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Testing mixing models of old and young groundwater in a tropical lowland rain forest with environmental tracers

We tested three models of mixing between old interbasin groundwater flow (IGF) and young, locally derived groundwater in a lowland rain forest in Costa Rica using a large suite of environmental tracers. We focus on the young fraction of water using the transient tracers CFC‐11, CFC‐12, CFC‐113, SF 6 , 3 H, and bomb 14 C. We measured 3 He, but 3 H/ 3 He dating is generally problematic due to the presence of mantle 3 He. Because of their unique concentration histories in the atmosphere, combinations of transient tracers are sensitive not only to subsurface travel times but also to mixing between waters having different travel times. Samples fall into three distinct categories: (1) young waters that plot along a piston flow line, (2) old samples that have near‐zero concentrations of the transient tracers, and (3) mixtures of 1 and 2. We have modeled the concentrations of the transient tracers using (1) a binary mixing model (BMM) of old and young water with the young fraction transported via piston flow, (2) an exponential mixing model (EMM) with a distribution of groundwater travel times characterized by a mean value, and (3) an exponential mixing model for the young fraction followed by binary mixing with an old fraction (EMM/BMM). In spite of the mathematical differences in the mixing models, they all lead to a similar conceptual model of young (0 to 10 year) groundwater that is locally derived mixing with old (>1000 years) groundwater that is recharged beyond the surface water boundary of the system.

Water Resources Research↗

eZ flow metrics: Using z-scores to estimate deviations from natural flow in the Colorado River below Glen Canyon Dam

River flow patterns are primary drivers of lotic ecosystems, and hundreds of metrics have been developed to quantify flow attributes. Although existing metrics have been a powerful tool in designing environmental flows, they are often developed with specific resources in mind and are rarely directly comparable with each other (i.e., units are often different). Here, we focus on natural flows as the resource of interest and develop z-score metrics that measure the naturalness of regulated flows, incorporating natural means and interannual variation. These “eZ metrics” summarize whole year, subdaily, and functional flow patterns as standard deviations from natural such that their values are directly comparable. We illustrate their utility with a case study from the Colorado River downstream of Glen Canyon Dam in Arizona, USA. We calculated metrics for 1964–2022, spanning greater than 5 decades of changing water policy, hydropower generation, and flow experimentation. We evaluate four options for estimating natural baseline flows. Across metrics, we found that subdaily stage variation deviated the most from baseline. Flows to satisfy regional water policy and power demands altered metrics more than designer flows (which target specific resource outcomes), and years with low water releases were closest to natural. Most of the designer flows have not made flow patterns more natural, due to incorrect seasonal timing, small magnitude, or short duration. By explicitly considering interannual variability and quantifying how regulated flows differ from natural using standard deviations, these metrics can inform management when the goal is to restore a natural flow regime.

Colorado River basin↗

Fluorescence-based proxies for lignin in freshwater dissolved organic matter

Lignin phenols have proven to be powerful biomarkers in environmental studies; however, the complexity of lignin analysis limits the number of samples and thus spatial and temporal resolution in any given study. In contrast, spectrophotometric characterization of dissolved organic matter (DOM) is rapid, noninvasive, relatively inexpensive, requires small sample volumes, and can even be measured in situ to capture fine-scale temporal and spatial detail of DOM cycling. Here we present a series of cross-validated Partial Least Squares models that use fluorescence properties of DOM to explain up to 91% of lignin compositional and concentration variability in samples collected seasonally over 2 years in the Sacramento River/San Joaquin River Delta in California, United States. These models were subsequently used to predict lignin composition and concentration from fluorescence measurements collected during a diurnal study in the San Joaquin River. While modeled lignin composition remained largely unchanged over the diurnal cycle, changes in modeled lignin concentrations were much greater than expected and indicate that the sensitivity of fluorescence-based proxies for lignin may prove invaluable as a tool for selecting the most informative samples for detailed lignin characterization. With adequate calibration, similar models could be used to significantly expand our ability to study sources and processing of DOM in complex surface water systems.

Journal of Geophysical Research G: Biogeosciences↗

Impacts of precipitation seasonality and ecosystem types on evapotranspiration in the Yukon River Basin, Alaska

Evapotranspiration (ET) is the largest component of water loss from terrestrial ecosystems; however, large uncertainties exist when estimating the temporal and spatial variations of ET because of concurrent shifts in the magnitude and seasonal distribution of precipitation as well as differences in the response of ecosystem ET to environmental variabilities. In this study, we examined the impacts of precipitation seasonality and ecosystem types on ET quantified by eddy covariance towers from 2002 to 2004 in three ecosystems (grassland, deciduous broadleaf forest, and evergreen needleleaf forest) in the Yukon River Basin, Alaska. The annual precipitation changed greatly in both magnitude and seasonal distribution through the three investigated years. Observations and model results showed that ET was more sensitive to precipitation scarcity in the early growing season than in the late growing season, which was the direct result of different responses of ET components to precipitation in different seasons. The results demonstrated the importance of seasonal variations of precipitation in regulating annual ET and overshadowing the function of annual precipitation. Comparison of ET among ecosystems over the growing season indicated that ET was largest in deciduous broadleaf, intermediate in evergreen needleleaf, and lowest in the grassland ecosystem. These ecosystem differences in ET were related to differences in successional stages and physiological responses.

Water Resources Research↗

Surveys of environmental DNA (eDNA): a new approach to estimate occurrence in Vulnerable manatee populations

Environmental DNA (eDNA) detection is a technique used to non-invasively detect cryptic, low density, or logistically difficult-to-study species, such as imperiled manatees. For eDNA measurement, genetic material shed into the environment is concentrated from water samples and analyzed for the presence of target species. Cytochrome b quantitative PCR and droplet digital PCR eDNA assays were developed for the 3 Vulnerable manatee species: African, Amazonian, and both subspecies of the West Indian (Florida and Antillean) manatee. Environmental DNA assays can help to delineate manatee habitat ranges, high use areas, and seasonal population changes. To validate the assay, water was analyzed from Florida’s east coast containing a high-density manatee population and produced 31564 DNA molecules l -1 on average and high occurrence (ψ) and detection (p) estimates (ψ = 0.84 [0.40-0.99]; p = 0.99 [0.95-1.00]; limit of detection 3 copies µl -1 ). Similar occupancy estimates were produced in the Florida Panhandle (ψ = 0.79 [0.54-0.97]) and Cuba (ψ = 0.89 [0.54-1.00]), while occupancy estimates in Cameroon were lower (ψ = 0.49 [0.09-0.95]). The eDNA-derived detection estimates were higher than those generated using aerial survey data on the west coast of Florida and may be effective for population monitoring. Subsequent eDNA studies could be particularly useful in locations where manatees are (1) difficult to identify visually (e.g. the Amazon River and Africa), (2) are present in patchy distributions or are on the verge of extinction (e.g. Jamaica, Haiti), and (3) where repatriation efforts are proposed (e.g. Brazil, Guadeloupe). Extension of these eDNA techniques could be applied to other imperiled marine mammal populations such as African and Asian dugongs.

Endangered Species Research↗

Assessment of public and private land cover change in the United States from 1985–2018

An assessment of annual land cover on publicly and privately managed lands across the conterminous United States (CONUS) from 1985–2018 was performed, including land cover conversions within their management category, to inform future policy and land-use decision-making in natural resource management. Synthesizing land cover data with land management delineations aids our ability to address effects of land management decisions by public or private entities. The U.S. Geological Survey (USGS) Protected Areas Database of the United States (PAD-US) version 2.1 data delineate land management categories and enable examination of land cover composition and change using the USGS Land Change Monitoring, Assessment, and Projection (LCMAP) reference data. Average composition of our delineated CONUS results using LCMAP land cover classes is 40% Grass/Shrub (GS), 29% Tree Cover (TC), 18% Cropland (CP), 5% Developed (DV), 5% Wetland (WL), 1.8% Water (WR), and 0.9% Barren (BN). Private (public) land is composed of 35% (52%) GS, 27% (36%) TC, 25% (1%) CP, 7% (1%) DV, 5% (5%) WL, 2% (2%) WR, and less than 1% (3%) BN. Land cover change averaged less than 1% per year. The largest net percentage gains across CONUS were in DV land and GS, and the greatest net losses were in CP and TC. Approximately 73% of CONUS is private land and, thus, land cover change across CONUS is largely a reflection of private land change dynamics. Private compositional changes show net gains from 1985–2018 in DV (2.3%), WR (0.2%), and GS (0.1%) classes, while net losses occurred in CP (−1.9%), TC (−0.6%), WL (−0.1%), and BN (−0.01%). Public land cover changes show net gains in GS (1%), DV (0.2%), WR (0.01%), WL (0.05%), and BN (0.1%) classes, and net losses in CP (−0.3%) and TC (−1%). Our study reveals connections between land cover conversion and various policy and socioeconomic decisions through time.

Environmental Research Communications↗

Evaluating large wood additions as a scalable method of urban stream restoration

Urbanization is associated with increased erosion and habitat homogenization in stream ecosystems. This habitat degradation often has biological consequences, such as decreased species richness. Conventional stream restoration practices are costly, and projects are limited to small areas with easy access. A scalable, low-cost method of stream restoration is needed to address the widespread degradation occurring in urban streams. Large wood (LW) is an important element in stream ecosystems that is typically abundant in forested watersheds but scarce in urban streams. LW can reduce water velocities, generate pool habitat, decrease erosion, and provide cover for aquatic organisms. In this study, we performed experimental LW installations to assess the capacity of LW restoration to improve habitat and reduce sediment transport in an urban headwater stream in Cincinnati, Ohio. We tracked the geomorphic effects of these installations using a before-after-control-impact study design in four 60-m reaches, two treatment and two control, over a 1.5-year period to investigate the following questions: (1) Will unanchored LW additions remain stable in a flashy urban stream? (2) Will LW additions increase the availability of pool habitat? (3) Will wood additions increase bed stability and modify sediment size distributions? We found that LW installations rapidly increased pool habitat availability (size) around stable jams, but a majority of the LW jams were frequently mobilized and reconfigured by high-flow events. LW additions had no significant impact on the probability of stream bed mobilization, likely due to the instability of LW; however, the distance particles traveled once mobilized significantly decreased. While LW additions can increase the availability of pool habitat in urban headwater streams, further investigation is needed to understand the stability of such structures and the environmental context where these additions will be most beneficial.

Ohio↗

Speaking the same language: Can the Sustainable Development Goals translate the needs of inland fisheries into irrigation decisions?

Irrigated agriculture and inland fisheries both make important contributions to food security, nutrition, livelihoods, and well-being. Typically, in modern irrigation systems, these components operate independently. Some practices, commonly associated with water use and intensification of crop production, can be in direct conflict with and have adverse impacts on fisheries. Food security objectives may be compromised if fish are not considered in the design phases of irrigation systems. The 2030 Agenda for Sustainable Development provides a framework that can serve as a backdrop to help integrate both sectors in policy discussions and optimize their contributions to achieving the Sustainable Development Goals (SDGs). Inland fisheries systems do play an important role in supporting many SDG objectives, but these contributions can sometimes be at odds with irrigated agriculture. Using case studies of two globally important river catchments, the Lower Mekong and Murray-Darling Basins, we highlight the conflicts and opportunities for improved outcomes between irrigated agriculture and inland fisheries. We explore SDG 2 (Zero Hunger) as a path to advance our irrigation systems as a means to benefit both agriculture and inland fisheries, preserving biodiversity and enhancing the economic, environmental, and social benefits they both provide to people.

Marine and Freshwater Research↗

A multidisciplinary framework to derive global river reach classifications at high spatial resolution

Projected climate and environmental change are expected to increase the pressure on global freshwater resources. To prepare for and cope with the related risks, stakeholders need to devise plans for sustainable management of river systems, which in turn requires the identification of management-appropriate operational units, such as groups of rivers that share similar environmental and biological characteristics. Ideally, these units are of a manageable size, and are biotically or abiotically distinguishable across a variety of river types. Here, we aim to address this need by presenting a new global river classification framework (GloRiC) to establish a common vocabulary and standardized approach to the development of globally comprehensive and integrated river classifications that can be tailored to different goals and requirements. We define the GloRiC conceptual framework based on five categories of variables: (1) hydrology; (2) physiography and climate; (3) fluvial geomorphology; (4) water chemistry; and (5) aquatic biology. We then apply the framework using hydro-environmental attributes provided by a seamless high-resolution river reach database to create initial instances of three sub-classifications (hydrologic, physio-climatic, and geomorphic) which we ultimately combine into 127 river reach types at the global scale. These supervised classifications utilize a mix of statistical analyses and expert interpretation to identify the classifier variables, the number of classes, and their thresholds. In addition, we also present an unsupervised, multivariable k-means statistical clustering of all river reaches into 30 groups. These first-of-their-kind global river reach classifications at high spatial resolution provide baseline information for a total of 35.9 million kilometers of rivers that have been assessed in this study, and are expected to be particularly useful in remote or data-poor river basins. The GloRiC framework and associated data are primarily designed for broad and rapid applicability in assessments that require stratified analyses of river ecosystem conditions at global and regional scales; smaller-scale applications could follow the same conceptual framework yet use more detailed data sources.

Environmental Research Letters↗

Concentrations and patterns of perfluoroalkyl acids in Georgia, USA surface waters near and distant to a major use source

Perfluoroalkyl acids (PFAAs) are widespread contaminants emanating from, among other sources, the production/degradation of fluorinated chemicals used in surface repellant applications, such as carpet manufacturing. The goal of the present study was to assess the concentrations of PFAAs, including perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA), perfluorononanoic acid (PFNA), perfluorodecanoic acid (PFDA), perfluoroundecanoic acid (PFUA), and perfluorooctane sulfonamide (PFOSA), in surface waters both near a wastewater land application system (LAS) in Dalton (GA, USA), home to North America's largest carpet manufacturing site, and distant to this location (Altamaha River, GA, USA) to understand the fate of PFAAs in freshwater. Levels of PFAAs were high in the Conasauga River (GA, USA) downstream of the LAS (PFOA, 253-1,150 ng/L; PFOS, 192-318 ng/L; PFNA, 202-369 ng/L; PFDA, 30.1-113 ng/L; PFUA, 58.0-99.2 ng/L; PFOSA, 162-283 ng/L) and in streams and ponds in Dalton (PFOA, 49.9-299 ng/L; PFOS, 15.8-120 ng/L), and were among the highest measured at a nonspill or directrelease location. Perfluoroalkyl acids in the Altamaha River were much lower (PFOA, 3.0-3.1 ng/L; PFOS, 2.6-2.7 ng/L), but were a source of PFAAs to Georgia's estuaries. A preliminary hazard assessment indicated that concentrations of PFOS at two sites in the Conasauga River exceeded the threshold effect predicted for birds consuming aquatic organisms that are exposed continuously to the PFOS levels at these sites. Assuming that toxicity for all PFAAs quantified is equal to that of PFOS, the sum total PFAAs at two sites within the Conasauga River exceeded PFOS thresholds for aquatic and avian species, warranting additional research. ?? 2008 SETAC Printed in the USA.

Environmental Toxicology and Chemistry↗

Water and bed-material quality of selected streams and reservoirs in the Research Triangle area of North Carolina, 1988-94

The Triangle Area Water Supply Monitoring Project was formed by a consortium of local governments and governmental agencies in cooperation with the U.S. Geological Survey to supplement existing data on conventional pollutants, nutrients, and metals to enable eventual determination of long-term trends; to examine spatial differences among water supplies within the region, especially differences between smaller upland sources, large multipurpose reservoirs, and run-of-river supplies; to provide tributary loading inlake data for predictive modeling of Falls of the Neuse and B. Everett Jordan reservoirs; and to establish a database for synthetic organic compounds. Water-quality sampling began in October 1988 at 35 sites located on area run-of-river and reservoir water supplies and their tributaries. Sampling has continued through 1994. Samples were analyzed for major ions, nutrients, trace metals, pesticides, and semivolatile and volatile organic compounds. Monthly concentration data, high-flow concentration data, and data on daily mean streamflow at most stream sites were used to calculate loadings of nitrogen, phosphorus, suspended sediment, and trace metals to reservoirs. Stream and lake sites were assigned to one of five site categories-- (1) rivers, (2) large multipurpose reservoirs, (3) small water-supply reservoirs, (4) streams below urban areas and wastewater-treatment plants, and (5) headwater streams--according to general site characteristics. Concentrations of nitrogen species, phosphorus species, and selected trace metals were compared by site category using nonparametric analysis of variance techniques and qualitatively (trace metals). Wastewater-treatment plant effluents and urban runoff had a significant impact on water quality compared to reservoirs and headwater streams. Streams draining these areas had more mineralized water than streams draining undeveloped areas. Moreover, median nitrogen and nitrite plus nitrate concentrations were significantly greater than all other site categories. Phosphorus was significantly greater than for reservoir sites or headwater streams. Few concentrations of trace metals were greater than the minimum reporting limit, and U.S. Environmental Protection Agency drinking-water standards were rarely exceeded. Detections, when they occurred, were most frequent for sites below urban areas and wastewater-treatment plant effluents. A small number of samples for analysis of acetanilide, triazine, carbamate, and chlorophenoxy acid pesticides indicate that some of these compounds are generally present in area waters in small concentrations. Organochlorine and organophosphorus pesticides are ubiquitous in the study area in very small concentrations. Trihalomethanes were detected at sites below urban areas and wastewater-treatment plants. Otherwise, volatile organic compounds and semivolatile compounds were generally not detected. Suspended-sediment, nitrogen, phosphorus, lead, and zinc loads into Falls Lake, Jordan Lake, University Lake, Cane Creek Reservoir, Little River Reservoir, and Lake Michie were calculated. In general, reservoirs act as traps for suspended sediment and constituents associated with suspended sediments. During 1989-94, annual suspended-sediment load to Falls Lake ranged from 29,500 to 88,200 tons. Because Lake Michie trapped from 83 to 93 percent of the suspended sediment delivered by Flat River, Flat River is a minor contributor of suspended sediment to Falls Lake. Yields of suspended sediment from Little River, Little Lick Creek, and Flat River Basins were between 184 and 223 tons per square mile and appear to have increased increased slightly from yields reported in a study for the period 1970-79. Annual suspended-sediment load to Jordan Lake ranged from 271,000 to 622,000 tons from 1989 through 1994 water years. The Haw River contributed more than 75 percent of the tota load to Jordan Lake. The suspended-sediment yields for Haw River and Northeast Cree

North Carolina↗

Transport of chemical and microbial compounds from known wastewater discharges: Potential for use as indicators of human fecal contamination

The quality of drinking and recreational water is currently (2005) determined using indicator bacteria. However, the culture tests used to analyze for these bacteria require a long time to complete and do not discriminate between human and animal fecal material sources. One complementary approach is to use chemicals found in human wastewater, which would have the advantages of (1) potentially shorter analysis times than the bacterial culture tests and (2) being selected for human-source specificity. At 10 locations, water samples were collected upstream and at two successive points downstream from a wastewaster treatment plant (WWTP); a treated effluent sample was also collected at each WWTP. This sampling plan was used to determine the persistence of a chemically diverse suite of emerging contaminants in streams. Samples were also collected at two reference locations assumed to have minimal human impacts. Of the 110 chemical analytes investigated in this project, 78 were detected at least once. The number of compounds in a given sample ranged from 3 at a reference location to 50 in a WWTP effluent sample. The total analyte load at each location varied from 0.018 μg/L at the reference location to 97.7 μg/L in a separate WWTP effluent sample. Although most of the compound concentrations were in the range of 0.01−1.0 μg/L, in some samples, individual concentrations were in the range of 5−38 μg/L. The concentrations of the majority of the chemicals present in the samples generally followed the expected trend:  they were either nonexistent or at trace levels in the upstream samples, had their maximum concentrations in the WWTP effluent samples, and then declined in the two downstream samples. This research suggests that selected chemicals are useful as tracers of human wastewater discharge.

Environmental Science & Technology↗

Riparian vegetated area in pre-dam, post-dam, and environmental flow periods in Canyonlands National Park from 1940 to 2022

The Upper Colorado River Basin is the principal water supply of the western United States and includes a series of canyons that provide habitat for disproportionate numbers of flora and fauna. Following the closing of Flaming Gorge and Blue Mesa dams in 1963 and 1966, decreases in peak flows and elevated base flows allowed extensive vegetation encroachment, channel narrowing, and channel simplification. Since 1992, reservoir releases have been modified to increase the ratio of peak to base flows for environmental reasons, including protection of endangered fish. We used remote imagery from 1940 to 2022 to examine rates of vegetation encroachment along three river reaches in Canyonlands National Park during the pre-dam (1940–1966), post-dam (1967–1992), and environmental flows (1993–2022) periods. We found an increase in the vegetated area along the Colorado and Green Rivers upstream of their confluence since 1940. We documented a 6.1% and 4.0% increase in vegetated area in the post-dam period and a 19.5% and 6.5% increase in vegetated area in the environmental flows period on the Colorado and Green Rivers, respectively. The Cataract Canyon reach (Colorado River below the confluence) has been stable since 1966. All three river reaches showed the slowest period of vegetation encroachment, indicative of channel narrowing, in the last 16 years of environmental flows that included a large peakflow in 2011. Environmental flows that mimic the natural hydrograph have not reversed decreases in peak flow and channel width, due in part to decreasing runoff and increasing flow diversion. Flow alterations that reduce the spring peak could cause further narrowing.

Utah↗

New tools for a legacy problem: How isotope tracers inform area of concern actions in the St. Louis River in Lake Superior

Numerous mercury (Hg) sources can contribute to biological burdens within the Great Lakes, including atmospheric deposition (e.g., precipitation), non-point source land runoff (e.g., watershed), and legacy contamination. Due to these different environmental entry points, it is often difficult to ascertain if legacy Hg contamination contributes to contemporary fish consumption advisories within Areas of Concern (AOCs), as designated by the United States-Canada Great Lakes Water Quality Agreement. In this study, we aimed to assess the contributions of legacy Hg to sediments in nearshore wetland habitats and co-located prey items (dragonfly larvae and yellow perch) within the St. Louis River AOC using Hg stable isotopes. We observed that nearshore sediments had the same Hg source portfolio as previously examined main channel sites. Furthermore, this data confirmed that two major Hg sources were contributing to sediments within nearshore regions of the St. Louis River AOC: legacy and watershed Hg. The contribution of legacy Hg was estimated in biota and demonstrated that up to 64% of the Hg in fish tissue in the lower estuary (St. Louis Bay) was from legacy sources, but that this percentage declined substantially when examining upstream regions of the AOC. These data indicate the influence of legacy Hg to the food web varies spatially within the St. Louis River. We further found that watershed Hg sources are an important Hg contributor to the St. Louis River, which likely applies to other impacted and unimpacted tributaries across the Great Lakes region.

Minnesota, Wisconsin↗

Leachability of uranium and other elements from freshly erupted volcanic ash

A study of leaching of freshly erupted basaltic and dacitic air-fall ash and bomb fragment samples, unaffected by rain, shows that glass dissolution is the dominant process by which uranium is initially mobilized from air-fall volcanic ash. Si, Li, and V are also preferentially mobilized by glass dissolution. Gaseous transfer followed by fixation of soluble uranium species on volcanic-ash particles is not an important process affecting uranium mobility. Gaseous transfer, however, may be important in forming water-soluble phases, adsorbed to ash surfaces, enriched in the economically and environmentally important elements Zn, Cu, Cd, Pb, B, F, and Ba. Quick removal of these adsorbed elements by the first exposure of freshly erupted ash to rain and surface water may pose short-term hazards to certain forms of aquatic and terrestrial life. Such rapid release of material may also represent the first step in transportation of economically important elements to environments favorable for precipitation into deposits of commercial interest. Ash samples collected from the active Guatemalan volcanoes Fuego and Pacaya (high-Al basalts) and Santiaguito (hornblende-hypersthene dacite); bomb fragments from Augustine volcano (andesite-dacite), Alaska, and Heimaey (basalt), Vestmann Islands, Iceland; and fragments of "rhyolitic" pumice from various historic eruptions were subjected to three successive leaches with a constant water-to-ash weight ratio of 4:1. The volcanic material was successively leached by: (1) distilled-deionized water (pH = 5.0-5.5) at room temperature for 24 h, which removes water-soluble gases and salts adsorbed on ash surfaces during eruption; (2) dilute HCl solution (pH = 3.5-4.0) at room temperature for 24 h, which continues the attack initiated by the water and also attacks acid-soluble sulfides and oxides; (3) a solution 0.05 M in both Na,CO, and NaHCO, (pH = 9.9) at 80°C for one week, which preferentially dissolves volcanic glass. The first two leaches mimic interaction of ash with rain produced in the vicinity of an active eruption. The third leach accelerates the effect of prolonged contact of volcanic ash with alkaline ground water present during ash diagenesis.

Journal of Volcanology and Geothermal Research↗

Recreational water quality response to a filtering barrier at a Great Lakes beach

Recent research has sought to determine the off- or onshore origin of fecal indicator bacteria (FIB) in order to improve local recreational water quality. In an effort to reduce offshore contamination, a filtering barrier (FB) was installed at Calumet Beach, Lake Michigan, Chicago, IL. A horseshoe-shaped curtain (146 m long, 0.18 mm apparent opening size, 1.5–1.6 m deepest point) was designed to exclude FIB containing or promoting debris and thus reduce the number of swimming advisories during the examination period of July through September 2012. Mean water Escherichia coli concentrations were significantly lower at southern transects (S; outside FB) than at transects within the FB (WN) and at northern transects (N; outside FB) (1.45 log (MPN)/100 ml vs. 1.74 and 1.72, respectively, p < 0.05, n = 234). Turbidity was significantly higher at the WN transects (p < 0.001, n = 233), but it tended to increase throughout the sampling season within and outside the FB. E. coli in adjacent foreshore sand was significantly lower at the WN transects. A combination of factors might explain higher E. coli and turbidity within the FB including increased sediment resuspension, trapped algae, shallowing within the FB, and large lake hydrodynamic processes. This remediation approach may find better use in a different hydrodynamic setting, but the results of this experiment provide insight on sources of contamination and nearshore dynamics that may direct future beach management strategies.

Illinois↗

Predicting flood damage probability across the conterminous United States

Floods are the leading cause of natural disaster damages in the United States, with billions of dollars incurred every year in the form of government payouts, property damages, and agricultural losses. The Federal Emergency Management Agency oversees the delineation of floodplains to mitigate damages, but disparities exist between locations designated as high risk and where flood damages occur due to land use and climate changes and incomplete floodplain mapping. We harnessed publicly available geospatial datasets and random forest algorithms to analyze the spatial distribution and underlying drivers of flood damage probability caused by excessive rainfall and overflowing water bodies across the conterminous United States. From this, we produced the first spatially complete map of flood damage probability for the nation, along with spatially explicit standard errors for four selected cities. We trained models using the locations of historical reported flood damage events ( n = 71,434) and a suite of geospatial predictors (e.g., flood severity, climate, socio-economic exposure, topographic variables, soil properties, and hydrologic characteristics). We developed independent models for each hydrologic unit code level 2 watershed and generated a flood damage probability for each 100-m pixel. Our model classified damage or no damage with an average area under the curve accuracy of 0.75; however, model performance varied by environmental conditions, with certain land cover classes (e.g., forest) resulting in higher error rates than others (e.g., wetlands). Our results identified flood damage probability hotspots across multiple spatial and regional scales, with high probabilities common in both inland and coastal regions. The highest flood damage probabilities tended to be in areas of low elevation, in close proximity to streams, with extreme precipitation, and with high urban road density. Given rapid environmental changes, our study demonstrates an efficient approach for updating flood damage probability estimates across the nation.

Environmental Research Letters↗

Distributions of uronic acids and O-methyl sugars in sinking and sedimentary particles in two coastal marine environments

Although recent research has indicated that bacteria may contribute an important fraction of biochemical residues in terrestrial and marine environments, it is difficult for geochemists to identify contributions from these ubiquitous and biochemically diverse organisms. Previous studies have suggested uronic acids and O -methyl sugars may be useful indicators of microbial abundance and activity, but have been limited primarily to analyses of a small number of isolated samples. We report here comparative distributions of O -methyl sugars, uronic acids, and aldoses in sediment trap material and sediments from Dabob Bay, WA and nearby Saanich Inlet, BC, where temporal and spatial trends may be used together with well-established patterns in other biochemicals to identify bacterial contributions against the background of other carbohydrate sources. O -methyl sugars and uronic acids were important contributors to the overall flux and burial of polysaccharide material in Dabob Bay and Saanich Inlet, composing ≤12 wt% of the total carbohydrate yields from sediment trap and sediment samples. O -methyl sugars accounted for an average of 5% of the carbohydrate yields from sediment trap materials and sediments, but were found rarely and only in low abundance in vascular plant tissues, phytoplankton, and kelp. In contrast, uronic acids were abundant products of sediment trap material and sediments, as well as vascular plant tissues, where in some cases they predominated among all carbohydrates. Uronic acid abundance in sediment trap material averaged 3% and ranged to >6% of total carbohydrate yields. The persistence of total minor sugar yields in water column collections from Dabob Bay throughout the seasonal cycle indicated they had a primary source that was not directly related to plankton bloom cycles nor pulsed inputs of vascular plant remains. Subsurface maxima in total minor sugar yields (and several individual components) within sediment cores from both sites indicate in situ sedimentary sources. Taken together, the observed environmental distributions strongly suggest that the minor sugar abundances in Dabob Bay and Saanich Inlet were controlled by in situ microbial production.

British Columbia, Washington↗