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USGS2000

Forecasting selenium discharges to the San Francisco Bay-Delta Estuary: Ecological effects of a proposed San Luis drain extension

During the next few years, federal and state agencies may be required to evaluate proposals and discharge permits that could significantly change selenium (Se) inputs to the San Francisco Bay-Delta Estuary (Bay-Delta), particularly in the North Bay (i.e., Suisun Bay and San Pablo Bay). These decisions may include discharge requirements for an extension of the San Luis Drain (SLD) to the estuary to convey subsurface agricultural drainage from the western San Joaquin Valley (SJV), a renewal of an agreement to allow the existing portion of the SLD to convey subsurface agricultural drainage to a tributary of the San Joaquin River (SJR) (coincident with changes in flow patterns of the lower SJR), and refinements to promulgated Se criteria for the protection of aquatic life for the estuary. Understanding the biotransfer of Se is essential to evaluating the fate and impact of proposed changes in Se discharges to the Bay-Delta. However, past monitoring programs have not addressed the specific protocols necessary for an element that bioaccumulates. Confusion about Se threats in the past have stemmed from failure to consider the full complexity of the processes that result in Se toxicity. Past studies show that predators are more at risk from Se contamination than their prey, making it difficult to use traditional methods to predict risk from environmental concentrations alone. In this report, we employ a novel procedure to model the fate of Se under different, potentially realistic load scenarios from the SJV. For each potential load, we progressively forecast the resulting environmental concentrations, speciation, transformation to particulate form, bioaccumulation by invertebrates, trophic transfer to predators, and effects in those predators. Enough is known to establish a first order understanding of effects should Se be discharged directly into the North Bay via a conveyance such as the SLD. Our approach uses 1) existing knowledge concerning the biogeochemical reactions of Se (e.g., speciation, partitioning between dissolved and particulate forms, and bivalve assimilation efficiency) and 2) site-specific data mainly from 1986 to 1996 on clams and bottom-feeding fish and birds. Forecasts of Se loading from oil refineries and agricultural drainage from the SJV enable the calculation of a composite freshwater endmember Se concentration at the head of the estuary and at Carquinez Strait as a foundation for modeling. Our analysis of effects also takes into account the mode of conveyance for agricultural drainage (i.e., the SLD or SJR). The effects of variable flows on a seasonal or monthly basis from the Sacramento River and SJR are also considered. The results of our forecasts for external SJV watershed sources of Se mirror predictions made since 1955 of a worsening salt (and by inference, Se) buildup exacerbated by the arid climate and irrigation for agricultural use. We show that the reservoir of Se in the SJV is sufficient to provide loading at an annual rate of approximately 42,500 pounds (lbs) of Se to a Bay-Delta disposal point for 63 to 304 years at the lower range of our projections, even if influx of Se from the California Coast Ranges could be curtailed. Disposal of wastewaters on an annual basis outside of the SJV may slow the degradation of valley resources, but drainage alone cannot alleviate the salt and Se buildup in the SJV, at least within a century. Our forecasts show the different proportions of Se loading to the Bay-Delta. Oil refinery loads from 1986 to 1992 ranged from 11 to 15 lbs Se per day; with treatment and cleanup, loads decreased to 3 lbs Se per day in 1999. In contrast, SJV agricultural drainage loads could range from of 45 to 117 lbs Se per day across a set of reasonable conditions. Components of this valley-wide load include five source subareas (i.e., Grassland, Westlands, Tulare, Kern, and Northern) based on water and drainage management. Loads vary per subarea mainly because of proximity of the s

California↗

USGS2021

The timing and magnitude of changes to Hortonian overland flow at the watershed scale during the post-fire recovery process

Extreme hydrologic responses following wildfires can lead to floods and debris flows with costly economic and societal impacts. Process-based hydrologic and geomorphic models used to predict the downstream impacts of wildfire must account for temporal changes in hydrologic parameters related to the generation and subsequent routing of infiltration-excess overland flow across the landscape. However, we lack quantitative relationships showing how parameters change with time-since-burning, particularly at the watershed scale. To assess variations in best-fit hydrologic parameters with time, we used the KINEROS2 hydrological model to explore temporal changes in hillslope saturated hydraulic conductivity ( K sh ) and channel hydraulic roughness ( n c ) following a wildfire in the upper Arroyo Seco watershed (41.5 km 2 ), which burned during the 2009 Station fire in the San Gabriel Mountains, California, USA. This study explored runoff-producing storms between 2008 and 2014 to infer watershed hydraulic properties by calibrating the model to observations at the watershed outlet. Modelling indicates K sh is lowest in the first year following the fire and then increases at an average rate of approximately 4.2 mm/h/year during the first 5 years of recovery. The estimated values for K sh in the first year following the fire are similar to those obtained in previous studies on smaller watersheds (<1.5 km 2 ) following the Station fire, suggesting hydrologic changes detected here can be applied to lower-order watersheds. Hydraulic roughness, n c , was lowest in the first year following the fire, but increased by a factor of 2 after 1 year of recovery. Post-fire observations suggest changes in n c are due to changes in grain roughness and vegetation in channels. These results provide quantitative constraints on the magnitude of fire-induced hydrologic changes following severe wildfires in chaparral-dominated ecosystems as well as the timing of hydrologic recovery.

California↗

USGS1993

Flow recommendations for maintaining riparian vegetation along the Upper Missouri River, Montana

Montana Power Company, Inc. (MPC) submitted a final license application to the Federal Energy Regulatory Commission (FERC) on November 30, 1992. In this application, MPC proposed a plan for the protection of fish, wildlife, habitat, and water-quality resources. One concern was maintenance of woody riparian vegetation along the Missouri River, especially along the Wild and Scenic reach of the river, where the riparian forest occurs in relatively small discontinuous stands. The objectives of this project were 1) to recommend flows that would protect and enhance riparian forests along the Missouri River, and 2) to develop elements of an environmental monitoring program that could be used to assess the effectiveness of the recommended flows. Plains cottonwood ( Populus deltoides subsp. monilifera ) is the key structural component of riparian forests along the Missouri River. Therefore, we focused our analysis on factors affecting populations of this species. Previous work had demonstrated that the age structure of cottonwood populations is strongly influenced by aspects of flow that promote successfully establishment. In this study our approach was to determine the precise age of plains cottonwood trees growing along the Upper Missouri River and to relate years of establishment to the flow record. Our work was carried out between Coal Banks Landing and the Fred G. Robinson Bridge within the Wild and Scenic portion of the Missouri River. This segment of the river occupies a narrow valley and exhibits little channel migration. Maps and notes from the journals of Lewis and Clark (1804-1806) suggest that the present distribution and abundance of cottonwoods within the study reach is generally similar to presettlement conditions. Flows in the study reach are influenced by a number of dams and diversions, most importantly, Canyon Ferry and Tiber Dams. Although flow regulation has decreased peak flows and increased low flows, the gross seasonal pattern of flow has not been greatly altered. Most cottonwood establishment in our study reach occurred in years with a peak mean daily flow greater than 1,400 m 3 /s (49,434 cfs), or in the two years following such a flow. These years include 35 out of the 111 years of record, and account for establishment of 47 of 60 trees examined, a highly significant relationship. Infrequent establishment of cottonwood trees is not the result of scarcity of seed or seedlings. In the study reach seedlings become established most years on bare, relatively low surfaces deposited by the river. However, the high elevation of establishment of all trees dating to before 1978 indicates that only individuals established on high flood deposits are able to survive subsequent floods and ice jams. In order to maintain the present abundance of plains cottonwood in the study area we recommend flood flows in excess of 1,400 m 3 /s (49,434 cfs) measures as mean daily discharge at Fort Benton (U.S. Geological Survey gage 06090800) with a recurrence interval of approximately 9 years. Because cottonwood seeds remain viable for only a few weeks, and because seedling require a moist, bare surface, we further recommend maintenance of the historic timing of flooding with peak flood flows occurring between mid-May and late-June. Flow is not the only factor influencing cottonwood regeneration along this reach of the Missouri River. Land management, especially cattle grazing, is clearly having an impact, and changes in cottonwood populations could be expected if these practices were altered. However, the dependence of cottonwood establishment on high flow is clear in this reach in spite of the effects of other factors. Given the value of the resource, we strongly suggest establishment of a monitoring program to determine the effectiveness of the recommended flows and to provide the data necessary for refining them. We recommend a monitoring program that would include: 1) ten permanent, widely space channel cross sections for annual measurement of channel geometry and cottonwood establishment, growth, and survival; 2) five livestock enclosures to monitor the influence of grazing in the study area; and 3) low-elevation aerial photography of the reach every five years and after every flood to detect changes in channel geometry and forested area. Because cottonwood establishment is episodic, a long-term commitment to the monitoring effort is essential. In addition, cross sections and exclosures should be easy enough to access that measurements during flood years are possible.

Montana↗

USGS2017

A simulation method for combining hydrodynamic data and acoustic tag tracks to predict the entrainment of juvenile salmonids onto the Yolo Bypass under future engineering scenarios

During water year 2016 the U.S. Geological Survey California Water Science Center (USGS) collaborated with the California Department of Water Resources (DWR) to conduct a joint hydrodynamic and fisheries study to acquire data that could be used to evaluate the effects of proposed modifications to the Fremont Weir on outmigrating juvenile Chinook salmon. During this study the USGS surgically implanted acoustic tags in juvenile late fall run Chinook salmon from the Coleman National Fish Hatchery, released the acoustically tagged juvenile salmon into the Sacramento River upstream of the Fremont Weir, and tracked their movements as they emigrated past the western end of the Fremont Weir. The USGS analyzed tracking data from the acoustically tagged juvenile salmon along with detailed hydrodynamic data collected in the Sacramento River during the winter/spring of water year 2016 in the vicinity of the western end of the Fremont Weir to assess the potential for enhancing the entrainment of Sacramento River Chinook salmon onto the Yolo Bypass under six different Fremont Weir modification scenarios. Each modification scenario consists of a notch or multiple notches in the Fremont Weir which are designed to divert a portion of the Sacramento River onto the Yolo Bypass when the Sacramento River is below the crest of the Fremont Weir. The primary goal of this entrainment analysis was to investigate how the location of the notch or notches in each scenario affected the entrainment of juvenile Chinook salmon onto the Yolo Bypass, and to predict the notch location or locations that would result in maximum entrainment under each modification scenario. Stumpner et al.’s (in review) analysis of hydraulic data collected during the 2016 study period showed that backwater effects in the Sacramento River created significant variability in the relationship between Sacramento River stage and the proportion of the Sacramento River flow that we expect to be diverted onto the Yolo Bypass under the modification scenarios. Because of this variability, accurately evaluating the entrainment potential of possible notch locations for each scenario required combining historic abundance data for juvenile Sacramento River Chinook salmon with historic hydraulic data for the Sacramento River in the vicinity of the Fremont Weir, so that the entrainment estimates would reflect the covariance between Sacramento River stage, Sacramento River discharge, and juvenile salmon abundance within the historic record. We used a Monte Carlo simulation framework to combine the high resolution hydrodynamic data and acoustic tag track data collected in 2016 with historic juvenile salmon abundance, Sacramento River stage, and Sacramento River discharge data from a period spanning water years 1996-2010 to assess the entrainment potential of different weir modification scenarios under historic conditions. The scenarios we simulated consisted of four single notch configurations, and two multiple notch configurations in the vicinity of the western end of the Fremont Weir. For each notch configuration the 15-water-year entrainment simulation was repeated for 63 possible notch locations in the vicinity of the western end of the Fremont Weir. This approach allowed us to assess the effect of notch location on the entrainment of juvenile salmonids onto the Yolo Bypass for each of the six notch configurations that we evaluated. The entrainment simulations showed that the location of each notch configuration had a major impact on the entrainment for each scenario; the predicted entrainment of some scenarios varied by as much as 400% based on where the notch (or notches) was (were) located in the study area. All of the single notch scenarios performed best when they were located within a 330 ft (100 meter) long section of the Sacramento River bank adjacent to the western terminus of the Fremont Weir (Table 1). Both of the multiple notch scenarios performed best when their upstream notches were located about 660 ft (200 meters) upstream of the western terminus of the Fremont Weir (Table 1). The results of the entrainment simulations indicated that for each notch configuration the same notch location produced near-maximum entrainment regardless of run abundance timing; this result suggests that there are areas within the study are where a notch (or notches) can be sited to achieve maximum entrainment for all runs (barring significant behavioral or physiological differences between runs). In addition, the simulation results indicate that for each notch configuration the same location is expected to produce nearmaximum entrainment for both wet water years and dry water years. Based on the results of the entrainment simulation we make three general recommendations for strategies to improve the entrainment potential of a notch in the Fremont Weir: 1) Comparisons between the maximum entrainment potential for each scenario suggested that total entrainment of winter run, spring run, and fall run salmon onto the Yolo Bypass can be increased by increasing the amount of water entering a notch when the Sacramento River stage is between 19 ft and 22 ft NAVD88; this could be accomplished by lowering notch invert elevations or by adding a control section to the Sacramento River to raise stage for a given discharge. 2) The relationship between Sacramento River stage and entrainment for each scenario indicated that entrainment efficiency for each scenario declined significantly once Sacramento River stage exceeded bankfull (approximately 28.5 ft NAVD88). This effect was likely due to inundation of the floodplain between the Sacramento River and the Fremont Weir; Stumpner et. al (In Review) have documented a reduction in the strength of the secondary circulation and centralization of the downwelling zone in the Sacramento River when this floodplain is inundated. Therefore, increasing the height of the river right bank of the Sacramento River to coincide with the height of the Fremont Weir is recommended to increase entrainment at higher stages. 3) Bathymetric features upstream of notch openings appeared to have a major impact on the entrainment potential of the simulated notches. For this reason we recommend taking care to avoid siting notches immediately downstream of bank features that alter the sidewall boundary layer, and we expect that smoothing the bank bathymetry upstream of a notch will enhance entrainment. Finally, we caution that the entrainment simulation was based on the behavior of large hatchery smolts, so it is likely that our results will be sensitive to any differences in behavior and physiology between these hatchery surrogates and naturally migrating juvenile salmon.

California↗

USGS1984

Preliminary study of the aquifers of the lower Mesilla Valley in Texas and New Mexico by model simulation

The aquifers in the lower Mesilla Valley of Texas and New Mexico provide water for irrigation, industrial use, and municipal supply. At present (1984), the shallow aquifer is used principally for irrigation. The medium-depth aquifer (the top of which is about 160 to 260 feet below land surface) and deep aquifer (about 460 to 680 feet below land surface) are used almost exclusively by the city of El Paso to provide about 28 percent of the city's ground-water withdrawal of about 82,000 acre-feet in 1980; however, a small percentage of the pumpage is from the shallow aquifer. The potential use of the medium-depth and deep aquifers for irrigation, together with a planned increase in pumping by the city, is causing concern on the part of El Paso water planners over the impact of this development on the limited supply from the two aquifers. A three-dimensional digital model of the aquifers was developed to evaluate the responses of water levels to various plans of development, with particular emphasis on the medium-depth and deep aquifers in and near the Canutillo well field. Simulations also were made to show the effect of eliminating seepage from the Rio Grande to the aquifer system. The model simulations indicate that if pumpage by the city of El Paso during 1^76-80 increases to 10,000 acre-feet, per year from the medium-depth aquifer and to 20,000 acre-feet per year from the deep aquifer, and elsewhere in the study area pumping was held constant at the 1975 rate, then additional lowering of water levels in representative observation wells would be as much as 24 feet in the medium-depth aquifer and as much as 52 feet in the deep aquifer. The water levels would decline sharply during the first few months, after which the levels would become nearly stable because the leakage between the aquifers probably is enough to balance the increased pumpage. The model also indicated that lining of the channel of the Rio Grande would result in an additional lowering of water levels in representative observation wells by 10 feet in the medium-depth aquifer and 8 feet in the deep aquifer. The accuracy of water levels simulated by a model is dependent on the accuracy and distribution of input data and how well model boundary conditions approximate actual boundary conditions. Because of a lack of hydro!ogic data (especial ly water-1 evel information) everywhere except the Canutillo wellfield area, because the simulated cone of depression reached two boundaries, and because the model contained an error and several deficiencies as explained in the "Discussion" section, the simulated results need to be interpreted carefully. The authors believe that the simulated results could be used best as a preliminary and conceptual evaluation of the pumping effects at the Canutillo well field, not as a quantitative interpretation. Although the patterns of simulated hydrographs of water-level change in observation wells in the Canutillo field generally may be correct, the amount of change simulated probably is not correct. Because the salinity of water in all three aquifers south of Canutillo is greater than elsewhere in the study area, there is potential for movement of this water northward toward the Canutillo well field if the cone of depression reaches that part of the aquifer system. This potential should be evaluated in future geohydrologic studies of the lower Mesilla Valley.

New Mexico, Texas↗

USGS1999

Hydrogeology and water quality of the upper Floridan aquifer, western Albany area, Georgia

Geologic, hydrologic, and water-quality data were collected to refine the hydrogeologic framework conceptual model of the Upper Floridan aquifer, and to qualitatively evaluate the potential of human activities to impact water quality in the Upper Floridan aquifer in the western Albany area, Georgia. Ground-water age dating was conducted by using chlorofluorocarbons (CFC) and tritium concentrations in water from the Upper Floridan aquifer to determine if recharge and possible contaminant migration to the aquifer is recent or occurred prior to the introduction of CFCs and tritium in the early 1950's into the global natural water system. Data were collected from core holes and wells installed during this study and previously existing wells in the Albany area. Hydrogeologic data collected during this study compare well to the regional hydrogeologic conceptual model developed during previous studies. However, the greater data density available from this study shows the dynamic and local variability in the hydrologic character of the Upper Floridan aquifer in more detail. The occurrence of sediment sizes from clay to gravel in the overburden, the absence of overburden because of erosion or sinkhole collapse, and large areas lacking surface drainage west of the Flint River provide potential areas for recharge and contaminant migration from the surface to the Upper Floridan aquifer throughout the study area. Ground-water ages generally range from 9 to 34 years, indicating that recharge consisting of 'modern' water (post early-1950's) is present in the aquifer. Ground-water ages and hydraulic heads in the Upper Floridan aquifer have an irregular distribution, indicating that localized areas of recharge to the aquifer are present in the study area. Generally, water in the Upper Floridan aquifer is calcium-bicarbonate rich, having low concentrations of magnesium, potassium, sodium, chloride, and sulfate. Water in the Upper Floridan aquifer is oxygenated, having dissolved-oxygen concentrations greater than 2 milligrams per liter. Nitrite-plus-nitrate as nitrogen, is present in the aquifer at concentrations ranging from less than 0.02 to 5.5 milligrams per liter. Areas of higher nitrate concentrations in the aquifer, coupled with widely distributed localized recharge to the aquifer indicates that suburban residential and agricultural land use in the western Albany area may affect water quality in the Upper Floridan aquifer. However, concentrations exceeding drinking water criteria were not detected in the study area. Generally, water in the Upper Floridan aquifer is calcium-bicarbonate rich, having low concentrations of magnesium, potassium, sodium, chloride, and sulfate. Water in the Upper Floridan aquifer is oxygenated, having dissolved-oxygen concentrations greater than 2 milligrams per liter. Nitrite-plus-nitrate as nitrogen, is present in the aquifer at concentrations ranging from less than 0.02 to 5.5 milligrams per liter. Areas of higher nitrate concentrations in the aquifer, coupled with widely distributed localized recharge to the aquifer indicates that suburban residential and agricultural land use in the western Albany area may affect water quality in the Upper Floridan aquifer. However, concentrations exceeding drinking water criteria were not detected in the study area.

Georgia↗

USGS1996

Surface-water hydrology and runoff simulations for three basins in Pierce County, Washington

The surface-water hydrology in Clear, Clarks, and Clover Creek Basins in central Pierce County, Washington, is described with a conceptual model of the runoff processes and then simulated with the Hydrological Simulation Program-FORTRAN (HSPF), a continuous, deterministic hydrologic model. The study area is currently undergoing a rapid conversion of rural, undeveloped land to urban and suburban land that often changes the flow characteristics of the streams that drain these lands. The complex interactions of land cover, climate, soils, topography, channel characteristics, and ground- water flow patterns determine the surface-water hydrology of the study area and require a complex numerical model to assess the impact of urbanization on streamflows. The U.S. Geological Survey completed this investigation in cooperation with the Storm Drainage and Surface Water Management Utility within the Pierce County Department of Public Works to describe the important rainfall-runoff processes within the study area and to develop a simulation model to be used as a tool to predict changes in runoff characteristics resulting from changes in land use. The conceptual model, a qualitative representation of the study basins, links the physical characteristics to the runoff process of the study basins. The model incorporates 11 generalizations identified by the investigation, eight of which describe runoff from hillslopes, and three that account for the effects of channel characteristics and ground-water flow patterns on runoff. Stream discharge was measured at 28 sites and precipitation was measured at six sites for 3 years in two overlapping phases during the period of October 1989 through September 1992 to calibrate and validate the simulation model. Comparison of rainfall data from October 1989 through September 1992 shows the data-collection period beginning with 2 wet water years followed by the relatively dry 1992 water year. Runoff was simulated with two basin models-the Clover Creek Basin model and the Clear-Clarks Basin model-by incorporating the generalizations of the conceptual model into the construction of two HSPF numerical models. Initially, the process-related parameters for runoff from glacial-till hillslopes were calibrated with numerical models for three catchment sites and one headwater basin where streamflows were continuously measured and little or no influence from ground water, channel storage, or channel losses affected runoff. At one of the catchments soil moisture was monitored and compared with simulated soil moisture. The values for these parameters were used in the basin models. Basin models were calibrated to the first year of observed streamflow data by adjusting other parameters in the numerical model that simulated channel losses, simulated channel storage in a few of the reaches in the headwaters and in the floodplain of the main stem of Clover Creek, and simulated volume and outflow of the ground-water reservoir representing the regional ground-water aquifers. The models were run for a second year without any adjustments, and simulated results were compared with observed results as a measure of validation of the models. The investigation showed the importance of defining the ground-water flow boundaries and demonstrated a simple method of simulating the influence of the regional ground-water aquifer on streamflows. In the Clover Creek Basin model, ground-water flow boundaries were used to define subbasins containing mostly glacial outwash soils and not containing any surface drainage channels. In the Clear-Clarks Basin model, ground-water flow boundaries outlined a recharge area outside the surface-water boundaries of the basin that was incorporated into the model in order to provide sufficient water to balance simulated ground-water outflows to the creeks. A simulated ground-water reservoir used to represent regional ground-water flow processes successfully provided the proper water balance of inflows and outfl

Washington↗

USGS2009

Assessing the impact of land use change on hydrology by ensemble modeling (LUCHEM). I: Model intercomparison with current land use

This paper introduces the project on 'Assessing the impact of land use change on hydrology by ensemble modeling (LUCHEM)' that aims at investigating the envelope of predictions on changes in hydrological fluxes due to land use change. As part of a series of four papers, this paper outlines the motivation and setup of LUCHEM, and presents a model intercomparison for the present-day simulation results. Such an intercomparison provides a valuable basis to investigate the effects of different model structures on model predictions and paves the ground for the analysis of the performance of multi-model ensembles and the reliability of the scenario predictions in companion papers. In this study, we applied a set of 10 lumped, semi-lumped and fully distributed hydrological models that have been previously used in land use change studies to the low mountainous Dill catchment, Germany. Substantial differences in model performance were observed with Nash-Sutcliffe efficiencies ranging from 0.53 to 0.92. Differences in model performance were attributed to (1) model input data, (2) model calibration and (3) the physical basis of the models. The models were applied with two sets of input data: an original and a homogenized data set. This homogenization of precipitation, temperature and leaf area index was performed to reduce the variation between the models. Homogenization improved the comparability of model simulations and resulted in a reduced average bias, although some variation in model data input remained. The effect of the physical differences between models on the long-term water balance was mainly attributed to differences in how models represent evapotranspiration. Semi-lumped and lumped conceptual models slightly outperformed the fully distributed and physically based models. This was attributed to the automatic model calibration typically used for this type of models. Overall, however, we conclude that there was no superior model if several measures of model performance are considered and that all models are suitable to participate in further multi-model ensemble set-ups and land use change scenario investigations. ?? 2008 Elsevier Ltd. All rights reserved.

Advances in Water Resources↗

USGS1984

Hydrology of Area 62, Northern Great Plains and Rocky Mountain Coal Provinces, New Mexico and Arizona

This report summarizes available hydrologic data for Area 62 and will aid leasing decisions, and the preparation and appraisal of environmental impact studies and mine-permit applications. Area 62 is located at the southern end of the Rocky Mountain Coal Province in parts of New Mexico and Arizona and includes approximately 9,500 square miles. Surface mining alters, at least temporarily, the environment; if the areas are unreclaimed, there can be long-term environmental consequences. The land-ownership pattern in Area 62 is complicated. The checkerboard pattern created by several types of ownership makes effective management of these lands difficult. The climate generally is semiarid with average annual precipitation ranging from 10 to 20 inches. Pinons, junipers, and grasslands cover most of the area, and much of it is used for grazing by livestock. Soils vary with landscape, differing from flood plains and hillslopes to mountain slopes. The major structural features of this area were largely developed during middle Tertiary time. The main structural features are the southern San Juan Basin and the Mogollon slope. Coal-bearing rocks are present in four Cretaceous rock units of the Mesaverde Group: the Gallup Sandstone, the Dileo Coal Member, and the Gibson Coal Member of the Crevasse Canyon Formation, and the Cleary Coal Member of the Menefee Formation. Area 62 is drained by Black Creek, the Puerco River, the Zuni River, Carrizo Wash-Largo Creek, and the Rio San Jose. Only at the headwaters of the Zuni River is the flow perennial. The streamflow-gaging station network consists of 25 stations operated for a variety of needs. Streamflow changes throughout the year with variation related directly to rainfall and snowmelt. Base flow in Area 62 is zero indicating no significant ground-water discharge. Mountainous areas contribute the highest mean annual runoff of 1.0 inch. Very few water-quality data are available for the surface-water stations. Of the nine surface-water stations that have water-quality data, only one has chemical analyses from more than 10 samples. Therefore, sufficient data to characterize the area in detail are not available. Suspended sediment data are available only for a few surface- water stations in the area. Erosion rates generally are less than 1 acre-foot per square mile per year. Greater erosion rates are found within the badland areas. Water levels are periodically measured at 21 selected wells in Area 62. These observation wells are located mostly along the Rio San Jose and northeast of Gallup, New Mexico. The recharge to ground-water aquifers generally coincide with areas of greater precipitation in the mountainous areas. Depth to water below land surface is generally less than 200 feet. Well yields of 100 gallons per minute are common in most of the area. Ground-water quality is variable both within each aquifer and between aquifers. Water quality generally is best near recharge areas. Historical and current data related to stream discharge, water quality, and suspended sediment are available from computer files in the U.S. Geological Survey's National Water Data Storage and Retrieval System (WATSTORE) and through the National Water Data Exchange (NAWDEX).

Water-Resources Investigations Report↗

USGS2000

Water-quality characteristics for selected streams in Lawrence County, South Dakota, 1988-92

During the 1980’s, significant economic development and population growth began to occur in Lawrence County in the northern part of the Black Hills of western South Dakota. Rising gold prices and heap-leach extraction methods allowed the economic recovery of marginal gold ore deposits, resulting in development of several large-scale, open-pit gold mines in Lawrence County. There was increasing local concern regarding potential impacts on the hydrologic system, especially relating to the quantity and quality of water in the numerous streams and springs of Lawrence County. In order to characterize the water quality of selected streams within Lawrence County, samples were collected from 1988 through 1992 at different times of the year and under variable hydrologic conditions. During the time of this study, the Black Hills area was experiencing a drought; thus, most samples were collected during low-flow conditions. Streamflow and water-quality characteristics in Lawrence County are affected by both geologic conditions and precipitation patterns. Most streams that cross outcrops of the Madison Limestone and Minnelusa Formation lose all or large part of their streamflow to aquifer recharge. Streams that are predominantly spring fed have relatively stable streamflow, varying slightly with dry and wet precipitation cycles. Most streams in Lawrence County generally have calcium magnesium bicarbonate type waters. The sites from the mineralized area of central Lawrence County vary slightly from other streams in Lawrence County by having higher concentrations of sodium, less bicarbonate, and more sulfate. False Bottom Creek near Central City has more sulfate than bicarbonate. Nitrogen, phosphorous, and cyanide concentrations were at or near the laboratory reporting limits for most sites and did not exceed any of the water-quality standards. Nitrite plus nitrate concentrations at Annie Creek near Lead, Whitetail Creek at Lead, Squaw Creek near Spearfish, and Spearfish Creek below Robison Gulch were somewhat higher than at other sites. Mining activity, agricultural activity, and domestic development are possible sources of nitrogen to the streams. Increased mining activities were identified as the probable cause of increased nitrogen concentrations in Annie Creek. In the mineralized area of the northern Black Hills, detectable concentrations of trace elements are common in stream water, occasionally exceeding beneficial-use and aquatic-life criteria. In addition, many basins have been disturbed by both historical and recent mining operations and cleanup activities. The maximum dissolved arsenic concentration at Annie Creek near Lead (48 micrograms per liter) approached the current arsenic drinking-water standard. Concentrations at or greater than 5 micrograms per liter were found in samples from Annie Creek near Lead, Spearfish Creek above Spearfish, Whitetail Creek at Lead, and False Bottom Creek near Spearfish. Bear Butte Creek near Deadwood had one sample with a dissolved copper concentration that exceeded acute and chronic aquatic-life criteria. Bear Butte Creek near Deadwood had several manganese concentrations that exceeded the secondary maximum contaminant level of 50 micrograms per liter. Bed-sediment and water-quality data from selected sites in small drainage basins were used to determine if factors such as pH, arsenic concentrations in bed sediments, and calcite saturation control dissolved arsenic concentrations. Arsenic solubility is controlled by adsorption, mainly on ferrihydrite. In addition, adsorption/desorption of arsenic is controlled by the pH of the stream, with high arsenic concentrations appearing only at higher pH conditions (above 8). There are significant arsenic sources available to almost all the small streams of the northern Black Hills mining area, but arsenic is less mobile in streams that are not influenced to the higher pH values by calcite. Streams where arsenic is more mobile have lower iron concentrations in their bed sediments, and they have relatively high concentrations of calcite Additional water-quality data have been collected as part of other studies or monitoring programs by the South Dakota Department of Environment and Natural Resources, U.S. Environmental Protection Agency, U.S. Forest Service, and the U.S. Geological Survey. Summaries of selected data from these other sources are included as additional information.

South Dakota↗

USGS1995

Water-quality assessment of the Rio Grande Valley study unit, Colorado, New Mexico, and Texas -- Analysis of selected nutrient, suspended-sediment, and pesticide data

This report contains a summary of data compiled from sources throughout the Rio Grande Valley study unit of the National Water-Quality Assessment program. Information presented includes the sources and types of water-quality data available, the utility of water-quality data for statistical analysis, and a description of recent water-quality conditions and trends and their relation to natural and human factors. Water-quality data are limited to concentrations of selected nutrient species in surface water and ground water, concentrations of suspended sediment and suspended solids in surface water, and pesticides in surface water, ground water, and biota. The Rio Grande Valley study unit includes about 45,900 square miles in Colorado, New Mexico, and Texas upstream from the streamflow-monitoring station Rio Grande at El Paso, Texas. The area also includes the San Luis Closed Basin and the surface-water closed basins east of the Continental Divide and north of the United States-Mexico international border. The Rio Grande drains about 29,300 square miles in these States; the remainder of the study unit area is in closed basins. Concentrations of all nutrients found in surface-water samples collected from the Rio Grande, with the exception of phosphorus, generally remained nearly constant from the northernmost station in the study unit to Rio Grande near Isleta, where concentrations were larger by an order of magnitude. Total nitrogen and total phosphorus loads increased downstream between Lobatos, Colorado, and Albuquerque, New Mexico. Nutrient concentrations remained elevated with slight variations until downstream from Elephant Butte Reservoir, where nutrient concentrations were lower. Nutrient concentrations then increased downstream from the reservoir, as evidenced by elevated concentrations at Rio Grande at El Paso, Texas. Suspended-sediment concentrations were similar at stations upstream from Otowi Bridge near San Ildefonso, New Mexico. The concentration and estimated load were nearly two orders of magnitude larger at this station relative to upstream stations. Cochiti Lake allows suspended sediment to settle, thus the resulting concentration is substantially lower downstream from the reservoir. Downstream from Cochiti Lake, concentrations again increased due to inflow from tributaries, other ephemeral streams and arroyos, and agricultural and urban areas. Two ephemeral tributaries (Rio Puerco and Rio Salado, which are south of Albuquerque) contribute substantial amounts of suspended sediment to the Rio Grande. Suspended-sediment concentrations in the Rio Grande just downstream from Elephant Butte Dam decreased by nearly three orders of magnitude due to settling in the reservoir. Concentrations then increased due to agricultural and urban impacts downstream from the reservoir. Nutrients in ground water in the study unit do not appear to be a widespread problem. However, localized areas that have elevated nitrate concentrations have been documented. The largest median nitrate concentration was found in water from wells located in the Basin and Range-mountains-urban data stratum (3.0 milligrams per liter) and the smallest median nitrate concentration was found in water from wells located in the Southern Rocky Mountainsmountains-forest data stratum (0.08 milligram per liter). Few (3 percent) nitrate concentrations in water from wells in all data strata were greater than 10 milligrams per liter, and most (82 percent) were less than 2 milligrams per liter. Comparison of nitrate concentrations in water from wells located in specific land-use settings across all hydrogeologic settings, with the exception of the Colorado Plateau, indicated that the largest median nitrate concentration was associated with rangeland land use and that larger nitrate concentrations were found in water from shallow wells. Water from wells located in areas of rangeland land use consistently had larger median nutrient concentrations than water from wells in areas of other land uses. The largest median ammonia concentration was in water from wells located in the Colorado Plateau-San Juan Basin-rangeland data stratum (0.27 milligram per liter). Most median ammonia concentrations were less than 0.03 milligram per liter, indicating that elevated ammonia concentrations are not a major issue in the study unit. The largest median orthophosphate concentration was found in water from wells located in the Southern Rocky Mountains-mountains-forest data stratum (0.15 milligram per liter) and the smallest was found in water from wells located in the Basin and Range-mountains-urban data stratum (0.02 milligram per liter). Most orthophosphate concentrations (85 percent) sampled were less than 0.2 milligram per liter, indicating that elevated orthophosphate concentrations are not a major issue in the study unit. Pesticide analyses were available for only 38 ground-water sampling sites in the Rio Grande Valley study unit. Diazinon, at a concentration of 0.01 microgram per liter, was the only pesticide detected and it was detected at only one site. More study is needed to determine if pesticides are affecting ground-water quality in the Rio Grande Valley study unit. Surface-water biological pesticide data were inadequate for in-depth analysis. The primary sources of data were the U.S. Fish and Wildlife Service and the U.S. Geological Survey. In the U.S. Fish and Wildlife Service study p,p'-DDE, a degradation product of DDT, was detected most frequently; highest concentrations were found at Stahman Farms in carp (6.3 micrograms per gram wet-weight) and at Hatch in Western kingbird (5.1 micrograms per gram wet-weight). In the U.S. Geological Survey study of Bosque del Apache National Wildlife Refuge no detectable organochlorine concentrations were found in plants, but detectable levels of p,p'-DDE were found in coot and carp, with a maximum concentration of 0.12 microgram per gram wet-weight found in coot.

Colorado, New Mexico, Texas↗

USGS1997

Summary of information on aquatic biota and their habitats in the Willamette Basin, Oregon, through 1995

Available information on aquatic biota of the Willamette Basin was reviewed and summarized to describe current and historical conditions as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Biological parameters emphasized include the status, distribution, and trends of aquatic biota, particularly algae, macroinvertebrates, and fish; the condition of aquatic and riparian habitat in which these biota reside; and the response of these biota to natural and human-associated impacts, including the level, type, and effect of contaminants. Considerable data are available on aquatic biota in the Willamette Basin, although the information is highly uneven relative to taxa and spatial scope. Extensive information exists for high-profile taxa, such as salmonid fishes, but less information is available for macroinvertebrates, and relatively little data exist for algae. Additionally, some areas such as the H.J. Andrews Experimental Forest and the main stem Willamette River have been extensively studied, whereas data are limited for many other areas. The basin supports a diverse aquatic macroinvertebrate fauna. Available data indicate a relatively high diversity of taxa and a high richness of Ephemeroptera, Plecoptera, Trichoptera (EPT) taxa in the upper reaches of the basin. In the lower main stem reaches, macroinvertebrate assemblages are dominated by pollution tolerant organisms and those adapted to low dissolved oxygen levels. Most of the limited data on algae are from sampling in the main stem Willamette River. Diatoms and blue-green algae are the dominant algal forms. Approximately 61 fish species occur in the basin, although nearly half are introduced. Species richness and distribution are highly correlated with elevation, stream gradient, and water temperature. High elevation, cold water, mountain streams are characterized by a few species of salmonids, sculpins, suckers, and whitefish. Low elevation, main stem reaches of major rivers and streams are dominated by warm water species, such as bass, catfish, and several species in the pan fish group. The only species of fish listed as threatened or endangered is the Oregon chub (Oregonichthys crameri). The effect of an expanding human presence in the Willamette Basin has substantially altered aquatic and riparian habitats, and the biota that use or reside in these habitats. Construction of dams, channelization and bank stabilization of rivers, species introductions, supplementations of fisheries through aquaculture, timber harvesting, agricultural activities, and urbanization have contributed to changes in aquatic habitats and biota from historical conditions. Aquatic toxicological investigations in the basin have focused primarily on fish. These studies have addressed chlorinated pesticides, polychlorinated biphenyls (PCBs), dioxins and furans, polycyclic aromatic hydrocarbons (PAHs), and trace elements in aquatic tissue, as well as fish health assessments, skeletal abnormalities, and aquatic toxicological responses. Several pesticides exceeded U.S. Environmental Protection Agency and State water-quality criteria for the protection of aquatic life. Elevated PCB, dioxin, and furan concentrations were associated with point sources, such as pulp and paper mills. Elevated concentrations of mercury in aquatic tissue were associated with several reservoirs. Fish health assessments and skeletal abnormality studies detected high levels of abnormalities in fish from the main stem Willamette River. Few investigations have examined aquatic toxicological responses, such as enzyme induction assays, growth assays, and biomarker studies.

Oregon↗

USGS2009

Assessing the impact of land use change on hydrology by ensemble modelling (LUCHEM) II: Ensemble combinations and predictions

This paper reports on a project to compare predictions from a range of catchment models applied to a mesoscale river basin in central Germany and to assess various ensemble predictions of catchment streamflow. The models encompass a large range in inherent complexity and input requirements. In approximate order of decreasing complexity, they are DHSVM, MIKE-SHE, TOPLATS, WASIM-ETH, SWAT, PRMS, SLURP, HBV, LASCAM and IHACRES. The models are calibrated twice using different sets of input data. The two predictions from each model are then combined by simple averaging to produce a single-model ensemble. The 10 resulting single-model ensembles are combined in various ways to produce multi-model ensemble predictions. Both the single-model ensembles and the multi-model ensembles are shown to give predictions that are generally superior to those of their respective constituent models, both during a 7-year calibration period and a 9-year validation period. This occurs despite a considerable disparity in performance of the individual models. Even the weakest of models is shown to contribute useful information to the ensembles they are part of. The best model combination methods are a trimmed mean (constructed using the central four or six predictions each day) and a weighted mean ensemble (with weights calculated from calibration performance) that places relatively large weights on the better performing models. Conditional ensembles, in which separate model weights are used in different system states (e.g. summer and winter, high and low flows) generally yield little improvement over the weighted mean ensemble. However a conditional ensemble that discriminates between rising and receding flows shows moderate improvement. An analysis of ensemble predictions shows that the best ensembles are not necessarily those containing the best individual models. Conversely, it appears that some models that predict well individually do not necessarily combine well with other models in multi-model ensembles. The reasons behind these observations may relate to the effects of the weighting schemes, non-stationarity of the climate series and possible cross-correlations between models. Crown Copyright ?? 2008.

Advances in Water Resources↗

USGS2010

Short-Term Effects of the 2008 High-Flow Experiment on Macroinvertebrates in Colorado River Below Glen Canyon Dam, Arizona

Glen Canyon Dam has dramatically altered the physical environment (especially discharge regime, water temperatures, and sediment inputs) of the Colorado River. High-flow experiments (HFE) that mimic one aspect of the natural hydrograph (floods) were implemented in 1996, 2004, and 2008. The primary goal of these experiments was to increase the size and total area of sandbar habitats that provide both camping sites for recreational users and create backwaters (areas of stagnant flow in the lee of return-current eddies) that may be important as rearing habitat for native fish. Experimental flows might also positively or negatively alter the rainbow trout (Oncorhynchus mykiss) sport fishery in the clear tailwater reach below Glen Canyon Dam, Ariz., and native fish populations in downstream reaches (for example, endangered humpback chub, Gila cypha) through changes in available food resources. We examined the short-term response of benthic macroinvertebrates to the March 2008 HFE at three sites [river mile 0 (RM 0, 15.7 miles downriver from the dam), RM 62, and RM 225] along the Colorado River downstream from Glen Canyon Dam by sampling immediately before and then 1, 7, 14, and 30 days after the HFE. We selected these sites because of their importance to management; RM 0 has a valuable trout fishery, and RM 62 is the location of the largest population of the endangered humpback chub in the Grand Canyon. In addition to the short-term collection of samples, as part of parallel investigations, we collected 3 years of monthly (quarterly for RM 62) benthic macroinvertebrate samples that included 15 months of post-HFE data for all three sites, but processing of the samples is only complete for one site (RM 0). At RM 0, the HFE caused an immediate 1.75 g AFDM/m2 (expressed as grams ash-free dry mass, or AFDM) reduction of macroinvertebrate biomass that was driven by significant reductions in the biomass of the two dominant taxa in this reach-Potamopyrgus antipodarum (New Zealand mud snails) and Gammarus lacustris (scuds or side-swimmers)-and also biomass reductions of other common taxa (worms in the families Lumbricidae and Tubificidae). Invertebrate drift estimates during the HFE suggest that reductions in biomass of some taxa were because of export from the reach. Reductions in biomass of P. antipodarum and G. lacustris persisted at least 15 months after the HFE, when this study concluded, and coincided with a significant decline in the annual production of these taxa: P. antipodarum production of 11 to 13 g AFDM/m2/yr in two pre-HFE years versus 2 g AFDM/m2/yr in the post-HFE year, and G. lacustris production of 7 to 8 g AFDM/m2/yr in two pre-HFE years versus 3 g AFDM/m2/yr in the post-HFE year. There were not changes in invertebrate feeding habits in response to the HFE, as our 3-year dataset of invertebrate diets indicated no substantial changes. Our long-term analysis of the composition of the drift indicates that because of a reduction in P. antipodarum in the drift relative to digestible taxa, the quality of the drift as a food resource for fishes increased. At downstream sites, total assemblage biomass did not decline, likely because assemblages were dominated by blackflies (Simulium arcticum), which were not affected by the HFE. Similar to RM 0, G. lacustris and Tubificidae had significantly lower biomass after the HFE at RM 62 and RM 225. Chironomids were also significantly lower following the flood at both downstream sites. Our findings demonstrate that the effects of a HFE on invertebrates may persist up to at least 15 months in the clear tailwater below the dam, whereas in downstream reaches impacts were more short lived. If controlling the abundance of P. antipodarum is a goal of managers, our findings indicate that periodic HFEs on the order of every 2 to 3 years may be an effective strategy for meeting that goal. More frequent HFEs may cause a shift in the state of the benthic invertebrate assemblage of the tailwa

Open-File Report↗

USGS2014

Users' guide to system dynamics model describing Coho salmon survival in Olema Creek, Point Reyes National Seashore, Marin County, California

The system dynamics model described in this report is the result of a collaboration between U.S. Geological Survey (USGS) scientists and National Park Service (NPS) San Francisco Bay Area Network (SFAN) staff, whose goal was to develop a methodology to integrate inventory and monitoring data to better understand ecosystem dynamics and trends using salmon in Olema Creek, Marin County, California, as an example case. The SFAN began monitoring multiple life stages of coho salmon (Oncorhynchus kisutch) in Olema Creek during 2003 (Carlisle and others, 2013), building on previous monitoring of spawning fish and redds. They initiated water-quality and habitat monitoring, and had access to flow and weather data from other sources. This system dynamics model of the freshwater portion of the coho salmon life cycle in Olema Creek integrated 8 years of existing monitoring data, literature values, and expert opinion to investigate potential factors limiting survival and production, identify data gaps, and improve monitoring and restoration prescriptions. A system dynamics model is particularly effective when (1) data are insufficient in time series length and/or measured parameters for a statistical or mechanistic model, and (2) the model must be easily accessible by users who are not modelers. These characteristics helped us meet the following overarching goals for this model: Summarize and synthesize NPS monitoring data with data and information from other sources to describe factors and processes affecting freshwater survival of coho salmon in Olema Creek. Provide a model that can be easily manipulated to experiment with alternative values of model parameters and novel scenarios of environmental drivers. Although the model describes the ecological dynamics of Olema Creek, these dynamics are structurally similar to numerous other coastal streams along the California coast that also contain anadromous fish populations. The model developed for Olema can be used, at least as a starting point, for other watersheds. This report describes each of the model elements with sufficient detail to guide the primary target audience, the NPS resource specialist, to run the model, interpret the results, change the input data to explore hypotheses, and ultimately modify and improve the model. Running the model and interpreting the results does not require modeling expertise on the part of the user. Additional companion publications will highlight other aspects of the model, such as its development, the rationale behind the methodological approach, scenario testing, and discussions of its use. System dynamics models consist of three basic elements: stocks , flows , and converters . Stocks are measurable quantities that can change over time, such as animal populations. Flows are any processes or conditions that change the quantity in a stock over time (Ford, 1999), are expressed in the model as a rate of change, and are diagrammed as arrows to or from stocks. Converters are processes or conditions that change the rate of flows. A converter is connected to a flow with an arrow indicating that it alters the rate of change. Anything that influences the rate of change (such as different environmental conditions, other external factors, or feedbacks from other stocks or flows) is modeled as a converter. For example, the number of fish in a population is appropriately modeled as a stock. Mortality is modeled as a flow because it is a rate of change over time used to determine the number of fish in the population. The density-dependent effect on mortality is modeled as a converter because it influences the rate of morality. Together, the flow and converter change the number, or stock, of juvenile coho. The instructions embedded in the stocks, flows, converters, and the sequence in which they are linked are processed by the simulation software with each completed sequence composing a model run. At each modeled time step within the model run, the stock counts will go up, down, or stay the same based on the modeled flows and the influence of converters on those flows. The model includes a user-friendly interface to change model parameters, which allows park staff and others to conduct sensitivity analyses, incorporate future knowledge, and implement scenarios for various future conditions. The model structure incorporates place holders for relationships that we hypothesize are significant but data are currently lacking. Future climate scenarios project stream temperatures higher than any that have ever been recorded at Olema Creek. Exploring climate change impacts on coho survival is a high priority for park staff, therefore the model provides the user with the option to experiment with hypothesized effects and to incorporate effects based on future observations.

California↗

USGS2002

Relations of benthic macroinvertebrates to concentrations of trace elements in water, streambed sediments, and transplanted bryophytes and stream habitat conditions in nonmining and mining areas of the upper Colorado River basin, Colorado, 1995-98

Intensive mining activity and highly mineralized rock formations have had significant impacts on surface-water and streambed-sediment quality and aquatic life within the upper reaches of the Uncompahgre River in western Colorado. A synoptic study by the U.S. Geological Survey National Water-Quality Assessment Program was completed in the upper Uncompahgre River Basin in 1998 to better understand the relations of trace elements (with emphasis on aluminum, arsenic, copper, iron, lead, and zinc concentrations) in water, streambed sediment, and aquatic life. Water-chemistry, streambed-sediment, and benthic macroinvertebrate samples were collected during low-flow conditions between October 1995 and July 1998 at five sites on the upper Uncompahgre River, all downstream from historical mining, and at three sites in drainage basins of the Upper Colorado River where mining has not occurred. Aquatic bryophytes were transplanted to all sites for 15 days of exposure to the water column during which time field parameters were measured and chemical water-quality and benthic macroinvertebrate samples were collected. Stream habitat characteristics also were documented at each site. Certain attributes of surface-water chemistry among streams were significantly different. Concentrations of total aluminum, copper, iron, lead, and zinc in the water column and concentrations of dissolved aluminum, copper, and zinc were significantly different between nonmining and mining sites. Some sites associated with mining exceeded Colorado acute aquatic-life standards for aluminum, copper, and zinc and exceeded Colorado chronic aquatic-life standards for aluminum, copper, iron, lead, and zinc. Concentrations of copper, lead, and zinc in streambed sediments were significantly different between nonmining and mining sites. Generally, concentrations of arsenic, copper, lead, and zinc in streambed sediments at mining sites exceeded the Canadian Sediment Quality Guidelines probable effect level (PEL), except at two mining sites where concentrations of copper and zinc were below the PEL. Concentrations of arsenic, copper, iron, and lead in transplanted bryophytes were significantly different between nonmining and mining sites. Bioconcentration factors calculated for 15-day exposure using one-half of the minimum reporting level were significantly different between nonmining and mining sites. In general, concentrations of trace elements in streambed sediment and transplanted bryophytes were more closely correlated than were the concentrations of trace elements in the water column with streambed sediments or concentrations in the water column with transplanted bryophytes. Stream habitat was rated as optimal to suboptimal using the U.S. Environmental Protection Agency Rapid Bioassessment Protocols for all sites in the study area. Generally, stream habitat conditions were similar at nonmining compared to mining sites and were suitable for diverse macroinvertebrate communities. All study sites had optimal instream habitat except two mining sites with suboptimal instream habitat because of disturbances in stream habitat. The benthic macroinvertebrate community composition at nonmining sites and mining sites differed. Mining sites had significantly lower total abundance of macroinvertebrates, fewer numbers of taxa, and lower dominance of Ephemeroptera (mayflies), Plecoptera (stoneflies), and Trichoptera (caddisflies), and a larger percentage of tolerant species than did nonmining sites. The predominance of Baetis sp. (mayflies), Hydropsychidae (caddisflies), and large percentage of Orthocladiinae chironomids (midges) at mining sites indicated that these species may be tolerant to elevated trace-element concentrations. The absence of Heptageniidae (mayflies), Chloroperlidae (stoneflies), and Rhyacophila sp. (caddisflies) at mining sites indicated that these species may be sensitive to elevated trace-element concentrations. Comparison of field parameters and

Water-Resources Investigations Report↗

USGS2001

The search for reliable aqueous solubility (Sw) and octanol-water partition coefficient (Kow) data for hydrophobic organic compounds; DDT and DDE as a case study

The accurate determination of an organic contaminant’s physico-chemical properties is essential for predicting its environmental impact and fate. Approximately 700 publications (1944–2001) were reviewed and all known aqueous solubilities (S w ) and octanol-water partition coefficients (K ow ) for the organochlorine pesticide, DDT, and its persistent metabolite, DDE were compiled and examined. Two problems are evident with the available database: 1) egregious errors in reporting data and references, and 2) poor data quality and/or inadequate documentation of procedures. The published literature (particularly the collative literature such as compilation articles and handbooks) is characterized by a preponderance of unnecessary data duplication. Numerous data and citation errors are also present in the literature. The percentage of original S w and K ow data in compilations has decreased with time, and in the most recent publications (1994–97) it composes only 6–26 percent of the reported data. The variability of original DDT/DDE S w and K ow data spans 2–4 orders of magnitude, and there is little indication that the uncertainty in these properties has declined over the last 5 decades. A criteria-based evaluation of DDT/DDE S w and K ow data sources shows that 95–100 percent of the database literature is of poor or unevaluatable quality. The accuracy and reliability of the vast majority of the data are unknown due to inadequate documentation of the methods of determination used by the authors. [For example, estimates of precision have been reported for only 20 percent of experimental S w data and 10 percent of experimental K ow data.] Computational methods for estimating these parameters have been increasingly substituted for direct or indirect experimental determination despite the fact that the data used for model development and validation may be of unknown reliability. Because of the prevalence of errors, the lack of methodological documentation, and unsatisfactory data quality, the reliability of the DDT/ DDE S w and K ow database is questionable. The nature and extent of the errors documented in this study are probably indicative of a more general problem in the literature of hydrophobic organic compounds. Under these circumstances, estimation of critical environmental parameters on the basis of S w and K ow (for example, bioconcentration factors, equilibrium partition coefficients) is inadvisable because it will likely lead to incorrect environmental risk assessments. The current state of the database indicates that much greater efforts are needed to: 1) halt the proliferation of erroneous data and references, 2) initiate a coordinated program to develop improved methods of property determination, 3) establish and maintain consistent reporting requirements for physico-chemical property data, and 4) create a mechanism for archiving reliable data for widespread use in the scientific/regulatory community.

Water-Resources Investigations Report↗

USGS2001

Water-quality assessment of the eastern Iowa basins– Nitrogen, phosphorus, suspended sediment, and organic carbon in surface water, 1996–98

Twelve sites on streams and rivers in the Eastern Iowa Basins study unit were sampled monthly and during selected storm events from March 1996 through September 1998 to assess the occurrence, distribution, and transport of nitrogen, phosphorus, suspended sediment, and organic carbon as part of the U.S. Geological Survey’s National Water-Quality Assessment Program. One site was dropped from monthly sampling after 1996. Dissolved nitrogen and phosphorus were detected in every water sample collected. Nitrate accounted for 92 percent of the total dissolved nitrogen. About 22 percent of the samples had nitrate concentrations that exceeded the U.S. Environmental Protection Agency’s maximum contaminant level of 10 milligrams per liter as nitrogen for drinking-water regulations. The median concentration of total dissolved nitrogen for surface water in the study unit was 7.2 milligrams per liter. The median total phosphorus concentration for the study unit was 0.22 milligram per liter. About 75 percent of the total phosphorus concentrations exceeded the U.S. Environmental Protection Agency recommended total phosphorus concentration of 0.10 milligram per liter or less to minimize algal growth. Median suspended sediment and dissolved organic-carbon concentrations for the study unit were 82 and 3.5 milligrams per liter, respectively. Median concentrations of nitrogen, phosphorus, and suspended sediment varied annually and seasonally. Nitrogen, phosphorus, and suspended-sediment concentrations increased each year of the study due to increased precipitation and runoff. Median concentrations of dissolved organic carbon were constant from 1996 to 1998. Nitrogen concentrations were typically higher in the spring after fertilizer application and runoff. During winter, nitrogen concentrations typically increased when there was little in-stream processing by biota. Nitrogen and phosphorus concentrations decreased in late summer when there was less runoff and in-stream processing of nitrogen and phosphorus was high. Dissolved organic carbon was highest in February and March when decaying vegetation and manure were transported during snowmelt. Suspendedsediment concentrations were highest in early summer (May–June) during runoff and lowest in January when there was ice cover with very little overland flow contributing to rivers and streams. Based on historical and study-unit data, eastern Iowa streams and rivers are impacted by both nonpoint and point-source pollution. Indicator sites that have homogeneous land use, and geology had samples with significantly higher concentrations of total dissolved nitrogen (median, 8.2 milligrams per liter) than did samples from integrator sites (median, 6.2 milligrams per liter) that were more heterogeneous in land use and geology. Samples from integrator sites typically had significantly higher total phosphorus and suspended-sediment concentrations than did samples from indicator sites. Typically, there was very little difference in median dissolved organic-carbon concentrations in samples from indicator and integrator sites. Concentrations of nitrogen and phosphorus varied across the study unit due to land use and physiography. Basins that are located in areas with a higher percentage of row-crop agriculture typically had samples with higher nitrogen concentrations. Basins that drain the Southern Iowa Drift Plain and the Des Moines Lobe typically had samples with higher total phosphorus and suspended-sediment concentrations. Total nitrogen loads increased each year from 1996 through 1998 in conjunction with increased concentrations and runoff. Total phosphorus loads in the Skunk River Basin decreased in 1997 due to less runoff and decreased sediment transport, but increased in 1998 due to higher runoff and increased sediment transport. Total nitrogen and total phosphorus loads varied seasonally. The highest loads typically occurred in early spring and summer after fertilizer application and runoff. Loads were lowest in January and September when there was typically very little runoff to transport nitrogen and phosphorus in the soil to the rivers and streams. Total nitrogen loads contributed to the Mississippi River from the Eastern Iowa Basins during 1996, 1997, and 1998 were 97,600, 120,000, and 234,000 metric tons, respectively. Total phosphorus loads contributed to the Mississippi River from the Eastern Iowa Basins during 1996, 1997, and 1998 were 6,860, 4,550, and 8,830 metric tons, respectively. Suspendedsediment loads contributed to the Mississippi River from the Eastern Iowa Basins during 1996, 1997, and 1998 were 7,480,000, 4,450,000, and 8,690,000 metric tons, respectively. The highest total nitrogen and total phosphorus yields typically occurred in samples from indicator sites. Sampling sites located in drainage basins with higher row-crop percentage typically had higher nitrogen and phosphorus yields. Sites that were located in the Des Moines Lobe and the Southern Iowa Drift Plain typically had higher phosphorus yields, probably due to physiographic features (for example, erodible soils, steeper slopes). Synoptic samples collected during low and high base flow had nitrogen, phosphorus, and organic-carbon concentrations that varied spatially and seasonally. Comparisons of water-quality data from six basic-fixed sampling sites and 19 other synoptic sites suggest that the water-quality data from basic-fixed sampling sites were representative of the entire study unit during periods of low and high base flow when most streamflow originates from ground water.

Iowa, Minnesota↗