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Geochemical analyses of ground-water ages, recharge rates, and hydraulic conductivity of the N aquifer, Black Mesa area, Arizona

The Navajo Nation and Hopi Tribe of the Black Mesa area, Arizona, depend on ground water from the N aquifer to meet most tribal and industrial needs. Increasing use of this aquifer is creating concerns about possible adverse effects of increased ground-water withdrawals on the water resources of the region. A thorough understanding of the N aquifer is necessary to assess the aquifer's response to ground-water withdrawals. This study used geochemical techniques as an independent means of improving the conceptual model of ground-water flow in the N aquifer and to estimate recharge rates and hydraulic conductivity. Ground water flows in a south-southeastward direction from the recharge area around Shonto into the confined part of the N aquifer underneath Black Mesa. Ground-water flow paths diverge in the confined part of the aquifer to the northeast and south. The N aquifer thins to extinction south of Black Mesa. This discontinuity could force ground water to diverge along paths of least resistance. Ground water discharges from the confined part of the aquifer into Laguna Creek and Moenkopi Wash and from springs southwest of Kykotsmovi and southeast of Rough Rock after a residence time of about 35,000 years or more. Recent recharge along the periphery of Black Mesa mixes with older ground water that discharges from the confined part of the aquifer and flows away from Black Mesa. Dissolved-ion concentrations, ratios of dissolved ions, dissolved-gas concentrations, tritium, carbon-13, and chlorine-36 data indicate that water in the overlying D aquifer could be leaking into the confined part of the N aquifer in the southeastern part of Black Mesa. The boundary between the leaky and nonleaky zones is defined roughly by a line from Rough Rock to Second Mesa and separates ground waters that have significantly different chemistries. The Dakota Sandstone and Entrada Formation of the D aquifer could be the sources of leakage. Adjusted radiocarbon ground-water ages and data on isotopes of oxygen and hydrogen indicate that more than 90 percent of the water in the confined part of the N aquifer is older than 10,000 years and was recharged during glacial periods. Estimates of recharge rates made on the basis of ground-water ages, aquifer thicknesses, and assumed porosities indicate that the annual average recharge rate in the northwestern part of the study area during the glacial periods was about four times the average annual rate of the past 10,000 years, and that recharge rates for the past 10,000 years are less than modern recharge rates assumed in a previous study. Estimates of horizontal hydraulic conductivity were 0.95 and 1.16 feet per day for the northeast and southwest flow paths, respectively. These values are within the range of hydraulic conductivities calculated from aquifer tests, which ranged from 0.05 to 2.1 feet per day and averaged 0.65 foot per day.

Arizona↗

Interaction between ground water and surface water in the northern Everglades and relation to water budget and mercury cycling; study methods and appendixes

The data presented in this report are products of an investigation that quantified interactions between ground water and surface water at several study sites in the northern Everglades. Goals included identifying the major geologic controls and human alterations that affect interactions between ground water and surface water, and determining how those interactions affect mercury contamination. The primary study area was the 3,815-acre Everglades Nutrient Removal (ENR), a wetland constructed in the early 1990s as a prototype Stormwater Treatment Area (STA), to determine the effectiveness in removing excess nutrients from agricultural drainage. In order to ensure that results from ENR are broadly informative, work was also conducted in Water Conservation Area-2A (WCA-2A), a 105,000-acre basin surrounded by levees. In the past 50 years, WCA-2A has experienced extensive re- engineering of water flow, alterations in the pattern of water-level fluctuations and timing of fire frequency, as well as substantial ecological changes. The most visible ecological alteration is the change in dominance over the past 30 years from a sawgrass wetland to cattail wetland in the northeastern part of WCA-2A. The drastic change in vegetation in WCA-2A resulted at least in part from inputs of excess phosphorus from agricultural drainage. Substantial data collection programs were already in progress in both ENR and WCA- 2A when the present work began. The South Florida Water Management District (SFWMD) constructed the ENR project in 1994 to determine the effectiveness of constructed wetlands for water treatment. Measurements of surface water flow and water quality were made frequently in ENR between 1994 and 1998. Fewer ground water data were collected at ENR, and almost all of it was collected from shallow wells emplaced on perimeter levees. In contrast to the short-term nature of data collection in ENR, hydrologic and chemical data were collected over a much longer period in WCA-2A (since at least the mid- 1970s), but the number of sites and data- collection frequency is much less. Very little prior ground water data were available in WCA-2A. Given the availability of prior information, the present study emphasized the collection of ground water field data, particularly in the interior wetland areas of ENR and WCA- 2A. New wells were emplaced to permit the geologic, hydraulic, and chemical sampling that was needed to characterize interactions between surface water and ground water. In particular, lithology and hydraulic properties of the Surficial aquifer were determined, ground water flow paths and velocities were delineated, hydrologic fluxes between surface water and ground water were measured, and water budgets and surface- subsurface fluxes of mercury were determined. The purpose of this report is to compile under one cover all of the data collected in this investigation. In addition, the report contains a detailed description of the study methods and information about study sites, borehole drilling, well construction, seepage meter installation, and hydraulic and geochemical chemical sampling. Data interpretations are the subject of a companion report.

Florida↗

Ground water and streamflow in the Nett Lake Indian Reservation, northern Minnesota, 1995-97

The Nett Lake Indian Reservation, about 164 square miles in area, is in northern Minnesota. About 300 people live in Nett Lake Community, about 100 people live in Palmquist Community, and a few people live in other parts of the Reservation. Water resources in the Reservation include: (1) ground water in sand and gravel aquifers and bedrock aquifers; (2) Nett Lake; (3) streams in the Nett Lake River watershed; and (4) wetlands that comprise about one-half of the area of the Reservation. Ground-water sources in the Reservation consist of sand and gravel aquifers and bedrock aquifers. Buried sand and gravel aquifers are important sources of water. Reported yields for wells completed in these aquifers are as much as 60 gallons per minute. Reported yields for wells completed in bedrock aquifers are as much as 34 gallons per minute. The Reservation is located within the Little Fork River Basin. Streams that flow into and out of Nett Lake are in the Nett Lake River watershed, a subbasin of the Little Fork River Basin. Most of the discharge into Nett Lake is from Lost River and Woodduck Creek; a small amount of discharge into Nett Lake is from several other small streams. Discharge from Nett Lake is to the Nett Lake River. Ground water in buried sand and gravel aquifers in the vicinity of three community wells and a closed landfill east of Nett Lake Community may have moved from the landfill toward the community wells. Ground water near Nett Lake locally discharged into the lake through underlying peat that ranges in thickness from 3 to 12 feet. Two Palmquist Community wells probably are not hydraulically connected to shallow ground water in the vicinity of a nearby closed landfill. The wells are located more than 2,000 feet away and are completed in a bedrock aquifer overlain by 124-154 feet of clay. The concentrations of the trace metals iron and manganese exceeded their respective U.S. Environmental Protection Agency Secondary Maximum Contaminant Level limits in water from three and six wells sampled, respectively. All but 3 of 63 VOCs (volatile organic compounds) analyzed for in water from seven wells sampled had concentrations less than the MDL (method detection limit) of 0.2000 ( μ g/L except for di-bromo-chloro-propane, which had a concentration less than the MDL of 1.000 ( μ g/L. The detected VOCs were phenols, benzene, and 1,1- dichloroethane. The sources of these VOCs may have been leachate from nearby closed landfills. Benzene, the only one of the three detected VOCs with an established MCL (Maximum Contaminant Level), had a concentration that was one order of magnitude less than its MCL of 5 ( μ g/L. The stage-discharge relations for Nett Lake River and Woodduck Creek were usable for estimation of daily mean discharge for each stream. Six discharge measurements made in the Lost River indicate that discharge in this stream could be substantially greater or smaller than concurrent discharge in Woodduck Creek.

Minnesota↗

Effects of phosphate mining on the ground water of Anguar, Palau Islands, Trust Territory of the Pacific Islands

Mining of phosphate ore on Angaur Island by mechanized methods created large water-table lakes, which became filled with brackish or saline water. A hydrologic investigation was started in 1949 to determine whether the saline water in the lakes would spread to surrounding areas and cause damage to agricultural lands and the water supply. Angaur, which is in the Palau Islands in the southwestern part of Micronesia, is administered as part of the Trust Territory of the Pacific Islands, under a trusteeship granted to the United States by the United Nations. The island has an area of 3.2 square miles and has a maximum altitude of about 150 feet. The climate is tropical oceanic. The average annual temperature is 82 ? F; the average annual rainfall is about 125 inches; and the average relative humidity is about 80 percent. The northwestern third of Angaur (province A) consists topographically of a series of concentric ridges and depressions which are underlain largely by well-cemented coralline limestone of Pliocene, Pleistocene, and Recent ages. The remaining two-thirds of Angaur (province B} is a low plain underlain in the northern and central parts by a low platform of coralline rubble of Pleistocene and Recent age and in the southern part by sandy and rubbly beach deposits of Recent age. Province A contained extensive phosphate deposits of which more than 3 million tons were mined in 1909-55. Weekly water-level measurements at 35 wells, test holes, and lakes indicate that the water table averages about 2 feet above mean sea level in the beach deposits, about half a foot above mean sea level in the rubble deposits, and about 1.35 feet above mean sea level in the coralline limestone. Water samples obtained weekly at the observation sites indicate that the ground water in province A is not of uniform quality, as large variations in salinity occur throughout the area. In contrast, the ground water in province B is of relatively uniform quality, and contains less than 1,000 ppm (parts per million) of chloride in most places. In province A removal of earthy phosphate which had acted as a seal allowed the infiltration of saline water through solution channels exposed at the bottom of several of the lakes. The sampling program showed no indication of large-scale movement of saline water out of the lakes into adjacent ground water. Provinces A and B apparently function as independent ground-water units, and the quality of the ground water in province B has not been noticeably affected by mining activities in province A. The lakes were backfilled with limestone rubble to reduce the possibility of underground movement of saline water out of the lakes. The gross permeability of the backfill material is less than that of the surrounding limestone in province A, and, as the rate of influx of saline water was curtailed, the recharge of fresh water from rainfall tended to reduce the salinity of the ground water in the fill. In parts of the backfilled area the salinity of the water at the water table decreased rapidly in less than 1 year, as a layer of fresh water was built up at the water table.

Water Supply Paper↗

Effects of land use and geohydrology on the quality of shallow ground water in two agricultural areas in the western Lake Michigan drainages, Wisconsin

Water-quality and geohydrologic data were collected between September 1993 and September 1994, from 56 wells and 2 springs, in two agricultural areas in the Western Lake Michigan Drainages study unit of the National-Water Quality Assessment Program. These data were used to study the effects of land use and geohydrology on shallow ground-water quality. Water samples from each well and spring were analyzed for major ions, nutrients, dissolved organic carbon, pesticides, volatile organic compounds, oxygen and hydrogen isotopes, and uranium; measurements of temperature, pH, specific conductance, and dissolved oxygen were made in the field. Ground-water samples were also analyzed for tritium or chlorofluorocarbons, or both, to estimate the recharge date of the ground water. Slug tests were performed on most of the wells to estimate the hydraulic conductivity of the surficial deposits in the vicinity of the well. The two areas chosen for study had similar agricultural land uses but different geohydrologic characteristics. Sampled monitor wells and springs were located down gradient from farm fields having similar crop rotation patterns, mainly corn and alfalfa. Area l is characterized by sand and clay surficial deposits overlying carbonate bedrock, and area 2 is characterized by sand and gravel surficial deposits overlying sandstone or crystalline bedrock. The depth to water was significantly deeper and the hydraulic conductivity of the surficial deposits was significantly higher in area 2. Water-quality analyses indicate that agricultural land use has affected the ground-water quality of both of the study areas, however, Wisconsin ground-water-quality enforcement standards were exceeded in only 22 percent (13 of 58) of samples for dissolved nitrate and 2 percent (l of 58) of samples for dissolved atrazine plus deethyl atrazine. There was a significant difference between the two areas in the concentrations of dissolved nitrate and atrazine plus deethyl atrazine in the shallow ground water. Although the amount of nitrogen fertilizer and manure applied to the land surface was similar or slightly higher in area 2, as compared to area 1, and atrazine application rates may have been slightly higher in area l, area 2 had significantly higher concentrations of both dis solved nitrate and atrazine plus deethyl atrazine in shallow ground water. The areal difference in nitrate and atrazine concentrations was likely due to the relatively higher permeability and lower organic matter content of the surficial deposits in area 2. The more permeable surficial deposits in area 2 allowed nitrate and atrazine (and its metabolites) to readily move from the land surface to ground water. Additionally, the lower organic matter content in area 2 helped to maintain higher dis solved oxygen concentrations in recharging water and throughout the saturated zone, thus reducing the possibility of denitrification or assimilative uptake. Estimated recharge dates showed that historic patterns of atrazine plus deethyl atrazine concentrations in ground water mimic historic patterns of atrazine use on corn. Concentrations in ground water that recharged prior to the early 1960s, when atrazine started to become widely used on corn in Wisconsin, were very low or not detectable. As atrazine use on corn steadily increased from the late 1960s to the late 1970s and early 1980s, detectable concentrations of atrazine plus deethyl atrazine in ground water became more common. The recharge dates of some of the highest measured concentrations of atrazine plus ethyl atrazine in ground water from both study areas correspond to the period of highest atrazine use on corn within the State.

Michigan, Wisconsin↗

Simulation of ground-water flow in the Cedar River alluvium, northwest Black Hawk County and southwest Bremer County, Iowa

Flooding and high ground-water levels after large or frequent rainstorms have occurred in an area of about 30 square miles along the eastern bank of the Cedar River from Cedar Falls in northwest Black Hawk County to Janesville in southwest Bremer County, Iowa. The U.S. Geological Survey, in cooperation with Black Hawk County, conducted a hydrologic study of the Cedar River alluvium in the northwest Black Hawk and southwest Bremer Counties, to improve understanding of the ground-water flow system and evaluate the effects of hypothetical variations in recharge and discharge conditions. A steady-state ground-water flow model was constructed for the area using November 2001 hydrologic conditions. The model was discretized into an 83-row by 47-column grid of cells measuring approximately 500 feet by 500 feet. Two model layers, one for the alluvium and one for the underlying bedrock units, were used to represent flow in the area. Precipitation during 2001 was similar to historical normals. Precipitation during 1999, especially during the summer when flooding occurred, was well above the historical normals. Borings in the unconsolidated deposits in the study area confirmed the presence of a bedrock valley dipping to the south in the central part of the study area. Water-level measurements in 2001 indicate that ground-water flow in much of the alluvial aquifer parallels the direction of flow in the Cedar River toward the south rather than following shorter flow paths to the west toward the Cedar River. Under steady-state conditions and 2001 pumpage, primary sources of inflow to the ground-water flow system are the Cedar River (65.5 percent), recharge through infiltration of precipitation and upland runoff (31.4 percent), and subsurface flow across the lateral boundaries (3.1 percent). The primary components of outflow from the ground-water flow system are intermittent streams (56.0 percent) and the Cedar River (43.7 percent). Two hypothetical scenarios were used to assess the potential effects of higher river levels and increased recharge compared to the steadystate conditions. For one scenario, river levels were set to bankfull conditions, and a recharge of 1.2 times the steady-state rate was applied. This simulation was used to evaluate the effects of wet conditions. This scenario led to increased water levels, in general, and large areas of shallow (0 to 10 feet) depths to water along the eastern part of the model area near Highway 218. For the second scenario, conditions were the same as for the first scenario, but streambed conductance of intermittent streams modeled as drains was increased to 10 times the steady-state value to simulate increased flow of water from the shallow groundwater flow system. The area with depth to water of 0 to 10 feet along the eastern part of the model area was substantially smaller than that of the first scenario. In general, once high ground-water levels occur, either because of high Cedar River water Abstract levels or above normal local precipitation or both, ground-water in the central part of the study area along Highway 218 flows toward the south rather than following shorter flow paths to the Cedar River. Intermittent streams in the study area discharge substantial amounts of water from the ground-water flow system.

Iowa↗

Ground-Water Flow, 2004-07, and Water Quality, 1992-2007, in McBaine Bottoms, Columbia, Missouri

The U.S. Geological Survey, in cooperation with the city of Columbia, Missouri, and the Missouri Department of Conservation, collected ground-water quality data, surface-water quality data, and water-level data in McBaine Bottoms, southwest of Columbia. McBaine Bottoms, adjacent to the Missouri River, is the location of the municipal-supply well field for the city of Columbia, the city of Columbia wastewater-treatment wetlands, and the Missouri Department of Conservation Eagle Bluffs Conservation Area. This report describes the ground-water flow and water quality of McBaine Bottoms and provides information to better understand the interaction between treated effluent from the wetlands used on the Eagle Bluffs Conservation Area and the water in the alluvial aquifer that is pumped from the city of Columbia municipal-supply well field. Changes in major chemical constituent concentrations have been detected at several sampling sites between pre- and post-effluent application data. Analysis of post-effluent data indicates substantial changes in calcium, potassium, sodium, chloride, and sulfate concentrations in ground water. These changes became apparent shortly after the beginning of the operation of the wastewater-treatment wetland in 1994 and the formation of the Eagle Bluffs Conservation Area, which uses the treated effluent as a water source for the management of migratory water fowl. The changes have continued throughout the 15 years of sample collection. The concentrations of these major chemical constituents are on the mixing continuum between pre-effluent ground water as one end member and the treated wastewater effluent as the other end member. For monitoring wells that had changes in major chemical constituent concentrations, the relative percentage of treated effluent in the ground water, assuming chloride is conservative, ranged from 6 to 88 percent. Twenty-two monitoring wells throughout McBaine Bottoms have been affected by effluent based on chloride concentrations larger than 40 milligrams per liter. The chloride concentration of ground water in the alluvial aquifer reflects several sources, including precipitation, water from the Missouri River, water in the aquifer, and the treated effluent. Chloride concentrations from precipitation, the Missouri River, and water in the alluvial aquifer were less than 40 milligrams per liter. These monitoring wells affected by effluent are located in two general areas - adjacent to treatment wetland unit 1 and near the ground-water high on and north of the Eagle Bluffs Conservation Area. The probable source of the large chloride concentrations in well samples adjacent to treatment wetland unit 1 is leakage from the unit. The source for the large chloride concentrations in the other monitoring well samples is the effluent mixed with ground water and Missouri River water that is used to fill pools on the Eagle Bluffs Conservation Area. One monitoring well had a single sample with a chloride concentration larger than 40 milligrams per liter. That sample may have been affected by the use of road salt because of the presence of ice and snow immediately before the sample was collected. Lateral ground-water flow was dominated by the presence of a persistent ground-water high beneath the Eagle Bluffs Conservation Area and the presence of a cone of depression centered around the city of Columbia well field in the northern part of the study area. Ground-water flow was radially away from the apex of the ground-water high; west and south of the high, flow was toward the Missouri River, east of the high, flow was toward Perche Creek, and north of the high, flow was to the north toward the cone of depression around the city of Columbia well field. Another permanent feature on the water-level maps was a ground-water high beneath treatment wetland unit 1. Although the ground-water high was present throughout the study period, the subsurface expression of the high changed depending on hydrolo

Scientific Investigations Report↗

Sensitivity of ground water to contamination in Lawrence County, South Dakota

Ground-water supplies in Lawrence County, South Dakota, can be contaminated by agricultural, urban, suburban, commercial, and industrial land uses. To address this issue, the U.S. Geological Survey in cooperation with Lawrence County and the City of Spearfish mapped the sensitivity of ground water to contamination in Lawrence County. Sensitivity of ground water to contamination was determined by delineating hydrogeologic settings with common hydrogeologic characteristics as described in the DRASTIC method, developed by the U.S. Environmental Protection Agency and the National Water Well Association. Within the framework of 11 hydrogeologic settings, sensitivity to contamination was ranked for six intrinsic hydrogeologic characteristics: (1) aquifer media, (2) unsaturated media (3) hydraulic conductivity, (4) recharge rate, (5) depth to water, and (6) land-surface slope. The rating conventions of DRASTIC were modified to provide a relative ranking of hydrogeologic characteristics without assignment of a combined numerical score. Soil characteristics were not included as a map layer because detailed digital data were not available; however, the general distribution of two soil characteristics were shown. A total of 956 polygons were delineated and assigned a sensitivity-unit code that represented unique groups of sensitivity rank for the six intrinsic hydrogeologic characteristics. The polygons were created by overlaying and intersecting maps that describe the geology, precipitation, land-surface elevation, and depth to water using a geographic information system. Thirty drainage areas upstream from potential streamflow-loss zones were delineated to describe an additional mechanism of transport of potential contamination. The sensitivity of ground water to contamination was presented on a 1:100,000-scale map with code and label explanations. Limitations of the sensitivity map are described to facilitate appropriate use of the map as a screening tool to compare sensitivity to contamination.

Water-Resources Investigations Report↗

Ground water in Osceola County, Florida

This report describes the ground-water resources of Osceola County, Florida, with emphasis on the (1) location of the principal aquifers, (2) location of areas of ground-water recharge and discharge, (3) chemical quality of ground water, and (4) quantities of ground water available. The investigation includes an inventory of 365 wells, test drilling in unconsolidated materials overlying the Floridan aquifer, water-level measurements, and water quality sampling and analysis. (USGS)

Open-File Report↗

1996 Water-Table Contours of the Mojave River, the Morongo, and the Fort Irwin Ground-Water Basins, San Bernardino County, California

This data set consists of digital water-table contours for the Mojave River, the Morongo and the Fort Irwin Ground-Water Basins. The U.S. Geological Survey constructed a water-table map of the Mojave River, the Morongo and the Fort Irwin Ground-Water Basins for ground-water levels measured during the period January-September 1996. Water-level data were collected from 632 wells to construct the contours. The water-table contours were digitized from the paper map which was published at a scale of 1:175,512. The contour interval ranges from 3,400 to 1,550 feet above sea level.

California↗

Factors affecting ground-water exchange and catchment size for Florida lakes in mantled karst terrain

In the mantled karst terrain of Florida, the size of the catchment delivering ground-water inflow to lakes is often considerably smaller than the topographically defined drainage basin. The size is determined by a balance of factors that act individually to enhance or diminish the hydraulic connection between the lake and the adjacent surficial aquifer, as well as the hydraulic connection between the surficial aquifer and the deeper limestone aquifer. Factors affecting ground-water exchange and the size of the ground-water catchment for lakes in mantled karst terrain were examined by: (1) reviewing the physical and hydrogeological characteristics of 14 Florida lake basins with available ground-water inflow estimates, and (2) simulating ground-water flow in hypothetical lake basins. Variably-saturated flow modeling was used to simulate a range of physical and hydrogeologic factors observed at the 14 lake basins. These factors included: recharge rate to the surficial aquifer, thickness of the unsaturated zone, size of the topographically defined basin, depth of the lake, thickness of the surficial aquifer, hydraulic conductivity of the geologic units, the location and size of karst subsidence features beneath and onshore of the lake, and the head in the Upper Floridan aquifer. Catchment size and the magnitude of ground-water inflow increased with increases in recharge rate to the surficial aquifer, the size of the topographically defined basin, hydraulic conductivity in the surficial aquifer, the degree of confinement of the deeper Upper Floridan aquifer, and the head in the Upper Floridan aquifer. The catchment size and magnitude of ground-water inflow increased with decreases in the number and size of karst subsidence features in the basin, and the thickness of the unsaturated zone near the lake. Model results, although qualitative, provided insights into: (1) the types of lake basins in mantled karst terrain that have the potential to generate small and large amounts of ground-water inflow, and (2) the location of ground-water catchments that could be managed to safeguard lake water quality. Knowledge of how ground-water catchments are related to lakes could be used by water-resource managers to recommend setback distances for septic tank drain fields, agricultural land uses, and other land-use practices that contribute nutrients and major ions to lakes.

Water-Resources Investigations Report↗

Ground-water conditions at Beale Air Force Base and vicinity, California

Ground-water conditions were studied in a 168-square-mile area between the Sierra Nevada and the Feather River in Yuba County, Calif. The area is in the eastern part of the Sacramento Valley and includes most of Beale Air Force Base. Source, occurrence, movement, and chemical quality of the ground water were evaluated. Ground water occurs in sedimentary and volcanic rocks of Tertiary and Quaternary age. The base of the freshwater is in the undifferentiated sedimentary rocks of Oligocene and Eocene age, that contain water of high dissolved-solids concentration. The ground water occurs under unconfined and partly confined conditions. At Beale Air Force Base it is at times partly confined. Recharge is principally from the rivers. Pumpage in the study area was estimated to be 129,000 acre-feet in 1975. In the 1960's, water levels in most parts of the study area declined less rapidly than in earlier years or became fairly stable. In the 1970's, water levels at Beale Air Force Base declined only slightly. Spacing of wells on the base and rates of pumping are such that excessive pumping interference is avoided. Water quality at the base and throughout the study area is generally good. Dissolved-solids concentrations are 700 to 900 milligrams per liter in the undifferentiated sedimentary rocks beneath the base well field. (USGS)

Open-File Report↗

Occurrence of Agricultural Chemicals in Shallow Ground Water and the Unsaturated Zone, Northeast Nebraska Glacial Till, 2002-04

Agricultural chemicals applied at the land surface in northeast Nebraska can move downward, past the crop root zone, to ground water. Because agricultural chemicals applied at the land surface are more likely to be observed in the shallowest part of an aquifer, an assessment of shallow ground-water and unsaturated zone quality in the northeast Nebraska glacial till was completed between 2002 and 2004. Ground-water samples were collected at the first occurrence of ground water or just below the water table at 32 sites located in areas likely affected by agriculture. Four of the 32 sites were situated along a ground-water flow path with its downgradient end next to Maple Creek. Twenty-eight sites were installed immediately adjacent to agricultural fields throughout the glacial-till area. In addition to those 32 sites, two sites were installed in pastures to represent ground-water conditions in a non-cropland setting. Ground-water samples were analyzed for physical properties and concentrations of nitrogen and phosphorus compounds, selected pesticides and pesticide degradates, dissolved solids, major ions, trace elements, and dissolved organic carbon. Chlorofluorocarbons (CFCs) or sulfur hexafluoride (SF6) concentrations were analyzed at about 70 percent of the monitoring wells to estimate the residence time of ground water. Borehole-core samples were collected from 28 of the well boreholes. Sediment in the unsaturated zone was analyzed for nitrate, chloride, and ammonia concentrations. Analytical results indicated that the agricultural chemicals most often detected during this study were nitrates and herbicides. Nitrate as nitrogen (nitrate-N) concentrations (2003 median 9.53 milligrams per liter) indicated that human activity has affected the water quality of recently recharged ground water in approximately two-thirds of the wells near corn and soybean fields. The principal pesticide compounds that were detected reflect the most-used pesticides in the area and included parent or degradate compounds of acetochlor, alachlor, atrazine, and metolachlor. Overall, pesticide concentrations in ground-water samples collected in 2003 and 2004 were small and did not exceed public drinking-water standards where established. On average, more pesticides were detected in the flow-path wells than in the glacial-till network wells. The presence of a perennial stream within 1,640 feet of a well was correlated to smaller nitrate-N concentrations in the well water, and the presence of a road ditch within 164 feet of the well was correlated to the presence of detectable pesticides in the well water. All other variables tested showed no significant correlations to nitrate-N concentrations or pesticide detections. Unsaturated zone soil cores collected in 2002 from well boreholes indicated that nitrogen in the forms of nitrate-N and ammonia as nitrogen (ammonia-N) was available in the unsaturated zone for transport to ground water. Concentrations of nitrate-N and ammonia-N in these soil cores were inversely correlated to depth, and nitrate-N concentrations were correlated to chloride concentrations.

Scientific Investigations Report↗

Ground-water resources of Rusk County, Texas

Fresh to slightly saline water is available in most parts of Rusk County, which is located in the Piney Woods region of northeast Texas. The Wilcox aquifer, which underlies the entire county, was the source of most of the ground water withdrawn during 1980. Other units capable of yielding fresh ground water are the Carrizo, Queen City, and Sparta aquifers and the Reklaw Formation. About 5.4 million gallons per day (20,440 cubic meters per day) of ground water was used for all purposes during 1980. Of this amount, about 78 percent was used for public supply, 10 percent for mining, 8 percent for industrial purposes, and 4 percent for rural domestic use. Water levels have declined extensively at the city of Henderson, which used about 38 percent of all ground water consumed in Rusk County. Generally, the ground water is of acceptable quality. Water in some of the near-surface beds and some of the deeper sands in the Wilcox aquifer may have become mineralized because of oilfield operations. Ground-water contamination by oilfield brines at Henderson Oil Field has been documented. Two separate instances of streamflow contamination at Striker Creek and Henderson Oil Field have been documented. Moderate amounts of ground water are available for development. The amount that is available perennially is not known, but it is greater than that being withdrawn. Assuming a hydraulic gradient of about 8 feet per mile (1.5 meters per kilometer), at least 12 million gallons per day (45,420 cubic meters per day) of fresh ground water is being transmitted through the Wilcox and about 3 million gallons per day (11,350 cubic meters per day) through the Carrizo. About 20 million acre-feet (24,660 cubic hectometers) of freshwater is available from storage in the Wilcox and about 4 million acre-feet (4,930 cubic hectometers) from storage in the Carrizo. Additional amounts of slightly saline water are available from the major aquifers. Smaller but undetermined amounts of fresh ground water are available from the Sparta and Queen City aquifers and from the Reklaw Formation. Properly constructed wells in the Wilcox and Carrizo aquifers can be expected to yield more than 500 gallons per minute (32 liters per second) if the wells are properly spaced. Development of additional resources around the city of Henderson and the Mount Enterprise Fault System should be considered cautiously because of the probability of saltwater encroachment. Ground water in other parts of the county is practically undeveloped. Some mineralization of ground water is due to natural causes. Other mineralization of ground water is due to contamination. A program needs to be initiated to determine the extent and cause of mineralization that has taken place in freshwater sands. Water-quality data is needed at Henderson in order to monitor saltwater encroachment.

Texas↗

Ground water resources of the lower Bear River drainage basin, Box Elder County, Utah

This report is intended to aid public officials and water users in the lower Bear River drainage basin to develop, conserve, and administer their water resources. Although the report is primarily about ground water, it describes the relation of ground water to surface water and presents a general water-budget analysis. It discusses the sources, occurrence, availability, quantity, movement, chemical quality, and development of the ground water and the effects of climate, geology, and development on the ground water. The appendix of the report describes the well- and spring-numbering system and defines some units and terms.

Utah↗

Ground-water levels, flow, and quality in northwestern Elkhart County, Indiana, 1980-89

Ground-water data were collected in northwestern Elkhart County, Indiana, from 1980 through 1989 to monitor hydrologic conditions and to provide information necessary for waterresources managers to evaluate the ground-water resources in this area. The area of study includes a closed industrial landfill and several areas of industrial and municipal pumping. Water levels were measured twice a year in 68 wells, and water samples were collected once a year from 32 wells. The wells were screened in unconsolidated glacial-outwash deposits primarily sand and gravel. During the study, measured ground-water levels ranged from about 6 feet above ground level to about 29 feet below ground level. The average depth to water for all wells was 10 feet, and the average water-level fluctuation for the entire study period was 4.8 feet. In the study area, ground water flows toward the St. Joseph River. Water levels near the river are higher than the stage of the river, indicating that ground water is discharged to the river. Water samples were collected and analyzed to determine concentrations of dissolved bromide. Onsite measurements of specific conductance, pH, water temperature, and concentrations of dissolved oxygen and alkalinity were made at the time of sampling. The water samples had a median specific conductance of 516 microsiemens per centimeter at 25 degrees Celsius, a median ph of 7.6, a median alkalinity of 216 milligrams per liter (as calcium carbonate), and a median dissolved-bromide concentration of 0.08 milligrams per liter. Water-quality data were grouped according to the depth and position of the wells in the flow system with respect to the closed industrial landfill. Shallow wells are those less than 100 feet deep; deep wells are those more than 100 feet deep. Comparison among groups indicates that water from shallow wells downgradient from the landfill had larger values of specific conductance, larger concentrations of alkalinity and dissolved bromide, and smaller values of pH than did water from shallow wells upgradient from the landfill and water from deep wells throughout the study area. Concentrations of dissolved bromide were used to estimate the extent of the landfill's effect on ground-water quality by plotting and contouring the concentration values on maps and hydrogeologic sections. The maps show a plume of bromide extending south of the landfill along the direction of groundwater flow. The hydrogeologic sections indicate that water containing bromide is moving vertically downward in the unconfined aquifer beneath and downgrfldient from the landfill. Maps and sections for different time periods were compared to determine how the distribution of bromide was changing. Although dissolved-bromide concentrations in water from individual wells were variable, the distribution of dissolved bromide did not change substantially during the study period. The time of peak dissolved-bromide concentrations in water from shallow wells downgradient from the landfill was used to estimate a rate of horizontal flow of water in the unconfined aquifer. The average rate of flow between shallow wells downgradient from the landfill was estimated to be 1.2 feet per day. This rate is within the range of values for ground-water flow calculated according to Darcy's law.

Indiana↗

Evaluation of ground-water quality in the Santa Maria Valley, California

The quality and quantity of recharge to the Santa Maria Valley groundwater basin from natural sources, point sources, and agriculture were evaluated. The results are expressed in terms of a hydrologic budget, a solute balance, and maps showing the distribution of selected chemical constituents in ground water. Point sources of waste discharge that could cause ground-water degradation were investigated including a sugar-beet refinery, oil refineries and oil-field wastewater, stockyards, golf courses, poultry farms, solid-waste landfills, and municipal and industrial wastewater-treatment facilities. Measurements of specific conductance of ground water and water levels in nearly 400 wells and the analyses of about 100 water samples for most major anions and cations plus detergents, dissolved organic carbon, and trace metals permitted preparation of maps showing the potentiometric surface and the distribution of dissolved solids, chloride, sulfate, calcium plus magnesium, and nitrogen in ground water. Pumpage of ground water for agricultural, municipal, and industrial uses has exceeded recharge by about 10,000 acre-feet per year (12.3 cubic hectometers per year). Most of the ground water pumped in the Santa Maria Valley is for agriculture. The result of pumping in excess of recharge is a declining potentiometric surface, an accumulation of solutes, and an increase in nitrogen in ground water. At present (1976), the area of confined water is most severely affected by this degradation. Nitrogen concentrations in ground water have reached as much as 50 milligrams per liter in isolated areas, with concentrations in excess of 10 milligrams per liter occurring through most of the area of confined water. Continued pumping in excess of recharge may also lower the potentiometric surface sufficiently to permit intrusion of seawater into the fresh-water zones. Discharge of wastewater from municipal and industrial wastewater-treatment facilities is also contributing solutes to the ground-water system. In comparison to the influences of irrigation return water on ground-water quality, the contribution from point sources is less than 10 percent of the total solutes. In some areas of the valley, the concentration of dissolved solids and some chemical constituents in water discharging from municipal and industrial wastewater-treatment facilities is lower than in the receiving ground water.

California↗

Assessment of the hydraulic connection between ground water and the Peace River, west-central Florida

The hydraulic connection between the Peace River and the underlying aquifers along the length of the Peace River from Bartow to Arcadia was assessed to evaluate flow exchanges between these hydrologic systems. Methods included an evaluation of hydrologic and geologic records and seismic-reflection profiles, seepage investigations, and thermal infrared imagery interpretation. Along the upper Peace River, a progressive long-term decline in streamflow has occurred since 1931 due to a lowering of the potentiometric surface of the Upper Floridan aquifer by as much as 60 feet because of intensive ground-water withdrawals for phosphate mining and agriculture. Another effect from lowering the potentiometric surface has been the cessation of flow at several springs located near and within the Peace River channel, including Kissengen Spring, that once averaged a flow of about 19 million gallons a day. The lowering of ground-water head resulted in flow reversals at locations where streamflow enters sinkholes along the streambed and floodplain. Hydrogeologic conditions along the Peace River vary from Bartow to Arcadia. Three distinctive hydrogeologic areas along the Peace River were delineated: (1) the upper Peace River near Bartow, where ground-water recharge occurs; (2) the middle Peace River near Bowling Green, where reversals of hydraulic gradients occur; and (3) the lower Peace River near Arcadia, where ground-water discharge occurs. Seismic-reflection data were used to identify geologic features that could serve as potential conduits for surface-water and ground-water exchange. Depending on the hydrologic regime, this exchange could be recharge of surface water into the aquifer system or discharge of ground water into the stream channel. Geologic features that would provide pathways for water movement were identified in the seismic record; they varied from buried irregular surfaces to large-scale subsidence flexures and vertical fractures or enlarged solution conduits. Generally, the upper Peace River is characterized by a shallow, buried irregular top of rock, numerous observed sinkholes, and subsidence depressions. The downward head gradient provides potential for the Peace River to lose water to the ground-water system. Along the middle Peace River area, head gradients alternate between downward and upward, creating both recharging and discharging ground-water conditions. Seismic records show that buried, laterally continuous reflectors in the lower Peace River pinch out in the middle Peace River streambed. Small springs have been observed along the streambed where these units pinch out. This area corresponds to the region where highest ground-water seepage volumes were measured during this study. Further south, along the lower Peace River, upward head gradients provide conditions for ground-water discharge into the Peace River. Generally, confinement between the surficial aquifer and the confined ground-water systems in this area is better than to the north. However, localized avenues for surface-water and ground-water interactions may exist along discontinuities observed in seismic reflectors associated with large-scale flexures or subsidence features. Ground-water seepage gains or losses along the Peace River were quantified by making three seepage runs during periods of: (1) low base flow, (2) high base flow, and (3) high flow. Low and high base-flow seepage runs were performed along a 74-mile length of the Peace River, between Bartow and Nocatee. Maximum losses of 17.3 cubic feet per second (11.2 million gallons per day) were measured along a 3.2-mile reach of the upper Peace River. The high-flow seepage run was conducted to quantify losses in the Peace River channel and floodplain between Bartow and Fort Meade. Seepage losses calculated during high-flow along a 7.2-mile reach of the Peace River, from the Clear Springs Mine bridge to the Mobil Mine bridge, were approximately 10 percent of the river flow, or 118 cubic feet per second. Calculated seepages along the Peace River in Hardee and De Soto Counties were inconclusive, because most seepages were within the range of discharge measurement error. Two continuous aerial thermal infrared imagery surveys were conducted to locate sites of ground-water discharge along the Peace River. Although temperature and hydrologic conditions were ideal to observe spring flow using thermal infrared imaging techniques, no sources of ground-water discharge were identified using this method. Diffuse ground-water seepage may, however, provide significant ground-water discharge.

Florida↗