Search USGS⌕ Search

SEARCH · Search USGS

Results for “Environmental Evidence”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,225 records · Page 68Linked to original sources
USGS2002

Degradation of marine ecosystems and decline of fishery resources in marine protected areas in the US Virgin Islands

The large number of marine protected areas (MPAs) in the Caribbean (over 100) gives a misleading impression of the amount of protection the reefs and other marine resources in this region are receiving. This review synthesizes information on marine resources in two of the first MPAs established in the USA, namely Virgin Islands National Park (1962) and Buck Island Reef National Monument (1961), and provides compelling evidence that greater protection is needed, based on data from some of the longest running research projects on coral reefs, reef fish assemblages, and seagrass beds for the Caribbean. Most of the stresses affecting marine resources throughout the Caribbean (e.g. damage from boats, hurricanes and coral diseases) are also causing deterioration in these MPAs. Living coral cover has decreased and macroalgal cover has increased. Seagrass densities have decreased because of storms and anchor damage. Intensive fishing in the US Virgin Islands has caused loss of spawning aggregations and decreases in mean fish size and abundance. Groupers and snappers are far less abundant and herbivorous fishes comprise a greater proportion of samples than in the 1960s. Effects of intensive fishing are evident even within MPA boundaries. Although only traditional fishing with traps of 'conventional design' is allowed, commercial trap fishing is occurring. Visual samples of fishes inside and outside Virgin Islands National 'Park showed no significant differences in number of species, biomass, or mean size of fishes. Similarly, the number of fishes per trap was statistically similar inside and outside park waters. These MPAs have not been effective because an unprecedented combination of natural and human factors is assaulting the resources, some of the greatest damage is from stresses outside the control of park managers (e.g. hurricanes), and enforcement of the few regulations has been limited. Fully functioning MPAs which prohibit fishing and other extractive uses (e.g. no-take marine reserves) could reverse some of the degradation, allowing replenishment of the fishery resources and recovery of benthic habitats.

Environmental Conservation↗
USGS2023

Influence of fine-scale habitat characteristics on sage-grouse nest site selection and nest survival varies by mesic and xeric site conditions

Resource managers and scientists across western U.S. agencies seek methodologies for identifying environmental attributes important to both wildlife conservation and broad-scale land stewardship. The Greater Sage-Grouse ( Centrocercus urophasianus ; hereafter, sage-grouse) exemplifies a species in need of this broad-scale approach given widespread population declines that have resulted from loss and degradation of habitat from natural and anthropogenic disturbances. These include agricultural land conversion, conifer expansion, energy development, and wildfire coupled with ecological conversion by invasive plants such as cheatgrass ( Bromus tectorum ). Development of habitat assessments and conservation actions for sage-grouse benefit from studies that link demographic responses to habitat selection patterns. To address this, we examined nest survival of sage-grouse in relation to fine-scale habitat patterns (i.e., field-based habitat measurements) that influenced nest site selection, using data from nests of telemetered females at 17 sites over 6 years in Nevada and northeastern California, USA. Importantly, sites spanned mesic and xeric average precipitation conditions that contributed substantially to vegetation community structure across cold desert ecosystems of the North American Great Basin. Vegetative cover immediately surrounding sage-grouse nests was important for both nest site selection and nest survival, but responses varied between mesic and xeric sites. For example, while taller perennial grasses were selected at xeric sites, we found no evidence of selection for perennial grass at mesic sites, indicating a functional response to availability of habitat features between hydrographic regions. Furthermore, perennial grass height and forb height both had positive effects on nest survival at xeric sites, but we found varying effects at mesic sites. We emphasize that precipitation conditions driving ecosystem productivity vary regionally among sagebrush communities, shaping vegetation structure and suitable habitat conditions for nesting sage-grouse.

Ornithological Applications↗
USGS2008

Pesticide fate and transport throughout unsaturated zones in five agricultural settings, USA

P esticide transport through the unsaturated zone is a function of chemical and soil characteristics, application, and water recharge rate. The fate and transport of 82 pesticides and degradates were investigated at five different agricultural sites. Atrazine and metolachlor, as well as several of the degradates of atrazine, metolachlor, acetochlor, and alachlor, were frequently detected in soil water during the 2004 growing season, and degradates were generally more abundant than parent compounds. Metolachlor and atrazine were applied at a Nebraska site the same year as sampling, and focused recharge coupled with the short time since application resulted in their movement in the unsaturated zone 9 m below the surface. At other sites where the herbicides were applied 1 to 2 yr before sampling, only degradates were found in soil water. Transformations of herbicides were evident with depth and during the 4-mo sampling time and reflected the faster degradation of metolachlor oxanilic acid and persistence of metolachor ethanesulfonic acid. The fraction of metolachlor ethanesulfonic acid relative to metolachlor and metolachlor oxanilic acid increased from 0.3 to > 0.9 at a site in Maryland where the unsaturated zone was 5 m deep and from 0.3 to 0.5 at the shallowest depth. The flux of pesticide degradates from the deepest sites to the shallow ground water was greatest (3.0–4.9 μmol m −2 yr −1 ) where upland recharge or focused flow moved the most water through the unsaturated zone. Flux estimates based on estimated recharge rates and measured concentrations were in agreement with fluxes estimated using an unsaturated-zone computer model (LEACHM).

Journal of Environmental Quality↗
USGS2013

Electrical signatures of ethanol-liquid mixtures: implications for monitoring biofuels migration in the subsurface

Ethanol (EtOH), an emerging contaminant with potential direct and indirect environmental effects, poses threats to water supplies when spilled in large volumes. A series of experiments was directed at understanding the electrical geophysical signatures arising from groundwater contamination by ethanol. Conductivity measurements were performed at the laboratory scale on EtOH–water mixtures (0 to 0.97 v/v EtOH) and EtOH–salt solution mixtures (0 to 0.99 v/v EtOH) with and without a sand matrix using a conductivity probe and a four-electrode electrical measurement over the low frequency range (1–1000 Hz). A Lichtenecker–Rother (L–R) type mixing model was used to simulate electrical conductivity as a function of EtOH concentration in the mixture. For all three experimental treatments increasing EtOH concentration resulted in a decrease in measured conductivity magnitude (|σ|). The applied L–R model fitted the experimental data at concentration ≤ 0.4 v/v EtOH, presumably due to predominant and symmetric intermolecular (EtOH–water) interaction in the mixture. The deviation of the experimental |σ| data from the model prediction at higher EtOH concentrations may be associated with hydrophobic effects of EtOH–EtOH interactions in the mixture. The |σ| data presumably reflected changes in relative strength of the three types of interactions (water–water, EtOH–water, and EtOH–EtOH) occurring simultaneously in EtOH–water mixtures as the ratio of EtOH to water changed. No evidence of measurable polarization effects at the EtOH–water and EtOH–water–mineral interfaces over the investigated frequency range was found. Our results indicate the potential for using electrical measurements to characterize and monitor EtOH spills in the subsurface.

Journal of Contaminant Hydrology↗
USGS2002

Possible sources of nitrate in ground water at swine licensed-managed feeding operations in Oklahoma, 2001

Samples collected and analyzed by the Oklahoma Department of Agriculture, Food, and Forestry from 1999 to 2001 determined that nitrate exceeded the U.S. Environmental Protection Agency maximum contaminant level for public drinking-water supplies of 10 milligrams per liter as nitrogen in 79 monitoring wells at 35 swine licensed-managed feeding operations (LMFO) in Oklahoma. The LMFOs are located in rural agricultural settings where long-term agriculture has potentially affected the ground-water quality in some areas. Land use prior to the construction of the LMFOs was assessed to evaluate the types of agricultural land use within a 500-meter radius of the sampled wells. Chemical and microbiological techniques were used to determine the possible sources of nitrate in water sampled from 10 wastewater lagoons and 79 wells. Samples were analyzed for dissolved major ions, dissolved trace elements, dissolved nutrients, nitrogen isotope ratios of nitrate and ammonia, wastewater organic compounds, and fecal coliform bacteria. Bacteria ribotyping analysis was done on selected samples to identify possible specific animal sources. A decision process was developed to identify the possible sources of nitrate. First, nitrogen isotope ratios were used to define sources as animal, mixed animal and fertilizer, or fertilizer. Second, wastewater organic compound detections, nitrogen-isotope ratios, fecal coliform bacteria detections, and ribotyping were used to refine the identification of possible sources as LFMO waste, fertilizer, or unidentified animal or mixtures of these sources. Additional evidence provided by ribotyping and wastewater organic compound data can, in some cases, specifically indicate the animal source. Detections of three or more wastewater organic compounds that are indicators of animal sources and detections of fecal coliform bacteria provided additional evidence of an animal source. LMFO waste was designated as a possible source of nitrate in water from 10 wells. The source of waste in water from five of those wells was determined through ribotyping, and the source of waste in water from the remaining five wells was determined by detections of three or more animal-waste compounds in the well samples. LMFO waste in the water from wells with unidentified animal source of nitrate does not indicate that LMFO waste was not the source, but indicated that multiple animal sources, including LMFO waste, may be the source of the nitrate.

Water-Resources Investigations Report↗
USGS2020

Endocrine and physiological responses of hatchling American kestrels (Falco sparverius) following embryonic exposure to technical short-chain chlorinated paraffins (C10-13)

Short chain chlorinated paraffins (SCCPs) are complex mixtures of polychlorinated n -alkanes, shown to bioaccumulate but with unknown effects in wild birds. The present study examined development-related effects of SCCPs on captive American kestrels ( Falco sparverius ) treated in ovo on embryonic day (ED) 5 by injection with technical Chloroparaffin® (C 10-13 , 55.5% Cl) at environmentally relevant nominal (measured) concentrations of 10 (10), 50 (29) or 100 (97) ng ΣSCCP/g egg ww, and artificially incubated until hatching (ED27–ED29). The SCCP concentrations measured in the yolk sacs of the hatchling kestrels bracketed concentrations reported in the eggs of wild birds. Uptake and deposition of these SCCPs differed between male and female hatchlings, with only males showing differences in SCCP concentrations, being highest in the high-dose males than each of the other male groups. Embryonic exposure to SCCPs suppressed glandular total thyroxine (TT4) (20–33%) and reduced circulating triiodothyronine (TT3) (37–40%) in male hatchlings only when compared to control males, but had no effect on glandular TT3 or circulating TT4 in male or female kestrels. Histological assessments of thyroid glands showed that both sexes experienced significant structural changes indicative of gland activation. These thyroid glandular changes and the variations in SCCP concentrations were related to circulating TT3 in female hatchlings. Hepatic deiodinase enzyme (D1, D2) activities were stable and no SCCP-related changes were observed in hatching success, hatchling size, or immune organ size. However, several of the thyroid function indicators were correlated with hatchling size and smaller bursas and spleens, possibly indirectly through SCCP-induced changes in thyroid function. Because changes in thyroid function were evident at concentrations measured in wild bird eggs, similar changes may occur in wild nestlings. The potential impact of these changes on thyroid-mediated growth and survival in wild birds requires further investigation.

Environment International↗
USGS1995

Water-quality assessment of the Albemarle-Pamlico drainage basin, North Carolina and Virginia: Characterization of suspended sediment, nutrients, and pesticides

The 28,000-square-mile Albemarle-Pamlico drainage basin includes the Roanoke, Dan, Chowan Tar, and Neuse Rivers. The basin extends through four physiographic provinces in North Carolina and Virginia-Valley and Ridge, Blue Ridge, Piedmont and Coastal Plain. The spatial and temporal trends in ground-water and riverine water quality in the study area were characterized by using readily available data sources The primary data sources that were used included the U.S. Geological Survey's National Water Data Storage and Retrieval System (WATSTORE) database, the U.S. Environmental Protection Agency's Storage and Retrieval System (STORET) database, and results of a few investigations of pesticide occurrence. The principal water-quality constituents examined were suspended sediment, nutrients, and pesticides. The data examined generally spanned the period from 1950 to 1993. The only significant trends in suspended sediment were detected at three Chowan River tributary sites which showed long-term decreases. Suspended- and total-solids concentrations have decreased throughout the Albemarle-Pamlico drainage basin. The decreases are probably a result of (1) construction of new lakes and ponds in the basin, which trap solids, (2) improved agricultural soil management, and (3) improved wastewater treatment. Nutrient point sources are much less than nonpoint nutrient sources at the eight NASQAN basins examined for nutrient loads. The greatest nitrogen inputs are associated with crop fertilizer and biological nitrogen fixation by soybeans and peanuts, whereas atmospheric and animal-related nitrogen inputs are comparable in magnitude. The largest phosphorus inputs are associated with animal wastes. The most commonly detected pesticides in surface water in the STORET database were atrazine and aldrin.Intensive organonitrogen herbicide sampling of Chicod Creek in 1992 showed seasonal variations in pesticide concentration. The most commonly detected herbicides were atrazine, alachlor, metolachlor, prometon, and metribuzin. No relation between streamflow and pesticide concentration was evident.

North Carolina, Virginia↗
USGS1997

Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico and Texas: Ground-water quality in the Rio Grande flood plain, Cochiti Lake, New Mexico, to El Paso, Texas, 1995

From March to May of 1995, water samples were collected from 30 wells located in the flood plain of the Rio Grande between Cochiti Lake, New Mexico, and El Paso, Texas. These samples were analyzed for a broad host of constituents, including field parameters, major constituents, nutrients, dissolved organic carbon, trace elements, radiochemicals, pesticides, and volatile organic compounds. The main purpose of this study was to observe the quality of ground water in this part of the Rio Grande Valley study unit of the U.S. Geological Survey National Water-Quality Assessment program. The sampling effort was limited to the basin- fill aquifer beneath the above-defined reach of the Rio Grande flood plain because of the relative homogeneity of the hydrogeology, the large amount of ground-water use for public supply, and the potential for land-use activities to affect the quality of ground water. Most of the wells sampled for the study are used for domestic purposes, including drinking water. Depths to the tops of the sampling intervals in the 30 wells ranged from 10 to 345 feet below land surface, and the median was 161.5 feet; the sampling intervals in most of the wells spanned about 10 feet or less. Quality-control data were collected at three of the wells. A significant amount of variation was found in the chemical composition of ground water sampled throughout the study area, but the water generally was found to be of suitable chemical quality for use as drinking water, according to current enforceable standards established by the U.S. Environmental Protection Agency (EPA). Nutrients generally were measured at concentrations near or below their method reporting limits. The most dominant nutrient species was nitrite plus nitrate, at a maximum concentration of 1.9 milligrams per liter (as N). Only eight of the trace elements analyzed for had median concentrations greater than their respective minimum reporting levels. Water from one well exceeded the lifetime health advisory established by the EPA for molybdenum; water from a different well exceeded the proposed EPA maximum contaminant level for uranium. Gross alpha and gross beta particle activities generally appeared to strongly correlate with quantities of uranium and potassium, respectively, detected in ground water. However, water from one well exceeded the EPA maximum contaminant level for gross alpha particle activity and may exceed the EPA maximum contaminant level for beta particle and photon activity, although current data on gross beta particle activities are not conclusive on this point. Radon concentrations did not appear to directly correlate with uranium concentrations. The herbicide prometon was the only synthetic organic compound detected in ground water in the study area, and was detected in only one well, at a concentration of 0.038 microgram per liter. This well is shallow and is not used for drinking water. With the exception of the one detection of prometon, no strong evidence was found of effects on ground-water quality from human activities. Therefore, most of the water sampled probably recharged at the margins of the alluvial basins or recharged through the flood plain before human development began. With respect to major constituents, the concentrations of dissolved solids ranged from 209 to 3,380 milligrams per liter, and the median concentration was 409.5 milligrams per liter. There is evidence that the overall chemical composition of ground water in the study area may be affected by several processes, including cation exchange, feldspar weathering, calcite dissolution and precipitation, dissolution of volcanic glass, and microbial activity. Several chemical constituents in ground water showed relatively distinct spatial patterns that appear to be related to one or more of these processes.

Texas↗
USGS2015

Evaluation of mercury in rainbow trout collected from Duck Valley Indian Reservation reservoirs, southwestern Idaho and northern Nevada, 2007, 2009, and 2013

The U.S. Geological Survey, in cooperation with the Shoshone-Paiute Tribes of the Duck Valley Indian Reservation, analyzed mercury (Hg) concentration in rainbow trout ( Oncorhynchus mykiss ) collected from three reservoirs on the reservation (Mountain View, Lake Billy Shaw, and Sheep Creek) during sampling events in 2007, 2009, and 2013, to determine the risk of Hg exposure to Tribal members and the general public. Mercury concentration in predatory fish tends to increase with fish length, and this tendency was true for rainbow trout in the reservoirs on the reservation (r 2 = 0.44–0.70). Mean (average) and median Hg concentrations in fish tissue were determined for each reservoir for each sample year. All Hg concentrations were less than the U.S. Environmental Protection Agency’s water-quality criterion of 0.30 milligram per kilogram (mg/kg wet weight [ww]) and the Idaho Department of Environmental Quality’s reasonable potential to exceed threshold of 0.24 mg/kg. Idaho Department of Health and Welfare toxicologists determined that the Hg concentrations in rainbow trout in this study would not warrant a fish-consumption advisory for this species. Throughout this report, statistical findings with a p -value of less than 0.05 are referred to as “significant.” Mean Hg concentrations in fish-tissue samples collected from Mountain View Reservoir were higher in 2007 (0.12 mg/kg ww) than in 2009 and 2013 (0.07 and 0.06 mg/kg ww, respectively), indicating a significant mean decrease. Mean Hg concentrations in fish-tissue samples collected from Lake Billy Shaw showed no significant differences among sample years (2007, 0.12 mg/kg ww; 2009, 0.07 mg/kg ww; 2013, 0.09 mg/kg ww). Mean Hg concentrations in fish-tissue samples collected from Sheep Creek Reservoir significantly increased in 2013 (0.10 mg/kg ww) from concentrations in 2007 and 2009 (0.06 and 0.05 mg/kg ww, respectively). These temporal and spatial variations are not unexpected, as each body of water may differ in the factors and conditions affecting the rate of methylation and demethylation. Coupled with the dynamic put-and-take fishery, the outcomes reflect the system complexities among reservoirs despite their fairly close proximity to one another. The influence of these other factors is evident when the analysis of atmospheric Hg deposition at Mercury Deposition Network site NV02 in northern Nevada showed no significant linear trend in wet Hg deposition rates for 2003–2013 (average 3.02 micrograms per square meter).

Idaho, Nevada↗
USGS1997

Cytochrome P450 and organochlorine contaminants in black-crowned night-herons from the Chesapeake Bay region, USA

Black-crowned night-heron ( Nycticorax nycticorax ) offspring were collected from a relatively uncontaminated coastal reference site (next to Chincoteague National Wildlife Refuge, VA, USA) and two sites in the Chesapeake Bay watershed (Baltimore Harbor, MD and Rock Creek Park, Washington, DC, USA). Hepatic microsomal activities of benzyloxyresorufin- O -dealkylase and ethoxyresorufin- O -dealkylase were significantly elevated (up to sixfold and ninefold induction, respectively) in pipping embryos from the Baltimore Harbor colony compared to the reference site, whereas values in embryos from the Rock Creek Park colony were intermediate. Concentrations of organochlorine pesticides and metabolites in pipping embryos from both sites in the Chesapeake watershed were greater than at the reference site but below the known threshold for reproductive impairment. However, concentrations of 10 arylhydrocarbon receptor-active polychlorinated biphenyl (PCB) congeners and estimated toxic equivalents were up to 37-fold greater in embryos collected from these two sites in the Chesapeake Bay region, with values for toxic congeners 77 and 126 exceeding those observed in pipping heron embryos from the Great Lakes. Monooxygenase activity of pipping embryos was associated with concentrations of several organochlorine pesticides, total PCBs, arylhydrocarbon receptor-active PCB congeners, and toxic equivalents ( r = 0.30–0.59), providing further evidence of the value of cytochrome P450 as a biomarker of organic contaminant exposure. Organochlorine contaminant levels were greater in 10-d-old nestlings from Baltimore Harbor than the reference site but had no apparent effect on monooxygenase activity or growth. These findings demonstrate induction of cytochrome P450 in pipping black-crowned night-heron embryos in the Chesapeake Bay region, probably by exposure to PCB congeners of local origin, and the accumulation of organochlorine pesticides and metabolites in nestling herons from Baltimore Harbor. Bio-monitoring with additional waterbird species (e.g., bald eagle, common tern, great blue heron) that appear to be more sensitive to PCBs than black-crowned night-herons is recommended to document health of waterbirds and remediation of the Chesapeake Bay.

Chesapeake Bay region↗
USGS2023

Can angler-assisted broodstock collection programs improve harvest rates of hatchery-produced steelhead?

Fish that exhibit high foraging activity or bold behavior can be particularly vulnerable to angling. If these traits are heritable, selection through harvest can drive phenotypic change, eventually rendering a target population less vulnerable to angling and consequently impacting the quality of the fishery. In this study, we used parental-based tags to investigate whether vulnerability to angling might be heritable in steelhead trout ( Oncorhynchus mykiss ) spawned at a hatchery in western Oregon, USA. We found modest evidence to support the hypothesis that vulnerability to angling is a heritable trait in steelhead. However, our data unexpectedly revealed that steelhead collected with in-river traps produced nearly twice as many adult offspring as steelhead collected by anglers. This difference in adult-to-adult production is explained in part through lower egg-to-fry survival of steelhead produced with angler-caught broodstock, possibly related to collection stress and greater time in captivity experienced by angler-caught broodstock. Our findings suggest that managers could improve broodstock fitness and program efficiencies by preferentially spawning fish collected with traps, and limiting use of broodstock collected by anglers. Additional research is needed to identify mechanisms contributing to higher juvenile mortality of steelhead produced with angler-caught broodstock.

Oregon↗
USGS2017

The Snowmastodon Project

Studies of terrestrial biotic and environmental dynamics of the last interglacial period, Marine Oxygen Isotope Stage (MIS) 5, provide insight into the effects of long-term climate change on Pleistocene ecosystems. In North America, however, there are relatively few fossil sites that definitively date to MIS 5. Even fewer contain multiple ecosystem components (vertebrates, invertebrates, plants) that have been studied in detail, and none are located at high elevation. Thus, our view of North American ecosystems during MIS 5 is, at best, an incomplete composite view, and alpine ecosystems are entirely undocumented. The Ziegler Reservoir fossil site allows us to begin filling these gaps. Discovered on October 14, 2010 by a construction crew while enlarging a small reservoir near Snowmass Village, Colorado (USA), the site is situated high in the Rocky Mountains at an elevation of ~ 2705 m. Initial excavations exposed a series of stacked fossil ecosystems, including abundant faunal and floral components. Subsequent work revealed an exceptionally diverse biota composed of nearly 6000 large bones of late Pleistocene megafauna, including mastodons, mammoths, ground sloths, horses, camels, deer, bison, black bear, coyotes, and big horn sheep. This collection is complemented by more than 200 bones from at least 40 species of small animals including otters, muskrats, minks, rabbits, beavers, frogs, lizards, snakes, fish, and birds, and more than 20,000 salamander bones. Geomorphic evidence and multiple dating techniques show that the small, ridge-top basin containing the site was formed by a lateral lobe of a valley glacier that filled, and ultimately overtopped, the Snowmass Creek drainage during the Bull Lake glaciation (MIS 6). When the glacier receded, a lake that occupied the basin began to fill slowly with what is hypothesized to be eolian sediment and occasional input from slope failures of the impounding moraine. As sedimentation continued, the lake transformed first into a shallow pond, then a marsh, and later an alpine meadow. In all, the Ziegler Reservoir sedimentary record spans the time encompassed by the end of MIS 6, all of MIS 5 and MIS 4, and the earliest part of MIS 3. MIS 5e, which is considered to be the peak warmth of the last interglacial period, is especially well represented. Preservation of organic material at the Ziegler Reservoir fossil site is exceptional. Even after more than 100,000 years of burial, sedge and willow leaves were still green, mollusks and gastropods showed color, beetle parts remained iridescent, fossil conifer cones were intact, and an entire beach of 20-meter-long driftwood logs was found intact. The exquisite preservation allowed for detailed analysis of pollen, plant macrofossils, conifer cones, and fossil wood, as well as insects, chironomids, mollusks, ostracodes, and other invertebrates — all in addition to the spectacular faunal remains. This special volume of Quaternary Research represents a comprehensive scientific report of “The Snowmastodon Project,” as the investigations at the Ziegler Reservoir fossil site came to be known. Summarizing the work of scientists from more than 20 institutions, the volume details the environments in which the animals lived, provides insight into how they died, and forms the foundation of our understanding of alpine ecosystem dynamics during the last interglacial period in the Rocky Mountains.

Quaternary Research↗
USGS2023

Nitrate-stimulated release of naturally occurring sedimentary uranium

Groundwater uranium (U) concentrations have been measured above the U.S. EPA maximum contaminant level (30 μg/L) in many U.S. aquifers, including in areas not associated with anthropogenic contamination by milling or mining. In addition to carbonate, nitrate has been correlated to uranium groundwater concentrations in two major U.S. aquifers. However, to date, direct evidence that nitrate mobilizes naturally occurring U from aquifer sediments has not been presented. Here, we demonstrate that the influx of high-nitrate porewater through High Plains alluvial aquifer silt sediments bearing naturally occurring U(IV) can stimulate a nitrate-reducing microbial community capable of catalyzing the oxidation and mobilization of U into the porewater. Microbial reduction of nitrate yielded nitrite, a reactive intermediate, which was further demonstrated to abiotically mobilize U from the reduced alluvial aquifer sediments. These results indicate that microbial activity, specifically nitrate reduction to nitrite, is one mechanism driving U mobilization from aquifer sediments in addition to previously described bicarbonate-driven desorption from mineral surfaces, such as Fe(III) oxides.

Nebraska↗
USGS2006

Regional patterns in the isotopic composition of natural and anthropogenic nitrate in groundwater, High Plains, U.S.A.

Mobilization of natural nitrate (NO 3 - ) deposits in the subsoil by irrigation water in arid and semiarid regions has the potential to produce large groundwater NO 3 - concentrations. The use of isotopes to distinguish between natural and anthropogenic NO 3 - sources in these settings could be complicated by the wide range in δ 15 N values of natural NO 3 - . An ∼10 000 year record of paleorecharge from the regionally extensive High Plains aquifer indicates that δ 15 N values for NO 3 - derived from natural sources ranged from 1.3 to 12.3‰ and increased systematically from the northern to the southern High Plains. This collective range in δ 15 N values spans the range that might be interpreted as evidence for fertilizer and animal-waste sources of NO 3 - ; however, the δ 15 N values for NO 3 - in modern recharge ( less than 50 years) under irrigated fields were, for the most part, distinctly different from those of paleorecharge when viewed in the overall regional context. An inverse relation was observed between the δ 15 N[NO 3 - ] values and the NO 3 - /Cl - ratios in paleorecharge that is qualitatively consistent with fractionating losses of N increasing from north to south in the High Plains. N and O isotope data for NO 3 - are consistent with both NH 3 volatilization and denitrification, having contributed to fractionating losses of N prior to recharge. The relative importance of different isotope fractionating processes may be influenced by regional climate patterns as well as by local variation in soils, vegetation, topography, and moisture conditions.

Environmental Science & Technology↗
USGS1995

Contaminants and sea ducks in Alaska and the circumpolar region

We review nesting sea duck population declines in Alaska during recent decades and explore the possibility that contaminants may be implicated. Aerial surveys of the surf scoter (Melanitta perspicillata), white-winged scoter (M. fusca), black scoter (M. nigra), oldsqaw (Clangula hyemalis), spectacled eider (Somateria fischeri), and Steller's eider (Polysticta stellei) show long-term breeding population declines, especially the latter three species. The spectacled eider was recently classified threatened under the Endangered Species Act. In addition, three other diving ducks, which commonly winter in coastal areas, have declined from unknown causes. Large die-offs of all three species of scoters during molt, a period of high energy demand, were documented in August 1990, 1991, and 1992 at coastal reefs in southeastern Alaska. There was no evidence of infectious diseases in those scoters. The die-offs may or may not be associated with the long-term declines. Many scoters had elevated renal concentrations of cadmium (high of 375 micrograms/g dry weight [dw]). Effects of cadmium in sea ducks are not well understood. Selenium concentrations in livers of nesting white-winged scoters were high; however, the eggs they laid contained less selenium than expected based on relationships for freshwater bird species. Histological evaluation found a high prevalence of hepatocellular vacuolation (49%), a degenerative change frequently associated with sublethal toxic insult. Cadmium and selenium mean liver concentrations were generally higher in those birds with more severe vacuolation; however, relationships were not statistically significant. We do not know if sea duck population declines are related to metals or other contaminants.

Alaska↗
USGS2011

Migration of Sakhalin taimen (Parahucho perryi): Evidence of freshwater resident life history types

Sakhalin taimen ( Parahucho perryi ) range from the Russian Far East mainland along the Sea of Japan coast, and Sakhalin, Kuril, and Hokkaido Islands and are considered to primarily be an anadromous species. We used otolith strontium-to-calcium ratios (Sr/Ca) to determine the chronology of migration between freshwater and saltwater and identify migratory contingents of taimen collected from the Koppi River, Russia. In addition, we examined taimen from the Sarufutsu River, Japan and Tumnin River, Russia that were captured in marine waters. Transects of otolith Sr/Ca for the Sarufutsu River fish were consistent with patterns observed in anadromous salmonids. Two fish from the Tumnin River appeared to be recent migrants to saltwater and one fish was characterized by an otolith Sr/Ca transect consistent with marine migration. Using these transects as benchmarks, all Koppi River taimen were classified as freshwater residents. These findings suggest more work is needed to assess life history variability among locations and the role of freshwater productivity in controlling migratory behavior in taimen.

Tumnin River, Koppi River, Sarufutsu River↗
USGS2020

Soil respiration response to rainfall modulated by plant phenology in a montane meadow, East River, Colorado, USA

Soil respiration is a primary component of the terrestrial carbon cycle. However, predicting the response of soil respiration to climate change remains a challenge due to the complex interactions between environmental drivers, especially plant phenology, temperature, and soil moisture. In this study, we use a 1‐D diffusion‐reaction model to calculate depth‐resolved CO 2 production rates from soil CO 2 concentrations and surface efflux observations in a subalpine meadow in the East River watershed, CO. Modeled rates are compared to in situ soil temperature and moisture conditions and MODIS satellite enhanced vegetation index (EVI) representing plant phenology across three hydrologically distinct growing seasons from 2016–2018. While soil respiration correlated with temperature on diel timescales ( p < 0.05), seasonal variability was dominated by soil moisture and plant phenology ( p < 0.05). We observed significant respiration increases in response to precipitation events; however, magnitude and duration were significantly higher in 2017 than 2016 despite similar wetting characteristics. Based on MODIS EVI, we suggest that the respiration response to rainfall is controlled by plant phenology, which in turn reflects the capacity of plants to respond to precipitation via increased photosynthesis and autotrophic respiration, behavior that is not captured in typical soil respiration pulse models. Projected changes in montane climate such as earlier snowmelt and prolonged fore‐summer drought may decrease soil respiration fluxes by decreasing the overlap between peak productivity and the summer monsoon. Finally, we observed significant late season CO 2 fluxes from the deep subsoil (>165 cm) that support growing evidence for the importance of subsoil processes in driving integrated respiration fluxes.

Colorado↗
USGS2011

Assessment of surface-water quantity and quality, Eagle River watershed, Colorado, 1947-2007

From the early mining days to the current tourism-based economy, the Eagle River watershed (ERW) in central Colorado has undergone a sequence of land-use changes that has affected the hydrology, habitat, and water quality of the area. In 2000, the USGS, in cooperation with the Colorado River Water Conservation District, Eagle County, Eagle River Water and Sanitation District, Upper Eagle Regional Water Authority, Colorado Department of Transportation, City of Aurora, Town of Eagle, Town of Gypsum, Town of Minturn, Town of Vail, Vail Resorts, City of Colorado Springs, Colorado Springs Utilities, and Denver Water, initiated a retrospective analysis of surface-water quantity and quality in the ERW. Surface-water quantity data and surface-water quality data were obtained from local, State, and Federal agencies to assist in the analysis of surface-water conditions in the ERW 1947-2007. Surface-water-quality data from 293 sites and 12 different source agencies were compiled into 192 unique sites located on streams and rivers in the ERW. Approximately 39 percent of the unique sites had fewer than 5 samples; while 23 percent of the sites had more than 100 samples. Physical properties were the most abundant type of samples collected, with major ions, nutrients, and trace elements also commonly collected. For selected water-quality properties and constituents in the watershed, this report: (1) characterizes available water quantity and water-quality data, (2) identifies spatial and seasonal variability in water quantity and water quality, (3) provides comparisons to Federal and State water-quality standards or recommendations, (4) characterizes temporal changes in water quality, and (5) where possible, identifies potential causes of these changes. This report provides reconnaissance-level statistical summaries and comparisons of water-quality conditions and characteristics using available data within the ERW. The report also includes streamflow statistics such as: mean annual runoff totals, peak-flood-frequency recurrence intervals, and minimum 7-day mean streamflows for selected sites within the watershed. The spatial patterns for concentrations of trace metals (aluminum, cadmium, copper, iron, manganese, and zinc) indicate an increase in dissolved concentrations of these metals near historical mining areas in the Eagle River and several tributaries near Belden. In general, concentrations decrease downstream from mining areas. Concentrations typically are near or below reporting limits in Gore Creek and other tributaries within the watershed. Concentrations for trace elements (arsenic, selenium, and uranium) in the watershed usually are below the reporting limit, and no prevailing spatial patterns were observed in the data. Step-trend analysis and temporal-trend analysis provide evidence that remediation of historical mining areas in the upper Eagle River have led to observed decreases in metals concentrations in many surface-waters. Comparison of pre- and post-remediation concentrations for many metals indicates significant decreases in metals concentrations for cadmium, manganese, and zinc at sites downstream from the Eagle Mine Superfund Site. Some sites show order of magnitude reductions in median concentrations between these two periods. Evaluation of monotonic trends for dissolved metals concentrations show downward trends at numerous sites in, and downstream from, historic mining areas. The spatial pattern of nutrients shows lower concentrations on many tributaries and on the Eagle River upstream from Red Cliff with increases in nutrients downstream of major urban areas. Seasonal variations show that for many nutrient species, concentrations tend to be lowest May-June and highest January-March. The gradual changes in concentrations between seasons may be related to dilution effects from increases and decreases in streamflow. Upward trends in nutrients between the towns of Gypsum and Avon were detected for nitrate, orthophosphate, and total phosphorus. An upward trend in nitrite was detected in Gore Creek. No trends were detected in un-ionized ammonia within the ERW. Exceedances of State water-quality standards (nitrite, nitrate, and un-ionized ammonia) and levels higher than U.S. Environmental Protection Agency recommendations (total phosphorus) occur in several areas within the ERW. The majority of the exceedances are from comparisons to the U.S. Environmental Protection Agency total phosphorus recommendations. A positive correlation was observed between suspended sediment and total phosphorus. An upward trend in total dissolved solids in Gore Creek may be the result of increases in chloride salts. Highly significant trends were detected in sodium, potassium, and chloride with a significant upward trend in magnesium and a weakly significant upward trend in calcium. A quantitative analysis of the relative abundance of calcium, magnesium, sodium, and potassium to the available anions suggests that chloride salts likely are the source for the detected upward trends because chloride is the only commonly occurring anion with a trend in Gore Greek. A potential source for the observed chloride salts may be the chemical anti-icing and deicing products used during winter road maintenance in municipal areas and on Interstate-70. A downward trend in dissolved solids in the Eagle River between Gypsum and Avon may be contributing to the detected trend on the Eagle River at Gypsum. Significant downward trends were detected in specific ions such as calcium, magnesium, sulfate, and silica. Measures of total dissolved solids as well as comparisons to specific ions show that in water-quality samples within the ERW concentrations generally are lower in the headwaters, with increases downstream from Wolcott. Differences in concentrations likely result from increased abundance of salt-bearing geologic units downstream from Avon. Few sites had measured concentrations that exceeded the State standards for chloride.

Scientific Investigations Report↗