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At least 127 records · Page 7Linked to original sources

A procedure for partitioning bulk sediments into distinct grain-size fractions for geochemical analysis

A method to separate sediments into discrete size fractions for geochemical analysis has been tested. The procedures were chosen to minimize the destruction or formation of aggregates and involved gentle sieving and settling of wet samples. Freeze-drying and sonication pretreatments, known to influence aggregates, were used for comparison. Freeze-drying was found to increase the silt/clay ratio by an average of 180 percent compared to analysis of a wet sample that had been wet sieved only. Sonication of a wet sample decreased the silt/clay ratio by 51 percent. The concentrations of metals and organic carbon in the separated fractions changed depending on the pretreatment procedures in a manner consistent with the hypothesis that aggregates consist of fine-grained organic- and metal-rich particles. The coarse silt fraction of a freeze-dried sample contained 20–44 percent higher concentrations of Zn, Cu, and organic carbon than the coarse silt fraction of the wet sample. Sonication resulted in concentrations of these analytes that were 18–33 percent lower in the coarse silt fraction than found in the wet sample. Sonication increased the concentration of lead in the clay fraction by an average of 40 percent compared to an unsonicated sample. Understanding the magnitude of change caused by different analysis protocols is an aid in designing future studies that seek to interpret the spatial distribution of contaminated sediments and their transport mechanisms.

Environmental Geology

Mercury, arsenic, antimony, and selenium contents of sediment from the Kuskokwim River, Bethel, Alaska, USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. ?? 1993 Springer-Verlag.

Environmental Geology

Prediction by regression and intrarange data scatter in surface-process studies

Modeling is a major component of contemporary earth science, and regression analysis occupies a central position in the parameterization, calibration, and validation of geomorphic and hydrologic models. Although this methodology can be used in many ways, we are primarily concerned with the prediction of values for one variable from another variable. Examination of the literature reveals considerable inconsistency in the presentation of the results of regression analysis and the occurrence of patterns in the scatter of data points about the regression line. Both circumstances confound utilization and evaluation of the models. Statisticians are well aware of various problems associated with the use of regression analysis and offer improved practices; often, however, their guidelines are not followed. After a review of the aforementioned circumstances and until standard criteria for model evaluation become established, we recommend, as a minimum, inclusion of scatter diagrams, the standard error of the estimate, and sample size in reporting the results of regression analyses for most surface-process studies. ?? 1993 Springer-Verlag.

Environmental Geology

Uranium in Holocene valley-fill sediments, and uranium, radon, and helium in waters, Lake Tahoe-Carson Range area, Nevada and California, U.S.A.

Uraniferous Holocene sediments occur in the Carson Range of Nevada and California, U.S.A., between Lake Tahoe and Carson Valley. The hosts for the uranium include peat and interbedded organic-rich sand, silt, and mud that underly valley floors, fens, and marshes along stream valleys between the crest of the range and the edge of Lake Tahoe. The known uranium accumulations extend along the Carson Range from the area just southeast of South Lake Tahoe northward to the area just east of Carson City; however, they almost certainly continue beyond the study area to the north, west, and south. Due to the young age of the accumulations, uranium in them is in gross disequilibrium with its highly radioactive daughter products. These accumulations have thus escaped discovery with radiation detection equipment in the past. The uranium content of these sediments approaches 0.6 percent; however, the average is in the range of 300-500 ppm. Waters associated with these sediments locally contain as much as 177 ppb uranium. Modest levels of helium and radon also occur in these waters. Uraniferous waters are clearly entering the private and public water supply systems in some parts of the study area; however, it is not known how much uranium is reaching users of these water supplies. Many of the waters sampled in the study area exceed the published health effects guidance level of the Environmental Protection Agency. Regulatory standards for uranium in waters have not been published, however. Much uranium is stored in the sediments along these stream valleys. Estimates for a marsh and a fen along one drainage are 24,000 and 15,000 kg, respectively. The potential effects of man-induced environmental changes on the uranium are uncertain. Laboratory studies of uraniferous sediment rich in organic matter may allow us to evaluate the potential of liberating uranium from such sediments and creating transient increases in the level of uranium moving in water in the natural environment. ?? 1989 Springer-Verlag New York Inc.

Environmental Geology and Water Sciences

Backwater effects in the Amazon River basin of Brazil

The Amazon River mainstem of Brazil is so regulated by differences in the timing of tributary inputs and by seasonal storage of water on floodplains that maximum discharges exceed minimum discharges by a factor of only 3. Large tributaries that drain the southern Amazon River basin reach their peak discharges two months earlier than does the mainstem. The resulting backwater in the lowermost 800 km of two large southern tributaries, the Madeira and Puru??s rivers, causes falling river stages to be as much as 2-3 m higher than rising stages at any given discharge. Large tributaries that drain the northernmost Amazon River basin reach their annual minimum discharges three to four months later than does the mainstem. In the lowermost 300-400 km of the Negro River, the largest northern tributary and the fifth largest river in the world, the lowest stages of the year correspond to those of the Amazon River mainstem rather than to those in the upstream reaches of the Negro River. ?? 1991 Springer-Verlag New York Inc.

Environmental Geology and Water Sciences

Vapor-phase interactions and diffusion of organic solvents in the unsaturated zone

This article presents an analysis of the interactions and static movement of 37 organic solvents as vapors through the unsaturated soil zone. The physicochemical interactions of the organic vapors with unsaturated soil materials were emphasized with focus on diffusive, and adsorptive interactions. Fick's Law and porous media diffusion coefficients for most of the solvent vapors were either compiled or estimated; coefficients were not available for some of the fluorinated solvents. The adsorption of some of the solvent vapors by silica was concluded to be due to hydrogen bond formation with surface silanol groups. Heats of adsorption data for different adsorbents were also compiled. There were very few data on the adsorption of these solvent vapors by soils, but it appears that the magnitude of adsorption of nonpolar solvents is reduced as the relative humidity of the vapor-solid system is increased. Consequently, the interaction of the vapors may then separated into two processes; (1) gas-water partitioning described by Henry's Law constants, and (2) solid-water adsorption coefficients which may be estimated from liquid-solid partition coefficients (Kd values). ?? 1990 Springer-Verlag New York Inc.

Environmental Geology and Water Sciences

Development of the Wink Sink in west Texas, U.S.A., due to salt dissolution and collapse

The Wink Sink, in Winkler County, Texas, is a collapse feature that formed in June 1980 when an underground dissolution cavity migrated upward by successive roof failures until it breached the land surface. The original cavity developed in the Permian Salado Formation salt beds more than 400 m (1,300 ft) below ground level. Natural dissolution of salt occurred in the vicinity of the Wink Sink in several episodes that began as early as Salado time and recurred in later Permian, Triassic, and Cenozoic times. Although natural dissolution occurred in the past below the Wink Sink, it appears likely that the dissolution cavity and resultant collapse described in this report were influenced by petroleum-production activity in the immediate area. Drilling, completion, and plugging procedures used on an abandoned oil well at the site of the sink appear to have created a conduit that enabled water to circulate down the borehole and dissolve the salt. When the dissolution cavity became large enough, the roof failed and the overlying rocks collapsed into the cavity. Similar collapse features exist where underground salt beds have been intentionally dissolved during solution mining or accidentally dissolved as a result of petroleum-production activity. ?? 1989 Springer-Verlag New York Inc.

Environmental Geology and Water Sciences

Increased concentrations of potassium in heartwood of trees in response to groundwater contamination

The wood of tuliptrees (Liriodendron tulipifera L.) growing above groundwater contamination from a hazardous-waste landfill in Maryland contained elevated concentrations of potassium (K). The groundwater contamination also contained elevated concentrations of dissolved K, as well as arsenic (As), cadmium (Cd), chloride (Cl), iron (Fe), manganese (Mn), zinc (Zn), and organic solvents. The dissolved K is derived from disposed smoke munitions. The excess K in the tuliptrees is concentrated in the heartwood, the part of the xylem most depleted in K in trees growing outside of the contamination. These data show that the uptake and translocation of K by tuliptrees can be strongly influenced by the availability of K in groundwater contamination and suggest the utility of this species as an areal indicator of groundwater contamination. ?? 1992 Springer-Verlag New York Inc.

Environmental Geology and Water Sciences

Transformation of Monoaromatic hydrocarbons to organic acids in anoxic groundwater environment

The transformation of benzene and a series of alkylbenzenes was studied in anoxic groundwater of a shallow glacial-outwash aquifer near Bemidji, Minnesota, U.S.A. Monoaromatic hydrocarbons, the most water-soluble components of crude oil, were transported downgradient of an oil spill, forming a plume of contaminated groundwater. Organic acids that were not original components of the oil were identified in the anoxic groundwater. The highest concentrations of these oxidized organic compounds were found in the anoxic plume where a decrease in concentrations of structurally related alkylbenzenes was observed. These results suggest that biological transformation of benzene and alkylbenzenes to organic acid intermediates may be an important attenuation process in anoxic environments. The transformation of a complex mixture of hydrocarbons to a series of corresponding oxidation products in an anoxic subsurface environment provides new insight into in situ anaerobic degradation processes.

Minnesota

Arsenic in streams, stream sediments, and ground water, Fairbanks area, Alaska

Arsenic concentrations of less than 5 ppb to as large as 1,260 ppb in stream waters and from 5 ppm to 4,000 ppm in stream sediments were found in the Pedro Dome-Cleary Summit area, Alaska. Waters from three of 20 wells sampled had arsenic concentrations exceeding the U.S. Public Health Service recommended limit of 50 ppb. The high arsenic levels are a consequence of arsenic enrichment in the rocks of the area. Placer and lode-gold mining may increase the arsenic content of the waters by exposing arsenic-containing rocks to surface waters and by increasing the load of arsenic-rich sediments in the streams. Finding these disturbingly large concentrations of arsenic in the waters of the Fairbanks area was the major result of this work, inasmuch as a subsequent study (to be published) revealed arsenic concentrations as large as 10 ppm in domestic wells and prompted an extensive study by Federal and State agencies of the health hazard posed by these arsenic-rich waters.

Alaska

Hydrologic inferences from ring widths of flood-damaged trees, Potomac River, Maryland

Year-to-year variability in the ring widths of trees on flood plains along two reaches of the Potomac River near Washington, D.C., seems in large part to be related to differences in flood-flow regimes. Trees directly exposed to high flood velocities are damaged more often than sheltered trees and thus exhibit more variable ring-width patterns. The ring-width variability of unsheltered trees on low levels of flood plains is greater than that of trees on high levels, indicating that variability values are positively correlated with flood frequency. Sheltered trees, however, have less variable ring-width patterns than those of unsheltered trees, and variability is not correlated with flood frequency. As a result, ring-width variations may be used to estimate the probability of flood damage along local channel reaches of a stream. Growth responses after hydrologic catastrophies in 1948 and 1972 indicate that rings of flood-plain trees can be used to document the occurrence and crest altitude of high-magnitude floods. ?? 1982 Springer-Verlag New York Inc.

Environmental Geology

Distribution of pollutants from a new paper plant in southern Lake Champlain, Vermont and New York

From November of 1973 to May of 1974, 15 arrays of sediment traps were placed along 33 km of southern Lake Champlain to sample the distribution of effluent from a large paper plant located on the western shore which had commenced operation in 1971. In the arrays located near the effluent diffuser pipeline as much as 2.3 cm of sediment accumulated, whereas elsewhere in the lake less than 1 cm accumulated. In the area of accelerated accumulation, sediments contained high concentrations of several components used in or derived from paper manufacturing. Values for kaolinite, expressed as the ratio of kaolinite to chlorite, for example, were as high as 1.4, anatase (TiO2) concentrations were as high as 0.8%, organic carbon 8.7%, and phosphorus 254 ??g/g; all were more abundant than in sediments collected in traps to the south or north. In surficial bottom sediments collected near each array organic carbon and phosphorus were also higher (4.2% and 127 ??g/g respectively) near the diffuser than elsewhere. Thus, the new plant after three years of production measurably affected the composition of suspended sediment and surficial bottom sediment despite the construction and use of extensive facilities to reduce the flow of pollutants to the lake. ?? 1977 Springer-Verlag New York Inc.

Environmental Geology

Sorption of radium-226 from oil-production brine by sediments and soils

The sorption of226Ra from oil-production brine by soils and sediments was investigated. Sorption was rapid, and the percentage sorbed increased with brine dilution. Greatest removals of226Ra from sediments in the laboratory occurred with alkaline DTPA, HCl, and BaCl2, with lesser removals using CaCl2 and NaCl solutions. Digestion of sediments with NaOCl indicates that most of the native and sorbed226Ra is associated with the mineral rather than organic fraction of the sediments. Correlation analysis based on 14 soils indicates that the retention of226Ra may involve precipitation reactions associated with sulfate-bearing minerals, as well as ion-exchange reactions with the clay mineral fractions of surficial earth materials. ?? 1982 Springer-Verlag New York Inc.

Environmental Geology

Coral reef recovery in Florida and the Persian Gulf

Long-term observations and study of coral reef destruction by hurricanes in the Florida Keys show, surprisingly, that although corals are devastated on a grand scale during storms, recovery is rapid. Recovery occurs because of the widespread scattering of live fragments, many of which become growth sites of new colonies. Reef recovery from death by chilling in the Persian Gulf was well under way when last observed, but it is not yet known if the recovery rate was as rapid as recovery from the storm destruction in Florida. Recovery from death by chilling requires settlement of transported coral larvae and a substrate suitable for larval attachment. Such resettlement is subject to the effects of currents, predators, pollution, and competition for substrate. A growth rate of 10 cm per year combined with geometrical progression of branch formation accounts for rapid Acropora cervicornis recovery. Although calculated coral proliferation seems unusually high, it has been confirmed by serial underwater photographs spanning ten years. More precise measurements of growth and branching are needed, along with growth data for other common reef-building corals. Such data would be useful for predicting standing crop of a restocked or transplanted reef.

Florida

Impacts of vehicles on natural terrain at seven sites in the San Francisco Bay area

The impacts of off-road vehicles on vegetation and soil were investigated at seven representative sites in the San Francisco Bay area. Plant cover of grass and chaparral (with shrubs to 4 m tall) have been stripped by the two- and four-wheel vehicles in use. Impacts on loamy soils include increased surface strength (as much as 275 bars), increased bulk density (averaging 18%) to depths of 90 cm or more, reduction of soil moisture by an average 43% to 30 cm depths, greatly reduced infiltration, extension of the diurnal temperature range by as much as 12??C, and reduction of organic carbon by an average 33% in exposed soils. Very sandy soils respond similarly to vehicular use except that moisture is increased and surface strength of beach sand is decreased. These physical and chemical impacts reduce the land's capability of restoring its vegetative cover, which in turn adversely affects animal populations. Both the loss of plant cover and the physical changes caused by vehicles promote erosion. Measured soil and substrate losses from vehicular use zones range from 7 to 1180 kg/m2. The estimated erosion rate of the Chabot Park site exceeds the rate of erosion considered a serious problem by a factor 30, it exceeds United States Soil Conservation Service tolerance values by a factor of 46, and it exceeds average San Francisco Bay area erosion rates by a factor of 17. The resulting soil losses are effectively permanent. Neither the increased sediment yield nor the increased runoff is accomodated on the sites of use, and both are causing adverse effects to neighboring properties. ?? 1978 Springer-Verlag New York Inc.

Environmental Geology

Measurement of irrigated acreage in Western Kansas from LANDSAT images

In the past four decades, irrigated acreage in western Kansas has increased rapidly. Optimum utilization of vital groundwater supplies requires implementation of long-term water-management programs. One important variable in such programs is up-to-date information on acreage under irrigation. Conventional ground survey methods of estimating irrigated acreage are too slow to be of maximum use in water-management programs. Visual interpretation of LANDSAT images permits more rapid measurement of irrigated acreage, but procedures are tedious and still relatively slow. For example, using a LANDSAT false-color composite image in areas of western Kansas with few landmarks, it is impossible to keep track of fields by examination under low-power microscope. Irrigated fields are more easily delineated on a photographically enlarged false-color composite and are traced on an overlay for measurement. Interpretation and measurement required 6 weeks for a four-county (3140 mi2, 8133 km2) test area. Video image-analysis equipment permits rapid measurement of irrigated acreage. Spectral response of irrigated summer crops in western Kansas on MSS band 5 (visible red, 0.6-0.7 ??m) images is low in contrast to high response from harvested and fallow fields and from common soil types. Therefore, irrigated acreage in western Kansas can be uniquely discriminated by video image analysis. The area of irrigated crops in a given area of view is measured directly. Sources of error are small in western Kansas. After preliminary preparation of the images, the time required to measure irrigated acreage was 1 h per county (average area, 876 ml2 or 2269 km2). ?? 1980 Springer-Verlag New York Inc.

Environmental Geology

Effects of erosion control structures along a portion of the northern Chesapeake Bay shoreline

A 6.500-meter reach of western Chesapeake Bay shoreline (lower Mayo Peninsula) lost about 1.1??106 cubic meters of sediment (equivalent to 170 cubic meters lost per meter of shoreline) between 1846 and 1932, when the first aerial photographs show the shoreline already substantially protected by a system of groins and intermittent bulkheading. These structures have eliminated the fastland as a source of erodable material, and have starved the supply of sand for littoral drift, thus limiting the extent of the beaches to the remaining groin fields. Volumes of sediment involved in these impacts are small in the overall sediment budget. Bulkheads produce no deficit in the budget since scouring of the beaches on their seaward sides makes up for the decreased erosion of protected fastland. Groins trap little of the potential littoral drift (computed to be about 104 cubic meters per meter of shoreline per year). The sand supply in the remaining beaches is nearly equivalent to the annual loss of sediment from the entire shoreline system due to the long-term rate of erosion of the shoreline and nearshore between 1846 and 1932. ?? 1981 Springer-Verlag New York Inc.

Environmental Geology

Small landslide types and controls in glacial deposits: Lower Skagit river drainage, northern cascade range, Washington

Observations of 167 small, shallow landslides spanning a 22-year period on extensively logged slopes of Quaternary terraces in the lower Skagit and Baker Valleys, Washington, shows that there is a relationship between the common slope failures in this area and the slope angle, stratigraphy, and logging practices. Landslide frequency increases upvalley, as do mean annual precipitation and the frequency of perched water tables. Debris slides are most common, occur on steep slopes (>50%) composed of sand and gravel, and are most abundant in areas previously logged by the clear-cut method. Debris flows occur on shallower slopes (>30%) where the stratigraphy leads to perched water tables. Debris flows larger than 600 m2 in area appear to be unrelated to logging practices. Slump flows, described here for the first time, occur on similar slope angles and stratigraphic situations as debris flows. They differ mainly by the presence of semiconsolidated material, usually till, at the slide head. Where till is breached-commonly along road cuts-water infiltration is increased, saturating underlying fine-grained deposits, which then fail by debris flowage. Secondary slumping of till happens when the slope steepens during debris flow failure. Small landslides surrounding Lake Shannon may contribute up to 80% of the total particulate matter yield to the fluvial system at present, increasing lake sedimentation by a rate of 5 mm/yr. ?? 1981 Springer-Verlag New York Inc.

Environmental Geology