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USGS2024

Water-quality constituent concentrations and loads computed using real-time water-quality data for the Republican River, Clay Center, Kansas, August 2018 through July 2023

Milford Lake, the largest reservoir by surface area in Kansas, has had confirmed harmful algal blooms every summer since reporting began in 2011, except 2018–19. Milford Lake has been listed as impaired and designated hypereutrophic under section 303(d) of the 1972 Clean Water Act. In 2014, the Kansas Department of Health and Environment established a total maximum daily load for eutrophication and dissolved oxygen impairments. In 2018, the Natural Resources Conservation Service funded the Regional Conservation Partnership Program for the Milford Lake Watershed to focus on best management practices in the Lower Republican River Basin. The U.S. Geological Survey, in cooperation with the Kansas Water Office, completed this study to assess and quantify water-quality constituent concentrations and loads for total nitrogen (TN), total phosphorus (TP), and suspended sediment (SS) using previously published models for the Republican River near Clay Center, Kansas (U.S. Geological Survey station 06856600), about 15 miles upstream from Milford Lake, during August 1, 2018, through July 31, 2023. TN, TP, and SS concentrations and loads were monitored because of their relation to water supply and water-quality issues in Milford Lake, including nutrient and sediment transport, taste-and-odor events, potentially toxic cyano-harmful algal bloom events, and subsequent downstream transport of contaminants. Data from this report can be used to evaluate changing conditions, provide science-based information for decision making, and help meet regulatory requirements. The study mean annual loads for TN and TP were greater than the reported mean annual total maximum daily load and exceeded the watershed reduction goals as well as Kansas nonpoint source reduction goals defined by the Watershed Restoration and Protection Strategy for the Lower Republican watershed. TN and TP annual loads during 2019–20 were greater than the defined mean annual total maximum daily load. During 2022, TN and TP annual loads were less than the Kansas nonpoint source reduction goal and during 2023 were less than the watershed reduction goal. SS loads were less than the mean annual sedimentation rate computed from the total maximum daily load for the entirety of the study period, and the study mean annual load was 72 percent less than the designed annual reservoir sedimentation rate for Milford Lake. Data collected during the study period represented a wide range of streamflow and water-quality conditions at the Clay Center site, ranging from low-flow with less frequent runoff during 2023 to high-flow with frequent runoff during 2018. Nutrient reduction goals were only met in the final 2 years of the study period when annual mean flow conditions were lower than normal, indicating that goals may be unattainable during average or high-flow conditions. In all years except 2019, the annual mean SS load was less than the 20-year sediment load reduction target. Although annual SS loads at the Clay Center site generally decreased over time, corresponding reductions in annual streamflow indicated that these reductions may primarily be related to less frequent runoff from the upstream basin. Continued water-quality monitoring and tracking of best management practices are necessary to understand the success of Regional Conservation Partnership Program efforts to reduce nutrient transport in the Milford Lake Watershed.

Kansas↗

USGS2007

Measured and Estimated Sodium-Adsorption Ratios for Tongue River and its Tributaries, Montana and Wyoming, 2004-06

The Tongue River drains an area of about 5,400 square miles and flows northward from its headwaters in the Bighorn National Forest of northeastern Wyoming to join the Yellowstone River at Miles City, Montana. Water from the Tongue River and its tributaries is extensively used for irrigation in both Wyoming and Montana. The Tongue River watershed contains vast coal deposits that are extracted at several surface mines. In some areas of the watershed, the coal beds also contain methane gas (coal-bed methane or natural gas), which has become the focus of intense exploration and development. Production of coal-bed methane requires the pumping of large volumes of ground water from the coal beds to reduce water pressure within the formation and release the stored gas. Water from the coal beds typically is high in sodium and low in calcium and magnesium, resulting in a high sodium-adsorption ratio (SAR). Disposal of ground water with high sodium concentrations into the Tongue River has the potential to increase salinity and SAR of water in the river, and potentially reduce the quality of water for irrigation purposes. This report documents SAR values measured in water samples collected at 12 monitoring sites in the Tongue River watershed and presents regression relations between specific conductance (SC) and SAR at each site for the years 2004-06. SAR in water samples was determined from laboratory-measured concentrations of sodium, calcium, and magnesium. The results of regression analysis indicated that SC and SAR were significantly related (p-values < 0.05) at most sites. The regression relations developed for most monitoring sites in the Tongue River watershed were used with continuous SC data to estimate daily SAR during the 2004 and 2005 irrigation seasons and to estimate 2006 provisional SAR values, which were displayed on the Web in real-time. Water samples were collected and analyzed from seven sites on the main stem of the Tongue River located at: (1) Monarch, Wyoming, station 06299980, (2) State line near Decker, Montana, station 06306300, (3) Tongue River Dam near Decker, Montana, station 06307500, (4) Birney Day School Bridge near Birney, Montana, station 06307616, (5) below Brandenberg Bridge near Ashland, Montana, station 06307830, (6) above T&Y Diversion Dam near Miles City, Montana, station 06307990, and (7) Miles City, Montana, station 06308500. Water samples were collected and analyzed from five sites on tributaries located at: (1) Goose Creek near Acme, Wyoming, station 06305700, (2) Prairie Dog Creek near Acme, Wyoming, station 06306250, (3) Hanging Woman Creek near Birney, Montana, station 06307600, (4) Otter Creek at Ashland, Montana, station 06307740, and (5) Pumpkin Creek near Miles City, Montana, station 06308400. All water-quality data for samples collected at these 12 sites can be accessed at Web sites http://waterdata.usgs.gov/mt/nwis or http://waterdata.usgs.gov/wy/nwis.

Scientific Investigations Report↗

USGS2006

Regionalized equations for bankfull-discharge and channel characteristics of streams in New York State—Hydrologic Region 7 in western New York

Computation of bankfull discharge and channel dimensions (width, depth, and cross-sectional area) at ungaged sites requires equations that relate bankfull discharge and channel dimensions to drainage-area at gaged sites. Bankfull-channel information commonly is needed for watershed assessments, stream channel classification, and the design of stream-restoration projects. Such equations are most accurate if they are derived on the basis of data from streams within a region of uniform hydrologic, climatic, and physiographic conditions and applied only within that region. New York State contains eight hydrologic regions that were previously delineated on the basis of high-flow (flood) characteristics. This report presents drainage areas and associated bankfull characteristics (discharge and channel dimensions) for surveyed streams in western New York (Region 7). Stream-survey data and discharge records from seven active and three inactive USGS streamflow-gaging stations were used in regression analyses to relate drainage area to bankfull discharge and to bankfull channel width, depth, and cross-sectional area. The resulting equations are: (1) bankfull discharge, in cubic feet per second = 37.1*(drainage area, in square miles) 0.765 ; (2) bankfull channel width, in feet = 10.8*(drainage area, in square miles) 0.458 ; (3) bankfull channel depth, in feet = 1.47*(drainage area, in square miles) 0.199 ; and (4) bankfull channel cross-sectional area, in square feet = 15.9*(drainage area, in square mile) 0.656 . The coefficients of determination (R 2 ) for these four equations were 0.94, 0.89, 0.52, and 0.96, respectively. The high coefficients of determination for three of these equations (discharge, width, and cross-sectional area) indicate that much of the range in the variables was explained by the drainage area. The low coefficient of determination for the equation relating bankfull depth to drainage area, however, suggests that other factors also affected water depth. Recurrence intervals for the estimated bankfull discharge of each stream ranged from 1.05 to 3.60 years; the mean recurrence interval was 2.13 years. The 10 surveyed streams were classified by Rosgen stream type; most were C- and E-type, with occasional B- and F-type cross sections. The equation (curve) for bankfull discharge for Region 7 was compared with those previously developed for four other hydrologic regions in New York State. The differences confirm that the hydraulic geometry of streams is affected by local climatic and physiographic conditions.

Scientific Investigations Report↗

USGS2013

Assessment of water-quality data from Long Lake National Wildlife Refuge, North Dakota--2008 through 2012

ong Lake National Wildlife Refuge, located in south-central North Dakota, is an important habitat for numerous migratory birds and waterfowl, including several threatened or endangered species. The refuge is distinguished by Long Lake, which is approximately 65 square kilometers and consists of four primary water management units. Water levels in the Long Lake units are maintained by low-level dikes and water-control structures, which after construction during the 1930s increased the water-storage capacity of Long Lake and reduced the frequency and volume of flushing flows downstream. The altered water regime, along with the negative precipitation:evaporation ratio of the region, may be contributing to the accumulation of water-borne chemical constituents such as salts, trace metals, and other constituents, which at certain threshold concentrations may impair aquatic plant, invertebrate, and bird communities of the refuge. The refuge’s comprehensive conservation planning process identified the need for water-quality monitoring to assess current (2013) conditions, establish comparative baselines, evaluate changes over time (trends), and support adaptive management of the wetland units. In 2008, the U.S. Geological Survey, U.S. Fish and Wildlife Service, and North Dakota Department of Health began a water-quality monitoring program at Long Lake National Wildlife Refuge to address these needs. Biweekly water-quality samples were collected for ions, trace metals, and nutrients; and in situ sensors and data loggers were installed for the continuous measurement of specific conductance and water depth. Long Lake was characterized primarily by sodium, bicarbonate, and sulfate ions. Overall results for total alkalinity and hardness were 580 and 329 milligrams per liter, respectively; thus, Long Lake is considered alkaline and classified as very hard. The mean pH and sodium adsorption ratio for Long Lake were 8.8 and 10, respectively. Total dissolved solids concentrations averaged approximately 1,750 milligrams per liter, and ranged from 117 to 39,700 milligrams per liter. Twelve of the 14 trace metals detected in the water samples had established North Dakota water-quality standards for aquatic life, and only aluminum and copper consistently exceeded these criteria. Aluminum is considered harmful to aquatic biota in acidic (pH less than 5.5) systems and most of the copper standard exceedances were collected from highly concentrated waters because of evaporation and seasonally low water levels. Concentrations for various forms of nitrogen and phosphorus generally were similar to reported regional values. Specific conductance of Long Lake varied seasonally and annually both within and among management units, with values ranging from less than 500 to nearly 40,000 microsiemens per centimeter at 25 degrees Celsius. Long Lake was characterized by consistent seasonal patterns of increasing specific conductance from spring (March and April) to fall (September and October), with levels stabilizing through the end of the sampling season (November). These seasonal patterns in specific conductance were associated with decreasing water levels throughout the summer due primarily to evaporation and continuous water releases through the Unit 1 outlet structure, which resulted in the concentration of salts. Specific conductance of each unit, along with water levels, also varied among years. Overall, specific conductance levels were greatest during the drier year of 2008 when water levels were low. Specific conductance levels were lowest during the spring of 2009 following above-average volumes of fresh water from snowmelt runoff. Comparisons of specific conductance among sample sites that were spatially distributed within each management unit suggested that spatial variability within units was low except for areas associated with local inflows. Data collected during this study revealed consistent seasonal patterns and low within-unit spatial variability of specific conductance. Based on these data results, future sample collection efforts may be reduced, as well as the number of sample locations, to limit sampling costs. Water-quality samples collected monthly or seasonally during the growing season (spring, summer, and fall) from a single representative location within each water-management unit should provide sufficient data to assess seasonal changes in water-quality over time and provide information for Long Lake management decisions.

North Dakota↗

USGS2020

Transmissivity estimated from brief aquifer tests of domestic wells and compared with bedrock lithofacies and position on hillsides in the Appalachian Plateau of New York

Procedures for undertaking and analyzing recovery from aquifer tests of 13 to 132 seconds (described in reports cited herein) were applied to 51 domestic drilled wells that penetrated bedrock outside major valleys in the part of the Appalachian Plateau of New York drained by the Susquehanna River. Transmissivities calculated from these tests ranged over three orders of magnitude in both the Catskill-Cattaraugus lithofacies (shales, mudstones, siltstones, medium to coarse sandstones, pebbly sandstones) and the Chemung-Hamilton lithofacies (shales, mudstones, siltstones, fine to medium sandstones). Median transmissivity values were 0.000425 foot squared per second (36.7 feet squared per day) in the Catskill-Cattaraugus lithofacies and 0.00055 foot squared per second (47.5 feet squared per day) in the Chemung-Hamilton lithofacies. The distributions of transmissivity values within the two lithofacies were likewise similar. The range and median values of transmissivity were also nearly the same on lower and midlevel hillsides and were only slightly greater on a few upper hillsides. Transmissivities estimated from such easily arranged and analyzed tests may be appropriate for estimating groundwater flux under the small gradients that prevail under natural conditions, but not under larger drawdowns and steeper gradients near clusters of domestic wells. Four of the 51 wells tested were also pumped for 10 to 32 minutes; analysis by the Theis recovery method yielded transmissivities consistent with the brief tests for 2 wells, but 7 to 9 times smaller for 2 wells. Transmissivity values estimated by the PICKINGmodel were not significantly different from values estimated by an automated application of the Picking method (PPC-Recovery) at a probability of 95 percent. Transmissivities calculated by either method from data for time intervals of 120 seconds or less may be of limited practical value because they apply only to a small volume of bedrock close to the pumped well.

New York↗

USGS2023

Using Global Fiducials Library high-resolution imagery, commercial satellite imagery, Landsat and Sentinel satellite imagery, and aerial photography to monitor change at East Timbalier Island, Louisiana, 1953–2021

This report documents morphological changes between 1953 and 2021 at East Timbalier Island, Louisiana, a Gulf of Mexico barrier island. East Timbalier Island, which was located west of the Mississippi River Delta at the front of Timbalier Bay, was one of the most rapidly changing barrier islands on Earth. Since aerial photographs were initially taken in 1953, the Island steadily lost length and area, finally eroding away by early summer 2021. After major storm events, sediment eroded from the Island and migrated hundreds of meters north. In August 1992, Hurricane Andrew breached the Island in several places, resulting in increased erosion and land loss. Until it completely eroded away, the Island underwent a cycle of washovers, vegetation removal, breaching, and erosion with sediment transport to the north. Satellite imagery shows that three such cycles occurred between 1992 and 2017, despite the partial restoration of the Island between 1998 and 2000. Each cycle increased the distance between the Island and the mainland to the east, reducing both the sediment supply from the east and the protection that Timbalier Bay and the adjacent coastal lands received from the barrier island. Previously, the U.S. Geological Survey (USGS) National Civil Applications Center used 1-meter resolution imagery archived at the USGS Global Fiducials Library (GFL), collected between 2000 and 2010 by U.S. National Imaging Systems, to monitor the changes at the Island. New research expands this study retrospectively and prospectively using aerial photography collected from 1953 to 2012 and in 2020; declassified imagery collected in 1962, 1972, and 1975; DigitalGlobe satellite imagery collected since 2004; Landsat satellite imagery collected since 1972; Sentinel–2 satellite imagery collected since 2015; and GFL imagery collected from 1991 to 2020.

Louisiana↗

USGS2006

Occurrence of organic wastewater compounds in drinking water, wastewater effluent, and the Big Sioux River in or near Sioux Falls, South Dakota, 2001-2004

The U.S. Geological Survey (USGS) in cooperation with the city of Sioux Falls conducted several rounds of sampling to determine the occurrence of organic wastewater compounds (OWCs) in the city of Sioux Falls drinking water and waste-water effluent, and the Big Sioux River in or near Sioux Falls during August 2001 through May 2004. Water samples were collected during both base-flow and storm-runoff conditions. Water samples were collected at 8 sites, which included 4 sites upstream from the wastewater treatment plant (WWTP) discharge, 2 sites downstream from the WWTP discharge, 1 finished drinking-water site, and 1 WWTP effluent (WWE) site. A total of 125 different OWCs were analyzed for in this study using five different analytical methods. Analyses for OWCs were performed at USGS laboratories that are developing and/or refining small-concentration (less than 1 microgram per liter (ug/L)) analytical methods. The OWCs were classified into six compound classes: human pharmaceutical compounds (HPCs); human and veterinary antibiotic compounds (HVACs); major agricultural herbicides (MAHs); household, industrial,and minor agricultural compounds (HIACs); polyaromatic hydrocarbons (PAHs); and sterol compounds (SCs). Some of the compounds in the HPC, MAH, HIAC, and PAH classes are suspected of being endocrine-disrupting compounds (EDCs). Of the 125 different OWCs analyzed for in this study, 81 OWCs had one or more detections in environmental samples reported by the laboratories, and of those 81 OWCs, 63 had acceptable analytical method performance, were detected at concentrations greater than the study reporting levels, and were included in analyses and discussion related to occurrence of OWCs in drinking water, wastewater effluent, and the Big Sioux River. OWCs in all compound classes were detected in water samples from sampling sites in the Sioux Falls area. For the five sampling periods when samples were collected from the Sioux Falls finished drinking water, only one OWC was detected at a concentration greater than the study reporting level (metolachlor; 0.0040 ug/L). During base-flow conditions, Big Sioux River sites upstream from the WWTP discharge had OWC contributions that primarily were from nonpoint animal or crop agriculture sources or had OWC concentrations that were minimal. The influence of the WWTP discharge on OWCs at downstream river sites during base-flow conditions ranged from minimal influence to substantial influence depending on the sampling period. During runoff conditions, OWCs at sites upstream from the WWTP discharge probably were primarily contributed by nonpoint animal and/or crop agriculture sources and possibly by stormwater runoff from nearby roads. OWCs at sites downstream from the WWTP discharge probably were contributed by sources other than the WWTP effluent discharge, such as stormwater runoff from urban and/or agriculture areas and/or resuspension of OWCs adsorbed to sediment deposited in the Big Sioux River. OWC loads generally were substantially smaller for upstream sites than downstream sites during both base-flow and runoff conditions.discharge had OWC contributions that primarily were from nonpoint animal or crop agriculture sources or had OWC concentrations that were minimal. The influence of the WWTP discharge on OWCs at downstream river sites during base-flow conditions ranged from minimal influence to substantial influence depending on the sampling period. During runoff conditions, OWCs at sites upstream from the WWTP discharge probably were primarily contributed by nonpoint animal and/or crop agriculture sources and possibly by stormwater runoff from nearby roads. OWCs at sites downstream from the WWTP discharge probably were contributed by sources other than the WWTP effluent discharge, such as stormwater runoff from urban and/or agriculture areas and/or resuspension of OWCs adsorbed to sediment deposited in the Big Sioux River. OWC loads generally were substantially smaller for

South Dakota↗

USGS2015

Trace-metal and organic constituent concentrations in bed sediment at Big Base and Little Base Lakes, Little Rock Air Force Base, Arkansas—Comparisons to sediment-quality guidelines and indications for timing of exposure

This report compares concentrations for a wide range of inorganic and organic constituents in bed sediment from Big Base Lake and Little Base Lake, which are located on Little Rock Air Force Base, Arkansas, to sediment-quality guidelines. This report also compares trace-metal concentrations in a bed-sediment core sample to sediment age to determine when the highest concentrations of trace metals were deposited in Big Base Lake. Trace-metal results often were higher than background concentrations in the surrounding Pulaski County area, and concentrations of arsenic, cadmium, cobalt, copper, lead, manganese, mercury, nickel, and zinc at one or more of three study sites were higher than median concentrations for a study involving 98 urban streams in seven metropolitan areas of the United States. Concentrations for most polycyclic aromatic hydrocarbons, polychlorinated biphenyls, and organochlorine pesticides in all three bed-sediment samples were less than the laboratory reporting limit or were detected at low concentrations. Some contaminants were detected at concentrations that are potentially toxic to sediment-dwelling biota; however, in general, the analyses suggest that the risk of sediment toxicity may be relatively low. Threshold effect concentrations were exceeded for 14 constituents—arsenic, copper, lead, nickel, and zinc, five polycyclic aromatic hydrocarbons compounds, chlordane, and all three dichlorodiphenyltrichloroethane (DDT) congeners—which suggests potential toxicity to some sediment-dwelling biota. Only two constituents had concentrations that exceeded published probable effect concentrations—arsenic (at the deepest site in Big Base Lake, NS6) and p,p’-dichlorodiphenyldichloroethylene (p,p’-DDE; at both sites in Big Base Lake, NS5 and NS6). Regarding highest concentrations and associated timing of exposure, trace metals analyzed in the sediment core seem to indicate three fairly distinct exposure patterns. For 11 trace metals that had the highest concentration measured in the shallowest and most recently deposited sediment, the most likely explanation is recent exposure by anthropogenic activities. Most of the 11 trace metals with highest concentrations in shallow sediment are relatively innocuous; however, arsenic, copper, selenium, and zinc are among the U.S. Environmental Protection Agency’s 126 priority pollutants. For three trace metals (cadmium, lead, and mercury), for which concentrations were highest in sediments that were 16–20 centimeters down the core, it is likely that a source associated with those contaminants during the period when those sediments were deposited, was reduced or eliminated. The eight remaining trace metals, for which concentrations were highest in sediments that were just below the prereservoir surface, likely had sources that were eliminated soon after lake construction or occurred at relatively high background concentrations in soils in the area around Little Rock Air Force Base.

Arkansas↗

USGS2004

Quality of water on the Prairie Band Potawatomi Reservation, northeastern Kansas, May 2001 through August 2003

Water-quality samples were collected from 20 surface-water sites and 11 ground-water sites on the Prairie Band Potawatomi Reservation in northeastern Kansas in an effort to describe existing water-quality conditions on the reservation and to compare water-quality conditions to results from previous reports published as part of a multiyear cooperative study with the Prairie Band Potawatomi Nation. Water is a valuable resource to the Prairie Band Potawatomi Nation as tribal members use the streams draining the reservation, Soldier, Little Soldier, and South Cedar Creeks, to fulfill subsistence hunting and fishing needs and as the tribe develops an economic base on the reservation. Samples were collected once at 20 surface-water monitoring sites during June 2001, and quarterly samples were collected at 5 of the 20 monitoring sites from May 2001 through August 2003. Ground-water-quality samples were collected once from seven wells and twice from four wells during April through May 2003 and in August 2003. Surface-water-quality samples collected from May through August 2001 were analyzed for physical properties, nutrients, pesticides, fecal indicator bacteria, and total suspended solids. In November 2001, an additional analysis for dissolved solids, major ions, trace elements, and suspended-sediment concentration was added for surface-water samples. Ground-water samples were analyzed for physical properties, dissolved solids, major ions, nutrients, trace elements, pesticides, and fecal indicator bacteria. Chemical oxygen demand and volatile organic compounds were analyzed in a sample from one monitoring well located near a construction and demolition landfill on the reservation. Previous reports published as a part of this ongoing study identified total phosphorus, triazine herbicides, and fecal coliform bacteria as exceeding their respective water-quality criteria in surface water on the reservation. Previous ground-water assessments identified occasional sample concentrations of dissolved solids, sodium, sulfate, boron, iron, and manganese as exceeding their respective water-quality criteria. Forty percent of the 65 surface-water samples analyzed for total phosphorus exceeded the aquatic-life goal of 0.1 mg/L (milligrams per liter) established by the U.S. Environmental Protection Agency (USEPA). Concentrations of dissolved solids and sodium occasionally exceeded USEPA Secondary Drinking-Water Regulations and Drinking-Water Advisory Levels, respectively. One of the 20 samples analyzed for atrazine concentrations exceeded the Maximum Contaminant Level (MCL) of 3.0 ?g/L (micrograms per liter) as an annual average established for drinking water by USEPA. A triazine herbicide screen was used on 63 surface-water samples, and triazine compounds were frequently detected. Triazine herbicides and their degradates are listed on the USEPA Contaminant Candidate List. Nitrite plus nitrate concentrations in two ground-water samples from one monitoring well exceeded the MCL of 10 mg/L established by USEPA for drinking water. Arsenic concentrations in two samples from one monitoring well also exceeded the proposed MCL of 10 ?g/L established by the USEPA for drinking water. Concentrations of dissolved solids and sulfate in some ground-water samples exceeded their respective Secondary Drinking-Water Regulations, and concentrations exceeded the taste threshold of the USEPA?s Drinking-Water Advisory Level for sodium. Consequently, in the event that ground water on the reservation is to be used as a drinking-water source, additional treatment may be necessary to remove excess dissolved solids, sulfate, and sodium.

Scientific Investigations Report↗

USGS2004

Simulation of ground-water flow in glaciofluvial aquifers in the Grand Rapids area, Minnesota

A calibrated steady-state, finite-difference, ground-waterflow model was constructed to simulate ground-water flow in three glaciofluvial aquifers, defined in this report as the upper, middle, and lower aquifers, in an area of about 114 mi2 surrounding the city of Grand Rapids in north-central Minnesota. The calibrated model will be used by Minnesota Department of Health and communities in the Grand Rapids area in the development of wellhead protection plans for their water supplies. The model was calibrated through comparison of simulated ground-water levels to measured static water levels in 351 wells, and comparison of simulated base-flow rates to estimated base-flow rates for reaches of the Mississippi and Prairie Rivers. Model statistics indicate that the model tends to overestimate ground-water levels. The root mean square errors ranged from +12.83 ft in wells completed in the upper aquifer to +19.10 ft in wells completed in the middle aquifer. Mean absolute differences between simulated and measured water levels ranged from +4.43 ft for wells completed in the upper aquifer to +9.25 ft for wells completed in the middle aquifer. Mean algebraic differences ranged from +9.35 ft for wells completed in the upper aquifer to +14.44 ft for wells completed in the middle aquifer, with the positive differences indicating that the simulated water levels were higher than the measured water levels. Percentage errors between simulated and estimated base-flow rates for the three monitored reaches all were less than 10 percent, indicating good agreement. Simulated ground-water levels were most sensitive to changes in general-head boundary conductance, indicating that this characteristic is the predominant model input variable controlling steady-state water-level conditions. Simulated groundwater flow to stream reaches was most sensitive to changes in horizontal hydraulic conductivity, indicating that this characteristic is the predominant model input variable controlling steady-state flow conditions.

Minnesota↗

USGS2007

Box Model of a Series of Salt Ponds, as Applied to the Alviso Salt Pond Complex, South San Francisco Bay, California

This report documents the development and application of a box model to simulate water level, salinity, and temperature of the Alviso Salt Pond Complex in South San Francisco Bay. These ponds were purchased for restoration in 2003 and currently are managed by the U.S. Fish and Wildlife Service to maintain existing wildlife habitat and prevent a build up of salt during the development of a long-term restoration plan. The model was developed for the purpose of aiding pond managers during the current interim management period to achieve these goals. A previously developed box model of a salt pond, SPOOM, which calculates daily pond volume and salinity, was reconfigured to simulate multiple connected ponds and a temperature subroutine was added. The updated model simulates rainfall, evaporation, water flowing between the ponds and the adjacent tidal slough network, and water flowing from one pond to the next by gravity and pumps. Theoretical and measured relations between discharge and corresponding differences in water level are used to simulate most flows between ponds and between ponds and sloughs. The principle of conservation of mass is used to calculate daily pond volume and salinity. The model configuration includes management actions specified in the Interim Stewardship Plan for the ponds. The temperature subroutine calculates hourly net heat transfer to or from a pond resulting in a rise or drop in pond temperature and daily average, minimum, and maximum pond temperatures are recorded. Simulated temperature was compared with hourly measured data from pond 3 of the Napa?Sonoma Salt Pond Complex and monthly measured data from pond A14 of the Alviso Salt-Pond Complex. Comparison showed good agreement of measured and simulated pond temperature on the daily and monthly time scales.

Scientific Investigations Report↗

USGS2022

Comparison of the results of enzyme-linked immunosorbent assay (ELISA) to mass-spectrometry based analytical methods for six unregulated contaminants in source water and finished drinking-water samples

Regulatory entities, such as the Minnesota Department of Health, monitor public water systems for conformance with Federal and State monitoring requirements and water-quality standards. Although some contaminants have Federal and (or) State regulations and guidance values, many contaminants, such as pesticides and pharmaceuticals, are unregulated in that only non-enforceable health-based guidance values have been assigned to them. Furthermore, because these contaminants are not regulated, commonly only limited resources are available to public water systems or regulatory entities to monitor them in drinking water. Focused screening efforts on contaminants that are frequently detected in the environment can provide information to help monitoring entities prioritize their sampling efforts. Here we assess the use of enzyme-linked immunosorbent assay (ELISA) method, a rapid, inexpensive screening method, as an alternative to more expensive methods to analyze source and finished drinking-water samples collected from public water systems throughout Minnesota for three commonly detected pesticides (atrazine, imidacloprid, and pyrethroids) and three commonly detected pharmaceuticals (caffeine, carbamazepine, and sulfamethoxazole). The ELISA results were compared to results provided by more advanced mass-spectrometry analytical methods at the U.S. Geological Survey National Water Quality Laboratory (NWQL) and SGS AXYS Analytical Services Ltd. (AXYS). Overall, these datasets are highly censored (>80 percent) and contain multiple reporting limits within and between laboratories. To discern agreement between paired contaminant group results (target contaminant plus immunologically similar contaminants) by ELISA and the advanced analytical methods at NWQL and AXYS, presence-absence agreement analysis was coupled with false negative and false positive analysis. Analysis of presence-absence agreement shows that ELISA has generally good agreement (77.9 to 100 percent) with both NWQL and AXYS for all unregulated contaminant groups. Imidicloprid, pyrethroids, and caffeine contaminant groups have relatively low false positivity rates (16, 6, and 5 percent, respectively) when analyzed by ELISA, which indicates the ELISA method, for these contaminant groups, could be experiencing low-level interference attributed to the detection of immunologically similar contaminants. Similarly, sulfamethoxazole has a low false positivity rate (0.8 percent), which indicates ELISA is likely not overestimating results for this contaminant group. Analyses for carbamazepine and sulfamethoxazole by ELISA resulted in low false negativity rates (1.6 and 0.8 percent, respectively), which indicates the ELISA method is likely not underestimating the results for this contaminant group. Conversely, the atrazine contaminant group has a high false negativity rate (84 percent), which indicates the method has a strong negative bias and that ELISA underestimates results for this contaminant. These qualitative results indicate that the ELISA method could potentially serve as a reliable and cost-effective screening method to help drinking water monitoring entities prioritize sampling efforts for analyzing carbamazepine and sulfamethoxazole in source and finished drinking-water samples collected from public water systems. At the same time, although ELISA did not prove to be a good screening method for atrazine, evaluation of ELISA results indicated that its use for screening imidacloprid, pyrethroids, and caffeine could be beneficial for water testing.

Minnesota↗

USGS2009

Water quality and evaluation of pesticides in lakes in the Ridge Citrus region of central Florida

Water chemistry, including major inorganic constituents, nutrients, and pesticide compounds, was compared between seven lakes surrounded by citrus agriculture and an undeveloped lake on the Lake Wales Ridge (herein referred to as the Ridge) in central Florida. The region has been recognized for its vulnerability to the leaching of agricultural chemicals into the subsurface due to factors including soils, climate, and land use. About 40 percent of Florida's citrus cultivation occurs in 'ridge citrus' areas characterized by sandy well drained soils, with the remainder in 'flatwoods citrus' characterized by high water tables and poorly drained soils. The lakes on the Ridge are typically flow-through lakes that exchange water with adjacent and underlying aquifer systems. This study is the first to evaluate the occurrence of pesticides in lakes on the Ridge, and also represents one of the first monitoring efforts nationally to focus on regional-scale assessment of current-use pesticides in small- to moderate-sized lakes (5 to 393 acres). The samples were collected between December 2003 and September 2005. The lakes in citrus areas contained elevated concentrations of major inorganic constituents (including alkalinity, total dissolved solids, calcium, magnesium, sodium, potassium, chloride, and sulfate), total nitrogen, pH, and pesticides compared to the undeveloped lake. Nitrate (as N) and total nitrogen concentrations were typically elevated in the citrus lakes, with maximum values of 4.70 and 5.19 mg/L (milligrams per liter), respectively. Elevated concentrations of potassium, nitrate, and other inorganic constituents in the citrus lakes likely reflect inputs from the surficial ground-water system that originated predominantly from agricultural fertilizers, soil amendments, and inorganic pesticides. A total of 20 pesticide compounds were detected in the lakes, of which 12 compounds exceeded the standardized reporting level of 0.06 ug/L (microgram per liter). Those most frequently detected above the 0.06-ug/L level were aldicarb sulfoxide, diuron, simazine degradates hydroxysimazine and didealkylatrazine (DDA), bromacil, norflurazon, and demethyl norflurazon which occurred at detection rates ranging from 25 to 86 percent of samples, respectively. Typically, pesticide concentrations in the lake samples were less than 1 microgram per liter. The number of targeted pesticide compounds detected per lake in the citrus areas ranged from 9 to 14 compared to 3 compounds detected at trace levels in the undeveloped lake. Consistent detections of parents and degradates in quarterly samples indicated the presence of pesticide compounds in the lakes many months or years (for example, bromacil) after their application, signaling the persistence of some pesticide compounds in the lakes and/or ground-water systems. Pesticide degradate concentrations frequently exceeded parent concentrations in the lakes. This study was the first in the Ridge citrus region to analyze for glyphosate - widely used in citrus - and its degradate aminomethylphosphonic acid (AMPA), neither of which were detected, as well as a number of triazine degradates, including hydroxysimazine, which were detected. The lake pesticide concentrations did not exceed current Federal aquatic-life benchmarks, available for 10 of the 20 detected pesticide compounds. Limited occurrences of bromacil, diuron, or norflurazon concentrations were within about 10 to 90 percent of benchmark guidelines for acute effects on nonvascular aquatic plants in one or two of the lakes. The lake pesticide concentrations for several targeted pesticides were relatively high compared to corresponding national stream-water percentiles, which is consistent with this region's vulnerability for pesticide leaching into water resources. Several factors were evaluated to gain insight into the processes controlling pesticide transport and fate, and to assess their utility for estimating th

Florida↗

USGS2012

Simulation of groundwater and surface-water resources and evaluation of water-management alternatives for the Chamokane Creek basin, Stevens County, Washington

A three-dimensional, transient numerical model of groundwater and surface-water flow was constructed for Chamokane Creek basin to better understand the groundwater-flow system and its relation to surface-water resources. The model described in this report can be used as a tool by water-management agencies and other stakeholders to quantitatively evaluate the effects of potential increases in groundwater pumping on groundwater and surface-water resources in the basin. The Chamokane Creek model was constructed using the U.S. Geological Survey (USGS) integrated model, GSFLOW. GSFLOW was developed to simulate coupled groundwater and surface-water resources. The model uses 1,000-foot grid cells that subdivide the model domain by 102 rows and 106 columns. Six hydrogeologic units in the model are represented using eight model layers. Daily precipitation and temperature were spatially distributed and subsequent groundwater recharge was computed within GSFLOW. Streamflows in Chamokane Creek and its major tributaries are simulated in the model by routing streamflow within a stream network that is coupled to the groundwater-flow system. Groundwater pumpage and surface-water diversions and returns specified in the model were derived from monthly and annual pumpage values previously estimated from another component of this study and new data reported by study partners. The model simulation period is water years 1980-2010 (October 1, 1979, to September 30, 2010), but the model was calibrated to the transient conditions for water years 1999-2010 (October 1, 1998, to September 30, 2010). Calibration was completed by using traditional trial-and-error methods and automated parameter-estimation techniques. The model adequately reproduces the measured time-series groundwater levels and daily streamflows. At well observation points, the mean difference between simulated and measured hydraulic heads is 7 feet with a root-mean-square error divided by the total difference in water levels of 4.7 percent. Simulated streamflow was compared to measured streamflow at the USGS streamflow-gaging station-Chamokane Creek below Falls, near Long Lake (12433200). Annual differences between measured and simulated streamflow for the site ranged from -63 to 22 percent. Calibrated model output includes a 31-year estimate of monthly water budget components for the hydrologic system. Five model applications (scenarios) were completed to obtain a better understanding of the relation between groundwater pumping and surface-water resources. The calibrated transient model was used to evaluate: (1) the connection between the upper- and middle-basin groundwater systems, (2) the effect of surface-water and groundwater uses in the middle basin, (3) the cumulative impacts of claims registry use and permit-exempt wells on Chamokane Creek streamflow, (4) the frequency of regulation due to impacted streamflow, and (5) the levels of domestic and stockwater use that can be regulated. The simulation results indicated that streamflow is affected by existing groundwater pumping in the upper and middle basins. Simulated water-management scenarios show streamflow increased relative to historical conditions as groundwater and surface-water withdrawals decreased.

Washington↗

USGS2021

Occurrence, fate, and transport of aerially applied herbicides to control invasive buffelgrass within Saguaro National Park Rincon Mountain District, Arizona, 2015–18

The spread of the invasive and fire-adapted buffelgrass ( Cenchrus ciliaris L.) threatens desert ecosystems by competing for resources, increasing fuel loads, and creating wildfire connectivity. The Rincon Mountain District of Saguaro National Park addressed this natural resource threat with the use of glyphosate-based herbicides (GBHs). In 2010, the Rincon Mountain District initiated an aerial restoration plan to control dense buffelgrass patches in remote areas and implemented a trial project to evaluate the effects of aerial restoration techniques that included the helicopter application of GBHs. In 2014, more than 250 acres of buffelgrass in the Rincon Mountain District were treated with the aerial application of GBHs. This widespread aerial application of GBHs continued through 2018, but the potential transport and effects to aquatic ecosystems were unknown. In 2015–18, the U.S. Geological Survey, in cooperation with the National Park Service, studied the occurrence, distribution, fate, and transport of glyphosate in surface water and sediments derived from areas that were treated during past and current aerial herbicide applications. Three watersheds, treated with different regimens of GBHs, were sampled for glyphosate and the primary metabolite of glyphosate, aminomethylphosphonic acid (AMPA), during various hydrologic flow conditions. Water and aquatic sediment were collected from three watersheds, each in a different stage of application during the U.S. Geological Survey study. The unnamed watershed above the Loma Verde Trailhead referred to by the National Park Service as “Loma Verde canyon” had received no aerial treatment since 2014, whereas the Box Canyon watershed was aerially treated every year beginning in 2014. The Madrona Canyon watershed was first sprayed in 2016 and aerial application continued once a year though the entirety of the study. In addition, terrestrial soil samples were sampled from areas sprayed to understand dissipation rates and herbicide transport via sediments washing away during rainfall runoff. The concentrations present in water and sediment samples were compared to ecological benchmarks and characterized within the context of the environmental conditions of the park setting. Of the 48 water samples collected and analyzed for glyphosate and AMPA, 10.4 percent and 14.6 percent were detected above the laboratory minimum detection limit, respectively. Mean water concentrations, calculated using specific statistical methods for non-detects, were equal to the laboratory minimum detection limit of 0.02 microgram per liter for samples collected in all the watersheds. In aquatic sediments, glyphosate and AMPA were detected in 10.7 and 25.0 percent of the samples, whereas 89.5 and 100 percent of the terrestrial soil samples had detections for glyphosate and AMPA, respectively. Mean aquatic sediment concentrations were 1.13 and 4.42 micrograms per kilogram (μg/kg) for glyphosate and AMPA, respectively. Mean terrestrial soil concentrations were orders of magnitude greater than water and aquatic sediment with concentrations of 678 μg/kg for AMPA and 1,240 μg/kg for glyphosate. Hours after glyphosate-based herbicide was applied, the concentrations of glyphosate and AMPA were present in terrestrial soil samples near or above the laboratory maximum detection limit of 5,000 μg/kg. The Box Canyon watershed was the most intensively treated watershed in terms of total land area treated, total amount of GBH applied, and number of years treated. The frequent and large volume of treatment resulted in the highest number of detections of glyphosate and AMPA in water (3 and 7 detections, respectively) and in aquatic sediment (2 and 6 detections, respectively) samples. In comparison, the other two watersheds had two or fewer detections for glyphosate and AMPA in water and aquatic sediment. Glyphosate detected in pools was associated with increased rainfall closer in time to the last herbicide treatment. Glyphosate and AMPA concentration ratios above one, along with stable-isotope and tritium results, indicated that runoff processes were the primary transport mechanism for the two compounds when found in streams and pools rather than subsurface recharge or deeper flow paths. One pool in a small tributary of Box Canyon consistently had detections of glyphosate and AMPA in aquatic sediments, but these frequent concentrations were likely related to the intensive application upstream, near the steep terrain above the head of the channel that supplies the downstream pool. Intense flows during summer rainfall events move treated sediments into this channel where vegetation and the incised bedrock banks of the pool retained those sediments and ultimately led to frequent detections of both compounds. Isotope results in most of the pools and tinajas indicated that the water source had residence time representative of recently recharged waters, on the order of years. No water concentrations exceeded published criteria for human health or aquatic life. Median and maximum glyphosate and AMPA water concentrations were lower than those reported in other national assessments, but maximum concentrations observed in individual runoff samples were higher than median concentrations measured in the national assessments. A similar finding was observed with aquatic sediment concentrations measured in the Rincon Mountain District. Results from the study were compared and assessed in the context of other studies examining GBHs and their effects on amphibians, fish, and macroinvertebrates. This comparison was used to generalize the potential risk to aquatic species similar to those species in the Rincon Mountain District. Concentrations of published effect levels were several orders of magnitude greater than the highest concentration detected in water at the Rincon Mountain District. Most published studies evaluate acute and chronic toxicity for glyphosate and GBHs, and these criteria may not be representative of environmental conditions in the Rincon Mountain District. The classic lethal dose studies conducted in a controlled laboratory setting may not be suitable for comparison to the longer, variable, low-dose exposure conditions in the pools and tinajas in the Rincon Mountain District. However, this study determined that the fate of GBHs transported from treated areas to potential aquatic habitat was highly variable in occurrence, timing, and concentrations. This variability in glyphosate concentrations was too high, and the potential exposure was determined to be far too complex to directly compare with the results from controlled studies. This study provides the first information collected on GBHs used to control invasive buffelgrass in a remote, mountainous, and semiarid setting. The information about the transport and fate of herbicide application near aquatic habitat will help to inform managers about the broader ecosystem implications and provide useful information to other agencies implementing buffelgrass remediation strategies near aquatic habitat.

Arizona↗

USGS2009

Pesticides in ground water in selected agricultural land-use areas and hydrogeologic settings in Pennsylvania, 2003-07

This report was prepared by the U.S. Geological Survey (USGS) in cooperation with the Pennsylvania Department of Agriculture (PDA) as part of the Pennsylvania Pesticides and Ground Water Strategy (PPGWS). Monitoring data and extensive quality-assurance data on the occurrence of pesticides in ground water during 2003–07 are presented and evaluated; decreases in the land area used for agriculture and corresponding changes in the use of pesticides also are documented. In the Pennsylvania ground waters assessed since 2003, concentrations of pesticides did not exceed any maximum contaminant or health advisory levels established by the U.S. Environmental Protection Agency; PPGWS actions are invoked by the PDA at fractions of these levels and were needed only in areas designated by the PDA for special ground-water protection. Previous investigations through 1998 of pesticides in Pennsylvania ground water identified land use, as a surrogate for pesticide use, and rock type of the aquifer combined with physiography as key hydrogeologic setting variables for understanding aquifer vulnerability to contamination and the common occurrence of atrazine and metolachlor in ground water. Of 20 major hydrogeologic settings in a framework established in 1999 for pesticide monitoring in Pennsylvania, 9 were identified as priorities for data collection in order to change the monitoring status from "inadequate" to "adequate" for the PPGWS. Agricultural and forested land-use areas are decreasing because of urban and suburban growth. In the nine hydrogeologic settings evaluated using 1992 and 2001 data, decreases of up to 12 percent for agricultural land and 10 percent for forested land corresponded to increases of up to 11 percent for urban land. Changes in agricultural pesticide use were computed from crop data. For example, from 1996 to 2004–05, atrazine use declined by about 15 percent to 1,314,000 lb/yr (pounds per year) and metolachlor use increased by about 20 percent to 895,000 lb/yr; these compounds are the two most-used agricultural pesticides statewide. In 2003–07, a baseline assessment of pesticides was conducted in five of nine hydrogeologic settings with inadequate monitoring data—the Blue Ridge crystalline and Triassic Lowland siliciclastic, Eastern Lake surficial, Devonian-Silurian carbonate, Great Valley siliciclastic, and Northeastern Glaciated surficial settings. Between 20 and 30 wells in each setting were monitored. Of the 126 wells sampled, 96 well-water samples were analyzed for at least 52 pesticide compounds at the USGS National Water Quality Laboratory (NWQL) using a method with a minimum reporting level (MRL) at or above 0.002 µg/L (micrograms per liter). Of the 96 well waters analyzed by NWQL, 43 had measureable concentrations of one or more pesticides. Atrazine and (or) deethylatrazine (CIAT), a degradation product of atrazine, were reported at or above the MRL in 39 of the 43 well waters. Neither atrazine nor CIAT were reported at concentrations exceeding 0.10 µg/L; all measured concentrations in these five settings were below PPGWS action levels. Metolachlor was present in 7 of the 43 well waters with measureable concentrations of 1 or more pesticides; however, concentrations were below the MRL. The other 30 samples (10 of 20 wells in the Blue Ridge crystalline and Triassic Lowland siliciclastic setting and all 20 wells in the Eastern Lake surficial setting) were analyzed for at least 19 pesticide compounds at the Pennsylvania Department of Environmental Protection Laboratory (PADEPL); the PADEPL reported no concentrations of pesticides at or above an MRL of 0.10 µg/L. Statistical tests using the NWQL analytical results showed correlations between pesticide occurrence and two indicators of water-quality degradation—the occurrence of total coliform bacteria and nitrate concentration. A 2 × 2 contingency-table test indicated a relation between presence or absence of atrazine or metolachlor and presence or absence of bacteria only for the 10 wells representing the Blue Ridge crystalline and Triassic Lowland siliciclastic setting. Results of Spearman’s rank test showed strong positive correlations in the Devonian-Silurian carbonate setting between 1) the number of pesticides above the MRLs and nitrate concentration, and 2) concentrations of atrazine and nitrate. Atrazine concentration and nitrate concentration also showed a statistically significant positive correlation in the Great Valley siliciclastic setting. An additional component of baseline monitoring was to evaluate changes in pesticide concentration in water from wells representing hydrogeologic settings most vulnerable to contamination from pesticides. In 2003, 16 wells originally sampled in the 1990s were resampled—4 each in the Appalachian Mountain carbonate, Triassic Lowland siliciclastic, Great Valley carbonate, and Piedmont carbonate settings. Nine of these wells, where pesticide concentrations from 1993 and 2003 were analyzed at the NWQL, were chosen for a paired-sample analysis using concentrations of atrazine and metolachlor. A statistically significant decrease in atrazine concentration was identified using the Wilcoxon signed-rank test (p = 0.004); significant temporal changes in metolachlor concentrations were not observed (p = 0.625). Monitoring in three areas of special ground-water protection, where selected pesticide concentrations in well water were at or above the PPGWS action levels, was done at wells BE 1370 (Berks County, Oley Township), BA 437 (Blair County, North Woodbury Township), and LN 1842 (Lancaster County, Earl Township). Co-occurrence of pesticide-degradation products with parent compounds was documented for the first time in ground-water samples collected from these three wells. Degradation products of atrazine, cyanazine, acetochlor, alachlor, and metolachlor were commonly at larger concentrations than the parent compound in the same water sample. Pesticide occurrence in water from wells neighboring the hot-spot wells was highly variable; however, the same sets of pesticide compounds that were present in wells BA 437, BE 1370, and LN 1842 were present to some degree in water from neighboring wells. To evaluate temporal changes in concentration, nonparametric statistical tests were used to determine overall and seasonal monotonic trends. Concentrations of alachlor, atrazine, metolachlor, and nitrate were examined using the 5-year (2003–07) and the long-term data from wells BA 437 and LN 1842 (1996–2007 and 1995–2007, respectively), and the long-term data for well BE 1370 (1998–2007); results showed either downward trends or no trends. Trends in acetochlor concentrations were tested only at well LN 1842 using the 5-year data; no trends were observed. Homogeneity of trend tests indicated statistically significant downward concentration trends in the long-term data were due to seasonal trends as follows: BA 437—alachlor and atrazine (summer); BE 1370—atrazine and metolachlor (winter) and alachlor (winter and spring); LN 1842—alachlor (summer and fall) and atrazine (spring and fall).

Pennsylvania↗

USGS2018

Streamflow and selenium loads during synoptic sampling of the Gunnison River and its tributaries near Delta, Colorado, November 2015

In response to the need for more information about selenium (Se) sources and transport, the U.S. Geological Survey, in cooperation with the Colorado Water Conservation Board, completed a study that characterized Se loads in a reach of the Gunnison River between Delta and Grand Junction, Colo. This report identifies where possible dissolved Se loading is occurring in a study reach in the Lower Gunnison River Basin between Delta and Grand Junction on November 19, 2015. The combined Se loads from the Gunnison River at Delta (site 3) and the Uncompahgre River at Delta (site 4) were about 95 percent of the load at the furthest downstream main-stem sample location at the Gunnison River below Roubideau Creek near Delta (site 20) (31.6 and 33.4 pounds per day, respectively), indicating that about 5 percent of the total load (1.8 pounds) was potentially contributed from diffuse groundwater inflow. Main-stem streamflow accounting during November 2015 in a downstream direction was not supportive of substantial net gains or losses in the main-stem water balance. The cumulative load from measured tributary inflows downstream from the Uncompahgre River confluence only amounted to 1.2 pounds of the main-stem loads (1.8 pounds gain) from site 4 to the end of the synoptic reach at site 20. The remaining 33 percent (about 0.6 pounds) of Se load increase was not accounted for by known tributary inflow. Yet, the small changes in the streamflow mass balance in the same reach does not strongly support a net inflow explanation for the apparent gain in load. Based on the results of the loading and streamflow analysis, when errors in the loading estimates are considered, there is no conclusive evidence of an appreciable amount of Se load that is unaccounted for in the study reach of the Gunnison River as was originally hypothesized. Differences determined from comparisons of cumulative tributary loads and Gunnison River main-stem loads for this study are within error estimates of the main-stem loads.

Colorado↗

USGS2019

Response of vegetation in open and partially wooded fens to prescribed burning at Seney National Wildlife Refuge

The health and function of northern peatlands, particularly for fens, are strongly affected by fire and hydrology. Fens are important to several avian species of conservation interest, notably the yellow rail ( Coturnicops noveboracensis ). Fire suppression and altered hydrology often result in woody encroachment, altering the plant community and structure. Woody encroachment and its effects on biodiversity have become an increasing concern in the conservation and management of plant communities. This study evaluated the effects of spring and summer prescribed burns on the plant community, cover, and structure in open and partially wooded fens at Seney National Wildlife Refuge, Michigan, using a before-after-control-impact design. Paired, 1-hectare blocks were established in two fen areas, C3 and Marsh Creek, and data were collected for 2 years before burning (2006–7) and 3 years after burning (2008–10). We used generalized linear mixed models and ordination to assess differences among four treatments: C3 control, C3 spring burn (May 2008), Marsh Creek control, and Marsh Creek summer burn (July 2008); results from a block burned under drier conditions in July 2007 also are reported. Variables include water depth; litter depth; graminoid height; species richness and diversity; percent cover of plant taxa, mosses, and open area; shrub height, number of patches, and cover; and visual obstruction readings. The 2008 prescribed burns were done under moderate fire conditions, whereas the 2007 summer burn on one block was done under high fire conditions because of prolonged drought. We identified 104 plant taxa over the 5 years and noted differences between C3 and Marsh Creek communities. We examined data for effects of treatment, year, and year × treatment interactions for percent open and the 28 most common taxa. Most differences among treatments were related to natural differences in the plant community and hydrology between the two areas rather than fire effects; year effects were likely related to annual differences in water conditions. We detected few effects of spring burning in C3, even in the same year of burning. In Marsh Creek, most treatment effects were in 2008, when data were collected within 3 weeks of burning. Some fire effects there, however, persisted one to two growing seasons (2009, 2010) and two to three growing seasons in the block burned in the more intense summer 2007 fire. Effects of burning on shrub measures were more apparent on summer-burned blocks, but most measures returned to preburn conditions by 2010. Our results demonstrate the heterogeneity of plant community and environmental conditions of fens within and among years and the interactions of water conditions with burning. The results also demonstrate that neither single spring nor summer burning under moderate fire conditions are effective in setting back woody cover. Maintaining more open conditions in fens may require different approaches to water management, more frequent fires, more aggressive fire management, or a combination of tools to control woody cover.

Michigan↗