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Assessment of natural gas pipeline construction on stream temperature and turbidity in southwestern Virginia, 2017–25

Despite the extensive natural gas pipeline network in the United States that intersects streams and other sensitive habitats, few case studies use a comparative upstream-to-downstream approach to evaluate potential short- and long-term effects of pipeline stream crossings from pre-construction through post-restoration. In 2017, the U.S. Geological Survey, in cooperation with the Virginia Department of Environmental Quality, deployed real-time continuous stream monitoring stations upstream and downstream from six proposed Mountain Valley Pipeline stream crossings in southwestern Virginia. Water temperature and turbidity data collected at the upstream and downstream sites were compared across three periods—before stream crossing construction, during stream crossing construction, and after stream crossing construction—to determine potential influences from the pipeline stream crossing. Additionally, the monitoring network was used to notify regulators of potentially anomalous conditions throughout the entire monitoring period. The results of this study indicate that pipeline stream crossing did not affect long-term or short-term upstream-to-downstream water temperature conditions or long-term upstream-to-downstream turbidity conditions in any of the six monitored streams. Some short-term anomalously elevated turbidity conditions were observed and attributable to pipeline stream crossing; however, the magnitudes and durations were not sufficient to alter the long-term turbidity regimes of the streams in which they were observed. The application of the monitoring network as a real-time alert system successfully alerted regulators to potentially anomalous conditions.

Virginia↗

Diatremes and craters attributed to natural explosions

Diatremes - volcanic pipes attributed to explosion - and craters have been studied to infer the ultimate causes and physical conditions attending natural explosive processes. Initial piercement of diatremes on the Navajo reservation, Arizona was probably along a fracture propagated by a high-pressure aqueous fluid. Gas rising at high velocity along the fracture would become converted to a gas-solid fluidized system by entrainment of wall- rock fragments. The first stages of widening of the vent are probably accomplished mainly by simple abrasion of the high-velocity fluidized system on the walls of the fracture. As the vent widens, its enlargement may be accelerated by inward spalling of the walls. The inferred mechanics of the Navajo-Hopi diatremes is used to illustrate the possibility of diatreme formation over a molten salt mass.

Trace Elements Memorandum↗

Integrating climate change considerations into natural resource planning—An implementation guide

Executive Summary Climate change vulnerability assessments and associated adaptation strategies and actions connect existing climate science with possible effects on natural resources and highlight potential responses. However, these assessments, which are commonly generated for large regional areas, suggest management options in general terms without guidance for choosing among strategies and actions under specific circumstances. Meanwhile, land and resource management plans1 often address smaller geographies, and management actions must address specific rather than general situations. Thus, there is a need for tools that enable managers to bridge the gap by downscaling assessments, plans, and data generated at regional scales to identify adaptation actions and strategies appropriate for smaller management units and project-level planning. To address this need, we have developed a tool–the Climate Adaptation Integration Tool (CAIT)–that helps resource managers use climate science and assessments, along with local knowledge, to identify those adaptation strategies and actions most appropriate for a given site or situation. Specifically, we provide: Guidance for acquiring and using downscaled climate change projections; Procedures for using these data to answer Critical Questions to make site-specific determinations of the appropriate management approach (specifically, resistance, resilience, transition, realignment, or no action); Lists of potential adaptation strategies and actions appropriate to the chosen management approach; and Supplemental information regarding adaptation strategies and actions to help managers choose among them. The CAIT is meant to help managers integrate climate change science and assessments into management decisions. The CAIT also serves as a way for managers to document how they have incorporated climate change information into their decision-making and why certain actions were selected over others. A particular strength of the CAIT is that it leads to potential solutions (that is, adaptation strategies and actions) without inflexibly prescribing actions. This flexibility enables managers to incorporate other factors and constraints to create workable management plans and projects that strengthen their ability to achieve long-term conservation goals.

Techniques and Methods↗

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Arsenic speciation in natural-water samples using laboratory and field methods

Analytical methods for the determination of arsenite [As(III)], arsenate [As(V)], dimethylarsinate (DMA), monomethylarsonate (MMA), and roxarsone in filtered natural-water samples are described. Various analytical methods can be used for the determination, depending on the arsenic species being determined. Arsenic concentration is determined by using inductively coupled plasma-mass spectrometry (ICP-MS) as an arsenic-specific detector for all methods. Laboratory-speciation methods are described that use an ion chromatographic column to separate the arsenic species; the column length, column packing, and mobile phase are dependent on the species of interest. Regardless of the separation technique, the arsenic species are introduced into plasma by eithe rpneumatic nebulization or arsine generation. Analysis times range from 2 to 8 minutes and method detection limits range from 0.1 to 0.6 microgram-arsenic per liter (ug-As/L), 10 to 60 picograms absolute (for a 100-microliter injection), depending on the arsenic species determined and the analytical method used. A field-generation specciation method also is described that uses a strong anion exchange cartridge to separate As(III) from As(V) in the field. As(III) in the eluate and the As(V) in the cartridge extract are determined by direct nebulization ICP-MS. Methylated arsenic species that also are retained on the cartridge will positively bias As(V) results without further laboratory separations. The method detection limit for field speciation is 0.3 ug-As/L. The distribution of arsenic species must be preserved in the field to eliminate changes caused by photochemical oxidation or metal oxyhydroxide precipitation. Preservation techniques, such as refrigeration, the addition of acides, or the additoin of ethylene-diaminetetraacetic acid (EDTA) and the effects of ambient light were tested. Of the preservatives evaluated, EDTA was found to work best with the laboratory- and field-speciation methods for all sample matrices tested. Storing the samples in opaque polytethylene bottles eliminated the effects of photochemical oxidation. The percentage change in As(III):As(V) ratios for an EDTA-preserved acid mine drainage (AMD) sample and ground-water sample during a 3-month period was -5 percent and +3 percent, respectively. The bias and variability of the methods were evaluated by comparing results for total arsenic and As(III), As(V), DMA, and MMA concentrations in ground water, AMD, and surface water. Seventy-one ground-water, 10 AMD, and 24 surface-water samples were analyzed. Concentrations in ground-water samples reached 720 ug-As/L for As(III) and 1080 ug-As/L for As(V); AMD samples reached 12800 ug-As/L for As(III) and 7050 ug-As/L for As(V); and surface-water samples reached 5 ug-As/L for As(III) and As(V). Inorganic arsenic species distribution in the samples ranged from 0 to 90 percent As(III). DMA and MMA were present only in surface-water samples from agricultural areas where the herbicide monosodium methylarsonate was applied; concentrations never exceeded 6 ug-As/L. Statistical analyses indicated that the difference between As(III) and As(V) concentrations for samples preserved with EDTA in opaque bottles and field-speciation results were analytically insignificant at the 95-percent confidence interval. There was no significant difference among the methods tested for total arsenic concentration. Percentage recovery for field samples spiked at 50 ug-As/L and analyzed by the laboratory-speciation method (n=2) ranged from 82 to 100 percent for As(III), 97 to 102 percent for As(V), 90 to 104 percent for DMA, and 81 to 96 percent for MMA; recoveries for samples spiked at 100 ug-As/L and analyzed by the field-speciation method ranged from 102 to 107 percent for As(III) and 105 to 106 percent for As(V). Laboratory-speciation results for Environment Canada reference material SLRS-2 closely matched reported concentrations. Laboratory-speciation metho

Water-Resources Investigations Report↗

Response of fish communities to cropland density and natural environmental setting in the Eastern Highland Rim Ecoregion of the lower Tennessee River basin, Alabama and Tennessee, 1999

Response of fish communities to cropland density and natural environmental setting were evaluated at 20 streams in the Eastern Highland Rim Ecoregion of the lower Tennessee River Basin during the spring of 1999. Sites were selected to represent a gradient of cropland densities in basins draining about 30 to 100 square miles. Fish communities were sampled by using a combination of seining and electrofishing techniques. A total of 10,550 individual fish, representing 63 species and 15 families, were collected during the study and included the families Cyprinidae (minnows), 18 species; Percidae (perch and darters), 12 species; and Centrarchidae (sunfish), 12 species. Assessments of environmental characteristics, including instream and terrestrial data and land-cover data, were conducted for each site. Instream measurements, such as depth, velocity, substrate type, and embeddedness, were recorded at 3 points across 11 equidistant transects at each site. Terrestrial measurements, such as bank angle, canopy angle, and canopy closure percentage, were made along the stream bank and midchannel areas. Water-quality data collected included pH, dissolved oxygen, specific conductivity, water temperature, nutrients, and fecal-indicator bacteria. Substrate embeddedness was the only variable correlated with both cropland density and fish communities (as characterized by ordination scores and several community level metrics). Multivariate and nonparametric correlation techniques were used to evaluate fish-community responses to physical and chemical factors associated with a cropland-density gradient, where the gradient was defined as the percentage of the basin in row crops. Principal component analysis and correspondence analysis suggest that the Eastern Highland Rim Ecoregion is composed of three subgroups of sites based on inherent physical and biological differences. Data for the subgroup containing the largest number of sites were then re-analyzed, revealing that several environmental variables, such as nutrient concentrations, stream gradient, bankfull width, and substrate embeddedness, were related to cropland density; however, only a subset of those variables (substrate embeddedness, elevation, and streamflow) were related to fish communities. Results from this analysis suggest that although many water-quality and habitat variables are covariant with cropland density, most of the variables do not significantly affect fish-community composition; instead, fish communities primarily respond to the cumulative effects of sedimentation.

Water-Resources Investigations Report↗

Water quality characteristics of six small lakes in Missouri: Mo. Dept. of Natural Resources.

A study of six small lakes, representative of those in the major physiographic regions of Missouri, shows variation in physical. chemical, and biological characteristics related to their location in the Slate. For example, because of climatic differences, ice cover and winter stratification are more prevalent in northern Missouri. Summer stratification lasts about one month longer in the southern than in the northern part of the State. Because of the difference in geology. lake water in the Plains area is more mineralized than in the Ozarks. Different geology and land use generally account for more sedimentation of Plains Jakes. Lakes in the Plains area usually receive enough nutrients to be classified as mesouophic or eutrophic while those in the Ozarks receive less nutrients from natural sources and are often oligotrophic or mesotrophic. However, as seen from one of the study lakes, an oligotrophic lake can be made quite productive through the application of commercial fertilizers within the lake.

Missouri↗

Estimating the magnitude and frequency of floods on natural-flow streams in Massachusetts

The magnitude and frequency of floods on natural-flow streams in Massachusetts, with drainage areas between 0.25 square mile and 497 square miles, may be estimated from drainage area, main channel slope, a precipitation index, and a storage factor. Multiple-regression techniques were used to define the relationship between basin and climatic characteristics, and flood peaks for 113 gaging stations. Flood-frequency and magnitude data at the gaging stations were computed using the guidelines recommended by the U.S. Water Resources Council. It was found that flood peaks of rural, unregulated Massachusetts streams can best be defined by dividing the State into an EASTERN MASSACHUSETTS and a WESTERN MASSACHUSETTS flood-frequency region. The regression equations relate peak discharges with 0.5, 0.2, 0.1, 0.04, 0.02, 0.01, 0.005, and 0.002 exceedance probabilities to basin and climatic parameters. Standard errors of estimate ranged from 42 to 70 percent for the eastern river basins and from 32 to 68 percent for the western river basins. The defined estimating relations do not apply to streams where the flood flows are significantly affected by regulation where the usable man-made storage is over 4.5 million cubic feet per square mile, or by diversions or urbanization, or where the basin indices are outside a specified range. Also, these equations should not be used for basins in eastern Plymouth County, or Barnstable, Dukes, or Nantucket Counties where the available data are insufficient to determine the influence of high infiltration and storage capacities of drainage basins on flood flows. (Woodard-USGS)

Water-Resources Investigations Report↗

Additional and revised thermochemical data and computer code for WATEQ2: a computerized chemical model for trace and major element speciation and mineral equilibria of natural waters

A computerized chemical model, WATEQ2, has resulted from extensive additions to and revision of the WATEQ model of Truesdell and Jones (Truesdell, A. H., and Jones, B. F., 1974, WATEQ, a computer program for calculating chemical equilibria of natural waters: J. Res. U. S. Geol, Survey, v. 2, p. 233-274). The model building effort has necessitated searching the literature and selecting thermochemical data pertinent to the reactions added to the model. This supplementary report manes available the details of the reactions added to the model together with the selected thermochemical data and their sources. Also listed are details of program operation and a brief description of the output of the model. Appendices-contain a glossary of identifiers used in the PL/1 computer code, the complete PL/1 listing, and sample output from three water analyses used as test cases.

Water-Resources Investigations Report↗

Quantitative hydrogeology of the Upper Republican Natural Resources District, southwest Nebraska

Ground-water use for irrigation from the Ogallala Formation }'as in-creased rapidly in the Upper Republican Natural Resources District in southwest Nebraska. Water levels declined as much as 16 feet between 1952 and 1975. Discharge of the aquifer to streams was reduced by as much as 19 percent between 1967 and 1975. Quantification of the hydrogeologic system was provided by the development, testing and use of simulation models describing the soil zone and ground-water/surface-water system. Models were linked through source-sink terms. The ground-water/surface-water model was used.to predict changes in water levels and streamflow caused by unrestricted irrigation-well installation and by no new wells after 1975. Water levels may decline as much as 140 feet in two areas by 2000 if installation of new wells is unrestricted. By 2000, water-level declines o-er the remainder of the area would be less than 60 feet under continued development and less than 40 feet with no new wells after 1975. The base flow of Frenchman, Stinking Water, and Spring Creeks coulA be reduced by more than.90 percent with no new well and eliminated by 1992 under continued development.

Nebraska↗

Technique for estimating magnitude and frequency of floods in natural-flow streams in Florida

A technique is presented for estimating floods on natural-flow streams in Florida for specific recurrence intervals of 2, 5, 10 , 25, 50, 100, 200, and 500 years. Florida peaks from 159 stream-gaging stations with long-term records (10-53 years) and 23 rainfall-runoff stations with short-term records (7-17 years) were used in a multiple linear regression analysis to develop the regional equations relating peak discharge to basin characteristics. The State is divided into 3 hydrologic regions, A, B, and C. The significant independent variables in Regions A and C were drainage area, channel slope, and lake area. In Region B, the significant independent variables were drainage area and lake area. (USGS)

Water-Resources Investigations Report↗

Estimation of natural streamflow characteristics in western Colorado

Regression relations were determined for estimating mean annual discharge, mean monthly discharge, minimum and maximum 7-day discharge, flow duration series, and peak discharge for natural streams in western Colorado. Multiple regression analyses were used to determine the best predictive relations for each of the streamflow characteristic; separate relations were developed for each of four hydrologically distinct regions in the study area. The standard errors associated with the regression relations generally were less than 100 percent, except for the low-flow relations which had standard errors ranging from 62 to greater than 200 percent. Basin drainage area, mean annual precipitation , mean basin elevation, and mean basin slope are used in the regression relations to estimate the flow characteristics of streams in the study area. (USGS)

Water-Resources Investigations Report↗

Manual for estimating selected streamflow characteristics of natural-flow streams in the Colorado River basin in Utah

Methods are presented for estimating 10 streamflow characteristics at three types of sites on natural flow streams in the Colorado River Basin in Utah. The streamflow characteristics include average discharge and annual maximum 1-, 7-, and 15-day mean discharges for recurrence intervals of 10, 50 and 100 years. At or near gaged sites, two methods weight gaging station data with regression equation values to estimate streamflow characteristics. At sites on ungaged streams, a method estimates streamflow characteristics using regression equations. The regression equations relate the streamflow characteristics to the following basin and climatic characteristics: contributing drainage area, mean basin elevation, mean annual precipitation, main channel slope, and forested area. Separate regression equations were developed for four hydrologically distinct regions in the study area. The standard error of estimate for the 10 streamflow characteristics ranges from 13% to 87%. Basin, climatic, and streamflow characteristics, available as of September 30, 1981, are presented for 135 gaging stations in Utah, Arizona, Colorado, and Wyoming. In addition, weighted estimates of the streamflow characteristics based on station data and the regression equation estimates are provided for most gaging stations. (Author 's abstract)

Water-Resources Investigations Report↗

Measuring and computing natural ground-water recharge at sites in south-central Kansas

To measure the natural groundwater recharge process, two sites in south-central Kansas were instrumented with sensors and data microloggers. The atmospheric-boundary layer and the unsaturated and saturated soil zones were monitored as a single regime. Direct observations also were used to evaluate the measurements. Atmospheric sensors included an anemometer, a tipping-bucket rain gage, an air-temperature thermistor, a relative-humidity probe, a net radiometer, and a barometric-pressure transducer. Sensors in the unsaturated zone consisted of soil-temperature thermocouples, tensiometers coupled with pressure transducers and dial gages, gypsum blocks, and a neutron-moisture probe. The saturated-zone sensors consisted of a water-level pressure transducer, a conventional float gage connected to a variable potentiometer, soil thermocouples, and a number of multiple-depth piezometers. Evaluation of the operation of these sensors and recorders indicates that certain types of equipment, such as pressure transducers, are very sensitive to environmental conditions. A number of suggestions aimed at improving instrumentation of recharge investigations are outlined. Precipitation and evapotranspiration data, taken together with soil moisture profiles and storage changes, water fluxes in the unsaturated zone and hydraulic gradients in the saturated zone at various depths, soil temperature, water table hydrographs, and water level changes in nearby wells, describe the recharge process. Although the two instrumented sites are located in sand-dune environments in area characterized by a shallow water table and a sub-humid continental climate, a significant difference was observed in the estimated total recharge. The estimates ranged from less than 2.5 mm at the Zenith site to approximately 154 mm at the Burrton site from February to June 1983. The principal reasons that the Burrton site had more recharge than the Zenith site were more precipitation, less evapotranspiration, and a shallower depth to the water table. Effective recharge took place only during late winter and spring. No summer or fall recharge was observed at either site during the observation period of this study. (Author 's abstract)

Water-Resources Investigations Report↗

Natural radioactivity in, and inorganic chemistry of, ground water in the Kirkwood-Cohansey aquifer system, southern New Jersey, 1983-89

The distribution of naturally occurring radionuclides in ground water of the Kirkwood- Cohansey aquifer system in southern New Jersey was assessed during 1988-89. The Kirkwood-Cohansey aquifer system consists of quartz-sand formations overlain by a feldspar-rich quartz-sand formation, the Bridgeton Formation, that is heavily developed agriculturally. The sum of the concentrations of radium-226 and radium-228 exceeded the U.S. Environmental Protection Agency maximum contaminant level (MCL) of 5 pCi/L (picocuries per liter) in 26 of 81 wells from which water samples were analyzed, and gross alpha-particle activity exceeded the MCL of 15 pCi/L in 5 of the 81 samples. The median concentrations of radon-222 and uranium were 280 pCi/L and 0.03 micrograms per liter, respectively. Water in the Kirkwood-Cohansey aquifer system generally is dilute (median dissolved solids concentration, 55 milligrams per liter) and acidic (median pH, 4.90), but concentrations of major ions and acidity are higher in water from wells in areas where the Bridgeton Formation outcrop and agricultural land use are present than in areas where they are absent. Concentrations and activities of radionuclides also were greatest in these areas. Results of statistical analyses indicate that these relations are significant and nonrandom. The positive relation of radionuclide concentration or activity to the presence of geologic outcrop and agricultural land, and a similar relation of the concentration of inorganic constituents to the presence of geologic outcrop and agricultural land, indicate that geochemical processes enhance mobilization of radionuclides in these areas relative to areas where the Bridgeton Formation and agricultural land are absent. The sum of the ccncentrations of radium-226 and radium-228 most likely exceeds the MCL in ground-water samples with nitrate concentrations greater than 5 milligrams per liter.

New Jersey↗

Simulated response of the High Plains aquifer to ground-water withdrawals in the Upper Republican Natural Resources District, Nebraska

The U.S. Geological Survey, in cooperation with the National Soil Tilth Laboratory of the U.S. Department of Agriculture, Agricultural Research Service, conducted a study as part of the multi- scale, interagency Management Systems Evaluation Area (MSEA) program to evaluate the effects of agricultural management (farming) systems on water quality. Data on surface flow, tileflow, and streamflow in the Walnut Creek watershed just south of Ames, Iowa, were collected during April 1991-September 1993 at five sites with drainage areas ranging from 366 to 5,130 hectares. Precipitation, flow discharge, and concentration, loads, and yields of nitrate as nitrogen, atrazine, and metolachlor were analyzed to relate the transport of agricultural chemicals to major water-flow processes and to examine and transport differences among three subwatersheds. Antecedent conditions and basin-characteristic differences had significant effects on the flow response from the subwatersheds. Monthly streamflow-to- precipitation ratios were greater than 1.0, as a result of snowmelt, and negative when streamflow was lost to the ground-water system in the downstream subwatershed. Dry antecedent conditions resulted in ratios less than 0.3 (July 1992), whereas wet antecedent conditions resulted in ratios from 0.7 to almost 1.0 (July 1993) during months with similar large rainfall amounts. Most of the streamflow from the upland subwatersheds came from tileflow. Surface flow (surface runoff, interflow, and return flow0 was highly variable and intermittent, usually lasting for only a few days after a storm, although it could be the dominant source of flow when stormflow was large. Tileflow was less variable and much more persistent, ceasing only after prolonged dry periods. Large quantities of nitrate as nitrogen were transported in Walnut Creek, with concen- trations often greater than the Maximum Contaminant Level of 10 milligrams per liter established by the U.S. Environmental Protection Agency for finished drinking water. In the upland subwatersheds, ground-water flow from the tiles appears to have been the primary means of transport to the streams. Concentrations in tileflow and streamflow generally were 4 to 16 milligrams per liter, with the lower concen- trations often the result of dilution by surface runoff. Loss ratios, chemical yields expressed as a percentage of average application rates of nitrate as nitrogen for October 1992-September 1993, were about 10 percent for surface flow and more than 100 percent for tileflow from the 366-hectare basin and were more than 200 percent for streamflow from the downstream subwatershed. Concentrations of atrazine and metolachlor in streamflow, typically, were less than the Maximum Contaminant Level of 3.0 micrograms per liter, but were as high as 59 and 80 micrograms per liter, respectively, during stormflow. Concentrations as high as 170 micrograms per liter occurred in tileflow, but these were related to surface flow through surface inlets. The transport of herbicides was extremely variable, with most of the loads occurring during stormflow. Atrazine appeared more susceptable to transport losses to streamflow than did metolachlor. Loss ratios for streamflow from the subwatersheds for April- September periods were 0.3 to 20 percent for atrazine and 0.1 to 2.9 percent for metolachlor. Chemical loss ratios indicated differences in the transport characteristics of the three subwatersheds. The downstream subwatershed, which has steeper terrain, a more-developed natural drainage system, and fewer tiles than the two upland subwatersheds, had the largest loss rates for all three chemicals--206 percent for nitrate as nitrogen (October 1992-September 1993) and 20 percent for atrazine and 2.9 percent for metolachlor (April-September 1993). For May-July 1993, when most of the herbicides were transported, the downstream subwatershed also had the largest cumulative unit discharge and the largest streamflow-to-precipitation ra

Water-Resources Investigations Report↗

Estimated natural ground-water recharge, discharge, and budget for the Dixie Valley area, west-central Nevada

The Dixie Valley area includes seven valleys in west-central Nevada (Dixie, Fairview, Stingaree, Cowkick, Eastgate, Pleasant, and Jersey Valleys; total, 2,380 square miles). Dixie Valley receives surface-water and ground-water flow from Stingaree, Cowkick, Eastgate, Pleasant, and Jersey Valleys and subsurface flow from Fairview Valley, which is a topographically closed basin. The relation between precipitation and altitude was re-evaluated for the Dixie Valley area using new data, and empirical estimates of recharge were revised accordingly. The revised estimate of total recharge is 23,000 acre-feet per Re-evaluation of ground-water discharge focused on Dixie Valley as the largest basin in the study area. Phreatophytic vegetation was mapped and partitioned into nine zones on the basis of species composition and foliage density. For woody phreatophytes, annual evapotranspiration rates of 0.7 cubic feet of water per cubic foot of foliage for greasewood and 1.1 cubic feet of water per cubic foot of foliage for rabbitbrush were adapted from lysimeter studies near Winnemucca, Nevada. These rates were multiplied by the foliage density of the respective phreatophytes in each zone to estimate a specific rate for that zone. Rates for salt-grass (0.5 to 0.8 foot per year) and the playa surface (0.1 to 0.3 foot per year) were based on a range of rates. used in other recent studies in western and central Nevada. These rates were multiplied by the areas of the zones to produce estimates of the annual volume of ground water discharged. The discharge estimated for Dixie Valley is between 17,000 and 28,000 acre-feet per year. The revised discharge estimate for the entire Dixie Valley area is between 20,000 and 31,000 acre-feet per year. The revised ground-water budget for the entire Dixie Valley study area has a total recharge of about 23,000 acre-feet per year. This is within the range of estimates of natural discharge--from 20,000 to 31,000 acre-feet per year. For Dixie Valley alone, the total recharge of about 8,900 acre-feet per year and the estimated subsurface inflow from tributary areas of about 11,000 acre-feet per year produce an estimated total inflow of about 20,000 acre-feet per year. This compares with the discharge estimate of 17,000 to 28,000 acre-feet per year.

Water-Resources Investigations Report↗

Geochemical processes and the effects of natural organic solutes on the solubility of selenium in coal-mine backfill samples from the Powder River basin, Wyoming

Geochemical processes and the effects of natural organic solutes on the solubility of selenium in coal-mine backfill aquifers were investigated. Backfill and ground-water samples were collected at coal mines in the Powder River Basin, Wyoming. Backfill was generally dominated by aluminum (14,400 to 49,000 mg/kg (milligrams per kilogram)), iron (3,330 to 23,200 mg/kg), and potassium (7,950 to 18,000 mg/kg). Backfill saturated-paste selenium concentrations ranged from 1 to 156 mg/kg (microsiemens per kilogram). Ground-water total selenium concentrations ranged from 3 to 125 mg/L. Dissolved organic carbon in all ground-water samples was dominated by hydrophobic and hydrophilic acids (38 to 84 percent). Selenite sorption/desorption experiments were conducted using background solutions of distilled-deionized water, 0.1 molar calcium chloride, and isolated hydrophobic and hydrophilic acids. Selenite sorption was larger when 0.1 molar calcium chloride was used. The addition of hydrophilic acid decreased selenite sorption more than the addition of hydrophobic acids. Geochemical modelling was used to predict the solid phases controlling dissolved selenium concentrations and to evaluate the effects of dissolved organic carbon on selenium solubility. Results suggested that 55 to 90 percent of selenium in backfill precipitation/dissolution extracts was dominated by magnesium selenate ion pairs. Dissolved organic carbon had little effect on selenium speciation. A redox chamber was constructed to control Eh and pH in water and backfill-core sample suspensions. The response of selenite and selenate in water samples to redox conditions did not follow thermodynamic predictions. Reduction of selenate in water samples did not occur at any of the redox levels tested.

Water-Resources Investigations Report↗

Reconnaissance of surface-water quality in the North Platte Natural Resources District, western Nebraska, 1993

In 1993, the U.S. Geological Survey and the North Platte Natural Resources District began a 3-year study to determine the geohydrology and water quality of the North Platte River alluvial aquifer near Oshkosh, Garden County, Nebraska. The objectives of the study were to determine the geohydrologic properties of the North Platte River alluvial aquifer, to establish a well network for long- term monitoring of concentrations of agricultural chemicals including nitrate and herbicides, and to establish baseline concentrations of major ions in the ground water. To meet these objectives, monitor wells were installed at 11 sites near Oshkosh. The geohydrologic properties of the aquifer were estimated from water-level measurements at selected irrigation wells located in the study area and short- term constant-discharge aquifer tests at two monitor wells. Water samples were collected bimonthly and analyzed for specific conductance, pH, water temperature, dissolved oxygen, and nutrients including dissolved nitrate. Samples were collected semiannually for analysis of major ions, and annually for triazine and acetamide herbicides. Evaluation of the aquifer-test data indicates the hydraulic conductivities of the North Platte River alluvial aquifer range between 169 and 184 feet per day and transmissivities ranged from 12,700 to 26,700 feet-squared per day. The average specific yield for the alluvial aquifer, based on the two aquifer tests, was 0.2. Additional hydrologic data for the alluvial aquifer include a horizontal gradient of about 0.002 foot per foot and estimated ground- water flow velocities of about 0.1 to 1.8 feet per day. Evaluation of the water-quality data indicates that nitrate concentrations exceed the U.S. Environmental Protection Agency's (USEPA) Maximum Contamination Level of 10 milligrams per liter for drinking water in areas to the east and west of Oshkosh. In these areas, nitrate concentrations generally are continuing to rise. West of Oshkosh the highest concentrations are now exceeding 50 milligrams per liter. With the exception of one sample, nitrate concentrations exceeding the Maximum Contamination Level were not detected in three wells used to monitor the ground water flowing into and out of the study area, nor in a monitor well located near a municipal well. Results of the study also indicate that an influx of water from Lost Creek Valley, north of the study area, may be mixing with ground water near Oshkosh and diluting concentrations of nitrate.

Water-Resources Investigations Report↗