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USGS1975

Stream reconnaissance for nutrients and other water-quality parameters, Greater Pittsburgh Region, Pennsylvania

Eighty-five stream sites in and near the six-county Greater Pittsburgh Region were sampled in mid-June 1971 in mid-October 1972. Data are reported for 89 sites because 4 substitute sites were sampled in the second period. Drainage areas of the basins sampled ranged from 4.1 to 19,5000 square miles (10.6 to 50,500 square kilometres). The chemical analyses included constituents of three general classes: (1) nutrients, (2) activity indicators, and (3) dominant anions. Modification of the natural chemical and physical characteristics of the surface waters by man's activities is evident in some of the data. However, the activities are so diverse in type and in areal extent that their influence in terms of cause and effect is often obscure. Nutrient concentrations were high enough to indicate potential problems at about a quarter of the sampling sites. Temperature, dissolved oxygen, and pH values indicated a generally favorable capacity for regeneration or recovery from degradation, although a number a streams east of the Allegheny and Monongahela Rivers are marginal or lacking in the capacity. Regionally, sulfate is the dominant ion and was observed in concentrations of 40 milligrams per litre or more at 90 percent of the sites. Bicarbonate exceeded 100 milligrams per litre at 22 sites. A moderate to high degree of mineralization, as indicated by conductance readings of more than 500 micromhos per cetrimetre at half of the sampling sites, is a characteristic of the region's surface waters.

Pennsylvania↗

USGS1977

Geochemical and hydrologic data for wells and springs in thermal-spring areas of the Appalachians

Current interest in geothermal potential of thermal-spring areas in the Appalachians enhances the value of data on thermal springs and wells in these areas. This report presents maps showing locations of selected springs and wells and tables of physical and chemical data pertaining to these wells and springs. The chemical tables show compositions of gases (oxygen, nitrogen, argon, methane, carbon dioxide, and helium), isotope contents (tritium, carbon-13, and oxygen-18), trace and minor element chemical data, and concentrations of the major chemical constituents.

Water-Resources Investigations Report↗

USGS1981

Water quality of Alimagnet, Farquar, and Long Lakes in Apple Valley, Minnesota

Alimagnet, Farquar, and Long Lakes, in Apple Valley, Minnesota, were sampled from 1973-79 to determine their physical and chemical characteristics. A storm-sewer inlet to Alimagnet Lake was also sampled during two storms in 1978. The 1976-77 drought caused a more noticeable effect on the quality of the lakes than any other factor. Chloride concentrations were 10 to 15 milligrams per liter before the drought, but increased 2 to 4 times during the drought. Dissolved solids reacted similarly. Dissolved oxygen and pH were governed mainly by biological activity. In February 1977, dissolved-oxygen concentration was less than 0.5 milligrams per liter in the three lakes. Ratios between mean total nitrogen and mean total phosphorus ranged from 22:1 to 26:1. Trophic-state indices indicate that the lakes are eutrophic. Blue-green algae dominated the phytoplankton populations. Storms sampled at a storm-sewer inlet to Alimagnet Lake showed higher concentrations of chromium, copper, nickel, and zinc than of lead, arsenic, cadmium, and mercury. Total phosphorus for the September 1978 storm had a concentration of 1.7 milligrams per liter, which means that approximately 29 pounds entered the lake during the 5.5-hour sampling period.

Minnesota↗

USGS1981

Reconnaissance samplings and characterization of aquatic humic substances at the Yuma Desalting Test Facility, Arizona

Smectite clay minerals were found to be the principal compound on the surface of the cellulose-acetate, reverse-osmosis membranes at the Yuma Desalting Test Facility. These clay minerals were not present in the pumped ground water, but were blown into the conveyance canal from adjacent soils. Humic substances from the water and suspended sediments were associated with the clay films on the membrane, but no definitive results concerning their role in fouling were achieved. Microbial fouling is believed to be only a minor aspect of membrane fouling. Chemical and physical changes in humic substances were extensively studied at four points in the water-treatment process. Humic substances accounted for the largest component (over 25 percent) of organic constituents. Humic substances in the canal source water were similar to other aquatic humic substances present in natural waters. During the treatment process, these substances are brominated and decolorized. The effect of these halogenated humic substances on membrane fouling is unclear, but their presence in the reverse-osmosis product water and reverse-osmosis reject brine, along with volatile trihalomethanes, has led to environmental concerns. (USGS)

Arizona↗

USGS1982

Effects of volcanic ash on the benthic environment of a mountain stream, northern Idaho

The May 18, 1980, eruption of Mount St. Helens deposited about 15 millimeters of volcanic ash on the Big Creek basin in northern Idaho. Much of the uncompacted ash remained on hillsides a year after the eruption. Physical and chemical analyses of water samples from Big Creek collected from December 1980 to December 1981 showed no anomalies attributable to ash. Qualitative collections showed benthic invertebrates to be abundant and diverse in Big Creek. Experiments conducted in an unimpacted mountain stream revealed a small quantity of volcanic ash may be beneficial not detrimental to invertebrate communities. Benthic invertebrates were most abundant on ash-covered artificial substrates, with detritovores dominating the communities on all substrates. (USGS)

Idaho↗

USGS1986

Design, operation, and monitoring capability of an experimental artificial-recharge facility at East Meadow, Long Island, New York

Artificial recharge with tertiary-treated sewage is being tested at East Meadow to evaluate the physical and chemical effects on the groundwater system. The recharge facility contains 11 recharge basins and 5 injection wells and is designed to accept 4 million gallons of reclaimed water per day. Of the 11 basins, 7 are recently constructed and will accept 0.5 million gallons per day each. An observation manhole (12-foot inside diameter and extending 16 feet below the basin floor) was installed in each of two basins to enable monitoring and sampling of percolating reclaimed water in the unsaturated zone with instruments such as tensiometers, gravity lysimeters, thermocouples, and soil-gas samplers. Five shallow (100-feet deep) injection wells will each return 0.5 million gallons per day to the groundwater reservoir. Three types of injection-well design are being tested; the differences are in the type of gravel pack around the well screen. When clogging at the well screen occurs, redevelopment should restore the injection capability. Flow to the basins and wells is regulated by automatic flow controllers in which a desired flow rate is maintained by electronic sensors. Basins can also operate in a constant-head mode in which a specified head is maintained in the basin automatically. An observation-well network consisting of 2-inch- and 6-inch-diameter wells was installed within a 1-square-mile area at the recharge facility to monitor aquifer response and recharge. During 48 days of operation within a 17-week period (October 1982 through January 1983), 88.5 million gallons of reclaimed water was applied to the shallow water table aquifer through the recharge basins. A 4.29-foot-high groundwater mound developed during a 14-day test; some water level increase associated with the mound was detected 1,000 ft from the basins. Preliminary water quality data from wells affected by reclaimed water show evidence that mechanisms of mixing, dilution, and dispersion are affecting chemical concentrations of certain constituents, such as nitrogen and trichloroethane, in the shallow aquifer beneath the recharge area. (USGS)

Water-Resources Investigations Report↗

USGS1985

A gazetteer of surface-mine lakes, Eastern Interior Coal Province, Illinois

Hundreds of lakes have been formed as a result of surface mining in Area 35 of the Eastern Interior Coal Province in Illinois. This gazetteer contains physical and chemical data from 107 surface-mine lakes sampled from June through August 1983. Information collected includes location, morphology, and vertical profile measurements of water quality of the lakes. Sampled lakes range in size from 8.8 to 210 acres, and are from 4.0 to 92.0 feet deep. Maximum widths range from 0.03 to 0.35 mile, and maximum lengths range from 0.27 to 3.08 miles. Some lake waters were stratified, whereas others were completely mixed. General water quality differed widely among the lakes. Specific conductances ranged from 130 to 7,800 micromhos per centimeter (at 25 degrees Celsius). Specific conductances of 2 ,000 to 5,000 micromhos per centimeter were most prevalent. The pH values ranged from 1.8 to 9.6 at the surface, whereas bottom measurements ranged from 2.0 to 8.5. Water temperatures near the surface ranged from 22.5 degrees Celsius in June to 34.5 degrees Celsius in August. Dissolved-oxygen concentrations differed greatly among the lakes; concentrations near the surface ranged from 6.0 to 13.2 milligrams per liter. Transparencies ranged from 0.3 to 35.4 feet. (USGS)

Water-Resources Investigations Report↗

USGS1989

Water quality in Reedy Fork and Buffalo Creek basins in the Greensboro area, North Carolina, 1986-87

Water and bottom-sediment samples were collected from April 1986 through September 1987 at 19 sites in Guilford County and the City of Greensboro, North Carolina. Sampling locations included 13 stream sites, two lakes that supply the City of Greensboro with drinking water, two City of Greensboro finished drinking-water filtration plants, and effluent from the two municipal wastewater plants prior to outfall into receiving streams. Water sampling consisted of six surveys during various stages of steady ground-water flow at all sites and high-flow-event sampling during two storms at six sites. Bottom-sediment samples were collected at three sites during two routine sampling surveys. A summary of nearly 22, 000 separate chemical or physical analyses of water samples or bottom sediment is presented and discussed as individual values, ranges of values, or median values with respect to the locations of sampling sites, streamflow conditions, or other information bearing on water-quality conditions under discussion. The results include discussions of general water-quality indicators; major ion, nutrient, and trace-element concentrations; acid and base/neutral extractable organic compounds; volatile organic compounds; and organochlorine and organophosphorus pesticides detected at each sampling site. Loadings of selected constituents are also estimated on a yearly and daily basis. The quality of the raw and finished water, municipal effluents, and streams in the Greensboro area are characterized by using State and Federal water-quality standards. Inorganic constituents most commonly found in excess of standards were iron, copper, zinc, arsenic, phosphorus, manganese, cyanide, and mercury. Relatively few organic compounds were detected; however, those consistently reported were phthalate, thihalomethane, organophosphorus pesticide, benzol, and phenolic compounds. Selected inorganic, physical, and total organic carbon data are used in a Wilcoxon test for two independent variables to statistically compare water-quality characteristics in selected rural, semideveloped and urban basins. During low-flow sampling, the constituents that differed significantly among all sites were calcium, magnesium, and chloride. During low flows, concentrations of orthophosphate, fluoride, sulfate, and TOC differed at the urban site from the rural and semideveloped and urban sites. There were no significant differences among sites in concentrations of sodium, suspended sediment, nickel, zinc, copper, and mercury during low flows. The Wilcoxon test performed on high-flow data indicated that concentrations of TOC, chloride, sulfate, suspended sediment, and nickel were not significantly different among the sites.

North Carolina↗

USGS1994

Surface-water-quality assessment of the Kentucky River Basin, Kentucky: Fixed-station network and selected water-quality data, April 1987 through August 1991

This report describes selected data-collection activities and the associated data collected during the Kentucky River Basin pilot study of the U.S. Geological Survey's National Water-Quality Assessment Program. The data are intended to provide a nationally consistent description and improved understanding of current water quality in the basin. The data were collected at seven fixed stations that represent stream cross sections where constituent transport and water-quality trends can be evaluated. The report includes descriptions of (1) the basin; (2) the design of the fixed-station network; (3) the fixed-station sites; (4) the physical and chemical measurements; (5) the methods of sample collection, processing, and analysis; and (6) the quality-assurance and quality-control procedures. Water-quality data collected at the fixed stations during routine periodic sampling and supplemental high-flow sampling from April 1987 to August 1991 are presented.

Kentucky↗

USGS1995

Quality of water and chemistry of bottom sediment in the Rillito Creek basin, Tucson, Arizona, 1992-93

Physical and chemical data were collected from four surface-water sites, six ground-water sites, and two bottom-sediment sites during 1992-93. Specific conductance, hardness, alkalinity, and dissolved- solids concentrations generally were higher in ground water than in surface water. The median concentrations of dissolved major ions, with the exception of potassium, were higher in ground water than in surface water. In surface water and ground water, calcium was the dominant cation, and bicarbonate was the dominant anion. Concentrations of dissolved nitrite and nitrite plus nitrate in surface water and ground water did not exceed the U.S. Environmental Protection Agency maximum contaminant levels of 1 and 10 milligrams per liter for drinking water, respectively. Ammonium plus organic nitrogen in bottom sediment was detected at the highest concentration of any nitrogen species. Median values for most of the dissolved trace elements in surface water and ground water were below the detection levels. Dissolved trace elements in surface water and ground water did not exceed the U.S. Environmental Protection Agency maximum contaminant levels for drinking water. Trace-element concentrations in bottom sediment were similar to trace-element concentrations reported for soils of the western conterminous United States. Several organochlorine pesticides and priority pollutants were detected in surface-water and bottom-sediment samples; however, they did not exceed water-quality standards. Pesticides or priority pollutants were not detected in ground-water samples.

Water-Resources Investigations Report↗

USGS1995

Quality of surface water and ground water in the proposed artificial-recharge project area, Rillito Creek basin, Tucson, Arizona, 1994

Controlled artificial recharge of surface runoff is being considered as a water-management technique to address the problem of ground-water overdraft. The planned use of recharge facilities in urban areas has caused concern about the quality of urban runoff to be recharged and the potential for ground-water contamination. The proposed recharge facility in Rillito Creek will utilize runoff entering a 1-mile reach of the Rillito Creek between Craycroft Road and Swan Road for infiltration and recharge purposes within the channel and excavated overbank areas. Physical and chemical data were collected from two surface-water and two ground-water sites in the study area in 1994. Analyses of surface-water samples were done to determine the occurrence and concentration of potential contaminants and to determine changes in quality since samples were collected during 1987-93. Analyses of ground-water samples were done to determine the variability of ground-water quality at the monitoring wells throughout the year and to determine changes in quality since samples were collected in 1989 and 1993. Surface-water samples were collected from Tanque Verde Creek at Sabino Canyon Road (streamflow-gaging station Tanque Verde Creek at Tucson, 09484500) and from Alamo Wash at Fort Lowell Road in September and May 1994, respectively. Ground-water samples were collected from monitoring wells (D- 13-14)26cbb2 and (D-13-14)26dcb2 in January, May, July, and October 1994. In surface water, calcium was the dominant cation, and bicarbonate was the dominant anion. In ground water, calcium and sodium were the dominant cations and bicarbonate was the dominant anion. Surface water in the area is soft, and ground water is moderately hard to hard. In surface water and ground water, nitrogen was found predominantly as nitrate. Concentrations of manganese in ground-water samples ranged from 60 to 230 micrograms per liter and exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level for drinking water of 50 micrograms per liter. None of the constituents in surface-water and ground-water samples exceeded the U.S. Environmental Protection Agency primary maximum contaminant levels for drinking water or State of Arizona aquifer water-quality standards. Concentrations of major ions, nutrients, and trace elements in water from the monitoring wells did not vary significantly throughout the year and were not significantly different from concentrations in samples collected in March 1989 and January and September 1993. Priority pollutants were not found in surface-water samples or ground-water samples, and organochlorine pesticides were not found in ground-water samples. Dieldrin and biphenyl polychlor were the only pesticides found in surface water and were at the minimum reporting levels in one sample from Alamo Wash.

Water-Resources Investigations Report↗

USGS1996

Hydrogeologic setting and simulation of pesticide fate and transport in the unsaturated zone of a regolith-mantled, carbonate-rock terrain near Newville, Pennsylvania

Physical and chemical data were collected from May 1991 through April 1993 at a 4.5 hectare field site in Cumberland County, Pa., about 5 kilometers southeast of Newville. These data were used to define the hydrogeologic setting of a field site representative of the intensively farmed carbonate valleys of southeastern and south-central Pennsylvania. The environmental processing of commonly used pesticides (herbicides, fungicides, and insecticides) in the unsaturated zone was simulated with a process- oriented digital model to evaluate the environmental fate and transport of pesticides to ground water. Site data and modelling results provide a basis for a discussion of water-quality implications of agricultural best-management practices. The carbonate valleys of Pennsylvania comprise regolith-mantled carbonate-rock terrains that consist of broad undulating upland areas dissected by mostly dry valleys and widely spaced spring-fed creeks. The upland areas are farmed and exhibit possess a doline karst topography with many closed depressions, sinkholes, and bedrock outcrops. Unsaturated materials at the field site consist of an almost continuous soil cover composed of fine-grained residuum underlain by an intermediate vadose zone composed of karstified limestone. Soils are absent on scattered bedrock outcrops and are more than 12 meters thick in other areas of the site. The soil profile stores appreciable quantities of water with a volumetric average of about 36 percent water at field capacity. Organic carbon content of soil materials is about 1.7 percent in the Ap-horizon and from 0.1 to 0.3 percent throughout the full thickness of the B- and C-horizons. Atrazine, metolachlor, simazine, and the atrazine soil metabolites deethylatrazine and deisopropylatrazine were detected at concentrations above 0.05 mg/L in just the upper 0.6 meters of soil materials. However, detectable concentrations of atrazine, simazine, and atrazine soil metabolites were measured in water samples from lysimeters installed in soil materials at depths of 1.2, 2.1, and 3.7 meters and from monitor wells completed in the saturated zone to depths of 122 meters. Data collected from the field site were used to configure a pesticide screening model based on the pesticide version of the leaching estimation and chemistry model (LEACHP) developed by Wagenet and Hutson (1987). Model simulations show that most field-applied pesticides volatilize to the atmosphere, accumulate in soils, degrade in the subsurface environment, or leach to ground water. Model results were used to rank the leaching potentials of 66 pesticides. Eighteen of 32 herbicides, 4 of 9 fungicides, and 10 of 25 insecticides have moderate to large potential for leaching to ground water. A review of available pesticide monitoring data suggests that many compounds given moderate or high leaching potentials have not been tested for in ground water and the presence of pesticides in Pennsylvania's ground water may be underreported. Monitoring data do not exist for more than two-thirds of the pesticide compounds currently used in agricultural, carbonate areas of Pennsylvania. Knowledge of processes that govern fate and transport of pesticides is needed to facilitate development of effective pesticide best-management practices. In addition to comprehensive monitoring for pesticides and pesticide degradation products in ground water downgradient of areas of pesticide use, improved (1) characterization of unsaturated flow and transport through regolith mantled carbonate rocks, (2) estimates of pesticide degradation rates, (3) understanding of soil-property controls on pesticide movement, and (4) management models developed from process-oriented research would aid in understanding the processes.

Water-Resources Investigations Report↗

USGS1997

Effects of urbanization on water quality in the Kansas River, Shunganunga Creek Basin, and Soldier Creek, Topeka, Kansas, October 1993 through September 1995

A study of urban-related water-qulity effects in the Kansas River, Shunganunga Creek Basin, and Soldier Creek in Topeka, Kansas, was conducted from October 1993 through September 1995. The purpose of this report is to assess the effects of urbanization on instream concentrations of selected physical and chemical constituents within the city of Topeka. A network of seven sampling sites was established in the study area. Samples principally were collected at monthly intervals from the Kansas River and from the Shunganunga Creek Basin, and at quarterly intervals from Soldier Creek. The effects of urbanization werestatistically evaluated from differences in constituent concentrations between sites on the same stream. No significant differences in median concentrations of dissolved solids, nutrients, or metals and trace elements, or median densities offecal bacteria were documented between sampling sites upstream and downstream from the major urbanized length of the Kansas River in Topeka.Discharge from the city's primary wastewater- treatment plant is the largest potential source of contamination to the Kansas River. This discharge increased concentrations of dissolved ammonia, totalphosphorus, and densities of fecal bacteria.Calculated dissolved ammonia as nitrogen concentrations in water from the Kansas River ranged from 0.03 to 1.1 milligrams per liter after receiving treatment-plant discharge. However, most of the calculated concentrations wereconsiderably less than 50 percent of Kansas Department of Health and Environment water- quality criteria, with a median value of 20 percent.Generally, treatment-plant discharge increased calculated total phosphorus concentrations in water from the Kansas River by 0.01 to 0.04 milligrams per liter, with a median percentage increase of 7.6 percent. The calculated median densities of fecal coliform and fecal Streptococci bacteria in water from the Kansas River increased from 120 and 150colonies per 100 milliliters of water, respectively, before treatment-plant discharge to a calculated 4,900 and 4,700 colonies per 100 milliliters of water, respectively, after discharge. Median concentrations of dissolved solids were not significantly different between three sampling sites in the Shunganunga Creek Basin. Median concentrations of dissolved nitrate as nitrogen, total phosphorus, and dissolved orthophosphate were significantly larger in water from the upstream- most Shunganunga Creek sampling site than in water from either of the other sampling sites in the Shunganunga Creek Basin probably because of the site's proximity to a wastewater-treatment plant.Median concentrations of dissolved nitrate as nitrogen and total phosphorus during 1993-95 at upstream sampling sites were either significantlylarger than during 1979-81 in response to increase of wastewater-treatment plant discharge or smaller because of the elimination of wastewater-treatment plant discharge. Median concentrations of dissolved ammonia as nitrogen were significantly less during 1993-95 than during 1979-81. Median concentrations of total aluminum, iron, maganese, and molybdenum were significantly larger in water from the downstream-mostShunganunga Creek sampling site than in water from the upstream-most sampling site. This probably reflects their widespread use in the urbanenvironment between the upstream and downstream Shunganunga Creek sampling sites. Little water-quality effect from the urbanization was indicated by results from the Soldier Creek sampling site. Median concentrations of most water-quality constituents in water from this sampling site were the smallest in water from any sampling site in the study area. Herbicides were detected in water from all sampling sites. Some of the more frequently detected herbicides included acetochlor, alachlor,atrazine, cyanazine, EPTC, metolachlor, prometon, simazine, and tebuthiuron. Detected insecticides including chlordane,

Water-Resources Investigations Report↗

USGS1998

Nitrate and pesticides in ground water in the eastern San Joaquin Valley, California : Occurrence and trends

The occurrence of nitrate and pesticides in ground water in California's eastern San Joaquin Valley may be greatly influenced by the long history of intensive farming and irrigation and the generally permeable sediments. This study, which is part of the U.S. Geological Survey National Water-Quality Assessment Program, was done to assess the quality of the ground water and to do a preliminary evaluation of the temporal trends in nitrate and pesticides in the alluvial fans of the eastern San Joaquin Valley. Ground-water samples were collected from 30 domestic wells in 1995 (each well was sampled once during 1995). The results of the analyses of these samples were related to various physical and chemical factors in an attempt to understand the processes that control the occurrence and the concentrations of nitrate and pesticides. A preliminary evaluation of the temporal trends in the occurrence and the concentration of nitrate and pesticides was done by comparing the results of the analyses of the 1995 ground-water samples with the results of the analyses of the samples collected in 1986-87 as part of the U.S. Geological Survey Regional Aquifer-System Analysis Program. Nitrate concentrations (dissolved nitrate plus nitrite, as nitrogen) in ground water sampled in 1995 ranged from less than 0.05 to 34 milligrams per liter, with a median concentration of 4.6 milligrams per liter. Nitrate concentrations exceeded the maximum contaminant level of 10 milligrams per liter (as nitrogen) in 5 of the 30 ground-water samples (17 percent), whereas 12 of the 30 samples (40 percent) had nitrate concentrations less than 3.0 milligrams per liter. The high nitrate concentrations were associated with recently recharged, well-oxygenated ground water that has been affected by agriculture (indicated by the positive correlations between nitrate, dissolved-oxygen, tritium, and specific conductance). Twelve pesticides were detected in 21 of the 30 ground-water samples (70 percent) in 1995, although only 5 pesticides were detected in more than 10 percent of the ground-water samples. All 12 pesticides were detected at concentrations below the maximum contaminant levels, except the banned soil fumigants 1,2-dibromo-3-chloropropane (3 detections) and 1,2-dibromoethane (1 detection). Atrazine and desethyl atrazine (a transformation product of atrazine) were the most frequently detected pesticides; they were detected in 11 ground-water samples. The frequent detections of atrazine and desethyl atrazine may be related either to past applications of atrazine or to recent application on rights-of-way. Simazine was detected in 10 ground-water samples and diuron was detected in 4 ground-water samples. The detections of simazine and diuron are generally consistent with their reported applications on the crops near the wells where they were detected. 1,2,3-trichloropropane, a manufacturing by-product of 1,2-dichloropropane and 1,3- dichloropropene formulations, was detected in 4 ground-water samples. The occurrence of 1,2,3-trichloropropane, 1,2-dibromo-3-chloropropane, and 1,2-dibromoethane is probably related to past use. Similar to nitrate concentrations, pesticide occurrence was positively correlated to dissolved-oxygen concentrations, indicating that areas with high dissolved-oxygen concentrations may be vulnerable to contamination by nitrate and pesticides. High dissolved-oxygen concentrations may be associated with water that has been rapidly recharged. A comparison of the concentrations and the occurrence of nitrate and pesticides between 1986-87 and 1995 indicates that nitrate concentrations may pose a greater threat to the quality of the ground-water resource in this region than pesticides, in the context of current drinking-water standards. Nitrate concentrations were significantly higher in the 1995 ground-water samples than in the 1986-87 samples collected from the same wells.

Calfornia↗

USGS1988

Hydrology and ecology of the Apalachicola River, Florida : a summary of the river quality assessment

During 1979-81, the U.S. Geological Survey conducted a large-scale study of the Apalachicola River in northwest Florida, the largest and one of the most economically important rivers in the State. Termed the Apalachicola River Quality Assessment, the study emphasized interrelations among hydrodynamics, the flood-plain forest, and the nutrient-detritus flow through the river system to the estuary. This report summarizes major findings of the study. Data on accumulation of toxic substances in sediments and benthic organisms in the river were also collected. Because of the multiple uses of the Apalachicola River system, there are many difficult management decisions. The river is a waterway for shipping; hence there is an economic incentive for modification to facilitate movement of barge traffic. Such modifications include the proposed construction of dams, levees, bend easings, and training dikes; ditching and draining in the flood plain; and dredging and snagging in the river channel. The river is also recognized as an important supplier of detritus, nutrients, and freshwater to the Apalachicola Bay, which maintains an economically important shellfish industry. The importance of this input to the bay creates an incentive to keep the river basin in a natural state. Other values, such as timber harvesting, recreation, sport hunting, nature appreciation, and wildlife habitat, add even more to the difficulty of selecting management strategies. Water and nutrient budgets based on data collected during the river assessment study indicate the relative importance of various inputs and outflows in the system. Waterflow is controlled primarily by rainfall in upstream watersheds and is not greatly affected by local precipitation, ground-water exchanges, or evapotranspiration in the basin. On an annual basis, the total nutrient inflow to the system is nearly equal in quantity to total outflow, but there is a difference between inflow and outflow in the chemical and physical forms in which the nutrients are carried. The flood plain tends to be a net importer of soluble inorganic nutrients and a net exporter of particulate organic material. Analysis of long-term records shows that dam construction in the upstream watersheds and at the Apalachicola headwaters has had little effect on the total annual waterflow but has probably suppressed low-flow extremes. Other effects include riverbed degradation and channelization which have to do with alteration of the habitat for aquatic biota and changes in flood-plain vegetation. Whatever management decisions are made should take into account the impact on the natural flooding cycle. Flooding is crucial to the present flood-plain plant community and to the production, decomposition, and transport of organic material from that community. Permanent, substantial changes in the natural flooding cycle would be likely to induce concomitant changes in the flood-plain environment and in the nutrient and detritus yield to the estuary.

Water Supply Paper↗

USGS1999

Surface-water-quality assessment of the Yakima River basin, Washington. Distribution of pesticides and other organic compounds in water, sediment, and aquatic biota, 1987-91: With a section on dissolved organic carbon in the Yakima River basin

During 1987-91, chemical data were collected for pesticides and other organic compounds in surface water, streambed sediment, suspended sediment, agricultural soil, and aquatic biota to determine the occurrence, distribution, transport, and fate of organic compounds in the Yakima River basin in Washington. The report describes the chemical and physical properties of the compounds most frequently detected in the water column; organochlorine compounds including DDT, organophosphorus compounds, thiocarbamate and sulfite compounds, acetamide and triazine compounds, and chlorophenoxy-acetic acid and benzoic compounds. Concentrations are evaluated relative to chronic-toxicity water quality criteria and guidelines for the protection of human health and freshwater aquatic life.

Washington↗

USGS1996

Hydrology and geochemistry of aquifer and stream contamination related to acidic water in Pinal Creek basin near Globe, Arizona

Hydrologic and geochemical research has identified and characterized the physical and chemical processes that control the evolution and movement of metal contaminants in ground water beneath Miami Wash and lower Pinal Creek. The dissolution of calcite in the alluvial aquifer has slowed and neutralized part of the acidic plume, and the sorption of some metals such as nickel and copper to other solids in the subsurface has lowered concentrations of these metals in the ground water.

Arizona↗

USGS2020

Characterization of feed coals and coal combustion byproducts from the Wyodak-Anderson coal zone, Powder River Basin, Wyoming

The U.S. Geological Survey (USGS) determined the physical and chemical properties of more than 260 feed coal and coal combustion byproducts from two coal-fired power plants. These plants utilized a low-sulfur (0.23-0.47 wt. % S) and low ash (4.9-6.3 wt. % ash) subbituminous coal from the Wyodak-Anderson coal zone in the Tongue River Member of the Paleocene Fort Union Formation, Powder River Basin, Wyoming. Fifty-three samples of bituminous coal were collected and analyzed from a Kentucky power plant, which used several sources of bituminous coals from the Appalachian and Illinois Basins. Based on scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses of feed coal samples collected and analyzed from 1996 through the late 2000s, two mineral suites were identified: (1) a primary or detrital suite consisting of quartz (including beta-form grains), biotite, feldspar, and minor zircon; and (2) a secondary authigenic mineral suite containing alumino-phosphates (crandallite and gorceixite), kaolinite, carbonates (calcite and dolomite), quartz, anatase, barite, and pyrite. The detrital mineral suite is interpreted, in part, to be of volcanic origin, whereas the authigenic mineral suite is interpreted, in part, to be the result of the alteration of the volcanic minerals. The mineral suites have contributed to the higher amounts of barium, calcium, magnesium, phosphorus, sodium, strontium, and titanium in the Powder River Basin feed coals in comparison to eastern US coals. XRD analysis indicates that (1) fly ash is mostly aluminate glass, perovskite, lime, gehlenite, quartz, and phosphates with minor amounts of periclase, anhydrite, hematite, and spinel group minerals; and (2) bottom ash is predominantly quartz, plagioclase (albite and anorthite), pyroxene (augite and fassaite), rhodonite, and akermanite, and spinel group minerals. Microprobe and SEM analyses of fly ash samples revealed quartz, zircon, and monazite, euhedral laths of corundum with merrillite, hematite, dendritic spinels/ferrites, wollastonite, and periclase. The abundant calcium and magnesium mineral phases in the fly ash are attributed to the alteration of carbonate, clay, and phosphate minerals in the feed coal during combustion. The calcium- and magnesium-rich and alumino-phosphate mineral phases in the coal combustion byproducts can be attributed to volcanic minerals deposited in peat-forming mires. Dissolution and alteration of these detrital volcanic minerals occurred either in the peat-forming stage or during coalification and diagenesis, resulting in the authigenic mineral suite. The presence of free lime (CaO) in fly ash produced from Wyodak-Anderson coal acts as a self-contained “scrubber” for SO 3 , where CaO + SO 3 form anhydrite either during combustion or in the upper parts of the boiler. Considering the high lime content in the fly ash and the resulting hydration reactions after its contact with water, there is little evidence that major amounts of leachable metals are mobilized in the disposal or utilization of this fly ash.

Wyoming↗