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At least 1,153 records · Page 64Linked to original sources
USGS1949

Chromite deposits near Seiad and McGuffy Creeks, Siskiyou County, California

The chromite deposits described in this report are in northcentral Siskiyou County, Calif. They are in two long tabular masses of peridotite which lie end to end and trend northnorthwest across the valley of the Klamath River. The Seiad Creek-Red Butte mass extends 10 miles north of the river and the Hamburg-McGuffy Creek mass 8 miles south. The outcrops of both are from 1 to 2 miles wide. The rocks that bound the peridotite on the east are thoroughly reconstructed schist and those bordering it to the west are less-metamorphosed volcanic and sedimentary rocks. The schists have been considered to be pre-Cambrian age, whereas the rocks to the west are probably of early Triassic age. Strictly speaking, the chromite-bearing masses are complex bodies of ultramafic rock consisting mainly of dunite but also containing saxonite, lherzolite, pyroxeni,te and hornblendite (listed in order of abundance). Only the dunite contains chromite ore. The tabular peridotite masses lie parallel to planar structures in the older rocks, but in their internal make-up no large- scale structural pattern has been recognized. The most con- spicuous internal structure is the linear arrangement of the chromite-rich schlieren in the ore-bearing parts of the peri- dotite. A typical ore body may include parts made up of evenly disseminated chromite; the richest and largest bodies, however, are made up of concentrated, closely spaced chromite schlieren of different size, shape, and richness. Some schlieren contain 80 to 95 percent of chromite, but most of them contain 25 percent or less, and the ore must be concentrated to yield a marketable product. Chromite is composed of chromic oxide, alumina, ferric oxide, ferrous oxide, and magnesia in different proportions. Hence the ~bromic-oxide content of pure chromites differ. It is consistently high for the chromite from this area as it ranges from 55 to 58 percent. The iron content is likewise consistently high, ranging from 14 to 21 percent. The total reserves of indicated and inferred ore as of May 1945 were 274,500 short tons, which would average 8 percent Cr 2 O 3 . The Seiad Creek mine (Mountain View group) contained the largest deposit; reserves amounted to 212,000 short tons. The McGuffy Creek mine contained 50,000 short tons of indicated and inferred ore. Four other deposits, the Emma Bell, Kangaroo, Mountain, Fairview, and Ladd, contain a few thousand tons of ore each.

California↗
USGS2022

Geoenvironmental model for roll-type uranium deposits in the Texas Gulf Coast

Geoenvironmental models were formulated by the U.S. Geological Survey in the 1990s to describe potential environmental effects of extracting different types of ore deposits in different geologic and climatic regions. This paper presents a geoenvironmental model for roll-front (roll-type) uranium deposits in the Texas Coastal Plain. The model reviews descriptive and quantitative information derived from environmental studies and existing databases to depict existing conditions and potential environmental concerns associated with mining this deposit type. This geoenvironmental model describes how features of the deposits including host rock; ore and gangue mineralogy; geologic, hydrologic, and climatic settings; and mining methods (legacy open-pit and in situ recovery [ISR]) influence potential environmental effects from mining. Element concentrations in soil and water are compared to regulatory thresholds to depict ambient surface water and groundwater conditions. Although most open-pit operations in this region have been reclaimed, concerns remain about groundwater quality at three of the four former mills that supported former open-pit mines and are undergoing closure activities. The primary environmental concerns with ISR mining are (1) radon gas at active ISR operations, (2) radiation or contaminant leakage during production and transport of ISR resin or yellowcake, (3) uranium excursions into groundwater surrounding active ISR operations, and (4) contamination of groundwater after ISR mining. Although existing regulations attempt to address these concerns, some problems remain. Researchers suggest that reactive transport modeling and a better understanding of geology, stratigraphy, and geochemistry of ISR production areas could minimize excursions into surrounding aquifers and improve results of groundwater restoration.

Texas↗
USGS2009

Response to critique by lucas et al. (2009) of paper by Fassett (2009) documenting Paleocene dinosaurs in the San Juan Basin

In this issue of Palaeontologia Electronica Lucas, et al. (2009) question the validity f the Fassett (2009) paper that presented evidence for Paleocene dinosaurs in the San Juan Basin of New Mexico and Colorado. Their challenges focus primarily on the lithostratigraphy, palynology, and paleomagnetism of the dinosaur-bearing Ojo Alamo Sandstone, shown by Fassett to be of Paleocene age. The lithostratigraphy of the Ojo Alamo is addressed by Lucas et al. (2009) based on detailed studies of outcrops of this formation in two relatively small areas in the southern San Juan Basin where Ojo Alamo dinosaur fossils have been found. When viewed over its 13,000 km2 extent, the Ojo Alamo is seen to be a much more complex formation than these authors recognize, thus their perception and description of the lithostratigraphy of this rock unit is limited and provincial. Fassett (2009) presented a detailed discussion of the palynology of the rocks adjacent to the Cretaceous-Tertiary (K-T) interface in the San Juan Basin, including a 67-page appendix and 25 tables listing the 244 palynomorph species identified from these strata. The Ojo Alamo Sandstone produced 103 palynomorphs from five principal localities including one especially prolific sample set from drill core through K-T strata. Without exception, all samples collected from the Ojo Alamo Sandstone for palynologic analysis were found to contain Paleocene palynomorph assemblages. Lucas et al. challenge only one Ojo Alamo palynomorph assemblage from one of the five areas studied, stating that they were unable to find palynomorph-productive samples at that locality. They submit no new palynologic data that refutes the Paleocene palynologic age of the Ojo Alamo Sandstone. In addressing the paleomagnetism of the Ojo Alamo, these authors dismiss the presence of a critical normal-polarity magnetochron discovered in the lower part of the Ojo Alamo - magnetochron C29n.2n of Fassett (2009) with no evidence to justify this dismissal. This magnetochron has been identified at five localities in the basin, thus its existence seems unquestionable. At the Mesa Portales locality, this normal chron was found in Ojo Alamo strata containing Paleocene palynomorph assemblages verifying its identification as chron C29n. Other minor arguments of Lucas et al. (2009) are also addressed in this paper. In sum, Lucas et al. (2009) present no new data to contradict the data presented in Fassett (2009).

Palaeontologia Electronica↗
USGS2023

Geology and undiscovered resource assessment of the potash-bearing, Middle Devonian (Givetian), Prairie Evaporite, Elk Point Basin, Canada and United States

The U.S. Geological Survey (USGS) assessed undiscovered potash resources in the Elk Point Basin in Canada and the United States as part of a global mineral resource assessment. The Elk Point Basin is a large, Middle Devonian (Givetian) intracratonic evaporite basin covering approximately 1,200,000 square kilometers (km 2 ) and filled mainly with marine evaporite and minor clastic sedimentary rocks that contain stratabound potash-bearing salt. The potash-bearing salt is concentrated in four stratigraphic members (Patience Lake, Belle Plaine, White Bear, and Esterhazy) in the upper 100 meters (m) of the Prairie Evaporite and are separated by beds of halite (NaCl) that contain lesser—presently non-economic—amounts of sylvite (KCl) and carnallite (KMgCl 3 ·6H 2 O). The principal ore-bearing salt contains mainly sylvite. Four permissive tracts were defined that permit the presence of undiscovered stratabound potash (both sylvite- and carnallite-bearing salt) using geological criteria. Permissive tracts are defined by the spatial extent of each stratigraphic member that is at least 1 m thick, are less than 3 kilometers (km) from the surface, contain at least 4 percent equivalent potassium oxide (K 2 O), and contain the currently known resources. The permissive tracts include known potash deposits and potash occurrences as wells or mines not in production and show where undiscovered potash resources may be present. Well data are used to define the extent, thickness, average K 2 O equivalent grades, and volumes of each member. Data were supplied by the Saskatchewan Geological Survey or were obtained from published National Instrument (NI) 43-101 technical reports and other published reports, such as annual 10-K reports or news releases. The Elk Point Basin is the world’s largest source of potash, producing 23.0 million metric tons (Mt) of potassium chloride (KCl) (the equivalent of about 14.4 Mt of K 2 O) in 2018. In terms of global importance, the Elk Point Basin may contain 40 to greater than 50 percent of the world’s potash resources. Since 1962, potash companies have mined more than 1.5 trillion metric tons of ore containing 605 Mt of KCl (the equivalent of about 380 Mt of K 2 O). The total value of the ore produced through 2018 is on the order of $70 trillion (CAD). Potash is currently produced from eight conventional and three underground solution mines at depths ranging from 900 m to nearly 1,800 m. Estimates of the amount of potash in the Elk Point Basin vary considerably and the data and methods used in those estimations are not well documented. Known potash resources are approximately 99 billion metric tons (Bt) of ore containing 22 Bt of K 2 O equivalent. As a result of new mine openings and increased production capacity at existing mines, the total production capacity of mines in the Elk Point Basin has increased significantly (to about 32.8 Mt of KCl or 22.8 Mt of K 2 O equivalent per year). Additional production capacity of about 31 Mt of KCl (or 17 Mt of K 2 O equivalent) per year could be realized over the next decade if several current (as of 2019) exploration and development projects reach production status. Stratabound potash-bearing salt of the Prairie Evaporite presently underlies a total area of about 188,000 km 2 and has a total volume of about 2,690 cubic kilometers (km 3 ). Post-depositional solution processes considerably modified the mineralogy and presence of the potash-bearing salt. These changes had a profound effect on the volume and grade of potash resources that remained in the Prairie Evaporite and are a major consideration of exploration and mining operations as well as in this assessment of undiscovered potash resources. This USGS assessment includes the locations and possible amounts of undiscovered potash resources in the Prairie Evaporite. Volumes for each stratigraphic member were computed using member thicknesses and areal extent modified by actual, estimated geologic loss owing to salt dissolution and extraction ratios, as well as estimated distribution of carnallite and sylvite. Both sylvite- and carnallite-bearing salts were assessed for potash in this study. The assessment uses modern published grade and tonnage data. The amount of undiscovered potash is estimated by using Monte Carlo simulations to combine volume estimates of the potash-bearing members with probability distributions for average grade and bulk density. Mean potash grades (expressed as percentage of K 2 O equivalent) calculated using drill core analyses are 17.76 for the Patience Lake Member, 15.98 for the Belle Plaine Member, 10.66 for the White Bear Member, and 15.30 for the Esterhazy Member. Geologic losses reported as extraction ratios during mining may range from 27.5 to 41.6 percent and are dependent on mining method and local geologic conditions. The assessment determined that mean estimated undiscovered K 2 O equivalent resources for the Patience Lake, Belle Plaine, White Bear, and Esterhazy Members are 340, 220, 34, and 190 Bt, respectively, and estimated a total mean of 790 Bt for the entire Prairie Evaporite above a depth of 3 km. The total mineralized rock tonnage is estimated to be about 5,000 Bt. Most of the assessed potash is located within Saskatchewan with lesser amounts in Alberta and Manitoba as well as Montana and North Dakota within the United States. Although carnallite is mined for potash in Europe, it has historically been avoided in mining plans for potash-producing companies in Saskatchewan because of mining, processing, and grade considerations. Carnallite-rich salt is locally present in concentrations and volumes that could be a significant resource of magnesium chloride (MgCl 2 ) obtained as a byproduct of processing the carnallite for potash. Previously estimated reserves (not NI 43-101 compliant) of mineralized material from 1955 to 2019 are 695 Mt at 22.1 percent MgCl 2 . The total amount of K 2 O equivalent as carnallite was estimated during this USGS assessment to be about 120 Bt (or 180 Bt KCl). With uncertainties in defining the areal extent of carnallite in each of the potash-bearing members, the amount of MgCl 2 as carnallite in the Elk Point Basin could be approximately 180 Bt.

Elk Point basin↗
USGS2023

Geologic map of Okmok Volcano

The geologic map and description of map units presented here cover approximately 880 km2 of northeastern Umnak Island, Aleutian Islands, Alaska. This report focuses on Okmok Volcano and its eruptive products and updates the mid-20th-century geologic map of Byers (1959). Mapped deposits reflect the state of the volcano just prior to the 2008 eruption. Published information about other portions of Umnak Island geology, including Mount Recheshnoi and Mount Vsevidof, can be found in Byers (1959). The 2008 eruption and its deposits are described in Larsen and others (2009, 2013, 2015). Okmok Volcano is one of 54 historically active volcanoes in the Alaska–Aleutian volcanic arc that stretches across southern mainland Alaska and the Aleutian Islands (fig. 1; Wood and Kienle, 1990; Miller and others, 1998; Cameron and others, 2020). The highest point of the modern Okmok Caldera is along the caldera’s northern rim, 967 m in elevation, and formally named “Mount Okmok” (U.S. Board on Geographic Names, www.usgs.gov/core-science-systems/ngp/boardon-geographic-names/domestic-names). Okmok Volcano dominates the northeastern portion of Umnak Island, which is 100 km southwest of Unalaska/Dutch Harbor and 1,400 km southwest of Anchorage (figs. 1, 2). The Port of Dutch Harbor on Unalaska Island produces the highest volume of seafood for any port in the United States (see fisheries.noaa.gov/resource/document/fisheries-united-states-2018-report). Unalaska city and the Port of Dutch Harbor have been impacted by ash fall and drifting ash clouds from Okmok Volcano’s explosive eruptions as recently as 2008. Holocene and late Pleistocene volcanic rocks and deposits of Okmok Volcano rest upon glaciated Tertiary volcanic and sedimentary rocks (Byers, 1959). The first geologic mapping expedition to Okmok Volcano was by the U.S. Geological Survey (USGS) after the 1945 eruption, largely in response to concerns about volcanic hazards to U.S. military activities in the Aleutians Islands (Byers and others, 1947, 1959; Byers and Brannock, 1949; Byers, 1955, 1959, 1961). The State of Alaska conducted further mapping and geochemical studies as part of its geothermal exploration program in the 1980s (Nye, 1983; Nye and Reid, 1986; Motyka and others, 1993). Additional modern geological work focused on Okmok Volcano and the rest of Umnak Island to address the geochemistry and origin of primary Aleutian arc magmas and subduction zone mass recycling (Marsh, 1982; Brophy and Marsh, 1986; Nye and Reid, 1986; Myers and Marsh, 1987; Miller and others, 1992; Fournelle and others, 1994; Kay and Kay, 1994). In 1998, the Alaska Volcano Observatory (AVO) began a multi-year effort to expand geophysical monitoring in the central Aleutians Islands, including at Okmok Volcano. As part of this effort, AVO geologists from the University of Alaska Fairbanks Geophysical Institute (UAF/GI), the Alaska Division of Geological & Geophysical Surveys (DGGS), and USGS also began a renewed effort to document Okmok Volcano’s recent eruption products. The project started with reconnaissance fieldwork to document and sample products from the 1997 eruption within Okmok Caldera. This evolved into an effort to produce an updated geologic map of Okmok Volcano and gather more information about its eruptive history and hazards. Three significant eruptions occurred at Okmok Volcano in 1958, 1997, and 2008—after fieldwork had been conducted for the original 1:63,360-scale geologic map produced by Byers (1959)—resulting in new volcanic deposits not previously described. Okmok Volcano is one of the most frequently active volcanoes in the Aleutian volcanic arc. Seismic and geodetic monitoring indicate ongoing unrest at Okmok Volcano since at least 1997. Geodetic observations of inflation before and after the 1997 and 2008 eruptions indicate a nearly continuous input of new magma from a depth consistent with frequent eruptions of basalt and basaltic andesite magmas over the past 200 years (Larsen and others, 2013; Lu and others, 2000, 2003, 2005; Mann, 2002; Mann and others, 2002). To better understand the likelihood and character of future eruptions from Okmok Volcano, it is necessary to understand its past behavior, including eruptions since the first geologic map was published by Byers (1959).

Alaska↗
USGS2012

Sequestration of non-pure carbon dioxide streams in iron oxyhydroxide-containing saline repositories

Iron oxyhydroxide, goethite (α-FeOOH), was evaluated as a potential formation mineral reactant for trapping CO 2 in a mineral phase such as siderite (FeCO 3 ), when a mixture of CO 2 -SO 2 flue gas is injected into a saline aquifer. Two thermodynamic simulations were conducted, equilibrating a CO 2 -SO 2 fluid mixture with a NaCl-brine and Fe-rich rocks at 150 °C and 300 bar. The modeling studies evaluated mineral and fluid composition at equilibrium and the influence of pH buffering in the system. Results show siderite precipitates both in the buffered and unbuffered system; however, the presence of an alkaline pH buffer enhances the stability of the carbonate. Based on the model, an experiment was designed to compare with thermodynamic predictions. A CO 2 -SO 2 gas mixture was reacted in 150 ml of NaCl-NaOH brine containing 10 g of goethite at 150 °C and 300 bar for 24 days. Mineralogical and brine chemistry confirmed siderite as the predominant reaction product in the system. Seventy-six mg of CO 2 are sequestered in siderite per 10 g of goethite.

International Journal of Greenhouse Gas Control↗
USGS2017

Saltwater intrusion in the Floridan aquifer system near downtown Brunswick, Georgia, 1957–2015

Introduction The Floridan aquifer system (FAS) consists of the Upper Floridan aquifer (UFA), an intervening confining unit of highly variable properties, and the Lower Floridan aquifer (LFA). The UFA and LFA are primarily composed of Paleocene- to Oligocene-age carbonate rocks that include, locally, Upper Cretaceous rocks. The FAS extends from coastal areas in southeastern South Carolina and continues southward and westward across the coastal plain of Georgia and Alabama, and underlies all of Florida. The thickness of the FAS varies from less than 100 feet (ft) in aquifer outcrop areas of South Carolina to about 1,700 ft near the city of Brunswick, Georgia. Locally, in southeastern Georgia and the Brunswick– Glynn County area, the UFA consists of an upper water-bearing zone (UWBZ) and a lower water-bearing zone (LWBZ), as identified by Wait and Gregg (1973), with aquifer test data indicating the upper zone has higher productivity than the lower zone. Near the city of Brunswick, the LFA is composed of two permeable zones: an early middle Eocene-age upper permeable zone (UPZ) and a highly permeable lower zone of limestone (LPZ) of Paleocene and Late Cretaceous age that includes a deeply buried, cavernous, saline water-bearing unit known as the Fernandina permeable zone. Maslia and Prowell (1990) inferred the presence of major northeast–southwest trending faults through the downtown Brunswick area based on structural analysis of geophysical data, northeastward elongation of the potentiometric surface of the UFA, and breaches in the local confining unit that influence the area of chloride contamination. Pronounced horizontal and vertical hydraulic head gradients, caused by pumping in the UFA, allow saline water from the FPZ to migrate upward into the UFA through this system of faults and conduits. Saltwater was first detected in the FAS in wells completed in the UFA near the southern part of the city of Brunswick in late 1957. By the 1970s, a plume of groundwater with high chloride concentrations had migrated northward toward two major industrial pumping centers, and since 1965, chloride concentrations have steadily increased in the northern part of the city. In 1978, data obtained from a 2,720-ft-deep test well (33H188) drilled south of the city showed water with a chloride concentration of 33,000 milligrams per liter (mg/L), suggesting the saltwater source was located below the UFA in the Fernandina permeable zone (FPZ) of the LFA. All U.S. Geological Survey (USGS) data collected for this study, including groundwater levels in wells and water-chemistry data, are available in the USGS National Water Information System.

Georgia↗
USGS2006

Oil and gas resources of the Arctic Alaska Petroleum Province

The Arctic Alaska Petroleum Province, encompassing all the lands and adjacent Continental Shelf areas north of the Brooks Range-Herald arch, is one of the most petroleum-productive areas in the United States, having produced about 15 billion bbl of oil. Seven unitized oil fields currently contribute to production, and three additional oil fields have been unitized but are not yet producing. Most known petroleum accumulations involve structural or combination structural-stratigraphic traps related to closure along the Barrow arch, a regional basement high, which has focused regional hydrocarbon migration since Early Cretaceous time. Several oil accumulations in stratigraphic traps have been developed in recent years. In addition to three small gas fields producing for local consumption, more than 20 additional oil and gas discoveries remain undeveloped. This geologically complex region includes prospective strata within passive-margin, rift, and foreland-basin sequences. Oil and gas were generated from multiple source rocks throughout the region. Although some reservoired oils appear to be derived from a single source rock, evidence for significant mixing of hydrocarbons from multiple source rocks indicates a composite petroleum system. Both extensional and contractional tectonic structures provide ample exploration targets, and recent emphasis on stratigraphic traps has demonstrated a significant resource potential in shelf and turbidite sequences of Jurassic through Tertiary age. Recent estimates of the total mean volume of undiscovered resources in the Arctic Alaska Petroleum Province by the U.S. Geological Survey and U.S. Minerals Management Service are more than 50 billion bbl of oil and natural-gas liquids and 227 trillion ft3 of gas, distributed approximately equally between Federal offshore and combined onshore and State offshore areas.

Alaska↗
USGS1998

Geologic framework and hydrogeologic characteristics of the outcrops of the Edwards and Trinity aquifers, Medina Lake area, Texas

The hydrogeologic subdivisions of the Edwards aquifer outcrop in the Medina Lake area in Medina and Bandera Counties generally are porous and permeable. The most porous and permeable appear to be hydrogeologic subdivision VI, the Kirschberg evaporite member of the Kainer Formation; and hydrogeologic subdivision III, the leached and collapsed members, undivided, of the Person Formation. The porosity of the rocks in the Edwards aquifer outcrop is related to depositional or diagenetic elements along specific stratigraphic horizons (fabric selective) and to dissolution and structural elements that can occur in any lithostratigraphic horizon (not fabric selective). Permeability depends on the physical properties of the rock such as size, shape, and distribution of pores. The Edwards aquifer has relatively large porosity and permeability resulting, in part, from the development or redistribution of secondary porosity. Lithology, stratigraphy, diagenesis, and karstification account for the effective porosity and permeability in the Edwards aquifer outcrop. Karst features that can greatly enhance effective porosity and permeability in the Edwards aquifer outcrop include sinkholes, dolines, and caves. Field observations in the Medina Lake area confirm the findings of previous investigators that Medina Lake mostly overlies rocks of the upper member of the Glen Rose Limestone. The channel downstream of Medina Dam to the upper end of Diversion Lake also overlies the upper member of the Glen Rose Limestone. Most of Diversion Lake overlies a thin section of the Edwards aquifer— hydrogeologic subdivision VIII (basal nodular member) and the basal part of hydrogeologic subdivision VII (dolomitic member). Hydrogeologic subdivisions VIII and VII might be hydraulically connected to Medina Lake at high lake stages. The Trinity aquifer, which crops out in the northern part of the Medina Lake area and underlies the Edwards aquifer in the southern part, is much less permeable and productive than the Edwards aquifer. Where the Trinity aquifer underlies the Edwards, the Trinity acts as a lower confining unit on the Edwards.

Texas↗
USGS1996

Ground water: the hidden resource

Ground water is water underground in saturated zones beneath the land surface. Contrary to popular belief, ground water does not form underground "rivers." It fills the pores and fractures in underground materials such as sand, gravel, and other rock. If ground water flows from rock materials or can be removed by pumping from the saturated rock materials In useful amounts, the rock materials are called aquifers. Ground water moves slowly, typically at rates of 7 to 60 centimeters per day in an aquifer. As a result, water could remain in an aquifer for hundreds or thousands of years. Ground water is the source of about 40 percent of water used for public supplies and about 38 percent of water used for agriculture in the United States.

General Information Product↗
USGS1979

Low temperature basalt alteration by sea water: an experimental study at 70°C and 150°C

Basaltic glass and diabase were reacted with seawater at 70°C at 1 bar and 150°C at 500 bars to determine fluid composition and alteration mineralogy. All experiments were performed at a water/ rock mass ratio of 10. The changes in seawater chemistry depended on temperature and crystallinity of the basalt. The experiment at 70°C produced a slight but continuous loss of Mg, Na and K and enrichment of Ca and SiO 2 in the seawater while pH decreased slowly. At 150°C, in contrast, Mg and SO 4 were quickly and quantitatively removed while Ca, SiO 2 , Na, K, Fe, Mn and Ba were added to the seawater. pH rose to values between 5.5 and 6.5 after an initial drop to lower values. Basalt glass reacted more extensively at 150°C than diabase. Smectite was the major alteration product (iron-rich saponite) at 150°C for both the glass and diabase experiments. Smectite from the diabase experiment was well crystallized while that from the glass experiment was poorly crystallized. The smectites are similar to smectites found in altered oceanic ophiolitic basalts.

Geochimica et Cosmochimica Acta↗
USGS2020

Isotopic and geochemical assessment of the sensitivity of groundwater resources of Guam, Mariana Islands, to intra- and inter-annual variations in hydroclimate

Assessing the sensitivity of groundwater systems to hydroclimate variability is critical to sustainable management of the water resources of Guam, US territory. We assess spatial and temporal variability of isotopic and geochemical compositions of vadose and phreatic groundwater sampled from cave drip sites and production wells, respectively, to better understand the vulnerability of the freshwater lens on Guam to variability in hydroclimate. We independently evaluate the existing conceptual model of the Northern Guam Lens Aquifer that is largely based on physical, as opposed to geochemical, observations. Sampling was conducted from 2008 to 2015, over which rainfall gradually increased. Major ion geochemistry and Sr isotope values of groundwater show varying influence from soil, limestone bedrock, and seawater. Geochemical modeling that can explain spatial variability in groundwater Na+ and Mg2+ concentrations and Sr/Ca and 87Sr/86 Sr values indicates that groundwater compositions are dominantly controlled by mixing of freshwater with seawater and water-rock interaction. Differences between amount-weighted annual average precipitation δ18 O values and groundwater δ18 O values indicate a recharge bias toward the wet season, consistent with other tropical carbonate island aquifer settings. Intra- and inter-annual variations in Na+ concentrations and δ18 O values in groundwater reflect sensitivity of recharge to seasonal variations in rainfall amount and changes in annual rainfall amounts. Our results indicate the influence of multiple modes of recharge on groundwater compositions and spatial variability in the sensitivity of groundwater to seawater mixing. This sensitivity of the freshwater lens points to the vulnerability of groundwater resources to changes in recharge associated with climate, land-use change, and increases in population.

Journal of Hydrology↗
USGS2024

Utica/Point Pleasant brine isotopic compositions (δ7Li, δ11B, δ138Ba) elucidate mechanisms of lithium enrichment in the Appalachian Basin

Global Li production will require a ~500 % increase to meet 2050 projected energy storage demands. One potential source is oil and gas wastewater (i.e., produced water or brine), which naturally has high total dissolved solids (TDS) concentrations, that can also be enriched in Li (>100 mg/L). Understanding the sources and mechanisms responsible for high naturally-occurring Li concentrations can aid in efficient targeting of these brines. The isotopic composition (δ 7 Li, δ 11 B, δ 138 Ba) of produced water and core samples from the Utica Shale and Point Pleasant Formation (UPP) in the Appalachian Basin, USA indicates that depth-dependent thermal maturity and water-rock interaction, including diagenetic clay mineral transformations, likely control Li concentrations. A survey of Li content in produced waters throughout the USA indicates that Appalachian Basin brines from the Marcellus Shale to the UPP have the potential for economic resource recovery.

Maryland, Ohio, Pennsylvania, West Virginia↗
USGS1980

Geology and hydrology for environmental planning in Washtenaw County, Michigan

Washteaw County is underlain by glacial deposits that range in thickness from about 50 feet to about 450 feet. Underlying the glacial deposits are sedimentary rocks of Mississippian and Devonian age. The youngest of these rocks are the sandstones of the Marshall Formation in the western part of the county; the oldest are the limestones of the Detroit River Group in the southeast corner. Sand and gravel deposits in some places in the county may yield more than 500 gallons per minute of water. Approximately 50 percent of the wells tapping the Marshall Formation, the most reliable bedrock aquifer, can yield as much as 60 gallons per minute. Washtenaw County has sand and gravel deposits that are more than 50 feet thick. The deposits are mined in several areas and are of economic importance. In addition, there may be potential for peat production in the western part of the county and for clay production in the eastern part.

Michigan↗
USGS2020

Geologic map of the Paeroa Fault block and surrounding area, Taupo Volcanic Zone, New Zealand

The Taupo Volcanic Zone (TVZ), New Zealand, is the most productive area of explosive silicic volcanism in the world. Faulted early and middle Pleistocene volcanic products are generally concealed beneath voluminous, generally unfaulted, younger volcanic products. An exception is the southeast margin of the TVZ where the two parallel, northeast-trending Paeroa and Te Weta Fault blocks expose Quaternary volcanic products consisting predominantly of caldera-related, rhyolitic ignimbrites and lacustrine sediments. The Taupo-Reporoa Basin is situated along the eastern part of the map area, and its northernmost part underwent collapse to form Reporoa Caldera. The Paeroa Fault block is the largest exposed fault block within the TVZ, and it encompasses early and middle Pleistocene ignimbrites and sedimentary deposits that are buried throughout the Taupo-Reporoa Basin to the east. This map displays the volcanic and sedimentary geology of ~430 km 2 of the Paeroa Fault block and the adjacent Te Weta Fault block at a scale of 1:50,000. Volcanic and sedimentary rocks are divided into the Reporoa Group, Whakamaru Group, and Huka Group (from oldest to youngest), which are overlain by relatively unfaulted late Pleistocene and Holocene surficial volcanic and sedimentary deposits.

Open-File Report↗
USGS1999

Preliminary digital geologic map of the Penokean (early Proterozoic) continental margin in northern Michigan and Wisconsin

The data on this CD consist of geographic information system (GIS) coverages and tabular data on the geology of Early Proterozoic and Archean rocks in part of the Early Proterozoic Penokean orogeny. The map emphasizes metasedimentary and metavolcanic rocks that were deposited along the southern margin of the Superior craton and were later deformed during continental collision at about 1850 Ma. The area includes the famous iron ranges of the south shore region of the Lake Superior district. Base maps, both as digital raster graphics (DRG) and digital line graphs (DLG) are also provided for the convenience of users. The map has been compiled from many individual studies, mostly by USGS researchers, completed during the past 50 years, including many detailed (1:24,000 scale) geologic maps. Data was compiled at 1:100,000 scale and preserves most of the details of source materials. This product is a preliminary release of the geologic map data bases during ongoing studies of the geology and metallogeny of the Penokean continental margin. Files are provided in three formats: Federal Spatial Data Transfer format (SDTS), Arc export format (.e00) files, and Arc coverages. All files can be accessed directly from the CD-ROM using either ARC/INFO 7.1.2 or later or Arc View 3.0 or later software. ESRI's Arc Explorer, a free GIS data viewer available at the web site: http://www.esri.com/software/arcexplorer/index.html also provides display and querying capability for these files.

Open-File Report↗
USGS1985

Ground-water quality and geochemistry of aquifers associated with coal in the Allegheny and Monongahela formations, southeastern Ohio

Ground water from aquifers associated with coal beds in the Allegheny and Monongahela Formations in southeastern Ohio is predominantly a calcium magnesium bicarbonate type. Sodium bicarbonate type water is less common. Isolated areas of sodium chloride and calcium sulfate types also are present. The water is predominantly very hard, and has a median hardness concentration of 258 milligrams per liter as calcium carbonate and a median dissolved-solids concentration of 436 milligrams per liter. Few wells contain water with dissolved-solids concentrations in excess of 1,000 milligrams per liter. Bicarbonate concentration in ground water was found to be significantly different among coals, whereas concentrations of bicarbonate, hardness, calcium, magnesium, sodium, iron, manganese, and strontium were significantly different between ground water in the Allegheny and Monongahela Formations. Many constituents are significantly correlated, but few correlation coefficients are high. The presence of sulfate or iron is attributed to the kinetic mechanism operating during the oxidation of pyrite. The position along the sulfide or ferrous-iron oxidation pathways controls the reaction products of pyrite found in solution, and the formation of either the sulfate of iron constituents. The availability and rate of diffusion of oxygen in the formations exerts control on the water quality. Discriminant-function analysis correctly classifies 89 percent of the observations into the Allegheny or Monongahela Formations. As a verifications, 39 of 41 observations from another study were correctly classified by formation. The differences in water chemistry between the Allegheny and the Monongahela Formations are gradational and are attributed the oxidation of iron sulfide. The diffusion and availability of oxygen, which controls the chemical reaction, is regulated by the porosity and permeability of the rock with respect to oxygen and the presence or absence of carbonates, which controls the pH.

Water-Resources Investigations Report↗
USGS1977

Hydrologic characteristics of the Madison Limestone, the Minnelusa Formation, and equivalent rocks as determined by well-logging formation evaluation, Wyoming, Montana, South Dakota, and North Dakota

Geophysical logs from wells distributed throughout the Powder River Basin were digitized, processed, and interpreted to get a regional understanding of the lithologic and ground-water characteristics of aquifers in the Madison Limestone and Minnelusa Formation. The percentage of sand, porosity, and apparent ground-water resistivity of the Minnelusa closely follow structural trends in the basin. Values increase from the structural axis of the basin toward the flanks. Close correlations between the water resistivities in the Madison and the Minnelusa indicate possible hydrologic connection between the two units. The low primary porosity from geophysical logs in the Madison indicates that secondary porosity is necessary to develop water supplies of economic importance from the Madison. Because of increased porosity and better water quality, the flanks of the basin appear to be the most favorable places for water production from either the Madison or the Minnelusa.

Wyoming, Montana, South Dakota, North Dakota↗