sulfide minerals and especially late ore-stage sulfide minerals. Although few igneous rocks are exposed in the mining area around these deposits, there is evidence of magmatic activity ~20 km away. Furthermore, gravity and magnetic geophysical investigations indicate the presence of a pluton ~5 km below the surface of the Shuiyindong district. Based on in situ S isotope results and recent data indicating proximal intrusions, we interpret a deep magmatic S source for the ore fluids that formed the Guizhou sediment-hosted Au deposits. However, as the age for Au mineralization of Guizhou sediment-hosted Au deposits is still debated, the mineralization-magma connection remains hypothetical. Identifying an ore fluid source and time frame for Guizhou Au mineralization continues to be a critically important research goal for this district.

Yunnan-Guizhou-Guangxi region

Estimating time-dependent connectivity in marine systems

Hydrodynamic connectivity describes the sources and destinations of water parcels within a domain over a given time. When combined with biological models, it can be a powerful concept to explain the patterns of constituent dispersal within marine ecosystems. However, providing connectivity metrics for a given domain is a three-dimensional problem: two dimensions in space to define the sources and destinations and a time dimension to evaluate connectivity at varying temporal scales. If the time scale of interest is not predefined, then a general approach is required to describe connectivity over different time scales. For this purpose, we have introduced the concept of a “retention clock” that highlights the change in connectivity through time. Using the example of connectivity between protected areas within Barnegat Bay, New Jersey, we show that a retention clock matrix is an informative tool for multitemporal analysis of connectivity.

Geophysical Research Letters

Seismic velocities for hydrate-bearing sediments using weighted equation

A weighted equation based on the three-phase time-average and Wood equations is applied to derive a relationship between the compressional wave (P wave) velocity and the amount of hydrates filling the pore space. The proposed theory predicts accurate P wave velocities of marine sediments in the porosity range of 40-80% and provides a practical means of estimating the amount of in situ hydrate using seismic velocity. The shear (S) wave velocity is derived under the assumption that the P to S wave velocity ratio of the hydrated sediments is proportional to the weighted average of the P to S wave velocity ratios of the constituent components of the sediment. In the case that all constituent components are known, a weighted equation using multiphase time-average and Wood equations is possible. However, this study showed that a three-phase equation with modified matrix velocity, compensated for the clay content, is sufficient to accurately predict the compressional wave velocities for the marine sediments. This theory was applied to the laboratory measurements of the P and S wave velocities in permafrost samples to infer the amount of ice in the unconsolidated sediment. The results are comparable to the results obtained by repeatedly applying the two-phase wave scattering theory. The theory predicts that the Poisson's ratio of the hydrated sediments decreases as the hydrate concentration increases and the porosity decreases. In consequence, the amplitude versus offset (AVO) data for the bottom-simulating reflections may reveal positive, negative, or no AVO anomalies depending on the concentration of hydrates in the sediments.

Journal of Geophysical Research B: Solid Earth

Hurricanes, submarine groundwater discharge, and Florida's red tides

A Karenia brevis Harmful Algal Bloom affected coastal waters shallower than 50 m off west-central Florida from January 2005 through January 2006, showing a sustained anomaly of ???1 mg chlorophyll m-3 over an area of up to 67,500 km2. Red tides occur in the same area (approximately 26-29??N, 82-83??W) almost every year, but the intense 2005 bloom led to a widespread hypoxic zone (dissolved oxygen <2 mg L-1) that caused mortalities of benthic communities, fish, turtles, birds, and marine mammals. Runoff alone provided insufficient nitrogen to support this bloom. We pose the hypothesis that submarine groundwater discharge (SGD) provides the missing nutrients, and indeed can trigger and support the recurrent red tides off west-central Florida. SGD inputs of dissolved inorganic nitrogen (DIN) in Tampa Bay alone are ???35% of that discharged by all central Florida rivers draining west combined. We propose that the unusual number of hurricanes in 2004 resulted in high runoff, and in higher than normal SGD emerging along the west Florida coast throughout 2005, initiating and fueling the persistent HAB. This mechanism may also explain recurrent red tides in other coastal regions of the Gulf of Mexico. Copyright 2006 by the American Geophysical Union.

Geophysical Research Letters

Law of the sea, the continental shelf, and marine research

The question of the amount of seabed to which a coastal nation is entitled is addressed in the United Nations Convention on the Law of the Sea (UNCLOS). This treaty, ratified by 153 nations and in force since 1994, specifies national obligations, rights, and jurisdiction in the oceans, and it allows nations a continental shelf out to at least 200 nautical miles or to a maritime boundary. Article 76 (A76) of the convention enables coastal nations to establish their continental shelves beyond 200 nautical miles and therefore to control, among other things, access for scientific research and the use of seabed resources that would otherwise be considered to lie beyond national jurisdiction. To date, seven submissions for extended continental shelves (ECS) have been filed under UNCLOS (Table 1). These submissions have begun to define the ambiguities in A76. How these ambiguities are resolved into final ECS boundaries will probably set important precedents guiding the future delimitation of the ECS by the United States, which has not ratified the convention, and other coastal nations. This report uses examples from the first three submissions—by the Russian Federation, Brazil, and Australia—to identify outstanding issues encountered in applying A76 to ECS delimitation.

Eos, Transactions, American Geophysical Union

The Aleutian Low – Beaufort Sea Anticyclone: A climate index for predicting the timing of springtime melt in the Pacific Arctic cryosphere

Early and late extremes in the timing of snowmelt have recently been observed in the Pacific Arctic. Subseasonal-to-seasonal forecasts of this timing are important for industry, environmental management and Arctic communities. In northern Alaska, the timing is influenced by the advection of marine air from the north Pacific by the Aleutian Low, modulated by high pressure centered in the Beaufort Sea. A new climate index that integrates their interaction could advance melt predictions. We define this index based on 850 hPa geopotential height at four fixed locations referred to as the Aleutian Low –Beaufort Sea Anticyclone (ALBSA). During positive ALBSA in May, advection of +0.5-1.5 K/day is observed through the Bering Strait. ALBSA is correlated with both snowmelt in northern Alaska and the onset of sea ice melt over the adjacent seas. ALBSA, therefore, may be suitable for monitoring the relevant circulation patterns and for developing predictive tools.

Geophysical Research Letters

The destructive 1946 Unimak near-field tsunami: New evidence for a submarine slide source from reprocessed marine geophysical data

The M w 8.6 earthquake in 1946 off the Pacific shore of Unimak Island at the end of the Alaska Peninsula generated a far-field tsunami that crossed the Pacific to Antarctica. Its tsunami magnitude, 9.3, is comparable to the 9.1 magnitude of the 2011 Tohoku tsunami. On Unimak Island's Pacific shore, a runup of 42 m destroyed the lighthouse at Scotch Cap. Elsewhere, localized tsunamis with such high runups have been interpreted as caused by large submarine landslides. However, previous to this study, no landslide large enough to generate this runup was found in the area that is limited by the time interval between earthquake shaking and tsunami inundation at Scotch Cap. Reworking of a seismic reflection transect and colocated multibeam bathymetric surveys reveal a landslide block that may explain the 1946 high runup. It is seaward of Scotch Cap on the midslope terrace and within the time-limited area.

Geophysical Research Letters

Photogrammetric portrayal of Mars topography

Special photogrammetric techniques have been developed to portray Mars topography, using Mariner and Viking imaging and nonimaging topographic information and earth-based radar data. Topography is represented by the compilation of maps at three scales: global, intermediate, and very large scale. The global map is a synthesis of topographic information obtained from Mariner 9 and earth-based radar, compiled at a scale of 1:25,000,000 with a contour interval of 1 km; it gives a broad quantitative view of the planet. At intermediate scales, Viking Orbiter photographs of various resolutions are used to compile detailed contour maps of a broad spectrum of prominent geologic features; a contour interval as small as 20 m has been obtained from very high resolution orbital photography. Imagery from the Viking lander facsimile cameras permits construction of detailed, very large scale (1:10) topographic maps of the terrain surrounding the two landers; these maps have a contour interval of 1 cm. This paper presents several new detailed topographic maps of Mars.

Journal of Geophysical Research Solid Earth

Linking the10Be continental record of Lake Baikal to marine and ice archives of the last 50 ka: Implication for the global dust-aerosol input

We present here a 10 Be profile from the continental sediments of Lake Baikal (the world's largest fresh water lake), which, for the first time, shows the ≈ 40 ka 10 Be enhancement and a pattern that strongly matches those from the marine and ice records for the last 50 ka. This finding provides a new horizon for global and regional correlation of continental archives. Additionally, our VADM-predicted 10 Be production confirms and further strengthens a common global cause (geomagnetic field intensity) for the change in atmospheric 10 Be over the last 50 ka. We also show that most of the 10 Be inventory to the lake has been provided by riverine input, but with a significant addition from direct precipitation and dust-aerosol fallout. We estimate a higher dust-aerosol contribution of 10 Be during the Holocene and interstadial stage 3 (22–50 ka) as compared with the glacial period (12–22 ka).

Geophysical Research Letters

A preliminary assessment of geologic framework and sediment thickness studies relevant to prospective US submission on extended continental shelf

Under the provisions of Articles 76 and 77 of the United Nations Convention on the Law of the Sea (UNCLOS), coastal States have sovereign rights over the continental shelf territory beyond 200-nautical mile (nm) from the baseline from which the territorial sea is measured if certain conditions are met regarding the geologic and physiographic character of the legal continental shelf as defined in those articles. These claims to an extended continental shelf must be supported by relevant bathymetric, geophysical and geological data according to guidelines established by the Commission on the Limits of the Continental Shelf (CLCS, 1999). In anticipation of the United States becoming party to UNCLOS, Congress in 2001 directed the Joint Hydrographic Center/Center for Coastal and Ocean Mapping at the University of New Hampshire to conduct a study to evaluate data relevant to establishing the outer limit of the juridical continental shelf beyond 200 nm and to recommend what additional data might be needed to substantiate such an outer limit (Mayer and others, 2002). The resulting report produced an impressive and sophisticated GIS database of data sources. Because of the short time allowed to complete the report, all seismic reflection data were classified together; the authors therefore recommended that USGS perform additional analysis on seismic and related data holdings. The results of this additional analysis are the substance of this report, including the status of geologic framework, sediment isopach research, and resource potential in the eight regions1 identified by Mayer and others (2002) where analysis of seismic data might be crucial for establishing an outer limit . Seismic reflection and refraction data are essential in determining sediment thickness, one of the criteria used in establishing the outer limits of the juridical continental shelf. Accordingly, the initial task has been to inventory public-domain seismic data sources, primarily those regionally extensive data held within the Department of the Interior (DOI). The numerous seismic reflection and refraction surveys collected prior to 1970 by academic and governmental institutions are generally not included in this compilation, except where they provide unique data in a region. These data sources were omitted from this report because they were deemed to be of insufficient quality (poorly navigated or low resolution) to meet the CLCS standards for a submission, or they were redundant with higher-quality, more modern data. Hence, this report attempts to identify those data sets of highest utility for establishing the outer limits of the juridical continental shelf. If there was any ambiguity or uncertainty about the relevance of a data set to a continental shelf submission, either by its quality, location, or other parameter, it was included in this compilation. This report does not summarize other geophysical data (such as marine magnetics or gravity) that might be relevant to understanding crustal provenance and geological continuity. Detailed metadata tables and maps are included to facilitate the location and utilization of these sources when a comprehensive assessment (?desktop study?) is undertaken.

Open-File Report

Tectonic relations of carbon dioxide discharges and earthquakes

CO 2 ‐rich springs occur worldwide along major zones of seismicity. They are mostly in young orogenic belts, but some are in areas of rifting continental platforms. Analyses of 13 C content indicate that much of the CO 2 is derived from the mantle and that other important sources are the metamorphism of marine carbonate‐bearing sedimentary rocks and the degradation of organic material. The presence of calc‐silicate minerals, such as pumpellyite in metagraywacke, is evidence of former conversion of carbonate‐bearing rocks into calc‐silicate minerals and release of CO 2 . The CO 2 pressure in fractured rocks of a fault zone reduces the effective normal stress and, if it is sufficiently great, allows the fault to slip. If the pressure were maintained at a sufficiently high level, the fault behavior might be characterized by frequent small earthquakes and aseismic creep such as occur along active segments of the San Andreas system. The presence of CO 2 ‐rich springs may indicate a potentially hazardous seismic region. Monitoring of CO 2 discharges could be useful in earthquake prediction.

Journal of Geophysical Research B: Solid Earth

Multicomponent seismic methods for characterizing gas hydrate occurrences and systems in deep-water Gulf of Mexico

In-situ characterization and quantification of natural gas hydrate occurrences remain critical research directions, whether for energy resource, drilling hazard, or climate-related studies. Marine multicomponent seismic data provide the full seismic wavefield including partial redundancy, and provide a promising set of approaches for gas hydrate characterization. Numerous authors have demonstrated the possibilities of multicomponent data at study sites around the world. We expand on this work by investigating the utility of very densely spaced (10&rsquo;s of meters) multicomponent receivers (ocean-bottom cables, OBC, or ocean-bottom seismometers, OBS) for gas hydrate studies in the Gulf of Mexico and elsewhere. Advanced processing techniques provide high-resolution compressional-wave (PP) and converted shearwave (PS) reflection images of shallow stratigraphy, as well as P-wave and S-wave velocity estimates at each receiver position. Reflection impedance estimates can help constrain velocity and density, and thus gas hydrate saturation. Further constraint on velocity can be determined through identification of the critical angle and associated phase reversal in both PP and PS wideangle data. We demonstrate these concepts with examples from OBC data from the northeast Green Canyon area and numerically simulated OBS data that are based on properties of known gas hydrate occurrences in the southeast (deeper water) Green Canyon area. These multicomponent data capabilities can provide a wealth of characterization and quantification information that is difficult to obtain with other geophysical methods.

Green Canyon, Gulf of Mexico

Seismic detection and analysis of icequakes at Columbia Glacier, Alaska

Contributions to sea level rise from rapidly retreating marine-terminating glaciers are large and increasing. Strong increases in iceberg calving occur during retreat, which allows mass transfer to the ocean at a much higher rate than possible through surface melt alone. To study this process, we deployed an 11-sensor passive seismic network at Columbia Glacier, Alaska, during 2004&ndash;2005. We show that calving events generate narrow-band seismic signals, allowing frequency domain detections. Detection parameters were determined using direct observations of calving and validated using three statistical methods and hypocenter locations. The 1&ndash;3 Hz detections provide a good measure of the temporal distribution and size of calving events. Possible source mechanisms for the unique waveforms are discussed, and we analyze potential forcings for the observed seismicity.

Journal of Geophysical Research

Intrusive dike complexes, cumulate cores, and the extrusive growth of Hawaiian volcanoes

The Hawaiian Islands are the most geologically studied hot-spot islands in the world yet surprisingly, the only large-scale compilation of marine and land gravity data is more than 45 years old. Early surveys served as reconnaissance studies only, and detailed analyses of the crustal-density structure have been limited. Here we present a new chain-wide gravity compilation that incorporates historical island surveys, recently published work on the islands of Hawai‘i, Kaua‘i, and Ni‘ihau, and >122,000 km of newly compiled marine gravity data. Positive residual gravity anomalies reflect dense intrusive bodies, allowing us to locate current and former volcanic centers, major rift zones, and a previously suggested volcano on Ka‘ena Ridge. By inverting the residual gravity data, we generate a 3-D view of the dense, intrusive complexes and olivine-rich cumulate cores within individual volcanoes and rift zones. We find that the Hāna and Ka‘ena ridges are underlain by particularly high-density intrusive material (>2.85 g/cm 3 ) not observed beneath other Hawaiian rift zones. Contrary to previous estimates, volcanoes along the chain are shown to be composed of a small proportion of intrusive material (<30% by volume), implying that the islands are predominately built extrusively.

Hawai'i

Subglacial discharge at tidewater glaciers revealed by seismic tremor

Subglacial discharge influences glacier basal motion and erodes and redeposits sediment. At tidewater glacier termini, discharge drives submarine terminus melting, affects fjord circulation, and is a central component of proglacial marine ecosystems. However, our present inability to track subglacial discharge and its variability significantly hinders our understanding of these processes. Here we report observations of hourly to seasonal variations in 1.5&ndash;10&thinsp;Hz seismic tremor that strongly correlate with subglacial discharge but not with basal motion, weather, or discrete icequakes. Our data demonstrate that vigorous discharge occurs from tidewater glaciers during summer, in spite of fast basal motion that could limit the formation of subglacial conduits, and then abates during winter. Furthermore, tremor observations and a melt model demonstrate that drainage efficiency of tidewater glaciers evolves seasonally. Glaciohydraulic tremor provides a means by which to quantify subglacial discharge variations and offers a promising window into otherwise obscured glacierized environments.

Alaska

Rising methane emissions from northern wetlands associated with sea ice decline

The Arctic is rapidly transitioning toward a seasonal sea ice-free state, perhaps one of the most apparent examples of climate change in the world. This dramatic change has numerous consequences, including a large increase in air temperatures, which in turn may affect terrestrial methane emissions. Nonetheless, terrestrial and marine environments are seldom jointly analyzed. By comparing satellite observations of Arctic sea ice concentrations to methane emissions simulated by three process-based biogeochemical models, this study shows that rising wetland methane emissions are associated with sea ice retreat. Our analyses indicate that simulated high-latitude emissions for 2005&ndash;2010 were, on average, 1.7&thinsp;Tg&thinsp;CH 4 &thinsp;yr &minus;1 higher compared to 1981&ndash;1990 due to a sea ice-induced, autumn-focused, warming. Since these results suggest a continued rise in methane emissions with future sea ice decline, observation programs need to include measurements during the autumn to further investigate the impact of this spatial connection on terrestrial methane emissions.

Geophysical Research Letters

Laboratory electrical conductivity of marine gas hydrate

Methane hydrate was synthesized from pure water ice and flash frozen seawater, with varying amounts of sand or silt added. Electrical conductivity was determined by impedance spectroscopy, using equivalent circuit modeling to separate the effects of electrodes and to gain insight into conduction mechanisms. Silt and sand increase the conductivity of pure hydrate, we infer by contaminant NaCl contributing to conduction in hydrate, to values in agreement with resistivities observed in well logs through hydrate The addition of silt and sand lowers the conductivity of hydrate synthesized from seawater by an amount consistent with Archie's Law. All samples were characterized using cryogenic scanning electron microscopy and energy dispersive spectroscopy, which show good connectivity of salt and brine phases. Electrical conductivity measurements of pure hydrate and hydrate mixed with silt during pressure‐induced dissociation supports previous conclusions that sediment increases dissociation rate.

Geophysical Research Letters

Bølling-Allerød productivity in the subarctic Pacific driven by seasonal upwelling

The Bølling-Allerød deglacial event is marked by high diatom productivity and opal deposition throughout the subarctic Pacific. This opal could either constitute a strengthened biological pump and thus carbon sequestration, or a weakened biological pump and release of marine-sequestered CO 2 to the atmosphere. We quantify silicic acid supply at IODP Site U1340 in the Bering Sea using biogenic opal and δ 30 Si of Coscinodiscus , a diatom genus. These records, along with diatom environmental indicators, suggest the Bølling-Allerød had high silicic acid availability related to a shift from stratification to seasonal upwelling dynamics. We thus propose the primary cause of the high productivity event was increased macronutrient supply from vertical exchange that injected old, nutrient-rich, CO 2 -rich waters into the surface. Enhanced CO 2 release from the subarctic Pacific may help explain critical intervals of CO 2 rise that occur at the onsets of the Bølling-Allerød and PreBoreal.

Geophysical Research Letters