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At least 127 records · Page 7Linked to original sources
USGS2010

Breakpoint analysis and assessment of selected stressor variables on benthic macroinvertebrate and fish communities in Indiana streams: Implications for developing nutrient criteria

Water chemistry, periphyton and seston chlorophyll a (CHL a ), and biological community data were collected from 321 sites from 2001 through 2005 to (1) determine statistically and ecologically significant relations among the stressor (total nitrogen, total phosphorus, periphyton and seston CHL a , and turbidity) variables and response (biological community) variables; and, (2) determine the breakpoint of biological community attributes and metrics in response to changes in stressor variables. Because of the typically weak relations among the stressor and response variables, methods were developed to reduce the effects of non-nutrient biological stressors that could mask the effect of nutrients. Stressor variable concentrations ranged from 0.30 to 11.0 milligrams per liter (mg/L) for total nitrogen, 0.025 to 1.33 mg/L for total phosphorus, 2.9 to 768 milligrams per square meter (mg/m 2 ) for periphyton CHL a , and 0.37 to 42 micrograms per liter (µg/L) for seston CHL a . Turbidity, another stressor variable, ranged from 0.8 to 65.4 Nephelometric turbidity units (NTUs). When the nutrient and CHL a data were compared to Dodds’ trophic classifications, 75.0 percent of the values for total nitrogen, 46.6 percent of the values for total phosphorus, 35.8 percent of the values for periphyton CHL a , and 3.5 percent of the values for seston CHL a , were eutrophic. The invertebrate communities were dominated by families considered highly nutrient tolerant, Chironimidae, (41.7 percent relative abundance), Hydropsychidae, (17.3 percent relative abundance), and Baetidae, (10.2 percent relative abundance). Fish communities were dominated by algivores and nutrient-tolerant species, specifically central stonerollers (13.3 percent relative abundance), creek chubs (9.9 percent relative abundance), and bluntnose minnows (9.3 percent relative abundance). Although not the dominant taxa, white sucker, spotted sucker, green sunfish, and bluegill species were correlated (p ‹0.05) with the stressor variables. The median breakpoints ranged from 2.4 to 3.3 mg/L for total nitrogen, from 0.042 to 0.129 mg/L for total phosphorus, from 54 to 68 mg/m 2 for periphyton CHL a , from 4.5 to 7.5 µg/L for seston CHL a , and from 14.1 to 16.1 NTU for turbidity. The breakpoints determined in this study, in addition to Dodds’ trophic classifications, were used as multiple lines of evidence to show changes in fish and invertebrate community and attributes based on annual exposure to nutrients.

Indiana↗
USGS2014

Groundwater-surface water relations in the Fox River watershed: insights from exploratory studies in Illinois and Wisconsin

Exploratory studies were conducted at sites bordering the Fox River in Waukesha, Wisconsin, during 2010 and McHenry, Illinois, during 2011–13. The objectives of the studies were to assess strategies for the study of and insights into the potential for directly connected groundwater and surface-water systems with natural groundwater discharge to streams diverted and (or) streamflow induced (captured) by nearby production-well withdrawals. Several collection efforts of about 2 weeks or less provided information and data on site geology, groundwater and surface-water levels, hydraulic gradients, water-temperature and stream-seepage patterns, and water chemistry including stables isotopes. Overview information is presented for the Waukesha study, and selected data and preliminary findings are presented for the McHenry study.

Illinois;Wisconsin↗
USGS2012

A benthic-macroinvertebrate index of biotic integrity and assessment of conditions in selected streams in Chester County, Pennsylvania, 1998-2009

The Stream Conditions of Chester County Biological Monitoring Network (Network) was established by the U.S. Geological Survey and the Chester County Water Resources Authority in 1969. Chester County encompasses 760 square miles in southeastern Pennsylvania and has a rapidly expanding population. Land-use change has occurred in response to this continual growth, as open space, agricultural lands, and wooded lands have been converted to residential and commercial lands. In 1998, the Network was modified to include 18 fixed-location sites and 9 flexible-location sites. Sites were sampled annually in the fall (October-November) during base-flow conditions for water chemistry, instream habitat, and benthic macroinvertebrates. A new set of 9 flexible-location sites was selected each year. From 1998 to 2009, 213 samples were collected from the 18 fixed-location sites and 107 samples were collected from the 84 flexible-location sites. Eighteen flexible-location sites were sampled more than once over the 12-year period; 66 sites were sampled only once. Benthic-macroinvertebrate data from samples collected during 1998-2009 were used to establish the Chester County Index of Biotic Integrity (CC-IBI). The CC-IBI was based on the methods and metrics outlined in the Pennsylvania Department of Environmental Protection's "A Benthic Index of Biotic Integrity for Wadeable Freestone Streams in Pennsylvania." The resulting CC-IBI consists of scores for benthic-macroinvertebrate samples collected from sites in the Network that related to reference conditions in Chester County. Mean CC-IBI scores for 18 fixed-location sites ranged from 37.21 to 88.92. Thirty-nine percent of the 213 samples collected at the 18 fixed-location sites had a CC-IBI score less than 50; 33 percent, 50 to 70; 28 percent, greater than 70. CC-IBI scores from the 107 flexible-location samples ranged from 23.48 to 99.96. Twenty-five percent of the 107 samples collected at the flexible-location sites had a CC-IBI score less than 50; 33 percent, 50 to 70; and 42 percent, greater than 70. Factors that were found to affect CC-IBI scores are nutrient concentrations, habitat conditions, and percent of wooded and urban land use. A positive relation was determined between mean CC-IBI scores and mean total habitat scores for the 18 fixed-location sites. CC-IBI scores were most strongly affected by stream bank vegetative protection, embeddedness, riparian zone width, and sediment deposition. The highest CC-IBI scores were associated with sites that had greater than 28 percent wooded-wetland-water land use, less than 5 percent urban land use, and no municipal wastewater discharges within 10 miles upstream from the sampling site. The lowest CC-IBI scores were associated with sites where urban land use was greater than 15 percent or a municipal wastewater discharge was within 10 miles upstream from the sampling reach. The Mann Kendall test for trends was used to determine trends in CC-IBI scores and concentrations of nitrate, orthophosphate, and chloride for the 18 fixed-location sites. A positive trend in CC-IBI was determined for six sites, and a negative trend was determined for one site. Positive trends in nitrate concentrations were determined for 4 of the 18 fixed-location sites, and a negative trend in orthophosphate concentrations was determined for 1 of the 18 fixed-location sites. Positive trends in chloride concentrations were determined for 16 of the 18 fixed-location sites.

Pennsylvania↗
USGS2019

Using stream-side groundwater discharge for geochemical exploration in mountainous terrain

Groundwater chemistry has been predominantly used in geochemical exploration studies to identify mineralized targets concealed under transported cover in areas with gentle topography. Another potentially valuable ap-plication that has received little attention is using groundwater chemistry to identify deposits concealed within mountain ridges. A number of geochemical exploration studies have employed surface water chemistry in hilly and mountainous terrain and have demonstrated mixed success. However, groundwater chemistry is potentially a more refined and powerful tool because groundwater sample locations can be selected to target a specific hillslope zone, whereas surface water integrates the geochemical signature of the entire watershed area above the sample site. In this study, we propose an approach that utilizes shallow groundwater samples collected from near-stream, hand-installed sampling points. We tested this approach in Handcart Gulch, an unmined catchment in the Montezuma Mining District, Colorado, USA, where previous studies suggested the possible presence of a concealed mineral occurrence. Seventeen near-stream mini-boreholes were drilled in a stream-parallel 3.3-km-long transect to depths of ~2 m in ferricrete (iron-oxide cemented colluvium and alluvium) using a handheld rock-coring drill. Groundwater in the mini-boreholes was sampled for major and trace element chemistry, as well as environmental tracers including stable water isotopes, dissolved noble gases, helium isotopes, and tritium, to identify possible variations in groundwater age and recharge conditions/sources. Chemistry data delineate a well-defined 900-m-wide zone of elevated SO4, Cu, and other metal concentrations on the east side of the stream. In this zone, Cu concentrations up to 2670 μg/L are 1–3 orders of magnitude greater than concentrations in upstream and downstream areas. Environmental tracer data show no corresponding anomalies in groundwater age or recharge conditions/sources within the zone, suggesting that the source of the elevated metals is a change in bedrock mineralogy as opposed to other hydrologic factors. The groundwater samples therefore successfully identify and refine the location of a potential concealed high-Cu mineral occurrence in the watershed, de-monstrating that near-stream groundwater discharge may be a valuable medium for geochemical exploration in mountainous areas.

Colorado↗
USGS2022

Biogeochemical and ecosystem properties in three adjacent semiarid grasslands are resistant to nitrogen deposition but sensitive to edaphic variability

Drylands have low nitrogen stocks and are predicted to be sensitive to modest increases in reactive nitrogen availability, but direct evidence that atmospheric nitrogen deposition will have sustained effects on dryland ecosystems is sparse and conflicting. We used three long-running in situ nitrogen deposition simulation experiments and a complementary laboratory incubation experiment to address fundamental questions about how nitrogen inputs affect drylands: 1) What are the long- and short-term consequences of nitrogen inputs for biogeochemical and ecosystem properties?; 2) Do these consequences depend on soil moisture availability?; and 3) Does soil texture modify the effects of nitrogen inputs and/or soil moisture availability? In 2011, we established three study sites along a soil texture gradient in Arches National Park with plots receiving 0, 2, 5, or 8 kg N ha -1 annually ( n = 5 per treatment per site). We assessed a suite of biogeochemical metrics over the long- and short-term. To assess longer-term effects, we sampled annually (2013-2019), just prior to spring nitrogen fertilization. To assess short-term effects, we sampled immediately before and after spring nitrogen fertilization in 2013. Additionally, we compared foliar chemistry, soil extracellular enzyme activities, heterotrophic respiration rates, and nitrogen trace gas fluxes at select intervals during the study period (2011-2019). Finally, we conducted a laboratory incubation to measure the individual and interacting effects of soil moisture and nitrogen additions on soil microbial activity. We identified some short-term effects in situ , but no lasting consequences of added nitrogen for any of the metrics measured. In the incubation, soil moisture treatments independently increased heterotrophic respiration rates but did not modify the effects of added nitrogen. In contrast to nitrogen treatments, soil texture was associated with large differences in biogeochemical cycling. Our results oppose the common prediction that coupled dryland biogeochemical cycles are sensitive to nitrogen inputs and suggest that fine scale edaphic heterogeneity is a key driver of dryland ecosystem properties. Synthesis . This study synthesizes a rare, long-term dataset, which provides robust evidence that carbon and nutrient cycling and availability are resistant to realistic levels of atmospheric nitrogen deposition in remote dryland ecosystems.

Utah↗
USGS2014

Executive summary

Fossil fuels from the Appalachian basin region have been major contributors to the Nation’s energy needs over much of the last three centuries. Early records indicate that Appalachian coal was first mined in the middle 1700s (Virginia and Pennsylvania) and was used sparingly to fuel colonial settlements and, later, a fledgling industrial-based economy along the eastern seaboard of the United States (de Witt and Milici, 1989). In 2011, central Appalachian basin coal production accounted for approximately 77 percent of all U.S. metallurgical (or coking) coal and 29 percent of total U.S. production (U.S. Energy Information Administration, 2013). Following initial discoveries and commercial use in western New York (1821) and Ohio and West Virginia (mid-1830s), the Appalachian petroleum (oil and gas) industry began in earnest in 1859 with the discovery of oil at the Drake well in northwestern Pennsylvania. Between 1860 and 1989, the Appalachian basin produced more than 2.5 billion barrels of oil (BBO) and more than 30 trillion cubic feet of gas (TCFG) from more than 500,000 wells (de Witt and Milici, 1989). Although both oil and gas continue to be produced in the Appalachian basin, most new wells in the region are drilled in shale reservoirs to produce natural gas. Appalachian coal and petroleum resources are still available in sufficient quantities to contribute significantly to the Nation’s energy needs. For example, the U.S. Energy Information Administration (2010) estimated that there are 6,484 million short tons of recoverable coal reserves in the Appalachian basin. Similarly, about 14.7 billion barrels of oil equivalent (BBOE) (1.2 BBO+81 TCFG [or 13.5 BBOE]) of recoverable Appalachian basin oil and gas remain available of an estimated ultimate endowment of approximately 25.5 billion BBOE (cumulative production + reserves + estimated recoverable undiscovered resources) (this volume, chap. C.1). U.S. Geological Survey (USGS) Professional Paper 1708 is a modern, indepth collection of reports, cross sections, and maps that describe the geology of the Appalachian basin and its fossil fuel resources. Several of the chapters have been published in outside journals or as other USGS publications. Although this volume is not a comprehensive regional treatment of all notable geologic and fossil fuel localities in the Appalachian basin, the selected study areas and topics presented in the chapters cover large segments of the basin and a wide range of stratigraphic intervals. As the title implies, this volume addresses topics that refer to the locations of coal and petroleum accumulations, the stratigraphic and structural framework, and the geochemical characteristics of the coal beds and petroleum in the basin, as well as the results and documentation of recent USGS assessments of coal, oil, and gas resources in the basin. Many of the maps and accompanying data supporting the reports in this volume are available as downloadable geographic information system (GIS) data files (such as selected coal beds, selected oil and gas fields, locations of oil and gas wells, coal production, coal chemistry, total petroleum system (TPS) boundaries, and bedrock geology). Log ASCII Standard (LAS) files for geophysical (gamma ray) wireline well logs also are included. This publication supplements and updates older USGS regional studies of Appalachian basin coal and petroleum resources such as those by Arndt and others (1968) and the numerous contributors to USGS Miscellaneous Map Series I−917 (for example, Harris and others, 1978), respectively. USGS Professional Paper 1708 is intended primarily for geoscientists in academia, industry, and government who are interested in Appalachian basin geology and its coal and petroleum resources. Other users, however, may find the wide variety of topics, papers, and digital images of value for landuse and policy planning issues. Among the anticipated benefits of the report are improvements in (1) resource assessment estimates and methodology, (2) exploration strategies, (3) basin models, and (4) energy use policies.

Appalachian Basin↗
USGS1980

Quality of ground water in Routt County, northwestern Colorado

Chemical and bacteriological data were collected to describe the quality of water from selected geologic units in Routt County, Colo. Calcium bicarbonate was the dominant water-chemistry type; magnesium, sodium, and sulfate frequently occurred as codominant ions. Specific conductance values ranged from 50 to 6,000 micromhos. Mean values of specific conductance, dissolved solids , and hardness from the sampled aquifers were generally greatest in waters from the older sedimentary rocks of the Lance Formation, Lewis Shale, Mesaverde Group, and Mancos Shale, and least in the ground waters from the alluvial deposits, Browns Park Formation, and the basement complex. Correlations of specific conductance with dissolved solids and specific conductance with hardness were found within specified concentration ranges. On the basis of water-quality analyses, water from the alluvial desposits, Browns Park Formation, and the basement complex generally is the most suitable for domestic uses. Chemical constituents in water from wells or springs exceeded State and Federal standards for public-water supplies or State criteria for agricultural uses were pH, arsenic, boron, chloride, iron, fluoride, manganese, nitrite plus nitrate, selenium, sulfate, or dissolved solids. Total-coliform bacteria were detected in water from 29 sites and fecal-coliform bacteria were detected in water from 6 of the 29 sites. (USGS)

Water-Resources Investigations Report↗
USGS2024

Carbon dioxide toxicity to zebra mussels (Dreissena polymorpha) is dependent on water chemistry

Carbon dioxide (CO 2 ) is gaining interest as a tool to combat aquatic invasive species, including zebra mussels ( Dreissena polymorpha ). However, the effects of water chemistry on CO 2 efficacy are not well described. We conducted five trials in which we exposed adult zebra mussels to a range of CO 2 in water with adjusted total hardness and specific conductance. We compared dose–responses and found differences in lethal concentration to 50% of organisms (LC50) estimates ranging from 108.3 to 179.3 mg/L CO 2 and lethal concentration to 90% of organisms (LC90) estimates ranging from 163.7 to 216.6 mg/L CO 2 . We modeled LC50 and LC90 estimates with measured water chemistry variables from the trials. We found sodium (Na + ) concentration to have the strongest correlation to changes in the LC50 and specific conductance to have the strongest correlation to changes in the LC90. Our results identify water chemistry as an important factor in considering efficacious CO 2 concentrations for zebra mussel control. Additional research into the physiological responses of zebra mussels exposed to CO 2 may be warranted to further explain mode of action and reported selectivity. Further study could likely develop a robust and relevant model to refine CO 2 applications for a wider range of water chemistries. Environ Toxicol Chem 2024;00:1–8. Published 2024. This article is a U.S. Government work and is in the public domain in the USA. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.

Environmental Toxicology and Chemistry↗
USGS2006

Macroinvertebrate abundance, water chemistry, and wetland characteristics affect use of wetlands by avian species in Maine

Our objective was to determine use by avian species (e.g., piscivores, marsh birds, waterfowl, selected passerines) of 29 wetlands in areas with low (<200 μeq l −1 ) acid-neutralizing capacity (ANC) in southeastern Maine. We documented bird, pair, and brood use during 1982–1984 and in 1982 we sampled 10 wetlands with a sweep net to collect invertebrates. We related mean numbers of invertebrates per wetland to water chemistry, basin characteristics, and avian use of different wetland types. Shallow, beaver ( Castor canadensis )-created wetlands with the highest phosphorus levels and abundant and varied macrophyte assemblages supported greater densities of macroinvertebrates and numbers of duck broods (88.3% of all broods) in contrast to deep, glacial type wetlands with sparse vegetation and lower invertebrate densities that supported fewer broods (11.7%). Low pH may have affected some acid-intolerant invertebrate taxa (i.e., Ephemeroptera), but high mean numbers of Insecta per wetland were recorded from wetlands with a pH of 5.51. Other Classes and Orders of invertebrates were more abundant on wetlands with pH > 5.51. All years combined use of wetlands by broods was greater on wetlands with pH ≤ 5.51 (77.4%) in contract to wetlands with pH > 5.51 that supported 21.8% of the broods. High mean brood density was associated with mean number of Insecta per wetland. For lentic wetlands created by beaver, those habitats contained vegetative structure and nutrients necessary to provide cover to support invertebrate populations that are prey of omnivore and insectivore species. The fishless status of a few wetlands may have affected use by some waterfowl species and obligate piscivores.

Hydrobiologia↗
USGS2006

Macroinvertebrate abundance, water chemistry, and wetland characteristics affect use of wetlands by avian species in Maine

Our objective was to determine use by avian species (e.g., piscivores, marsh birds, waterfowl, selected passerines) of 29 wetlands in areas with low (<200 ueq 1-1) acid-neutralizing capacity (ANC) in southeastern Maine. We documented bird, pair, and brood use during 1982?1984 and in 1982 we sampled 10 wetlands with a sweep net to collect invertebrates. We related mean numbers of invertebrates per wetland to water chemistry, basin characteristics, and avian use of different wetland types. Shallow, beaver (Castor canadensis)-created wetlands with the highest phosphorus levels and abundant and varied macrophyte assemblages supported greater densities of macroinvertebrates and numbers of duck broods (88.3% of all broods) in contrast to deep, glacial type wetlands with sparse vegetation and lower invertebrate densities that supported fewer broods (11.7%). Low pH may have affected some acid-intolerant invertebrate taxa (i.e., Ephemeroptera), but high mean numbers of Insecta per wetland were recorded from wetlands with a pH of 5.51. Other Classes and Orders of invertebrates were more abundant on wetlands with pH > 5.51. All years combined use of wetlands by broods was greater on wetlands with pH < 5.51 (77.4%) in contrast to wetlands with pH > 5.51 that supported 21.8% of the broods. High mean brood density was associated with mean number of Insecta per wetland. For lentic wetlands created by beaver, those habitats contained vegetative structure and nutrients necessary to provide cover to support invertebrate populations that are prey of omnivore and insectivore species. The fishless status of a few wetlands may have affected use by some waterfowl species and obligate piscivores.

Conference Paper↗
USGS2005

Trends in surface-water quality at selected National Stream Quality Accounting Network (NASQAN) stations, in Michigan

To demonstrate the value of long-term, water-quality monitoring, the Michigan Department of Environmental Quality (MDEQ), in cooperation with the U.S. Geological Survey (USGS), initiated a study to evaluate potential trends in water-quality constituents for selected National Stream Quality Accounting Network (NASQAN) stations in Michigan. The goal of this study is to assist the MDEQ in evaluating the effectiveness of water-pollution control efforts and the identification of water-quality concerns. The study included a total of nine NASQAN stations in Michigan. Approximately 28 constituents were analyzed for trend tests. Station selection was based on data availability, land-use characteristics, and station priority for the MDEQ Water Chemistry Monitoring Project. Trend analyses were completed using the uncensored Seasonal Kendall Test in the computer program Estimate Trend (ESTREND), a software program for the detection of trends in water-quality data. The parameters chosen for the trend test had (1) at least a 5-year period of record (2) about 5 percent of the observations censored at a single reporting limit, and (3) 40 percent of the values within the beginning one-fifth and ending one-fifth of the selected period. In this study, a negative trend indicates a decrease in concentration of a particular constituent, which generally means an improvement in water quality; whereas a positive trend means an increase in concentration and possible degradation of water quality. The results of the study show an overall improvement in water quality at the Clinton River at Mount Clemens, Manistee River at Manistee, and Pigeon River near Caseville. The detected trend for these stations show decreases in concentrations of various constituents such as nitrogen compounds, conductance, sulfate, fecal coliform bacteria, and fecal streptococci bacteria. The negative trend may indicate an overall improvement in agricultural practices, municipal and industrial wastewater-treatment processes, and effective regulations. Phosphorus data for most of the study stations could not be analyzed because of the data limitations for trend tests. The only station with a significant negative trend in total phosphorus concentration is the Clinton River at Mount Clemens. However, scatter-plot analyses of phosphorus data indicate decreasing concentrations with time for most of the study stations. Positive trends in concentration of nitrogen compounds were detected at the Kalamazoo River near Saugatuck and Muskegon River near Bridgeton. Positive trends in both fecal coliform and total fecal coliform were detected at the Tahquamenon River near Paradise. Various different point and nonpoint sources could produce such positive trends, but most commonly the increase in concentrations of nitrogen compounds and fecal coliform bacteria are associated with agricultural practices and sewage-plant discharges. The constituent with the most numerous and geographically widespread significant trend is pH. The pH levels increased at six out of nine stations on all the major rivers in Michigan, with no negative trend at any station. The cause of pH increase is difficult to determine, as it could be related to a combination of anthropogenic activities and natural processes occurring simultaneously in the environment. Trends in concentration of major ions, such as calcium, sodium, magnesium, sulfate, fluoride, chloride, and potassium, were detected at eight out of nine stations. A negative trend was detected only in sulfate and fluoride concentrations; a positive trend was detected only in calcium concentration. The major ions with the most widespread significant trends are sodium and chloride; three positive and two negative trends were detected for sodium, and three negative and two positive trends were detected for chloride. The negative trends in chloride concentrations outnumbered the positive trends. This result indicates a slight improvement in surface-water quality because chloride as a point source in natural water comes from deicing salt, sewage effluents, industrial wastes, and oil fields. For other major ions, such as magnesium and potassium, both positive and negative trends were detected. These changes in trends indicate changes in surface-water quality caused by a variety of point and non-point sources throughout Michigan, as well as natural changes in the environment.

Michigan↗
USGS1999

Evaluating sediment chemistry and toxicity data using logistic regression modeling

This paper describes the use of logistic-regression modeling for evaluating matching sediment chemistry and toxicity data. Contaminant- specific logistic models were used to estimate the percentage of samples expected to be toxic at a given concentration. These models enable users to select the probability of effects of concern corresponding to their specific assessment or management objective or to estimate the probability of observing specific biological effects at any contaminant concentration. The models were developed using a large database (n = 2,524) of matching saltwater sediment chemistry and toxicity data for field-collected samples compiled from a number of different sources and geographic areas. The models for seven chemicals selected as examples showed a wide range in goodness of fit, reflecting high variability in toxicity at low concentrations and limited data on toxicity at higher concentrations for some chemicals. The models for individual test endpoints (e.g., amphipod mortality) provided a better fit to the data than the models based on all endpoints combined. A comparison of the relative sensitivity of two amphipod species to specific contaminants illustrated an important application of the logistic model approach.

Environmental Toxicology and Chemistry↗
USGS2001

Benthic invertebrate communities and their responses to selected environmental factors in the Kanawha River basin, West Virginia, Virginia, and North Carolina

The effects of selected environmental factors on the composition and structure of benthic invertebrate communities in the Kanawha River Basin of West Virginia, Virginia and North Carolina were investigated in 1997 and 1998. Environmental factors investigated include physiography, land-use pattern, streamwater chemistry, streambed- sediment chemistry, and habitat characteristics. Land-use patterns investigated include coal mining, agriculture, and low intensity rural-residential patterns, at four main stem and seven tributary sites throughout the basin. Of the 37 sites sampled, basin size and physiography most strongly affected benthic invertebrate-community structure. Land-use practices also affected invertebrate community structure in these basins. The basins that differed most from the minimally affected reference condition were those basins in which coal mining was the dominant nonforest land use, as determined by comparing invertebrate- community metric values among sites. Basins in which agriculture was important were more similar to the reference condition. The effect of coal mining upon benthic invertebrate communities was further studied at 29 sites and the relations among invertebrate communities and the selected environmental factors of land use, streamwater chemistry, streambed- sediment chemistry, and habitat characteristics analyzed. Division of coal-mining synoptic-survey sites based on invertebrate-community composition resulted in two groups?one with more than an average production of 9,000 tons of coal per square mile per year since 1980, and one with lesser or no recent coal production. The group with significant recent coal production showed higher levels of community impairment than the group with little or no recent coal production. Median particle size of streambed sediment, and specific conductance and sulfate concentration of streamwater were most strongly correlated with effects on invertebrate communities. These characteristics were related to mining intensity, as measured by thousands of tons of coal produced per square mile of drainage area.

North Carolina, Virginia, West Virginia↗
USGS1982

Liming of acidified waters: issues and research - a report of the International Liming Workshop

Acidic deposition is a problem of significant national and international concern. It is strongly suspected that acidic deposition has adversely affected aquatic resources in Scandinavia and North America. While substantial resources are being devoted to understanding the causative factors associated with surface water acidification, much less research is being conducted on mitigative strategies. Mitigative techniques involving liming may be useful for short-term protection of specific component of aquatic communities or for renovation of seriously impacted aquatic ecosystems. The selection of effective liming strategies is based on an integrated understanding of the following key factors: biological systems, water chemistry, sediment chemistry, hydrology, and watershed characteristics, effectiveness of neutralizing materials, and application techniques. Research in Scandinavia, Canada, and the U.S. has led to a partial understanding of some of the key factors for successful neutralization of surface waters (Bengtsson, 1982; Fraser and Britt, 1982). However, conflicting results of liming operations and experiments have been reported. (Fraser et al., 1982; Fraser and Britt, 1982; Sverdrup and Bjerle, 1982). Additional research is required to improve the ability of scientists and resource managers to select effective liming strategies. An International Liming workshop was convened during 19-25 September 1982 at the University of Washington's Friday Harbor Laboratories. The major objective of this workshop were: - To identify the most critical deficiencies in the scientific understanding of liming techniques and their long-term consequences. - To develop and document a research strategy to address information deficiencies that are pertinent to the protection or renovation of acidic surface waters in the United States. The participants who contributed to this workshop are listed in Table 1.

FWS/OBS↗
USGS2018

Magmatic origin for sediment-hosted Au deposits, Guizhou Province, China: In situ chemistry and sulfur isotope composition of pyrites, Shuiyindong and Jinfeng deposits

The southwest Guizhou Province, China, contains numerous sediment-hosted Au deposits with Au reserves greater than 700 tonnes. To date, the source of ore fluids that formed the Guizhou sediment-hosted Au deposits is controversial, hampering the formulation of genetic models. In this study, we selected the Shuiyindong and Jinfeng Au deposits, the largest strata-bound and fault-controlled deposits in Guizhou, respectively, for detailed research on pyrite chemistry and S isotope composition using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) and laser ablation-multicollector-inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS), respectively. Petrography and pyrite chemistry studies distinguished five generations of pyrite. Among these, pre-ore pyrite 2 and ore pyrite are the most abundant types in the deposits. Pre-ore pyrite 2 is anhedral to euhedral and with ~2,639 ppm As and wider ranges of Cu, Sb, and Pb (<~22–4,837 ppm, <~6 to 532 ppm, and <~4 to 1,344 ppm, respectively). Gold in pre-ore pyrite 2 is below the detection limit of LA-ICP-MS (~2 ppm). Pre-ore pyrite 2 is interpreted to have a sedimentary (syngenetic or diagenetic) origin. Ore pyrite commonly rims the four identified pre-ore pyrites or occurs as individual, anhedral to euhedral crystals. Ore pyrite is enriched in Au (~641 ppm), As (~9,147 ppm), Cu (~1,043 ppm), Sb (~188 ppm), Hg (~43 ppm), and Tl (~22 ppm) in both deposits. Ore pyrite formed mainly by sulfidation of Fe in Fe-bearing host rocks, mainly Fe dolomite, and As, Cu, Sb, Hg, and Tl, also in ore fluids, were incorporated into ore pyrite. In situ δ 34 S isotope ratios for pre-ore pyrite 2 and ore pyrite were measured by LA-MC-ICP-MS. Pre-ore pyrite 2 from Shuiyindong and Jinfeng deposits resulted in δ 34 S values ranging from −0.8 to +3.4‰ and from 5.1 to 10.5‰, respectively. Analyses of ore pyrite from the Shuiyindong have δ 34 S values that vary from −3.3 to +2.5‰, with a median of 0.7‰; analyses of ore pyrite from the Jinfeng range from 8.9 to 11.2‰, with a median at 10.3‰. Available bulk and in situ δ 34 S data in the literature for pre-ore pyrites 1 and 2 and ore-related sulfide minerals including ore pyrite, arsenopyrite, and late ore-stage stibnite, realgar, orpiment, and cinnabar from several Guizhou sediment-hosted Au deposits were compiled for comparison. Pre-ore-stage pyrites from Guizhou sediment-hosted Au deposits have a broad range of δ 34 S values, from −33.8 to + 17.9‰ (including in situ and available bulk δ 34 S data). Ore-related sulfide minerals in all Guizhou sediment-hosted Au deposits, except Jinfeng, have very similar δ 34 S values, and most data plot between ~−5 and +5‰. In the Jinfeng deposit, the ore-related sulfide minerals exhibit δ 34 S values ranging from 1.9 to 18.1‰, with most data plotting between 6 and 12‰. The broad range of S isotope compositions for the sedimentary pyrites (pre-ore pyrites 1 and 2) indicate that S in these pre-ore pyrites was most likely generated by bacterial reduction from marine sulfate. The narrow range of δ 34 S values (~−5–+5‰) for ore-related sulfide minerals in all Guizhou sediment-hosted Au deposits, excepting the Jinfeng deposit, suggests that the deposits may have formed in response to a single widespread metallogenic event. As the S isotope fractionation between hydrothermal fluids and sulfide minerals in a sulfide-dominated system is small (<2‰) at ~250°C, the initial ore fluids that formed the Guizhou sediment-hosted Au deposits would have had δ 34 S values similar to the ore-related sulfide minerals, between ~−5 and +5‰. At Jinfeng, initial ore fluids may have mixed with local fluids with heavier δ 34 S, possibly basin brine ( δ 34 S basin brine >18‰), resulting in elevated δ 34 S values of ore-related sulfide minerals and especially late ore-stage sulfide minerals. Although few igneous rocks are exposed in the mining area around these deposits, there is evidence of magmatic activity ~20 km away. Furthermore, gravity and magnetic geophysical investigations indicate the presence of a pluton ~5 km below the surface of the Shuiyindong district. Based on in situ S isotope results and recent data indicating proximal intrusions, we interpret a deep magmatic S source for the ore fluids that formed the Guizhou sediment-hosted Au deposits. However, as the age for Au mineralization of Guizhou sediment-hosted Au deposits is still debated, the mineralization-magma connection remains hypothetical. Identifying an ore fluid source and time frame for Guizhou Au mineralization continues to be a critically important research goal for this district.

Yunnan-Guizhou-Guangxi region↗
USGS2002

Hydrology and chemistry of floodwaters in the Yolo Bypass, Sacramento River system, California, during 2000

Discharges to and floodwaters in the Yolo Bypass were sampled during winter and spring, 2000. The primary purpose of the study was to link changes in water quality in the Yolo Bypass to inflows from the Sacramento River (over Fremont Weir) and from four local streams that discharge to the west side of the floodplain. Specific conductance, chloride, sulfate, dissolved inorganic nutrients, dissolved organic carbon, particulate carbon and nitrogen, suspended particulate matter (mass), and selected dissolved metals were measured in most of the samples. When the Sacramento River was spilling over Fremont Weir, the water chemistry in the Yolo Bypass was very similar to that in the river except along the western margin of the floodplain where influences of local stream inflow were evident. When flow over Fremont Weir stopped, floodwaters drained from the Yolo Bypass, and the local streams were the major discharges as the floodwaters receded eventually to the perennial channel along the eastern margin of the floodplain. After the initial draining of the floodplain, chemical concentrations at sites along the perennial channel showed strong influences of inflows from Cache Creek and Ridge Cut, which are sources of nutrients and contaminants that are potentially hazardous to wildlife. Runoff from spring storms increased flow in the perennial channel and flushed accumulated nutrients and organic matter to the tidal river. Releases of freshwater to the perennial channel might be beneficial in maintaining habitat quality for aquatic species during the dry seasons.

California↗
USGS2013

Agricultural disturbance response models for invertebrate and algal metrics from streams at two spatial scales within the U.S.

As part of the USGS study of nutrient enrichment of streams in agricultural regions throughout the United States, about 30 sites within each of eight study areas were selected to capture a gradient of nutrient conditions. The objective was to develop watershed disturbance predictive models for macroinvertebrate and algal metrics at national and three regional landscape scales to obtain a better understanding of important explanatory variables. Explanatory variables in models were generated from landscape data, habitat, and chemistry. Instream nutrient concentration and variables assessing the amount of disturbance to the riparian zone (e.g., percent row crops or percent agriculture) were selected as most important explanatory variable in almost all boosted regression tree models regardless of landscape scale or assemblage. Frequently, TN and TP concentration and riparian agricultural land use variables showed a threshold type response at relatively low values to biotic metrics modeled. Some measure of habitat condition was also commonly selected in the final invertebrate models, though the variable(s) varied across regions. Results suggest national models tended to account for more general landscape/climate differences, while regional models incorporated both broad landscape scale and more specific local-scale variables.

Hydrobiologia↗
USGS2009

Simulations of Groundwater Flow and Particle Tracking Analysis in the Area Contributing Recharge to a Public-Supply Well near Tampa, Florida, 2002-05

Shallow ground water in the north-central Tampa Bay region, Florida, is affected by elevated nitrate concentrations, the presence of volatile organic compounds, and pesticides as a result of groundwater development and intensive urban land use. The region relies primarily on groundwater for drinking-water supplies. Sustainability of groundwater quality for public supply requires monitoring and understanding of the mechanisms controlling the vulnerability of public-supply wells to contamination. A single public-supply well was selected for intensive study based on the need to evaluate the dominant processes affecting the vulnerability of public-supply wells in the Upper Floridan aquifer in the City of Temple Terrace near Tampa, Florida, and the presence of a variety of chemical constituents in water from the well. A network of 29 monitoring wells was installed, and water and sediment samples were collected within the area contributing recharge to the selected public-supply well to support a detailed analysis of physical and chemical conditions and processes affecting the water chemistry in the well. A three-dimensional, steady-state groundwater flow model was developed to evaluate the age of groundwater reaching the well and to test hypotheses on the vulnerability of the well to nonpoint source input of nitrate. Particle tracking data were used to calculate environmental tracer concentrations of tritium and sulfur hexafluoride and to calibrate traveltimes and compute flow paths and advective travel times in the model area. The traveltime of particles reaching the selected public-supply well ranged from less than 1 day to 127.0 years, with a median of 13.1 years; nearly 45 percent of the simulated particle ages were less than about 10 years. Nitrate concentrations, derived primarily from residential/commercial fertilizer use and atmospheric deposition, were highest (2.4 and 6.11 milligrams per liter as nitrogen, median and maximum, respectively) in shallow groundwater from the surficial aquifer system and lowest (less than the detection level of 0.06 milligram per liter) in the deeper Upper Floridan aquifer. Denitrification occurred near the interface of the surficial aquifer system and the underlying intermediate confining unit, within the intermediate confining unit, and within the Upper Floridan aquifer because of reducing conditions in this part of the flow system. However, simulations indicate that the rapid movement of water from the surficial aquifer system to the selected public-supply well through karst features (sinkholes) and conduit layers that bypass the denitrifying zones (short-circuits), coupled with high pumping rates, allow nitrate to reach the selected public-supply well in concentrations that resemble those of the overlying surficial aquifer system. Water from the surficial aquifer system with elevated concentrations of nitrate and low concentrations of some volatile organic compounds and pesticides is expected to continue moving into the selected public-supply well, because calculated flux-weighted concentrations indicate the proportion of young affected water contributing to the well is likely to remain relatively stable over time. The calculated nitrate concentration in the selected public-supply well indicates a lag of 1 to 10 years between peak concentrations of nonpoint source contaminants in recharge and appearance in the well.

Scientific Investigations Report↗