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Observed and modeled mercury and dissolved organic carbon concentrations and loads at control structure S-12D, Florida Everglades, 2013–17

Mercury (Hg) has been a contaminant of concern for several decades in South Florida, particularly in the Florida Everglades. The transport and bioavailability of Hg in aquatic systems is intimately linked to dissolved organic carbon (DOC). In aquatic systems, Hg can be converted to methylmercury (MeHg), which is the form of Hg that bioaccumulates in food webs. The bioaccumulation of MeHg poses significant health risks to wildlife and humans. Fish consumption advisories triggered by elevated Hg levels first appeared in the 1980s in South Florida. Multiple structures regulate freshwater distribution to Everglades National Park, including S-12D. This report summarizes seasonal and annual concentration and load data from late September 2013 to April 2017 for the total of (1) filter-passing total mercury (FTHg), (2) filter-passing methylmercury (FMeHg), (3) particulate total mercury (PTHg), (4) particulate methylmercury (PMeHg) and, (5) DOC discharged through control structure S-12D. The loads of Hg fractions and DOC at control structure S-12D were determined by pairing discharge data with constituent concentrations estimated by empirical models based on surrogate in situ water-quality measurements. Calculated concentrations of DOC ranged from 12.8 milligrams per liter (mg/L) to 27.9 mg/L with a mean of 18.8 mg/L during the study period. Annual loads of DOC ranged from 3,950 tons in 2015 to 10,900 tons in 2016. DOC loads increased linearly with an increase in flow, and the highest monthly DOC load of 1,630 tons was observed in February 2016. Calculated concentrations of FTHg ranged from 0.35 to 1.55 nanograms per liter (ng/L) with a mean of 0.85 ng/L during the study period. Calculated concentrations of FMeHg ranged from 0.06 ng/L to 0.24 ng/L with a mean of 0.14 ng/L during the study period. Generally, FTHg and FMeHg con­centrations were lower during periods of decreased flow and higher during periods of increased flow. Calculated PTHg concentrations ranged from 0.09 ng/L to 4.19 ng/L with a mean of 0.58 ng/L during the study period. Calculated PMeHg concentrations ranged from below the limit of detection <0.01 ng/L to 0.29 ng/L with a mean of 0.03 ng/L during the study period. Loads of Hg were often zero or lowest from November to May, owing to the lack of flow or low-flow conditions. FTHg and FMeHg loads increased linearly with an increase in flow and typically were highest from June to October. During periods of increasing flow or following changes in gate operations, PTHg and PMeHg constituted a greater percentage of the total Hg load. Annual loads of total Hg (filter-passing and particulate) ranged from 254 grams in 2015 to 658 grams in 2016. FTHg was the predominant contributor to the total Hg load. Information presented herein provides the first assessment of DOC and Hg loads to Everglades National Park through control structure S-12D using continuous in situ measurements of discharge and constituent surrogates and compares the sur­rogate model approach to loads calculated from monthly sam­pling. Analysis of calculated and observed loads demonstrates the significance of flow data on calculating constituent loads.

Florida

Estimating flood discharges at selected annual exceedance probabilities for unregulated, rural streams in Vermont, 2023

This report provides estimates of flood discharge at selected annual exceedance probabilities (AEPs) for streamgages in and adjacent to Vermont and equations for estimating flood discharges at AEPs of 50-, 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent (recurrence intervals of 2-, 5-, 10-, 25-, 50-, 100-, and 500-years, respectively) for ungaged, unregulated, rural streams in Vermont with drainage areas between 0.47 and 851 square miles. The equations were developed using generalized least-squares regression and flood-frequency and drainage-basin characteristics from 156 streamgages. Flood-frequency analyses were completed using data through the 2023 water year. The drainage-basin characteristics used as explanatory variables in the regression equations are drainage area, percentage of wetland area, and basin-wide mean of the average annual precipitation. The average standard errors of prediction used to estimate flood discharges at the 50-, 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent AEP with these equations are 34.9, 37.1, 38.2, 41.6, 43.8, 46.0, 49.1, and 53.2 percent, respectively. Flood discharges at selected AEPs for streamgages were computed using the Expected Moments Algorithm. Techniques used to adjust an AEP discharge computed from a streamgage record with results from the regression equations and to estimate flood discharge at a selected AEP for an ungaged site upstream or downstream from a streamgage using a drainage-area adjustment are both described. The final regression equations and the flood-discharge frequency data used in this study will be available in StreamStats. StreamStats is an internet-based application that provides automated regression-equation solutions for user-selected sites on streams.

Vermont

Gas shale/oil shale

The production of natural gas from shales continues to increase in North America, and shale gas exploration is on the rise in other parts of the world since the previous report by this committee was published by American Association of Petroleum Geologists, Energy Minerals Division (2009). For the United States, the volume of proved reserves of natural gas increased 11% from 2008 to 2009, the increase driven largely by shale gas development (Energy Information Administration 2010c). Furthermore, shales have increasingly become targets of exploration for oil and condensate as well as gas, which has served to greatly expand their significance as ‘‘unconventional’’ petroleum reservoirs. This report provides information about specific shales across North America and Europe from which gas (biogenic or thermogenic), oil, or natural gas liquids are produced or is actively being explored. The intent is to reflect the recently expanded mission of the Energy Minerals Division (EMD) Gas Shales Committee to serve as a single point of access to technical information on shales regardless of the type of hydrocarbon produced from them. The contents of this report were drawn largely from contributions by numerous members of the EMD Gas Shales Advisory Committee, with much of the data being available from public websites such as state or provincial geological surveys or other public institutions. Shales from which gas or oil is being produced in the United States are listed in alphabetical order by shale name. Information for Canada is presented by province, whereas for Europe, it is presented by country.

Natural Resources Research

Rocky Mountain snowpack chemistry at selected sites for 2001

Because regional-scale atmospheric deposition data in the Rocky Mountains are sparse, a program was designed by the U.S. Geological Survey, in cooperation with the National Park Service, U.S. Department of Agriculture Forest Service, and other agencies, to more thoroughly determine the chemical composition of precipitation and to identify sources of atmospherically deposited contaminants in a network of high-elevation sites. Samples of seasonal snowpacks at 57 geographically distributed sites, in a regional network from New Mexico to Montana, were collected and analyzed for major ions (including ammonium, nitrate, and sulfate), alkalinity, and dissolved organic carbon during 2001. Sites selected in this report have been sampled annually since 1993, enabling identification of increases or decreases in chemical concentrations from year to year. Spatial patterns in snowpack-chemical data for concentrations of ammonium, nitrate, and sulfate indicate that concentrations of these acid precursors in less developed areas of the region are lower than concentrations in the heavily developed areas. Results for the 2001 snowpack-chemistry analyses, however, indicate increases in concentrations of ammonium and nitrate in particular at sites where past concentrations typically were lower. Since 1993, concentrations of nitrate and sulfate were highest from snowpack samples in northern Colorado that were collected from sites adjacent to the Denver metropolitan area to the east and the coal-fired powerplants to the west. In 2001, relatively high concentrations of nitrate (12.3 to 23.0 microequivalents per liter (?eq/L) and sulfate (7.7 to 12.5 ?eq/L) were detected in Montana and Wyoming. Ammonium concentrations were highest in north-central Colorado (14.5 to 16.9 ?eq/L) and southwestern Montana (12.8 to 14.2 ?eq/L).

Open-File Report

Water, ice, and meteorological measurements at South Cascade glacier, Washington, balance year 2003

Winter snow accumulation and summer snow and ice ablation were measured at South Cascade Glacier, Washington, to estimate glacier mass-balance quantities for balance year 2003. The 2003 glacier-average maximum winter snow balance was 2.66 meters water equivalent, which was about equal to the average of such balances for the glacier since balance year 1959. The 2003 glacier summer balance (-4.76 meters water equivalent) was the most negative reported for the glacier, and the 2003 net balance (-2.10 meters water equivalent), was the second-most negative reported. The glacier 2003 annual (water year) balance was -1.89 meters water equivalent. The area of the glacier near the end of the balance year was 1.89 square kilometers, a decrease of 0.03 square kilometer from the previous year. The equilibrium-line altitude was higher than any part of the glacier; however, because snow remained along part of one side of the upper glacier, the accumulation-area ratio was 0.07. During September 13, 2002-September 13, 2003, the glacier terminus retreated at a rate of about 15 meters per year. Average speed of surface ice, computed using a series of vertical aerial photographs dating back to 2001, ranged from 2.2 to 21.8 meters per year. Runoff from the subbasin containing the glacier and from an adjacent non-glacierized basin was gaged during part of water year 2003. Air temperature, precipitation, atmospheric water-vapor pressure, wind speed, and incoming solar radiation were measured at selected locations on and near the glacier. Summer 2003 at the glacier was among the warmest for which data are available.

Scientific Investigations Report

Variation in annual run-off in the Rocky Mountain region: Chapter A in Contributions to the hydrology of the United States, 1923-1924

Records of run-off in the Rocky Mountain States since the nineties and for a few stations since the eighties afford a means of studying the variation in the annual run-off in this region. The data presented in this report show that the variation in annual run-off differs in different areas in the Rocky Mountain region, owing to the differences in the sources of the precipitation in these areas. Except in the drainage basins of streams in northern Montana the year of lowest run-off shown by the records was 1902, when the run-ff at one station was only 36 per cent of the mean run-ff for the periods covered by the several records available. The percentage variation of run-ff for streams in different parts of Colorado is less for any one year than that for streams in the mountain region as a whole, and for streams in the same major drainage basin the annual variation is markedly similar. The influence of topography upon variation in annual run-ff for streams in Colorado is marked, the streams that rise in the central mountain region having a smaller range in variation than the streams that rise on the eastern or western edges of the central mountain mass. The streams that rise on the plains just east of the mountains have a greater variation than those of any of the mountain groups. The ratio of any 10-year mean to the mean for the entire period covered by the records ranges from 72 to 133 per cent. For the South Platte, Arkansas, and Rio Grande the run-off during the nineties was below the normal, but since about 1903 it has been above normal. For the Cache la Poudre low-water periods occurred during the eighties and from 1905 to 1922, but during the nineties the run-off was above the normal.

Colorado;Montana;Wyoming

Estimating peak-flow quantiles for selected annual exceedance probabilities in Illinois

This report presents the methods, results, and applications of an updated flood-frequency study for the State of Illinois. This study, which uses data through September 2017, updates two previous studies that used data through 1999 and 2009, respectively. Flood-frequency estimates are used for a variety of land-use planning and infrastructure design purposes, including for the hydraulic design of bridges. The flood frequencies presented are the stream discharges (or quantiles) that are exceeded each year with a given probability, called the annual exceedance probability (AEP). Estimates are provided for eight AEPs: 0.5, 0.2, 0.1, 0.04, 0.02, 0.01, 0.005, and 0.002. The basic data used are the annual maximum discharges (peak flows) at streamgages in and near Illinois and the measurable physical properties (basin characteristics) of the basins upstream from those streamgages. The logarithms of the peak flow records at qualifying streamgages were fit to the Pearson Type 3 distribution using federally recommended methods, providing one of the two primary products of the study, which is the set of peak-flow quantiles at the streamgages and their uncertainties. The other primary product is sets of equations, determined by least-squares regression, that relate the peak-flow quantiles and the basin characteristics. There is one set of equations for each of Illinois’ seven hydrologic regions, and, for each region, one equation for each AEP. These regional equations allow the estimation of peak-flow quantiles at ungaged locations throughout the state and their uncertainties. A set of illustrative example applications is provided, and tables of all results at all study streamgages and regions are provided in associated data releases. The study results are also being made available in a web application, StreamStats.

Illinios

Proceedings of the twentieth annual meeting of the Society for Organic Petrology

The Society for Organic Petrology (TSOP; pronounced "Tee'-sop") was established in 1984 to consolidate and foster the organizational activities of scientists and engineers involved with coal petrology, kerogen petrology, organic geochemistry, and related disciplines. The following report, "Proceedings of the Twentieth Annual Meeting of The Society for Organic Petrology" (ISSN 1060-7250), features technical talks, poster presentations, business meetings, short courses, and field trips from the Fall 2003 annual meeting held in Washington, D.C.

Open-File Report

Flow‐duration characteristics of Illinois streams

The paper entitled “An investigation of the flow‐duration characteristics of North Carolina streams,” by Thorndlke Saville and John Dargan Watson, which was published by the American Geophysical Union in its report of the Fourteenth Annual Meeting in 1933 (pp. 406–425), stimulated the writer, who is familiar with the streams discussed, having been assigned for several years to the United States Geological Survey offices that collected the base data. Knowing that there is a marked similarity in runoff‐characteristics of the western North Carolina streams and also that fairly good similarity is shown by New England streams within reasonable zones, he felt it would be desirable to carry the investigation to a part of the country where stream‐flow characteristics are diverse. The present investigation was therefore made to cover all the long‐time records in Illinois on streams of definite drainage‐area, particular attention being paid to comparisons of records from the same stream. The record on the Rock River at Afton, Wisconsin, was also included. The streams studied are listed in Table 1.

Illinois

Maintenance of influenza A viruses and antibody response in mallards (Anas platyrhynchos) sampled during the non-breeding season in Alaska

Prevalence of influenza A virus (IAV) infections in northern-breeding waterfowl has previously been reported to reach an annual peak during late summer or autumn; however, little is known about IAV infection dynamics in waterfowl populations persisting at high-latitude regions such as Alaska, during winter. We captured mallards ( Anas platyrhynchos ) throughout the non-breeding season (August–April) of 2012–2015 in Fairbanks and Anchorage, the two largest cities in Alaska, to assess patterns of IAV infection and antibody production using molecular methods and a standard serologic assay. In addition, we used virus isolation, genetic sequencing, and a virus microneutralization assay to characterize viral subtypes and to evaluate the immune response of mallards captured on multiple occasions through time. We captured 923 mallards during three successive sampling years: Fairbanks in 2012/13 and 2013/14, and Anchorage in 2014/15. Prevalence varied by age, season, and year/site with high and relatively stable estimates throughout the non-breeding season. Infected birds were detected in all locations/seasons except early-winter in Fairbanks during 2013/14. IAVs with 17 combinations of hemagglutinin (H1–5, H7–9, H11, H12) and neuraminidase (N1–6, N8, N9) subtypes were isolated. Antibodies to IAVs were detected throughout autumn and winter for all sampling locations and years, however, seroprevalence was higher among adults and varied among years. Mallards exhibited individual heterogeneity with regard to immune response, providing instances of both seroconversion and seroreversion to detected viral subtypes. The probability that an individual transitioned from one serostatus to another varied by age, with juvenile mallards having higher rates of seroconversion and seroreversion than adults. Our study provides evidence that a diversity of IAVs circulate in populations of mallards wintering at urban locations in Alaska, and we suggest waterfowl wintering at high-latitudes may play an important role in maintenance of viruses across breeding seasons.

Alaska

Hydrology of area 4, Eastern Coal Province, Pennsylvania, Ohio, and West Virginia

Area 4 (one of the 24 hydrologic areas defining the Eastern Coal Province) is located at the northern end of the Eastern Coal Province in eastern Ohio, northern West Virginia, and western Pennsylvania. It is part of the upper Ohio River basin, which includes the Beaver, Mahoning, and Shenango Rivers. The area is underlain by rocks of the Pottsville, Allegheny, Conemaugh, Monongahela Groups (or Formations) and Dunkard Group. Area 4 has a temperate climate with an annual average rainfall of 38 to 42 inches, most of its area is covered by forest. The soils have a high erosion potential where the vegetation cover is removed. In response to Public Law 95-87, 132 sites were added to the existing surface-water data-collection network in area 4. At these added sites, collected data includes discharge, water quality, sediment, and biology. The data are available from computer storage through the National Water Data Exchange (NAWDEX) or the published annual Water Resources Data reports for Ohio, Pennsylvania, and West Virginia. Hydrologic problems related to mining are: (1) Erosion and increased sedimentation, and (2) degradation of water quality. Erosion and sedimentation are associated chiefly with surface mining. Sediment yields increase drastically when vegetation is removed from the highly erosive soils. Degradation of water quality can be caused by acid-mine drainage from underground and surface mining. More than half the acid-mine drainage effluent in area 4 comes from underground mines. The rest seeps from abandoned surface mines. Usually in reclaimed surface mines the overburden is replaced in such a short time after the coal is taken out that oxidation of acid-forming minerals, commonly pyrite or marcasite, is not complete or is neutralized by the buffering action of calcareous minerals in the soils. (USGS)

Open-File Report

Development of ground-water resources in Orange County, Texas, and adjacent areas in Texas and Louisiana, 1971-80

Pumpage in Orange County from the lower unit of the Chicot aquifer averaged 21.2 million gallons per day (0.93 cubic meter per second) and pumpage from the upper unit of the Chicot averaged about 2 million gallons per day (0.088 cubic meter per second) from 1971-79. Annual pumpage increased in municipal areas and decreased in industrial areas with little net change in total annual pumpage during the report period. The major water-bearing unit in the study area is the Chicot aquifer, which overlies the Evangeline aquifer. The Evangeline aquifer is undeveloped in Orange County, but is developed at Evadale in Jasper County, Texas, and at Silsbee in Hardin County, Texas. Both aquifers consist of unconsolidated and discontinuous layers of sand and clay that gently dip toward the Gulf of Mexico. Water levels in Orange County tended to stabilize or rise in areas where ground-water withdrawals decreased. Elsewhere in Orange County, most water levels continued to decline, generally at a slower rate than before 1971. Bench-mark elevations determined during 1973 show regional land-surface subsidence from 1918-73, generally attributed to ground-water development, to be less than 0.5 foot (0.15 meter). Locally, subsidence due to production of oil, gas, saltwater, or sulfur was about 15 feet (4.6 meters) at Spindletop Dome, Jefferson County, Texas, and as much as 3 feet (1.0 meter) near Port Acres gas field, Jefferson County, Texas. Although saltwater encroachment is evident in parts of southern Orange County, the encroachment is not expected to be detrimental if the ground-water pumping remains stable and the projected increase in demands for water is met with surface-water supplies.

Louisiana, Texas

Measuring streamflow in Virginia (2002 revision)

The U.S. Geological Survey (USGS), U.S. Department of the Interior, is the Nation's largest Earth-science information agency. Among its many responsibilities, such as map making and providing information on earthquakes and other natural hazards, the USGS provides information on the Nation's water resources. The USGS has collected and analyzed hydrologic (water-related) information for more than 100 years. In 1889, the first streamflow-gaging station (a site where regular observations of streamflow data are collected) operated in the United States by the USGS was established on the Rio Grande near Embudo, New Mexico. As the need for streamflow data increased, the USGS's streamflow-gaging program has grown to include more than 7,000 continuous-record streamflow-gaging stations. More than 90 percent of these stations are operated with at least partial support from State, local, or other Federal agencies In Virginia, the Department of Environmental Quality (DEQ) is a major cooperator in the streamflow-gaging program, which consists of 161 continuous-record streamflow-gaging stations located throughout the State (fig. 1). The USGS and DEQ cooperate to publish the annual USGS State data report, 'Water Resources Data-Virginia'; this two-volume publication includes streamflow data collected at the 161 streamflow-gaging stations, chemical data collected at 19 streamflow-gaging stations, and ground-water data collected from more than 250 wells located in Virginia.

Virginia

Measuring streamflow in Virginia (1999 revision)

The U.S. Geological Survey (USGS), U.S. Department of the Interior, is the Nation's largest Earth-science information agency. Among its many responsibilities, such as map making and providing information on earthquakes and other natural hazards, the USGS provides information on the Nation's water resources. The USGS has collected and analyzed hydrologic (water-related) information for more than 100 years. In 1889, the first streamflow-gaging station (a site where regular observations of streamflow data are collected) operated in the United States by the USGS was established on the Rio Grande near Embudo, New Mexico. As the need for streamflow data increased, the USGS's streamflow-gaging program has grown to include more than 7,000 continuous-record streamflow-gaging stations. More than 90 percent of these stations are operated with at least partial support from State, local, and other Federal agencies. In Virginia, the Department of Environmental Quality (DEQ) is a major cooperator in the streamflow-gaging program, which consists of 152 continuous-record streamflow-gaging stations located throughout the State (fig. 1). The USGS and DEQ cooperate to publish the annual USGS State data report, "Water Resources Data-Virginia;" this two-volume publication includes streamflow data collected at the 152 streamflow-gaging stations, chemical data collected at more than 24 streamflow-gaging stations, and ground-water data collected from more than 338 wells.

Virginia

Summary of Optical-Backscatter and Suspended-Sediment Data, Tomales Bay Watershed, California, Water Years 2004, 2005, and 2006

The U.S. Geological Survey, in cooperation with Point Reyes National Seashore, is studying suspended-sediment transport dynamics in the two primary tributaries to Tomales Bay, Lagunitas Creek and Walker Creek. Suspended-sediment samples and continuous optical backscatter (turbidity) data were collected at three locations during water years 2004?06 (October 1, 2003?September 30, 2006): at two sites in the Lagunitas Creek watershed and at one site in the Walker Creek watershed. Sediment samples were analyzed for suspended-sediment concentration, grain size, and turbidity. Data were used to estimate mean daily and annual seasonal suspended-sediment discharge, which were published in U.S. Geological Survey Annual Water-Data Reports. Data were utilized further in this report to develop field-based optical-backscatter calibration equations, which then were used to derive a continuous time series (15-minute interval) of suspended-sediment concentrations. Sensor fouling and aggradation of the channel bed occurred periodically throughout the project period, resulting in data loss. Although periods of data loss occurred, collection of optical sensor data improved our understanding of suspended-sediment dynamics in the Lagunitas Creek and Walker Creek watersheds by providing continuous time-series storm event data that were analyzed to determine durations of elevated sediment concentrations (periods of time when suspended-sediment concentration was greater than 100 mg/L). Data derived from this project contributed baseline suspended-sediment transport information that will be used to develop and implement sediment total maximum daily loads for Tomales Bay and its tributary watersheds, and provides supporting information for additional total maximum daily loads (pathogens, nutrients, and mercury) and restoration efforts for four federally listed aquatic species that are affected directly by sediment loading in the Tomales Bay watershed. In addition, this project provided an opportunity to evaluate the suitability of using optical data as a surrogate for more traditional labor-intensive methods of measuring suspended-sediment transport in steep coastal watersheds.

Scientific Investigations Report

Water resources data--Illinois, water year 2003

This annual Water-Data Report for Illinois contains current water year (Oct. 1, 2003, to Sept. 30, 2004) and historical data of discharge, stage, water quality and biology of streams; stage of lakes and reservoirs; levels and quality of ground water; and records of precipitation, air temperature, dew point, solar radiation, and wind speed. The current year's (2004) data provided in this report include (1) discharge for 177 surface-water gaging stations and for 10 crest-stage partial-record stations; (2) stage for 27 surface-water gaging stations; (3) stage for 8 reservoirs; (4) water-quality records for 7 surface-water stations; (5) sediment-discharge records for 16 surface-water stations; (6) water-level records for 14 ground-water wells; (7) precipitation records for 50 rain gages; (8) records of air temperature, dew point, solar radiation and wind speed for 1 meteorological station; and (9) biological records for 6 sample sites. Also included are miscellaneous data collected at various sites not in the systematic data-collection network. Data were collected and compiled as a part of the National Water Information System (NWIS) maintained by the U.S. Geological Survey in cooperation with Federal, State, and local agencies.

Water Data Report

Water Resources Data for Illinois - Water Year 2005 (Includes Historical Data)

This annual Water-Data Report for Illinois contains current water year (Oct. 1, 2004, to Sept. 30, 2005) and historical data of discharge, stage, water quality and biology of streams; stage of lakes and reservoirs; levels and quality of ground water; and records of precipitation, air temperature, dew point, solar radiation, and wind speed. The current year's (2005) data provided in this report include (1) discharge for 182 surface-water gaging stations and for 9 crest-stage partial-record stations; (2) stage for 33 surface-water gaging stations; (3) water-quality records for 10 surface-water stations; (4) sediment-discharge records for 14 surface-water stations; (5) water-level records for 98 ground-water wells; (6) water-quality records for 17 ground-water wells; (7) precipitation records for 48 rain gages; (8) records of air temperature, dew point, solar radiation and wind speed for 1 meteorological station; and (9) biological records for 6 sample sites. Also included are miscellaneous data collected at various sites not in the systematic data-collection network. Data were collected and compiled as a part of the National Water Information System (NWIS) maintained by the U.S. Geological Survey in cooperation with Federal, State, and local agencies.

Water Data Report