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Research in the United States relative to geochemistry and health

Increasing concern regarding the effects of the geochemical environment on health in the United States has fostered research studies in a number of universities and government agencies. The necessity to evaluate the effects of natural and man-made elemental excesses in the environment on health requires the establishment of requirements and tolerance limits for the various elements in water and crops. Maps of the geographic distribution of these elements in rocks, surficial materials and ground and surface waters are also essential for comparison with the occurrence of disease. Funding support for research projects that relate to various parameters of these problems emanates largely from a few federal agencies, and much of the work is conducted at government, university and private facilities. An example of the latter is the National Academy of Sciences-National Research Council, which has several components that are addressing a variety of comparative studies of the geochemical environment related to health; studies involve specific trace elements (like selenium and magnesium), diseases (like cancer, urolithiasis and cardiovascular disease), other health factors (like aging and nutrition) and links with timely major problems (like the health effects of greatly increasing the use of coal).

Physics and Chemistry of the Earth↗

Coastal processes influencing water quality at Great Lakes beaches

In a series of studies along the Great Lakes, U.S. Geological Survey scientists are examining the physical processes that influence concentrations of fecal indicator bacteria and related pathogens at recreational beaches. These studies aim to estimate human health risk, improve management strategies, and understand the fate and transport of microbes in the nearshore area. It was determined that embayed beaches act as traps, accumulating Escherichia coli (E. coli) and other bacteria in the basin and even in beach sand. Further, shear stress and wave run-up could resuspend accumulated bacteria, leading to water-contamination events. These findings are being used to target beach design and circulation projects. In previous research, it was determined that E. coli followed a diurnal pattern, with concentrations decreasing throughout the day, largely owing to solar inactivation, but rebounding overnight. Studies at a Chicago beach identified the impact of wave-induced mass transport on this phenomenon, a finding that will extend our understanding of bacterial fate in the natural environment. In another series of studies, scientists examined the impact of river outfalls on bacteria concentrations, using mechanistic and empirical modeling. Through these studies, the models can indicate range and extent of impact, given E. coli concentration in the source water. These findings have been extended to extended lengths of coastlines and have been applied in beach management using empirical predictive modeling. Together, these studies are helping scientists identify and eliminate threats to human and coastal health.

Great Lakes Beaches↗

Linking scale-specific sinuosity to hydrogeomorphic domains in Alaska watersheds

River meander patterns arise from geomorphological processes influenced by climate, geology, terrain, and hydrology. These processes produce a wide spectrum of sinuous channel and meander forms, and understanding them is essential for land management practices, such as natural channel restoration (Dominguez et al., 2018), flood and erosion control, bank stabilization (U.S. Department of Interior, 2015), and riparian corridor and agricultural land management (Ran, et al., 2022; Yu, et al., 2023; Zhu et al., 2022). Studies of meander migration provide insight into sediment dynamics and river ecosystem health (Ielpi et al. 2023, Constantine et al., 2014). A river’s natural ability to clean itself, or reduce pollutants, through physical, chemical, and biological processes, also termed self-purification capacity, has been linked to river sinuosity (Xiao et al, 2019, 2025). Scale-specific sinuosity (S3) is an easily computed metric for characterizing planform meander bend geometry across a range of measurement scales (Stanislawski et al., 2023). Unlike the traditional single summary value of sinuosity for a stream section, S3 estimates the relative distribution of meander‑bend sizes, such as peak‑to‑trough lengths, within a planform linear representation of a stream section, along with the relative contributions of these bend sizes to its overall sinuosity. The aim of this study is to assess the potential of S3 as a diagnostic geomorphic metric with applications to process-based river and fluvial domain classification. Rivers vary widely in their sensitivity to change depending on sediment and bedload materials, landscape position, and hydroclimatic variability, including flooding or drought. River classification systems were developed to organize the diversity of river forms and processes in ways that support both scientific understanding and management needs. Classification provides a framework for geomorphological analyses related to resource assessment, habitat evaluation, and mitigation of natural or human-driven disturbances. Process-based classification systems help predict how channels respond to changes in flow or sediment regimes (Buffington and Montgomery, 2022), and also support resource exploration because ecological habitats, mineral deposits, and other natural resources often correspond to sediment characteristics that vary systematically across channel types (Rosgen, 1994; Wheaton et al., 2013; Wheaton et al., 2015). Planform-based metrics such as channel sinuosity have long been components of river classification systems (Rosgen, 1994; Wheaton et al., 2015; Buffington and Montgomery, 2022), where sinuosity is measured as a simple ratio of path length over end-to-end distance.

Alaska↗

Preface: Multiscale feedbacks in ecogeomorphology

Geomorphic systems are known to exhibit nonlinear responses to physical–biological feedbacks (Thornes, 1985; Baas, 2002; Reinhardt et al., 2010). These responses make understanding and/or predicting system response to change highly challenging. With growing concerns over ecosystem health, a pressing need exists for research that tries to elucidate these feedbacks (Jerolmack, 2008; Darby, 2010; National Research Council, 2010). A session was convened at the Fall 2008 meeting of the American Geophysical Union (AGU) to provide an outlet for some of this truly interdisciplinary and original research, which is central to understanding geomorphic and ecological dynamics. The session attracted over 39 contributions, which were divided into two well-attended oral sessions and a very busy poster session. This special issue presents new research from the AGU session, which highlights clear physical–biological feedbacks. The aim is to bring together contrasting perspectives on biological and geomorphic feedbacks in a diversity of physiographic settings, ranging from wetlands and estuaries, through rivers, to uplands. These papers highlight biological and physical feedbacks which involve the modulation or amplification of geomorphic processes. These papers will be of interest to a core geomorphology audience, and should also draw attention from the fields of ecohydraulics, hydroecology, ecohydrology, ecomorphology, biogeochemistry and biogeography, and biogeomorphology as well as the more traditional fields of hydrology, ecology and biology. In this preface to the special issue, we a) review past contributions to the emerging field of ecogeomorphology and related disciplines, b) provide some context for how this topical special issue came to fruition, and c) summarize the contributions to this special issue.

Geomorphology↗

Iron mineralogy and bioaccessibility of dust generated from soils as determined by reflectance spectroscopy and magnetic and chemical properties--Nellis Dunes recreational area, Nevada

Atmospheric mineral dust exerts many important effects on the Earth system, such as atmospheric temperatures, marine productivity, and melting of snow and ice. Mineral dust also can have detrimental effects on human health through respiration of very small particles and the leaching of metals in various organs. These effects can be better understood through characterization of the physical and chemical properties of dust, including certain iron oxide minerals, for their extraordinary radiative properties and possible effects on lung inflammation. Studies of dust from the Nellis Dunes recreation area near Las Vegas, Nevada, focus on characteristics of radiative properties (capacity of dust to absorb solar radiation), iron oxide mineral type and size, chemistry, and bioaccessibility of metals in fluids that simulate human gastric, lung, and phagolysosomal fluids. In samples of dust from the Nellis Dunes recreation area with median grain sizes of 2.4, 3.1, and 4.3 micrometers, the ferric oxide minerals goethite and hematite, at least some of it nanosized, were identified. In one sample, in vitro bioaccessibility experiments revealed high bioaccessibility of arsenic in all three biofluids and higher leachate concentration and bioaccessibility for copper, uranium, and vanadium in the simulated lung fluid than in the phagolysosomal fluid. The combination of methods used here to characterize mineral dust at the Nellis Dunes recreation area can be applied to global dust and broad issues of public health.

Nevada↗

Stream temperature prediction in a shifting environment: The influence of deep learning architecture

Stream temperature is a fundamental control on ecosystem health. Recent efforts incorporating process guidance into deep learning models for predicting stream temperature have been shown to outperform existing statistical and physical models. This performance is in part because deep learning architectures can actively learn spatiotemporal relationships that govern how water and energy propagate through a river network. However, exploration of how spatiotemporal awareness and process guidance influence a model's generalizability under shifting environmental conditions such as climate change is limited. Here, we use Explainable Artificial Intelligence (XAI) to interrogate how differing deep learning architectures affect a model's learned spatial and temporal dependencies, and how those learned dependencies affect a model's ability to maintain high accuracy when applied to unseen environmental conditions. Using the Delaware River Basin in the northeastern United States as a test case, we compare two spatiotemporally aware process-guided deep learning models for predicting stream temperature (a recurrent graph convolution network—RGCN, and a temporal convolution graph model—Graph WaveNet). Both models achieve equally high predictive performance when testing data are well represented in the training data (test root mean squared errors of 1.64°C and 1.65°C); however, Graph WaveNet significantly outperforms RGCN in 4 out of 5 experiments where test partitions represent different types of unseen environmental conditions. XAI results show that the architecture of Graph WaveNet leads to learned spatial relationships with greater fidelity to physical processes, and that this fidelity improves the generalizability of the model when applied to shifting and/or unseen environmental conditions.

Delaware River Basin↗

Urban development results in stressors that degrade stream ecosystems

In 2003, eighty-three percent of Americans lived in metropolitan areas, and considerable population increases are predicted within the next 50 years. Nowhere are the environmental changes associated with urban development more evident than in urban streams. Contaminants, habitat destruction, and increasing streamflow flashiness resulting from urban development have been associated with the disruption of biological communities, particularly the loss of sensitive aquatic biota. Every stream is connected downstream to other water bodies, and inputs of contaminants and (or) sediments to streams can cause degradation downstream with adverse effects on biological communities and on economically valuable resources, such as fisheries and tourism. Understanding how algal, invertebrate, and fish communities respond to physical and chemical stressors associated with urban development can provide important clues on how multiple stressors may be managed to protect stream health as a watershed becomes increasingly urbanized. This fact sheet highlights selected findings of a comprehensive assessment by the National Water-Quality Assessment Program of the U.S. Geological Survey (USGS) of the effects of urban development on stream ecosystems in nine metropolitan study areas.

Fact Sheet↗

Gaps in water quality modeling of hydrologic systems

This review assesses gaps in water quality modeling, emphasizing opportunities to improve next-generation models that are essential for managing water quality and are integral to meeting goals of scientific and management agencies. In particular, this paper identifies gaps in water quality modeling capabilities that, if addressed, could support assessments, projections, and evaluations of management alternatives to support ecosystem health and human beneficial use of water resources. It covers surface water and groundwater quality modeling, dealing with a broad suite of physical, biogeochemical, and anthropogenic drivers. Modeling capabilities for six constituents (or constituent categories) are explored: water temperature, salinity, nutrients, sediment, geogenic constituents, and contaminants of emerging concern. Each constituent was followed through the coupled atmospheric-hydrologic-human system, with prominent modeling gaps described for a diverse array of relevant inputs, processes, and human activities. Commonly identified modeling gaps primarily fall under three types: (1) model gaps, (2) data gaps, and (3) process understanding gaps. In addition to potential solutions for addressing specific individual modeling limitations, some broad approaches (e.g., enhanced data collection and compilation, machine learning, reduced-complexity modeling) are discussed as ways forward for tackling multiple gaps. This gap analysis establishes a framework of diverse approaches that may support improved process representation, scale, and accuracy of models for a wide range of water quality issues.

Water↗

Identify potential lock treatment options to prevent movement of aquatic invasive species through the Chicago Area Waterways System (CAWS)

Introduction The Illinois River is a primary tributary of the Mississippi River, connecting with the Mississippi at Grafton, Illinois. The headwaters of the river are at the confluence of the Des Plaines and Kankakee Rivers in eastern Grundy County, Illinois. Approximately 273 miles long, it runs through the heart of Illinois and is the connection between the Mississippi River and Lake Michigan in the Great Lakes basin. Because of this connection, there is concern about the potential for introduced aquatic species in one basin to migrate through this connection into the other basin. A prime example of this are the Asian carps, which were introduced into commercial fishing ponds in Arkansas in the 1970s and, following escape, are now making their way up the Mississippi, Illinois, and Missouri Rivers. Options are being investigated to minimize or prevent non-native aquatic species from invading either basin through the Illinois River connection and eventually having detrimental impacts on the basin into which they migrate. The Illinois River has a series of locks and dams that are used to facilitate the navigation of commercial and recreational shipping from Chicago to Beardstown, Illinois. One option under consideration is to develop a lock treatment process that stops aquatic invasive species from entering (and moving through) the Chicago Area Waterway System (CAWS), while at the same time not unduly impeding the movement of barges and other boat traffic between Lake Michigan and the Mississippi River. The purpose this report was to evaluate the feasibility of using chemical and (or) physical treatments to determine if a sufficiently efficacious option could be used to prevent aquatic invasive species from being transported through the locks. Approximately 30 chemical and physical control options were evaluated on the basis of nine factors ranging from viability for use on a large scale, rapid lethality, human health effects, and potential damage to lock structures and vessel hulls. Compatibility of the various options was also evaluated to assess the possibility that options could be combined to enhance efficacy. Engineering requirements were not considered as part of this evaluation. The available information suggests that hot water at 43 °C and ozone are the most feasible options.

Chicago Area Waterway System↗

Comparative health assessment of western Pacific leatherback turtles (Dermochelys coriacea) foraging off the coast of California, 2005-2007

Leatherback turtles ( Dermochelys coriacea ) are critically endangered, primarily threatened by the overharvesting of eggs, fisheries entanglement, and coastal development. The Pacific leatherback population has experienced a catastrophic decline over the past two decades. Leatherbacks foraging off the coast of California are part of a distinct Western Pacific breeding stock that nests on beaches in Indonesia, Papua New Guinea, and the Solomon Islands. Although it has been proposed that the rapid decline of Pacific leatherback turtles is due to increased adult mortality, little is known about the health of this population. Health assessments in leatherbacks have examined females on nesting beaches, which provides valuable biological information, but might have limited applicability to the population as a whole. During September 2005 and 2007, we conducted physical examinations on 19 foraging Pacific leatherback turtles and measured normal physiologic parameters, baseline hematologic and plasma biochemistry values, and exposure to heavy metals (cadmium, lead, and mercury), organochlorine contaminants, and domoic acid. We compared hematologic values of foraging Pacific leatherbacks with their nesting counterparts in Papua New Guinea ( n =11) and with other nesting populations in the Eastern Pacific in Costa Rica ( n =8) and in the Atlantic in St. Croix ( n =12). This study provides the most comprehensive assessment to date of the health status of leatherbacks in the Pacific. We found significant differences in blood values between foraging and nesting leatherbacks, which suggests that health assessment studies conducted only on nesting females might not accurately represent the whole population. The establishment of baseline physiologic data and blood values for healthy foraging leatherback turtles, including males, provides valuable data for long-term health monitoring and comparative studies of this endangered population.

California↗

Understanding beach health throughout the Great Lakes-Entering a new era of investigations

For over a decade, the U.S. Geological Survey (USGS) has been a leader in the science of beach health. The overall mission of this work is to provide science-based information and methods that will allow beach managers to more accurately make beach closure and advisory decisions, understand the sources and physical processes affecting beach contaminants, and understand how science-based information can be used to mitigate and restore beaches and protect the public. The work consists of four science elements-real-time assessments; pathogens and microbial source tracking; coastal processes; and data analysis, interpretation, and communication - which are described in this fact sheet. Some of the key questions for USGS beach research are the following: Are there better ways to inform the public whether they can use a beach without risking their health? How do new rapid analytical methods compare to traditional methods for determining concentrations of fecal-indicator bacteria at beaches? Are pathogens present at beaches and, if so, how do they get to the beach, and what is their source? How do sand movement and wave action on the beach affect fecal-indicator-bacteria and pathogen concentrations in the lake water? What are the best indicators of pathogenic microorganisms? With so many potential sources of fecal contamination at a beach, what methods can be used to distinguish the contributions from humans? What characteristics of beaches contribute most to influencing bacterial indicator and pathogen concentrations in beach sands and groundwater?

Fact Sheet↗

Measuring polar bear health using allostatic load

The southern Beaufort Sea polar bear sub-population ( Ursus maritimus ) has been adversely affected by climate change and loss of sea ice habitat. Even though the sub-population is likely decreasing, it remains difficult to link individual polar bear health and physiological change to sub-population effects. We developed an index of allostatic load, which represents potential physiological dysregulation. The allostatic load index included blood- and hair-based analytes measured in physically captured southern Beaufort bears in spring. We examined allostatic load in relation to bear body condition, age, terrestrial habitat use and, over time, for bear demographic groups. Overall, allostatic load had no relationship with body condition. However, allostatic load was higher in adult females without cubs that used terrestrial habitats the prior year, indicating potential physiological dysregulation with land use. Allostatic load declined with age in adult females without cubs. Sub-adult males demonstrated decreased allostatic load over time. Our study is one of the first attempts to develop a health scoring system for free-ranging polar bears, and our findings highlight the complexity of using allostatic load as an index of health in a wild species. Establishing links between individual bear health and population dynamics is important for advancing conservation efforts.

Alaska↗

Sediment vulnerability ranking for river basins across the contiguous U.S. using integrated biophysical and social-ecological data

Nearly half of streams and rivers in the United States (U.S.) have fair to poor conditions for aquatic ecosystem health as declared by the U.S. Environmental Protection Agency, and sediment was identified as a primary factor impairing these waterbodies. We rank sediment vulnerability using physical, ecological, and socioeconomic datasets in 163 4-digit Hydrologic Unit Codes within 18 regions across the contiguous U.S. based on the National Hydrography Dataset. We refer to sediment vulnerability as the potential for excess sediment to adversely impact social-ecological aspects of streams and rivers. Metrics were organized into six variable groups: (1) geomorphic setting, (2) modeled sediment and phosphorus, (3) hydrologic conditions, (4) anthropogenic factors and land use, (5) socioeconomic considerations, and (6) measures of ecosystem sensitivity. Correlations and principal component analysis were used to reduce and select metrics that explained the highest variability across basins. Results from the regional analysis identify basins with higher sediment vulnerability in each region, whereas national results identify hotspots of highly ranked basins in the Midwest and the central U.S. with a concentration of moderately to highly ranked basins in the south-central and southwestern U.S. Indicators of socioeconomic and ecological vulnerability integrated with physical drivers of sediment production help identify important gaps in sediment monitoring and research.

contiguous United States↗

Chemical and ancillary data associated with bed sediment, young of year Bluefish ( Pomatomus saltatrix ) tissue, and mussel ( Mytilus edulis and Geukensia demissa ) tissue collected after Hurricane Sandy in bays and estuaries of New Jersey and New York, 2013–14

This report describes the methods and data associated with a reconnaissance study of young of year bluefish and mussel tissue samples as well as bed sediment collected as bluefish habitat indicators during August 2013–April 2014 in New Jersey and New York following Hurricane Sandy in October 2012. This study was funded by the Disaster Relief Appropriations Act of 2013 (PL 113-2) and was conducted by the U.S. Geological Survey (USGS) in cooperation with the National Oceanic and Atmospheric Administration (NOAA). Young of year Pomatomus saltatrix (bluefish) were collected from nine sites in New Jersey (N.J.) and New York (N.Y.) including Barnegat Bay, N.J., Sandy Hook Bay, N.J., Jamaica Bay, N.Y., and Great South Bay, N.Y., and analyzed for indicators of health and chemical contamination. At each bluefish sampling location, bed sediment was also collected and analyzed for a suite of contaminants. Resident mussels, Mytilus edulis (blue mussels) and (or) Geukensia demissa (ribbed mussels), were collected from 11 historic NOAA Mussel Watch Program sites along the N.J. and N.Y. coastlines in the winter/spring of 2014 and analyzed for contaminants. Individual age of a subset of the mussels sampled was also determined at each site. Bed sediment samples were analyzed for a suite of organic contaminants including 34 polychlorinated biphenyl (PCB) congeners, 28 polybrominated diphenyl ether (PBDE) congeners, 24 organochlorine pesticides (OCPs), 53 polycyclic aromatic hydrocarbons (PAHs) and alkylated PAHs, 33 aliphatic hydrocarbons (AHs), and 10 petroleum biomarkers (steranes and hopanes). Bed sediment collected from the Navesink River (Sandy Hook, N.J.), Metedeconk River (Barnegat Bay, N.J.), and Toms River (Barnegat Bay, N.J.) had the highest concentrations of contaminants compared to the other sites. Bluefish and mussel tissue collected throughout the study area was analyzed for 34 PCB congeners, 28 PBDE congeners, and 24 OCPs. Thirty-three PCB congeners, 22 PBDE congeners, and 24 OCPs were detected in the bluefish analyzed. The highest median concentrations of total PCBs were present in tissue from Jamaica Bay, N.Y., whereas the highest median concentrations of total PBDEs and total OCPs were present in tissue from Sandy Hook Bay. Of the OCPs detected, p,p’ -DDE was found in 99 percent (%) of the tissue samples and at the highest median concentrations compared to the other OCPs. Fish health assessments were conducted on 20 fish from the 4 bays. Results indicate that the sex ratio and the mean total length varied by site. Physical fish damage, such as lesions and parasites, was observed in fish from all four bays. The most common parasite observed visually was the presence of Livoneca redmanii , an ectoparasitic gill isopod, which can cause localized gill erosion. The prevalence of the gill isopod infestation ranged from 20% at Great South Bay, N.Y., to 35% at Jamaica Bay, N.Y. Twenty three PCB congeners, 9 PBDE congeners, and 20 OCPs were detected in composite mussel samples collected throughout the study area. The co-eluting PCB congeners 153 and 132, PBDE 47, 99, and 100, and p,p’ -DDE were detected in samples from each site. The highest median concentrations of PCBs and PBDEs were present in mussels from Raritan Bay, N.Y., whereas the highest median concentrations of OCPs were present in mussels from Fire Island Inlet, N.Y., and Shark River, N.J. Mytilus edulis (blue mussels) and Geukensia demissa (ribbed mussels) were thin-sectioned and aged. The blue mussels collected ranged in age from 4 to 13 years, and the ribbed mussels ranged in age from 3 to 12 years.

New Jersey, New York↗

Physical, chemical, and isotopic data for samples from the Anderson Springs area, Lake County, California, 1998-1999

Anderson Springs is located about 90 miles (145 kilometers) north of San Francisco, California, in the southwestern part of Lake County. The area was first developed in the late 1800s as a health resort, which was active until the 1930s. In the rugged hills to the south of the resort were four small mercury mines of the eastern Mayacmas quicksilver district. About 1,260 flasks of mercury were produced from these mines between 1909 and 1943. In the 1970s, the high-elevation areas surrounding Anderson Springs became part of The Geysers geothermal field. Today, several electric powerplants are located on the ridges above Anderson Springs, utilizing steam produced from a 240°C vapor-dominated reservoir. The primary purpose of this report is to provide physical, chemical, and isotopic data on samples collected in the Anderson Springs area during 1998 and 1999, in response to a Freedom of Information Act request. In July 1998, drainage from the Schwartz adit of the abandoned Anderson mercury mine increased substantially over a 2-day period, transporting a slurry of water and precipitates down a tributary and into Anderson Creek. In August 1998, J.J. Rytuba and coworkers sampled the Schwartz adit drainage and water from the Anderson Springs Hot Spring for base metal and methylmercury analysis. They measured a maximum temperature (Tm) of 85°C in the Hot Spring. Published records show that the temperature of the Anderson Springs Hot Spring (main spring) was 63°C in 1889, 42–52°C from 1974 through 1991, and 77°C in March 1995. To investigate possible changes in thermal spring activity and to collect additional samples for geochemical analysis, C.J. Janik and coworkers returned to the area in September and December 1998. They determined that a cluster of springs adjacent to the main spring had Tm=98°C, and they observed that a new area of boiling vents and small fumaroles (Tm=99.3°C) had formed in an adjacent gully about 20 meters to the north of the main spring. During August–October 1999, several field trips were conducted in the vicinity of Anderson Springs to continue monitoring and sampling the thermal manifestations. The new fumarolic area had increased in temperature and in discharge intensity since 1998, and a zone of dead trees had developed on the steep bank directly west of the fumaroles. Ground temperatures and diffuse flow of CO2 flow through soils were measured in the area surrounding the main spring and new fumaroles and in the zone of tree-kill.

California↗

Data summary report: Unregulated contaminants monitoring project

The Drinking Water Protection Section of the Minnesota Department of Health conducted reconnaissance monitoring of selected public water systems in Minnesota. Funding was obtained primarily from the Environment and Natural Resources Trust Fund. Sampling was conducted in 2019 and 2021. Laboratory analysis of samples was conducted for a variety of different contaminants of emerging concern (CECs), including selected pharmaceuticals, pesticides, PFAS, wastewater indicators and other parameters chosen for the physical and land use setting surrounding the sampling points. Sampling site and parameter selection were designed with several goals, as follows: Characterize occurrence and distribution of selected CECs in settings where such chemicals are most likely to be present; Determine if any such occurrences represent a public health concern; Compare results from coupled source water and finished (i.e., treated) water samples at public water system sites where such sampling is feasible; Assess if results from geologically vulnerable (sensitive subject to rapid recharge) and geologically non-vulnerable settings differ significantly. 306 samples were collected as part of the study, from three networks of public water systems differentiated on the basis of source water type (i.e., surface water or groundwater) and land use environment (agricultural and wastewater influenced). This report provides a preliminary, qualitative evaluation of the results. Additionally, more rigorous research will be conducted on these water quality data to evaluate the below findings in more detail. High-level findings from this assessment include the following: Very few samples exceeded health-based guidance for CECs; o When this occurred, MDH staff conducted follow up sampling at the system and provided technical advice about managing the situation. Only a fraction of the CECs analyzed were detected; o Of the 522 different CECs analyzed in the water samples, 161 were detected in one or more samples; o Additionally, most detections were at low levels; Among the CEC classes included in the analytical work, pesticides and PFAS were generally detected at a greater frequency than other CECs; o See Executive Summary Figure 1. The ten most commonly detected individual compounds include: o Tribromomethane, or bromoform, (a disinfection by-product) (70% of sites where analyzed); o norgestrel (a pharmaceutical) (69% of sites where analyzed); o lithium (68% of sites where analyzed); o Metolachlor SA (52%), Deethylatrazine (49%), atrazine (45%), and deisopropylatrazine (31%) (pesticides); o PFBA (44%) and PFHxS (27%) (PFAS compounds); and o 5-methyl benzotriazole (29%) (a benzotriazole). Some CECs were detected more frequently in samples collected from surface waters than those collected from groundwater sources; CEC concentrations were generally higher in vulnerable settings compared to nonvulnerable settings; Whether CECs were detected more frequently in the source water or finished water varied by CEC class. For example, o Benzotriazoles and pharmaceuticals were more frequently detected in source water samples than finished water samples; and o Tribromomethane, or bromoform, a common disinfection by-product, was more frequently found in finished water samples than in source water samples. This work prompted a series of programmatic changes and innovations: A response framework was established for helping the program and public water systems manage detections of unregulated CECs in drinking water; Results were forwarded to the program within MDH responsible for developing healthbased guidance in order to nominate specific compounds found in drinking water but for which limited or no risk advice is available; MDH is seeking support from the Clean Water Council to support the establishment of permanent capacity within the Drinking Water Protection Section to continue sampling efforts of this type.

Minnesota↗

The major coral reefs of Maui Nui, Hawai‘i—distribution, physical characteristics, oceanographic controls, and environmental threats

Coral reefs are widely recognized as critical to Hawaiʻi’s economy, food resources, and protection from damaging storm waves. Yet overfishing, land-based pollution, and climate change are threatening the health and sustainability of those reefs, and accordingly, both the Federal and State governments have called for protection and effective management. In 2000, the U.S. Coral Reef Task Force stated that 20 percent of coral reefs should be protected by 2010. In 2016, the Governor of Hawaiʻi committed to effective management of 30 percent of Hawaiian coastal habitats by 2030 to protect coral reefs. At present, the amount of coral protected in the main Hawaiian Islands is less than 1 percent. Most of the large, highly diverse coral reef tracts in the main Hawaiian Islands surround the four islands of Maui, Molokaʻi, Lānaʻi, and Kahoʻolawe, collectively known as Maui Nui. This report provides fundamental information on the location, extent, coral cover, threats, and connectivity of these major coral reef tracts in Maui Nui essential for identifying areas for management and protection. By combining high-resolution bathymetric data with available maps, publications, and satellite and underwater images, nine major coral reef tracts are identified in the coastal waters of Maui Nui. Three very large reef tracts lie along the south side of Molokaʻi, two on the east side of Lānaʻi, and four off Maui. The factors that make these Maui Nui coral reef tracts a major and important resource for Hawaiʻi include their vast size and high coral cover (nearly 16,000 acres of reef, most of which has more than 50 percent live coral cover); diversity of shape, size, and location; and separation between reefs while retaining connectivity via currents. The decline in the health of these coral reefs over the past several decades has been slow but persistent. Punctuation of the decline by large-scale disturbance events, such as the thermal bleaching that occurred in 2015, is accelerating the loss of viable reef areas by an order of magnitude. The economic, cultural, and recreational value of these coral reef tracts highlights the importance of their long-term survival to the local communities and all of Hawaiʻi. There is scientific consensus that increasing pressures from climate change, overfishing, and land-based pollution will virtually assure the continued, and perhaps accelerating, decline of Hawaiʻi’s coral reefs unless action is taken. Information presented in this report, coupled with the results of numerous scientific studies, provides scientific underpinning to help establish a network of large-scale, connected Marine Protected Areas to meet the Federal and State governments’ call for effective management and protection of coral reefs in Maui Nui.

Hawaii↗

Aquatic biological communities and associated habitats at selected sites in the Big Wood River Watershed, south-central Idaho, 2014

Assessments of streamflow (discharge) parameters, water quality, physical habitat, and biological communities were completed between May and September 2014 as part of a monitoring program in the Big Wood River watershed of south-central Idaho. The sampling was conducted by the U.S. Geological Survey in cooperation with Blaine County, Trout Unlimited, the Nature Conservancy, and the Wood River Land Trust to help identify the status of aquatic resources at selected locations in the watershed. Information in this report provides a basis with which to evaluate and monitor the long-term health of the Big Wood River and its major tributaries. Sampling sites were co-located with existing U.S. Geological Survey streamgaging stations: three on the main stem Big Wood River and four on the North Fork Big Wood River (North Fork), Warm Springs Creek (Warm Sp), Trail Creek (Trail Ck), and East Fork Big Wood River (East Fork) tributaries. The analytical results and quality-assurance information for water quality, physical habitat, and biological community samples collected at study sites during 2 weeks in September 2014 are summarized. Water-quality data include concentrations of major nutrients, suspended sediment, dissolved oxygen, and fecal-coliform bacteria. To assess the potential effects of nutrient enrichment on algal growth, concentrations of periphyton biomass (chlorophyll- a and ash free dry weight) in riffle habitats were determined at each site. Physical habitat parameters include stream channel morphology, habitat volume, instream structure, substrate composition, and riparian vegetative cover. Biological data include taxa richness, abundance, and stream-health indicator metrics for macroinvertebrate and fish communities. Statistical summaries of the water-quality, habitat, and biological data are provided along with discussion of how these findings relate to the health of aquatic resources in the Big Wood River watershed. Seasonal discharge patterns using statistical summaries of daily discharge from selected sites are reported for water years 2012–15. Results showed that annual average daily mean discharge increased from the Big Wood River near Ketchum, ID (BW Ketchum) downstream to the Big Wood River at Hailey, ID (BW Hailey), but decreased by nearly 50 percent from BW Hailey downstream to Big Wood River at Stanton Crossing near Bellevue, ID (BW Stanton). Annual variability in daily mean discharge among main-stem sites was highest at BW Stanton, suggesting that this part of the river may be subject to some level of flow alteration. Hydrologic alterations resulting in flow reduction can contribute to higher water temperature, especially during the summer months when conditions are often most stressful to fish and other stream organisms. Daily water temperature and water temperature trends from June to September 2014 are reported for select tributary and main-stem sites on the Big Wood River and can be used to assess the potential for biological impairment based on aquatic life temperature criteria for cold-water streams. The State of Idaho maximum temperature criteria for protection of cold-water aquatic life of 22 °C was exceeded at Warm Sp and BW Stanton during summer 2014, but at none of the other main-stem or tributary sites. The 13 °C critical temperature criterion for salmonid spawning was exceeded in early July 2014 at BW Ketchum and BW Hailey near the end of the rainbow trout critical spawning and rearing period. Temperature exceedances were most frequent at BW Stanton, where exceedances for rainbow trout and brown trout occurred from May through early July 2014 during most of the critical spawning and rearing period. Water quality and habitat availability did not seem to be limiting for fish or other aquatic organisms at most sites in the Big Wood River watershed. Water quality assessments in September 2014 determined no exceedances of total maximum daily load target levels. The availability and quality of habitat was limited at BW Stanton, where shallow-water habitat conditions prevailed. Macroinvertebrate community diversity was high at all sites except for BW Stanton, where low community diversity was attributed to low species richness and high abundances of a few tolerant taxa. Presence of low species diversity and high macroinvertebrate tolerance values at BW Stanton indicates that benthic community condition and stream health were reduced at that location. Fish surveys done in September 2014 did not indicate any significant reductions in native fish communities in the Big Wood River or its tributaries. Native rainbow trout ( Oncorhynchus mykiss ) and Wood River sculpin ( Cottus leiopomus ) were the dominant fish species in the drainage and were found at all tributary and main-stem sites. Non-native brown ( Salmo trutta ) and brook trout ( Salvelinus fontinalis ) were limited to lower drainage sites on the Big Wood River (BW Hailey and BW Stanton), and occurred in relatively low numbers.

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