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At least 1,243 records · Page 69Linked to original sources

Occurrence of transformation products in the environment

Historically, most environmental occurrence research has focused on the parent compounds of organic contaminants. Research, however, has documented that the environmental transport of chemicals, such as pesticides and emerging contaminants, are substantially underestimated if transformation products are not considered. Although most examples described herein were drawn from research conducted by the U.S. Geological Survey, such results are generally reflective of those found in other parts of the world. Results from a study of 51 streams in the Midwestern United States found that transformation products were seven of the ten most frequently detected pesticide compounds in late spring runoff (after application of pre-emergent herbicides), and nine of the ten most frequently detected compounds in fall season runoff (during and after harvest). In fact, 70% of the total herbicide concentration in water from the Mississippi River Basin was from transformation products. Results from a study of 86 municipal wells in Iowa found the frequency of detection increased from 17%, when pesticide parent compounds were considered, to 53%, when both parents and transformation products were considered. Transformation products were 12 of the 15 most frequently detected compounds for this groundwater study. Although studies on transformation products of synthetic organic compounds other than pesticides are not as common, wastewater treatment plant discharges have repeatedly been shown to contribute such transformation products to streams. In addition, select detergent transformation products have been commonly found in solid waste in the 1000's mg/kg. These findings and many others document that transformation products must be considered to fully assess the potential environmental occurrence of chemical contaminants and their transport and fate in various compartments of the hydrologic system. ?? 2008 Springer-Verlag Berlin Heidelberg.

The Handbook of Environmental Chemistry series↗

Geochemistry of the Amazon Estuary

The Amazon River supplies more freshwater to the ocean than any other river in the world. This enormous volume of freshwater forces the estuarine mixing out of the river channel and onto the continental shelf. On the continental shelf, the estuarine mixing occurs in a very dynamic environment unlike that of a typical estuary. The tides, the wind, and the boundary current that sweeps the continental shelf have a pronounced influence on the chemical and biological processes occurring within the estuary. The dynamic environment, along with the enormous supply of water, solutes and particles makes the Amazon estuary unique. This chapter describes the unique features of the Amazon estuary and how these features influence the processes occurring within the estuary. Examined are the supply and cycling of major and minor elements, and the use of naturally occurring radionuclides to trace processes including water movement, scavenging, sediment-water interaction, and sediment accumulation rates. The biogeochemical cycling of carbon, nitrogen, and phosphorus, and the significances of the Amazon estuary in the global mass balance of these elements are examined.

Amazon River↗

On estimating the economic value of insectivorous bats: Prospects and priorities for biologists

Bats are among the most economically important nondomesticated mammals in the world. They are well-known pollinators and seed dispersers, but crop pest suppression is probably the most valuable ecosystem service provided by bats. Scientific literature and popular media often include reports of crop pests in the diet of bats and anecdotal or extrapolated estimates of how many insects are eaten by bats. However, quantitative estimates of the ecosystem services provided by bats in agricultural systems are rare, and the few estimates that are available are limited to a single cotton-dominated system in Texas. Despite the tremendous value for conservation and economic security of such information, surprisingly few scientific efforts have been dedicated to quantifying the economic value of bats. Here, we outline the types of information needed to better quantify the value of bats in agricultural ecosystems. Because of the complexity of the ecosystems involved, creative experimental design and innovative new methods will help advance our knowledge in this area. Experiments involving bats in agricultural systems may be needed sooner than later, before population declines associated with white-nose syndrome and wind turbines potentially render them impossible.

Book chapter↗

Using transport model interpretations of tracer tests to study microbial processes in groundwater

It has long been known that microorganisms affect the geochemistry of groundwater. But despite this recognition, little detailed information is available regarding the rates and the factors controlling microbial processes in groundwater. Part of the reason stems from the relatively inaccessible nature of most groundwater and the difficulties encountered in obtaining representative samples of groundwater and subsurface sediments. At the same time, most groundwater systems are nutrient poor or oligotrophic environments in which the resident microorganisms are severely stressed and often nearly inactive. These populations are functioning so slowly that many types of activity measurements designed to assess microbial processes in more productive environments are ineffective for groundwater. However, because groundwater is by far the largest reservoir of freshwater in the world ( Freeze and Cherry 1979 ), our lack of knowledge about groundwater microorganisms and their processes represents a significant void in the study of microbial ecology and in our ability to predict the outcome when these reserves are compromised by contamination.

Book chapter↗

Nitrate isotopes in groundwater systems

Nitrate contamination, often associated with agricultural activities, is a major problem in some shallow aquifers and is increasingly becoming a threat to groundwater supplies (Gillham and Cherry, 1978; Ronen et al. , 1983; Spalding and Exner, 1991). The intake of high levels of nitrate can cause methemoglobinemia in infants, and there is substantial evidence collected from animal experiments that N-nitroso compounds are carcinogens. Similar conclusive evidence is not yet available for humans but many observations suggest that these compounds can function as initiators of human carcinogenesis. These findings are the basis for the maximum permissible limit of 10 ppm nitrate-N (50 ppm as NO 3 ) in drinking water set by the World Health Organization and the U.S. Environmental Protection Agency. The impact of high loading of nutrients such as nitrate and phosphorous from agricultural practices via groundwater into surface water is also a major environmental concern, causing eutrophication of streams, rivers and lakes (Hill, 1978; Böhlke and Denver, 1995).

Book chapter↗

Applications of knowledge and predictions of atmospheric rivers

This chapter reviews how AR research is being applied in real-world situations to address issues of flood planning and emergency intervention. It includes water supply management case studies. Examples comprise five distinct sections that show how AR research is being directly applied to the challenges that water managers, dam operators, crisis-management engineers such as USACE, National Weather Service (NWS) personnel, the media, and others face. These topics include how decision-makers on the ground must iteratively alternate between forecasts and their own field observations, especially in unfolding emergency-response conditions, and the trade-offs necessitated between acting on competing priorities such as flood-risk management and water supply management. Ultimately, almost all AR studies have the potential to directly benefit the public’s need for ongoing water supply as well as for accurate weather forecasts and deployable emergency protocols for natural hazards that necessitate municipal, state, and federal government personnel to collaborate.

Book chapter↗

Diving and foraging behaviors

Manatees and dugongs live in tropical and semi-tropical regions around the world. Their preferred habitats are seagrass beds, rivers, lakes, and estuaries. Manatees live in both freshwater and marine systems although habitat preferences vary across the three species, while the dugong is entirely marine. Sirenians are shallow water divers, and their dive durations are short compared to most other marine mammals. The maximum recorded manatee dive duration is 24 min, with the maximum recorded duration of a dugong dive being about half that. Even though the durations of dugong dives are shorter than those of manatees, current data indicate that dugongs dive deeper than manatees. Dive depths for manatees generally do not exceed 5 m, other than during occasional travel over deeper water; however, this may be an artifact of water depth in areas where diving data were recorded, or where manatees live. In some parts of their range, dugongs are found over deep-water seagrass beds and dives have been recorded to more than 30 m. All extant sirenians eat diverse plant-based diets: collectively they have been documented feeding on at least 55 genera of marine and freshwater plants. Although not confirmed for the Amazonian manatee, it is likely that all extant sirenians eat animal, as well as plant, matter. West Indian and African manatees have been documented eating marine and freshwater fish and invertebrates , and for African manatees, these food resources are a regular part of their diet, arguably making them omnivores . Dugongs have been recorded targeting invertebrates at the high latitude limits of their range in winter. All manatees like to drink fresh water, in contrast to dugongs, which live entirely in marine systems and apparently meet the water requirements from their food.

Book chapter↗

Numerical modeling of debris flows: A conceptual assessment

Real-world hazard evaluation poses many challenges for the development and application of numerical models of debris flows. In this chapter we provide a conceptual overview of physically based, depth-averaged models designed to simulate debris-flow motion across three-dimensional terrain. When judiciously formulated and applied, these models can provide useful information about anticipated depths, speeds, and extents of debris-flow inundation as well as debris interactions with structures such as levees and dams. Depth-averaged debris-flow models can differ significantly from one another, however. Some of the greatest differences result from simulation of one-phase versus two-phase flow, use of parsimonious versus information-intensive initial and boundary conditions, use of tuning coefficients versus physically measureable parameters, application of dissimilar numerical solution techniques, and variations in computational speed and model accessibility. This overview first addresses these and related attributes of depth-averaged debris-flow models. It then describes model testing and application to hazard evaluation, with a focus on our own model, D-Claw. The overview concludes with a discussion of outstanding challenges for development of improved debris-flow models and suggestions for prospective model users.

Book chapter↗

Instrumenting caves to collect hydrologic and geochemical data: case study from James Cave, Virginia

Karst aquifers are productive groundwater systems, supplying approximately 25 % of the world’s drinking water. Sustainable use of this critical water supply requires information about rates of recharge to karst aquifers. The overall goal of this project is to collect long-term, high-resolution hydrologic and geochemical datasets at James Cave, Virginia, to evaluate the quantity and quality of recharge to the karst system. To achieve this goal, the cave has been instrumented for continuous (10-min interval) measurement of the (1) temperature and rate of precipitation; (2) temperature, specific conductance, and rate of epikarst dripwater; (3) temperature of the cave air; and (4) temperature, conductivity, and discharge of the cave stream. Instrumentation has also been installed to collect both composite and grab samples of precipitation, soil water, the cave stream, and dripwater for geochemical analysis. This chapter provides detailed information about the instrumentation, data processing, and data management; shows examples of collected datasets; and discusses recommendations for other researchers interested in hydrologic and geochemical monitoring of cave systems. Results from the research, briefly described here and discussed in more detail in other publications, document a strong seasonality of the start of the recharge season, the extent of the recharge season, and the geochemistry of recharge.

Virginia↗

Ecohydrology and Its Relation to Integrated Groundwater Management

In the twentieth century, groundwater characterization focused primarily on easily measured hydraulic metrics of water storage and flows. Twenty-first century concepts of groundwater availability, however, encompass other factors having societal value, such as ecological well-being. Effective ecohydrological science is a nexus of fundamental understanding derived from two scientific disciplines: (1) ecology, where scale, thresholds, feedbacks and tipping points for societal questions form the basis for the ecologic characterization, and (2) hydrology, where the characteristics, magnitude, and timing of water flows are characterized for a defined system of interest. In addition to ecohydrology itself, integrated groundwater management requires input from resource managers to understand which areas of the vast world of ecohydrology are important for decision making. Expectations of acceptable uncertainty, or even what ecohydrological outputs have utility, are often not well articulated within societal decision making frameworks, or within the science community itself. Similarly, “acceptable levels of impact” are difficult to define. Three examples are given to demonstrate the use of ecohydrological considerations for long-term sustainability of groundwater resources and their related ecosystem function. Such examples illustrate the importance of accommodating ecohydrogeological aspects into integrated groundwater management of the twenty-first century, regardless of society, climate, or setting.

Book chapter↗

Interactions of water quality and integrated groundwater management: Examples from the United States and Europe

Groundwater is available in many parts of the world, but the quality of the water may limit its use. Contaminants can limit the use of groundwater through concerns associated with human health, aquatic health, economic costs, or even societal perception. Given this broad range of concerns, this chapter focuses on examples of how water quality issues influence integrated groundwater management. One example evaluates the importance of a naturally occurring contaminant Arsenic (As) for drinking water supply, one explores issues resulting from agricultural activities on the land surface and factors that influence related groundwater management, and the last examines unique issues that result from human-introduced viral pathogens for groundwater-derived drinking water vulnerability. The examples underscore how integrated groundwater management lies at the intersections of environmental characterization, engineering constraints, societal needs, and human perception of acceptable water quality. As such, water quality factors can be a key driver for societal decision making.

Book chapter↗

How biological soil crusts became recognized as a functional unit: a selective history

It is surprising that despite the world-wide distribution and general importance of biological soil crusts (biocrusts), scientific recognition and functional analysis of these communities is a relatively young field of science. In this chapter, we sketch the historical lines that led to the recognition of biocrusts as a community with important ecosystem functions. The idea of biocrusts as a functional ecological community has come from two main scientific branches: botany and soil science. For centuries, botanists have long recognized that multiple organisms colonize the soil surface in the open and often dry areas occurring between vascular plants. Much later, after the initial taxonomic and phyto-sociological descriptions were made, soil scientists and agronomists observed that these surface organisms interacted with soils in ways that changed the soil structure. In the 1970’s, research on these communities as ecological units that played an important functional role in drylands began in earnest, and these studies have continued to this day. Here, we trace the history of these studies from the distant past until 1990, when biocrusts became well-known to scientists and the public.

Book chapter↗

The F'derik-Zouerate iron district: Mesoarchean and Paleoproterozoic iron formation of the Tiris Complex, Islamic Republic of Mauritania

High-grade hematitic iron ores (of HIF, containing 60-65 wt%Fe) have been mined in Mauritania since 1952 from Superior-type iron deposits of the F'derik-Zouerate district. Depletion of the high-grade ores in recent years has resulted in new exploration projects focused on lower-grade magnetite ores occurring in Algoma-type banded iron formation (of BIF, containing ca. 35 wt% Fe). Mauritania is the seventeenth largest iron producer in the world and currently has about 1.1 Gt of crude iron ore reserves.

Book chapter↗

Advancing mangrove macroecology

Mangrove forests provide a wide range of ecosystem services to society, yet they are among the most anthropogenically impacted coastal ecosystems in the world. In this chapter, we discuss and provide examples for how macroecology can advance our understanding of mangrove ecosystems. Macroecology is broadly defined as a discipline that uses statistical analyses to investigate large-scale, universal patterns in the distribution, abundance, diversity, and organization of species and ecosystems, including the scaling of ecological processes and structural and functional relationships. Macroecological methods can be used to advance our understanding of how non-linear responses in natural systems can be triggered by human impacts at local, regional, and global scales. Although macroecology has the potential to gain knowledge on universal patterns and processes that govern mangrove ecosystems, the application of macroecological methods to mangroves has historically been limited by constraints in data quality and availability. Here we provide examples that include evaluations of the variation in mangrove forest ecosystem structure and function in relation to macroclimatic drivers (e.g., temperature and rainfall regimes) and climate change. Additional examples include work focused upon the continental distribution of aboveground net primary productivity and carbon storage, which are rapidly advancing research areas. These examples demonstrate the value of a macroecological perspective for the understanding of global- and regional-scale effects of both changing environmental conditions and management actions on ecosystem structure, function, and the supply of goods and services. We also present current trends in mangrove modeling approaches and their potential utility to test hypotheses about mangrove structural and functional properties. Given the gap in relevant experimental work at the regional scale, we also discuss the potential use of mangrove restoration and rehabilitation projects as macroecological studies that advance the critical selection and conservation of ecosystem services when managing mangrove resources. Future work to further incorporate macroecology into mangrove research will require a concerted effort by research groups and institutions to launch research initiatives and synthesize data collected across broad biogeographic regions.

Book chapter↗

Anticoagulant rodenticides and wildlife: Concluding remarks

Rodents are known to affect human society globally in various adverse ways, resulting in a widespread demand for their continuous control. Anticoagulant rodenticides (ARs) have been, and currently remain, the cornerstone of rodent control throughout the world. Although alternative control methods exist, they are generally less effective. ARs work by affecting vitamin K metabolism, thereby preventing the activation of blood clotting factors and eventual coagulopathy. Since ARs are non-selective, their undoubted benefits for rodent control have to be balanced against the environmental risks that these compounds pose. Although they have been used for decades, pharmacokinetic and toxicokinetic data are mainly available for laboratory mammals and have concentrated on acute effects. Limited information is available on chronic exposure scenarios and for wildlife species. Important gaps exist in our understanding of the large inter- and intra-species differences in sensitivity to ARs, especially for non-target species, and in our knowledge about the occurrence and importance of sub-lethal effects in wildlife. It is clear that mere presence of AR residues in the body tissues may not indicate the occurrence of effects, although unequivocal assessment of effects under field conditions is difficult. Ante-mortem symptoms, like lethargy, subdued behaviour and unresponsiveness are generally not very specific as is true for more generic post-mortem observations (e.g. pallor of the mucous membranes or occurrence of haemorrhages). It is only by combining ante or post-mortem data with information on exposure that effects in the field may be confirmed. We do know however that a wide variety of non-target species are directly exposed to ARs. Secondary exposure in predators is also widespread although there is limited information on whether this exposure causes actual effects. Exposure is driven by ecological factors and is context specific with respect to spatial habitat configuration and bait placement. Another key factor that affects the interaction between ARs and wildlife is the development of resistance in target species. The development of resistance has resulted in higher use of SGARs, thereby increasing the potential of non-target and secondary exposure. AR use has increasingly become more strictly regulated, increasing the need for alternatives. Alternatives are available, including non-anticoagulant rodenticides, but these may also pose significant risk to environmental organisms, humans and pets. There are also various mitigation measures that can be implemented when using ARs, including bait protection, pulsed baiting at the onset of infestation, restricting use by non-professionals, and avoiding use in areas of high non-target density. Reduction in secondary exposure may result from e.g. non-chemical control, habitat management, and, in agricultural habitats, the use of lure crops and supplemental feeding. Such Integrated Pest Management (IPM) may not only reduce non-target exposure but also benefit resistance management. Barriers to adopt IPM approaches however, include the perception that they do not work or too slowly and are more laborious, expensive and time consuming. It is therefore important that the expectations of stakeholders are considered and managed. Nevertheless, further development of alternatives and IPM measures is essential, so the key research priority related to rodent control may ultimately be to address the lack of scientific assessment of the effectiveness of both specific AR mitigation measures and of IPM approaches to rodent control.

Book chapter↗

The increasing wildfire and post-fire debris-flow threat in western USA, and implications for consequences of climate change

In southern California and the intermountain west of the USA, debris flows generated from recently-burned basins pose significant hazards. Increases in the frequency and size of wildfires throughout the western USA can be attributed to increases in the number of fire ignitions, fire suppression practices, and climatic influences. Increased urbanization throughout the western USA, combined with the increased wildfire magnitude and frequency, carries with it the increased threat of subsequent debris-flow occurrence. Differences between rainfall thresholds and empirical debris-flow susceptibility models for southern California and the intermountain west indicate a strong influence of climatic and geologic settings on post-fire debris-flow potential. The linkages between wildfires, debris-flow occurrence, and global warming suggests that the experiences in the western United States are highly likely to be duplicated in many other parts of the world, and necessitate hazard assessment tools that are specific to local climates and physiographies.

Book chapter↗

Risk management of El Chichón and Tacaná Volcanoes: Lessons learned from past volcanic crises: Chapter 8

Before 1985, Mexico lacked civil-protection agencies with a mission to prevent and respond to natural and human-caused disasters; thus, the government was unprepared for the sudden eruption of El Chichón Volcano in March–April 1982, which produced the deadliest volcanic disaster in the country’s recorded history (~2,000 fatalities). With the sobering lessons of El Chichón still fresh, scientists and governmental officials had a higher awareness of possible disastrous outcome when Tacaná Volcano began to exhibit unrest in late 1985. Seismic and geochemical studies were quickly initiated to monitor activity. At the same time, scientists worked actively with officials of the Federal and local agencies to develop the “Plan Operativo” (Operational Plan)—expressly designed to effectively communicate hazards information and reduce confusion and panic among the affected population. Even though the volcano-monitoring data obtained during the Tacaná crisis were limited, when used in conjunction with protocols of the Operational Plan, they proved useful in mitigating risk and easing public anxiety. While comprehensive monitoring is not yet available, both El Chichón and Tacaná volcanoes are currently monitored—seismically and geochemically—within the scientific and economic resources available. Numerous post-eruption studies have generated new insights into the volcanic systems that have been factored into subsequent volcano monitoring and hazards assessments. The State of Chiapas is now much better positioned to deal with any future unrest or eruptive activity at El Chichón or Tacaná, both of which at the moment are quiescent as of 2014. Perhaps more importantly, the protocols first tested in 1986 at Tacaná have served as the basis for the development of risk-management practices for hazards from other active and potentially active volcanoes in Mexico. These practices have been most notably employed since 1994 at Volcán Popocatépetl since a major eruption under unfavorable prevailing winds may constitute a substantial threat to densely populated metropolitan Mexico City. While the 1982 El Chichón disaster was a national tragedy, it greatly accelerated volcanic emergency preparedness and multidisciplinary scientific studies of eruptive processes and products, not only at El Chichón but also at other explosive volcanoes in Mexico and elsewhere in the world.

Chiapas↗

Environmental impact of the landslides caused by the 12 May 2008, Wenchuan, China earthquake

The magnitude 7.9 (M w ) Wenchuan, China, earthquake of May 12, 2008 caused at least 88,000 deaths of which one third are estimated to be due to the more than 56,000 earthquake-induced landslides. The affected area is mountainous, featuring densely-vegetated, steep slopes through which narrowly confined rivers and streams flow. Numerous types of landslides occurred in the area, including rock avalanches, rock falls, translational and rotational slides, lateral spreads and debris flows. Some landslides mobilized hundreds of million cubic meters of material, often resulting in the damming of rivers and streams, impacting river ecosystems and morphology. Through an extensive search of both Chinese- and English-language publications we provide a summary of pertinent research on environmental effects, emphasizing key findings. Environmental effects caused by landslides include the alteration of agriculture, changes to natural ecosystems, changes in river morphology due to landslide dams and other effects such as sedimentation and flooding. Damage by landslides to the giant panda reserve infrastructure and habitat, was severe, threatening the survival of one of the world’s rarest species. The Panda reserves are of national significance to China, and to the vital tourism economy of the region. One of the major impacts to both the natural and built environment is the complete relocation of some human populations and infrastructure to new areas, resulting in the abandonment of towns and other areas that were damaged by the earthquake and landslides. The landslide effects have affected the biodiversity of the affected area, and it has been hypothesized that strict forest preservation measures taken in the years preceding the earthquake resulted in a reduction of the environmental damage to the area.

Wenchuan↗