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Recent (2008-10) concentrations and isotopic compositions of nitrate and concentrations of wastewater compounds in the Barton Springs zone, south-central Texas, and their potential relation to urban development in the contributing zone

During 2008–10, the U.S. Geological Survey, in cooperation with the City of Austin, the City of Dripping Springs, the Barton Springs/Edwards Aquifer Conservation District, the Lower Colorado River Authority, Hays County, and Travis County, collected and analyzed water samples from five streams (Barton, Williamson, Slaughter, Bear, and Onion Creeks), two groundwater wells (Marbridge well [YD–58–50–704] and Buda well [LR–58–58–403]), and the main orifice of Barton Springs in Austin, Texas, with the objective of characterizing concentrations and isotopic compositions of nitrate and concentrations of wastewater compounds in the Barton Springs zone. The Barton Springs zone is in south-central Texas, an area undergoing rapid growth in population and in land area affected by development, with associated increases in wastewater generation. Over a period of 17 months, during which the hydrologic conditions transitioned from dry to wet, samples were collected routinely from the streams, wells, and spring and, in response to storms, from the streams and spring; some or all samples were analyzed for nitrate, nitrogen and oxygen isotopes of nitrate, and waste­water compounds. The median nitrate concentrations in routine samples from all sites were higher in samples collected during the wet period than in samples collected during the dry period, with the greatest difference for stream samples (0.05 milligram per liter during the dry period to 0.96 milligram per liter for the wet period). Nitrate concentrations in recent (2008–10) samples were elevated relative to concentrations in historical (1990–2008) samples from streams and from Barton Springs under medium- and high-flow conditions. Recent nitrate concentrations were higher than historical concentrations at the Marbridge well but the reverse was true at the Buda well. The elevated concentrations likely are related to the cessation of dry conditions coupled with increased nitrogen loading in the contributing watersheds. An isotopic composition of nitrate (delta nitrogen–15) greater than 8 per mil in many of the samples indicated there was a contribution of nitrate with a biogenic (human and or animal waste, or both) origin. Wastewater compounds measured in routine samples were detected infrequently (3 percent of cases), and concentrations were very low (less than the method reporting level in most cases). There was no correlation between nitrate concentrations and the frequency of detection of wastewater compounds, indicating that wastewater compounds might be undergoing removal during such processes as infiltration through soil. Three potential sources of biogenic nitrate to the contributing zone were considered: septic systems, land application of treated wastewater, and domesticated dogs and cats. During 2001–10, the estimated densities of septic systems and domesticated dogs and cats (number per acre) increased in the watersheds of all five creeks, and the rate of land application of treated wastewater (gallons per day per acre) increased in the watersheds of Barton, Bear, and Onion Creeks. Considering the timing and location of the increases in the three sources, septic systems were considered a likely source of increased nitrate to Bear Creek; land application of treated wastewater a likely source to Barton, Bear, and Onion Creeks; and domestic dogs and cats a potential source principally to Williamson Creek. The results of this investigation indicate that baseline water quality, in terms of nitrate, has shifted upward between 2001 and 2010, even without any direct discharges of treated wastewater to the creeks.

Texas

Effects of changes in pumping on regional groundwater-flow paths, 2005 and 2010, and areas contributing recharge to discharging wells, 1990–2010, in the vicinity of North Penn Area 7 Superfund site, Montgomery County, Pennsylvania

A previously developed regional groundwater flow model was used to simulate the effects of changes in pumping rates on groundwater-flow paths and extent of recharge discharging to wells for a contaminated fractured bedrock aquifer in southeastern Pennsylvania. Groundwater in the vicinity of the North Penn Area 7 Superfund site, Montgomery County, Pennsylvania, was found to be contaminated with organic compounds, such as trichloroethylene (TCE), in 1979. At the time contamination was discovered, groundwater from the underlying fractured bedrock (shale) aquifer was the main source of supply for public drinking water and industrial use. As part of technical support to the U.S. Environmental Protection Agency (EPA) during the Remedial Investigation of the North Penn Area 7 Superfund site from 2000 to 2005, the U.S. Geological Survey (USGS) developed a model of regional groundwater flow to describe changes in groundwater flow and contaminant directions as a result of changes in pumping. Subsequently, large decreases in TCE concentrations (as much as 400 micrograms per liter) were measured in groundwater samples collected by the EPA from selected wells in 2010 compared to 2005‒06 concentrations. To provide insight on the fate of potentially contaminated groundwater during the period of generally decreasing pumping rates from 1990 to 2010, steady-state simulations were run using the previously developed groundwater-flow model for two conditions prior to extensive remediation, 1990 and 2000, two conditions subsequent to some remediation 2005 and 2010, and a No Pumping case, representing pre-development or cessation of pumping conditions. The model was used to (1) quantify the amount of recharge, including potentially contaminated recharge from sources near the land surface, that discharged to wells or streams and (2) delineate the areas contributing recharge that discharged to wells or streams for the five conditions. In all simulations, groundwater divides differed from surface-water divides, partly because of differences in stream elevations and because of geologic structure and pumping. In the 1990 and 2000 simulations, all recharge in and near the vicinity of North Penn Area 7 discharged to wells, but in the 2005 and 2010 simulations some recharge in this area discharged to streams, indicating possible discharge of contaminated groundwater from North Penn Area 7 sources to streams. As the amount of groundwater withdrawals by wells has declined since 1990, the area contributing recharge to wells in the vicinity of North Penn Area 7 has decreased. To determine the effect of changes in pumping on flow paths and possible flow-path-related contributions to the observed changes in spatial distribution of contaminants in groundwater from 2005 to 2010, the USGS conducted simulations using the previously developed regional groundwater-flow model using reported pumping and estimated recharge rates for 2005 and 2010. Flow paths from recharge at known contaminant source areas to discharge locations at wells or streams were simulated under steady-state conditions for the two periods. Simulated groundwater-flow paths shifted only slightly from 2005 to 2010 as a result of changes in pumping rates. These slight changes in groundwater-flow paths from known sources of contamination are not coincident with the spatial distribution of observed changes in TCE concentrations from 2005 to 2010, indicating that the decreases of TCE concentrations may be a result of other processes, such as source removal or degradation. Results of the simulations and the absence of increases in TCE-degradation-product concentrations indicate that the decreases of TCE concentrations observed in 2010 may be at least partly related to contaminant-source removal by soil excavation completed in 2005, although additional data would be needed to confirm this preliminary explanation.

Pennsylvania

Source contributions to suspended sediment and particulate selenium export from the Loutsenhizer Arroyo and Sunflower Drain watersheds in Colorado

Selenium in aquatic ecosystems of the lower Gunnison River Basin in Colorado is affecting the recovery of populations of endangered, native fish species. Dietary exposure is the primary pathway for bioaccumulation of selenium in fish, and particulate selenium can be consumed directly by fish or by the invertebrates on which fish feed. Although selenium can be incorporated into particulate matter via biogeochemical processes, particulate selenium can also enter aquatic ecosystems of the lower Gunnison River Basin from sediments derived from the selenium-rich Mancos Shale. The U.S. Geological Survey, in cooperation with the Colorado Water Conservation Board, conducted this study during 2018–19 to identify sources of selenium-rich suspended sediments from two watersheds underlain by Mancos Shale: Loutsenhizer Arroyo and Sunflower Drain, which is a locally known agricultural drainage near the municipality of Delta, Colorado. A multipronged approach (fieldwork, laboratory work, and computer modeling) referred to as “sediment fingerprinting” was used to evaluate sources of suspended sediments in the streams flowing out of the two studied watersheds. Four potential source types for suspended sediments were identified and sampled (using soil plugs) within the watersheds: rangelands, agricultural fields, arroyo walls, and streambanks. The sediment fingerprinting approach used elemental concentrations and naturally occurring fallout radionuclides as tracers to apportion percent contributions from the four source types of suspended sediments found in streamflow from both watersheds. To determine the dominant sources of suspended sediment in streamflow from both watersheds, a mathematical “unmixing” model was used. Unmixing models apportion source percentages to samples of material in which those sources are mixed. These models used elemental and isotopic data in the suspended sediments to unmix them into proportional contributions from source types. The results indicated that arroyo walls and streambanks generally dominated as sources of the suspended sediment. Arroyo walls and streambanks were channel-adjacent sources, with sediments mobilized by water flowing within the stream channel. These sources accounted for greater than 50 percent of suspended sediment in all but one sample and accounted for 100 percent of suspended sediment in 5 of the 11 samples collected. Rangeland and agricultural field sources were located in uplands outside of stream channels and were detected more often during the non-irrigation season. Rangeland and agricultural field sources each were found in 5 of the 11 samples collected. Concentrations of selenium in sediment-source samples were comparatively greater in streambanks and lower in rangelands, with agricultural fields and arroyo walls being intermediate. As a result, source apportionments for particulate selenium skewed towards sources adjacent to stream channels more than for suspended sediments. Water imports for irrigation have changed the hydrology of the watersheds, and a notable fraction of imported water passes through the watersheds rapidly. The rapid flowthrough water during the irrigation season likely contributes heavily to sediment erosion and transport in Loutsenhizer Arroyo and Sunflower Drain, particularly from channel-adjacent sources of sediment. Decreases in irrigation season streamflow, at least in Loutsenhizer Arroyo, may have decreased sediment erosion and transport during the 2018–20 irrigation seasons compared to the 2015–17 seasons.

Colorado

Estimation of the recharge areas contributing water to the South Well Field, Columbus, Ohio

The city of Columbus, Ohio, operates four radial collector wells, designed to yield 42 Mgal/d (million gallons per day), in southern Franklin County, Ohio, as part of their municipal supply of water. The collector wells are adjacent to, and designed to induce infiltration from, Big Walnut Creek and Scioto River. A previously constructed, three-dimensional, steady-state and transient ground-water-flow model of this river-aquifer system was used to estimate contributing recharge areas (CRA's) and calculate particle flowpaths in southern Franklin County. The simulations were of two steady-state periods (October 1979 and March 1986) and one 5-year transient period (March 1986---June 1991). The first simulation (1979) was of conditions before construction of the collector wells. The second simulation (1986) was of conditions when the collector wells were producing 8 Mgal/d. During the 5 years covered in the transient simulation, production at the well field averaged 18.5 Mgal/d. Under the 1979 conditions, the largest ground-water contributing areas were of the quarries and Scioto River (41 and 47 percent of the study area, respectively). During 1986, when 8 Mgal/d was withdrawn, the primary contributing areas were of the quarries (40 percent), collector wells (34 percent), and rivers (8 percent). Travel times associated with simulated particles of water tracked from cells along Big Walnut Creek to their discharge points in cells along Scioto River were about 5 to 60 years in the 1979 simulation and about 7 to 41 years in the 1986 simulation. The endpoints of these particles varied as simulated pumping rates were increased to 22 Mgal/d. The 1986, 10-year CRA's of the collector wells under 8 Mgal/d-conditions totalled about 4.5 mi2. As the pumping rate was increased to 22 Mgal/d in a predictive simulation, 10-year CRA's of the collector wells increased to 6.7mi2. Because the transient simulation encompassed only 5 years, the 10-year CRA's could not be estimated from the transient simulation. However, the size of the 1- to 5-year CRA's for the transient simulation was similar to the size of the 1- to 5-year CRA's for a steady-state predictive simulation if well-field production were 16 Mgal/d. The transient simulations predicted discontinuous CRA's, especially adjacent to the rivers, due to changes in hydrologic stresses. Analyses of the steady-state and transient models showed that sizes of CRA's were most sensitive to changes in porosity, pumping rate, riverbed conductance, and horizontal hydraulic conductivity.

Ohio

Evaluating contributions of recent tracking-based animal movement ecology to conservation management

The use of animal-born sensors for location-based tracking and bio-logging in terrestrial systems has expanded dramatically in the past 10 years. This rapid expansion has generated new data on how animals interact with and respond to variation in their environment, resulting in important ecological, physiological, and evolutionary insights. Although understanding the finer details of animal locations has important management relevance, applied studies are not prominent in the movement ecology literature. This is despite the long history of applied studies of animal movement and the urgent and growing need for evidence-based conservation guidance, especially in the challenging field of human-wildlife interactions. The goal of this review is to evaluate the realized contribution of tracking-based animal movement ecology to solving specific conservation problems, and to identify barriers that may hinder expansion of that contribution. To do this, we (a) briefly review the history and technologies used in animal tracking and bio-logging, (b) use a series of literature searches to evaluate the frequency with which movement ecology studies are designed to solve specific conservation problems, and (c) use this information to identify challenges that may limit the applied relevance of the field of movement ecology, and to propose pathways to expand that applied relevance. Our literature review quantifies the limited extent to which research in the field of movement ecology is designed to solve specific conservation problems, but also the fact that such studies are slowly becoming more prevalent. We discuss how barriers that limit application of these principles are likely due to constraints imposed by the types of data used commonly in the field. Problems of scale mismatch, error compounding, and data paucity all create challenges that are relevant to the field of movement ecology but may be especially pertinent in applied situations. Finding solutions to these problems will create new opportunity for movement ecologists to contribute to conservation science.

Frontiers in Ecology and Evolution

River-to-lake transitional areas contribute disproportionately to in-lake nutrient loading

River-to-lake transitional areas are biogeochemically active sections of the aquatic continuum that are often understudied compared to their adjoining environments. Internal nutrient loading from river-to-lake transitional areas may be a considerable source of nutrients to lakes and if overlooked disconnect upstream management initiatives from in-lake improvements. To contextualize internal nutrient loading by river-to-lake sediments, we conducted sediment core incubations and nutrient assays at 3 time points over a field season from a major contributing tributary of Lake Erie. Using statistical and spatial interpolation models, we upscaled internal nitrogen and phosphorus loading rates across the highly impaired mouth of the Maumee River, which drains into the western basin of Lake Erie. We found that internal nutrient dynamics in this river-to-lake transitional area were regulated by spatial differences in the physical composition and nutrient and organic matter contents of sediments. The Maumee river-to-lake transitional area was largely a source of phosphorus and ammonium nitrogen and a sink of nitrate nitrogen through high denitrification rates. Yet, we observed substantial temporal variation whereby internal nutrient loading was greatest in late summer coinciding with near-zero denitrification. Sediments at this time could contribute an additional ~17% more soluble reactive phosphorus and ~3% more total kjeldahl nitrogen in the bioavailable ammonium nitrogen fraction relative to the daily external nutrient load. High internal nutrient loading rates compared to more offshore areas in western Lake Erie suggest that this degraded river-to-lake transitional area has a disproportional biogeochemical significance and a high potential to contribute to nearshore water quality issues.

Ohio

Techniques of contributing-area delineation for analysis of nonpoint-source contamination of Long Island, New York

Ninety shallow monitoring wells on Long Island, N.Y., were used to test the hypothesis that the correlation between the detection of volatile organic compounds (VOC's) at a well and explanatory variables representing land use, population density, and hydrogeologic conditions around the well is affected by the size and shape of the area defined as the contributing area. Explanatory variables are quantified through overlay of various specified contributing areas on 1:24 000-scale landuse and population-density geographic information system (GIS) coverages. Four methods of contributing-area delineation were used: (a) centering a circle of selected radius on the well site, (b) orienting a triangular area along the direction of horizontal ground-water flow to the well, (c) generating a shaped based on direction and magnitude of horizontal flow to the well, and (d) generating a shape based on three-dimensional particle pathlines backtracked from the well screen to the water table. The strongest correlations with VOC detections were obtained from circles of 400- to 1 000-meter radius. Improvement in correlation through delineations based on ground-water flow would require geographic overlay on more highly detailed GIS coverages than those used in the study.

Models for assessing and monitoring groundwater qu

Controls on old and new water contributions to stream flow at some nested catchments in Vermont, USA

Factors controlling the partitioning of old and new water contributions to stream flow were investigated for three events in four catchments (three of which were nested) at Sleepers River Research Watershed in Danville, Vermont. In the 1993 snowmelt period, two-component isotopic hydrograph separations showed that new water (meltwater) inputs to the stream ranged widely from 41 to 74%, and increased with catchment size (41 to 11 125 ha) (with one exception) and with open land cover (0-73%). Peak dissolved organic carbon concentrations and relative alkalinity dilution in stream water ranked in the same order among catchments as the new water fractions, suggesting that new water followed shallow flow paths. During the 1994 snowmelt, despite similar timing and magnitude of melt inputs, the new-water contribution to stream flow ranged only from 30 to 36% in the four catchments. We conclude that the uncommonly high and variable new water fractions in streamwater during the 1993 melt were caused by direct runoff of meltwater over frozen ground, which was prevalent in open land areas during the 1993 winter. In a high-intensity summer rainstorm in 1993, new water fractions were smaller relative to the 1993 snowmelt, ranging from 28 to 46%, but they ranked in the identical catchment order. Reconciliation of the contrasting patterns of new-old water partitioning in the three events appears to require an explanation that invokes multiple processes and effects, including: 1 topographically controlled increase in surface-saturated area with increasing catchment size; 2 direct runoff over frozen ground; 3 low infiltration in agriculturally compacted soils; 4 differences in soil transmissivity, which may be more relevant under dry antecedent conditions. These data highlight some of the difficulties faced by catchment hydrologists in formulating a theory of runoff generation at varying basin scales. Copyright ?? 2002 John Wiley and Sons, Ltd.

Hydrological Processes

Hosts, pathogens and hot ponds: Thermal mean and variability contribute to spatial patterns of chytrid infection

Temperature is a primary driver of heterogeneity in host–pathogen dynamics and understanding how patch-scale temperature affects landscape-scale patterns of pathogen infection is key to effective monitoring and management. In field studies, both temperature variability and mean temperature are often related to infection of ectothermic animals by fungal pathogens, and although these factors vary spatiotemporally, their contributions to infection outcomes are rarely decomposed into spatial and temporal components. We studied how patch-scale thermal conditions (mean and variability) affect infection of eastern newts Notophthalmus viridescens by Batrachochytrium dendrobatidis ( Bd ), with a special focus on disentangling spatial versus temporal contributions of thermal conditions to infection outcomes. We measured in situtemperature and Bd infection across 20 ponds in two years in southeastern Wisconsin, USA to 1) understand thermal mediation of infection and 2) quantify whether seasonal and/or among-site variation in thermal conditions drive heterogeneity in host–pathogen interactions. In our system, thermal mean and variability covaried tightly, necessitating the creation of a single index to capture both components. We found that 1) this index of thermal mean and variability was strongly and nonlinearly related to Bd infection and 2) differences among patches in thermal conditions drove this relationship, highlighting that variation in patch-level conditions can drive heterogenous host–pathogen outcomes across landscapes. Our research collectively reveals insights about the importance of local, patch-level conditions for mediating disease risk at broader scales.

Wisconsin

Measuring carbon and nitrogen bioassimilation, burial, and denitrification contributions of oyster reefs in Gulf coast estuaries

The eastern oyster ( Crassostrea virginica ) and the reefs they create provide significant ecosystem services. This study measured their possible role in nutrient mitigation through bioassimilation, burial, and oyster-mediated sediment denitrification in near-shore shallow water (< 1 m water depth) and deep-water (> 1 m water depth) oyster reefs in Louisiana. Nitrogen (N) and carbon (C) in shell and tissue differed by oyster reproductive status, size, and habitat type. Changes in tissue percent N and C post-spawning combined with significant reductions in tissue dry weight from the release of gametes, resulted in 20 and 46% reductions in tissue N and C load (mg), respectively, for a 100-mm oyster. Oyster reefs did not enhance burial rates, with burial range rates estimated at 1.4–2.6 g N m −2 year −1 , and 26.9–43.8 g C m −2 year −1 . Closed-system ex situ incubations indicated net denitrification in all habitat types studied, with the highest rates exceeding 600 µmol N m −2 h −1 during the summer, but no enhancement attributable to oyster reefs specifically. Within the highly productive, organic-rich wetland complex systems of coastal Louisiana, oyster reefs were not associated with enhanced denitrification, likely due to the organic-rich setting, and redundant supplies of organic nitrogen and carbon from adjacent marshes. Context remains critical in determining ecosystem provision of habitats, and efforts to extrapolate and predict nitrogen removal across locations necessitates consideration of local conditions. Considering the large extent of reefs and oyster production across coastal Louisiana, oyster habitats may still contribute to N and C mitigation, but their unique contribution likely comes from bioassimilation, and removal of the oysters from the system.

Louisiana

The contributions and influence of two Americans, Henry S. Washington and Frank A. Perret, to the study of Italian volcanism with emphasis on volcanoes in the Naples area

A century ago, two Americans, Henry Stephens Washington and Frank Alvord Perret, made significant contributions to the geology, petrology, and volcanology of Italy, in particular to those volcanoes in the Naples area, Vesuvius, Campi Flegrei (Phlegraean Fields), and the Island of Ischia. Both were from the eastern United States, both were born in 1867, and both studied physics as undergraduates. However, each man followed a different scientific path and approach in his volcanological studies. Washington was classically trained and more interested in rock chemistry, mineralogy, and petrogenesis. Perret was a gifted inventor, worked in Edison's laboratory, established his own company, and was a keen observer of volcanic phenomena and processes; today he would be called a “physical volcanologist” Each man published classic works on Italian volcanoes, The Roman Comagmatic Region (Washington, 1906) and The Vesuvius Eruption of 1906 (Perret, 1924); both were published by the Carnegie Institution of Washington. However, both men had cosmopolitan tastes for other volcanoes, and they traveled widely and made significant contributions to the knowledge of other volcanic areas. The following two sections present, albeit briefly, their work, significance, and influence to Italian volcanism with emphasis on those volcanoes in the Naples area.

Naples

From extreme pH to extreme temperature: An issue in honor of the geochemical contributions of Kirk Nordstrom, USGS hydrogeochemist

This special issue of Applied Geochemistry honors Dr. D. Kirk Nordstrom, and his influential career spent primarily at the U.S. Geological Survey (USGS). This issue does not herald his retirement or other significant career milestone, but serves as a recognition of the impact his work has had on the field of geochemistry in general. This special issue grew from a symposium in Kirk’s honor (affectionately dubbed “Kirkfest”) at the Geological Society of America’s annual meeting in Denver, Colorado, USA, during October 2013. At GSA, 27 talks and 35 posters showed how Kirk’s work has influenced a wide range of current hydrogeochemical research, from geothermal processes to acid mine drainage to geochemical modeling. The breadth of his knowledge and his many contributions to the published literature have left an indelible mark on the field of geochemistry, and this special issue is a tribute to his experience and contributions.

Applied Geochemistry

Contribution of deep-sourced carbon from hydrocarbon seeps to sedimentary organic carbon: Evidence from radiocarbon and stable isotope geochemistry

Sulfate-driven anaerobic oxidation of methane (AOM) limits the release of methane from marine sediments and promotes the formation of carbonates close to the seafloor in seepage areas along continental margins. It has been established that hydrocarbon seeps are a source of methane, dissolved inorganic carbon, and dissolved organic carbon to marine environments. However, questions remain about the contribution of deep-sourced carbon from hydrocarbon seeps to the sedimentary organic carbon pool. In this study, we analyzed carbon quantity, radiocarbon content (as percent modern carbon, pMC), stable carbon isotopic compositions (as δ 13 C) of organic matter enclosed within seep carbonates from the Gulf of Mexico and the South China Sea to assess if sediment organic matter may be used as a proxy for methane seepage intensity. The δ 13 C values of organic matter (δ 13 C org ) exhibited a large range from −81.4‰ to −23.9‰. Radiocarbon contents of the carbonate-bound organic matter in seep carbonates ranged from 6% to 28% pMC, suggesting organic matter of the carbonates is a mixture of marine particulate organic matter (δ 13 C = −22‰ VPDB and 90% modern carbon) and biomass resulting from methane oxidation (assumed to have 0% modern carbon). Assuming constant productivity in the marine photic zone, it is proposed that seepage intensity and duration are the most important factors controlling the contribution of methane-derived carbon to the sedimentary column. This study reinforces the potential for using δ 13 C values of organic carbon to discern methane-rich environments in ancient sedimentary environments where authigenic carbonate is not present and to constrain the record of AOM through Earth history.

Chemical Geology

Species-area curves indicate the importance of habitats' contributions to regional biodiversity

We examined species-area curves, species composition and similarity (Jaccard's coefficients), and species richness in 17 vegetation types to develop a composite index of a vegetation type's contribution to regional species richness. We collected data from 1 to 1000 m2 scales in 147 nested plots in Rocky Mountain National Park, Colorado, USA to compare three species-area curve models' abilities to estimate the number of species observed in each vegetation type. The log(species)-log(area) curve had the largest adjusted coefficients of determination (r2 values) in 12 of the 17 types, followed by the species-log(area) curve with five of the highest values. When the slopes of the curves were corrected for species overlap among plots with Jaccard's coefficients, the species-log(area) curves estimated values closest to those observed. We combined information from species-area curves and measures of heterogeneity with information on the area covered by each vegetation type and found that the types making the greatest contributions to regional biodiversity covered the smallest areas. This approach may provide an accurate and relatively rapid way to rank hotspots of plant diversity within regions of interest.

Colorado

Nutrient contributions to the Santa Barbara Channel, California, from the ephemeral Santa Clara River

The Santa Clara River delivers nutrient rich runoff to the eastern Santa Barbara Channel during brief (???1-3 day) episodic events. Using both river and oceanographic measurements, we evaluate river loading and dispersal of dissolved macronutrients (silicate, inorganic N and P) and comment on the biological implications of these nutrient contributions. Both river and ocean observations suggest that river nutrient concentrations are inversely related to river flow rates. Land use is suggested to influence these concentrations, since runoff from a subwatershed with substantial agriculture and urban areas had much higher nitrate than runoff from a wooded subwatershed. During runoff events, river nutrients were observed to conservatively mix into the buoyant, surface plume immediately seaward of the Santa Clara River mouth. Dispersal of these river nutrients extended 10s of km into the channel. Growth of phytoplankton and nutrient uptake was low during our observations (1-3 days following runoff), presumably due to the very low light levels resulting from high turbidity. However, nutrient quality of runoff (Si:N:P = 16:5:1) was found to be significantly different than upwelling inputs (13:10:1), which may influence different algal responses once sediments settle. Evaluation of total river nitrate loads suggests that most of the annual river nutrient fluxes to the ocean occur during the brief winter flooding events. Wet winters (such as El Nin??o) contribute nutrients at rates approximately an order-of-magnitude greater than "average" winters. Although total river nitrate delivery is considerably less than that supplied by upwelling, the timing and location of these types of events are very different, with river discharge (upwelling) occurring predominantly in the winter (summer) and in the eastern (western) channel. ?? 2004 Elsevier Ltd. All rights reserved.

Estuarine, Coastal and Shelf Science

Quantifying the relative contribution of an ecological reserve to conservation objectives

Evaluating the role public lands play in meeting conservation goals is an essential step in good governance. We present a tool for comparing the regional contribution of each of a suite of wildlife management units to conservation goals. We use weighted summation ( simple additive weighting ) to compute a Unit Contribution Index ( UCI ) based on species richness, population abundance, and a conservation score based on IUCN Red List classified threat levels. We evaluate UCI for a subset of the 729 participating wetlands of the Integrated Waterbird Management and Monitoring (IWMM) Program across U.S. Fish and Wildlife Service Regions 3 (Midwest USA), 4 (Southeast USA), and 5 (Northeast USA). We found that the median across-Region UCI for Region 5 was greater than Regions 3 and 4, while Region 4 had the greatest within-Region UCI median. This index is a powerful tool for wildlife managers to evaluate the performance of units within the conservation estate.

Global Ecology and Conservation

Atmospheric dust in modern soil on aeolian sandstone, Colorado Plateau (USA): Variation with landscape position and contribution to potential plant nutrients

Rock-derived nutrients in soils originate from both local bedrock and atmospheric dust, including dust from far-distant sources. Distinction between fine particles derived from local bedrock and from dust provides better understanding of the landscape-scale distribution and abundance of soil nutrients. Sandy surficial deposits over dominantly sandstone substrates, covering vast upland areas of the central Colorado Plateau, typically contain 5-40% silt plus clay, depending on geomorphic setting and slope (excluding drainages and depressions). Aeolian dust in these deposits is indicated by the presence of titanium-bearing magnetite grains that are absent in the sedimentary rocks of the region. Thus, contents of far-traveled aeolian dust can be estimated from magnetic properties that primarily reflect magnetite content, such as isothermal remanent magnetization (IRM). Isothermal remanent magnetization was measured on bulk sediment samples taken along two transects in surficial sediment down gentle slopes away from sandstone headwalls. One transect was in undisturbed surficial sediment, the other in a setting that was grazed by domestic livestock until 1974. Calculation of far-traveled dust contents of the surficial deposits is based on measurements of the magnetic properties of rock, surficial deposits, and modern dust using a binary mixing model. At the undisturbed site, IRM-based calculations show a systematic down-slope increase in aeolian dust (ranging from 2% to 18% of the surface soil mass), similar to the down-slope increase in total fines (18-39% of surface soil mass). A combination of winnowing by wind during the past and down-slope movement of sediment likely accounts for the modern distribution of aeolian dust and associated nutrients. At the previously grazed site, dust also increases down slope (5-11%) in sediment with corresponding abundances of 13-25% fines. Estimates of the contributions of aeolian dust to the total soil nutrients range widely, depending on assumptions about grain-size partitioning of potential nutrients in weathered bedrock. Nevertheless, aeolian dust is important for this setting, contributing roughly 40-80% of the rock-derived nutrient stocks (P, K, Na, Mn, Zn, and Fe) in uppermost soil over most of the sampled slope at the undisturbed site, which shows no evidence of recent wind erosion.

Utah

Relative contributions of microbial and infrastructure heat at a crude oil-contaminated site

Biodegradation of contaminants can increase the temperature in the subsurface due to heat generated from exothermic reactions, making temperature observations a potentially low-cost approach for determining microbial activity. For this technique to gain more widespread acceptance, it is necessary to better understand all the factors affecting the measured temperatures. Biodegradation has been occurring at a crude oil-contaminated site near Bemidji, Minnesota for 39 years, creating a quasi-steady-state plume of contaminants and degradation products. A model of subsurface heat generation and transport helps elucidate the contribution of microbial and infrastructure heating to observed temperature increases at this site. We created a steady-state, two-dimensional, heat transport model using previous-published parameter values for physical, chemical and biodegradation properties. Simulated temperature distributions closely match the observed average annual temperatures measured in the contaminated area at the site within less than 0.2 °C in the unsaturated zone and 0.4 °C in the saturated zone. The model results confirm that the observed subsurface heat from microbial activity is due primarily to methane oxidation in the unsaturated zone resulting in a 3.6 °C increase in average annual temperature. Another important source of subsurface heat is from the active, crude-oil pipelines crossing the site. The pipelines impact temperatures for a distance of 200 m and contribute half the heat. Model results show that not accounting for the heat from the pipelines leads to overestimating the degradation rates by a factor of 1.7, demonstrating the importance of identifying and quantifying all heat sources. The model results also highlighted a zone where previously unknown microbial activity is occurring at the site.

Minnesota