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At least 127 records · Page 7Linked to original sources

Accessory apatite from hybrid granitoid rocks of the southern Snake Range, Nevada

Analytical data, optical properties, and unit-cell parameters are presented for 24 samples of accessory apatites recovered from hybrid granitoid rocks of the southern Snake Range, Nev. A complete chemical analysis is given for one. In the Snake Creek-Williams Canyon outcrop area, where the hybrid rocks grade from granodiorite with 63 percent SiO 2 to a quartz monzonite with 76 percent SiO 2 within a horizontal distance of about 3 miles, abundance and crystal habit of the apatite change with rock chemistry. The apatite probably is slightly more than 90 mole percent fluorapatite in the most felsic rocks, slightly less in the most mafic. The range of F->OH substitution in apatite from this outcrop area is much smaller than in the coexisting biotites. Except for manganese, strontium, sodium, and the rare earths, there is very limited substitution for calcium in the crystal structure of these apatites. Apatites from the more mafic rocks tend to contain a lighter, more basic assemblage of rare earths, in agreement with results obtained for coexisting allanites, monazites, and zircons.

Nevada

Chemical structure of humic acids - Part 1, a generalized structural model

A new model is proposed for the structure of humic acids. In this model humic acid is pictured as being made up of a hierarchy of structural elements. At the lowest level in this hierarchy are simple phenolic, quinoid, and benzene carboxylic acid groups. These groups are bonded covalently into small particles. Particles of similar chemical structure are linked together by weak bonds to form "homogeneous" aggregates. Two or more different types of aggregates may be linked together to form mixed aggregates. Complexes of humic acid and clay minerals are also formed.

Journal of Research of the U.S. Geological Survey

Metamorphic rocks of the Yakutat-St. Elias area, south-central Alaska

Metamorphic rocks in the Yakutat-St. Elias area range in grade from zeolite to amphibolite facies. Radiometric age determinations on selected metamorphic rocks have helped to identify two major metamorphic events, one in Late Cretaceous time that was characterized by penetrative deformation, and one in the Miocene Epoch that resulted in widespread recrystallization and igneous intrusions. Mapped facies units show many discontinuities across major faults, and their distribution indicates major differential uplift between several structurally bound crustal blocks within a strongly deformed mobile belt west of the Art Lewis fault. Late Cretaceous metamorphic gradients indicate that the blocks have been tilted to the west or northwest parallel to their general structural grain. As mineral assemblages that were recrystallized during Miocene time occur on both sides of the Fairweather fault, large-scale, post-Miocene strike-slip movement along the fault is not indicated.

Alaska

Latest Quaternary paleoseismology and evidence of distributed dextral shear along the Mohawk Valley fault zone, northern Walker Lane, California

The dextral-slip Mohawk Valley fault zone (MVFZ) strikes northwestward along the eastern margin of the Sierra Nevada in the northern Walker Lane. Geodetic block modeling indicates that the MVFZ may accommodate ~3 mm/yr of regional dextral strain, implying that it is the highest slip-rate strike-slip fault in the region; however, only limited geologic data are available to constrain the system’s slip rate and earthquake history. We mapped the MVFZ using airborne lidar data and field observations and identified a site near Sulphur Creek for paleoseismic investigation. At this site, oblique dextral-normal faulting on the steep valley margin has created a closed depression that floods annually during spring snowmelt to form an ephemeral pond. We excavated three fault-perpendicular trenches at the site and exposed pond sediment that interfingers with multiple colluvial packages eroded from the scarp that bounds the eastern side of the pond. We documented evidence for four surface-rupturing earthquakes on this strand of the MVFZ. OxCal modeling of radiocarbon and luminescence ages indicates that these earthquakes occurred at 14.0 ka, 12.8 ka, 5.7 ka, and 1.9 ka. The mean ~4 kyr recurrence interval is inconsistent with slip rates of ~3 mm/yr; these rates imply surface ruptures of more than 10 m per event, which is geologically implausible for the subdued geomorphic expression and 60 km length of the MVFZ. We propose that unidentified structures not yet incorporated into geodetic models may accommodate significant dextral shear across the northern Walker Lane, highlighting the role of distributed deformation in this region.

California

Exploration and discovery in Yellowstone Lake: Results from high-resolution sonar imaging, seismic reflection profiling, and submersible studies

Discoveries from multi-beam sonar mapping and seismic reflection surveys of the northern, central, and West Thumb basins of Yellowstone Lake provide new insight into the extent of post-collapse volcanism and active hydrothermal processes occurring in a large lake environment above a large magma chamber. Yellowstone Lake has an irregular bottom covered with dozens of features directly related to hydrothermal, tectonic, volcanic, and sedimentary processes. Detailed bathymetric, seismic reflection, and magnetic evidence reveals that rhyolitic lava flows underlie much of Yellowstone Lake and exert fundamental control on lake bathymetry and localization of hydrothermal activity. Many previously unknown features have been identified and include over 250 hydrothermal vents, several very large (>500 m diameter) hydrothermal explosion craters, many small hydrothermal vent craters (∼1–200 m diameter), domed lacustrine sediments related to hydrothermal activity, elongate fissures cutting post-glacial sediments, siliceous hydrothermal spire structures, sublacustrine landslide deposits, submerged former shorelines, and a recently active graben. Sampling and observations with a submersible remotely operated vehicle confirm and extend our understanding of the identified features. Faults, fissures, hydrothermally inflated domal structures, hydrothermal explosion craters, and sublacustrine landslides constitute potentially significant geologic hazards. Toxic elements derived from hydrothermal processes also may significantly affect the Yellowstone ecosystem.

Wyoming

Subsurface structure across the Tacoma Basin, Washington State, using trans-dimensional Bayesian inversion of fundamental mode spatial autocorrelation data

Spatial autocorrelation (SPAC), the azimuthal average of the normalized cross-correlation between equidistant station pairs deployed in a 2-D array, is widely used to image the subsurface structure. However, the rigorous estimate of subsurface structure and its uncertainties as a function of depth using SPAC data is challenging due to the nonlinear relation between the SPAC data and Earth structure as well as the trade-off between depth and velocity. Additionally, data noise is strongly correlated due to data processing (e.g. filtering, stacking from multiple time segments and azimuthal averaging). Most studies do not account for the correlated noise and fix the ratio of compressional-wave velocity ( V P ) to shear-wave velocity ( V s ) (i.e. V P / V s ratio) and the number of layers, both of which are typically unknown. To address these challenges, we develop a hierarchical trans-dimensional Bayesian inversion of fundamental mode of SPAC data that properly accounts for the correlated data noise, samples the V P / V s ratio and relaxes the number of layers (i.e. model parametrization) to be unknown in the inversion. We further examine the limitation of using only fundamental modes in the inversion. Our synthetic experiments show that the inversion recovers an incorrect model unless we sample the correlated noise and V P / V s ratio in the inversion. The inversion is then applied to SPAC data acquired at 19 sites across the Tacoma basin in Washington State to characterize the V s and the time-averaged V s over 30-m depth ( V s 30 ). Our results show that the V s 30 varies from ∼200 to 800 m s −1 . The V s 30 within the basin is higher in the middle and lower on the east and west sides. We find that these V s 30 values vary with geologic unit. The uncertainties for V s 30 are within 20 m s −1 in average except for the most eastern site TB28. Additionally, the uncertainties are greater for deeper depths beneath most of the sites as the sensitivity decreases as a function of depth. The Vs structure as a function of depth is also complex beneath some sites, possibly because the SPAC curves are affected by higher order Rayleigh modes that are not considered in the inversion. To better constrain the deeper V s structure, V s 30 and/or other average measures of V s over depth, additional constraints from complementary data, such as ellipticity or geologic data are needed. Moreover, our synthetic experiments show that higher order modes can have significant effect in the inversion results, particularly when there is a low-velocity layer.

Washington

Application of laser microprobe (LAMMA 1000) to "fingerprinting" of coal constituents in bituminous coal

A laser microprobe (LAMMA-1000) microchemical analysis of vitrinites of different morphologies but similar reflectances within the same bituminous coal bed indicates distinct “fingerprint” spectra. The banded form of vitrinite contains Li, Ti, Ba, Sr, F, and Cl which were not detected in the nonbanded vitrinite. These differences may indicate a different plant source or the introduction of these elements from fluids mobilized during diagenesis. The nonbanded vitrinite (called corpocollinite), which was contained in a pyrite coal-ball seed fern permineralization of Myeloxylon , may have been protected from influx of these elements due to entrapment by pyrite during an early peat stage. An ion at M/Z 65, which is characteristic of the banded vitrinite, may indicate C 5 H 5 + and, perhaps a difference in the chemical structure of the two vitrinites. These results demonstrate that “fingerprint” spectra can be obtained from vitrinite macerals by LAMMA and that these “fingerprints” have genetic implications.

International Journal of Coal Geology

Resolution analysis of finite fault source inversion using one- and three-dimensional Green's functions 1. Strong motions

We develop a methodology to perform finite fault source inversions from strong motion data using Green's functions (GFs) calculated for a three-dimensional (3-D) velocity structure. The 3-D GFs are calculated numerically by inserting body forces at each of the strong motion sites and then recording the resulting strains along the target fault surface. Using reciprocity, these GFs can be recombined to represent the ground motion at each site for any (heterogeneous) slip distribution on the fault. The reciprocal formulation significantly reduces the required number of 3-D finite difference computations to at most 3NS, where NS is the number of strong motion sites used in the inversion. Using controlled numerical resolution tests, we have examined the relative importance of accurate GFs for finite fault source inversions which rely on near-source ground motions. These experiments use both 1-D and 3-D GFs in inversions for hypothetical rupture models in order (1) to analyze the ability of the 3-D methodology to resolve trade-offs between complex source phenomena and 3-D path effects, (2) to address the sensitivity of the inversion results to uncertainties in the 3-D velocity structure, and (3) to test the adequacy of the 1-D GF method when propagation effects are known to be three-dimensional. We find that given "data" from a prescribed 3-D Earth structure, the use of well-calibrated 3-D GFs in the inversion provides very good resolution of the assumed slip distribution, thus adequately separating source and 3-D propagation effects. In contrast, using a set of inexact 3-D GFs or a set of hybrid 1-D GFs allows only partial recovery of the slip distribution. These findings suggest that in regions of complex geology the use of well-calibrated 3-D GFs has the potential for increased resolution of the rupture process relative to 1-D GFs. However, realizing this full potential requires that the 3-D velocity model and associated GFs should be carefully validated against the true 3-D Earth structure before performing the inverse problem with actual data.

Journal of Geophysical Research B: Solid Earth

Relations between thermal, photographic, and topographic linears and mapped and measured structures in a Precambrian terrane in Colorado

Comparison of orientation of faults, foliations, and joints, observed during geologic mapping in Colorado, with thermal, photographic, and topographic linears shows that topographic linears are statistically useful indicators of mappable faults and fractures, photographic linears are less useful, and thermal linears, believed to represent zones of moisture concentration, are parallel to faults, foliations, and, a statistically minor, but more open joint set.

Colorado

Modes of occurrence of mercury and other trace elements in coals from the warrior field, Black Warrior Basin, Northwestern Alabama

The mineralogic residence and abundance of trace metals is an important environmental issue. Data from the USGS coal quality database show that potentially toxic elements, including Hg, As, Mo, Se, Cu, and Tl are enriched in a subset of coal samples in the Black Warrior Basin of Alabama, USA. Although the coal as-mined typically is low in these elements, localized enrichments occur in high-pyrite coals and near faults. Microscopic analyses demonstrate that the residence of these elements is dominantly in a late-stage pyrite associated with structurally disrupted coal. Further, our data suggest addition of Hg to the coal matrix as well. The source of these trace elements was hydrothermal fluids driven into the Black Warrior Basin by Alleghanian age tectonism. ?? 2004 Published by Elsevier B.V.

International Journal of Coal Geology

Applications of remote sensing to structural interpretations in the southern Appalachians

Remote sensing is the technology of studying distant objects by measuring and recording energy from one or more segments of the electromagnetic spectrum. Imaging sensors which operate from medium- and high-altitude aircraft or from spacecraft can provide a synoptic view of large areas and of surface phenomena not evident in the field. Image-acquiring systems and instruments have been designed to partially automate data collection and to reduce the time devoted to analysis, information extraction, and detection of changes of surface phenomena. Among these phenomena are the surface distribution of heat, moisture, snow, water, vegetation, and cultural features. When coupled with ancillary data, including field surveys, sensor data provide useful information for the recognition and mapping of regional structure, jointing patterns, drainage patterns, fault and fracture traces, and rock types. The recognition of several major linear surface features, two of which proved to be traces of previously unrecognized faults (the Canebrake and the Coeburn faults) in the Appalachian Plateaus, demonstrates the pragmatic application of aircraft and spacecraft remote sensing to geological investigations in the Appalachians.

Virginia, West Virginia

Petrography and structural relations of granitic basement rocks in the Monterey Bay area, California

In the past, the granitic basement of the Coast Ranges has been thought to be dominantly quartz diorite and low in K-feldspar. However, a study of outcrops around Monterey Bay, basement well samples, and dredge samples from Monterey Bay shows that the granitic basement averages about 15 to 20 percent K-feldspar. Therefore, as a sedimentary provenance, the basement around Monterey Bay could have contributed abundant K-feldspar to the Cenozoic sedimentary deposits of the region; that is, in the Monterey Bay area the local basement is an adequate source for the abundant K-feldspar in the sedimentary units. The distribution of basement rocks and mapped faults, coupled with gravity-geophysical data, suggests that the area between the San Andreas and Sur-Nacimiento fault zones (the Salinian block) near Monterey Bay is broken into several discrete structural blocks. Some of these blocks juxtapose not only different basement rocks, but also different contour patterns on the buried basement surface. These features suggest large strike-slip movements along some faults within the Salinian block in the Monterey Bay area.

California

Minor element distribution in iron disulfides in coal: a geochemical review

Electron beam microanalysis of coal samples in U.S. Geological Survey (USGS) labs confirms that As is the most abundant minor constituent in Fe disulfides in coal and that Se, Ni, and other minor constituents are present less commonly and at lower concentrations than those for As. In nearly all cases, Hg occurs in Fe disulfides in coal at concentrations below detection by electron beam instruments. Its presence is shown by laser ablation ICP-MS, by selective leaching studies of bulk coal, and by correlation with Fe disulfide proxies such as total Fe and pyritic sulfur. Multiple generations of Fe disulfides are present in coal. These commonly show grain-to-grain and within-grain minor- or trace element compositional variation that is a function of the early diagenetic, coalification, and post-coalification history of the coal. Framboidal pyrite is almost always the earliest Fe disulfide generation, as shown by overgrowths of later Fe disulfides which may include pyrite or marcasite. Cleat- (or vein) pyrite (or marcasite) is typically the latest Fe disulfide generation, as shown by cross-cutting relations. Cleat pyrite forms by fluid migration within a coal basin and consequently may be enriched in elements such as As by deposition from compaction-driven fluids, metal enriched basinal brines or hydrothermal fluids. In some cases, framboidal pyrite shows preferential Ni enrichment with respect to co-occurring pyrite forms. This is consistent with bacterial complexing of metals in anoxic sediments and derivation of framboidal pyrite from greigite (Fe 3 S 4 ), an Fe monosulfide precursor to framboidal pyrite having the thio-spinel structure which accommodates transition metals. Elements such as As, Se, and Sb substitute for S in the pyrite structure whereas metals, including transition metals, Hg and Pb, are thought to substitute for Fe. Understanding the distribution of minor and trace elements in Fe disulfides in coal has important implications for their availability to the environment through coal mining and use, as well as for potential reduction by coal preparation, and for delineating diagenetic compositional changes throughout and after coal formation.

International Journal of Coal Geology

Primary centers and secondary concentrations of tectonic activity through time in the western hemisphere of Mars

Five main stages of radial and concentric structures formed around Tharsis from the Noachian through the Amazonian as determined by geologic mapping of 24,452 structures within the stratigraphic framework of Mars and by testing their radial and concentric orientations. Tectonic activity peaked in the Noachian (stage 1) around the largest center, Claritas, an elongate center extending more than 20° in latitude and defined by about half of the total grabens which are concentrated in the Syria Planum, Thaumasia, and Tempe Terra regions. During the Late Noachian and Early Hesperian (stage 2), extensional structures formed along the length of present-day Valles Marineris and in Thaumasia (with a secondary concentration near Warrego Vallis) radial to a region just to the south of the central margin of Valles Marineris. Early Hesperian (stage 3) radial grabens in Pavonis, Syria, Ulysses, and Tempe Terra and somewhat concentric wrinkle ridges in Lunae and Solis Plana and in Thaumasia, Sirenum, Memnonia, and Amazonis are centered northwest of Syria with secondary centers at Thaumasia, Tempe Terra, Ulysses Fossae, and western Valles Marineris. Late Hesperian/Early Amazonian (stage 4) structures around Alba Patera, the northeast trending alignment of Tharsis Montes, and Olympus Mons appears centered on Alba Patera. Stage 5 structures (Middle-Late Amazonian) represent the last pulse of Tharsis-related activity and are found around the large shield volcanoes and are centered near Pavonis Mons. Tectonic activity around Tharsis began in the Noachian and generally decreased through geologic time to the Amazonian. Statistically significant radial distributions of structures formed during each stage, centered at different locations within the higher elevations of Tharsis. Secondary centers of radial structures during many of the stages appear related to previously identified local magmatic centers that formed at different times and locations throughout Tharsis.

Journal of Geophysical Research E: Planets

Three-dimensional basin and fault structure from a detailed seismic velocity model of Coachella Valley, Southern California

The Coachella Valley in the northern Salton Trough is known to produce destructive earthquakes, making it a high seismic hazard area. Knowledge of the seismic velocity structure and geometry of the sedimentary basins and fault zones is required to improve earthquake hazard estimates in this region. We simultaneously inverted first P wave travel times from the Southern California Seismic Network (39,998 local earthquakes) and explosions (251 land/sea shots) from the 2011 Salton Seismic Imaging Project to obtain a 3-D seismic velocity model. Earthquakes with focal depths ≤10 km were selected to focus on the upper crustal structure. Strong lateral velocity contrasts in the top ~3 km correlate well with the surface geology, including the low-velocity (<5 km/s) sedimentary basin and the high-velocity crystalline basement rocks outside the valley. Sediment thickness is ~4 km in the southeastern valley near the Salton Sea and decreases to <2 km at the northwestern end of the valley. Eastward thickening of sediments toward the San Andreas fault within the valley defines Coachella Valley basin asymmetry. In the Peninsular Ranges, zones of relatively high seismic velocities (~6.4 km/s) between 2 to 4 km depth may be related to Late Cretaceous mylonite rocks or older inherited basement structures. Other high-velocity domains exist in the model down to 9 km depth and help define crustal heterogeneity. We identify a potential fault zone in Lost Horse Valley unassociated with mapped faults in Southern California from the combined interpretation of surface geology, seismicity, and lateral velocity changes in the model.

California

Silurian and Devonian miogeosynclinal and transitional rocks of the Fish Creek Reservoir window, central Idaho

Documentation of Devonian continental-shelf shallow-water carbonate rocks in the core of the Fish Creek Reservoir window shifts the known westernmost limit of the Devonian miogeosyncline 50 km (30 mi) southwest across the structural grain from the well-known miogeosynclinal sequence in the Lost River Range. The miogeosynclinal carbonate sequence in the window has a minimum thickness of 450 m (1,500 ft). It comprises the upper Lower Devonian (Emsian) and lower Middle Devonian (Eifelian) Carey Dolomite (new), the upper Middle Devonian (Givetian) and Upper Devonian Jefferson Formation, and the Upper Devonian Picabo Formation (new). Conodont faunas precisely date the Carey. The Picabo Formation, composed of interbedded sandy dolomite-pebble conglomerate and dolomitic quartzose sandstone, is unlike any previously described formation of Late Devonian or Early Mississippian age in central Idaho. It resembles parts of the Stansbury, Beirdneau, Leatham, and Victoria Formations, which reflect areas of local Late Devonian uplift and erosion of older shelf rocks in northern Utah and southeastern Idaho. Transitional (continental-slope) rocks of the Roberts Mountains Formation representing reef and offreef facies are thrust over the Devonian shelf sequence within the Fish Creek Reservoir window. The Roberts Mountains Formation here is precisely dated as latest Silurian (Pridolian, eosteinhornensis Zone) through earliest Devonian (Lochkovian) by a sequence of conodont faunas. The easternmost known exposures of possible Devonian siliceous facies rocks assigned to the Milligen(?) Formation are present less than 4.8 km (3 mi) southwest of the shelf sequence. Structural relations and paleotectonic reconstructions suggest that they have a minimum eastward translation of 32 km (20 mi). The Devonian continent-ocean basin interface, along which the Antler orogenic belt developed at this latitude, probably was located near the east edge of the present Idaho batholith.

Idaho

Boron-bearing potassium feldspar of authigenic origin in closed-basin deposits

Silicic vitric tuffs in saline, alkaline lacustrine deposits are commonly altered to a variety of zeolites and potassium feldspar. The tuffs generally show a lateral gradation, in a basinward direction, of fresh glass to zeolites and then to potassium feldspar. Zeolites were formed early in diagenesis by reaction of the glass with the interstitial water. The feldspar, however, was formed later by reaction of the zeolites with interstitial water, and its formation can be correlated with water of relatively high salinity and alkalinity. Semiquantitative spectrographic analyses for boron in the zeolites and potassium feldspar show that most of the boron resides in the relatively late feldspar. The boron content of the zeolites is commonly less than 100 ppm, whereas the boron content of the potassium feldspar is commonly greater than 1,000 ppm. Boron apparently substitutes for aluminum in the feldspar structure and causes distortion of the monoclinic unit cell such that the b and c dimensions are shortened. These boron-bearing potassium feldspars having anomalous cell parameters seem unique to saline, alkaline lacustrine deposits and could serve as a prospecting aid for locating buried saline minerals.

Journal of Research of the U.S. Geological Survey