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1,140 records · Page 64Linked to original sources
USGS2005

Reconnaissance study of late quaternary faulting along Cerro Goden fault zone, western Puerto Rico

The Cerro Goden fault zone is associated with a curvilinear, continuous, and prominent topographic lineament in western Puerto Rico. The fault varies in strike from northwest to west. In its westernmost section, the fault is ∼500 m south of an abrupt, curvilinear mountain front separating the 270- to 361-m-high La Cadena de San Francisco range from the Rio Añasco alluvial valley. The Quaternary fault of the Añasco Valley is in alignment with the bedrock fault mapped by D. McIntyre (1971) in the Central La Plata quadrangle sheet east of Añasco Valley. Previous workers have postulated that the Cerro Goden fault zone continues southeast from the Añasco Valley and merges with the Great Southern Puerto Rico fault zone of south-central Puerto Rico. West of the Añasco Valley, the fault continues offshore into the Mona Passage (Caribbean Sea) where it is characterized by offsets of seafloor sediments estimated to be of late Quaternary age. Using both 1:18,500 scale air photographs taken in 1936 and 1:40,000 scale photographs taken by the U.S. Department of Agriculture in 1986, we identified geomorphic features suggestive of Quaternary fault movement in the Añasco Valley, including aligned and deflected drainages, apparently offset terrace risers, and mountain-facing scarps. Many of these features suggest right-lateral displacement. Mapping of Paleogene bedrock units in the uplifted La Cadena range adjacent to the Cerro Goden fault zone reveals the main tectonic events that have culminated in late Quaternary normal-oblique displacement across the Cerro Goden fault. Cretaceous to Eocene rocks of the La Cadena range exhibit large folds with wavelengths of several kms. The orientation of folds and analysis of fault striations within the folds indicate that the folds formed by northeast-southwest shortening in present-day geographic coordinates. The age of deformation is well constrained as late Eocene–early Oligocene by an angular unconformity separating folded, deep-marine middle Eocene rocks from transgressive, shallow-marine rocks of middle-upper Oligocene age. Rocks of middle Oligocene–early Pliocene age above unconformity are gently folded about the roughly east-west–trending Puerto Rico–Virgin Islands arch, which is well expressed in the geomorphology of western Puerto Rico. Arching appears ongoing because onshore and offshore late Quaternary oblique-slip faults closely parallel the complexly deformed crest of the arch and appear to be related to extensional strains focused in the crest of the arch. We estimate ∼4 km of vertical throw on the Cerro Goden fault based on the position of the carbonate cap north of the fault in the La Cadena de San Francisco and its position south of the fault inferred from seismic reflection data in Mayaguez Bay. Based on these observations, our interpretation of the kinematics and history of the Cerro Goden fault zone includes two major phases of motion: (1) Eocene northeast-southwest shortening possibly accompanied by left-lateral shearing as determined by previous workers on the Great Southern Puerto Rico fault zone; and (2) post–early Pliocene regional arching of Puerto Rico accompanied by normal offset and right-lateral shear along faults flanking the crest of the arch. The second phase of deformation accompanied east-west opening of the Mona rift and is inferred to continue to the present day.

Puerto Rico↗
USGS2022

Downhill from Austin and Ely to Las Vegas: U-Pb detrital zircon suites from the Eocene–Oligocene Titus Canyon Formation and associated strata, Death Valley, California

In a reconnaissance investigation aimed at interrogating the changing topography and paleogeography of the western United States prior to Basin and Range faulting, a preliminary study made use of U-Pb ages of detrital zircon suites from 16 samples from the Eocene–Oligocene Titus Canyon Formation, its overlying units, and correlatives near Death Valley. The Titus Canyon Formation unconformably overlies Neoproterozoic to Devonian strata in the Funeral and Grapevine Mountains of California and Nevada. Samples were collected from (1) the type area in Titus Canyon, (2) the headwaters of Monarch Canyon, and (3) unnamed Cenozoic strata exposed in a klippe of the Boundary Canyon fault in the central Funeral Mountains. Red beds and conglomerates at the base of the Titus Canyon Formation at locations 1 and 2, which contain previously reported 38–37 Ma fossils, yielded mostly Sierran batholith–age detrital zircons (defined by Triassic, Jurassic, and Cretaceous peaks). Overlying channelized fluvial sandstones, conglomerates, and minor lacustrine shale, marl, and limestone record an abrupt change in source region around 38–36 Ma or slightly later, from more local, Sierran arc–derived sediment to extraregional sources to the north. Clasts of red radiolarian-bearing chert, dark radiolarian chert, and quartzite indicate sources in the region of the Golconda and Roberts Mountains allochthons of northern Nevada. Sandstones intercalated with conglomerate contain increasing proportions of Cenozoic zircon sourced from south-migrating, caldera-forming eruptions at the latitude of Austin and Ely in Nevada with maximum depositional ages (MDAs) ranging from 36 to 24 Ma at the top of the Titus Canyon Formation. Carbonate clasts and ash-rich horizons become more prevalent in the overlying conglomeratic Panuga Formation (which contains a previously dated 15.7 Ma ash-flow tuff). The base of the higher, ash-dominated Wahguyhe Formation yielded a MDA of 14.4 Ma. The central Funeral Mountains section exposes a different sequence of units that, based on new data, are correlative to the Titus Canyon, Panuga, and Wahguyhe Formations at locations 1 and 2. An ash-flow tuff above its (unexposed) base provided a MDA of 34 Ma, and the youngest sample yielded a MDA of 12.7 Ma. The striking differences between age-correlative sections, together with map-based evidence for channelization, indicate that the Titus Canyon Formation and overlying units likely represent fluvial channel, floodplain, and lacustrine deposits as sediments mostly bypassed the region, moving south toward the Paleogene shoreline in the Mojave Desert. The profound changes in source regions and sedimentary facies documented in the Titus Canyon Formation took place during ignimbrite flareup magmatism and a proposed eastward shift of the continental divide from the axis of the Cretaceous arc to a new divide in central Nevada in response to thermal uplift and addition of magma to the crust. This uplift initiated south-flowing fluvial systems that supplied sediments to the Titus Canyon Formation and higher units.

Arizona, California, Nevada, Utah↗
USGS2010

Pesticides in groundwater in the Anacostia River and Rock Creek watersheds in Washington, D.C., 2005 and 2008

The U.S. Geological Survey (USGS), in cooperation with the District Department of the Environment, conducted a groundwater-quality investigation to (a) determine the presence, concentrations, and distribution of selected pesticides in groundwater, and (b) assess the presence of pesticides in groundwater in relation to selected landscape, hydrogeologic, and groundwater-quality characteristics in the shallow groundwater underlying the Anacostia River and Rock Creek watersheds in Washington, D.C. With one exception, well depths were 100 feet or less below land surface. The USGS obtained or compiled ancillary data and information on land use (2001), subsurface sediments, and groundwater samples from 17 wells in the lower Anacostia River watershed from September through December 2005, and from 14 wells in the lower Anacostia River and lower Rock Creek watersheds from August through September 2008. Twenty-seven pesticide compounds, reflecting at least 19 different types of pesticides, were detected in the groundwater samples obtained in 2005 and 2008. No fungicides were detected. In relation to the pesticides detected, degradate compounds were as or more likely to be detected than applied (parent) compounds. The detected pesticides chiefly reflected herbicides commonly used in urban settings for non-specific weed control or insecticides used for nonspecific haustellate insects (insects with specialized mouthparts for sucking liquid) or termite-specific control. Detected pesticides included a combination of pesticides currently (2008) in use, banned or under highly restricted use, and some that had replaced the banned or restricted-use pesticides. The presence of banned and restricted-use pesticides illustrates their continued persistence and resistance to complete degradation in the environment. The presence of the replacement pesticides indicates the susceptibility of the surficial aquifer to contamination irrespective of the changes in the pesticides used. A preliminary review of the data collected in 2005 and 2008 indicated that differences in the surficial geology, land use (as a surrogate for pesticide use), and above-average precipitation for most of 2004 through 2008, as well as differences in the number and performance of USGS laboratory methods used, could have led to more pesticides detected in groundwater samples collected in 2008 than in groundwater samples collected in 2005. Thus, although data from both years of collection were used for interpretive analysis, emphasis was placed on the analysis of the data obtained in 2008. The presence of pesticides in shallow groundwater (less than approximately 100 ft (feet), or 30 m (meters), below land surface) indicated at least the upper surficial aquifer in Washington, D.C. was susceptible to contamination. One or more herbicides or insecticides were detected in groundwater samples collected from 50 percent of the shallow wells sampled in 2005, and from 62 percent of the shallow wells sampled in 2008. Differences among types of pesticides in shallow groundwater were apparent. The most frequently detected class of herbicides was the s-triazine compounds—atrazine, simazine, or prometon, or the atrazine-degradate compounds—2-chloro-4-ethylamino-6-amino-s-triazine (desethylatrazine or CIAT) and 2-chloro-4-isopropylamino-6-amino-s-triazine (hydroxyatrazine or OIET). The next most frequently detected classes of herbicides were the chloroacetanilides, including metolachlor and acetochlor, and the ureic herbicides, including diuron (and degradate, 3,4-dichloroaniline), fluometuron, metsulfuron methyl, sulfameturon, bromacil, and tebuthiuron. Insecticides also were detected, but less frequently than herbicides, with one or more insecticides present in groundwater samples from 38 percent of shallow wells sampled in 2008. Detected insecticides included parent or degradate compounds commonly used for either nonspecific or haustellate (sucking) insects, including chlorpyrifos and dichlorodiphenyldichloroethane (p,p’-DDD; a degradate of dichlorodiphenyltrichloroethane, DDT), and for termite control, including dieldrin, chlordane, heptachlor epoxide, (a degradate of heptachlor), fipronil, and the sulfone and sulfide degradates of fipronil. The concentrations of individual pesticides in shallow groundwater in both years were low. Maximum concentrations were no greater than a few tenths of a microgram per liter (μg/L); typical concentrations often were less than 0.1 μg/L. Multiple pesticides, however, commonly were present in groundwater. For example, in 2008, approximately 88 percent (7 of 8) of the wells that yielded a sample with at least one detectable pesticide contained five or more pesticides. The highest number of detections occurred in a groundwater sample from well WE Ca 32, which is located in a highly developed urban area; this sample contained 15 different pesticide residues. In relation to human and aquatic health, no pesticide concentration in either 2005 or 2008 exceeded Federal drinking-water standards. Groundwater samples from a few sites, however, contained levels of chiefly banned or restricted-use pesticides that exceeded other human-health and (or) aquatic-health guidelines. For example, concentrations of dieldrin in 2008 groundwater samples from three wells—WE Ca 32 (0.028 μg/L), WE Ba 11 (0.016 μg/L), and WW Ac 8 (0.014 μg/L)—fell within the range of concern for 2004 Federally approved non-regulatory USGS Health-Based Assessment benchmarks (0.002 to 0.2 μg/L), and exceeded earlier (1999) Federal criteria for drinking water (0.000052 μg/L). Other individual compounds whose concentrations exceeded 1999 Federal guidelines for samples from one or more of these three sites, or another site, included p,p’-DDD, dichlorodiphenyldichloroethylene (p,p’-DDE; another degradate of DDT), chlordane, and heptachlor epoxide. Pesticide concentrations in groundwater also were compared to three aquatic-health guidelines for freshwater (United States, Great Lakes, or Canada). One or more of these guidelines were exceeded in groundwater samples obtained in 2005 or 2008 for one or more of the compounds chlordane, dieldrin, heptachlor epoxide, p,p’-DDE, p,p’-DDD, and chlorpyrifos. The spatial distribution of pesticides in the shallow groundwater appeared to be related, in part, to land use, a surrogate for pesticide use. Although most of the wells sampled in this study are in parklands or other relatively open and accessible space, multiple pesticides most often were detected in 2008 groundwater samples collected from wells where a considerable percentage (in excess of 60 percent) of the land within a 500-m radius is developed space (residential, commercial, or other urban infrastructure). Insecticides were detected in wells surrounded by at least 50 percent, and most commonly by more than 80 percent, development. Well WE Ca 32, the site associated with the highest number of pesticide residues in groundwater (8 herbicides and 7 insecticides), is in a small residential park, where 99 percent of the surrounding land is well-maintained residential and commercial development. The vertical distribution of detected pesticides in shallow groundwater appeared to be related, in part, to depth below land surface, surficial-bedrock type, and differences in the chemistry of shallow groundwater. Pesticides were detected at relatively shallow depths in wells that may not have fully penetrated the shallow aquifer. For wells in which at least one pesticide was detected, the median depth below land surface to the top of the well screen was 5.8 m, and the maximum depth was 8.5 m. Among the types of surficial materials in which wells were completed—alluvium, terrace deposits, or Potomac Formation sub- or outcrops in the Coastal Plain Province, and saprolite or fractured bedrock (Laurel and Sykesville Formations) underlying saprolite in the Piedmont Province—no pesticides were detected in groundwater associated with wells completed in the alluvium or fractured bedrock. Detections occurred in some but not all wells completed in the other surficial materials. Overall, the pattern in occurrence appeared related to the local permeability of these sediments and groundwater chemistry. Groundwater with multiple pesticide detections tended to occur in permeable sediments (absent any appreciable overlying clay, silt, or clay-silt layers), in conjunction with other common urban contaminants (elevated chloride in excess of tens to hundreds of milligrams per liter (mg/L), and oxic, rather than reduced, groundwater as evidenced by elevated (in excess of 5 mg/L) concentrations of nitrate). The results of this investigation were compared to results from two other similar and recent studies on pesticide occurrence in the shallow aquifer. These included a study in the nearby Maryland and Delaware Coastal Plain Physiographic Province and one in the Maryland and Virginia Piedmont Physiographic Province. Results from these studies were similar to the current study in relation to (a) the types, frequencies, concentrations, and mixtures of pesticides detected; (b) compounds that exceeded human-and aquatic-health criteria; and (c) the occurrence and distribution of pesticides within the surficial aquifer in relation to depths, sediment types, and groundwater chemistries.

Washington D.C.↗
USGS1993

Entrenchment and widening of the upper San Pedro River, Arizona

The San Pedro River of southeast Arizona is a north-flowing tributary of the Gila River. The area of the drainage basin upstream of the 40-km-long study reach is about 3,200 km 2 . This study traces the historical evolution of the San Pedro River channel—specifically, the deepening, widening, and sediment deposition that have occurred since 1900—and it aims to evaluate the causes of channel widening and deepening, the rate of widening, and the present stability of the channel. Alluvium of the river valley consists of upper Holocene pre- and postentrenchment deposits. The pre-entrenchment alluvium, which forms the principal terrace of the inner valley, accumulated between about A.D. 1450 and 1900 in a relatively sluggish, low-energy fluvial system with extensive marshy reaches and high water table. In contrast, postentrenchment alluvium, which forms the terrace, floodplain, and channel of the San Pedro River, was deposited in a relatively high-energy, entrenched, and meandering fluvial system. The river flowed in a shallow, narrow channel on the surface of the unentrenched valley before 1890. A series of large floods, perhaps beginning as early as 1881, eventually led to entrenchment of the channel between 1890 and 1908. This deepening placed the channel 1 to 10 m below the former floodplain. The channel has widened substantially since entrenchment through lateral migration and expansion of entrenched meanders; its present size is 5.7 times greater than before entrenchment. The rate of channel expansion, however, has decreased since about 1955, coincident with a decrease of peak-flood discharge. Channel area increased at 0.1 km 2 yr −1 from entrenchment until 1955; since then the area increased at only 0.02 km 2 yr −1 , suggesting that the channel has stabilized and that further widening will probably be minor under present conditions of land use, discharge, and climate. The reduction of peak-flow rates was related partly to increased channel sinuosity and to development of floodplains and riparian woodlands. The increased sinuosity produced a reservoir effect that attenuated flood waves, and the development of flood-plains enabled flood waters to spread laterally, thereby increasing transmission losses. In addition, flow rates were probably affected by improved land use and changes of rainfall intensity and short-term rainfall patterns, which reduced runoff and decreased the time necessary for channel stabilization. Livestock grazing decreased steadily after the turn of the century, and numerous stock ponds and small water-retention structures were constructed in tributaries. The cumulative effect of these structures probably reduced peak-flow rates. Short-term rainfall patterns of the wet season (June 15–October 15) have probably changed from annual alternation of above- and below-average rainfall to a biennial or longer pattern. Moreover, frequency of low-intensity rainfall (daily rainfall less than about 1.27 cm) was consistently above average for the decade 1957–1967. These factors probably improved conditions for growth and establishment of vegetation both in and outside of the channel. The causes of the large floods that resulted in entrenchment are poorly understood, although climate and land use were key factors. Floods followed closely the rapid settlement of the area brought about by mining activity in the late 1870s; population rose from a few hundred to 6,000 in less than 5 yr. Extensive wood cutting for mine timber and fuel, suppression of wildfire, and reintroduction of large cattle herds undoubtedly exacerbated entrenchment. Flood-producing wet-season rainfall in the Southwest, however, was unusually heavy before, during, and shortly after entrenchment.

Arizona↗
USGS2009

Hydrothermal processes above the Yellowstone magma chamber: Large hydrothermal systems and large hydrothermal explosions

Hydrothermal explosions are violent and dramatic events resulting in the rapid ejection of boiling water, steam, mud, and rock fragments from source craters that range from a few meters up to more than 2 km in diameter; associated breccia can be emplaced as much as 3 to 4 km from the largest craters. Hydrothermal explosions occur where shallow interconnected reservoirs of steam- and liquid-saturated fluids with temperatures at or near the boiling curve underlie thermal fields. Sudden reduction in confining pressure causes fluids to flash to steam, resulting in significant expansion, rock fragmentation, and debris ejection. In Yellowstone, hydrothermal explosions are a potentially significant hazard for visitors and facilities and can damage or even destroy thermal features. The breccia deposits and associated craters formed from hydrothermal explosions are mapped as mostly Holocene (the Mary Bay deposit is older) units throughout Yellowstone National Park (YNP) and are spatially related to within the 0.64-Ma Yellowstone caldera and along the active Norris-Mammoth tectonic corridor. In Yellowstone, at least 20 large (>100 m in diameter) hydrothermal explosion craters have been identified; the scale of the individual associated events dwarfs similar features in geothermal areas elsewhere in the world. Large hydrothermal explosions in Yellowstone have occurred over the past 16 ka averaging ~1 every 700 yr; similar events are likely in the future. Our studies of large hydrothermal explosion events indicate: (1) none are directly associated with eruptive volcanic or shallow intrusive events; (2) several historical explosions have been triggered by seismic events; (3) lithic clasts and comingled matrix material that form hydrothermal explosion deposits are extensively altered, indicating that explosions occur in areas subjected to intense hydrothermal processes; (4) many lithic clasts contained in explosion breccia deposits preserve evidence of repeated fracturing and vein-filling; and (5) areal dimensions of many large hydrothermal explosion craters in Yellowstone are similar to those of its active geyser basins and thermal areas. For Yellowstone, our knowledge of hydrothermal craters and ejecta is generally limited to after the Yellowstone Plateau emerged from beneath a late Pleistocene icecap that was roughly a kilometer thick. Large hydrothermal explosions may have occurred earlier as indicated by multiple episodes of cementation and brecciation commonly observed in hydrothermal ejecta clasts. Critical components for large, explosive hydrothermal systems include a water-saturated system at or near boiling temperatures and an interconnected system of well-developed joints and fractures along which hydrothermal fluids flow. Active deformation of the Yellowstone caldera, active faulting and moderate local seismicity, high heat flow, rapid changes in climate, and regional stresses are factors that have strong influences on the type of hydrothermal system developed. Ascending hydrothermal fluids flow along fractures that have developed in response to active caldera deformation and along edges of low-permeability rhyolitic lava flows. Alteration of the area affected, self-sealing leading to development of a caprock for the hydrothermal system, and dissolution of silica-rich rocks are additional factors that may constrain the distribution and development of hydrothermal fields. A partial low-permeability layer that acts as a cap to the hydrothermal system may produce some over-pressurization, thought to be small in most systems. Any abrupt drop in pressure initiates steam flashing and is rapidly transmitted through interconnected fractures that result in a series of multiple large-scale explosions contributing to the excavation of a larger explosion crater. Similarities between the size and dimensions of large hydrothermal explosion craters and thermal fields in Yellowstone may indicate that catastrophic events which result in large hydrothermal explosions are an end phase in geyser basin evolution. The Mary Bay hydrothermal explosion crater complex is the largest such complex in Yellowstone, and possibly in the world, with a diameter of 2.8 km in length and 2.4 km in width. It is nested in Mary Bay in the northern basin of Yellowstone Lake, an area of high heat flow and active deformation within the Yellowstone caldera. A sedimentary sequence exposed in wave-cut cliffs between Storm Point and Mary Bay gives insight into the geologic history of the Mary Bay hydrothermal explosion event. The Mary Bay explosion breccia deposits overlie sand above varved lake sediments and are separated locally into an upper and lower unit. The sand unit contains numerous small normal faults and is coextensive with the Mary Bay breccia in its northern extent. This sand may represent deposits of an earthquake-generated wave. Seismicity associated with the earthquake may have triggered the hydrothermal explosion responsible for development of the Mary Bay crater complex. Large hydrothermal explosions are rare events on a human time scale; however, the potential for additional future events of the sort in Yellowstone National Park is not insignificant. Based on the occurrence of large hydrothermal explosion events over the past 16,000 yr, an explosion large enough to create a 100-m-wide crater might be expected every 200 yr.

Wyoming↗
USGS1993

Stable carbon and oxygen isotope studies of the sediments of Elk Lake, Minnesota

Variations in the ratios of 18 O: 16 O and 13 C: 12 C in calcite throughout the Holocene in Elk Lake, Minnesota, are recorded in three varve-calibrated carbonate cores. Marl in a varved deep-basin (29.6 m) core consists mainly of calcite precipitated from surface waters during the summer and probably provides the least complicated isotope record. Marl in a sublittoral (10 m) core consists of calcite contributed from several inorganic and organic sources and probably is the most complicated of the three isotope records. Calcite from shells of the ostracod Candona ohioensis in the sublittoral core provides a record of shallow-water conditions in Elk Lake for the period between 10,500 and 5500 varve yr. Variations in the 13 C: 12 C ratio of organic carbon deposited in Elk Lake during the Holocene are recorded in organic matter in the deep-basin core. All three oxygen isotope records show that, in general, the 18 O: 16 O ratio in carbonate was enriched in 18 O by several parts per mil during the mid-Holocene relative to the past few thousand years. This pattern of oxygen isotope variation is similar to that observed for carbonate materials from other lakes in the northeastern and north-central United States. Oxygen isotope records from these other lakes also show that the 18 O: 16 O ratio during the early Holocene was lower than during the mid-Holocene, and this pattern has been interpreted as representing a response to a generally warmer and drier climate during the mid-Holocene beginning about 8000 varve yr (the so-called hypsithermal). Ostracod and diatom assemblages from Elk Lake cores show, however, that the lake was colder and more saline than at present until at least 6700 varve yr, with conditions similar to those that exist today in cold prairie lakes of Canada. It may be more appropriate, therefore, to refer to the mid-Holocene in northwestern Minnesota as the “prairie period” rather than the hypsithermal, indicating that the climate was drier, but with no connotation regarding temperature. The oxygen isotope data from the three Elk Lake records for this period are somewhat equivocal. Values of δ 18 O in the marl from the sublittoral core and shells of Candona increase from 10,000 to about 6800 varve yr. However, values of δ 18 O in the marl that accumulated in the deepest part of the lake over the same interval (10,000–6800 varve yr) are more or less constant and enriched in 18 O; this probably reflects the cold, saline prairie-lake conditions predicted from the ostracod and diatom assemblage data. All three oxygen isotope records show decreases in 18 O: 16 O ratios after about 6800 varve yr in response to an increase in temperature and decrease in salinity of the lake. The 13 C: 12 C ratios in carbonates from all three Elk Lake records show a distinct pattern; the ratio increased gradually from 10,000 to 8000 varve yr going into the mid-Holocene prairie period and then decreased gradually coming out of the prairie period between about 5500 and 2500 varve yr. These changes in the 13 C: 12 C ratio could have been related to temperature through its effect on solubility of carbon dioxide; however, this interpretation is not supported by the oxygen isotope data. Another possibility is that changes in the 13 C: 12 C ratio are related to organic productivity that removes 13 C-depleted organic carbon and results in 13 C-enriched surface waters. This interpretation implies that organic productivity was higher in Elk Lake during the mid-Holocene prairie period. Support for the high-productivity, 13 C-enriched surface-water model for the mid-Holocene prairie period in Elk Lake is provided by changes in the 13 C: 12 C ratio of organic carbon in the deep-basin core. These changes parallel almost exactly those in the 13 C: 12 C ratio of carbonate carbon, but are about 2% larger (about 6% as opposed to about 4% for carbonate carbon). The difference of about 2% may represent 13 C depletion due to CO 2 limitation. The percentage of organic carbon in the sediment did not increase during the prairie period because it was diluted by an increased flux of detrital clastic material. The ultimate burial rate of organic carbon increased considerably, however, indicating that organic productivity was higher and/or the degree of preservation increased. Diatom assemblages and plant-pigment concentrations indicate that productivity was higher during the prairie period. Pyrolysis hydrogen and oxygen indices show that the 13 C-enriched organic matter that accumulated during the prairie period was hydrogen rich and oxygen poor relative to organic matter that accumulated before and after. These two indices demonstrate that the organic matter that accumulated during the prairie period was much better preserved.

Minnestoa↗