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Measuring the impacts of natural amenities and the US-Mexico Border, on housing values in the Santa Cruz Watershed, using spatially-weighted hedonic modeling

Assessing the sustainability of International policy or urban development requires consideration of the impacts of these decisions on Ecosystem Services, or the values that humans receive from the ecosystem, including market-land price, environmental, and human well-being values. Hedonic modeling helps to identify the market land price, considering the price is determined by multiple factors affecting it. In U.S. portions of the bi-national Santa Cruz Watershed (SCW), situated at the Arizona-Sonora International border, natural amenities like the riparian corridor and green space have been documented as positive amenities that boost local real estate. The goal of this research is to isolate the effects of the US-Mexico border and known environmental or natural amenities or disamenities on housing prices in the binational watershed, while controlling for housing stock characteristics and social-environmental vulnerability. In the ultimate analysis, the mean house values within census blocks will be used to represent local housing stock. A human well-being index that measures people’s socio-environmental vulnerability for the entire SCW is in publication that is based on access to infrastructure, number of bedrooms per house and other social data from the binational census and local colonias database will also be compared. The hedonic pricing method will be applied to statistically estimate a function that relates property values to the variables described. This presentation will provide a synopsis of the quality of life and hedonics literature review used to develop this research agenda. Variables relevant for local environmental management, having significant effects on property values, will be discussed. The final results obtained from this study can be used determine the benefits of preserving or developing land binationally and will be uploaded to the Santa Cruz Watershed Ecosystem Portfolio Model (SCWEPM), an online Ecosystem Services tool, being created to promote sustainable development in the Borderlands.

Conference Paper↗

Methodology for estimating times of remediation associated with monitored natural attenuation

Natural attenuation processes combine to disperse, immobilize, and biologically transform anthropogenic contaminants, such as petroleum hydrocarbons and chlorinated ethenes, in ground-water systems. The time required for these processes to lower contaminant concentrations to levels protective of human health and the environment, however, varies widely between different hydrologic systems, different chemical contaminants, and varying amounts of contaminants. This report outlines a method for estimating timeframes required for natural attenuation processes, such as dispersion, sorption, and biodegradation, to lower contaminant concentrations and mass to predetermined regulatory goals in groundwater systems. The time-of-remediation (TOR) problem described in this report is formulated as three interactive components: (1) estimating the length of a contaminant plume once it has achieved a steady-state configuration from a source area of constant contaminant concentration, (2) estimating the time required for a plume to shrink to a smaller, regulatoryacceptable configuration when source-area contaminant concentrations are lowered by engineered methods, and (3) estimating the time needed for nonaqueous phase liquid (NAPL) contaminants to dissolve, disperse, and biodegrade below predetermined levels in contaminant source areas. This conceptualization was used to develop Natural Attenuation Software (NAS), an interactive computer aquifers. NAS was designed as a screening tool and requires the input of detailed site information about hydrogeology, redox conditions, and the distribution of contaminants. Because NAS is based on numerous simplifications of hydrologic, microbial, and geochemical processes, the program may introduce unacceptable errors for highly heterogeneous hydrologic systems. In such cases, application of the TOR framework outlined in this report may require more detailed, site-specific digital modeling. The NAS software may be downloaded from the Web site http://www.cee.vt.edu/NAS/ Application of NAS illustrates several general characteristics shared by all TOR problems. First, the distance of stabilization of a contaminant plume is strongly dependent on the natural attenuation capacity of particular ground-water systems. The time that it takes a plume to reach a steady-state configuration, however, is independent of natural attenuation capacity. Rather, the time of stabilization is most strongly affected by the sorptive capacity of the aquifer, which is dependent on the organic matter content of the aquifer sediments, as well as the sorptive properties of individual contaminants. As a general rule, a high sorptive capacity retards a plume.s growth or shrinkage, and increases the time of stabilization. Finally, the time of NAPL dissolution depends largely on NAPL mass, composition, geometry, and hydrologic factors, such as ground-water flow rates. An example TOR analysis for petroleum hydrocarbon NAPL was performed for the Laurel Bay site in South Carolina. About 500 to 1,000 pounds of gasoline leaked into the aquifer at this site in 1991, and the NAS simulations suggested that TOR would be on the order of 10 years for soluble and poorly sorbed compounds, such as benzene and methyl tertiary-butyl ether (MTBE). Conversely, TOR would be on the order of 40 years for less soluble, more strongly sorbed compounds, such as toluene, ethylbenzene, and xylenes (TEX). These TOR estimates are roughly consistent with contaminant concentrations observed over 10 years of monitoring at this site where benzene and MTBE concentrations were observed to decrease rapidly and are approaching regulatory maximum concentration limits, whereas toluene, ethylbenzene, and xylene concentrations decreased at a slower rate and have remained relatively high. An example TOR analysis for petroleum hydrocarbon NAPL was performed for the Laurel Bay site in South Carolina.

South Carolina↗

Volcanic aquifers of Hawai‘i—Hydrogeology, water budgets, and conceptual models

Hawai‘i’s aquifers have limited capacity to store fresh groundwater because each island is small and surrounded by saltwater. Saltwater also underlies much of the fresh groundwater. Fresh groundwater resources are, therefore, particularly vulnerable to human activity, short-term climate cycles, and long-term climate change. Availability of fresh groundwater for human use is constrained by the degree to which the impacts of withdrawal—such as lowering of the water table, saltwater intrusion, and reduction in the natural discharge to springs, streams, wetlands, and submarine seeps—are deemed acceptable. This report describes the hydrogeologic framework, groundwater budgets (inflows and outflows), conceptual models of groundwater occurrence and movement, and the factors limiting groundwater availability for the largest and most populated of the Hawaiian Islands—Kaua‘i, O‘ahu, Maui, and Hawai‘i Island. The bulk of each of Hawai‘i’s islands is built of many thin lava flows erupted from shield volcanoes; the great piles of lava flows form highly permeable aquifers. In some areas, low-permeability dikes cutting across the lava flows, or low-permeability ash and soil horizons interlayered with the lava flows, can substantially alter groundwater flow. On some islands, sedimentary rocks form thick semiconfining coastal-plain deposits, locally known as caprock, that impede natural groundwater discharge to the ocean. In some regions, thick lava flows that ponded in preexisting depressions form aquifers that are much less permeable than aquifers formed by thin lava flows. Fresh groundwater inflow to Hawai‘i’s aquifers comes from recharge. For predevelopment conditions (1870), estimates of groundwater recharge from this study are 871, 675, 1,279, and 5,291 million gallons per day (Mgal/d) for Kaua‘i, O‘ahu, Maui, and Hawai‘i Island, respectively. Estimates of recharge for recent conditions (2010 land cover and 1978–2007 rainfall for Kaua‘i, O‘ahu, and Maui; 2008 land cover and 1916–1983 rainfall for Hawai‘i Island) are 875, 660, 1,308, and 6,595 Mgal/d for Kaua‘i, O‘ahu, Maui, and Hawai‘i Island, respectively. Recent recharge values differ from predevelopment recharge values by only a few percent for all islands except Hawai‘i Island, where changes in forest cover affected recharge. Spatial distribution of recharge mimics the orographic rainfall pattern—recharge is high on windward slopes and mountain peaks below the top of the trade-wind inversion. Human activity such as irrigation also contributes to recharge in some areas. Outflows from Hawai‘i’s aquifers include withdrawals from wells and natural groundwater discharge to springs, streams, wetlands, and submarine seeps. Under predevelopment conditions, groundwater withdrawal is assumed to be negligible and natural groundwater discharge probably was equal, or close, to recharge. Under recent conditions (2000–2010), groundwater withdrawal averaged 19, 209, 104, and 103 Mgal/d on Kaua‘i, O‘ahu, Maui, and Hawai‘i Island, respectively. If recent withdrawal and recharge rates are maintained until steady state is achieved, natural groundwater discharge will be reduced by an amount equal to the withdrawal rate. Total recent withdrawal for the four islands is only about 5 percent of total recharge, but about half of the withdrawal comes from O‘ahu, whereas O‘ahu receives only 7 percent of the total recharge. Effects of high withdrawals on O‘ahu cannot be mitigated by the lower withdrawals on other islands because no freshwater flows between islands. Even within an island, high withdrawals from one area cannot be completely mitigated by recharge in another area. Water-level, saltwater/freshwater-transition-zone, spring, and stream base-flow data indicate an overall reduction in storage for most areas where groundwater has been developed. Groundwater occurrence and movement in Hawai‘i’s volcanic aquifers can be described in terms of four conceptual models: (1) fresh groundwater lenses in high-permeability lava-flow aquifers, (2) aquifers with groundwater impounded by dikes, (3) thickly saturated low-permeability aquifers, and (4) perched aquifers. In Hawai‘i, most fresh groundwater withdrawn for human use comes from freshwater lenses in the dike-free high-permeability lava-flow aquifers where the principal limiting factor to groundwater availability is saltwater intrusion, but impacts of reduced natural groundwater discharge may also limit availability. Dike-impounded groundwater is common near the center of Hawaiian shield volcanoes, where water moves and is stored in permeable lava flows between the dikes; groundwater availability in these aquifers is primarily limited by storage depletion and reduction of flow to adjacent aquifers and natural groundwater discharge. Thickly saturated low-permeability aquifers have been identified on Kaua‘i and Maui; groundwater availability is primarily limited by streamflow depletion and water-table decline. Perched groundwater is postulated to exist in some areas of Hawai‘i, but store much less water than other modes ofgroundwater occurrence. Limits on groundwater availability in perched aquifers include the potential of reducing inflow to other groundwater settings and reducing natural discharge and stream seepage. Some groundwater bodies in Hawai‘i are enigmatic; consequences of groundwater development in these bodies and their relation to groundwater availability are not completely understood.

Hawai'i↗

Wildlife as valuable natural resources vs. intolerable pests: A suburban wildlife management model

Management of wildlife in suburban environments involves a complex set of interactions between both human and wildlife populations. Managers need additional tools, such as models, that can help them assess the status of wildlife populations, devise and apply management programs, and convey this information to other professionals and the public. We present a model that conceptualizes how some wildlife populations can fluctuate between extremely low (rare, threatened, or endangered status) and extremely high (overabundant) numbers over time. Changes in wildlife abundance can induce changes in human perceptions, which continually redefine species as a valuable resource to be protected versus a pest to be controlled. Management programs thatincorporate a number of approaches and promote more stable populations of wildlife avoid the problems of the resource versus pest transformation, are less costly to society, and encourage more positive and less negative interactions between humans and wildlife. We presenta case example of the beaver Castor canadensis in Massachusetts to illustrate how this model functions and can be applied. ?? 2005 Springer Science + Business Media, Inc.

Urban Ecosystems↗

Geologic history of natural coal-bed fires, Powder River basin, USA

Coal-bed fires ignited by natural processes have baked and fused overlying sediments to form clinker, a hard red or varicolored rock, through much of the northern Great Plains of the United States (USA). The gently dipping coal beds in the region burn when regional downwasting brings them above the local water table. The resulting clinker forms a rim along the exposed edge of the coal bed in an ongoing process through geologic time. The resistant clinker is left capping buttes and ridges after the softer unbaked strata erode away. Clinker outcrops cover more than 4100 km2 in the Powder River basin (PRB), which lies in Wyoming (WY) and Montana (MT). The clinker in place records tens of billions of tons of coal that have burned, releasing gases into the atmosphere. The amount of clinker that has eroded away was at least an order of magnitude greater than the clinker that remains in place. Fission-track and uranium-thorium/ helium ages of detrital zircon crystals in clinker, and paleomagnetic ages of clinker, show that coal beds have burned naturally during at least the past 4 million years (Ma). The oldest in-place clinker that has been dated, collected from a high, isolated, clinker-capped ridge, has a fission track age of 2.8??0.6 Ma. Evidence of erosion and downcutting is also preserved by clinker clasts in gravel terraces. One clinker boulder in a terrace 360 m above the Yellowstone River has a fission track age of 4.0??0.7 Ma. Coal-bed fires are caused by lightning, wildfires, spontaneous combustion, or human activity on coal outcrops and in mines. Miners, government agencies, and ranchers have extinguished thousands of coal bed fires, but natural ignition continues where fresh coal has access to air. At any given time, hundreds of fires, mostly small, are burning. In the Powder River basin, the total amount of coal burned by natural fires in the last 2 Ma is one to two orders of magnitude greater than the total amount of coal removed by mining in the past century. However, current annual rates of coal mining are three to four orders of magnitude greater than estimated prehistoric annual rates of coal consumption by natural fires. ?? 2004 Published by Elsevier B.V.

International Journal of Coal Geology↗

Endocrine-disrupting chemicals and oil and natural gas operations: Potential environmental contamination and recommendations to assess complex environmental mixtures

Background : Hydraulic fracturing technologies, developed over the last 65 years, have only recently been combined with horizontal drilling to unlock oil and gas reserves previously deemed inaccessible. While these technologies have dramatically increased domestic oil and natural gas production, they have also raised concerns for the potential contamination of local water supplies with the approximately 1,000 chemicals used throughout the process, including many known or suspected endocrine-disrupting chemicals. Objectives : We discuss the need for an endocrine component to health assessments for drilling-dense regions in the context of hormonal and anti-hormonal activities for chemicals used. Methods : We discuss the literature on 1) surface and ground water contamination by oil and gas extraction operations, and 2) potential human exposure, particularly in context of the total hormonal and anti-hormonal activities present in surface and ground water from natural and anthropogenic sources, with initial analytical results and critical knowledge gaps discussed. Discussion : In light of the potential for environmental release of oil and gas chemicals that can disrupt hormone receptor systems, we recommend methods for assessing complex hormonally active environmental mixtures. Conclusions : We describe a need for an endocrine-centric component for overall health assessments and provide supporting information that using this may help explain reported adverse health trends as well as help develop recommendations for environmental impact assessments and monitoring programs.

Environmental Health Perspectives↗

A synthesis of patterns of environmental mercury inputs, exposure and effects in New York State

Mercury (Hg) pollution is an environmental problem that adversely affects human and ecosystem health at local, regional, and global scales—including within New York State. More than two-thirds of the Hg currently released to the environment originates, either directly or indirectly, from human activities. Since the early 1800s, global atmospheric Hg concentrations have increased by three- to eight-fold over natural levels. In the U.S., atmospheric emissions and point-source releases to waterways increased following industrialization into the mid-1980s. Since then, water discharges have largely been curtailed. As a result, Hg emissions, atmospheric concentrations, and deposition over the past few decades have declined across the eastern U.S. Despite these decreases, Hg pollution persists. To inform policy efforts and to advance public understanding, the New York State Energy Research and Development Authority (NYSERDA) sponsored a scientific synthesis of information on Hg in New York State. This effort includes 23 papers focused on Hg in atmospheric deposition, water, fish, and wildlife published in Ecotoxicology . New York State experiences Hg contamination largely due to atmospheric deposition. Some landscapes are inherently sensitive to Hg inputs driven by the transport of inorganic Hg to zones of methylation, the conversion of inorganic Hg to methylmercury, and the bioaccumulation and biomagnification along food webs. Mercury concentrations exceed human and ecological risk thresholds in many areas of New York State, particularly the Adirondacks, Catskills, and parts of Long Island. Mercury concentrations in some biota have declined in the Eastern Great Lakes Lowlands and the Northeastern Highlands over the last four decades, concurrent with decreases in water releases and air emissions from regional and U.S. sources. However, widespread changes have not occurred in other ecoregions of New York State. While the timing and magnitude of the response of Hg levels in biota varies, policies expected to further diminish Hg emissions should continue to decrease Hg concentrations in food webs, yielding benefits to the fish, wildlife, and people of New York State. Anticipated improvements in the Hg status of aquatic ecosystems are likely to be greatest for inland surface waters and should be roughly proportional to declines in atmospheric Hg deposition. Efforts that advance recovery from Hg pollution in recent years have yielded significant progress, but Hg remains a pollutant of concern. Indeed, due to this extensive compilation of Hg observations in biota, it appears that the extent and intensity of the contamination on the New York landscape and waterscape is greater than previously recognized. Understanding the extent of Hg contamination and recovery following decreases in atmospheric Hg deposition will require further study, underscoring the need to continue existing monitoring efforts.

New York↗

2011 floods of the central United States

The Central United States experienced record-setting flooding during 2011, with floods that extended from headwater streams in the Rocky Mountains, to transboundary rivers in the upper Midwest and Northern Plains, to the deep and wide sand-bedded lower Mississippi River. The U.S. Geological Survey (USGS), as part of its mission, collected extensive information during and in the aftermath of the 2011 floods to support scientific analysis of the origins and consequences of extreme floods. The information collected for the 2011 floods, combined with decades of past data, enables scientists and engineers from the USGS to provide syntheses and scientific analyses to inform emergency managers, planners, and policy makers about life-safety, economic, and environmental-health issues surrounding flood hazards for the 2011 floods and future floods like it. USGS data, information, and scientific analyses provide context and understanding of the effect of floods on complex societal issues such as ecosystem and human health, flood-plain management, climate-change adaptation, economic security, and the associated policies enacted for mitigation. Among the largest societal questions is "How do we balance agricultural, economic, life-safety, and environmental needs in and along our rivers?" To address this issue, many scientific questions have to be answered including the following: * How do the 2011 weather and flood conditions compare to the past weather and flood conditions and what can we reasonably expect in the future for flood magnitudes? * What is the “natural” hydrology of these watersheds and how have they been changed? * How do rivers change during floods and what effects do they have on the natural and built environment: conversely, what effects do the natural and built environments have on rivers and floods? * Do floods contribute to the transport and fate of contaminants that affect human and ecosystem health? In an effort to help address these and other questions, USGS Professional Paper 1798 consists of independent but complementary chapters dealing with various scientific aspects of the 2011 floods in the Central United States.

Professional Paper↗

Thermal variability drives synchronicity of an aquatic insect resource pulse

Spatial heterogeneity in environmental conditions can prolong food availability by desynchronizing the timing of ephemeral, high‐magnitude resource pulses. Spatial patterns of water temperature are highly variable among rivers as determined by both natural and anthropogenic features, but the influence of this variability on freshwater resource pulse phenology is poorly documented. We quantified water temperature and emergence phenology of an aquatic insect (salmonfly, Pteronarcys californica ) resource pulse in two rivers characterized by differing catchment topography and human impact. Along both rivers, salmonfly emergence occurred earlier where spring temperatures were warmer. Emergence events were brief (4–8 d) at sites in the more human‐impacted river, but occurred asynchronously along the entire river, lasting 27 d in total. In contrast, emergence events were more prolonged (6–11 d) at sites on the more natural and topographically complex river, but occurred synchronously along the entire river, lasting 13 d in total. These scale‐specific differences in subsidy duration could have opposing consequences for salmonfly consumers depending on their mobility and foraging habits. Asynchronous emergence at a large scale is potentially most important for mobile consumers like birds and fish that can migrate to feed on aquatic insects and track resource waves across a landscape, whereas prolonged emergence duration at a smaller scale may be most important for immobile or opportunistic consumers like spiders and ants. Relating environmental heterogeneity and resource pulse phenology across a gradient of human impact and at multiple spatial scales is needed for a better understanding of how food availability, aquatic–terrestrial linkages, and consumer–resource dynamics may change with climate variability and increasing human activity in the future.

Montana↗

The distribution of uranium over Europe: Geological and environmental significance

The variation of baseline levels of uranium in soil and stream sediments over Europe is described, based on new data prepared by the Forum of European Geological Surveys (FOREGS). The samples have been collected and analysed according to the protocols established for the International Union of Geological Sciences/International Association of Geochemistry and Cosmochemistry (IUGS/IAGC) Working Group on Global Geochemical Baselines. The baseline levels of U vary between 0??21 to 53 mg kg-1 in topsoils, 0??19 to 30 mg kg-1 in subsoils and < 1 to 59 mg kg-1 in stream sediments. There is generally good agreement between the levels of U in the three sample types, and the median concentration in all three media is approximately 2 mg kg-1. The most anomalous baseline levels occur over the Variscan orogen, especially areas into which late post-orogenic radiothermal high heat production (HHP) granites were emplaced. Spiderdiagrams based on trace element levels and rare earth element (REE) plots, confirm the association between the highest U anomalies and evolved radiothermal granites. High values are also associated with parts of the Alpine terrain especially in Slovenia, where there are historical U workings, and Southern Italy, where high values of U reflect contemporary volcanism. In contrast, much of the Caledonides of North West Europe and the Precambrian of the Baltic Shield and East European craton and its overlying sedimentary cover have very low values, generally < 4 mg kg-1. The results suggest that the main concern for the environment and human health from U, and the Th and K with which it is generally associated, is the naturally occurring total gamma radiation and radon potential associated with radiothermal granites. This is likely to be especially important where the granites are mineralised and have been worked historically, for example in the North West of the Iberian Peninsula where U and its decay products are likely to be more dispersed in the surface environment. The study also indicates the value of multi-element data in distinguishing between anthropogenic and naturally occurring anomalies.

Transactions of the Institution of Mining and Meta↗

Natural disasters: forecasting economic and life losses

Events such as hurricanes, earthquakes, floods, tsunamis, volcanic eruptions, and tornadoes are natural disasters because they negatively impact society, and so they must be measured and understood in human-related terms. At the U.S. Geological Survey, we have developed a new method to examine fatality and dollar-loss data, and to make probabilistic estimates of the frequency and magnitude of future events. This information is vital to large sectors of society including disaster relief agencies and insurance companies.

Fact Sheet↗

Water-quality assessment of the Central Arizona Basins, Arizona and northern Mexico – Environmental setting and overview of water quality

The Central Arizona Basins study area in central and southern Arizona and northern Mexico is one of 60 study units that are part of the U.S. Geological Survey's National Water-Quality Assessment program. The purpose of this report is to describe the physical, chemical, and environmental characteristics that may affect water quality in the Central Arizona Basins study area and present an overview of water quality. Covering 34,700 square miles, the study area is characterized by generally north to northwestward-trending mountain ranges separated by broad, gently sloping alluvial valleys. Most of the perennial rivers and streams are in the northern part of the study area. Rivers and streams in the south are predominantly intermittent or ephemeral and flow in response to precipitation such as summer thunderstorms. Effluent-dependent streams do provide perennial flow in some reaches. The major aquifers in the study area are in the basin-fill deposits that may be as much as 12,000 feet thick. The 1990 population in the study area was about 3.45 million, and about 61 percent of the total was in Maricopa County (Phoenix and surrounding cities). Extensive population growth over the past decade has resulted in a twofold increase in urban land areas and increased municipal water use; however, agriculture remains the major water use. Seventy-three percent of all water with drawn in the study area during 1990 was used for agricultural purposes. The largest rivers in the study area-the Gila, Salt, and Verde-are perennial near their headwaters but become intermittent downstream because of impoundments and artificial diversions. As a result, the Central Arizona Basins study area is unique compared to less arid basins because the mean surface-water outflow is only 528 cubic feet per second from a total drainage area of 49,650 square miles. Peak flows in the northern part of the study area are the result of snowmelt runoff; whereas, summer thunderstorms account for the peak flows in the southern part. Ground water is the primary water supply in most of Arizona and the only source of drinking water used by communities in the southern half of the study area. Years of overpumping have caused water tables in basin fill to drop below once-perennial streams leaving streambeds dry, water too deep to pump economically, pumping of poorer quality water with depth, and earth fissures resulting from subsidence after dewatering of sediments. Natural processes-such as leaching of trace elements and major ions from geologic formations-and human activities-such as mining, agriculture, and urban development-have major effects on the quality of surface-water and ground-water resources in the Central Arizona Basins study area. Surface-water quality standards in Arizona are based on the designated use of the water such as full or partial body contact, fish consumption, aquatic and wildlife uses, and agriculture. Maintaining the biological integrity (health) of surface waters in Arizona is an important part of ensuring that these waters are suitable for designated uses. Important water-quality issues for surface water that are somewhat unique to Arizona include: (1) streamflows and riparian environments sustained by effluent from municipal wastewater-treatment plants that contains high concentrations of nutrients, potentially toxic trace elements and organic compounds, and fecal bacteria; (2) industrial, mining, agricultural, and municipal sources of contamination from Mexico; and (3) unpredictable high flows from major summer thunder storms causing stream-channel changes; high suspended-sediment concentrations and loads; sewage overflows; and breaching, erosion, and washout of landfills and mining operations. The quality of water in aquifers that are protected for drinking- water use is subject to standards that are in most cases equal to or more stringent than the primary drinking-water regulations of the U.S. Environmental Protection Agency. The general che

Arizona↗

Avian influenza

Wild birds, especially waterfowl and shorebirds, have long been a focus for concern by the poultry industry as a source for influenza infections in poultry. Human health concerns have also been raised. For these reasons, this chapter has been included to provide natural resource managers with basic information about avian influenza viruses.

Information and Technology Report↗

Mercury in the national parks

One thing is certain: Even for trained researchers, predicting mercury’s behavior in the environment is challenging. Fundamentally it is one of 98 naturally occurring elements, with natural sources, such as volcanoes, and concentrated ore deposits, such as cinnabar. Yet there are also human-caused sources, such as emissions from both coal-burning power plants and mining operations for gold and silver. There are elemental forms, inorganic or organic forms, reactive and unreactive species. Mercury is emitted, then deposited, then re-emitted—thus earning its mercurial reputation. Most importantly, however, it is ultimately transferred into food chains through processes fueled by tiny microscopic creatures: bacteria.

The George Wright Forum↗

Arsenic and mercury contamination related to historical goldmining in the Sierra Nevada, California

Arsenic (As) is a naturally occurring constituent in low-sulphide gold-quartz vein deposits, the dominant deposit type for lode mines in the Sierra Nevada Foothills (SNFH) gold (Au) province of California. Concentrations of naturally occurring mercury (Hg) in the SNFH Au province are low, but extensive use and loss of elemental Hg during amalgamation processing of ore from lode and placer Au deposits led to widespread contamination of Hg in the Sierra Nevada foothills and downstream areas, such as the Sacramento–San Joaquin Delta and San Francisco Bay. This review paper provides an overview of As and Hg contamination related to historical Au mining in the Sierra Nevada of California. It summarizes the geology, mineralogy, and geochemistry of the Au deposits, and provides information on specific areas where detailed studies have been done in association with past, ongoing, and planned remediation activities related to the environmental As and Hg contamination. Arsenic is a naturally occurring constituent in low-sulphide Au-quartz vein deposits, the dominant deposit type for lode mines in the Sierra Nevada Foothills (SNFH) Au province ( Ashley 2002 ). Because of elevated concentrations of As in accessory iron-sulphide minerals including arsenopyrite (FeAsS) and arsenian pyrite (Fe(S,As) 2 ), As is commonly a contaminant of concern in lode Au mine waste, including waste rock and mill tailings. The principal pathways of human As exposure from mine waste include ingestion of soil or drinking water, and inhalation of dust in contaminated areas ( Mitchell 2014 ). Concentrations of naturally occurring Hg in the SNFH Au province are low, but extensive use and loss of elemental Hg during amalgamation processing of ore from lode and placer Au deposits ( Churchill 2000 ) led to widespread contamination of Hg in the Sierra Nevada foothills and downstream areas, such as the Sacramento–San Joaquin Delta and San Francisco Bay ( Alpers et al. 2005 a ). Conversion of Hg to monomethylmercury (MeHg) by sulphate-reducing and iron-reducing microbes facilitates its bioaccumulation ( Wiener et al. 2003 ). The human Hg exposure pathway of main concern is ingestion of MeHg from sport (non-commercial) fish, especially higher trophic levels such as bass species ( Davis et al. 2008 ). Wildlife exposure to MeHg is also a concern because of chronic and reproductive effects, for example in fish-eating and invertebrate-foraging birds (e.g. Wiener et al. 2003 ; Eagles-Smith et al. 2009 ; Ackerman et al. 2016 ).

California↗

Modeling, mapping, and measuring the risk of freshwater invasive species across Alaska

Freshwater ecosystems of the Alaskan Arctic and Subarctic provide resources that are culturally, ecologically, and economically invaluable. Presently, these regions are relatively free of the impacts from invasive species compared to southern latitudes. To date, there have been relatively few verified introductions of aquatic invasive species (AIS) to freshwater ecosystems in Alaska. The expanding list and distribution of AIS has led to significant negative ecological and economic impacts (e.g., waterweed Elodea nuttalli ; E. canadensis and northern pike Esox Lucius introduced outside its native range in Alaska). Escalating human activity across Alaskan lands and waters, coupled with rapidly shifting environmental conditions, increases the potential for new species introductions and subsequent establishment. Creating a proactive framework for well-informed decision-making and action can improve the effectiveness of prevention efforts and bolster decision support tools that help resource managers direct limited resources. Prioritizing AIS that may be introduced and become established, as well as the locations at highest risk of invasion, is foundational to building a proactive invasive species management framework in Alaska. This project sought to identify and prioritize AIS known to be invasive in the contiguous United States, evaluate current and future habitat suitability for AIS in Alaska, and assess potential for AIS to be transported to habitats across Alaska, utilizing similar assessment methods as implemented for Bering Sea marine invasive species and non-native plants in Alaska. To accomplish this goal, the objectives of the project were to: 1) develop a formal ranked list of potential AIS to freshwater systems of Alaska; 2) assess the level of establishment risk for potential AIS by developing habitat suitability models for waterbodies across Alaska; and 3), identify potential pathways and specific vectors for high-risk AIS to invade Alaska and develop a framework for how vector analysis will be completed to understand transport risk. Overall, our goal is horizon scanning which is defined by Roy et al. (2019) as “a systematic examination of potential threats and opportunities, within a given context, and likely future developments, which are at the margin of current thinking and planning.” The scans include pathway analyses and risk screening of species present at pathway origin points, with a focus on identifying species at high risk of being introduced, becoming established, spreading, and causing harm. We refined a list of 28 AIS from a list of hundreds based on characterizations of species’ invasiveness and species’ proximity to Alaska (USGS 2020; GBIF 2022). Next, we evaluated the relative invasiveness of individual species to create an initial AIS ranking. We sought to characterize habitat suitability of AIS by selecting variables that were continental in scale, covering North America to include Alaska as well as the lower 48 states comparing natural discharge, sub-basin average terrain slope (degrees), average silt fraction, average organic carbon, lithological class, and human footprint in sub-basin in 2009. We estimated AIS habitat suitability across the entire state of Alaska using the physiological tolerances of the AIS (Appendix 2). We also evaluated pathways and vectors for the introduction of AIS (Appendix 2). Many pathways and vectors considered did not meet the criteria for Alaska or freshwater systems. Of the 28 ranked species that we categorized as very high, high, and moderate levels of invasiveness; all three risk groups included fish and mollusks (Appendix 2). One commonality of the very high-invasiveness-ranked species was the availability of Ecological Risk Screening Summary documents (USFWS, 2022) produced by U.S. Fish and Wildlife Service (USFWS), except for the goldfish ( Carassius auratus ) and the New Zealand mudsnail ( Potamopyrgus antipodarum ). The Ecological Risk Screening Summary is now available for New Zealand mudsnails. In general, fish species often ranked very high or high in invasiveness and included sportfish and aquarium fish, suggesting the importance of pathways such as aquarium trade, fishing industry, intentional (but illegal) introductions of sportfishes and aquarium fishes for establishment. The technique we used for habitat suitability models necessitated aquatic environmental datasets that were continental in scale, which was often interpolated from very coarse resolution source data layers, particularly in Alaska. Better spatial data representing aquatic environments would likely improve this approach. While the lack of introductions in Alaska and nearby provinces and states is encouraging, the lack of occurrence data for the focal species also created complications for habitat suitability modeling. Despite the challenges, the habitat suitability models indicated limited suitability for warmwater species while some species, such as Brook trout (S alvelinus fontinalis ), have high habitat suitability across Alaska no matter what threshold approach is taken. Some environmental predictors were more important than others. Specifically, the most important predictor variable, ‘frost free days,’ was critical for 15 out of 28 species as expected due to harsh winter conditions in Arctic and Subarctic regions. The second most important predictor was ‘subbasin land surface runoff’, a variable that indicates the amount of discharge and runoff, while the third most important predictor was ‘snow cover’ another indication of winter conditions. Overall, the ability to understand the effect of future climate scenarios on the establishment of AIS was challenging. A detailed dataset of freshwater temperatures and water chemistry (e.g., pH, calcium) would greatly improve the ability to predict invasiveness of freshwater species to Alaska’s ecosystems on a regional basis. Future studies may benefit from a more focused geographic scope examining a group of subbasins or a regional basin rather than the entire state. These drainages could be selected based upon the mostly likely locations of introduction pathways. The two most prevalent pathway risks for AIS are in-state transfer and stowaways/contaminants. Although there are examples of introductions from other pathways, the risk is somewhat mitigated by Alaska’s climate and regulations. However, variable application of protocols for inspection and cleaning of fishing gear, watercraft, and other similar items while traveling into Alaska as well as transferring from waterbody to waterbody within the state creates a substantial risk in introducing invasive species. We plot cumulative invasive vulnerability for all subbasins and for the top 10% of subbasins (Appendix 3).

Alaska↗

Manatee response to boating activity in a thermal refuge

Thermal refuges are important for the endangered Florida manatee (Trichechus manatus latirostris) during winter cold periods in temperate latitudes. However, little research has examined impacts on manatees from human disturbance during these critical periods. We studied the effect of recreational boating activity on manatee use of established sanctuaries in the natural thermal refuge created by warm-water springs in Kings Bay, Crystal River, Florida. We examined the relationship among manatee use of the study area and sanctuaries, temperature, and level of boating activity. Manatees continued to use the Bay regardless of the number of boats present; however, their use of sanctuaries in the southern portion of the Bay increased (P<0.001) as number of boats increased. Temperature, as expected, was inversely related to manatee use of the study area. Human activity patterns were variable, with significantly greater numbers of boats in the study area on weekends (x??=32.7, SE=2.71) than on weekdays (x??=10.7, SE=1.23). We concluded that recreational boating influenced manatee distribution, sanctuaries are important to manatees in Kings Bay, and sanctuaries are an effective management tool to reduce the impact of boating activities on manatees.

Wildlife Society Bulletin↗

Estrogen and androgen receptor activities of hydraulic fracturing chemicals and surface and ground water in a drilling-dense region

The rapid rise in natural gas extraction using hydraulic fracturing increases the potential for contamination of surface and ground water from chemicals used throughout the process. Hundreds of products containing more than 750 chemicals and components are potentially used throughout the extraction process, including more than 100 known or suspected endocrine-disrupting chemicals. We hypothesized thataselected subset of chemicalsusedin natural gas drilling operationsandalso surface and ground water samples collected in a drilling-dense region of Garfield County, Colorado, would exhibit estrogen and androgen receptor activities. Water samples were collected, solid-phase extracted, and measured for estrogen and androgen receptor activities using reporter gene assays in human cell lines. Of the 39 unique water samples, 89%, 41%, 12%, and 46% exhibited estrogenic, antiestrogenic, androgenic, and antiandrogenic activities, respectively. Testing of a subset of natural gas drilling chemicals revealed novel antiestrogenic, novel antiandrogenic, and limited estrogenic activities. The Colorado River, the drainage basin for this region, exhibited moderate levels of estrogenic, antiestrogenic, and antiandrogenic activities, suggesting that higher localized activity at sites with known natural gas–related spills surrounding the river might be contributing to the multiple receptor activities observed in this water source. The majority of water samples collected from sites in a drilling-dense region of Colorado exhibited more estrogenic, antiestrogenic, or antiandrogenic activities than reference sites with limited nearby drilling operations. Our data suggest that natural gas drilling operationsmayresult in elevated endocrine-disrupting chemical activity in surface and ground water.

Colorado↗