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Guidelines and standard procedures for continuous water-quality monitors: Station operation, record computation, and data reporting

The U.S. Geological Survey uses continuous water-quality monitors to assess the quality of the Nation's surface water. A common monitoring-system configuration for water-quality data collection is the four-parameter monitoring system, which collects temperature, specific conductance, dissolved oxygen, and pH data. Such systems also can be configured to measure other properties, such as turbidity or fluorescence. Data from sensors can be used in conjunction with chemical analyses of samples to estimate chemical loads. The sensors that are used to measure water-quality field parameters require careful field observation, cleaning, and calibration procedures, as well as thorough procedures for the computation and publication of final records. This report provides guidelines for site- and monitor-selection considerations; sensor inspection and calibration methods; field procedures; data evaluation, correction, and computation; and record-review and data-reporting processes, which supersede the guidelines presented previously in U.S. Geological Survey Water-Resources Investigations Report WRIR 00-4252. These procedures have evolved over the past three decades, and the process continues to evolve with newer technologies.

Techniques and Methods

Water resources data for Florida, water year 1973; Part 2. Water quality records

Water-resources investigations of the U. S. Geological Survey include the collection of water quality data on the chemical and physical characteristics of surface- and ground-water supplies of the Nation. These data for the 1973 water year for the quality of surface waters in Florida are presented in this report. The data were collected by the Water Resources Division of the U. S. Geological Survey under the direction of Clyde S. Conover, District Chief, Florida District.

Florida

Synoptic survey of septic indicators in streams and springs at Monte Sano Mountain, Madison County, Alabama, January 29-31, 1998

The U.S. Geological Survey conducted a synoptic investigation of fecal bacterial pollution in headwater streams and springs on Monte Sano Mountain. A total of 18 sites were sampled over a 3 day period in late January 1998. Fifteen of the sites were located hydrologically downgradient from residential areas on top of Monte Sano Mountain. Three additional sites were selected as background sites in unpopulated areas on Huntsville Mountain, south of Monte Sano Mountain. Sampling was conducted during a period of high baseflow after a recent storm when no surface runoff was present. Any contaminants identified in the streams and springs were likely derived from ground-water discharge because overland flow was not evident. Four of the five sites in the Pottsville-Pennington unit (uppermost) with the highest concentration of residential land use had Escherichia coli (E. coli) concentrations that were more than 25 times the background level. In contrast, with the exception of one site, E. coli concentrations in the Bangor-Monteagle unit (middle) and Tuscumbia unit (lowermost) were at or near background levels. Caffeine was also detected in the Pottsville-Pennington unit at a site with one of the highest densities of E. coli. Elevated levels of nitrate and chloride were also identified at sites in the Pottsville-Pennington unit. The results of this synoptic sampling event identified elevated concentrations of fecal bacteria in the Pottsville-Pennington unit at the top of the mountain. These elevated bacterial concentrations occurred in conjunction with caffeine detection and elevated levels of nitrate and chloride. This indicates that there is a potential water-quality problem related to discharge from the shallow ground-water system. These sites are located in close proximity to residential development, indicating that the most probable source of the elevated fecal bacterial concentrations was septic tank effluent.

Alabama

Ground water in northeastern Louisville, Kentucky with reference to induced infiltration

In cooperation with the city of Louisville, Ky., the U. S. Geological Survey made a detailed investigation during the period February 1945 to March 1947 of the ground-water resources of a 3-square-mile area along the Ohio River north-east of Louisville. Test drilling shows that the principal aquifer consists of about 80 feet of glacial-outwash sands and gravels lying in an old river channel which was cut into rocks of Ordovician, Silurian, and Devonian age. The total ground-water storage in the area is estimated as 7 billion gallons. The ground-water levels are affected by changes in river elevation, by rainfall, and by the effects of pumping in the downtown part of Louisville 3 miles to the southwest. In the northeastern part of the area the flow of ground water, as defined by contour maps, is toward the river, and in the southwestern part of the area it is from the river toward the downtown area of overpumping. Ground water in the area has an average temperature of 56° F. The water, which is moderately hard, is suitable for domestic and industrial uses. Analysis of a pumping test made during the investigation proves that infiltration supplies can be developed. Studies to determine the degree of connection between the river and aquifer were made on the basis of chemical analyses, sections showing temperature distribution in the aquifer during the pumping test, shapes of water-level profiles in the test area, and shapes of time-drawdown curves for a number of observation wells. Quantitative studies to evaluate the hydrologic constants of the aquifer were made by both graphical and mathematical methods. The transmissibility was determined as 121,000 gpd/ft in the test area; the distance to the line source, 400 feet; and the coefficient of storage, 0.0003. A comparison of river-level fluctuations and water-level fluctuations in observation wells shows that conditions along the 6.4-mile reach of river are not greatly different from those at the site of the pumping test. It is estimated that under adverse temperature and river-stage conditions infiltration supplies could be developed to the extent of 280 million gpd in the entire 6.4-mile reach investigated; at average river-water temperature (59° F) about 400 million gpd could be developed. Diagrams were drawn showing the estimated yield of wells of different radii, at various distances from the river, and at various spacings. In making the computations allowance was made for screen losses, dewatering of the aquifer, partial penetration of wells, location wells, eccentricity of large wells, and interference among wells.

Kentucky

Olympic Fisher Reintroduction Project: 2010 Progress Report

The 2010 progress report is a summary of the reintroduction, monitoring, and research efforts undertaken during the third year of the Olympic fisher reintroduction project. Jeffrey C. Lewis of Washington Department of Fish and Wildlife, Patti J. Happe of Olympic National Park, and Kurt J. Jenkins of U. S. Geological Survey are the principal investigators of the monitoring and research program associated with the reintroduction. David J. Manson of Olympic National Park is the lead biological technician.

Washington

Olympic Fisher Reintroduction Project- 2009 Progress Report

The 2009 progress report is a summary of the reintroduction, monitoring, and research efforts undertaken during the first two years of the Olympic fisher reintroduction project. Jeffrey C. Lewis of Washington Department of Fish and Wildlife, Patti J. Happe of Olympic National Park, and Kurt J. Jenkins of U. S. Geological Survey are the principal investigators of the monitoring and research program associated with the reintroduction. David J. Manson of Olympic National Park is the lead biological

Washington

Late Quaternary stratigraphy and depositional history of the Long Island Sound basin

The stratigraphy of Late Quaternary geologic units beneath Long Island Sound (LIS) is interpreted from 3,500 km of high-resolution, seismic-reflection profiles supplemented by vibracore data. Knowledge gained from onshore regional geologic studies and previous offshore investigations is also incorporated in these interpretations. Glacial deposits overlie and nearly fill an Inner Lowland which is floored by crystalline rocks in the north and bounded to the south by an irregular, north-facing cuesta scarp in Cretaceous Coastal-Plain strata. The thick glacial section consists largely of sediment that was deposited in glacial Lake Connecticut during the retreat of the last (late Wisconsin) ice sheet. Ice-marginal lacustrine fan deposits and submerged extensions of the southeastern Connecticut recessional moraines mark positions of the ice margin during systematic northward retreat. When the ice margin stood at positions just north of the present shoreline of Connecticut (17.6-16.5 ka), glacial Lake Connecticut was slightly larger than Long Island Sound is today. Ice-marginal deltas and near-ice marginal fluviodeltaic deposits occur along coastal Connecticut. Delta-building was diachronous; progressively younger deltas record northwesterly retreat of the ice margin and lowering lake levels. Distally from the deltas, varied lake-clays (up to 150 m thick) drape the underlying topography. The lake spillway cut across the Harbor Hill-Roanoke Point-Fishers Island-Charlestown end moraine at its lowest point just west of Fishers Island (The Race). Lake levels fell as the spillway notch was erosionally deepened, and gradually the lakebed became subaerially exposed. A largely preserved channel system cuts the lake-deposit surface; fluvial channel-fill sediments are overlain by estuarine sediments in the channel system. Perhaps as early as 15 ka, but no later than 13 ka, the sea entered the Basin through the channel at The Race and quickly transgressed westward via the lakebed channel system. As the sea rose further and spread throughout the Basin, a wave-cut surface was formed. Extensive marine deltaic deposits, up to 40 m thick, overlie the wave-cut marine unconformity in the east-central part of the Basin. These sediments were derived from erosion of the drained bed of Lake Hitchcock, in the Connecticut valley to the north, and were deposited in a -40-m relative sea at about 12.4 ka. Where quiet waters prevail, marine mud generally less than 15 m thick blankets the older deposits of the Basin. Elsewhere, especially in eastern LIS, tidal currents are actively reworking and transporting glacial and postglacial deposits.

Connecticut, New York

Hydrogeologic characterization of Area B, Fort Detrick, Maryland

Groundwater in the karst groundwater system at Area B of Fort Detrick in Frederick County, Maryland, is contaminated with chlorinated solvents from the past disposal of laboratory wastes. In cooperation with U.S. Army Environmental Command and U.S. Army Garrison Fort Detrick, the U.S. Geological Survey performed a 3-year study to refine the conceptual model of groundwater flow in and around Area B of Fort Detrick at the site- to regional-scale. The investigation was designed to review the geologic setting, assess the temporal variability of the hydrologic system, evaluate the potential for interbasin groundwater flow, determine the degree of vertical connectivity of the aquifer, characterize the sources and timing of groundwater recharge, and identify if dyes from previous tracer tests continue to drain from the aquifer. This study established a continuous hydrologic monitoring network of 12 water level gages, 2 streamgages, a precipitation gage, and in situ fluorometric monitoring. A water budget analysis was performed using hydrologic monitoring data and a soil-water balance model constructed for the study. In this study each individual water budget term is calculated using available data or through modeling, and a water budget residual term is calculated. If the water budget residual term is small relative to the uncertainty of the underlying data, then an additional import or export of water (in other words, interbasin transfer) is not needed to fully describe the hydrologic system. Groundwater and spring samples from 20 locations were collected in a 2019 synoptic geochemical sampling event and analyzed for a suite of analytes that included groundwater age tracer constituents. The karst groundwater system was found to be highly responsive to hydrologic events, with strong water level and stream base flow responses to individual storm events and a historic wet period in 2017 and 2018. The water budget analysis included historic flooding in May 2018, though more typical hydrologic patterns were observed in 2019 and 2020. During most evaluated intervals, the water budget residual was less than the estimated uncertainty on the residual for the two Carroll Creek watersheds, which suggested no substantial net interbasin flow occurs from these watersheds. The watershed difference area, a region that includes Area B, had a significant negative water budget residual, which may be the result of a net interbasin import of groundwater or the result of focused groundwater recharge not simulated by the soil-water balance model. Geochemical analysis and groundwater age dating reveals shallow groundwater (approximately less than [<] 150 feet deep) appears to be relatively young (approximately <30 years) and to be recharged in the vicinity of Area B. In the deep groundwater sampled in this study (approximately greater than [>] 150 feet deep), older groundwater from a differing recharge source, based on stable isotopes and noble gas analyses, is observed and interpreted to represent less direct connectivity to the surface and increased proportions of water recharged to the north and (or) west of Area B. A clustering analysis to reveal groupings within the suite of geochemical data was used to define seven groups. The groupings generally show that wells in similar depths and lateral aquifer positions generally cluster together, with some exceptions. Although limited by suspended sediments, the in situ fluorometric monitoring at springs did not detect any dye leaving the system above the limit of detection for the method. Dye was only detected above the limit of detection in one well, which was used as an injection well during a previous dye tracer test. The results of this study support and refine the conceptual site model of groundwater hydrology at Area B. The geologic and geophysical log review in this study agrees with prior assessments of physical controls on groundwater flow. A literature review of mid-Atlantic karst studies identified similar controls reported in these environments. The additional characterization of hydrologic responsiveness in this study suggests that hydrologic conditions and events are important considerations when interpreting potentiometric surfaces and contaminant trends over time and highlights the importance of continuous hydrologic monitoring. There is evidence to suggest that either intense focused groundwater recharge occurs in the vicinity of Area B or net along-valley groundwater interbasin flow from the upper study watershed enters the lower watershed and discharges to Carroll Creek. Geochemical analyses also suggest that water recharged from Catoctin Mountain and the elevated areas to the north and (or) west of the site may be present in the older and deeper Area B groundwater.

Maryland

Ground Water Atlas of the United States: Introduction and national summary

The Ground Water Atlas of the United States provides a summary of the most important information available for each principal aquifer, or rock unit that will yield usable quantities of water to wells, throughout the 50 States, Puerto Rico, and the U.S. Virgin Islands. The Atlas is an outgrowth of the Regional Aquifer-System Analysis (RASA) program of the U.S. Geological Survey (USGS), a program that investigated 24 of the most important aquifers and aquifer systems of the Nation and one in the Caribbean Islands (fig. 1). The objectives of the RASA program were to define the geologic and hydrologic frameworks of each aquifer system, to assess the geochemistry of the water in the system, to characterize the ground-water flow system, and to describe the effects of development on the flow system. Although the RASA studies did not cover the entire Nation, they compiled much of the data needed to make the National assessments of ground-water resources presented in the Ground Water Atlas of the United States. The Atlas, however, describes the location, extent, and geologic and hydrologic characteristics of all the important aquifers in the United States, including those not studied by the RASA program. The Atlas is written so that it can be understood by readers who are not hydrologists. Simple language is used to explain technical terms. The principles that control the presence, movement, and chemical quality of ground water in different climatic, topographic, and geologic settings are clearly illustrated. The Atlas is, therefore, useful as a teaching tool for introductory courses in hydrology or hydrogeology at the college level and as an overview of ground-water conditions for consultants who need information about an individual aquifer. It also serves as an introduction to regional and National ground-water resources for lawmakers, personnel of local, State, or Federal agencies, or anyone who needs to understand ground-water occurrence, movement, and quality. The purpose of the Ground Water Atlas of the United States is to summarize, in one publication with a common format, the most important ground-water information that has been collected over many years by the USGS, other Federal agencies, and State and local water management agencies. The purpose of this introductory chapter is to describe the content of the Atlas; to discuss the characteristics, use, and limitations of the maps and other types of illustrations used in the different chapters of the book; to summarize the locations of the principal aquifers on a Nationwide map; and to give an example of an aquifer in each principal hydrogeologic setting.

Hydrologic Atlas

U. S. Geological Survey Federal-State Cooperative Water-Resources Program Fiscal Year 1993

The Federal-State Cooperative Program is a part- nership between the U.S. Geological Survey and State and local agencies. It provides a balanced approach to the study and resolution of water- related problems and to acquiring hydrologic data. The principal program objectives are to: (1) collect, on a systematic basis, data needed for the continuing determination and evaluation of the quantity, quality, and use of the Nation's water resources, and (2) appraise the availa- bility and the physical, chemical, and biological characteristics of surface and ground water through analytical and interpretive investi- gations. During fiscal year 1993, hydrologic data collection, interpretive investigations, and research were conducted by Geological Survey personnel in offices in every State, Puerto Rico, and in several territories in cooperation with about 1,100 local, State, and regional agencies. In fiscal year 1993, Federal funding of $63.5 million was matched by cooperating agencies, which also provided almost $23 million unmatched for a total program of about $150 million. This amounted to nearly 40 percent of the total funds for Geological Survey water- resources activities. This report presents examples of current (1993) investigations. It also provides updated information on Cooperative Program investigations related to agricultural activities.

Open-File Report

Water levels in bedrock aquifers in South Dakota

This report on water levels in bedrock aquifers in South Dakota is the result of a continuing investigation begun in 1959 by the U.S. Geological Survey in cooperation with the South Dakota Department of Water and Natural Resources. The purpose of the investigation is to collect data on the artesian water supply in the bedrock aquifers and to present these data in data reports that will aid in planning the use and conservation of water from these aquifers in South Dakota. The locations of wells were data have been collected are included.

South Dakota

Applied geochemistry, geology and mineralogy of the northernmost Carlin trend, Nevada

Investigations in the northernmost Carlin trend were undertaken to advance understanding of the geochemical signatures and genesis of precious metal deposits in the trend . Two fundamental geologic relationships near the trend significantly affect regional geochemical distributions: a remarkably intact lower Paleozoic stratigraphic sequence of siliceous rocks in the upper plate of the middle Paleozoic Roberts Mountains thrust, and the widespread repetition of rocks high in the upper plate during late Paleozoic thrusting that thickens the cover above mineralized rock in the lower plate. A compilation of previously published chemical analyses of 440 stream sediment samples and 115 rocks from two 7 1/2-minute quadrangles, as well as new chemical analyses of approximately 1,000 drill core samples in a 1,514 m (4,970 ft) hole through the Rodeo Creek deposit were used to construct three-dimensional element distribution models that highlight metal zonation in the mineralized systems. The Rodeo Creek deposit comprises deep Ag base-metal ± Au-mineralized rock below the Roberts Mountains thrust and contains an unusually high Ag/Au ratio greater than 30. Stacked geochemical halos related to the deposit are confined to the lower plate of the Roberts Mountains thrust and include two horizons of Hg, Cu, and Zn anomalies-as much as 180 m above the deposit-that mostly result from mercurian sphalerite. Extremely subtle indications of mineralization in the upper plate of the Roberts Mountains thrust above the deposit include arsenopyrite overgrowths on small pyrite crystals in 50- to 75-μm-wide clay-carbonate veinlets that lack alteration halos, arsenical rims on small disseminated crystal of recrystallized diagenetic pyrite, and partial replacement of diagenetic pyrite by tennantite. Some of these minerals contain anomalously high Au. However, these As-(Au)-bearing rocks most likely represent another locus of largely untested mineralized rock rather than distal halos related to either the Rodeo Creek or the nearby Dee and Storm gold deposits. Application of micromineralogic techniques helped to identify mineral assemblages that are specific to mineralization and provided an empirical foundation for interpretations of geochemical halos in the Carlin trend . District-scale geochemical patterns of several elements in stream sediments and surface rocks coincide with the northernmost Carlin trend and can be used to explore for Carlin -type deposits. Concentrations of elevated As and Sb in stream sediments (as much as 54 ppm As) have northwest-elongate lobate patterns that clearly outline the trend across a width of approximately 4 km. Arsenic contents of exposed rocks (as much as 90 ppm As) strongly correlate with As contents of derivative stream sediments, and rock contents of Sb show a somewhat lesser but nonetheless strong and similar correspondence. Factor analysis of stream-sediment data shows that those factor scores that are correlated with As, Sb, Au, and Pb also are high along the trend and suggest that mineralized rocks may be present. Although As was not detected by scanning electron microscope-energy dispersive spectrometer (SEM-EDS) studies in heavy mineral concentrates of high-As stream sediments in the Carlin trend , X-ray absorption near-edge spectra (XANES) of selected light fractions of stream sediment samples indicate that Al-bearing phases, such as gibbsite, amorphous Al oxyhydroxides, or aluminosilicate clay minerals host most of the As(V). The best fit, visually and in terms of the lowest residual, was obtained by a model compound of As(V) sorbed to gibbsite. Thus, most As in stream sediments derived from altered rock within the Carlin trend apparently is contained in light fractions. The geochemical character of young, unconsolidated, postmineral deposits that cover mineralized rocks on the Carlin trend partly results from mineralized sources along the trend . Concentration of As in the Miocene Carlin Formation shows an exceptionally well developed progressive increase to about 30 ppm As as altered rock surrounding the trend is approached. Mineralized and/or altered rock fragments probably have been shed directly into the sedimentary basin of the Carlin Formation, and migration of As, now fixed as As(V), also may have occurred in the supergene environment after material was recycled out of the Carlin Formation and into present-day gulleys.

Nevada

Contributions to economic geology (short papers and preliminary reports), 1915: Part I. - metals and nonmetals except fuels

This volume is the thirteenth of a series that includes Bulletins 213, 225, 260, 285, 315, 340, 380, 430, 470, 530, 540, and 580, "Contributions to economic geology" for 1902, 1903, 1904, 1905, 1906 (Pt. I), 1907 (Pt. I), 1908 (Pt. I), 1909 (Pt. I), 1910 (P t. I), 1911 (Pt. I) , 1912 (Pt. I), and 1913 (Pt. I), respectively . These bulletins are prepared primarily to insure prompt publication of the economic results of investigations made by the United States Geological Survey. Beginning with the present volume the year included in the title will be the year of publication 1 instead of the year in which the field work reported was done. This volume is therefore dated 1915, and there will be no volume entitled "Contributions to economic geology, 1914." As the subtitle indicates, the papers included are of two classes -(1) short papers giving comparatively detailed description of occurrences that have economic interest but are not of sufficient importance to warrant a more extended description; (2) preliminary reports on economic investigations the results of which are to be published later in more detailed form. These papers are such only as have a direct economic bearing, all topic of purely scientific interest being excluded. Each paper has been issued as an advance chapter as soon as it was ready. Brief abstracts of the publications of the year are given in the annual report of the Director. The complete list of Survey publications affords, by means of finding list of subjects and of authors, further aid in ascertaining the extent of the Survey's work in economic geology. Since 1905 the annual economic bulletin has been printed in two parts, the second part comprising paper on mineral fuels. These volumes for 1906, 1907, 190 , 1909, 1910, 1911, 1912, and 1913 are Bulletins 316, 341, 381, 431, 471, 531, 541, and 581. Bulletin 621 forms Part II of the "Contributions" for 1915. The reports on work in Alaska have been printed in a separate series since 1904, the volume so far issued being Bulletins 259, 284, 314, 345, 379, 442, 480, 520, 542, 592, and 622.

Bulletin

Low-flow frequency and flow-duration characteristics of selected streams in Alabama through March 2014

Low-flow statistics are needed by water-resource engineers, planners, and managers to protect and manage the water resources of Alabama. The accuracy of these statistics is influenced by such factors as length of record and specific hydrologic conditions measured in those records. As such, it is generally recommended that flow statistics be updated about every 10 years to provide improved and representative low-flow characteristics. The previous investigation of low-flow characteristics for Alabama included data through September 1990. Since that time, Alabama has experienced several historic droughts highlighting the need to update the low-flow characteristics at U.S. Geological Survey streamgaging stations. Consequently, this investigation was undertaken in cooperation with a number of State and local agencies to update low-flow frequency and flow-duration statistics at 210 continuous-record streamgaging stations in Alabama and 67 stations from basins that are shared with surrounding States. The flow characteristics were computed on the basis of available data through March 2014.

Alabama

Evaluation of electrical and electromagnetic geophysical techniques to inspect earthen dam and levee structures in Arkansas

Within the state of Arkansas there is an increasing number of aging dams and levees that have little to no documentation concerning their construction or composition. Surface geophysical surveys offer a non-intrusive method for investigating these structures: To describe their lithologic makeup, to evaluate the materials that they were constructed upon, and to identify potential flow paths through them. Techniques such as electrical resistivity tomography, seismic refraction, and electromagnetic induction have all been used to image dams and levees and require additional information from geologic outcrops, geotechnical borings, or drill cores in order to make informed geologic interpretations of the geophysical models. These geologic models then allow the owners of these structures to make more informed decisions about their operation and maintenance. Between 2011 and 2018, the U.S. Geological Survey conducted geophysical and geotechnical investigations of three earthen structures within the state of Arkansas. Electrical and electromagnetic geophysical data were used to develop lithologic models of these structures and the underlying geology. Self-potential surveys were utilized to detect the movement of water through these structures indicating possible seepage pathways. Geotechnical methods such as electric and hydraulic direct-push well logs and cores acted as both a control on the geophysical interpretations and a confirmation of anomalies. This integrated approach detected the lack of an impermeable core within a levee, imaged a change in lithology of the bedrock forming the seal beneath a gravity dam, and identified a potential seepage feature within the core of an earthen dam. These results further support that this method of extending known lithologic features via surface and borehole geophysics is a useful approach for characterizing earthen water control structures.

Arkansas

Floods in New York, 1971

This report, for the calendar year 1971, was prepared at the request of the New York State Department of Transportation under provisions of an agreement between the New York State Department of Environmental Conservation and the U.S. Geological Survey fore a cooperative statewide program investigate the water resources of the State. The report was complied in the New York, Water Resources Division, U.S. Geological Survey, under the direction of Robert J. Dingman, District Chief. The information was obtained from newspaper clippings, publications of the National Weather Service, and the Environmental Data Service, and the Environmental Data Service of the National Oceanic and Atmospheric Administration ("Climatological Data" and "Storm Data"), and records of the U.S. Geological Survey.

New York

Hydrogeology and water quality of the Leetown area, West Virginia

The U.S. Geological Survey’s Leetown Science Center and the co-located U.S. Department of Agriculture’s National Center for Cool and Cold Water Aquaculture both depend on large volumes of cold clean ground water to support research operations at their facilities. Currently, ground-water demands are provided by three springs and two standby production wells used to augment supplies during periods of low spring flow. Future expansion of research operations at the Leetown Science Center is dependent on assessing the availability and quality of water to the facilities and in locating prospective sites for additional wells to augment existing water supplies. The hydrogeology of the Leetown area, West Virginia, is a structurally complex karst aquifer. Although the aquifer is a karst system, it is not typical of most highly cavernous karst systems, but is dominated by broad areas of fractured rock drained by a relatively small number of solution conduits. Characterization of the aquifer by use of fluorometric tracer tests, a common approach in most karst terranes, therefore only partly defines the hydrogeologic setting of the area. In order to fully assess the hydrogeology and water quality in the vicinity of Leetown, a multi-disciplinary approach that included both fractured rock and karst research components was needed. The U.S. Geological Survey developed this multi-disciplinary research effort to include geologic, hydrologic, geophysical, geographic, water-quality, and microbiological investigations in order to fully characterize the hydrogeology and water quality of the Leetown area, West Virginia. Detailed geologic and karst mapping provided the framework on which hydrologic investigations were based. Fracture trace and lineament analysis helped locate potential water-bearing fractures and guided installation of monitoring wells. Monitoring wells were drilled for borehole geophysical surveys, water-quality sampling, water-level measurements, and aquifer tests to characterize the quality of water and the hydraulic properties of the aquifer. Surface geophysical surveys provided a 3-dimensional view of bedrock resistivity in order to assess geologic and lithologic controls on ground-water flow. Borehole geophysical surveys were conducted in monitoring wells to assess the storage and movement of water in subsurface fractures. Numerous single-well, multi-well, and straddle packer aquifer tests and step-drawdown tests were conducted to define the hydraulic properties of the aquifer and to assess the role of bedrock fractures and solution conduits in the flow of ground water. Water samples collected from wells and springs were analyzed to assess the current quality of ground water and provide a baseline for future assessment. Microbiological sampling of wells for indicator bacteria and human and animal DNA provided an analysis of agricultural and suburban development impacts on ground-water quality. Light detection and ranging (LiDAR) data were analyzed to develop digital elevation models (DEMs) for assessing sinkhole distribution, to provide elevation data for development of a ground-water flow model, and to assess the distribution of major fractures and faults in the Leetown area. The flow of ground water in the study area is controlled by lithology and geologic structure. Bedrock, especially low permeability units such as the shale Martinsburg Formation and the Conococheague Limestone, act as barriers to water flowing down gradient and across bedding. This retardation of cross-strike flow is especially pronounced in the Leetown area, where bedding typically dips at steep angles. Highly permeable fault and fracture zones that disrupt the rocks in cross-strike directions provide avenues through which ground water can flow laterally across or through strata of low primary permeability. Significant strike parallel thrust faults and cross-strike faults typically coincide with larger solution conduits and act as drains for the more pervasive network of interconnected diffuse fractures. Results of borehole geophysical surveys indicate that although numerous fractures may intersect a borehole, only one or two of the fractures typically transmit most of the water to a well. The diffuse-flow dominated network of fractures that provides the majority of storage occupies only a small proportion of the total aquifer volume but constitutes the majority of porosity within the aquifer. Solution conduits, while occupying a relatively small volume of the overall aquifer, are especially important because they serve as primary drains for the ground-water flow system. Surface resistivity maps and cross-sectionsshow anomalous areas of low resistivities coincident with the prevailing geologic strike at N. 20º E., with major cross-strike faults, and with major springs in the region. Transmissivity derived from straddle packer tests was highly variable, and ranged over three orders of magnitude (1.8 x 10 -6 to 5.9 x 10 -3 ft 2 /d) in diffuse-flow fractures. A similar large variability in transmissivity was documented by single- and multi-well aquifer tests conducted in conduit-flow dominated portions of the aquifer (2.0 x 10 3 to 1.4 x 10 4 ft 2 /d) in lowland areas immediately adjacent to the Leetown Science Center. A stream-gaging station installed on Hopewell Run near the point where the stream exits the Leetown watershed indicates average daily streamflow for the Hopewell Run of approximately 11.2 ft 3 /s, and ranged from a minimum of 1.80 ft 3 /s on September 28, 2005, to a maximum of 73.0 ft 3 /s on December 11, 2003. Base-flow (ground-water) discharge surveys identified numerous small seeps adjacent to streams in the area. Hydrographs of the stage of Balch Spring show rapid response to individual storms. Strong correlation of the flow of Hopewell Run and Balch Spring indicates the nearby losing stream reach is partly responsible for higher fluctuations in the stage of Balch Spring. A water budget for the study period (2003-2005), based on measured precipitation and hydrograph analyses, is expressed as Precipitation (38.60 in/yr) = Surface Runoff (1.36 in/yr) + Ground-Water Discharge (17.73 in/yr) + Evapotranspiration (24.23 in/yr) – Change in storage (4.72 in/yr). Flow of ground water through the epikarst, a shallow zone of intensely weathered rock and regolith, can be rapid (on the order of days or weeks) as flow is concentrated in solution conduits. Flow within the intermediate and deeper zones is typically much slower. Eight dye-tracer tests conducted in the Leetown area found ground-water flow patterns to be divergent, with velocities ranging from about 12.5 to 610 ft/day and a median velocity of 50 ft/day. Estimates of ground-water age in carbonate rocks in the region are on the order of 15 years in the shallower portions of the aquifer to 50 years or older for deeper portions of the aquifer. Shallow springs can have a significant component of fairly young water (< 5 years in age). Ground-water samples collected from 16 sites (12 wells and 4 springs) in the Leetown area were analyzed for more than 340 constituents. Only turbidity, indicator bacteria, and radon were typically present in concentrations exceeding U.S. Environmental Protection Agency (USEPA) drinking-water or aquatic life standards.

West Virginia