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Ground-water quality data in the Owens and Indian Wells Valleys study unit, 2006: Results from the California GAMA Program

Ground-water quality in the approximately 1,630 square-mile Owens and Indian Wells Valleys study unit (OWENS) was investigated in September-December 2006 as part of the Priority Basin Project of Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in collaboration with the California State Water Resources Control Board (SWRCB). The Owens and Indian Wells Valleys study was designed to provide a spatially unbiased assessment of raw ground-water quality within OWENS study unit, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 74 wells in Inyo, Kern, Mono, and San Bernardino Counties. Fifty-three of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and 21 wells were selected to evaluate changes in water chemistry in areas of interest (understanding wells). The ground-water samples were analyzed for a large number of synthetic organic constituents [volatile organic compounds (VOCs), pesticides and pesticide degradates, pharmaceutical compounds, and potential wastewater- indicator compounds], constituents of special interest [perchlorate, N-nitrosodimethylamine (NDMA), and 1,2,3- trichloropropane (1,2,3-TCP)], naturally occurring inorganic constituents [nutrients, major and minor ions, and trace elements], radioactive constituents, and microbial indicators. Naturally occurring isotopes [tritium, and carbon-14, and stable isotopes of hydrogen and oxygen in water], and dissolved noble gases also were measured to help identify the source and age of the sampled ground water. This study evaluated the quality of raw ground water in the aquifer in the OWENS study unit and did not attempt to evaluate the quality of treated water delivered to consumers. Water supplied to consumers typically is treated after withdrawal from the ground, disinfected, and blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and non-regulatory thresholds established for aesthetic concerns (secondary maximum contamination levels, SMCL-CA) by CDPH. VOCs and pesticides were detected in samples from less than one-third of the grid wells; all detections were below health-based thresholds, and most were less than one-one hundredth of threshold values. All detections of perchlorate and nutrients in samples from OWENS were below health-based thresholds. Most detections of trace elements in ground-water samples from OWENS wells were below health-based thresholds. In samples from the 53 grid wells, three constituents were detected at concentrations above USEPA maximum contaminant levels: arsenic in 5 samples, uranium in 4 samples, and fluoride in 1 sample. Two constituents were detected at concentrations above CDPH notification levels (boron in 9 samples and vanadium in 1 sample), and two were above USEPA lifetime health advisory levels (molybdenum in 3 samples and strontium in 1 sample). Most of the samples from OWENS wells had concentrations of major elements, TDS, and trace elements below the non-enforceable standards set for aesthetic concerns. Samples from nine grid wells had concentrations of manganese, iron, or TDS above the SMCL-CAs.

California↗

The New Hampshire watershed tool: a geographic information system tool to estimate streamflow statistics and ground-water-recharge rates

Estimates of low-flow statistics, flow durations, and ground-water-recharge rates are needed to assist water-resource managers in assessing surface-water resources and ground-water availability. Often these estimates are required at ungaged sites where no observed streamflow data are available for analysis. Regression equations for estimating low-flow statistics and flow durations, and for estimating ground-water-recharge rates at ungaged sites have been developed for New Hampshire. However, use of these equations requires numerous input parameters, such as basin and climatic characteristics. This report describes a customized geographic information system (GIS) application, the New Hampshire Watershed Tool, that automates the measurement of the characteristics used for input to the regression equations and calculates the corresponding flow statistics and ground-water-recharge rates.

Open-File Report↗

Summary appraisals of the nation's ground-water resources – Caribbean region

The Caribbean Region consists of the Commonwealth of Puerto Rico (8,990 km 2 (square kilometers)) and the U.S. Virgin Islands (350 km 2 ). The mean annual precipitation varies locally from a high of 5,000 mm (millimeters) to a low of 730 mm. Maximum precipitation occurs within the peaks of Sierra de Luquillo, and minimum precipitation occurs along the windward parts of the smaller islands and in southwestern Puerto Rico, which lies in a rain shadow. The annual average precipitation is 1,800 mm in Puerto Rico and 1,061 mm in the U.S. Virgin Islands. Of this amount 1,130 mm in Puerto Rico and 990 mm in the U.S. Virgin Islands are lost to evapotranspiration. Aquifers constitute a valuable resource in the Caribbean Region. In Puerto Rico, ground-water withdrawals supply about 38 percent of the total water requirements, whereas in the U.S. Virgin Islands they supply 10 percent. Of the ground-water withdrawal of 350 hm 3 /yr (cubic hectometers per year) in Puerto Rico, 54 percent is used for irrigation, 29 percent is used by industry, and 17 percent is used for public water supply. Ground-water withdrawal in the U.S. Virgin Islands is about 1.9 hm 3 /yr and is almost equally distributed between public supply and privately owned wells. Based on past trends and future economic expectations in the region, estimates are that by 1985 ground-water pumpage in Puerto Rico will be about 426 hm 3 /yr with additional future development potential; U.S. Virgin Islands pumpage may amount to 4.5 hm 3 /yr, which is the estimated maximum sustained yield of all aquifers under natural recharge conditions. Most large ground-water developments in Puerto Rico have been in the North Coast and South Coast ground-water provinces. The North Coast province contains the island's most productive aquifer, which was virtually undeveloped until 1968, when an artesian system having a 150-meter head was tapped. Since then, the artesian aquifer has undergone rapid development for industrial water supply. The extent of the artesian system is unknown, but it has been tapped within the Montebello Limestone Member of the Cibao Formation and in the upper part of the Lares Limestone. The south-coast aquifer consists of deep alluvial deposits. This aquifer has been extensively developed for irrigation and industrial water supply and can sustain only minor future development under present water-management conditions. In the U.S. Virgin Islands the most extensive aquifer is fragmented igneous rock, but the most productive aquifers are the marl and alluvial deposits of central St. Croix. Although yields from wells in central St. Croix are low (less than 6.3 liters per second), the aquifer provides about 0.86 hm 3 /yr to public water-supply wells and 0.54 hm 3 /yr to private wells. Future development within this aquifer could probably produce an additional 1.0 hm 3 /yr under natural infiltration conditions. Ground-water resources will continue to be important within the region. In order to meet future needs, it is necessary that hydrologic principles be applied in managing the total water resource. Optimal use of the water resources can be accomplished through conjunctive use of surface and ground waters and through conservation practices. Optimal use may involve artificial recharge, ground-water salvage, saline-ground-water mining, use of seawater, desalination of saline ground water, waste-water reuse, and use of underground space for temporary storage of wastes, which could otherwise contaminate valuable water supplies.

Professional Paper↗

Ground-water resources of northern Utah Valley, Utah

An evaluation was made of the ground-water resources of northern Utah Valley, Utah, to describe the ground-water system and to document changes in ground-water conditions since 1963. The principal ground-water reservoir is in basin-fill deposits. It consists of three major confined aquifers and an unconfined aquifer in pre-Lake Bonneville deposits along the mountains that adjoin the valley. The principal ground-water reservoir contains about 10 million acre-feet of recoverable water.

Utah↗

Ground-water supplies in the Murfreesboro area, Tennessee

Ground water occurs in the Murfreesboro area in solution openings in the otherwise dense paleozoic limestones that underlie most of central Tennessee. Test drilling based on conceptual models of ground-water occurrence in carbonate-rock aquifers indicate that multimillion-gallon-per-day supplies could be developed from strategically located production wells in the Shiloh and Overall Creek localities. The Shiloh locality which encompasses an elongated synclinal depression in the bedrock has the potential to supply 5 to 8 million gallons per day. The Overall Creek locality which straddles a joint-oriented lineament has the potential to supply 3 to 6 million gallons per day. Some local springs could be used as a supplemental source of potable water, but storage facilities would be needed to offset poorly sustained flows during dry periods. An exception is Fox Camp Spring which appears to be a natural well. The quality of ground water in the Murfreesboro area is typically hard, moderately mineralized and moderately to highly alkaline. Although the shallowest aquifers are subject to bacterial contamination from the land surface, aquifers beneath a depth of 100 feet are prone to yield potable water. (Woodard-USGS)

Tennessee↗

A survey of ground-water quality in the Toppenish Creek basin, Yakama Indian Reservation, Washington, 1989-91

Ground-water quality in the Toppenish Creek Basin, near Yakima, Washington, is generally good with respect to U.S. Environmental Protection Agency drinking water standards. Of 487 wells sampled during one phase of the study, only 2 produced water with nitrite-plus-nitrate concentrations greater than the U.S. Environmental Protection Agency standard of 10 milligrams per liter as nitrogen. Ground-water samples with elevated nitriteplus-nitrate concentrations (greater than 5 milligrams per liter as nitrogen) were obtained from wells located in the eastern and southern parts of the basin and in areas underlain by the Touchet Beds, in the central part of the basin. In another phase of the study, in which 60 wells were sampled, atrazine, an herbicide used on asparagus and corn, was detected in water samples from 4 wells, and 2 insecticides, diazinon and disulfoton, were detected in separate samples from 2 wells. Bacteria, indicators of the sanitary water quality, were detected in samples from 64 wells, suggesting that ground water may be contaminated in some areas. However, other sources of bacteria may include leaks in the plumbing of the well or residence, or improper well construction. Small seasonal variations in nitrite-plus-nitrate concentrations in ground water appeared to be related to fertilizer use in the basin, indicating that the potential exists for more serious contamination of ground water. Groundwater quality is affected by agricultural activities in some parts of the basin. However, widespread degradation in ground-water quality was not detected.

Washington↗

The water situation in the United States with special reference to ground water

This report constitutes appendixes B and C of a report prepared in April 1950 by the Geological Survey at the request of the President’s Water Resources Policy Commission. The full report was entitled "Water facts in relation to a national water-resources policy.” The brief text, entitled "Water in relation to the national economy,” and appendix A, entitled "A summary of the water situation in the United States, with special reference to ground water,” were drafted by A. M. Piper of the Geological Survey and are to be published separately, in slightly modified form, under his name. This report discusses the occurrence of ground water in nature and its relation to surface water and to the national water picture as a whole, and it lists numerous existing water problems and discusses their solution.

Circular↗

Ground-water monitoring in the Albuquerque area

At present (1996), all drinking water for Albuquerque residents comes from ground-water reserves. The Albuquerque area is the largest population center in the State and the largest consumer of ground water. Recent reports concerning the water resources of the Albuquerque area suggest that the Albuquerque Basin may soon face serious water-availability and water-quality problems due to anticipated ground-water development. Recent studies completed by the U.S. Geological Survey (USGS) have improved the understanding of the ground-water resources in the Albuquerque Basin. These studies have indicated that the more permeable units within the aquifer system--the upper Santa Fe Group--are less extensive than previously thought, and that water-levels have declined as much as 160 feet.

New Mexico↗

Field tests of diffusion samplers for inorganic constituents in wells and at a ground-water discharge zone

Field tests were performed on two types of diffusion samplers to collect representative samples of inorganic constituents from ground water in wells and at an arsenic-contaminated ground-water-discharge zone beneath a stream. Nylon-screen samplers and dialysis samplers were tested for the collection of arsenic, calcium, chloride, iron, manganese, sulfate, and dissolved oxygen. The investigations were conducted at the Naval Industrial Reserve Ordnance Plant (NIROP), Fridley, Minnesota, and at the Naval Air Station Fort Worth Joint Reserve Base (NAS Fort Worth JRB), Texas. Data indicate that, in general, nylon-screen and dialysis diffusion samplers are capable of obtaining concentrations of inorganic solutes in ground water that correspond to concentrations obtained by low-flow sampling. Diffusion samplers offer a potentially time-saving approach to well sampling. Particular care must be taken, however, when sampling for iron and other metals, because of the potential for iron precipitation by oxygenation and when dealing with chemically stratified sampling intervals. Simple nylon-screen jar samplers buried beneath creekbed sediment appear to be effective tools for locating discharge zones of arsenic contaminated ground water. Although the LDPE samplers have proven to be inexpensive and simple to use in wells, they are limited by their inability to provide a representative sample of ionic solutes. The success of nylon-screen samplers in sediment studies suggests that these simple samplers may be useful for collecting water samples for inorganic constituents in wells. Results using dialysis bags deployed in wells suggest that these types of samplers have the potential to provide a representative sample of both VOCs and ionic solutes from ground water (Kaplan and others, 1991; Theodore A. Ehlke, U.S. Geological Survey, written commun., 2001). The purpose of this report is to provide results of field tests investigating the potential to use diffusion samplers to collect representative samples of inorganic constituents from ground water in wells and at an arsenic-contaminated ground-water-discharge zone beneath a stream. The investigations were performed at NIROP, Fridley, Minn. (fig. 1) and at NAS Fort Worth JRB, Texas (fig. 2). Two types of samplers were tested. One type was a nylon-screen sampler, which consisted of a 30-mL jar filled with deionized water, with its opening covered by a nylon screen. The second type was a dialysis sampler that consisted of a tube of dialysis membrane filled with deionized water. The nylon-screen samplers were deployed in wells at NIROP Fridley and NAS Fort Worth JRB and beneath the ground-water/surface water interface of a stream at NAS Fort Worth JRB. The dialysis samplers were deployed only in wells at NAS Fort Worth JRB.

Water-Resources Investigations Report↗

Comparison of two approaches for determining ground-water discharge and pumpage in the lower Arkansas River Basin, Colorado, 1997-98

In March 1994, the Colorado Division of Water Resources (CDWR) adopted “Rules Governing the Measurement of Tributary Ground Water Diversions Located in the Arkansas River Basin” (Office of the State Engineer, 1994); these initial rules were amended in February 1996 (Office of the State Engineer, 1996). The amended rules require users of wells that divert tributary ground water to annually report the water pumped monthly by each well. The rules allow a well owner to report the pumpage measured by a totalizing flowmeter (TFM) or pumpage determined from electrical power data and a power conversion coefficient (PCC) (Hurr and Litke, 1989). Opinions by representatives of the State of Kansas, presented before the Special Master hearing a court case [State of Kansas v. State of Colorado, No. 105 Original (1996)] concerning post-Compact well pumping, stated that the PCC approach does not provide the same level of accuracy and reliability as a TFM when used to determine pumpage. In 1997, the U.S. Geological Survey (USGS), in cooperation with the CDWR, began a 2-year study to compare ground-water pumpage estimates made using the TFM and the PCC approaches. The study area was along the Arkansas River between Pueblo, Colorado, and the Colorado-Kansas State line (fig. 1). The two approaches for estimating ground-water discharge and pumpage were compared for more than 100 wells completed in the alluvial aquifer of the Arkansas River Basin. The TFM approach uses an inline flowmeter to directly measure instantaneous discharge and the total volume of water pumped at a well. The PCC approach uses electrical power consumption records and a power conversion coefficient to estimate the pumpage at ground-water wells. This executive summary describes the results of the comparison of the two approaches. Specifically, (1) the differences in instantaneous discharge measured with three portable flowmeters and measured with an inline TFM are evaluated, and the statistical differences in paired instantaneous discharge between the two approaches are determined; (2) short- and long-term variations in the PCC’s are presented; (3) differences in pumpage between the two approaches are evaluated, and the statistical differences in pumpage between the two approaches are determined; (4) potential sources of discrepancy between pumpage estimates are discussed; and (5) differences in total network pumpage using the two approaches are presented. During the irrigation seasons of 1997 and 1998, instantaneous discharge and electrical power demand were measured at randomly selected wells to determine PCC’s. At more than 100 wells, the PCC’s determined during the 1998 season were applied to total electrical power consumption data that was recorded between the initial and final readings at each network well site in 1998 to estimate total ground-water pumpage. At each site, an inline TFM was installed in a full-flowing, acceptable test section of pipe on the discharge side of the pump where the measurement of discharge was made. Measurements of instantaneous ground-water discharge also were made using three different types of portable flowmeters. The average velocity multiplied by the cross-sectional area of the discharge pipe was used to compute the discharge in gallons per minute. Whenever possible, discharge measurements were made at each network site using all three types of portable flowmeters.

Colorado↗

Simulation of ground-water flow in the Potomac-Raritan-Magothy aquifer system, Pennsauken Township and vicinity, New Jersey

The Potomac-Raritan-Magothy aquifer system is one of the primary sources of potable water in the Coastal Plain of New Jersey, particularly in heavily developed areas along the Delaware River. In Pennsauken Township, Camden County, local drinking-water supplies from this aquifer system have been contaminated by hexavalent chromium at concentrations that exceed the New Jersey maximum contaminant level. In particular, ground water at the Puchack well field has been adversely affected to the point where, since 1984, water is no longer withdrawn from this well field for public supply. The area that contains the Puchack well field was added to the National Priorities List in 1998 as a Superfund site. The U.S. Geological Survey (USGS) conducted a reconnaissance study from 1996 to 1998 during which hydrogeologic and water-quality data were collected and a ground-water-flow model was developed to describe the conditions in the aquifer system in the Pennsauken Township area. The current investigation by the USGS, in cooperation with the U.S. Environmental Protection Agency (USEPA), is an extension of the previous study. Results of the current study can be applied to a Remedial Investigation and Feasibility Study conducted at the Puchack well field Superfund site. The USGS study collected additional data on the hydrogeology and water-quality in the area. These data were incorporated into a refined model of the ground-water-flow system in the Potomac-Raritan-Magothy aquifer system. A finite-difference model was developed to simulate ground-water flow and the advective transport of chromium-contaminated ground water in the aquifers of the Potomac-Raritan-Magothy aquifer system in the Pennsauken Township area. An 11-layer model was used to represent the complex hydrogeologic framework. The model was calibrated using steady-state water-level data from March 1998, April 1998, and April 2001. Water-level recovery during the shutdown of Puchack 1 during March to April 1998 was simulated to evaluate model performance in relation to changing stresses. The Delaware River contributes appreciable-flow to the ground-water system from areas where the Middle and Lower aquifers crop out beneath the river. A transient simulation of an aquifer test near the Delaware River was run to help characterize the hydraulic conductivity of the riverbed sediments represented in the model. Vertical flow across confining units between the aquifers is highly variable and is important in the movement of water and associated contaminants through the flow system. The model was imbedded within a regional model of the Potomac-Raritan-Magothy aquifer system in Camden County. In general, a simulation of baseline conditions, which can provide a representation on which simulations of various alternatives can be based for the feasibility study, incorporated average conditions from 1998 to 2000. Ground-water withdrawals within the model area during this period averaged about 14 Mgal/d. Regional ground-water flow is from recharge areas and from the Delaware River to downgradient pumped wells located just east of the model area in central Camden County. Simulation results show an important connection between the Intermediate sand and the Lower aquifer of the Potomac-Raritan-Magothy aquifer system in the vicinity of the chromium-contaminated area. The Delaware River contributes nearly 10 Mgal/d to the flow system, whereas recharge contributes about 6 Mgal/d. Ground-water withdrawals within the model area account for nearly 14 Mgal/d (mostly from the Lower aquifer of the Potomac-Raritan-Magothy aquifer system).

Scientific Investigations Report↗

Shallow ground water in the Boulder-Fort Collins-Greeley area, Front Range urban corridor, Colorado, 1975-77

Shallow ground water may limit the location of construction and excavation projects in parts of the Front Range Urban Corridor. A shallow water table occurs from 0 to 50 feet below the land surface principally in the alluvial deposits along the streams and rivers in the Boulder-Fort Collins-Greeley area. This shallow water table underlies approximately 400 square miles and is maintained by natural recharge within the South Platte River basin and by the infiltration of irrigation water that is diverted into the basin from streams and reservoirs in the Colorado and the Laramie River basins. Return flow from irrigation, which is mostly ground water, helps maintain the flow of the South Platte River and its tributaries. The report includes a map from which depth to water table and the direction of ground-water movement can be determined. The map, compiled on a topographic base, shows the areal extent of the saturated materials and the altitude and configuration of the ground-water surface. The water-table contour map was prepared using data from approximately 400 wells. Monitoring of shallow ground-water within the study area shows depths to water have changed only slightly over the last 20 years, except for some seasonal and drought-related fluctuations. Gradients, computed from ground-water measurements, range from 27.7 feet per mile in Lone Tree-Spring Creek valley to 10.3 feet per mile in the South Platte River valley. The shallow ground-water underflow from the major tributaries in the basin is about 29,000 acre-feet per year, and underflow calculated at a cross section near Kersey is about 12,000 acre-feet per year.

Colorado↗

Effects of Agricultural Land-Use Changes and Rainfall on Ground-Water Recharge in Central and West Maui, Hawai`i, 1926-2004

Concern surrounding declines in ground-water levels and an increase in the chloride concentration of water pumped from wells in the Iao aquifer system on the Island of Maui has prompted an investigation into the long-term sustainability of current (2006) and future ground-water withdrawals. As part of this investigation, a water budget for central and west Maui was calculated from which (1) ground-water recharge was estimated for the period 1926-2004 and (2) the effects of agricultural land-use changes and drought were analyzed. Estimated mean ground-water recharge decreased 44 percent from 1979 to 2004 in central and west Maui. Reduction in agricultural irrigation, resulting from more efficient irrigation methods and a reduction in the acreage used for agriculture, is largely responsible for the declining recharge. Recently, periods of lower-than-average rainfall have further reduced recharge. During the period 1926-79, ground-water recharge averaged 693 Mgal/d, irrigation averaged 437 Mgal/d, and rainfall averaged 897 Mgal/d. During the period 2000-04, ground-water recharge averaged 391 Mgal/d, irrigation averaged 237 Mgal/d, and rainfall averaged 796 Mgal/d. Simulations of hypothetical future conditions indicate that a cessation of agriculture in central and west Maui would reduce mean ground-water recharge by 18 percent in comparison with current conditions, assuming that current climatic conditions are the same as the long-term-average conditions during the period 1926-2004. A period of drought identical to that of 1998-2002 would reduce mean recharge by 27 percent. Mean recharge would decrease by 46 percent if this drought were to occur after a cessation of agriculture in central and western Maui. Whereas droughts are transient phenomena, a reduction in agricultural irrigation is likely a permanent condition.

Scientific Investigations Report↗

Ground water and surface water: A single resource

The importance of considering ground water and surface water as a single resource has become increasingly evident. Issues related to water supply, water quality, and degradation of aquatic environments are reported on frequently. The interaction of ground water and surface water has been shown to be a significant concern in many of these issues. Contaminated aquifers that discharge to streams can result in long-term contamination of surface water; conversely, streams can be a major source of contamination to aquifers. Surface water commonly is hydraulically connected to ground water, but the interactions are difficult to observe and measure. The purpose of this report is to present our current understanding of these processes and activities as well as limitations in our knowledge and ability to characterize them.

Circular↗

Simulation of ground-water flow in the Coastal Plain aquifer system of North Carolina

A three-dimensional finite-difference digital model was used to simulate ground-water flow in the 25,000-square-mile aquifer system of the North Carolina Coastal Plain. The model was developed from a hydrogeologic framework that is based on an alternating sequence of 10 aquifers and 9 confining units, which make up a seaward-thickening wedge of sediments that form the Coastal Plain aquifer system in the State of North Carolina. The model was calibrated by comparing observed and simulated water levels. The model calibration was achieved by adjusting model parameters, primarily leakance of confining units and transmissivity of aquifers, until differences between observed and simulated water levels were within acceptable limits, generally within 15 feet. The maximum transmissivity of an individual aquifer in the calibrated model is 200,000 feet squared per day in a part of the Castle Hayne aquifer, which consists predominantly of limestone. The maximum value for simulated vertical hydraulic conductivity in a confining unit was 2.5 feet per day, in a part of the confining unit overlying the upper Cape Fear aquifer. The minimum value was 4.1x10-6 feet per day, in part of the confining unit overlying the lower Cape Fear aquifer. Analysis indicated the model is highly sensitive to changes in transmissivity and leakance near pumping centers; away from pumping centers, the model is only slightly sensitive to changes in transmissivity but is moderately sensitive to changes in leakance. Recharge from precipitation to the surficial aquifer ranges from about 12 inches per year in areas having clay at the surface to about 20 inches per year in areas having sand at the surface. Most of this recharge moves laterally to streams, and only about 1 inch per year moves downward to the confined parts of the aquifer system. Under predevelopment conditions, the confined aquifers were generally recharged in updip interstream areas and discharged through streambeds and in downdip coastward areas. Hydrologic analysis of the flow system using the calibrated model indicated that, because of ground-water withdrawals, areas of ground-water recharge have expanded and encroached upon some major stream valleys and into coastal area. Simulations of pumping conditions indicate that by 1980 large parts of the former coastal discharge areas had become areas of potential or actual recharge. Declines of ground-water level, which are the result of water taken from storage, are extensive in some areas and minimal in others. Hydraulic head declines of more than 135 feet have occurred in the northern Coastal Plain since 1940 primarily due to withdrawals in the Franklin area in Virginia. Declines of ground-water levels greater than 110 feet have occurred in aquifers in the central Coastal Plain due to combined effects of pumpage for public and industrial water supplies. Water-level declines exceeding 100 feet have occurred in the Beaufort County area because of withdrawals for a mining operation and water supplies for a chemical plant. Head declines have been less than 10 feet in the shallow surficial and Yorktown aquifers and in the updip parts of the major confined aquifers distant from areas of major withdrawals. In 1980, contribution from aquifer storage was 14 cubic feet per second, which is about 4.8 percent of pumpage and about 0.05 percent of ground-water recharge. A water-budget analysis using the model simulations indicates that much of the water removed from the ground-water system by pumping ultimately is made up by a reduction in water leaving the aquifer system, which discharges to streams as base flow. The reduction in stream base flow was 294 cubic feet per second in 1980 and represents about 1.1 percent of the ground-water recharge. The net reduction to streamflow is not large, however, because most pumped ground water is eventually discharged to streams. In places, such as at rock quarries in Onslow and Craven Counties, water is lost from st

North Carolina↗

Simulation of regional ground-water flow in the Cambrian-Ordovician aquifer system in the northern Midwest, United States: in Regional aquifer-system analysis

A six-State area in the northern Midwest of the United States has become increasingly dependent on ground water from the Cambrian-Ordovician aquifer system, which consists of a sequence of sandstones, carbonate rocks, and shales. Ground-water withdrawals from the aquifer system began in the late 1800's and increased to approximately 684 million gallons per day (1,058 cubic feet per second) by 1980. This withdrawal has caused more than 900 feet of decline in the potentiometric surface of the aquifer system in parts of the Chicago, Ill., area. Pumping in Minneapolis-St. Paul, Minn., Milwaukee, Wis., and central Iowa has produced a few hundreds of feet of water-level decline. A quasi-three-dimensional ground-water flow model was developed to improve understanding of the regional ground-water flow system by simulating the aquifer system under the conditions that existed before and during ground-water development. The Cambrian-Ordovician aquifer system and the overlying rocks were incorporated in the conceptual model as five aquifer layers with four intervening confining layers. The aquifer layers, from top to bottom, are as follows: Quaternary deposits and Cretaceous rocks (aquifer layer 5); basal Devonian carbonate rocks and underlying Silurian carbonate rocks (aquifer layer 4); Middle Ordovician St. Peter Sandstone, Lower Ordovician Prairie du Chien Group, and Upper Cambrian Jordan Sandstone (aquifer layer 3); Upper Cambrian Ironton and Galesville Sandstones (aquifer layer 2); and Upper Cambrian Mount Simon Sandstone and Precambrian Hinckley Sandstone (aquifer layer 1). The effects on the flow system of ground water having variable density and the individual aquifer layer contribution of flow to wells open to several aquifer layers were simulated by incorporating appropriate terms in the ground-water flow equation and corresponding modifications in the ground-water flow model. Results of steady-state simulations are shown as maps of freshwater head and as flow-rate vectors. A comparison was made of available predevelopment head data and simulated predevelopment heads for the Mount Simon, St. Peter-Prairie du Chien-Jordan, and Silurian-Devonian aquifers. The root mean square of the differences between observed and simulated heads for these aquifers was 53, 36, and 44 feet, respectively. Steady-state model simulation indicates that regional recharge areas are located in northwestern Iowa, southeastern Minnesota, much of Wisconsin, northern Illinois, and central Missouri. Regional discharge areas are located near the Mississippi River and its tributaries, the Missouri River, Lake Michigan, and the Illinois basin. Results of a transient simulation of the period 1861 to 1980 are shown as maps of freshwater head and freshwater-head decline. The root mean square of the differences between observed and simulated heads for the St. Peter-Prairie du Chien-Jordan aquifer was 63 feet. In addition, hydrographs of simulated hydraulic head were compared with hydrographs of observed head in wells open to various combinations of aquifers. The numerous head measurements within a model node display a wide range in magnitude; however, their historical trend generally follows the trend of the simulated heads. The simulated recharge from the glacial drift to the immediately underlying bedrock aquifers averages 0.03, 0.06, 0.24, and 0.02 inch per year, respectively, to the Mount Simon, Ironton-Galesville, St. Peter- Prairie du Chien-Jordan, and Silurian-Devonian aquifers for predevelopment conditions and 0.03, 0.07, 0.45, and 0.07 inch per year, respectively, to the same aquifers for 1976-80. These recharge rates are less than 1.5 percent of average annual precipitation of about 30 inches per year. Most of the recharge from precipitation discharges to streams as base flow through local and intermediate ground-water flow systems. Only a small fraction of the precipitation recharges the deeper, regional flow system. The simulated predevelopment recharge of 571 cubic feet per second is balanced by an equivalent discharge. For the period 1976-80, simulated recharge increased to 1,398 cubic feet per second. Total discharge, including pumpage from the four bedrock aquifers, increased to 1,619 cubic feet per second. The difference in recharge and discharge during this period is from aquifer storage. Results of variable-density simulations indicate that the rate of ground-water movement is small in areas where ground water is highly mineralized. The rates and directions are controlled by the intrinsic permeability of the rock, freshwater head gradients, and gravitational force.

Iowa, Illinois, Indiana, Michigan, Minnesota, Miss↗

Fresh and saline ground-water zones in the Punjab region, West Pakistan

An extensive program of test drilling and water sampling, undertaken by the Water and Soils Investigation Division (WASID) of the West Pakistan Water and Power Development Authority (WAPDA) to evaluate hydrologic problems related to waterlogging and soil salinity, has furnished data for the delineation of fresh and saline ground-water zones in the Punjab region of West Pakistan. Fresh ground water containing generally less than 500 ppm (parts per million) of total dissolved solids is found in wide belts paralleling the major rivers and in other areas of ground-water recharge. The fresh groundwater zone of upper (northeastern) Rechna Doab, where annual precipitation in places exceeds 30 inches, is the most extensive of the Punjab region and attains a depth of 1,700 feet or more below land surface near Gujranwala. Fresh ground water adjacent to the Indus River extends locally to depths of about l,500 feet. Saline ground water occurs downgradient from sources of recharge, particularly in the central parts of the interfluvial areas. Also, available data indicate a gradual increase in mineralization with depth and distance from sources of fresh-water recharge. Thus, even extensive fresh-water zones appear to be underlain, at variable depths, by saline ground water in most of the Punjab region. The saline ground waters of the Punjab region do not constitute, however, a distinct salt-water body that can be defined in terms of stratigraphic position, sea-level datum, particular lithology, or by chemical character. The ground waters of the Punjab region are characterized by a gradation from calcium magnesium bicarbonate types, near the sources of recharge, to waters containing a dominant proportion of sodium. Water containing from 500 to 1,000 ppm is commonly of the sodium bicarbonate type, or it may be of the mixed type, having about equal proportions of the common anions (bicarbonate, chloride, and sulfate). With increasing mineralization from about 1,000 to 3,000 ppm, ,the relative proportion of chloride and sulfate increases, and these waters are generally of the sodium chloride or sodium sulfate type. The highly mineralized waters of the Punjab region are generally of the sodium chloride type, whereas in Dera Ismail (D.I.) Khan District sodium sulfate waters predominate. The ground waters from more than 900 sampling sites have been classified into eight types, according to dominant cations and anions. These types have been further subdivided into groups containing different amounts of total dissolved solids. The pattern of distribution of saline ground-water zones in the Punjab region and the observed gradual increase in mineral content, downgradient from sources of fresh-water recharge, can be explained best by the processes of evaporation from the water table and solution of minerals within the alluvial aquifer.

Water Supply Paper↗

Trichloroethylene and 1,1-dichloroethylene concentrations in ground water after temporary shutdown of the reclamation well field at Air Force Plant 44, Tucson, Arizona, 1999

Industrial activities beginning in the early 1940s resulted in extensive contamination of ground water near the Tucson International Airport, Tucson, Arizona, including an area around Air Force Plant 44, an industrial facility located on land owned by the U.S. Air Force and operated by a defense contractor. Principal ground-water contaminants are volatile organic compounds, primarily trichloroethylene (also called trichloroethene) and 1,1-dichloroethylene (also called 1,1-dichloroethene). A ground- water reclamation system was put into operation in 1987 to extract and treat contaminated ground water at Air Force Plant 44 and the downgradient area that is south of Los Reales Road. The ground- water reclamation system consists of 25 extraction wells, 22 recharge wells, and a water-treatment facility. Soil-vapor extraction techniques are being used to remove volatile organic compounds from the unsaturated zone. More than 120,000 pounds of volatile organic compounds have been removed from the regional aquifer and overlying unsaturated zone at Air Force Plant 44 and adjacent downgradient areas south of Los Reales Road. Air Force Plant 44 and adjacent areas being remediated by the ground-water reclamation system are about 7 square miles. To assess ground-water cleanup progress at Air Force Plant 44 and surrounding areas south of Los Reales Road, and possibly to identify areas that are resistant to cleanup attempts, ground-water samples were collected and analyzed after water levels had returned to near-equilibrium conditions following a 3-week shutdown of extraction and recharge wells. Modifications of the standard ground-water sampling procedures used at the site also were tested. The modifications included tests of a reduced-flow purging and sampling method in six monitoring wells and vertical- profile sampling in five extraction wells at the reclamation well field. The water treatment facility and all extraction and recharge wells at the reclamation well field were shut down on April 15, 1999, and water levels were allowed to recover for about 3 weeks before samples of ground water were obtained from 102 wells at Air Force Plant 44 and surrounding areas. Concentrations of trichloroethylene and 1,1-dichloroethylene were determined for samples obtained during the sitewide sampling effort. Data for 101 wells sampled in February 1999 before shutdown were compared with data obtained for wells sampled in May 1999 after shutdown. Concentrations of trichloroethylene increased in 36 wells, remained the same in 32 wells, and decreased in 33 wells. Increases in concentrations of trichloroethylene of as much as 1,476 micrograms per liter and decreases of as much as 2,292 micrograms per liter were reported after shutdown. Concentrations of trichloroethylene remained the same for the two sampling periods in wells that had concentrations that were at, or close to, the lower reporting limit (0.5 micrograms per liter) before shutdown. Net change in concentrations of trichloroethylene after shutdown on a percentage basis ranged from an increase of 1,300 percent to a decrease of 100 percent. Increases in concentrations of 1,1-dichloroethylene after shutdown of the reclamation well field of as much as 66 micrograms per liter and decreases of as much as 411.6 micro- grams per liter were reported. Concentrations of 1,1-dichloroethylene remained the same for the two sampling periods in wells that had concentrations that were at, or close to, the lower reporting limit (0.5 micrograms per liter) before shutdown. Net change in concentrations of 1,1-dichloroethylene after shutdown on a percentage basis ranged from an increase of 660 percent to a decrease of 100 percent. Data obtained from the water samples indicate that the largest changes in concentrations of trichloroethylene and 1,1-dichloroethylene occurred in samples collected from wells completed in the upper zone of the regional aquifer, along the axis of the contaminant plume, in close proximity to previously identified historical disposal areas. Changes in contaminant concentrations observed after shutdown of the well field probably were the result of changes in ground-water flow directions under nonpumping conditions compared with those present when the extraction and recharge wells were operating. Minimal changes occurred at the perimeter of the plume, which suggests that operation of the reclamation well field has been successful at containing the spread of the plume. New contaminant-source areas were not identified within the perimeter of the plume. A modification of the standard sampling technique used at Air Force Plant 44 was tested in six wells. In these wells, greatly reduced flow rates were used for well purging and sampling. Results indicate no distinct pattern of change of contaminant concentrations compared with concentrations in samples subsequently obtained using the standard technique, and no advantage was evident for using this method in routine sampling of the monitoring wells at Air Force Plant 44. Temperature profiles obtained before vertical-profile sampling of selected wells indicate little temperature variation with depth. The temperature-profile information suggests that under nonpumping conditions, most of the water enters these wells near the top of the screened interval and moves downward in response to a hydraulic gradient in the regional aquifer. Samples at depths below the top of the screened interval probably do not accurately represent water from the adjacent sediments. Vertical-profile samples were obtained in five wells and analyzed for concentrations of trichloroethylene. None of the wells showed large enough variation of contaminant concentrations with depth to indicate that a major improvement in extraction efficiency could be obtained by pumping selectively from a restricted interval. The largest variation in concentrations of trichloroethylene with depth that was observed ranged from 62 micrograms per liter near the top of the screened interval to 42 micrograms per liter near the bottom of the screened interval of one of the wells. The lack of large variation is probably the result of downward water flow in the casing of these wells.

Arizona↗