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USGS1971

Application of borehole geophysics to water-resources investigations

This manual is intended to be a guide for hydrologists using borehole geophysics in ground-water studies. The emphasis is on the application and interpretation of geophysical well logs, and not on the operation of a logger. It describes in detail those logging techniques that have been utilized within the Water Resources Division of the U.S. Geological Survey, and those used in petroleum investigations that have potential application to hydrologic problems. Most of the logs described can be made by commercial logging service companies, and many can be made with small water-well loggers. The general principles of each technique and the rules of log interpretation are the same, regardless of differences in instrumentation. Geophysical well logs can be interpreted to determine the lithology, geometry, resistivity, formation factor, bulk density, porosity, permeability, moisture content, and specific yield of water-bearing rocks, and to define the source, movement, and chemical and physical characteristics of ground water. Numerous examples of logs are used to illustrate applications and interpretation in various ground-water environments. The interrelations between various types of logs are emphasized, and the following aspects are described for each of the important logging techniques: Principles and applications, instrumentation, calibration and standardization, radius of investigation, and extraneous effects.

Techniques of Water-Resources Investigations↗

USGS1963

Some relations between streamflow characteristics and the environment in the Delaware River region

Streamflow characteristics are determined by a large number of factors of the meteorological and terrestrial environments. Because of lack of quantitative data to describe some of the factors and complex interrelations among them, complete analysis of the relations between streamflow and the various environmental factors is impossible. However, certain simplifying assumptions and generalizations made possible a partial analysis for the Delaware River region. For relations involving average runoff or low-flow parameters, average annual precipitation was assumed to be the principal meteorological factor, and geology (a complex of many factors) was assumed to be the principal terrestrial influence, except for that of basin size which was largely eliminated by expression of discharge in terms of unit area. As a first approximation, physiographic units were used as a basis for classifying the geology. Relations between flow parameters and precipitation are fairly well defined for some physiographic units, but not for those in which the geology varies markedly or the areal variation in average precipitation is very small. These relations provide a basis for adjusting the flow parameters to reduce or eliminate the effects of areal variations in precipitation and increase their significance in studies of the effects of terrestrial characteristics. An investigation of the residual effect of basin size (the effect remaining when discharge is expressed in terms of unit area) on relations between flow parameters and average precipitation indicates that such effect is negligible, except for very large differences in area. Parameters that are derived from base-flow recession curves and are related to a common discharge per unit area have inherent advantages as indicators of effects of terrestrial characteristics of basins, because the.y are independent of areal variations in average annual precipitation. Winter base-flow parameters are also practically independent of the effects of evapotranspiration from ground water. However, in many parts of the region these advantages are reduced or nullified by the difficulties of defining base-flow recession curves, particularly winter curves, with sufficient accuracy. In the absence of suitable base-flow recession data and a suitable basis for adjusting parameters, the ratio of the discharge equaled or exceeded 90 percent of the time to the average discharge (Qtt/Qa), or a similar duration parameter, probably is the best indicator of the influence of terrestrial characteristics, although the ratio may vary somewhat with average precipitation. In a part of the region where geologic differences are large and areal variations in average precipitation are small, values of Qm/Qa for each major geologic unit were determined from streamflow records. From these values and the percentage of area represented by each unit, a ratio for each gaging station was computed. Comparison of these computed results with the observed results indicates that nearly all of the variation in the ratio is associated with variation in geology. The investigation indicates that the original assumptions are correct; average precipitation is the principal meteorological influence and geology is the principal terrestrial influence. Together these two factors account for a very large proportion of the variation in average runoff and low-flow characteristics.

Delaware, New Jersey, Pennsylvania↗

USGS2015

Are Piton de la Fournaise (La Réunion) and Kīlauea (Hawai‘i) really “Analog Volcanoes”?

The basaltic ocean island volcanoes of Kīlauea (Island of Hawai‘i) and Piton de la Fournaise (La Réunion Island) are remarkable natural laboratories for volcanology. Both are near the active ends of long hotspot chains and host frequent eruptive activity (both effusive and explosive). Investigations of the geophysical, geochemical, and geologic manifestations of volcanism at the two locales provide insights into a variety of processes, from the supply of magma to its eruption at the surface. The oft-stated claim that Kīlauea and Piton de la Fournaise are “analog volcanoes” appears well founded, at least in part. The two volcanoes share similar characteristics with regard to magma plumbing, occurrence of flank instability, structural and compositional evolution, and eruptive activity. Noteworthy differences include the size of the edifices (Kīlauea is about an order-of-magnitude larger in volume), their life spans (Piton de la Fournaise has been active for twice as long), and flank instability mechanisms. These differences are attributable to Hawai‘i's higher magma supply from and faster plate velocity relative to the hotspot compared to Piton de la Fournaise. Understanding these similarities and differences can be used to leverage studies of processes at one volcano by exploiting their occurrence or absence at the other.

Hawaii↗

USGS2026

Neutron scattering reveals fractionation of natural gas mixtures in unconventional petroleum reservoir pores: Perspectives on energy resource recovery and storage

In unconventional petroleum reservoirs hydrocarbon fluids are hosted by both mineral and organic matter pores. These pores can have diameters that range from microns to less than a single nanometer and, for unconventional reservoirs, there is evidence that small pores ( <20 nm diameter) may constitute a large proportion of the available space. Understanding subsurface volumes and how fluids behave in them can be helpful for predicting hydrocarbon production and storage in the subsurface. One area with knowledge gaps regarding hydrocarbon behavior in small pores is the possibility for mixtures to fractionate (i.e., unmix) based on pore size or pore type. Mixture fractionation as a function of pore size could impact recovery of hydrocarbons, drive compositional shifts during production, and limit fluid storage within candidate reservoirs. To investigate natural gas fractionation in small geologic pores, we applied total neutron scattering to probe methane-ethane mixtures at reservoir pressures (up to ≈30 MPa) and temperature (60°C) within a sample from the Upper Cretaceous Niobrara Formation. Neutron scattering data reveal only minor fractionation occurs between methane and ethane in 20-nm diameter sample mesopores. Increased fractionation is observed for sample micropores, with up to 72% (±1% at 1-sigma) methane found in 2 nm diameter pores following injection of a 50%-50% methane-ethane mixture. These data provide rarely available direct experimental observations of hydrocarbon mixture behavior under nanoconfinement in a sample from an important unconventional petroleum reservoir. Our results are discussed in the context of evaluating hydrocarbon resources in unconventional reservoir meso- and micropores, reconciling observed gas composition changes during production, and more broadly, understanding subsurface pore volumes within an energy storage framework.

Fuel↗

USGS2005

Direct measurement of methane hydrate composition along the hydrate equilibrium boundary

The composition of methane hydrate, namely n w for CH 4 · n w H 2 O, was directly measured along the hydrate equilibrium boundary under conditions of excess methane gas. Pressure and temperature conditions ranged from 1.9 to 9.7 MPa and 263 to 285 K. Within experimental error, there is no change in hydrate composition with increasing pressure along the equilibrium boundary, but n w may show a slight systematic decrease away from this boundary. A hydrate stoichiometry of n w = 5.81−6.10 H 2 O describes the entire range of measured values, with an average composition of CH 4 ·5.99(±0.07)H 2 O along the equilibrium boundary. These results, consistent with previously measured values, are discussed with respect to the widely ranging values obtained by thermodynamic analysis. The relatively constant composition of methane hydrate over the geologically relevant pressure and temperature range investigated suggests that in situ methane hydrate compositions may be estimated with some confidence.

Journal of Physical Chemistry B↗

USGS2006

Remote sensing studies of the Dionysius region of the Moon

The Dionysius region is located near the western edge of Mare Tranquillitatis and is centered on Dionysius crater, which exhibits a well-developed dark ray system. Proposed origins for these dark rays included impact melt deposits and dark primary ejecta. The region also contains extensive deposits of Cayley-type light plains. Clementine multispectral images and a variety of spacecraft photography were utilized to investigate the composition and origin of geologic units in the Dionysius region. The portions of the dark rays for which spectral and chemical data were obtained are composed of mare debris contaminated with minor amounts of highland material. Both five-point spectra and values of the optical maturity (OMAT) parameter indicate that the dark rays are dominated by mare basalts, not glassy impact melts. The high-albedo rays associated with Dionysius exhibit FeO and TiO2 values that are lower than those of the adjacent dark ray surfaces and OMAT values that indicate that bright ray surfaces are not fully mature. The high-albedo rays are bright largely because of the contrast in albedo between ray material containing highlands-rich ejecta and the adjacent mare-rich surfaces. The mafic debris ejected by Dionysius was derived from a dark, iron-rich unit exposed high on the inner wall of the crater. This layer probably represents a mare deposit that was present at the surface of the preimpact target site. With one possible exception, there is no evidence for buried mare basalts associated with Cayley plains in the region.

Journal of Geophysical Research E: Planets↗

USGS2022

Regional-scale liquefaction analyses

Regional-scale liquefaction hazard analyses are necessary for resilience planning and prioritization of seismic upgrades for critical distributed infrastructure such as levees, pipelines, roadways, and electrical transmission facilities. Two approaches are often considered for liquefaction hazard analysis of distributed infrastructure: (1) conventional, site-specific probe or borehole-based analyses, which do not quantify the uncertainty between investigation locations; or (2) surface geology-based analyses, which often neglect localized geotechnical properties and include a great amount of uncertainty. We describe an analytical method to unify the disparate site-specific and deposit-scale approaches using Gaussian processes. We use borehole data to produce spatial fields of random variables for liquefaction triggering analyses, such as groundwater elevation, soil texture classification, penetration resistance, and cyclic resistance ratio that converge to the site-specific uncertainty at sampling locations but also quantify the uncertainty in-between sampling locations. We demonstrate the effectiveness of Gaussian process models for regional-scale liquefaction hazard analyses in two example studies in Washington state and California, US.

Conference Paper↗

USGS2019

The effect of stress changes on time-dependent earthquake probabilities for the central Wasatch Fault Zone, Utah, USA

Static and quasi-static Coulomb stress changes produced by large earthquakes can modify the probability of occurrence of subsequent events on neighboring faults. This approach is based on physical (Coulomb stress changes) and statistical (probability calculations) models, which are influenced by the quality and quantity of data available in the study region. Here, we focus on the Wasatch Fault Zone (WFZ), a well-studied active normal fault system having abundant geologic and paleoseismological data. Paleoseismological trench investigations of the WFZ indicate that at least 24 large, surface-faulting earthquakes have ruptured the fault’s five central, 35–59-km long segments since ~7 ka. Our goal is to determine if the stress changes due to the youngest paleoevents have significantly modified the present-day probability of occurrence of large earthquakes on each of the segments. For each segment, we modeled the cumulative (coseismic + postseismic) Coulomb stress changes (∆CFScum) due to earthquakes younger than the most recent event on the segment in question and applied the resulting values to the time-dependent probability calculations. Results from the Coulomb stress modeling suggest that the Brigham City, Salt Lake City, and Provo segments have accumulated ∆CFScum larger than 10 bars, whereas the Weber segment has experienced a stress decrease of 5 bars, in the scenario of recent rupture of the Great Salt Lake fault to the west. Probability calculations predict high probability of occurrence for the Brigham City and Salt Lake City segments, due to their long elapsed times (>1-2 ka) when compared to the Weber, Provo, and Nephi segments (< 1 ka). The range of calculated coefficients of variation (CV) has a large influence on the final probabilities, mostly in the case of the Brigham City segment. Finally, when the Coulomb stress and the probability models are combined, our results indicate that the ∆CFScum resulting from earthquakes postdating the youngest events on each of the five segments significantly affects the probability calculations for three of the segments: Brigham City, Salt Lake City, and Provo. The probability of occurrence of a large earthquake in the next 50 years on these three segments may therefore be underestimated if a time-independent approach, or a time-dependent approach that does not consider ∆CFS, is adopted.

Utah↗

USGS2009

Channel, floodplain, and wetland responses to floods and overbank sedimentation, 1846-2006, Halfway Creek Marsh, Upper Mississippi Valley, Wisconsin

Conversion of upland forest and prairie vegetation to agricultural land uses, following Euro-American settlement in the Upper Mississippi River System, led to accelerated runoff and soil erosion that subsequently transformed channels, floodplains, and wetlands on bottomlands. Halfway Creek Marsh, at the junction of Halfway Creek and the Mississippi River on Wisconsin's western border, is representative of such historical transformation. This marsh became the focus of a 2005-2006 investigation by scientists from the U.S. Geological Survey, the University of Wisconsin- Madison, and the U.S. Environmental Protection Agency, who used an understanding of the historical transformation to help managers identify possible restoration alternatives for Halfway Creek Marsh. Field-scale topographic surveys and sediment cores provided data for reconstructing patterns and rates of historical overbank sedimentation in the marsh. Information culled from historical maps, aerial photographs, General Land Offi ce Survey notes, and other historical documents helped establish the timing of anthropogenic disturbances and document changes in channel patterns. Major human disturbances, in addition to agricultural land uses, included railroad and road building, construction of artifi cial levees, drainage alterations, and repeated dam failures associated with large floods. A volume of approximately 1,400,000 m 3 , involving up to 2 m of sandy historical overbank deposition, is stored through the upper and lower marshes and along the adjacent margins of Halfway Creek and its principal tributary, Sand Lake Coulee. The estimated overbank sedimentation rate for the entire marsh is ??3,000 m 3 yr- 1 for the recent period 1994-2006. In spite of reduced surface runoff and soil erosion in recent years, this recent sedimentation rate still exceeds by ??4 times the early settlement (1846-1885) rate of 700 m 3 yr- 1 , when anthropogenic acceleration of upland surface runoff and soil erosion was beginning. The highest rate of historical bottomland sedimentation occurred from 1919 to 1936, when the estimated overbank sedimentation rate was 20,400 m 3 yr- 1 . This rate exceeded by nearly 30 times the 1846-1886 rate. Artifi cial levees were constructed along the upper reach of Halfway Creek in the marsh during the early twentieth century to restrict fl ooding on the adjacent bottomlands. Anomalously high overbank sedimentation rates subsequently occurred on the fl oodplain between the levees, which also facilitated more effi cient transport of sediment into the lower marsh bottomland. Although overbank sedimentation rates dropped after 1936, corresponding to the widespread adoption of soil-conservation and agricultural best-management practices, the continuation of anomalously high overbank sedimentation between the levees led to increased bank heights and development of a relatively deep channel. The deep cross-section morphology is commonly mistaken as evidence of channel incision; however, this morphology actually resulted from excessive overbank sedimentation. The historical metamorphosis of the Halfway Creek channel and riparian wetlands underscores the importance of understanding the long-term history of channel and fl oodplain evolution when restoration of channels and riparian wetlands are under consideration. Sedimentation patterns and channel morphology for Halfway Creek Marsh probably are representative of other anthropogenically altered riparian wetlands in the Upper Mississippi River System and similar landscapes elsewhere.

Special Paper of the Geological Society of America↗

USGS1983

Deep structure of northern Mississippi embayment

In September 1980, the U. S. Geological Survey conducted a seismic refraction investigation of the northern Mississippi Embayment. During the investigation, 34 shots from nine shotpoints were recorded along a series of profiles. The profiles were parallel to and across an inferred Precambrian rift zone which is outlined by a series of magnetic anomalies and covers an area at least 200 km (125 mi) long and 70 km (45 mi) wide. The paper presents an interpretation of the survey results. The tectonic model proposed to explain the origin of the embayment velocity structure includes a late Precambrian mantle plume that intruded the lower crust of the northern embayment, causing uplift (and/or crustal stretching) and subsequent rifting of the axial area. This was followed by erosion, subsidence, and subsequent deposition of sediments in the resulting trough.

Northern Mississippi embayment↗

USGS1973

Hydrologic Data of the Neponset and Weymouth River Basins, Massachusetts

The Neponset, Weymouth Fore, and Weymouth Back River basins occupy an area of 183 square miles in eastern Massachusetts south of Boston and Braintree, Brockton, Canton, Dedham, Dover, Foxborough, Hingham, Holbrook, Medfield, Milton, Norwood, Quincy, Randolph, Rockland, Sharon, Stoughton, Walpole, Westwood, and Weymouth. Hydrologic data presented in this report were collected during an investigation of the water resources in the areas of these basins that are upstream from tide effect or heavy urbanization. This investigation was conducted by the U.S. Geological Survey in cooperation with the Massachusetts Water Resources Commission. The data are released in order to make available to the public basic hydrologic and related information that will facilitate the planning of water-resources development and will complement an interpretive report, "Hydrology and water resources of the Neoponset and Weymouth River basins, Massachusetts" (HA-484). The well and boring data contained herein were selected from a larger group of data in order to minimize redundancy of information for intensely drilled areas. All of the data are on filed and available for inspection at the office of the U.S. Geological Survey, Water Resources Division, Boston, Massachusetts.

Massachusetts↗

USGS1967

Northern part, Ten Mile and Taunton River basins

The northern part of the Ten Mile and Taunton River basins is an area of about 195 square miles within Norfolk, Plymouth, and Bristol Counties in southeastern Massachusetts. The northern boundary of the area (plate 1) is the drainage divide separating these basins from that of the Charles, Neponset, and Weymouth River basins. The western boundary is, for the most part, the divide separating the basins from the Blackstone River basin. The eastern boundary is at the edge of the Brockton-Pembroke area (Petersen, 1962; Petersen and Shaw, 1961). The southern boundary in Seekonk is the northern limit of the East Providence quadrangle, for which a ground-water map was prepared by Allen and Gorman (1959); eastward, the southern boundaries of the city of Attleboro and the towns of Norton, Easton, and West Bridgewater form the southern boundary of the area. This report is one of two prepared by the Geological Survey for the Water Resources Commission. The principal purpose of this report is to make available the basic data on which the other, a map showing availability of ground water, is based. This basic-data report also can be used by engineers, planners, and others interested in or responsible for water-resources planning to determine the materials to be encountered (tables 3 and 4) and the yields which may be obtained from wells and test holes (tables 1 and 2) in the stratified sand and gravel that are the principal source of ground water and in bedrock. Partial and complete chemical analyses (tables 7 and 8) of these test holes and of some privately-owned wells provide information on the general quality of the water for domestic and other uses. A tabulation of existing municipal supplies, their capacity, production (table 5), and chemical quality of the water (table 6) may be used for regional planning purposes. Water-level measurements (figure 1) can be used to determine the annual fluctuations of the water table in certain types of materials. Seismic work (table 9) in the Canoe River valley, Norton, and test drilling with a power augur (tables 2 and 4) were done for the Geological Survey as part of the investigation.

Massachusetts↗

USGS1986

Mineral resources of the Castle Peaks Wilderness Study Area, San Bernardino County, California

The Castle Peaks Wilderness Study Area (CDCA266) comprises approximately 45,000 acres in the northern New York Mountains, San Bernardino County, California. At the request of the Bureau of Land Management, 39,303 acres of the wilderness study area were studied. The area was investigated during 1982-1985 using combined geologic, geochemical, and geophysical methods. are considered preliminarily suitable for wilderness deignation. There are no mineral reserves or identified resources in the study area. Fluorspar, occurring in sparse veins, has moderate resource potential, as do silver and lead in fault zones, and gold and silver in sparse, high-grade veins and fault breccia. Each area of moderate resource potential encompasses less than one square mile. These same commodities have low resource potential in similar occurrences throughout much of the study area. In addition, there is low resource potential for gold in placer deposits, uranium in altered breccia and gouge, and rare-earth elements in pegmatite dikes. There is no resource potential for oil and gas resources over most of the study area, but the potential is unknown along its western margin. In this report, the area studied is referred to"the wilderness study area", or simply "the study area."

California↗

USGS1992

Mineral resource assessment of the Dillon 1° x 2° quadrangle, Idaho and Montana

The Dillon 1 ° x2° quadrangle in southwestern Montana and east-central Idaho was investigated as part of the U.S. Geological Survey's Conterminous United States Mineral Assessment Program (CUSMAP) to determine its mineral resource potential. An interdisciplinary study was made of geology, geochemistry, geophysics (gravity and aeromagnetics), remote sensing, and mineral deposits. The results of those studies, as well as mineral resource assessment of numerous mineraldeposit types, are published separately as a folio of maps. This report summarizes the studies, provides background information on them, and presents a selected bibliography relevant to the geology and mineral resources of the quadrangle. The quadrangle contains large resources of gold and substantial resources of talc and chlorite, all of which were being mined in the 1980's and early 1990's. Submarginal resources of molybdenum, copper, tungsten, and iron range from moderately large to large. Other commodities that may be present in significant amounts are chromite, lead, zinc, silver, barite, zeolite minerals, and various nonmetallic metamorphic minerals.

Idaho, Montana↗

USGS2017

The Surge, Wave, and Tide Hydrodynamics (SWaTH) network of the U.S. Geological Survey—Past and future implementation of storm-response monitoring, data collection, and data delivery

After Hurricane Sandy made landfall along the northeastern Atlantic coast of the United States on October 29, 2012, the U.S. Geological Survey (USGS) carried out scientific investigations to assist with protecting coastal communities and resources from future flooding. The work included development and implementation of the Surge, Wave, and Tide Hydrodynamics (SWaTH) network consisting of more than 900 monitoring stations. The SWaTH network was designed to greatly improve the collection and timely dissemination of information related to storm surge and coastal flooding. The network provides a significant enhancement to USGS data-collection capabilities in the region impacted by Hurricane Sandy and represents a new strategy for observing and monitoring coastal storms, which should result in improved understanding, prediction, and warning of storm-surge impacts and lead to more resilient coastal communities. As innovative as it is, SWaTH evolved from previous USGS efforts to collect storm-surge data needed by others to improve storm-surge modeling, warning, and mitigation. This report discusses the development and implementation of the SWaTH network, and some of the regional stories associated with the landfall of Hurricane Sandy, as well as some previous events that informed the SWaTH development effort. Additional discussions on the mechanics of inundation and how the USGS is working with partners to help protect coastal communities from future storm impacts are also included.

Connecticut, Delaware, Maine, Maryland, Massachuse↗

USGS2017

Vulnerable transportation and utility assets near actively migrating streams in Indiana

An investigation was completed by the U.S. Geological Survey in cooperation with the Indiana Office of Community and Rural Affairs that found 1,132 transportation and utility assets in Indiana are vulnerable to fluvial erosion hazards due to close proximity to actively migrating streams. Locations of transportation assets (bridges, roadways, and railroad lines) and selected utility assets (high-capacity overhead power-transmission lines, underground pipelines, water treatment facilities, and in-channel dams) were determined using aerial imagery hosted by the Google Earth platform. Identified assets were aggregated by stream reach, county, and class. Accompanying the report is a polyline shapefile of the stream reaches documented by Robinson. The shapefile, derived from line work in the National Hydrography Dataset and attributed with channel migration rates, is released with complete Federal Geographic Data Committee metadata. The data presented in this report are intended to help stakeholders and others identify high-risk areas where transportation and utility assets may be threatened by fluvial erosion hazards thus warranting consideration for mitigation strategies.

Indiana↗

USGS2013

Water quality, sediment characteristics, aquatic habitat, geomorphology, and mussel population status of the Clinch River, Virginia and Tennessee, 2009-2011

Chemical, physical, and biological data were collected during 2009-2011 as part of a study of the Clinch River in Virginia and Tennessee. The data from this study, data-collection methods, and laboratory analytical methods used in the study are documented in this report. The study was conducted to describe the conditions of the Clinch River and to determine if there are measurable differences in chemical, physical, or biological characteristics in a segment of the river where freshwater mussel populations are in decline, have low density, richness, little to no recruitment, and lack endangered species (low-quality reach) compared to a segment of the river where mussel assemblages have relatively high density, richness, evidence of recruitment, and support endangered species (high-quality reach). Five continuous water-quality monitors were installed and operated on the mainstem of the Clinch River and two tributaries. Discrete water-quality sample sets were collected during base-flow and stormflow conditions two sites on the Clinch River and on the Guest River, a tributary to the Clinch River predominantly in the Appalachian Plateaus Physiographic Province. Base-flow water-quality samples were collected in July and August 2011 at 15 sites along the mainstem of the Clinch River. Other analyses included longitudinal sampling along the mainstem of the Clinch River at 10 sites to evaluate bed-sediment chemistry, habitat condition, and mollusk community status. In situ freshwater mussel growth and mortality experiments were conducted with hatchery propogated Villosa iris (rainbow mussels). Tissue from the V. iris as well as tissue from 16 Actinonaias pectorosa mussels were analyzed for trace metals, and V. iris mussel tissue was analyzed for organic compounds. Data collected during this investigation were analyzed by various U.S. Geological Survey or U.S. Fish and Wildlife Service laboratories.

Tennessee, Virginia↗

USGS1997

Herbicides and nitrates in the Iowa River alluvial aquifer prior to changing land use, Iowa County, Iowa, 1996

The Iowa River alluvial aquifer in Iowa County, Iowa (fig. 1), underlies an area of intensive agricultural activity where pesticides and nitrogen-based fertilizers are extensively used. The effects of changing land use on shallow ground-water quality in part of the Iowa River alluvial aquifer are currently being investigated as part of the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program. Approximately one-third of the cropland in the study area will be taken out of production over the next few years as part of wetland restoration. Over a three-week period in 1996, the USGS collected water samples from 23 observation wells completed in the Iowa River alluvial aquifer and analyzed the samples for selected agricultural chemicals. Four herbicides (alachlor, atrazine, cyanazine, and metolachlor) and one nutrient (nitrate) were selected for study on the basis of frequent usage in Iowa and high detection rates in ground water (Detroy and Kuzniar, 1988). Alachlor was not detected at concentrations greater than the method detection limit (MDL). Atrazine was detected at concentrations greater than the MDL in samples from 48 percent of the 23 wells, cyanazine from 13 percent, metolachlor from 26 percent, and nitrate from 91 percent. None of the four herbicides were detected at concentrations greater than the respective U.S. Environmental Protection Agency's (USEPA) Maximum Contaminant Level (MCL) for drinking water. Thirteen percent of the samples had nitrate concentrations above the USEPA's MCL of 10 mg/L (milligrams per liter). Relations between constituent concentration and well depth were observed for specific constituents at individual well nests.

Iowa↗