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USGS2005

Concentrations of cadmium, lead, and zinc in fish from mining-influenced waters of northeastern Oklahoma: Sampling of blood, carcass, and liver for aquatic biomonitoring

The Tri-States Mining District (TSMD) of Missouri (MO), Kansas (KS), and Oklahoma (OK), USA, was mined for lead (Pb) and zinc (Zn) for more than a century. Mining ceased more than 30 years ago, but wastes remain widely distributed in the region, and there is evidence of surface- and groundwater contamination in the Spring River-Neosho River (SR-NR) system of northeastern OK. In October 2001, we collected a total of 74 fish from six locations in the SR-NR system that included common carp (Cyprinus carpio), channel- and flathead catfish (Ictalurus punctatus and Pylodictis olivaris), largemouth- and spotted bass (Micropterus salmoides and Micropterus punctulatus), and white crappie (Pomoxis annularis). We obtained additional fish from locations in MO that included three reference sites and one site that served as a "positive control" (heavily contaminated by Pb). Blood, carcass (headed, eviscerated, and scaled) and liver (carp only) samples were analyzed for cadmium (Cd), Pb, and Zn. Our objectives were to assess the degree to which fish from the OK portion of the SR-NR system are contaminated by these elements and to evaluate fish blood sampling for biomonitoring. Concentrations of Cd and Pb in carp and catfish from OK sites were elevated and Pb concentrations of some approached those of the highly contaminated site in MO, but concentrations in bass and crappie were relatively low. For Zn, correlations were weak among concentrations in the three tissues and none of the samples appeared to reflect site contamination. Variability was high for Cd in all three tissues of carp; differences between sites were statistically significant (p < 0.05) only for blood even though mean liver concentrations were at least 100-fold greater than those in blood. Blood concentrations of Cd and Pb were positively correlated (r 2 = 0.49 to 0.84) with the concentration of the same element in carp and catfish carcasses or in carp livers, and the corresponding multiple regression models were highly significant (p < 0.001). Our data indicate that potentially nonlethal blood sampling can be useful for monitoring of selected metals in carp, catfish, and perhaps other fishes. ?? 2005 Springer Science+Business Media, Inc.

Archives of Environmental Contamination and Toxico↗

USGS2005

Freshwater mussel shells as environmental chronicles: Geochemical and taphonomic signatures of mercury-related extirpations in the North Fork Holston River, Virginia

This study utilized freshwater mussel shells to assess mercury (Hg) contamination in the North Fork Holston River that extirpated (caused local extinctions of) a diverse mussel fauna. Shells (n = 366) were collected from five sites situated upstream (two sites), just below (one site), and downstream (two sites) of the town of Saltville, Virginia, where Hg was used to produce chlorine and caustic soda from 1950 to 1972. Shell samples were used to test the (1) utility of geochemical signatures of shells for assessing the spatial variation in Hg levels in the river relative to the contamination source and (2) value of taphonomy (postmortem shell alteration) for distinguishing sites that differ in extirpation histories. Geochemical signatures of 40 shells, analyzed using atomic absorption spectroscopy, indicated a strong longitudinal pattern. All shells from the two upstream sites had low Hg concentrations (<5-31 ??g/kg), shells directly below Saltville had variable, but dramatically higher concentrations (23-4637 ??g/kg), and shells from the two downstream sites displayed intermediate Hg levels (<5-115 ??g/kg) that declined with distance from Saltville. Two pre-industrial shells, collected at Saltville in 1917, yielded very low Hg estimates (5-6 ??g/kg). Hg signatures were consistent among mussel species, suggesting that Hg concentrations were invariant to species type; most likely, highly variable Hg levels, both across sites and through time, overwhelmed any interspecific differences in Hg acquisition. Also, a notable postmortem incorporation of Hg in mussel shells seemed unlikely, as the Hg content was not correlated with shell taphonomy (r = 0.18; p = 0.28). The taphonomic analysis (n = 366) showed that the degree of shell alteration reliably distinguished sites with different extirpation histories. At Saltville, where live mussels have been absent for at least 30 years, shells were most heavily altered and fragmented. Conversely, fresh-looking shells abounded upstream, where reproducing mussel populations are still present. In summary, relic shells offered valuable spatiotemporal data on Hg concentrations in a polluted ecosystem, and shell taphonomic signatures discriminated sites with different extirpation histories. The shell-based strategies exemplified here do not require sampling live specimens and may augment more standard strategies applied to environmental monitoring. The approach should prove especially useful in areas with unknown extirpation and pollution histories. ?? 2005 American Chemical Society.

Environmental Science & Technology↗

USGS2020

Characterizing land surface phenology and exotic annual grasses in dryland ecosystems using Landsat and Sentinel-2 data in harmony

Invasive annual grasses, such as cheatgrass (Bromus tectorum L.), have proliferated in dryland ecosystems of the western United States, promoting increased fire activity and reduced biodiversity that can be detrimental to socio-environmental systems. Monitoring exotic annual grass cover and dynamics over large areas requires the use of remote sensing that can support early detection and rapid response initiatives. However, few studies have leveraged remote sensing technologies and computing frameworks capable of providing rangeland managers with maps of exotic annual grass cover at relatively high spatiotemporal resolutions and near real-time latencies. Here, we developed a system for automated mapping of invasive annual grass (%) cover using in situ observations, harmonized Landsat and Sentinel-2 (HLS) data, maps of biophysical variables, and machine learning techniques. A robust and automated cloud, cloud shadow, water, and snow/ice masking procedure (mean overall accuracy >81%) was implemented using time-series outlier detection and data mining techniques prior to spatiotemporal interpolation of HLS data via regression tree models (r = 0.94; mean absolute error (MAE) = 0.02). Weekly, cloud-free normalized difference vegetation index (NDVI) image composites (2016–2018) were used to construct a suite of spectral and phenological metrics (e.g., start and end of season dates), consistent with information derived from Moderate Resolution Image Spectroradiometer (MODIS) data. These metrics were incorporated into a data mining framework that accurately (r = 0.83; MAE = 11) modeled and mapped exotic annual grass (%) cover throughout dryland ecosystems in the western United States at a native, 30-m spatial resolution. Our results show that inclusion of weekly HLS time-series data and derived indicators improves our ability to map exotic annual grass cover, as compared to distribution models that use MODIS products or monthly, seasonal, or annual HLS composites as primary inputs. This research fills a critical gap in our ability to effectively assess, manage, and monitor drylands by providing a framework that allows for an accurate and timely depiction of land surface phenology and exotic annual grass cover at spatial and temporal resolutions that are meaningful to local resource managers.

California, Idaho, Nevada, Oregon↗

USGS2022

Volcano and earthquake monitoring plan for the Yellowstone Caldera system, 2022–2032

Executive Summary The Yellowstone Volcano Observatory (YVO) is a consortium of nine Federal, State, and academic agencies that: (1) provides timely monitoring and hazards assessment of volcanic, hydrothermal, and earthquake activity in and around Yellowstone National Park, and (2) conducts research to develop new approaches to volcano monitoring and better understand volcanic activity in the Yellowstone region and elsewhere. The U.S. Geological Survey (USGS) arm of YVO is also responsible for monitoring and reporting on volcanic activity in the Intermountain West of the United States. The previous YVO monitoring plan for the Yellowstone region spanned 2006–2015 and focused on strengthening the region-wide coverage, or backbone, of monitoring systems (Yellowstone Volcano Observatory, 2006). The goals of that plan have largely been achieved thanks to significant investments in instrumentation and infrastructure, especially by the National Science Foundation EarthScope Plate Boundary Observatory (now known as the Network Of The Americas, or NOTA) and the American Reinvestment and Recovery Act. This revision of the monitoring plan, covering 2022–2032, builds upon these improvements to monitoring systems in the Yellowstone region while also accounting for new insights into the dynamics of the area’s seismic, volcanic, and hydrothermal activity. These additional improvements are designed to fill gaps in the monitoring network and to better understand and track hazards associated with hydrothermal processes. These improvements include: Conversion of remaining analog seismic stations to digital, Addition of Global Positioning System (GPS) stations in the vicinity of Norris Geyser Basin and other areas where changes in deformation rate and style have been observed, Implementation of continuous gas monitoring in several areas of Yellowstone National Park, and Improvements to lake, meteorological, and hydrological monitoring to better track hydrothermal activity, including that occurring on lake bottoms, and to aid in understanding of whether such activity might be influenced by external forces, like environmental conditions. The 2022–2032 monitoring plan for the Yellowstone volcanic system also proposes to improve monitoring of hydrothermal areas to better understand these dynamic systems and their associated hazards. To date, only a single seismometer has been placed within one of Yellowstone National Park’s geyser basins because seismic noise associated with boiling water can hinder interpretation of overall seismic and magmatic activity, but this concern has been mitigated by improvements to backbone monitoring. Deployment of geophysical, geochemical, hydrological, and geological monitoring instruments in geyser basins will be accompanied by campaigns to measure gas and water chemistry and flux, as well as aerial and satellite surveys of gas and thermal emissions. Close collaboration between YVO member institutions and other research agencies is needed to achieve these monitoring goals and to use the derived data to advance understanding of how Yellowstone Caldera and similar volcanic systems work. At the same time, attention must be paid to minimize the impact of monitoring efforts and infrastructure on the environment. YVO thus commits to serving as stewards of the natural, cultural, and historical resources in and around Yellowstone National Park while maximizing scientific gain for the betterment of society.

Wyoming↗

USGS2021

Investigation of land surface phenology detections in shrublands using multiple scale satellite data

Shrublands occupy about 13% of the global land surface, contain about one-third of the biodiversity, store about half of the global terrestrial carbon, and provide many ecosystem services to a large amount of world's human population and livestock. Because phenology is a sensitive indicator of the response of shrubland ecosystems to climate change, the alteration of ecosystems following species invasions, and the dynamics of shrubland ecosystem function, biodiversity, and carbon budgets, it is critical to monitor and assess phenological dynamics in shrubland ecosystems. However, most current land surface phenology (LSP) products derived from satellite data do not provide phenology detections in some semiarid shrublands where the amplitude of seasonal vegetation greenness is small. Therefore, we investigated the LSP detection using multiple spatial resolution satellite data and examined the impacts of spatial scales and shrubland ecosystem components (shrub and herb cover) on LSP detections over the western United States. Specifically, greenup onset date (GUD) in shrublands was detected from 30 m Harmonized Landsat and Sentinel-2 (HLS) data and 500 m Visible Infrared Imaging Radiometer Suite (VIIRS) data to quantify scale effects. The GUD spatial patterns were explored with 30 m pixel variations in shrubland ecosystem components. The results show that GUD values varied with percent vegetation cover and shifted to earlier dates with increasing vegetation cover, demonstrating that satellite observations were not able to capture greenup onset until a threshold of green vegetation cover is reached. GUD was mostly undetectable from both HLS and VIIRS pixels with vegetation cover less than 10% and became fully detectable with vegetation covers larger than 50%. Similarly, the differences of GUD between HLS and VIIRS detections also decreased with increased vegetation cover. As a result of high shrubland heterogeneity, GUD from 30 m HLS pixels could be partially detected within a 500 m pixel despite GUD being undetectable from VIIRS time series. Moreover, vegetation cover heterogeneity also made it difficult for GUD at 30 m to be aggregated to coarse scales (such as to 500 m VIIRS pixels). These findings have significant implications to the detection and characterization of shrubland LSP responses to environmental and climate changes.

Nevada, Utah↗

USGS2021

Groundwater conditions and trends, 2009–19, Saipan, Commonwealth of the Northern Mariana Islands

Groundwater is the primary source of municipal water for Saipan. Nearly all groundwater for the municipal water supply is withdrawn from a freshwater-lens system with a limited amount of freshwater that is susceptible to saltwater intrusion. The status of Saipan’s groundwater resources has not been thoroughly assessed since 2003. The U.S. Geological Survey—in cooperation with the Office of Grants Management, Commonwealth of the Northern Mariana Islands, and in collaboration with the Commonwealth Utilities Corporation—assessed the status and characteristics of Saipan’s groundwater resources by (1) evaluating groundwater withdrawals from municipal production wells during 2014–19, (2) evaluating chloride concentrations of municipal groundwater withdrawals during 2009–19, and (3) collecting salinity profiles at selected groundwater-monitoring wells during 2018–19. At the time of preparation of this report (2019), the periods of groundwater-withdrawal and chloride-concentration data represent the only periods of data available since 2003. During 2014–19, groundwater for the municipal water supply was withdrawn from about 143 production wells. Most of the wells are drilled into limestone formations in the southern plateau and the Kagman Peninsula and generally have withdrawal rates of about 40–60 gallons per minute. Records of monthly groundwater withdrawals from municipal production wells were available for May 2014–March 2019; during that period, monthly withdrawals ranged from 5.7 to 12.8 million gallons per day (Mgal/d) and averaged 9.3 Mgal/d, although records were unavailable for 9 months (May 2015–January 2016). Private wells, mainly located on the western coastal plain, currently are permitted to withdraw a total of about 7 Mgal/d of groundwater. Actual groundwater withdrawals from private wells, however, are uncertain because withdrawal records for private wells are not available. The Commonwealth Utilities Corporation measured the chloride concentration of groundwater pumped from each of its production wells about twice a year from 2009–19; during this period, 146 production wells were active and sampled. Only 32 of the 146 (22 percent) municipal production wells had median chloride concentrations less than or equal to 250 milligrams per liter (mg/L), the secondary drinking water standard set by the U.S. Environmental Protection Agency. Eighty-one wells (55 percent) pumped water with median chloride concentrations above 500 mg/L. The Mann-Kendall test was used to determine if chloride concentrations of groundwater withdrawals at 146 municipal production wells had statistically significant trends during December 2009–February 2019. Trends were considered statistically significant for probability values (p-values) less than or equal to 0.05. Test results indicate an upward trend at 9 wells, a downward trend at 52 wells, and no trend at 85 wells. Salinity profiles were measured in 12 selected monitor wells during July–August 2018 and were measured in six of the twelve selected monitor wells during March 2019. The salinity profiles were used to estimate the thickness of the freshwater lens at 10 monitor wells; freshwater-lens thickness was greatest (46 ft) in a monitor well in the Dan Dan well field near the northern part of the southern plateau. Freshwater-lens-thickness estimates elsewhere were (1) between 0 and 28 ft for the remaining monitor wells on the southern plateau, (2) between 19 and 21 ft for monitor wells on the Kagman Peninsula, (3) 2 ft for a monitor well in the Sablan Quarry well field on west-central Saipan, and (4) 8 ft for a monitor well in the Marpi Quarry well field on northern Saipan.

Commonwealth of the Norhtern Marianas Islands, Sai↗

USGS2021

Effect of organic matter concentration and characteristics on mercury mobilization and methylmercury production at an abandoned mine site

Thousands of abandoned mines throughout the western region of North America contain elevated total-mercury (THg) concentrations. Mercury is mobilized from these sites primarily due to erosion of particulate-bound Hg (THg-P). Organic matter-based soil amendments can promote vegetation growth on mine tailings, reducing erosion and subsequent loading of THg-P into downstream waterbodies. However, the introduction of a labile carbon source may stimulate microbial activity that can produce methylmercury (MeHg)—the more toxic and bioaccumulative form of Hg. Our objectives were to investigate how additions of different organic matter substrates impact Hg mobilization and methylation using a combination of field observations and controlled experiments. Field measurements of water, sediment, and porewater were collected downstream of the site and multi-year monitoring (and load calculations) were conducted at a downstream gaging station. MeHg production was assessed using stable isotope methylation assays and mesocosm experiments that were conducted using different types of organic carbon soil amendments mixed with materials from the mine site. The results showed that >80% of the THg mobilized from the mine was bound to particles and that >90% of the annual Hg loading occurred during the period of elevated discharge during spring snowmelt. Methylation rates varied between different types of soil amendments and were correlated with the components of excitation emission matrices (EEMs) associated with humic acid fractions of organic matter. The mesocosm experiments showed that under anoxic conditions carbon amendments to tailings could significantly increase porewater MeHg concentrations (up to 13 ± 3 ng/L). In addition, the carbon amendments significantly increased THg partitioning into porewater. Overall, these results indicate that soil amendment applications to reduce surface erosion at abandoned mine sites could be effective at reducing particulate Hg mobilization to downstream waterbodies; however, some types of carbon amendments can significantly increase Hg methylation as well as increase the mobilization of dissolved THg from the site.

Idaho↗

USGS2020

A national-scale assessment of mercury bioaccumulation in United States National Parks using dragonfly larvae as biosentinels through a citizen-science framework

We conducted a national-scale assessment of mercury (Hg) bioaccumulation in aquatic ecosystems using dragonfly larvae as biosentinels, by developing a citizen science network to facilitate biological sampling. Implementing a carefully designed sampling methodology for citizen scientists, we developed an effective framework for landscape-level inquiry that might otherwise be resource limited. We assessed variation in dragonfly Hg concentrations across >450 sites spanning 100 US National Park Service units, and examined intrinsic and extrinsic factors associated with variation in Hg concentrations. Mercury concentrations ranged between 10.4-1,411 ng/g dry weight across sites and varied among habitat types. Dragonfly total Hg (THg) concentrations were up to 1.8-fold higher in lotic habitats than in lentic habitats, and 37% higher in waterbodies with abundant wetlands along their margins than those without wetlands. Mercury concentrations in dragonflies differed among families, but were correlated (R2>0.80) with each other, enabling adjustment to a consistent family to facilitate spatial comparisons among sampling units. Dragonfly THg concentrations were positively correlated with THg in both fish and amphibians from the same locations, indicating that dragonfly larvae are effective indicators of Hg bioavailability in aquatic food webs. Collectively, this continental-scale study demonstrates the utility of dragonfly larvae for estimating potential mercury risk to fish and wildlife in aquatic ecosystems and provides a framework for engaging citizen science as a component of landscape Hg monitoring programs.

Environmental Science and Technology↗

USGS2022

Temporal variability in TiO2 engineered particle concentrations in rural Edisto River

Titanium dioxide (TiO 2 ) is widely used in engineered particles including engineered nanomaterial (ENM) and pigments, yet its occurrence, concentrations, temporal variability, and fate in natural environmental systems are poorly understood. For three years, we monitored TiO 2 concentrations in a rural river basin (Edisto River, < 1% urban land cover) in South Carolina, United States. The total concentrations of Ti, Nb, Al, Fe, Ce, and La in the Edisto River trended higher during spring/summer compared to autumn/winter. Upward trending Ti/Nb ratio in the spring/summer compared to near-background autumn/winter ratios of 255.7 ± 8.9 indicated agricultural preparation and growing-season-related increases in TiO 2 engineered particles. In contrast, downward trending of the Ti/Al and Ti/Fe ratios in the spring and summer compared to the near-background autumn/winter ratios of 0.05 indicated greater mobilization of Fe and Al, relative to Ti during spring/summer. Surface-water concentrations of TiO 2 engineered particles varied between 0 and 128.7 ± 3.9 μg TiO 2 L −1 . Increases in TiO 2 concentrations over the spring/summer were associated with increases in phosphorus, orthophosphate, nitrate, ammonia, anthropogenic gadolinium, water temperature, suspended sediments, organic carbon, and alkalinity, and with decreases in dissolved oxygen. The association between these contaminants together with the timing of the increases in their concentrations is consistent with diffuse wastewater sources, such as reuse application overspray, biosolids fertilization, leaking sewers, or septic tanks, as the driver of instream concentrations; however, other diffuse sources cannot be ruled out. The findings of this study indicate spatially-distributed (non-point source) releases can result in high concentrations of TiO 2 engineered particles, which may pose higher risks to rural stream aquatic ecosystems during the agricultural season. The results illustrate the importance of monitoring seasonal variations in engineered particles concentrations in surface waters for a more representative assessment of ecosystem risk.

South Carolina↗

USGS2021

Conservation of northwestern and southwestern pond turtles: Threats, population size estimates, and population viability analysis

Accurate status assessments of long-lived, widely distributed taxa depend on the availability of long-term monitoring data from multiple populations. However, monitoring populations across large temporal and spatial scales is often beyond the scope of any one researcher or research group. Consequently, wildlife managers may be tasked with utilizing limited information from different sources to detect range-wide evidence of population declines and their causes. When assessments need to be made under such constraints, the research and management communities must determine how to extrapolate from variable population data to species-level inferences. Here, using three different approaches, we integrate and analyze data from the peer-reviewed literature and government agency reports to inform conservation for northwestern pond turtles (NPT) Actinemys marmorata and southwestern pond turtles (SPT) Actinemys pallida . Both NPT and SPT are long-lived freshwater turtles distributed along the west coast of the United States and Mexico. Conservation concerns exist for both species; however, SPT may face more severe threats and are thought to exist at lower densities throughout their range than NPT. For each species, we ranked the impacts of 13 potential threats, estimated population sizes, and modeled population viability with and without long-term droughts. Our results suggest that predation of hatchlings by invasive predators, such as American bullfrogs Lithobates catesbeianus and Largemouth Bass Micropterus salmoides, is a high-ranking threat for NPT and SPT. Southwestern pond turtles may also face more severe impacts associated with natural disasters (droughts, wildfires, and floods) than do NPT. Population size estimates from trapping surveys indicate that SPT have smaller population sizes on average than do NPT ( P = 0.0003), suggesting they may be at greater risk of local extirpation. Population viability analysis models revealed that long-term droughts are a key environmental parameter; as the frequency of severe droughts increases with climate change, the likelihood of population recovery decreases, especially when census sizes are low. Given current population trends and vulnerability to natural disasters throughout their range, we suggest that conservation and recovery actions first focus on SPT to prevent further population declines.

Journal of Fish and Wildlife Management↗

USGS2016

Assessing atmospheric concentration of polychlorinated biphenyls (PCBs) by evergreen Rhododendron maximum next to a contaminated stream

Conifers are often used as an “air passive sampler”, but few studies have focused on the implication of broadleaf evergreens to monitor atmospheric semivolatile organic compounds such as polychlorinated biphenyls (PCBs). In this study, we used Rhododendron maximum (rhododendron) growing next to a contaminated stream to assess atmospheric PCB concentrations. The study area was located in a rural setting and approximately 2 km downstream of a former Sangamo-Weston (S-W) plant. Leaves from the same mature shrubs were collected in late fall 2010, and winter and spring 2011. PCBs were detected in the collected leaves suggesting that rhododendron can be used as air passive samplers in rural areas where active sampling is impractical. Estimated ΣPCB (47 congeners) concentrations in the atmosphere decreased from fall 2010 to spring 2011 with concentration means at 3990, 2850, and 931 pg m -3 in fall 2010, winter 2011, and spring 2011, respectively. These results indicate that the atmospheric concentrations at this location continue to be high despite termination of active discharge from the former S-W plant. Leaves had a consistent pattern of high concentrations of tetra- and penta-CBs similar to the congener distribution in polyethylene (PE) passive samplers deployed in the water column suggesting that volatilized PCBs from the stream were the primary source of contaminants in rhododendron leaves.

South Carolina↗

USGS2022

Using piecewise regression to identify biological phenomena in biotelemetry datasets

1. Technological advances in the field of animal tracking have greatly expanded the potential to remotely monitor animals, opening the door to exploring how animals shift their behavior over time or respond to external stimuli. A wide variety of animal-borne sensors can provide information on an animal’s location, movement characteristics, external environmental conditions, and internal physiological status. 2. Here, we demonstrate how piecewise regression can be used to identify the presence and timing of potential shifts in a variety of biological responses using GPS telemetry and other biologging data streams. Different biological latent states can be inferred by partitioning a time-series into multiple segments based on changes in modeled responses (e.g., their mean, variance, trend, degree of autocorrelation) and specifying a unique model structure for each interval. 3. We provide six example applications highlighting a variety of taxonomic species, data streams, timescales and biological phenomena. These examples include a short-term behavioural response (flee and return) by a trumpeter swan Cygnus buccinator following a GPS collar deployment; remote identification of parturition based on movements by a pregnant moose Alces alces ; a physiological response (spike in heart-rate) in a black bear Ursus americanus to a stressful stimulus(presence of a drone); a mortality event of a trumpeter swan signalled by changes in collar temperature and overall dynamic body acceleration; an unsupervised method for identifying the onset, return, duration and staging use of sandhill crane Antigone canadensis migration; and estimation of the transition between incubation and brood-rearing (i.e. hatching) for a breeding trumpeter swan. 4. We implement analyses using the MCP package in R, which provides functionality for specifying and fitting a wide variety of user-defined model structures in a Bayesian framework and methods for assessing and comparing models using information criteria and cross-validation measures.

Journal of Animal Ecology↗

USGS2024

Predictive understanding of stream salinization in a developed watershed using machine learning

Stream salinization is a global issue, yet few models can provide reliable salinity estimates for unmonitored locations at the time scales required for ecological exposure assessments. Machine learning approaches are presented that use spatially limited high-frequency monitoring and spatially distributed discrete samples to estimate the daily stream-specific conductance across a watershed. We compare the predictive performance of space- and time-unaware Random Forest models and space- and time-aware Recurrent Graph Convolution Neural Network models (KGE: 0.67 and 0.64, respectively) and use explainable artificial intelligence methods to interpret model predictions and understand salinization drivers. These models are applied to the Delaware River Basin, a developed watershed with diverse land uses that experiences anthropogenic salinization from winter deicer applications. These models capture seasonality for the winter first flush of deicers, and the streams with elevated predictions correspond well with indicators of deicer application. This result suggests that these models can be used to identify potential salinity-impaired streams for winter best management practices. Daily salinity predictions are driven primarily by land cover (urbanization) trends that may represent anthropogenic salinization processes and weather at time scales up to three months. Such modeling approaches are likely transferable to other watersheds and can be applied to further understand salinization risks and drivers.

Environmental Science and Technology↗

USGS1996

Occurrence of selected contaminants in water, fish tissue, and streambed sediments in central Nebraska, 1992-95

Surface and ground water in Nebraska may contain contaminants resulting from human activities. For purposes of this publication, a contaminant is any element or compound whose presence may affect the water's suitability for certain uses. For example, herbicide concentrations may exceeed the U.S. Environmental Protection Agency's (USEPA) Health Advisory Levels (HAL) for drinking water or trace-element concentrations may exceed guidelines for the protection of aquatic life. In general, the contaminats discussed in this report enter the aquatic system through nonpoint-source runoff from agricultural lands that dominate the Nebraska landscape. However,because this assessment was conducted as part of a larger, national program, a screening for contaminants with non-agricultural origins was included. The measurement of water quality involves a variety of steps, each contributing unique information while also aggregating to an overall assessment. One aspect of water-quality assesment is to describe the occurrence and distribution of contaminants. Some contaminants may be hundreds or thousands of times more concentrated in the tissues of aquatic organisms or in fine sediments than they are in the water. As a result, fish tissue and streambed sediments are well suited for the detection of certain contaminants. For example, pesticides used in the United States prior to the early 1970's, such as DDT, may have degraded into more stable but still toxic compounds that are highly concentrated in fish tissues. Conversely, other contaminants are not concentrated in sediments or tissues but are readily detected in water samples. Organonitrogen herbicides (such as atrazine), the most commonly used herbicides in Nebraska, are examples of water-soluble contaminants. Several sampling strategies were used to address specific questions. Some sites were sampled repeatedly through time and during all hydrologic conditions, whereas others were sampled only once to determine presence of contaminants. Because a strong relation between concentration and streamflow often exists for contaminants originating from nonpoint sources, streams typically were sampled near gaging stations that monitor streamflow.

Nebraska↗

USGS2016

Mercury concentrations in water and mercury and selenium concentrations in fish from Brownlee Reservoir and selected sites in the Boise and Snake Rivers, Idaho and Oregon, 2013–15

Mercury (Hg) analyses were conducted on samples of sport fish and water collected from selected sampling sites in Brownlee Reservoir and the Boise and Snake Rivers to meet National Pollution Discharge and Elimination System (NPDES) permit requirements for the City of Boise, Idaho, between 2013 and 2015. City of Boise personnel collected water samples from six sites between October and November 2013 and 2015, with one site sampled in 2014. Total Hg concentrations in unfiltered water samples ranged from 0.48 to 8.8 nanograms per liter (ng/L), with the highest value in Brownlee Reservoir in 2013. All Hg concentrations in water samples were less than the U.S. Environmental Protection Agency (USEPA) Hg chronic aquatic life criterion of 12 ng/L. The USEPA recommended a water-quality criterion of 0.30 milligrams per kilogram (mg/kg) methylmercury (MeHg) expressed as a fish-tissue residue value (wet-weight MeHg in fish tissue). The Idaho Department of Environmental Quality adopted the USEPA’s fish-tissue criterion and established a reasonable potential to exceed (RPTE) threshold 20 percent lower than the criterion or greater than 0.24 mg/kg Hg based on an average concentration of 10 fish from a receiving waterbody. NPDES permitted discharge to waters with fish having Hg concentrations exceeding 0.24 mg/kg are said to have a reasonable potential to exceed the water-quality criterion and thus are subject to additional permit obligations, such as requirements for increased monitoring and the development of a Hg minimization plan. The Idaho Fish Consumption Advisory Program (IFCAP) issues fish advisories to protect general and sensitive populations of fish consumers and has developed an action level of 0.22 mg/kg Hg in fish tissue. Fish consumption advisories are water body- and species-specific and are used to advise allowable fish consumption from specific water bodies. The geometric mean Hg concentration of 10 fish of a single species collected from a single water body (lake or stream) in Idaho is compared to the action level to determine if a fish consumption advisory should be issued. The U.S. Geological Survey collected and analyzed individual fillets of mountain whitefish ( Prosopium williamsoni ), rainbow trout ( Oncorhynchus mykiss ), smallmouth bass ( Micropterus dolomieu ), and channel catfish ( Ictalurus punctatus ) for Hg. The 2013 average Hg concentration for small mouth bass (0.32 mg/kg) collected at Brownlee Reservoir and for channel catfish (0.33 mg/kg) collected at the Boise River mouth, exceeded the Idaho water quality criterion (>0.3 mg/kg), the Hg RPTE threshold (>0.24 mg/kg), and the IFCAP action level (>0.22 mg/kg). Average Hg concentrations in fish collected in 2014 or 2015 did not exceed evaluation criteria for any of the species assessed. Selenium (Se) analysis was conducted on one composite fish tissue sample per site to assess general concentrations and to provide information for future risk assessments. Composite concentrations of Se in fish tissue collected between 2013 and 2015 ranged from 0.07 and 0.49 mg/kg wet weight with the highest concentration collected from smallmouth bass from the Snake River near Murphy, and the lowest from mountain whitefish from the Boise River at Eckert Road.

Idaho↗

USGS2013

Sources and characteristics of organic matter in the Clackamas River, Oregon, related to the formation of disinfection by-products in treated drinking water

This study characterized the amount and quality of organic matter in the Clackamas River, Oregon, to gain an understanding of sources that contribute to the formation of chlorinated and brominated disinfection by-products (DBPs), focusing on regulated DBPs in treated drinking water from two direct-filtration treatment plants that together serve approximately 100,000 customers. The central hypothesis guiding this study was that natural organic matter leaching out of the forested watershed, in-stream growth of benthic algae, and phytoplankton blooms in the reservoirs contribute different and varying proportions of organic carbon to the river. Differences in the amount and composition of carbon derived from each source affects the types and concentrations of DBP precursors entering the treatment plants and, as a result, yield varying DBP concentrations and species in finished water. The two classes of DBPs analyzed in this study-trihalomethanes (THMs) and haloacetic acids (HAAs)-form from precursors within the dissolved and particulate pools of organic matter present in source water. The five principal objectives of the study were to (1) describe the seasonal quantity and character of organic matter in the Clackamas River; (2) relate the amount and composition of organic matter to the formation of DBPs; (3) evaluate sources of DBP precursors in the watershed; (4) assess the use of optical measurements, including in-situ fluorescence, for estimating dissolved organic carbon (DOC) concentrations and DBP formation; and (5) assess the removal of DBP precursors during treatment by conducting treatability "jar-test" experiments at one of the treatment plants. Data collection consisted of (1) monthly sampling of source and finished water at two drinking-water treatment plants; (2) event-based sampling in the mainstem, tributaries, and North Fork Reservoir; and (3) in-situ continuous monitoring of fluorescent dissolved organic matter (FDOM), turbidity, chlorophyll- a , and other constituents to continuously track source-water conditions in near real-time. Treatability tests were conducted during the four event-based surveys to determine the effectiveness of coagulant and powdered activated carbon (PAC) on the removal of DBP precursors. Sample analyses included DOC, total particulate carbon (TPC), total and dissolved nutrients, absorbance and fluorescence spectroscopy, and, for regulated DBPs, concentrations of THMs and HAAs in finished water and laboratory-based THM and HAA formation potentials (THMFP and HAAFP, respectively) for source water and selected locations throughout the watershed. The results of this study may not be typical given the record and near record amounts of precipitation that occurred during spring that produced streamflow much higher than average in 2010-11. Although there were algal blooms, lower concentrations of chlorophyll- a were observed in the water column during the study period compared to historical data. Concentrations of DBPs in finished (treated) water averaged 0.024 milligrams per liter (mg/L) for THMs and 0.022 mg/L for HAAs; maximum values were about 0.040 mg/L for both classes of DBPs. Although DBP concentrations were somewhat higher within the distribution system, none of the samples collected for this study or for the quarterly compliance monitoring by the water utilities exceeded levels permissible under existing U.S. Environmental Protection Agency (USEPA) regulations: 0.080 mg/L for THMs and 0.060 mg/L for HAAs. DOC concentrations were generally low in the Clackamas River, typically about 1.0-1.5 mg/L. Concentrations in the mainstem occasionally increased to nearly 2.5 mg/L during storms; DOC concentrations in tributaries were sometimes much higher (up to 7.8 mg/L). The continuous in-situ FDOM measurements indicated sharp rises in DOC concentrations in the mainstem following rainfall events; concentrations were relatively stable during summer base flow. Even though the first autumn storm mobilized appreciable quantities of carbon, higher concentrations of DBPs in finished water were observed 3-weeks later, after the ground was saturated from additional rainfall. The majority of the DOC in the lower Clackamas River appears to originate from the upper basin, suggesting terrestrial carbon was commonly the dominant source. Lower-basin tributaries typically contained the highest concentrations of DOC and DBP precursors and contributed substantially to the overall loads in the mainstem during storms. During low-flow periods, tributaries were not major sources of DOC or DBP precursors to the Clackamas River. Although the dissolved fraction of organic carbon contributed the majority of DBP precursors, at times the particulate fraction (inorganic sediment and organic particles including detritus and algal material) contributed a substantial fraction of DBP precursors. Considering just the main-stem sites, on average, 10 percent of THMFP and 32 percent of HAAFP were attributed to particulate carbon. This finding suggests water-treatment methods that remove particles prior to chlorination would reduce finished-water DBP concentrations to some degree. Overall, concentrations of THM and HAA precursors were closely linked to DOC concentrations; laboratory DBP formation potentials (DBPFPs) clearly showed that THMFP and HAAFP were greatest in the downstream tributaries that contained elevated carbon concentrations. However, carbon-normalized "specific" formation potentials for THMs and HAAs (STHMFP and SHAAFP, respectively) revealed changes in carbon character over time that affected the two types of DBP classes differently. HAA precursors were elevated in waters containing aromatic-rich soil-derived material arising from forested areas. In contrast, THM precursors were associated with carbon having a lower aromatic content; highest STHMFP occurred in autumn 2011 in the mainstem from North Fork Reservoir downstream to LO DWTP. This pattern suggests the potential for a link between THM precursors and algal-derived carbon. The highest STHMFP value was measured within North Fork Reservoir, indicating reservoir derived carbon may be important for this class of DBPs. Weak correlations between STHMFP and SHAAFP emphasize that precursor sources for these types of DBPs may be different. This highlights not only that different locations within the watershed produce carbon with different reactivity (specific DBPFP), but also that different management approaches for each class of DBP precursors could be required for control. Treatability tests conducted on source water during four basin-wide surveys demonstrated that an average of about 40 percent of DOC can be removed by coagulation. While the decrease in THMFP following coagulation was similar to DOC, the decrease in HAAFP was much greater (approximately 70 percent), indicating coagulation is particularly effective at removing HAA precursors'likely because of the aromatic nature of the carbon associated with HAA precursors. Several findings from this study have direct implications for managing drinking-water resources and for providing useful information that may help improve treatment-plant operations. For example, the use of in-situ fluorometers that measure FDOM provided an excellent proxy for DOC concentration in this system and revealed short-term, rapid changes in DOC concentration during storm events. In addition, the strong correlation between FDOM values measured in-situ and HAA5 concentrations in finished water may permit estimation of continuous HAA concentrations, as was done here. As part of this study, multiple in-situ FDOM sensors were deployed continuously and in real-time to characterize the composition of dissolved organic matter. Although the initial results were promising, additional research and engineering developments will be needed to demonstrate the full utility of these sensors for this purpose. In conclusion, although DBPFPs were strongly correlated to DOC concentration, some DBPs formed from particulate carbon, including terrestrial leaf material and algal material such as planktonic species of blue-green algae and sloughed filaments, stalks, and cells of benthic algae. Different precursor sources in the watershed were evident from the data, suggesting specific actions may be available to address some of these sources. In-situ measurements of FDOM proved to be an excellent proxy for DOC concentration as well as HAA formation during treatment, which suggests further development and refinement of these sensors have the potential to provide real-time information about complex watershed processes to operators at the drinking-water treatment plants. Follow-up studies could examine the relative roles that terrestrial and algal sources have on the DBP precursor pool to better understand how watershed-management activities may be affecting the transport of these compounds to Clackamas River drinking-water intakes. Given the low concentrations of algae in the water column during this study, additional surveys during more typical river conditions could provide a more complete understanding of how algae contribute DBP precursors. Further development of FDOM-sensor technology can improve our understanding of carbon dynamics in the river and how concentrations may be trending over time. This study was conducted in collaboration with Clackamas River Water and the City of Lake Oswego water utilities. Other research partners included Oregon Health and Science University in Hillsboro, Oregon, Alexin Laboratory in Tigard, Oregon, U.S. Geological Survey National Research Program Laboratory in Denver, Colorado, and the U.S. Geological Survey Water Science Centers in Portland, Oregon, and Sacramento, California. This project was supported with funding from Clackamas River Water, City of Lake Oswego, the U.S. Geological Survey, and the Water Research Foundation.

Oregon↗

USGS2019

Mercury concentrations vary within and among individual bird feathers: A critical evaluation and guidelines for feather use in mercury monitoring programs

Feathers are widely used to represent mercury contamination in birds. Yet, few recommendations exist that provide guidance for using bird feathers in mercury monitoring programs. We conducted a literature review and 5 experiments to show that mercury concentrations vary substantially within (vane >100% higher than calamus) and among (>1000%) individual feathers from the same bird. We developed a research tool and guidelines for using bird feathers for mercury studies based on three components: 1) variability of feather mercury concentrations within an individual bird (coefficient of variation [CV]), 2) desired accuracy of the measured mercury concentration, and 3) feather and bird mass. Our results suggest a general rule that if the goal is to limit analytical and processing costs by using whole feathers in only one sample boat, then to achieve an accuracy within 10% of a bird’s overall average feather mercury concentration a bird with a CV≤10% must be <190 g (size of large shorebird). To achieve an accuracy within 20%, a bird with a CV≤10% must be <920 g (size of large duck). When >1 sample boat is needed to fit the required number of feathers to achieve the desired accuracy, results suggest homogenizing feathers and analyzing an aliquot of ≥20 mg for mercury. This study indicates increasing the number of feathers typically used per bird to assess mercury concentrations.

Environmental Toxicology and Chemistry↗

USGS2019

Exploring trends in wet-season precipitation and drought indices in wet, humid and dry regions

This study examines wet season droughts using eight products from the FROGS database. The study begins by evaluating wet season precipitation totals and wet day counts at seasonal and decadal time scales. While we find a high level of agreement among the products at a seasonal timescale, evaluations of 10-year variability indicate substantial non-stationary inter-product differences that make the assessment of low-frequency changes difficult, especially in data-sparse regions. Some products, however, appear more reliable than others on decadal time scales. Global time series of dry, middle, and wet region standardized precipitation index (SPI) time series indicate little coherent change. There is substantial coherence in year-to-year variations in these time series, for the better performing products, likely indicative of skill for monitoring variations at large spatial scales. During the wet season, the data do not appear to indicate wide spread global increases in precipitation, RefET or Standardized Precipitation Evapotranspiration Index (SPEI) values. Neither the precipitation, RefET or SPEI indicate a wide-spread regional shift towards more arid conditions. Focusing on SPEI values for dry regions during droughts, however, indicate substantial increases in dry region aridity when wet season precipitation is below normal. Dry region SPEI values during droughts have decreased by -0.2 since the 1990s. More detailed analysis in further studies will be needed to confirm this result. For wet regions, however, the majority of products appear to indicate increases in wet season precipitation, although many products perform poorly in these regions due to limited observation networks, and estimated increases vary substantially.

Environmental Research Letters↗