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Water quality in Reedy Fork and Buffalo Creek basins in the Greensboro area, North Carolina, 1986-87

Water and bottom-sediment samples were collected from April 1986 through September 1987 at 19 sites in Guilford County and the City of Greensboro, North Carolina. Sampling locations included 13 stream sites, two lakes that supply the City of Greensboro with drinking water, two City of Greensboro finished drinking-water filtration plants, and effluent from the two municipal wastewater plants prior to outfall into receiving streams. Water sampling consisted of six surveys during various stages of steady ground-water flow at all sites and high-flow-event sampling during two storms at six sites. Bottom-sediment samples were collected at three sites during two routine sampling surveys. A summary of nearly 22, 000 separate chemical or physical analyses of water samples or bottom sediment is presented and discussed as individual values, ranges of values, or median values with respect to the locations of sampling sites, streamflow conditions, or other information bearing on water-quality conditions under discussion. The results include discussions of general water-quality indicators; major ion, nutrient, and trace-element concentrations; acid and base/neutral extractable organic compounds; volatile organic compounds; and organochlorine and organophosphorus pesticides detected at each sampling site. Loadings of selected constituents are also estimated on a yearly and daily basis. The quality of the raw and finished water, municipal effluents, and streams in the Greensboro area are characterized by using State and Federal water-quality standards. Inorganic constituents most commonly found in excess of standards were iron, copper, zinc, arsenic, phosphorus, manganese, cyanide, and mercury. Relatively few organic compounds were detected; however, those consistently reported were phthalate, thihalomethane, organophosphorus pesticide, benzol, and phenolic compounds. Selected inorganic, physical, and total organic carbon data are used in a Wilcoxon test for two independent variables to statistically compare water-quality characteristics in selected rural, semideveloped and urban basins. During low-flow sampling, the constituents that differed significantly among all sites were calcium, magnesium, and chloride. During low flows, concentrations of orthophosphate, fluoride, sulfate, and TOC differed at the urban site from the rural and semideveloped and urban sites. There were no significant differences among sites in concentrations of sodium, suspended sediment, nickel, zinc, copper, and mercury during low flows. The Wilcoxon test performed on high-flow data indicated that concentrations of TOC, chloride, sulfate, suspended sediment, and nickel were not significantly different among the sites.

North Carolina↗

Environmental setting of benchmark streams in agricultural areas of eastern Wisconsin

This report describes the environmental setting of 20 benchmark streams in agricultural areas of eastern Wisconsin that are part of the Western Lake Michigan Drainages, National Water-Quality Assessment Program. Benchmark streams are defined as those that show minimal adverse effects from human activity, and they were selected on the basis of field reconnaissance and the following criteria: (1) available invertebrate or fisheries data that indicated good to excellent water quality, (2) instream habitat restoration for fisheries enhancement, and (3) land management to protect riparian vegetation. Information gathered from these benchmark sites can be used as a standard of reference to compare the health of other streams in agricultural areas on the basis of aquatic-biota communities, habitat, and water-quality characteristics. The information included in this report serves as background information that will be useful for a series of studies at these benchmark-stream sites in the Western Lake Michigan Drainages study unit as part of the National Water-Quality Assessment Program. Four relatively homogeneous units (RHU's) in agricultural areas that differed in bedrock and surficial geology were selected for study. RHU 1 (clayey surficial deposits over carbonate bedrock) and RHU 3 (sandy-till surficial deposits over carbonate bedrock) are in adjacent agricultural areas in the Southeastern Wisconsin Till Plains ecoregion. RHU 20 (sandy/sand and gravel surficial deposits over igneous and metamorphic bedrock) and RHU 26 (sandy/sand and gravel surficial deposits over sandstone bedrock) are in adjacent areas of agriculture and mixed forests in the North Central Hardwood Forests ecoregion. Differences in land use/land cover, and riparian vegetation and instream habitat characteristics are presented. Summaries of field measurements of water temperature, pH, specific conductance and concentrations of dissolved oxygen, total organic plus ammonia nitrogen, dissolved ammonium, nitrate plus nitrte as nitrogen, total phosphorus, dissolved orthophosphate, and atrazine are listed. Concentrations of dissolved oxygen for the sampled streams ranged from 6 A to 14.3 and met the standards set by the Wisconsin Department of Natural Resources (WDNR) for supporting fish and aquatic life. Specific conductance ranged from 98 to 753 u,Scm with values highest in RHU's 1 and 3, where streams are underlain by carbonate bedrock. Median pH did not vary greatly among the four RHU's and ranged from 6.7 to 8.8 also meeting the WDNR standards. Concentrations of total organic plus ammonia nitrogen, dissolved ammonium, total phosphorus, and dissolved orthophosphate show little variation between streams and are generally low, compared to concentrations measured in agriculturally-affected streams in the same RHU's during the same sampling period. Concentrations of the most commonly used pesticide in the study unit, atrazine, were low in all streams, and most concentrations were below trn 0.1 u,g/L detection limit. Riparian vegetation for the benchmark streams were characterized by lowland species of the native plant communities described by John T. Curtis in the "Vegetation of Wisconsin." Based on the environmental setting and water-quality information collected to date, these streams appear to show minimal adverse effects from human activity.

Wisconsin↗

Water-quality assessment of the New England coastal basins in Maine, Massachusetts, New Hampshire, and Rhode Island: Environmental settings and implications for water quality and aquatic biota

The New England Coastal Basins in Maine, Massachusetts, New Hampshire, and Rhode Island constitute one of 59 study units selected for water-quality assessment as part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program. England Coastal Basins study unit encompasses the fresh surface waters and ground waters in a 23,000 square-mile area that drains to the Atlantic Ocean. Major basins include those of the Kennebec, Androscoggin, Saco, Merrimack, Charles, Blackstone, Taunton, and Pawcatuck Rivers. Defining the environmental setting of the study unit is the first step in designing and conducting a multi-disciplinary regional water-quality assessment. The report describes the natural and human factors that affect water quality in the basins and includes descriptions of the physiography, climate, geology, soils, surface- and ground-water hydrology, land use, and the aquatic ecosystem. Although surface-water quality has greatly improved over the past 30 years as a result of improved wastewater treatment at municipal and industrial wastewater facilities, a number of water-quality problems remain. Industrial and municipal wastewater discharges, combined sewer overflows, hydrologic modifications from dams and water diversions, and runoff from urban land use are the major causes of water-quality degradation in 1998. The most frequently detected contaminants in ground water in the study area are volatile organic compounds, petroleum-related products, nitrates, and chloride and sodium. Sources of these contaminants include leaking storage tanks, accidental spills, landfills, road salting, and septic systems and lagoons. Elevated concentrations of mercury are found in fish tissue from streams and lakes throughout the study area.

Maine, Massachusetts, New Hampshire, Rhode Island↗

Ground-water conditions and effects of mine dewatering in Desert Valley, Humboldt and Pershing Counties, northwestern Nevada, 1962-91

Desert Valley is a 1,200-square-mile, north- trending, structural basin, about 30 miles northwest of Winnemucca, Nevada. Unconsolidated basin-fill deposits exceeding 7,000 feet in thickness constitute the primary ground-water reservoir. Dewatering operations at an open-pit mine began in the Spring of 1985 in the northeast part of Desert Valley. Ground-water withdrawal for mine dewatering in 1991 was greater than three times the estimated average annual recharge from precipitation. The mine discharge water has been allowed to flow to areas west of the mine where it has created an artificial wetlands. This report documents the 1991 hydrologic conditions in Desert Valley and the change in conditions since predevelopment (pre-1962). It also summarizes the results of analyzing the simulated effects of open-pit mine dewatering on a basin-wide scale over time. Water-level declines associated with the dewatering have propagated north and south of the mine, but have been attenuated to the west due to the infiltration beneath the artificial wetlands. Maximum water-level declines beneath the open pits at the mine, as of Spring 1991, are about 300 feet. Changes in the hydrologic conditions since predevelopment are observed predominantly near the dewatering operations and the associated discharge lakes. General ground-water chemistry is essentially unchanged since pre- development. On the basis of a ground-water flow model used to simulate mine dewatering, a new equilibrium may slowly be approached only after 100 years of recovery from the time mine dewatering ceases.

Water-Resources Investigations Report↗

Organochlorine compounds and trace elements in fish tissue and bed sediments in the lower Snake River basin, Idaho and Oregon

Fish-tissue and bed-sediment samples were collected to determine the occurrence and distribution of organochlorine compounds and trace elements in the lower Snake River Basin. Whole-body composite samples of suckers and carp from seven sites were analyzed for organochlorine compounds; liver samples were analyzed for trace elements. Fillets from selected sportfish were analyzed for organochlorine compounds and trace elements. Bed-sediment samples from three sites were analyzed for organochlorine compounds and trace elements. Twelve different organochlorine compounds were detected in 14 fish-tissue samples. All fish-tissue samples contained DDT or its metabolites. Concentrations of total DDT ranged from 11 micrograms per kilogram wet weight in fillets of yellow perch from C.J. Strike Reservoir to 3,633 micrograms per kilogram wet weight in a whole-body sample of carp from Brownlee Reservoir at Burnt River. Total DDT concentrations in whole-body samples of sucker and carp from the Snake River at C.J. Strike Reservoir, Snake River at Swan Falls, Snake River at Nyssa, and Brownlee Reservoir at Burnt River exceeded criteria established for the protection of fish-eating wildlife. Total PCB concentrations in a whole-body sample of carp from Brownlee Reservoir at Burnt River also exceeded fish-eating wildlife criteria. Concentrations of organochlorine compounds in whole-body samples, in general, were larger than concentrations in sportfish fillets. However, concentrations of dieldrin and total DDT in fillets of channel catfish from the Snake River at Nyssa and Brownlee Reservoir at Burnt River, and concentrations of total DDT in fillets of smallmouth bass and white crappie from Brownlee Reservoir at Burnt River exceeded a cancer risk screening value of 10 -6 established by the U.S. Environmental Protection Agency. Concentrations of organochlorine compounds in bed sediment were smaller than concentrations in fish tissue. Concentrations of p,p'DDE, the only compound detected in all three bed-sediment samples, ranged from 1.1 micrograms per kilogram dry weight in C.J. Strike Reservoir to 11 micrograms per kilogram dry weight in Brownlee Reservoir at Burnt River. Data from this study, compared with data collected in the upper Snake River Basin from 1992 to 1994, indicates that, in general, organochlorine concentrations in fish tissue and bed sediment increased from the headwaters of the Snake River in Wyoming downstream to Brownlee Reservoir. The largest trace-element concentrations in fish tissue were in liver samples from carp from Brownlee Reservoir at Burnt River and suckers from the Boise River near Twin Springs. Concentrations of most trace elements were larger in livers than in the sport- fish fillets. However, mercury concentrations were generally larger in the sportfish fillets; they ranged from 0.08 microgram per gram wet weight in yellow perch from C.J. Strike Reservoir to 0.32 microgram per gram wet weight in channel catfish from Brownlee Reservoir at Burnt River. None of the trace-element concentrations in fillets exceeded median international standards or U.S. Food and Drug Administration action levels. Large trace-element concentrations in the upper Snake River Basin were reported in liver samples from suckers from headwater streams, probably a result of historical mining and weathering of metal-rich rocks. Concentrations of most trace elements in the bed-sediment samples were largest in Brownlee Reservoir at Mountain Man Lodge. Concentrations of arsenic, cadmium, chromium, copper, nickel, and zinc in bed sediment from the Mountain Man Lodge site exceeded either the threshold effect level or probable effect level established by the Canadian Government for the protection of benthic life. Arsenic, chromium, copper, and nickel concentrations in bed sediment from Brownlee Reservoir at Burnt River and chromium, copper, and nickel in bed sediment from C.J. Strike Reservoir also exceeded the threshold effect level.

Idaho, Oregon↗

Development of health-based screening levels for use in state- or local-scale water-quality assessments

The U.S. Geological Survey (USGS) has a need to communicate the significance of the water-quality findings of its National Water-Quality Assessment (NAWQA) Program in a human-health context. Historically, the USGS has assessed water-quality conditions by comparing water concentration data against established drinking-water standards and guidelines. However, because drinking- water standards and guidelines do not exist for many of the contaminants analyzed by the NAWQA Program and other USGS studies, this approach has proven to be insufficient for placing USGS data in a human-health context. To help meet this need, health-based screening level (HBSL) concentrations or ranges are being determined for unregulated compounds (that is, those for which Federal or State drinking-water standards have not been established), using a consensus approach that was developed collaboratively by the USGS, U.S. Environmental Protection Agency(USEPA), New Jersey Department of Environmental Protection, and Oregon Health & Science University. USEPA Office of Water methodologies for calculating Lifetime Health Advisory and Risk-Specific Dose values for drinking water are being used to develop HBSL concentrations (for unregulated noncarcinogens) and HBSL concentration ranges (for most unregulated carcinogens). This report describes the methodologies used to develop HBSL concentrations and ranges for unregulated compounds in State- and local-scale analyses, and discusses how HBSL values can be used as tools in water-quality assessments. Comparisons of measured water concentrations with Maximum Contaminant Level values and HBSL values require that water-quality data be placed in the proper context, with regard to both hydrology and human health. The use of these HBSL concentrations and ranges by USGS will increase by 27 percent the number of NAWQA contaminants for which health-based benchmarks are available for comparison with USGS water-quality data. USGS can use HBSL values to assist the USEPA and State and local agencies by providing them with comparisons of measured water concentrations to scientifically defensible human health-based benchmarks, and by alerting them when measured concentrations approach or exceed these benchmarks.

Water-Resources Investigations Report↗

Review of Selected References and Data sets on Ambient Ground- and Surface-Water Quality in the Metedeconk River, Toms River, and Kettle Creek Basins, New Jersey, 1980-2001

Surface water and ground water from unconfined aquifers are the primary sources of drinking water for much of the population, about 391,000, in the Metedeconk River, Toms River, and Kettle Creek watersheds in the New Jersey Coastal Plain. The quality of these sources of drinking water is a concern because they are vulnerable to contamination. Indications of the occurrence, distribution, and likely sources and transport mechanisms of certain contaminants were obtained from 48 selected reports and 2 selected data sets on water quality in or near the watersheds (1980-2001). These indications are described and briefly summarized in this report. The findings of studies on ground-water quality indicate that shallow ground water within the study area generally meets primary drinking-water standards, with notable exceptions. Volatile organic compounds, mercury, arsenic, radionuclides, nitrate, and coliform bacteria have been detected in shallow ground water in some areas at levels that exceed Federal and State drinking-water standards. For example, results of analyses of untreated samples collected from more than 13,000 private wells during 1983-99 indicated that concentrations of volatile organic compounds in samples from 7.3 percent of the wells exceeded at least 1 of 11 drinking-water standards, according to records maintained by the Ocean County Health Department. In cases of exceedances, however, water treatment, well replacement, and (or) retesting assured that applicable drinking-water standards were being met at the tap. Reported concentrations of the pesticide chlordane in some areas exceeded the drinking-water standard; few data are available on the occurrence of other pesticides. Studies of nearby areas, however, indicate that pesticide concentrations generally could be expected to be below drinking-water standards. The combination of low pH and low dissolved solids in many areas results in shallow ground water that is highly corrosive and, if untreated, able to leach trace elements and release asbestos fibers from plumbing materials. Reported concentrations of nitrate, volatile organic compounds, trace elements, and pesticides in samples from the monitored mainstem and tributary streams within the study area generally are below maximum contaminant levels for drinking water or below detection limits. Results of studies in other areas indicate that pesticide concentrations in surface water could be considerably higher during high flows soon after the application of pesticides to crops than during low flows. Fecal coliform bacteria counts in streams vary considerably. Concentrations or counts of these classes of surface-water-quality constituents likely are functions of the intensity and type of upstream development. Results of limited monitoring for radionuclide concentrations reported by the Brick Township Municipal Utilities Authority of the Metedeconk River indicate that radionuclide concentrations or activities do not exceed maximum contaminant levels for drinking water. As a consequence of organic matter in surface water, the formati ultraviolet absorbance in samples from the Metedeconk River and the Toms River exceeded the alternative compliance criteria for source water (2.0 milligrams per liter for total organic carbon and 0.02 absorbance units-liters per milligram-centimeter for specific ultraviolet absorbance) with respect to treatment requirements for preventing elevated concentrations of disinfection by-products in treated water. Water-quality and treatment issues associated with use of ground and surface water for potable supply in the study area are related to human activities and naturally occurring factors. Additional monitoring and analysis of ground and surface water would be needed to determine conclusively the occurrence and distribution of some contaminants and the relative importance of various potential contaminant sources, transport and attenuation mechanisms, and transport pathways.

Water-Resources Investigations Report↗

Land application of domestic wastewater in Florida--statewide assessment of impact on ground-water quality

In Florida domestic waste water is being applied to the land for disposal and reuse. State and Federal regulations favor land-application methods over other advanced waste water treatment practices. Despite the increasing use of this alternative technology, little is known about localized effects on groundwater quality. This report documents the extent of land-application practices in Florida and summarizes case study information on some of the more adequately monitored site throughout the State. More than 2,500 sites in Florida are permitted by the Department of Environmental Regulation for applying domestic waste water to the land. The majority (more than 1,700 sites), classified as infiltration ponds, are concentrated in central and southern Florida. More than 560 sites classified as drainfields, and more than 250 sites classified as irrigation sites, are located primarily in central Florida. An estimated 150 million gallons per day of domestic waste water, after required secondary treatment, are applied to Florida soils. Despite the large numbers of sites and the considerable volume of waste water utilized, little is known about potential impact on groundwater quality. At the few sites where observation wells have been drilled and local groundwater quality monitored, no significant deterioration of water quality has been detected. (USGS)

Water-Resources Investigations Report↗

Area of influence and zone of contribution to superfund-site wells G and H, Woburn, Massachusetts

Groundwater contamination by chlorinated volatile organic compounds detected by the Massachusetts Department of Environmental Quality Engineering in 1979 forced the closing of public supply wells G and H in the City of Woburn, MA. The EPA has ranked the wells G and H site on the National Priorities List as a CERCLA (Superfund) site and currently is conducting a feasibility study to determine a remedial action cleanup plan for the site. A 30-day aquifer test was conducted to determine the hydraulic properties of the stratified drift aquifer in the vicinity of the wells, and to determine the area of influenced and zone of contribution to wells G and H under pumping conditions. The estimated transmissivity of the aquifer in the vicinity of well G was 29,700 sq ft/day, with a storage coefficient of 0.20. The average horizontal hydraulic conductivity in the vicinity of the well ranged from 125 to 350 ft/day. The estimated transmissivity of the aquifer at well H was 17,600 sq ft/day, with a storage coefficient of 0.16. The average horizontal hydraulic conductivity ranges from 130 to 215 ft/day. The area of influence after 30 days of pumping well G at 700 gal/min and well H at 400 gal/min was oblong in shape, and approximately 3000 ft long and 1700 ft wide, as measured at the midpoint between wells G and H. The area of influence of wells G and H described in this report is considered to be a ' snapshot ' representative of the hydrologic and pumping conditions of the 30-day aquifer test. Most of the water pumped by the wells is obtained directly from the part of the aquifer immediately surrounding both wells and from induced infiltration of surface water from the overlying river and wetland. The remaining part of the zone of contribution is that area of the Aberjona River drainage basin up-gradient and outside the area of influence of wells G and H. A small amount of the surface water in the river entering the northern end of the study area, which is derived from groundwater discharge and surface water runoff in the up-gradient drainage area, is induced from the river to the wells under pumping conditions. The size of the area south of wells G and H that contributes water to the wells is variable, dependent on pumping rates and hydrologic conditions. (Author 's abstract)

Water-Resources Investigations Report↗

Hydrology and water and sediment quality at James Campbell National Wildlife Refuge near Kahuku, Island of Oahu, Hawaii

The James Campbell National Wildlife Refuge occupies two lowland marsh and pond complexes on the northern coastal plain of Oahu: the mostly natural ponds and wetlands of the Punamano Unit and the constructed ponds of the Kii Unit. The U.S. Fish and Wildlife Service manages the Refuge primarily to protect and enhance habitat for four endangered species of Hawaiian waterbirds. Kii Unit is fed by artesian wells and rainfall, whereas Punamano Unit is fed naturally by rainfall, runoff, and ground-water seepage. Streams drain from the uplands into lowland ditches that pass through Kii Unit on their way to the ocean. A high-capacity pump transfers water from the inner ditch terminus at Kii to the ocean outlet channel. Stormwaters also exit the inner ditch system over flood-relief swales near the outlet pump and through a culvert with a one-way valve. A hydrologic investigation was done from November 1996 through February 1998 to identify and quantify principal inflows and outflows of water to and from the Refuge, identify hydraulic factors affecting flooding, document ground-water/surface-water interactions, determine the adequacy of the current freshwater supply, and determine water and sediment quality. These goals were accomplished by installing and operating a network of stream-gaging stations, meteorology stations, and shallow ground-water piezometers, by computing water budgets for the two Refuge units, and by sampling and analyzing water and pond-bottom sediments for major ions, trace metals, and organic compounds. Streamflow during the study was dominated by winter stormflows, followed by a gradual recession of flow into summer 1997, as water that had been stored in alluvial fans drained to lowland ditches. Outflow at the ditch terminus in 1997 was 125 million gallons greater than measured inflow to the coastal plain, mainly reflecting gains from ground water along the ditches between outlying gages and the ditch terminus. Of the measured 1997 outflow, 98 percent was through the Kii outlet pump, with the outlet culvert valve only opening for brief periods during storms. Large volumes of stormflow overflowed the flood-relief swales unmeasured. The largest storm of the study, in November 1996, was estimated to have a flood frequency of about 3 to 4 years. Streamflow exceeded culvert capacity and overtopped Kamehameha Highway at Kalaeokahipa Stream and Hospital ditch. Slight overbank flooding in Kii ditch resulted strictly from high discharge. Minor overbank flooding farther out on the coastal plain probably was caused mainly by the small hydraulic gradients available to convey stormflows along the lowland ditches. Stormwaters flooded Kii ponds and flowed back upstream along Punamano ditch into Punamano marsh, introducing suspended sediment and possibly other contaminants to the Refuge. Two smaller storms in January 1997 resulted in smaller flows and no overbank flooding. The Kii outlet pump ran continuously for 7 days during the November 1996 storm and for 1 to 2 days during the January 1997 storms. During all three storms, the outlet culvert valve opened and the inner ditches overtopped the flood-relief swales, allowing free outflow of water from the inner ditch. Backwater effects hindered drainage during the January 1997 storms at Hospital ditch at Kamehameha Highway, and at Punamano ditch at Nudist Camp Road (where the backflow into Punamano marsh in November 1996 constituted an extreme backwater effect). A probable marine backwater effect was imposed at the ocean outlet ditch during the November 1996 storm through a combination of high spring tides and wave setup from large surf. Whether this backwater effect propagated upstream in the ditches to affect inland sites could not be determined conclusively. A sand plug may have built up in the ocean outlet channel before the November 1996 storm, but if so, it probably washed out prior to, or early in the storm, and was not present at the time of peak stage at inland sites. A season-long buildup of the sand plug in late 1997 was inferred from rising water levels in the outlet ditch. Seawater flows up the outlet channel or over the sand berm and into the outer ditch system on most high tides, and particularly during spring high tides. Ponds and ditches of the Refuge and surrounding lowlands have mud- and clay-lined bottoms that form an effective confining unit and inhibit interaction with an underlying shallow limestone aquifer. At Kii Unit, pond levels are higher than adjacent ditch levels and underlying ground-water levels, establishing lateral and downward head gradients that could foster seepage losses from the ponds. Regional ground-water discharge from the Koolau aquifer to the coastal-plain sediments is mostly diffuse, but is concentrated where ridges of Koolau Basalt plunge beneath coastal-plain sediments near Punamano Unit and at the head of Hospital ditch. Kii ditch gains brackish ground water downstream of Kamehameha Highway. Wastewater disposal from the sewage treatment plant adjoining Kii Unit poses little or no threat to Refuge habitat. Disposal is at six injection wells located 0.45 mi away at Kahuku, and the wells inject into confined limestone aquifers that do not extend to Kii Unit. The natural freshwater supply to Punamano Unit is adequate for maintaining the wildlife habitat, judging from stable pond levels and low salinities there. A monthly water budget for Punamano showed an apparent annual deficit in measurable flows in 1997, requiring unmeasured ground-water gains equalling 51 inches of water. The freshwater supply to Kii Unit is inadequate according to Refuge managers, because there is not enough water to manipulate levels adequately in the ponds during most of the year, and particularly during the driest months. This is confirmed by monthly deficits in the water budget for the Kii ponds during summer months. However, the Kii budget showed an annual surplus in measurable flows for 1997 equalling 24 inches of water. Unmeasured losses are required to explain the apparent annual surplus, such as discharge to the ditches through pond water-control structures and downward and/or lateral ground-water seepage. The apparent surplus at Kii is strictly hydrologic and is not a surplus in a management sense; it cannot be stored or used to supply the Refuge, but instead reflects losses from the system that render this amount of water unavailable for use. The budget year, 1997, was drier than normal (24 percent below long-term mean rainfall) and so the measured potential evaporation for 1997 was probably higher than the long-term mean. Few metals or organic compounds of potential concern were detected in pond and ditch waters and in pond-bottom sediments. Detected pesticides were at trace levels or just above minimum reporting limits. Exceptions that exceeded quality guidelines for freshwater sediment were copper and zinc in sediment from Kii ponds C and D, and copper in sediment from Punamano north pond. Therefore, urban and agricultural runoff probably have contributed little in the way of harmful metals or organic compounds to the Refuge, although the potential for such contribution remains from periodic flooding of the ponds by ditch stormflows. Salinity was low throughout most Refuge waters, qualifying as fresh to slightly brackish and suitable for the environmental needs of Refuge fauna. Higher salinities have been observed in ditches during past periods of sugarcane cultivation and saltwater aquaculture, however. Resumption of saltwater aquaculture could raise ditch salinities if saltwater effluents are disposed directly into the ditches, as they were in the past.

Hawaii↗

Simulation of ground-water flow and potential contaminant transport at Area 6 Landfill, Naval Air Station Whidbey Island, Island County, Washington

A three-dimensional finite-difference steady-state ground-water flow model was developed to simulate hydraulic conditions at the Area 6 Landfill, Naval Air Station Whidbey Island, near Oak Harbor, Washington. Remediation efforts were started in 1995 in an attempt to contain trichloroethene and other contaminants in the ground water. The model was developed as a tool to test the effectiveness of the pump-and-treat remediation efforts as well as alternative remediation strategies. The model utilized stratigraphic data from approximately 76 Navy and 19 private wells to define the geometry of the shallow, intermediate, and deep aquifers and the intervening confining layers. Initial aquifer parameters and recharge estimates from aquifer tests and published remedial investigation reports were used in the model and then adjusted until simulated water levels closely matched observed water-level data collected prior to the onset of remediation in 1995. The calibrated model was then modified to depict the remedial pump-and-treat system, in which contaminated ground water is extracted, treated, and returned to the ground surface for infiltration. The water levels simulated by the modified model were compared with observed water levels for the 1998 calendar year, during which time the pump-and-treat system was in nearly continuous operation and the ground-water system had equilibrated to steady-state conditions. Although artificial boundaries were used in the model, the choice of model boundary conditions was simulation in the area of primary concern surrounding the western contaminant plume and extraction wells. Particle tracking results indicate that the model can effectively simulate the advective transport of contaminants from the source area to the pumping wells and thus be used to test alternative remedial pumping strategies.

Water-Resources Investigations Report↗

Geohydrology and susceptibility of major aquifers to surface contamination in Alabama; area 9

This report delineates and describes the geohydrology and susceptibility of the major aquifers to contamination in Area 9 - Barbour, Bullock, Macon, Pike, and Russell Counties. The major aquifers in the study area are the Tuscaloosa, Eutaw, and Providence-Ripley aquifers of Cretaceous age; and the Nanafalia-Clayton aquifer of Tertiary age. The five counties constitute the primary recharge area for the aquifers which are the source of public supplies in the study area. The total withdrawals of groundwater for all uses in 1986 were estimated to be about 14 million gallons per day. Areas of water level declines in the Tuscaloosa aquifer have developed near Eufaula and Union Springs. Water levels in the Eutaw aquifer have declined at Union Springs. All recharge areas for the major aquifers are susceptible to contamination from the surface. Shallow wells in the outcrop area are most susceptible.

Alabama↗

Techniques for estimating flood-peak discharges of rural, unregulated streams in Ohio

Regional equations for estimating 2-, 5-, 10-, 25-, 50-, 100-, and 500-year flood-peak discharges at ungaged sites on rural, unregulated streams in Ohio were developed by means of ordinary and generalized least-squares (GLS) regression techniques. One-variable, simple equations and three-variable, full-model equations were developed on the basis of selected basin characteristics and flood-frequency estimates determined for 305 streamflow-gaging stations in Ohio and adjacent states. The average standard errors of prediction ranged from about 39 to 49 percent for the simple equations, and from about 34 to 41 percent for the full-model equations. Flood-frequency estimates determined by means of log-Pearson Type III analyses are reported along with weighted flood-frequency estimates, computed as a function of the log-Pearson Type III estimates and the regression estimates. Values of explanatory variables used in the regression models were determined from digital spatial data sets by means of a geographic information system (GIS), with the exception of drainage area, which was determined by digitizing the area within basin boundaries manually delineated on topographic maps. Use of GIS-based explanatory variables represents a major departure in methodology from that described in previous reports on estimating flood-frequency characteristics of Ohio streams. Examples are presented illustrating application of the regression equations to ungaged sites on ungaged and gaged streams. A method is provided to adjust regression estimates for ungaged sites by use of weighted and regression estimates for a gaged site on the same stream. A region-of-influence method, which employs a computer program to estimate flood-frequency characteristics for ungaged sites based on data from gaged sites with similar characteristics, was also tested and compared to the GLS full-model equations. For all recurrence intervals, the GLS full-model equations had superior prediction accuracy relative to the simple equations and therefore are recommended for use.

Ohio↗

U.S. Geological Survey research in radioactive waste disposal - Fiscal years 1983, 1984, and 1985

The report summarizes progress on geologic and hydrologic research related to the disposal of radioactive wastes. The research is described according to whether it is related most directly to: (1) high-level and transuranic wastes, (2) low-level wastes, or (3) uranium mill tailings. Included is research applicable to the identification and geohydrologic characterization of waste-disposal sites, to investigations of specific sites where wastes have been stored, and to studies of regions or environments where waste-disposal sites might be located. A significant part of the activity is concerned with techniques and methods for characterizing disposal sites and studies of geologic and hydrologic processes related to the transport and (or) retention of waste radionuclides.

Water-Resources Investigations Report↗

Areal distribution and concentrations of contaminants of concern in surficial streambed and lakebed sediments, Lake Erie-Lake Saint Clair drainages, 1990–97

Concerns about elevated concentrations of contaminants such as polychlorinated biphenyls and mercury in aquatic bed sediments throughout the Great Lakes Basin have resulted in a need for better understanding of the scope and severity of the problem. Various organochlorine pesticides, polychlorinated biphenyls, trace metals, and polycyclic aromatic hydrocarbons are a concern because of their ability to persist and accumulate in aquatic sediments and their association with adverse aquatic biological effects. The areal distribution and concentrations in surficial bed sediments of 20 contaminants of concern with established bed-sediment-toxicity guidelines were examined in relation to their potential effects on freshwater aquatic biota. Contaminants at more than 800 sampling locations are characterized in this report. Surficial bed-sediment-quality data collected from 1990 to 1997 in the Lake Erie– Lake Saint Clair Drainages were evaluated to reflect recent conditions. In descending order, concentrations of total polycyclic aromatic hydrocarbons, phenanthrene, total polychlorinated biphenyls, chrysene, benz[ a ]anthracene, benzo[ a ]pyrene, cadmium, lead, zinc, arsenic, and mercury were the contaminants that most commonly exceeded levels associated with probable adverse effects on aquatic benthic organisms. The highest concentrations of most of these contaminants in aquatic bed sediments are confined to the 12 specific geographic Areas of Concern identified in the 1987 Revisions to the Great Lakes Water Quality Agreement of 1972. An exception is arsenic, which was detected at concentrations exceeding threshold effect levels at many locations outside Areas of Concern.

Indiana, Michigan, New York, Ohio, Pennsylvania↗

Geohydrology and susceptibility of major aquifers to surface contamination in Alabama; area 6

This report delineates and describes the geohyrology and susceptibility of the major aquifers to contamination in Area 6, Greene, Marengo, Pickens, Sumter, and Tuscaloosa Counties in west-central Alabama. The major aquifers in the study area are the Nanafalia, Eutaw, Gordo, and Coker aquifers of Tertiary and Cretaceous age. The recharge areas for one or more of these aquifers are in each of the five counties. East aquifer is a source of public water supply in one or more of the five counties. All recharge areas for the major aquifers are susceptible to contamination from the surface. However, large parts of the recharge areas are in rural settings that are used for timberlands, farms, and pastures, and are several miles from pumping centers; therefore, these areas are not highly susceptible to contamination. (USGS)

Water-Resources Investigations Report↗

Public water-supply systems and water use in Tennessee, 1988

This report summarizes the results of a study conducted by the U.S. Geological Survey, in cooperation with the Tennessee Department of Environment and Conservation (TDEC), Division of Water Supply in 1988. Data gathered during an inventory by the TDEC were collated to determine water use, supply sources, population served, and design and storage capacities of the systems. The inventory was limited to systems that were active on June 30, 1988. Results of a survey of the systems conducted by the Tennessee Department of Health and Environment during 1988 were a primary source of data for this report. Data from computer and manual files maintained by the Tennessee Department of Health and Environment and the U.S. Geological Survey also were used. The Division of Water Supply, TDEC, surveyed 541 public water-supply systems. These systems served 81 percent of the population of the State, or 3.95 million people. The gross per capita use statewide for public-supplied water was 179 gallons per day. Total water withdrawals for public supply increased about 39 percent from 510 million gallons per day (Mgal/d) in 1980, to 708 Mgalld in 1988. During the same period, the population increased about 7 percent. Surface-water withdrawals accounted for 63 percent (446 Mgal/d) of the total water withdrawn in the State. All of these withdrawals occurred in the Tennessee (56 percent or 249 Mgal/d) and the Ohio (44 percent or 197 Mgalld) hydrologic regions. Ground water supplied 262 Mgal/d or 37 percent of the total water withdrawn by public-supply systems statewide. Of that amount, 79 percent, or 208 Mgalld, was used in western Tennessee.

Tennessee↗

Comment on the International Atomic Energy Agency Report on the Advisory Group Meeting on Stable Isotope Reference Samples for Geochemical and Hydrological Investigation, Vienna, Austria, September 19-21, 1983

According to U.S. Geological Survey records, a report prepared by R. Gonfiantini summarizing the findings and recommendations of the 1983 Advisory Group Meeting on Stable Isotope Reference Samples for Geochemical and Hydrologic Investigations held in Vienna does not accurately represent the consultants ' consensus on three important points. The consultants (1) recommended no value for the C02-H20 oxygen isotope fractionation factor, not the cited value of 1.04115, (2) adopted a value of 1.0309 rather than 1.03086 to relate the PDB and SMOW scales, and (3) adopted a firm 180 value of -2.20% for NBS-19 on the PDB scale rather than agreeing that this would be a tentative value subject to modification when more measurements in selected laboratories are available. (USGS)

Water-Resources Investigations Report↗