Search USGS⌕ Search

SEARCH · Search USGS

Results for “Experimental Results”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,117 records · Page 62Linked to original sources
USGS2000

Mobilization of major inorganic ions during experimental diagenesis of characterized peats

Laboratory experiments were undertaken to study changes in concentrations of major inorganic ions during simulated burial of peats to about 1.5 km. Cladium, Rhizophora, and Cyrilla peats were first analyzed to determine cation distributions among fractions of the initial materials and minerals in residues from wet oxidation. Subsamples of the peats (80 g) were then subjected to increasing temperatures and pressures in steps of 5??C and 300 psi at 2-day intervals and produced solutions collected. After six steps, starting from 30??C and 300 psi, a final temperature of 60??C and a final pressure of 2100 psi were achieved. The system was then allowed to stand for an additional 2 weeks at 60??C and 2100 psi. Treatments resulted in highly altered organic solids resembling lignite and expelled solutions of systematically varying compositions. Solutions from each step were analyzed for Na+, Ca2+, Mg2+, total dissolved Si (Si(T)), Cl-, SO42-, and organic acids and anions (OAAs). Some data on total dissolved Al (Al(T)) were also collected. Mobilization of major ions from peats during these experiments is controlled by at least three processes: (1) loss of dissolved ions in original porewater expelled during compaction, (2) loss of adsorbed cations as adsorption sites are lost during modification of organic solids, and (3) increased dissolution of inorganic phases at later steps due to increased temperatures (Si(T)) and increased complexing by OAAs (Al(T)). In general, results provide insight into early post-burial inorganic changes occurring during maturation of terrestrial organic matter. (C) 2000 Elsevier Science B.V. All rights reserved.

Chemical Geology↗
USGS2014

Beta-thymosin gene polymorphism associated with freshwater invasiveness of alewife ( Alosa pseudoharengus )

Predicting the success of a species’ colonization into a novel environment is routinely considered to be predicated on niche-space similarity and vacancy, as well as propagule pressure. The role genomic variation plays in colonization success (and the interaction with environment) may be suggested, but has not rigorously been documented. To test an hypothesis that previously observed ecotype-specific polymorphisms between anadromous and landlocked alewife (Alosa pseudoharengus) populations are an adaptive response to osmoregulatory challenges rather than a result of allele sampling at founding, we examined multiple anadromous and landlocked (colonized) populations for their allelic profiles at a conserved region (3’-UTR end) of a β-thymosin gene whose protein product plays a central role in the organization of cytoskeleton. The putatively ancestral β-thymosin allele was prevalent in anadromous populations, whereas a newly derived allele was overrepresented in landlocked populations; a third allele was exclusive to the anadromous populations. We also conducted a complementary set of salinity exposure experiments to test osmoregulatory performance of the alewife ecotypes in contrasting saline environments. The pattern of variation and results from these challenges indicate a strong association of β-thymosin with colonization success and a transition for species with an anadromous life-history to one with only a freshwater component.

Journal of Experimental Zoology↗
USGS1999

Geothermal elements in lichens of Yellowstone National Park, USA

Geothermal features (e.g. geysers, fumaroles, vents, and springs) emit gaseous mercury, sulfur and heavy metals and therefore, are natural sources of these elements in the atmosphere. Field studies of heavy metals in lichens in Italy have detected elevated concentrations near geothermal power plants, and have determined that the origin of mercury is from soil degassing, not soil particles. We studied this phenomenon in a geothermal area without power plants to determine the natural levels of mercury and other elements. Two common and abundant species of epiphytic lichens, Bryoria fremontii and Letharia vulpina , were collected at six localities in Yellowstone National Park, USA in 1998 and analyzed for 22 chemical elements. Thirteen elements differed significantly between species. Some elements were significantly higher in the southern part of the park, while others were higher in the north. Levels of most elements were comparable with those in other national parks and wilderness areas in the region, except Hg, which was unusually high. The most likely sources of this element are the geothermal features, which are known emitters of Hg. Multivariate analyses revealed strong positive associations of Hg with S, and negative associations with soil elements, providing strong evidence that the Hg in the lichens is the result of soil degassing of elemental Hg rather than particulate Hg directly from soils. Average Hg levels in the lichens were 140 p.p.b. in Bryoria and 110 p.p.b. in Letharia , but maxima were 291 and 243 p.p.b., respectively. In spite of this, both species were healthy and abundant throughout the park.

Idaho, Montana, Wyoming↗
USGS1999

Multiple stresses from a single agent: Diverse responses to the experimental acidification of Little Rock Lake, Wisconsin

A single stress, acidification with sulfuric acid, was applied to Little Rack Lake in a whole-ecosystem manipulation. We documented a wide range of responses to the acidification, including increases in the concentrations of various chemicals, shifts in microbial processes and a major increase in water clarity to UV-B radiation. Each of these changes could in itself be considered as a separate ecosystem stress that is distinct from the intended manipulation. Acidification in Little Rock Lake was accompanied by a number of substantial changes in the occurrence of organisms. A series of detailed investigations indicates that the mechanisms underlying these organismal changes are varied but cannot usually be tied to the direct effects of acidification. Overall, our results demonstrate how multiple stresses can arise from a single agent operating on an ecosystem and suggest that singly operating stresses may actually be quite rare.

Limnology and Oceanography↗
USGS1999

Multiple stresses from a single agent: Diverse responses to the experimental acidification of Little Rock Lake, Wisconsin

A single stress, acidification with sulfuric acid, was applied to Little Rock Lake in a whole-ecosystem manipulation. We documented a wide range of responses to the acidification, including increases in the concentrations of various chemicals, shifts in microbial processes and a major increase in water clarity to UV-B radiation. Each of these changes could in itself be considered as a separate ecosystem stress that is distinct from the intended manipulation. Acidification in Little Rock Lake was accompanied by a number of substantial changes in the occurrence of organisms. A series of detailed investigations indicates that the mechanisms underlying these organismal changes are varied but cannot usually be tied to the direct effects of acidification. Overall, our results demonstrate how multiple stresses can arise from a single agent operating on an ecosystem and suggest that singly operating stresses may actually be quite rare.

Limnology and Oceanography↗
USGS2025

Dynamic risk from Mexican wolves and mountain lions influences elk foraging behavior

Foraging time is a major component of ungulate activity budgets but can be limited by anti-predator behaviors (e.g., vigilance). Multitasking can reduce the nutritional costs of vigilance under heightened predation risk, but this may depend on the response of prey to risk from multiple predators across a complex spatiotemporal landscape. Mexican gray wolves ( Canis lupus baileyi ) and mountain lions ( Puma concolor ) are primary predators for elk ( Cervus canadensis ) in the Mexican wolf experimental population area in east-central Arizona and west-central New Mexico. We observed elk foraging across varying levels of wolf risk throughout all seasons and diel periods to quantify proportions of foraging, intense vigilance, and multitasking at the individual and herd levels. We quantified encounter and kill risk from Mexican wolves and mountain lions using habitat selection functions and utilization distributions. We modeled elk behaviors as functions of predicted risk for both predators in addition to temporal and environmental covariates and accounted for human presence. Our results indicate that individual elk reduced foraging in areas with higher predicted risk from Mexican wolves or mountain lions and increased intense vigilance and multitasking in areas with higher wolf risk. A reduction in the proportion of bedded elk in the herd during all diel periods under increased wolf risk supports previous findings. These results also suggest that elk compensate for higher intense vigilance and reduced foraging during foraging bouts by increasing cumulative foraging bouts per day at the cost of resting. Additionally, the probability of multitasking for individuals depended on an interaction between short- and long-term wolf risk, and the likelihood of intense vigilance was highest under the greatest combined spatial and temporal risk from wolves. This research provides insight into the fine-scale and complex behavioral responses of elk to their primary predators and implies a need for researchers to consider these non-consumptive effects in future studies of predator–prey dynamics.

Arizona, New Mexico↗
USGS2014

Laboratory generated M -6 earthquakes

We consider whether mm-scale earthquake-like seismic events generated in laboratory experiments are consistent with our understanding of the physics of larger earthquakes. This work focuses on a population of 48 very small shocks that are foreshocks and aftershocks of stick–slip events occurring on a 2.0 m by 0.4 m simulated strike-slip fault cut through a large granite sample. Unlike the larger stick–slip events that rupture the entirety of the simulated fault, the small foreshocks and aftershocks are contained events whose properties are controlled by the rigidity of the surrounding granite blocks rather than characteristics of the experimental apparatus. The large size of the experimental apparatus, high fidelity sensors, rigorous treatment of wave propagation effects, and in situ system calibration separates this study from traditional acoustic emission analyses and allows these sources to be studied with as much rigor as larger natural earthquakes. The tiny events have short (3–6 μs) rise times and are well modeled by simple double couple focal mechanisms that are consistent with left-lateral slip occurring on a mm-scale patch of the precut fault surface. The repeatability of the experiments indicates that they are the result of frictional processes on the simulated fault surface rather than grain crushing or fracture of fresh rock. Our waveform analysis shows no significant differences (other than size) between the M -7 to M -5.5 earthquakes reported here and larger natural earthquakes. Their source characteristics such as stress drop (1–10 MPa) appear to be entirely consistent with earthquake scaling laws derived for larger earthquakes.

Pure and Applied Geophysics↗
USGS2017

Inferring infection hazard in wildlife populations by linking data across individual and population scales

Our ability to infer unobservable disease-dynamic processes such as force of infection (infection hazard for susceptible hosts) has transformed our understanding of disease transmission mechanisms and capacity to predict disease dynamics. Conventional methods for inferring FOI estimate a time-averaged value and are based on population-level processes. Because many pathogens exhibit epidemic cycling and FOI is the result of processes acting across the scales of individuals and populations, a flexible framework that extends to epidemic dynamics and links within-host processes to FOI is needed. Specifically, within-host antibody kinetics in wildlife hosts can be short-lived and produce patterns that are repeatable across individuals, suggesting individual-level antibody concentrations could be used to infer time since infection and hence FOI. Using simulations and case studies (influenza A in lesser snow geese and Yersinia pestis in coyotes), we argue that with careful experimental and surveillance design, the population-level FOI signal can be recovered from individual-level antibody kinetics, despite substantial individual-level variation. In addition to improving inference, the cross-scale quantitative antibody approach we describe can reveal insights into drivers of individual-based variation in disease response, and the role of poorly understood processes such as secondary infections, in population-level dynamics of disease.

Ecology Letters↗
USGS2020

An experimental investigation of interaction between andesite and hyperacidic volcanic lake water

Alteration in magmatic-hydrothermal systems leads to distinct changes in rock texture and mineralogy, and a strong redistribution of elements between fluid and rock. Here, we experimentally interacted andesite scoria with hyperacidic, high-sulfidation style fluids from Kawah Ijen volcano (Indonesia) at 25 and 100˚C, seeking to reproduce the textures observed in natural samples from this volcano, and to understand the element fluxes that accompany alteration. The susceptibility to alteration in the experiments is Cu-Fe-sulphide > calcic plagioclase > pyroxene > titano-magnetite > sodic plagioclase, with complete preservation of glass. Silicate minerals alter to opaline silica, and gypsum, barite and a Zr-phase precipitate. The selective alteration of the phenocryst minerals results in a preferential release of compatible elements, as the glass is the main incompatible element host. The experiments reproduce the alteration textures of the natural samples, including the preservation of glass, but the predicted compatible over incompatible element enrichment in the alteration element flux is not observed in the natural setting. This suggests that alteration at Kawah Ijen is dominated by lithologies that lack abundant glass, in particular lava flows where the glass has devitrified, despite these lava flows having a lower surface area compared to scoria.

Kawah Ijen↗
USGS2014

An experimental investigation of chemical communication in the polar bear

The polar bear ( U rsus maritimus ), with its wide-ranging movements, solitary existence and seasonal reproduction, is expected to favor chemosignaling over other communication modalities. However, the topography of its Arctic sea ice habitat is generally lacking in stationary vertical substrates routinely used for targeted scent marking in other bears. These environmental constraints may have shaped a marking strategy, unique to polar bears, for widely dispersed continuous dissemination of scent via foot pads. To investigate the role of chemical communication, pedal scents were collected from free-ranging polar bears of different sex and reproductive classes captured on spring sea ice in the Beaufort and Chukchi seas, and presented in a controlled fashion to 26 bears in zoos. Results from behavioral bioassays indicated that bears, especially females, were more likely to approach conspecific scent during the spring than the fall. Male flehmen behavior, indicative of chemosignal delivery to the vomeronasal organ, differentiated scent donor by sex and reproductive condition. Histologic examination of pedal skin collected from two females indicated prominent and profuse apocrine glands in association with large compound hair follicles, suggesting that they may produce scents that function as chemosignals. These results suggest that pedal scent, regardless of origin, conveys information to conspecifics that may facilitate social and reproductive behavior, and that chemical communication in this species has been adaptively shaped by environmental constraints of its habitat. However, continuously distributed scent signals necessary for breeding behavior may prove less effective if current and future environmental conditions cause disruption of scent trails due to increased fracturing of sea ice.

Journal of Zoology↗
USGS2017

Mangrove species' responses to winter air temperature extremes in China

The global distribution and diversity of mangrove forests is greatly influenced by the frequency and intensity of winter air temperature extremes. However, our understanding of how different mangrove species respond to winter temperature extremes has been lacking because extreme freezing and chilling events are, by definition, relatively uncommon and also difficult to replicate experimentally. In this study, we investigated species-specific variation in mangrove responses to winter temperature extremes in China. In 10 sites that span a latitudinal gradient, we quantified species-specific damage and recovery following a chilling event, for mangrove species within and outside of their natural range (i.e., native and non-native species, respectively). To characterize plant stress, we measured tree defoliation and chlorophyll fluorescence approximately one month following the chilling event. To quantify recovery, we measured chlorophyll fluorescence approximately nine months after the chilling event. Our results show high variation in the geographic- and species-specific responses of mangroves to winter temperature extremes. While many species were sensitive to the chilling temperatures (e.g., Bruguiera sexangula and species in the Sonneratia and Rhizophora genera), the temperatures during this event were not cold enough to affect certain species (e.g., Kandelia obovata , Aegiceras corniculatum , Avicennia marina, and Bruguiera gymnorrhiza ). As expected, non-native species were less tolerant of winter temperature extremes than native species. Interestingly, tidal inundation modulated the effects of chilling. In comparison with other temperature-controlled mangrove range limits across the world, the mangrove range limit in China is unique due to the combination of the following three factors: (1) Mangrove species diversity is comparatively high; (2) winter air temperature extremes, rather than means, are particularly intense and play an important ecological role; and (3) due to afforestation and restoration efforts, several species of non-native mangroves have been introduced beyond their natural range limits. Hence, from a global perspective, mangroves in China provide valuable opportunities to advance understanding of the effects of freezing and chilling temperatures on mangroves. Within the context of climate change, our findings provide a foundation for better understanding and preparing for mangrove species-specific responses to future changes in the duration and intensity of winter temperature extremes.

Ecosphere↗
USGS2026

Dynamics and evolution of the Kı̄lauea lower East Rift Zone 2018 fissure 8 lava flow and implications for multiphase magma properties

The 2018 Kı̄lauea lower East Rift Zone (KLERZ) eruption was one of the most voluminous eruptions on the Island of Hawai’i in the past 200 years, leading to major disruption and destroying over 700 homes and structures. The majority of the erupted magma was emitted as a lava flow from Ahu’ailā’au (fissure 8), which was active from late May to early August. To better understand the evolution of long-lived channelized lava flows, we examined the evolution of velocity, texture, and inferred rheology of the fissure 8 lava in space and time. We quantified lava flow surface velocities using particle image velocimetry in more than 200 aerial videos that span the lava flow duration and length. Velocity measurements were analyzed together with vesicularity and crystallinity measurements from 9 co-located post-eruptive field samples to understand the textural evolution of this flow and its impact on lava rheology and flow velocity. The fissure 8 flow was highly vesicular, with 79%–88% vesicularity at the vent, decreasing to 16%–26% vesicularity 12.5 km from the vent. The volume fraction occupied by crystals 50 in size increased from 6% at the vent to about 18% at 12.5 km downstream. We find that the effective flow viscosity increased at a quadratic rate with distance. Using experimentally determined liquid viscosity and applying established models to account for the effect of crystals and bubbles, we attribute this increase primarily to textural evolution driven initially by the near-vent loss of deformable bubbles and later by cooling and crystal growth. We demonstrate the importance of accounting for the evolution of vesicularity and the role of vesicles by showing that utilizing this capability in the open-source thermo-rheological lava flow propagation model PyFLOWGO allows for more accurate predictions of the observed flow velocities. Our modeling results suggest that small bubbles behaving rigidly are required to simulate the observed flow length, speed, and viscosities. Flow velocities of the fissure 8 lava also varied with time, driven by near-daily collapse events of the summit caldera. Temporal velocity changes were characterized by a period of steep acceleration, with the volumetric flux peaking around 4 h after a caldera collapse, followed by a period of gradual deceleration lasting up to 40 h or until the next collapse event. We use this temporal behavior to estimate the compressibility of the magma inside the plumbing system between the summit reservoir and the lower East Rift Zone. Overall, quantifying the spatial and temporal evolution of the KLERZ eruption provides information about magma and lava properties that can inform predictive modeling and hazard assessment during an eruption.

Hawaii↗
USGS2003

Sex differences in the thermoregulation and evaporative water loss of a heterothermic bat, Lasiurus cinereus, during its spring migration

This study quantifies sex differences in thermoregulation and water loss of a small (20-35 g) insectivorous heterothermic mammal, the hoary bat Lasiurus cinereus , during its spring migration. We measured body temperature, metabolic rate and evaporative water loss, and calculated wet thermal conductance, for bats exposed to air temperatures ranging from 0 to 40°C for periods of 2-5 h. Pregnant females maintained normothermic body temperatures (35.7±0.7°C; mean ± s.e.m. ) independent of air temperature. In contrast, males became torpid during the majority (68%) of exposures to air temperatures <25°C. The thermal neutral zone (TNZ) ranged between approximately 30°C and 34°C in both sexes and, within the TNZ, females had lower mass-specific metabolic rates (6.1±0.2 mW g -1 ) than males (9.0±0.9 mW g -1 ). Wet thermal conductance values in torpid bats (0.7±0.5 mW g -1 deg. -1 ) were lower than those of normothermic individuals (1.1±0.3 mW g -1 deg. -1 ). Mass-specific rates of evaporative water loss in males were consistently higher than in females at most air temperatures and rates of water loss in torpid bats were 63±6% of normothermic values. These results suggest that male and pregnant female L. cinereus employ different thermoregulatory strategies during their spring migration. Females defend normothermic body temperatures, presumably to expedite embryonic growth, while males use torpor, presumably to minimize energy and water deficits. These variable thermoregulatory strategies may reflect continental differences in the summer distribution of the sexes.

Journal of Experimental Biology↗
USGS1974

Seismotectonic map of the Eastern United States

The purpose of a seismotectonic map is to describe the distribution of historic seismic activity in relation to geologic structures and tectonic provinces and to identify structures or regions that are characterized by consistent relations between seismic activity and structural features. An experimental study to test the feasibility of preparing such a map and its usefulness in evaluating earthquake hazards was initiated jointly by the U.S. Geological Survey and the former Seismology Division of the National Oceanic and Atmospheric Administration; financial support was provided by the U.S. Atomic Energy Commission. It was hoped that the study would develop evidence for the existence of tectonic regions or structural provinces that are useful in defining parameters of seismic hazard in relation to engineered structures. As with many experiments, this one did not produce the results envisioned at the outset, but it did result, we think, in assembling seismic and structural data useful in evaluating the distribution and origin of earthquakes in the eastern part of the United States and in delimiting areas of relative seismic activity.

Miscellaneous Field Studies Map↗
USGS2011

Summary report of responses of key resources to the 2000 Low Steady Summer Flow experiment, along the Colorado River downstream from Glen Canyon Dam, Arizona

In the spring and summer of 2000, a series of steady discharges of water from Glen Canyon Dam on the Colorado River were used to evaluate the effects of aquatic habitat stability and water temperatures on native fish growth and survival, with a special focus on the endangered humpback chub (Gila cypha), downstream from the dam in Grand Canyon. The steady releases were bracketed by peak powerplant releases in late-May and early-September. The duration and volume of releases from the dam varied between spring and summer. The intent of the experimental hydrograph was to mimic predam river discharge patterns by including a high, steady discharge in the spring and a low, steady discharge in the summer. The hydrologic experiment was called the Low Steady Summer Flow (LSSF) experiment because steady discharges of 226 m3/s dominated the hydrograph for 4 months from June through September 2000. The experimental hydrograph was developed in response to one of the U.S. Fish and Wildlife Service's Recommended and Prudent Alternatives (RPA) in its Biological Opinion of the Operation of Glen Canyon Dam Final Environmental Impact Statement. The RPA focused on the hypothesis that seasonally adjusted steady flows were dam operations that might benefit humpback chub more than the Record of Decision operations, known as Modified Low Fluctuating Flow (MLFF) operations. Condensed timelines between planning and implementation (2 months) of the experiment and the time required for logistics, purchasing, and contracting resulted in limited data collection during the high-release part of the experiment that occurred in spring. The LSSF experiment is the longest planned hydrograph that departed from the MLFF operations since Record of Decision operations began in 1996. As part of the experiment, several studies focused on the responses of physical properties related to environments that young-of-year (YOY) native fish might occupy (for example, measuring mainstem and shoreline water temperature, and quantifying useable shorelines). The part of the hydrograph that included a habitat maintenance flow (a 4-day spike at a powerplant capacity of 877 m3/s) and sustained high releases in April and May (averaging 509 m3/s) resulted in sediment export to Lake Mead, the reservoir downstream from Glen Canyon Dam, which is outside the study area. Some mid-elevation sandbar building (between 566 and 877 m3/s stage elevations) occurred from existing sediment deposits rather than from sediment inputs from tributaries during the previous winter. Low releases in the summer combined with low tributary sediment inputs resulted in minor sediment accumulation in the study area. The September habitat maintenance flow reworked accumulated sediment and resulted in increases in the area of some backwaters. The mainstem water temperatures in the reach near the Little Colorado River during the LSSF experiment varied little from previous years. Mainstem water temperatures in western Grand Canyon average 17 to 20 degrees C. During the LSSF, backwaters warmed more than other shoreline environments during the day, but most backwaters returned to mainstem water temperatures overnight. Shoreline surface water temperatures from river mile (RM) 30 to 72 varied between 9 and 28 degrees C in the middle of the day in July. These temperatures are within the optimal temperature range for humpback chub growth and spawning, which is between 15 and 24 degrees C. How surface water temperatures transfer to subsurface water temperatures is unknown. Data collection associated with the response of fish to the 2000 LSSF hydrograph focused on fish growth and abundance along the Colorado River in Grand Canyon. The target resource, humpback chub and other native fishes, did not respond in a strongly positive or strongly negative manner to the LSSF hydrograph during the sampling period, which extended from June to September 2000. In 2000, the mean total length of YOY native fishes was similar to the mean

Arizona↗
USGS2020

Continuous nitrate monitoring in groundwater and potential contribution to surface-water nitrogen loads in Mason County, Illinois

Illinois has some of the most productive farmland in the country. The use of fertilizers to improve crop production has increased, which has resulted in an increase in the concentration of nitrogen in many streams and aquifers. The U.S. Geological Survey, in cooperation with the Illinois Environmental Protection Agency, is continuously monitoring (one reading every 15 minutes) the concentration of nitrate plus nitrite, as nitrogen, in a groundwater well and assessing the potential contribution to surface-water nitrogen loads. Continuous monitoring of the nitrate concentration allows for the collection of a larger dataset in comparison to periodic or event-based sampling. This fact sheet describes the data collection methods, describes the overall experimental design, and displays data collected for the study. The analysis of continuous data improves understanding of the fate and transport of nitrate.

Illinois↗
USGS2003

Visible/near-infrared spectra of experimentally shocked plagioclase feldspars

High shock pressures cause structural changes in plagioclase feldspars such as mechanical fracturing and disaggregation of the crystal lattice at submicron scales, the formation of diaplectic glass (maskelynite), and genuine melting. Past studies of visible/ near-infrared spectra of shocked feldspars demonstrated few spectral variations with pressure except for a decrease in the depth of the absorption feature near 1250-1300 nm and an overall decrease in reflectance. New visible/near-infrared spectra (400-2500 nm) of experimentally shocked (17-56 GPa) albite- and anorthite-rich rock powders demonstrate similar trends, including the loss of minor hydrated mineral bands near 1410, 1930, 2250, and 2350 nm. However, the most interesting new observations are increases in reflectance at intermediate pressures, followed by subsequent decreases in reflectance at higher pressures. The amount of internal scattering and overall sample reflectance is controlled by the relative proportions of micro-fractures, submicron grains, diaplectic glass, and melts formed during shock metamorphism. We interpret the observed reflectance increases at intermediate pressures to result from progressively larger proportions of submicron feldspar grains and diaplectic glass. The ensuing decreases in reflectance occur after diaplectic glass formation is complete and the proportion of genuine melt inclusions increases. The pressure regimes over which these reflectance variations occur differ between albite and anorthite, consistent with thermal infrared spectra of these samples and previous studies of shocked feldspars. These types of spectral variations associated with different peak shock pressures should be considered during interpretation and modeling of visible/near-infrared remotely sensed spectra of planetary and asteroidal surfaces.

Journal of Geophysical Research E: Planets↗
USGS1981

Experimental seawater-basalt interaction at 300°C, 500 bars, chemical exchange, secondary mineral formation and implications for the transport of heavy metals

Seawater and NaCl solutions were reacted with basalt (basalt glass and diabase) for several months at 300&deg;C, 500 bars and a water/rock ratio of 10. During reaction, seawater was significantly modified, increasing in Ca, H 2 S, CO 2 . SiO 2 , K. Fe, Mn. Ba, Al and H + , and decreasing in Mg and SO 4 . Basalt glass was completely replaced by smectite, wairakite, anhydrite and hematite, and diabase was partially replaced by mixed layered smectite-chlorite, anhydrite and magnetite (?). Diabase was altered more slowly than basalt glass and the corresponding changes in seawater chemistry were less pronounced. Basalt glass reacted with a 0.45 m NaCl solution resulted in the formation of smectite, albite. truscottite and wairakite. Solutions from this experiment were characterized by a relatively high pH and dominated by Ca for Na exchange reactions. At no point in this experiment were heavy metals solubilized, in contrast to the seawater experiments. This behavior illustrates the fundamental importance of seawater chemistry to heavy-metal solubility; that is, the removal of Mg from seawater generates acidity which maintains heavy metals in solution. Apparently seawater chlorinity is not capable of enhancing heavy-metal solubility by chloride complexing. Seafloor heavy-metal deposits can result from the following: Seawater-basalt interaction at moderate temperature (&sim;-300&deg;C and high effective water/rock ratios; or at relatively high temperatures (&sim;-400&deg;C) and low (e.g.< 10) water/rock ratios.

Geochimica et Cosmochimica Acta↗