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At least 1,099 records · Page 61Linked to original sources
USGS1999

Processes affecting dissolved-oxygen concentrations in the lower reaches of Middle Fork and South Fork Beargrass Creek, Jefferson County, Kentucky

This report provides data on dissolved-oxygen (DO) concentrations and identifies the environmental processes that most affect DO concentrations during base-flow periods in the lower reaches of Middle Fork and South Fork Beargrass Creek in Jefferson County, Kentucky. These reaches are affected by inputs from combined-sewer overflows. Sections of the lower reaches of the two streams run through single-family residential areas and public parks that are used extensively by local residents during the summer. Recreational fishing and wading also are common in the Middle Fork reach. Continuous-record data collected during the summer and early fall (July-September 1996 on the Middle Fork and July-October 1995 on the South Fork) at three monitoring sites along each reach indicate generally decreasing DO concentrations in the downstream direction except for the South Fork Beargrass Creek at Winter Avenue site where channel modifications have resulted in higher velocities along with shallower depths during low-flow conditions. The channel modifications at this site increased the reaeration-rate coefficient (a measure of the capacity of the stream to absorb oxygen through the air-water interface), increased the potential for algae to attach to the rough concrete surface, and increased algal exposure to sunlight. Synoptic data available for selected constituent concentrations were used to calibrate and verify a computer model (U.S. Environmental Protection Agency QUAL2E model) capable of simulating processes that affect DO concentrations in streams. The results of the study indicate that streamflow, reaeration, and sediment-oxygen demand (SOD) are the factors that most affect net production and depletion of DO in the lower reaches of Middle Fork and South Fork Beargrass Creek. For the QUAL2E model, streamflow is used in the determination of depth, which in tum is used to estimate the consumption of oxygen by SOD. Streamflow also is used in the determination of the reaeration-rate coefficient. From the QUAL2E simulations, DO concentrations (in the mass balance) attributed to reaeration and SOD were at least an order of magnitude greater than any of the other factors that can affect DO concentrations. Large diurnal variability in DO concentrations resulted at the monitoring sites located at upstream and downstream ends of the Middle Fork and South Fork reaches, but as indicated in model simulation, the net effect of photosynthesis and respiration on DO concentration was small. Nitrogen, ammonia, and carbonaceous biochemical-oxygen demand were present at low concentrations in each of the study reaches; the model results indicate these constituents did not have a substantial effect on DO concentrations. Model simulations indicated that lowering the SOD rate by 50 percent would result in a substantial improvement in DO concentrations in the Middle Fork Beargrass Creek reach for extremely low base-flow conditions but would result in only limited improvement in DO concentrations in the South Fork Beargrass Creek reach. However, no simulations for extremely low base-flow conditions were conducted for the South Fork Beargrass Creek reach. More information on SOD is needed for stream reaches affected by periodic inputs of effluent. In such stream systems, the temporal and spatial variability of SOD needs to be better defined.

Kentucky↗
USGS1999

Water resources of Monroe County, New York, water years 1989-93, with emphasis on water quality in the Irondequoit Creek basin: Part 2. Atmospheric deposition, ground water, streamflow, trends in water quality, and chemical loads to Irondequoit Bay

Irondequoit Creek, which drains 169 square miles in the eastern part of Monroe County, has been recognized as a source of contaminants that contribute to the eutrophication of Irondequoit Bay on Lake Ontario. The discharge from sewage-treatment plants to the creek and its tributaries was eliminated in 1979 by diversion to another wastewater-treatment facility, but sediment and nonpoint-source pollution remain a concern. This report presents data from five surface-water sites in the Irondequoit Creek basin. Irondequoit Creek at Railroad Mills, East Branch Allen Creek, Allen Creek near Rochester, Irondequoit Creek at Blossom Road, and Irondequoit Creek at Empire Boulevard, to supplement published data from 1984-88. Data from Northrup Creek, which drains 11.7 square miles in western Monroe County, provide information on surface-water quality west of the Genesee River. Also presented are water-level and water-quality data from 12 observation-well sites in Ellison and Powdermill Parks and atmospheric-deposition data from 1 site (Mendon Ponds). Concentrations of several chemical constituents in streams of the Irondequoit Creek basin showed statistically significant trends during 1989-93. Concentrations of total suspended-solids and volatile suspended-solids in Irondequoit Creek at Blossom Road decreased 13.5 and 12.5 percent per year, respectively, and those at Empire Boulevard decreased 33.5 and 22 percent per year, respectively. Concentrations of ammonia plus organic nitrogen increased 17.6 percent per year at one site in the basin, but decreased 8.5 and 22.3 percent per year at two sites. Nitrite plus nitrate decreased at only one site (3.5 percent per year). Concentrations of total phosphorus increased at two sites (about 7 percent per year) and decreased at two other sites (7.6 and 29.9 percent per year), and orthophosphate concentrations increased at one site (10.8 percent per year). Dissolved chloride increased at three sites (1.7 to 10.9 percent per year), and dissolved sulfate decreased at one site (2.1 percent per year) and increased at one site (6.8 percent per year). Median concentrations of constituents were significantly lower in atmospheric deposition than in streamflow, although annual deposition of ammonia nitrogen, nitrite plus nitrate, total phosphorus, and orthophosphate in the basin exceeded the amounts removed by streamflow. Atmospheric deposition of chloride and sulfate, by contrast, represented only 1 and 12 percent, respectively, of the loads transported by Irondequoit Creek (Blossom Road site). Comparison of water-quality data from the Allen Creek site and Irondequoit Creek at Blossom Road from water years 1989-93 with corresponding data from 1984-88 indicates significant changes in median concentrations of several constituents. The concentration of dissolved chloride increased at Blossom Road and was unchanged at Allen Creek, whereas sulfate decreased at both sites. Concentrations of ammonia plus organic nitrogen, and nitrite plus nitrate, were significantly lower during 1989-93 than during 1984-88 at both sites. Total phosphorus concentration was lower during 1984-88 than during 1989-93 at Blossom Road but showed no change at Allen Creek, and orthophosphate concentration for 1989-93 was lower than in 1984-88 at both sites. Comparison of chemical loads in atmospheric deposition also indicates significant changes in many constituents. Five-year-mean loads of sodium, sulfate, and lead in atmospheric deposition for 1989-93 exceeded those for 1984-88, whereas 5-year-mean loads of calcium, magnesium, potassium, chloride, nitrite plus nitrate, ammonia nitrogen, and orthophosphate for 1989-93 were lower than in 1984-88. The changes in surface-water quality resulted from several factors within the basin, including land-use changes, annual and seasonal variations in streamflow, and year-to-year variations in the application of deicing salts on area roads. Statistical analyses of long-term (9 years or more) flow records of three unregulated streams in Monroe County indicate that annual mean flows for water years 1989- 93 were in the normal range (20th- to 80th-percentile). The greatest mean annual flow in this period-about 140 percent of normal at Irondequoit Creek and Black Creek-occurred in 1993, but the annual mean flow for that water year at Allen Creek was only 98 percent of normal. The lowest annual mean flows of these streams-ranging from 75 percent of normal to 93 percent of normal-occurred in 1989. The average annual mean flows for these streams for 1989-93 was 104 percent of normal, and that for 1984-88 was normal.

New York↗
USGS2006

Measurements of wind, aeolian sand transport, and precipitation in the Colorado River corridor, Grand Canyon, Arizona: January 2005 to January 2006

This report presents measurements of aeolian sediment-transport rates, wind speed and direction, and precipitation records from six locations that contain aeolian deposits in the Colorado River corridor through Grand Canyon, Grand Canyon National Park, Arizona. Aeolian deposits, many of which contain and preserve archaeological material, are an important part of the Grand Canyon ecosystem. This report contains data collected between January 2005 and January 2006, and is the second in a series; the first contained data that were collected between November 2003 and December 2004 (Draut and Rubin, 2005; http://pubs.usgs.gov/of/2005/1309/ ). Analysis of data collected in 2005 shows great spatial and seasonal variation in wind and precipitation patterns. Total annual rainfall can vary by more than a factor of two over distances ~ 10 km. Western Grand Canyon received substantially more precipitation than the eastern canyon during the abnormally wet winter of 2005. Great spatial variability in precipitation indicates that future sedimentary and geomorphic studies would benefit substantially from continued or expanded data collection at multiple locations along the river corridor, because rainfall records collected by NPS at Phantom Ranch (near river-mile 88) cannot be assumed to apply to other areas of the canyon. Wind velocities and sand transport in 2005 were greatest during May and June, with maximum winds locally as high as ~25 m s -1 , and transport rates locally >100 g cm -1 d -1 . This represents a later peak in seasonal aeolian sand transport compared to the previous year, in which transport rates were greatest in April and May 2004. Dominant wind direction varies with location, but during the spring windy season the greatest transport potential was directed upstream in Marble Canyon (eastern Grand Canyon). At all locations, rates of sand transport during the spring windy season were 5–15 times higher than at other times of year. This information has been used to evaluate the potential for aeolian reworking of new fluvial sand deposits, and restoration of higher-elevation aeolian deposits, following the 60-hour controlled flood release from Glen Canyon Dam in November 2004. Substantial deposition of new sand occurred at all study sites during this high-flow experiment, but most of the new sediment was eroded by high flow fluctuations between January and March 2005. Comparison of aeolian sand transport in the spring windy seasons of the preand post-flood years indicates that, where some of the flood-deposited sand remained by spring, aeolian sand transport was significantly higher than during the pre-flood spring. Gully incision in an aeolian dune field was observed to be partially ameliorated by deposition of wind-blown sand derived from a nearby 2004 flood deposit. These results imply that sediment-rich controlled floods can renew sand deposition in aeolian dune fields above the flood-stage elevation. The potential for restoration of archaeological sites in aeolian deposits can be maximized by using dam operations that maximize the open sand area on fluvial sandbars during spring, when aeolian sediment transport is greatest.

Arizona↗
USGS2007

Near-field receiving water monitoring of trace metals and a benthic community near the Palo Alto Regional Water Quality Control Plant in South San Francisco Bay, California--2006

Results reported herein include trace element concentrations in sediment and in the clam Macoma petalum (formerly reported as Macoma balthica (Cohen and Carlton 1995)), clam reproductive activity, and benthic macroinvertebrate community structure for a mudflat one kilometer south of the discharge of the Palo Alto Regional Water Quality Control Plant in South San Francisco Bay. This report includes data collected for the period January 2006 to December 2006, and extends a critical long-term biogeochemical record dating back to 1974. These data serve as the basis for the City of Palo Alto's Near-Field Receiving Water Monitoring Program, initiated in 1994. Metal concentrations in both sediments and clam tissue during 2006 were consistent with results observed since 1990. Most notably, copper and silver concentrations in sediment and clam tissue increased in the last year but the values remain well within range of past data. Other metals such as chromium, nickel, vanadium, and zinc remained relatively constant throughout the year except for maximum values generally occurring in winter months (January-March). Mercury levels in sediment and clam tissue were some of the lowest seen on record. Conversely, selenium concentrations reached a maximum level but soon returned to baseline levels. In all, metal concentrations in sediments and tissue remain within past findings. There are no obvious directional trends (increasing or decreasing). Analyses of the benthic-community structure of a mudflat in South San Francisco Bay over a 31-year period show that changes in the community have occurred concurrent with reduced concentrations of metals in the sediment and in the tissues of the biosentinel clam M. petalum from the same area. Analysis of the reproductive activity of M. petalum shows increases in reproductive activity concurrent with the decline in metal concentrations in the tissues of this organism. Reproductive activity is presently stable, with almost all animals initiating reproduction in the fall and spawning the following spring of most years. The community has shifted from being dominated by several opportunistic species to a community where the species are more similar in abundance, a pattern that suggests a more stable community that is subjected to less stress. In addition, two of the opportunistic species (Ampelisca abdita and Streblospio benedicti) that brood their young and live on the surface of the sediment in tubes, have shown a continual decline in dominance coincident with the decline in metals. Heteromastus filiformis, a subsurface polychaete worm that lives in the sediment, consumes sediment and organic particles residing in the sediment, and reproduces by laying their eggs on or in the sediment, has shown a concurrent increase in dominance. These changes in species dominance reflect a change in the community from one dominated by surface dwelling, brooding species to one with species with varying life history characteristics. For the first time since its invasion in 1986, the non-indigenous filter-feeding clam Corbula (Potamocorbula) amurensis has shown up in small, but persistent, numbers in the benthic community.

California↗
USGS2010

Distribution and condition of larval and juvenile Lost River and shortnose suckers in the Williamson River Delta restoration project and Upper Klamath Lake, Oregon

Federally endangered Lost River sucker ( Deltistes luxatus ) and shortnose sucker ( Chasmistes brevirostris ) were once abundant throughout their range but populations have declined. They were extirpated from several lakes in the 1920s and may no longer reproduce in others. Poor recruitment to the adult spawning populations is one of several reasons cited for the decline and lack of recovery of these species and may be the consequence of high mortality during juvenile life stages. High larval and juvenile sucker mortality may be exacerbated by an insufficient quantity of suitable or high quality rearing habitat. In addition, larval suckers may be swept downstream from suitable rearing areas in Upper Klamath Lake into Keno Reservoir, which is seasonally anoxic. The Nature Conservancy flooded about 3,600 acres (1,456 hectares) to the north of the Williamson River mouth (Tulana Unit) in October 2007 and about 1,400 acres (567 hectares) to the south and east of the Williamson River mouth (Goose Bay Unit) a year later to retain larval suckers in Upper Klamath Lake, create nursery habitat, and improve water quality. The U.S. Geological Survey joined a long-term research and monitoring program in collaboration with The Nature Conservancy, the Bureau of Reclamation, and Oregon State University in 2008 to assess the effects of the Williamson River Delta restoration on the early life-history stages of Lost River and shortnose suckers. The primary objectives of the research were to describe habitat colonization and use by larval and juvenile suckers and non-sucker fishes and to evaluate the effects of the restored habitat on the health and condition of juvenile suckers. This report summarizes data collected in 2009 by the U.S. Geological Survey as a part of this monitoring effort. The Williamson River Delta appeared to provide suitable rearing habitat for endangered larval Lost River and shortnose suckers in 2008 and 2009. Larval suckers captured in this delta typically were larger than those captured in the adjacent lake habitat in 2008, but the opposite was true for larval shortnose suckers in 2009. Mean sample density was greater for both species in the Williamson River Delta than adjacent lake habitats in both years. Larval suckers captured in the restoration area, however, had less food in their guts compared to those captured in Upper Klamath or Agency Lakes. Differential distribution among sucker species within the Williamson River Delta and between the delta and adjacent lakes indicated that shortnose suckers likely benefited more from the restored Williamson River Delta than Lost River or Klamath largescale suckers ( Catostomus snyderi ). Catch rates in shallow-water habitats with vegetation within the delta were higher for shortnose and Klamath largescale suckers than for larval Lost River suckers in 2008 and 2009.However, catch rates at the mouth of the Williamson River in 2008 and in Upper Klamath Lake in 2009 were higher for larval Lost River suckers than for larvae identified as either shortnose or Klamath largescale suckers. Shortnose suckers also comprised the greatest portion of age-0 suckers captured in the Williamson River Delta in 2008 and 2009. The relative abundance of age-1 shortnose suckers was high in our catches compared to age-1 Lost River suckers in 2009 in the delta and adjacent lakes, which may or may not indicate shortnose suckers experienced better survival than Lost River suckers in 2008. Age-0 and age-1 suckers were similarly distributed throughout the Williamson River Delta in 2008 and 2009. Age-0 suckers used shallow vegetated and unvegetated habitats primarily in mid- to late July in both years. A comparison of catch rates between our study and a concurrent study in Upper Klamath Lake indicated that Goose Bay was the most used habitat in 2009 and the Tulana Unit was the one of the least used habitats in 2008 and 2009 by age-0 suckers. Catch rates for age-1 suckers, however, indicated that bo

Oregon↗
USGS2012

Multilevel groundwater monitoring of hydraulic head and temperature in the eastern Snake River Plain aquifer, Idaho National Laboratory, Idaho, 2009–10

During 2009 and 2010, the U.S. Geological Survey’s Idaho National Laboratory Project Office, in cooperation with the U.S. Department of Energy, collected quarterly, depth-discrete measurements of fluid pressure and temperature in nine boreholes located in the eastern Snake River Plain aquifer. Each borehole was instrumented with a multilevel monitoring system consisting of a series of valved measurement ports, packer bladders, casing segments, and couplers. Multilevel monitoring at the Idaho National Laboratory has been ongoing since 2006. This report summarizes data collected from three multilevel monitoring wells installed during 2009 and 2010 and presents updates to six multilevel monitoring wells. Hydraulic heads (heads) and groundwater temperatures were monitored from 9 multilevel monitoring wells, including 120 hydraulically isolated depth intervals from 448.0 to 1,377.6 feet below land surface. Quarterly head and temperature profiles reveal unique patterns for vertical examination of the aquifer’s complex basalt and sediment stratigraphy, proximity to aquifer recharge and discharge, and groundwater flow. These features contribute to some of the localized variability even though the general profile shape remained consistent over the period of record. Major inflections in the head profiles almost always coincided with low-permeability sediment layers and occasionally thick sequences of dense basalt. However, the presence of a sediment layer or dense basalt layer was insufficient for identifying the location of a major head change within a borehole without knowing the true areal extent and relative transmissivity of the lithologic unit. Temperature profiles for boreholes completed within the Big Lost Trough indicate linear conductive trends; whereas, temperature profiles for boreholes completed within the axial volcanic high indicate mostly convective heat transfer resulting from the vertical movement of groundwater. Additionally, temperature profiles provide evidence for stratification and mixing of water types along the southern boundary of the Idaho National Laboratory. Vertical head and temperature change were quantified for each of the nine multilevel monitoring systems. The vertical head gradients were defined for the major inflections in the head profiles and were as high as 2.1 feet per foot. Low vertical head gradients indicated potential vertical connectivity and flow, and large gradient inflections indicated zones of relatively low vertical connectivity. Generally, zones that primarily are composed of fractured basalt displayed relatively small vertical head differences. Large head differences were attributed to poor vertical connectivity between fracture units because of sediment layering and/or dense basalt. Groundwater temperatures in all boreholes ranged from 10.2 to 16.3˚C. Normalized mean hydraulic head values were analyzed for all nine multilevel monitoring wells for the period of record (2007-10). The mean head values suggest a moderately positive correlation among all boreholes, which reflects regional fluctuations in water levels in response to seasonality. However, the temporal trend is slightly different when the location is considered; wells located along the southern boundary, within the axial volcanic high, show a strongly positive correlation.

Idaho↗
USGS1979

January 1979 water levels, and data related to water-level changes, western and south-central Kansas

This report contains hydrologic data on water-level measurements in observation wells in western and south-central Kansas. The measurements were made in mid-winter, mostly in January, when pumping was minimal and water levels had recovered from the effects of pumping during the previous irrigation season. This report also provides basic hydrologic data for relating water-level changes from a "base-reference year" (predevelopment year), a year of abnormally high rainfall and minimum pumpage (1966), and the previous year (1978). The "base-reference year" is designated as 1950 for the northwestern and west-central areas, 1940 for the southwestern area, and 1944 for the south-central area. Water-level data in the south-central area also are compared with data for 1974, which represents the recent period of intensified irrigation-well development. Tables in the report show the depths to water level in 1940, 1944, or 1950 (predevelopment year), 1966, 1974, 1978, and 1979; water-level changes from 1940-79, 1944-79, 1950-79, 1966-79, 1974-79, and 1978-79; and the average annual changes from 1940-79, 1944-79, 1950-79, 1966-79, and 1974-79. Also shown are saturated thicknesses of the deposits in 1940, 1944, or 1950 and in 1979, as well as the percentage change in saturated thickness from 1940-79, 1944-79, or 1950-79. The annual water-level measurements are made by personnel of the Division of Water Resources of the Kansas State Board of Agriculture and of the U.S. Geological Survey. State-agency support for this program is provided through the Kansas Geological Survey. Wells in this report are numbered according to the Bureau of Land Management's system of land subdivision. In this system, the first set of digits of a well number indicates the township; the second set, the range east or west of the sixth principal meridian; and the third set, the section in which the well is situated. The first letter denotes the 160-acre tract within the section; the second, the 40-acre tract; and the third, the 10-acre tract. The letters are designated in a counterclockwise direction beginning in the northeast quadrant. Where there is more than one well in a 10-acre tract, consecutive numbers, beginning with "2", are added in the order in which the data from the wells are collected.

Kansas↗
USGS2008

Near-field receiving water monitoring of trace metals and a benthic community near the Palo Alto Regional Water Quality Control Plant in South San Francisco Bay, California: 2007

Results reported herein include trace element concentrations in sediment and in the clam Macoma petalum (formerly reported as Macoma balthica (Cohen and Carlton 1995)), clam reproductive activity, and benthic macroinvertebrate community structure for a mudflat one kilometer south of the discharge of the Palo Alto Regional Water Quality Control Plant in South San Francisco Bay. This report includes data collected for the period January 2007 to December 2007, and extends a critical long-term biogeochemical record dating back to 1974. These data serve as the basis for the City of Palo Alto’s Near-Field Receiving Water Monitoring Program, initiated in 1994. Metal concentrations in both sediments and clam tissue during 2007 remained consistent with results observed since 1990. Most notably, copper and silver concentrations in sediment and clam tissue are elevated for the second consecutive year, but the values remain well within the range of past findings. Other metals such as chromium, nickel, vanadium, and zinc remained relatively constant throughout the year except for maximum values that generally occur in winter months (January-March). Mercury levels in sediment and clam tissue were some of the lowest seen on record. Last year’s elevated selenium levels appear to be transient, and selenium concentrations have returned to background levels. Overall, metal concentrations in sediments and tissue remain within past findings. Analyses of the benthic-community structure of a mudflat in South San Francisco Bay over a 31-year period show that changes in the community have occurred concurrent with reduced concentrations of metals in the sediment and in the tissues of the biosentinel clam, M. petalum , from the same area. Analysis of the reproductive activity of M. petalum shows increases in reproductive activity concurrent with the decline in metal concentrations in the tissues of this organism. Reproductive activity is presently stable, with almost all animals initiating reproduction in the fall and spawning the following spring of most years. The community has shifted from being dominated by several opportunistic species to a community where the species are more similar in abundance, a pattern that suggests a more stable community that is subjected to less stress. In addition, two of the opportunistic species ( Ampelisca abdita and Streblospio benedicti ) that brood their young and live on the surface of the sediment in tubes, have shown a continual decline in dominance coincident with the decline in metals. Heteromastus filiformis , a subsurface polychaete worm that lives in the sediment, consumes sediment and organic particles residing in the sediment, and reproduces by laying their eggs on or in the sediment, has shown a concurrent increase in dominance and is now showing signs of population stability. These changes in species dominance reflect a change in the community from one dominated by surface dwelling, brooding species to one with species with varying life history characteristics.

California↗
USGS2009

Near-field receiving water monitoring of trace metals and a benthic community near the Palo Alto Regional Water Quality Control Plant in South San Francisco Bay, California: 2008

Results reported herein include trace element concentrations in sediment and in the clam Macoma petalum (formerly reported as Macoma balthica (Cohen and Carlton, 1995)), clam reproductive activity, and benthic macroinvertebrate community structure for a mudflat one kilometer south of the discharge of the Palo Alto Regional Water Quality Control Plant (PARWQCP) in South San Francisco Bay. This report includes data collected for the period January 2008 to December 2008 and extends a critical long-term biogeochemical record dating back to 1974. These data serve as the basis for the City of Palo Alto's Near-Field Receiving Water Monitoring Program, initiated in 1994. In 2008, metal concentrations in both sediments and clam tissue were among the lowest concentrations on record and consistent with results observed since 1991. Following significant reductions in the late 1980's, silver (Ag) and copper (Cu) concentrations appeared to have stabilized. Annual mean concentrations have fluctuated modestly (2–4 fold) in a nondirectional manner. Data for other metals, including chromium, mercury, nickel, selenium, vanadium, and zinc, have been collected since 1994. Over this period, concentrations of these elements, which more likely reflect regional inputs and systemwide processes, have remained relatively constant, aside from typical seasonal variation that is common to all elements. Within years, concentrations generally reach maximum in winter months (January–March) and decline to annual minima in spring through fall. Mercury (Hg) in sediments spiked to the highest observed level in January 2008. However, sedimentary concentrations for the rest of the year and concentrations of Hg in M. petalum for the entire year were consistent with data from previous years. Average selenium (Se) concentrations in sediment were the highest on record, but there is no evidence, yet, to suggest a temporal trend of increasing sedimentary Se. Selenium in M. petalum was not elevated relative to past years. Overall, Cu and Ag concentrations in sediments and soft tissues of the clam, M. petalum , remained representative of the concentrations observed since 1991 following significant reductions in the discharge of these elements from PARWQCP, suggesting that, similar to other elements of regulatory interest, regional scale factors now largely influence sedimentary and bioavailable concentrations of Cu and Ag. Analyses of the benthic-community structure of a mudflat in South San Francisco Bay over a 31-year period show that changes in the community have occurred concurrent with reduced concentrations of metals in the sediment and in the tissues of the biosentinel clam, M. petalum , from the same area. Analysis of the reproductive activity of M. petalum shows increases in reproductive activity concurrent with the decline in metal concentrations in the tissues of this organism. Reproductive activity is presently stable, with almost all animals initiating reproduction in the fall and spawning the following spring of most years. The community has shifted from being dominated by several opportunistic species to a community where the species are more similar in abundance, a pattern that suggests a more stable community that is subjected to less stress. In addition, two of the opportunistic species ( Ampelisca abdita and Streblospio benedicti ) that brood their young and live on the surface of the sediment in tubes, have shown a continual decline in dominance coincident with the decline in metals. Heteromastus filiformis , a subsurface polychaete worm that lives in the sediment, consumes sediment and organic particles residing in the sediment, and reproduces by laying their eggs on or in the sediment, has shown a concurrent increase in dominance and is now showing signs of population stability. An unidentified disturbance occurred on the mudflat in early 2008 that resulted in the loss of the benthic animals, except for those deep dwelling animals like Macoma petalum . Animals immediately returned to the mudflat, which is indicative that the disturbance was not due to a persistent toxin or due to anoxia. This event allows us to examine the response of the mudflat benthic community to a natural disturbance (possible causes include sediment accretion or freshwater inundation) and compare this recovery to the longer term recovery we observed in the 1970s.

California↗
USGS2011

Review of samples of water, sediment, tailings, and biota at the Little Bonanza mercury mine, San Luis Obispo County, California

Background and Objectives The Little Bonanza mercury (Hg) mine, located in San Luis Obispo County, California, is a relatively small mine with, a historical total Hg production of about 1,000 flasks. The mine workings and tailings are located in the headwaters of the previously unnamed west fork of Las Tablas Creek (WF Las Tablas Creek), which flows into the Nacimiento Reservoir. Wasterock and tailings eroded from the Little Bonanza Hg Mine have contributed Hg-enriched mine wastes to the headwaters of WF Las Tablas Creek. The mine is located on Federal land managed by the U.S. Bureau of Land Management (BLM), which requested that the U.S. Geological Survey (USGS) measure and characterize Hg and other geochemical constituents in tailings, sediment, water, and biota at and downstream from the minesite. This report is in response that request, from the lead agency which is mandated to conduct a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Removal Site Investigation (RSI). The RSI applies to removal of Hg-contaminated mine waste from the Little Bonanza minesite as a means of reducing Hg transport to WF Las Tablas Creek. This report summarizes data obtained from field sampling of mine tailings, wasterock, sediment, water, and biota at the Little Bonanza Mine that was completed on April 6, 2010. Conditions during sampling were dry and no rain had occurred in the watershed for several weeks. Our results permit a preliminary assessment of the mining sources of Hg and associated chemical constituents that could produce elevated levels of monomethyl mercury (MMeHg) in WF Las Tablas Creek and in biota. History and Geology The history of the Little Bonanza Hg mine is summarized here from Yates (1943) and other references as cited. The Little Bonanza Mine, located 20 mi west of Paso Robles, was discovered in 1862. Although production was minor until 1900, from 1900 to 1906, the mine produced about 1,000 flasks of Hg. Intermittent production continued into the 1940s but was relatively limited. Underground workings, now caved and inaccessible, include about 3,000 ft of drifts, crosscuts, and raises on three levels extending 260 ft downward. The workings at the Little Bonanza Mine explore a zone of fault breccia, which trends northwest. The breccia is composed of fragments of sandstone, greenstone, serpentine, and chert in a shale matrix. The serpentine has been hydrothermally altered to silica-carbonate rock, and the Hg deposit is hosted within the zone of alteration. The veins are discontinuous and irregular, but form a steplike pattern along the fault zone. The principal mineralization occurring in the veins is irregular, consisting of disseminated zones of cinnabar. Most of the veins in the mine area contain cinnabar. Sample Sites and Methods Samples were collected to assess the concentrations of Hg and biogeochemically relevant constituents in tailings and wasterock piles at the Little Bonanza Hg mine. Tailings are present adjacent to a three-pipe retort used to process the Hg ore. The tailings occur in the upper 15 cm of the soil adjacent to the retort and slag from the retort is present on the surface. An area of disturbed soil and rock uphill from the retort was likely formed during construction of a dam that provided water for mining activities. Wasterock in these piles was sampled. The largest amount of tailings is exposed to the west of the retort in the bank of WF Las Tablas Creek. Water, sediment, and biota were sampled from WF Las Tablas Creek, which flows through the mine area. Sample-site locations are shown in figures 10 and 11 and listed in table 1. Samples were collected when streamflow was low and no precipitation had occurred.

California↗
USGS2023

Comprehensive inventory of habitat assessment and evaluation datasets to support Deepwater Horizon mesophotic and deep benthic communities

This report is part of the NOAA Mesophotic and Deep Benthic Communities (MDBC) Series of publications that share the results of work conducted by the Deepwater Horizon MDBC restoration projects. The 2010 Deepwater Horizon oil spill was an unprecedented event. Approximately 3.2 million barrels of oil were released into the deep ocean over nearly three months. The plume of oil moved throughout the water column, formed surface slicks that cumulatively covered an area the size of Virginia, and washed oil onto at least 1,300 miles of shoreline habitats. More than 770 square miles (2,000 square kilometers) of deep benthic habitat surrounding the Deepwater Horizon wellhead and 4-square miles of the Pinnacles mesophotic reef complex, located at the edge of the continental shelf, were injured by the oil spill. Under the Oil Pollution Act, state and federal natural resource trustees conducted a Natural Resource Damage Assessment (NRDA). The Trustees assessed damages, quantifying the unprecedented injuries to natural resources and lost services. They also developed a programmatic restoration plan to restore injured resources and compensate the public for lost services. In April 2016, a settlement was finalized that included up to $8.8 billion in funding for the Deepwater Horizon Trustees to restore the natural resource injuries caused by the oil spill as described in their programmatic restoration plan, Final Programmatic Damage Assessment and Restoration Plan and Final Programmatic Environmental Impact Statement. The Deepwater Horizon Open Ocean Trustee Implementation Group is responsible for restoring natural resources and their services within the Open Ocean Restoration Area that were injured by the oil spill. The Open Ocean Trustees include NOAA, Department of the Interior, U.S. Environmental Protection Agency, and U.S. Department of Agriculture. In 2019, the Open Ocean Trustee Implementation Group committed more than $126 million to implement four restoration projects to address the injury to MDBC. The MDBC projects are: mapping, Ground-truthing, and Predictive Habitat Modeling; Habitat Assessment and Evaluation; Coral Propagation Technique Development; and Active Management and Protection. NOAA and the Department of the Interior are implementing the projects, in cooperation with a range of partners, over eight years. Together, the projects take a phased approach to meet the challenges involved in restoring deep-sea habitats. Challenges to restoration include a limited scientific understanding of these communities, limited experience with restoration at the depths at which these communities occur, and remote locations that limit accessibility. More information about Deepwater Horizon restoration and the MDBC restoration projects is available at: www.gulfspillrestoration.noaa.gov.

Gulf of Mexico↗
USGS1999

Gas and Isotope Geochemistry of 81 Steam Samples from Wells in The Geysers Geothermal Field, Sonoma and Lake Counties, California

The Geysers geothermal field in northern California, with about 2000-MW electrical capacity, is the largest geothermal field in the world. Despite its importance as a resource and as an example of a vapor-dominated reservoir, very few complete geochemical analyses of the steam have been published (Allen and Day, 1927; Truesdell and others, 1987). This report presents data from 90 steam, gas, and condensate samples from wells in The Geysers geothermal field in northern California. Samples were collected between 1978 and 1991. Well attributes include sampling date, well name, location, total depth, and the wellhead temperature and pressure at which the sample was collected. Geochemical characteristics include the steam/gas ratio, composition of noncondensable gas (relative proportions of CO2, H2S, He, H2, O2, Ar, N2, CH4, and NH3), and isotopic values for deltaD and delta18O of H2O, delta13C of CO2, and delta34S of H2S. The compilation includes 81 analyses from 74 different production wells, 9 isotopic analyses of steam condensate pumped into injection wells, and 5 complete geochemical analyses on gases from surface fumaroles and bubbling pools. Most samples were collected as saturated steam and plot along the liquid-water/steam boiling curve. Steam-togas ratios are highest in the southeastern part of the geothermal field and lowest in the northwest, consistent with other studies. Wells in the Northwest Geysers are also enriched in N2/Ar, CO2 and CH4, deltaD, and delta18O. Well discharges from the Southeast Geysers are high in steam/gas and have isotopic compositions and N2/Ar ratios consistent with recharge by local meteoric waters. Samples from the Central Geysers show characteristics found in both the Southeast and Northwest Geysers. Gas and steam characteristics of well discharges from the Northwest Geysers are consistent with input of components from a high-temperature reservoir containing carbonrich gases derived from the host Franciscan rocks. Throughout the geothermal field, the carbon-isotopic composition of CO2 is consistent with derivation of carbon from Franciscan metasedimentary rocks. NH3 concentrations are high in most Geysers well fluids, and are 2-3 orders of magnitude greater than would be expected in a the gas phase exhibiting homogeneous equilibrium at normal reservoir temperatures and pressures. Evidently, NH3 is flushed from the Franciscan host rocks at a rate that exceeds the reaction rate for NH3 breakdown. Many wells show clear influence by fluids from reinjection wells where steam condensate has been pumped back into the geothermal reservoir. Six wells were resampled over the time period of this study. One of these six wells was strongly affected by a nearby injection well. Three of the six resampled wells showed some signs of decreasing liquid/ steam within the geothermal reservoir, consistent with 'drying out' of the reservoir due to steam withdrawal. However, two wells exhibited little change. Analyses of gases from five surface manifestations (fumaroles and bubbling pools) are roughly similar to the deeper geothermal samples in both chemical and isotopic composition, but are lower in soluble gases that dissolve in groundwater during transit toward the surface.

Open-File Report↗
USGS2006

Near-Field Receiving Water Monitoring of trace metals and a benthic community near the Palo Alto Regional Water Quality Control Plant in South San Francisco Bay, California: 2005

Trace elements in sediment and the clam Macoma petalum (formerly reported as Macoma balthica (Cohen and Carlton 1995)), clam reproductive activity and benthic, macroinvertebrate community structure are reported for a mudflat one kilometer south of the discharge of the Palo Alto Regional Water Quality Control Plant in South San Francisco Bay. This report includes data collected for the period January to December 2005, and extends a critical long-term biogeochemical record dating back to 1974. These data serve as the basis for the City of Palo Alto’s Near-Field Receiving Water Monitoring Program, initiated in 1994. Metal concentrations in both sediments and clam tissue during 2005 were consistent with results observed since 1990. Copper and zinc concentrations in sediment and bivalve tissue displayed a continued decrease over the last decade. In 2005, Cu concentrations were at or below the effects range-low (ERL) concentration (34 µg/g) for the entire year, the first time this has been observed. Also, zinc concentrations never exceeded the ERL (150 µg/g). Yearly average concentrations of copper, zinc and silver in Macoma petalum for 2005 were some of the lowest recorded since monitoring for metals began in 1975. The concentrations of mercury and selenium in sediments, during April and January 2004, respectively, were the highest values observed for these elements during this study. Later in 2005, concentrations decreased to historic levels. The increase in mercury and selenium in 2004 was not a permanent trend and concentrations of these elements in sediments and clams at Palo Alto remain similar to concentrations observed elsewhere in the San Francisco Bay. Analyses of the benthic-community structure of a mudflat in South San Francisco Bay over a 31-year period show that changes in the community have occurred concurrent with with reduced concentrations of metals in the sediment and in the tissues of the biosentinal clam Macoma petalum from the same area. Analysis of the reproductive activity of M. petalum shows increases in reproductive activity concurrent with the decline in metal concentrations in the tissues of this organism. Reproductive activity is presently stable with almost all animals initiating reproduction in the fall and spawning the following spring of most years. The community has shifted from being dominated by several opportunistic species to a community where the species are more similar in abundance, a pattern that suggests a more stable community that is subjected to less stress. In addition, two of the opportunistic species ( Ampelisca abdita and Streblospio benedicti ) that brood their young and live on the surface of the sediment in tubes have shown a continual decline in dominance coincident with the decline in metals. Heteromastus filiformis , a subsurface polychaete worm that lives in the sediment, consumes sediment and organic particles residing in the sediment, and reproduces by laying their eggs on or in the sediment has shown a concurrent increase in dominance. These changes in species dominance reflect a change in the community from one dominated by surface dwelling, brooding species to one with species with varying life history characteristics. For the first time since its invasion in 1986, the non-indigenous filter-feeding bivalve Corbula ( Potamocorbula ) amurensis has shown up in small but persistent numbers in the benthic community.

California↗
USGS2005

Chemistry of runoff and shallow ground water at the Cattlemans Detention basin site, South Lake Tahoe, California, August 2000-November 2001

A study at the Cattlemans detention basin site began in November 2000. The site is adjacent to Cold Creek in South Lake Tahoe, California. The purpose of the study is to evaluate the effects of the detention basin on ground-water discharge and changes in nutrient loads to Cold Creek, a tributary to Trout Creek and Lake Tahoe. The study is being done in cooperation with the Tahoe Engineering Division of the El Dorado County Department of Transportation. This report summarizes data collected prior to and during construction of the detention basin and includes: (1) nutrient and total suspended solid concentrations of urban runoff; (2) distribution of unconsolidated deposits; (3) direction of ground-water flow; and (4) chemistry of shallow ground water and Cold Creek. Unconsolidated deposits in the area of the detention basin were categorized into three classes: fill material consisting of a red-brown loamy sand with some gravel and an occasional cobble that was placed on top of the meadow; meadow deposits consisting of gray silt and sand with stringers of coarse sand and fine gravel; and a deeper brown to yellow-brown sand and gravel with lenses of silt and sand. Prior to construction of the detention basin, ground water flowed west-northwest across the area of the detention basin toward Cold Creek. The direction of ground-water flow did not change during construction of the detention basin. Median concentrations of dissolved iron and chloride were 500 and 30 times higher, respectively, in ground water from the meadow deposits than dissolved concentrations in Cold Creek. Median concentration of sulfate in ground water from the meadow deposits was 0.4 milligrams per liter and dissolved oxygen was below the detection level of 0.3 milligrams per liter. The relatively high concentrations of iron and the lack of sulfate in the shallow ground water likely are caused by chemical reactions and biological microbial oxidation of organic matter in the unconsolidated deposits that result in little to no dissolved oxygen in the ground water. The higher chloride concentrations in ground water compared with Cold Creek likely are caused from the application of salt on Pioneer Trail and streets in Montgomery Estates subdivision during the winter. Runoff from these roads contributes to the recharge of the shallow ground water. The range of dissolved constituents generally was greater in the meadow deposits than in the deeper sand and gravel. Ammonia plus organic nitrogen were the dominant forms of dissolved nitrogen and concentrations ranged from 0.04 to 18 milligrams per liter as nitrogen. Highest concentration was beneath the middle of the detention basin. Nitrate plus nitrite concentrations were low (<0.33 milligrams per liter as nitrogen) throughout the area and dissolved phosphorus concentrations ranged from 0.001 to 0.34 milligrams per liter. Nitrogen and dissolved organic carbon showed no consistent pattern in the direction of ground-water flow, which suggests that, similar to iron and sulfate, local variations in the chemical and biological reactions within the meadow deposits controlled the variation in nitrogen concentrations. The gradual increase in dissolved phosphorus along the direction of ground-water flow suggest that phosphorus may be slowly dissolving into ground water. Dissolved phosphorus was consistently low in July, which may be the result of greater microbial activity in the unconsolidated deposits or from uptake by roots during the summer.

Scientific Investigations Report↗
USGS1997

Nitrate in ground water and stream base flow in the lower Susquehanna River Basin, Pennsylvania and Maryland

High concentrations of nitrate in both ground and surface water have been identified as a significant water-quality issue in the Lower Susquehanna River Basin. This report uses data collected by the National Water Quality Assessment (NAWQA) Program in the basin and compares nitrate concentrations found in ground water and surface water on both a spatial and temporal basis and relates nitrate concentrations to land use. Nitrate concentrations in the Lower Susquehanna River Basin in Pennsylvania and Maryland were higher in ground water than in surface water in agricultural areas underlain by carbonate bedrock and agricultural areas underlain by crystalline bedrock. Nitrate concentrations were higher in surface water than in ground water in urban areas underlain by carbonate bedrock. Nitrate concentrations also were higher in surface water than ground water in both agricultural and forested areas underlain by sandstone and shale. Nitrate concentrations in ground water vary in areas with different land use and bedrock type. Ground-water nitrate concentrations were highest in agricultural areas underlain by carbonate bedrock, where 45 percent of the samples exceeded the U.S. Environmental Protection Agency (USEPA) Maximum Contaminant Level (MCL) of 10 mg/L (milligrams per liter as N). Waters from 36 percent of the wells in agricultural areas underlain by crystalline bedrock also had nitrate concentrations greater than 10 mg/L. Nitrate concentrations in water from wells in urban areas underlain by carbonate bedrock and in forested and agricultural areas underlain by sandstone and shale seldom exceeded the MCL. Nitrate concentrations were generally higher in surface water in areas underlain by carbonate bedrock than in areas underlain by noncarbonate bedrock; however, when an agricultural area underlain by carbonate bedrock and an agricultural area underlain by sandstone and shale with similar manure application rates were compared, nitrate concentrations in surface water were not significantly different. A comparison of three agricultural areas underlain by carbonate bedrock shows that the manure application rate is strongly correlated with nitrate concentration. Nitrate concentrations in stream base flow at seven sites where samples were collected throughout the year were commonly higher in the winter months than in the summer months. A statistically significant correlation between streamflow and nitrate concentration existed for six of the seven sites, indicating that seasonal variability in precipitation may be the cause of some of the seasonal variation in concentration. Other possible explanations for this variation include the seasonal cycle in plant uptake of nitrogen and seasonal fluctuations in uptake of nitrate by algae in streams. Because no information was available about the traveltime for ground water, interpretation of this temporal variation was not conclusive. Estimates of base-flow loads and yields of nitrate showed that agricultural areas underlain by carbonate bedrock provide the highest yield of nitrate when compared with the other areas studied. Agricultural areas underlain by sandstone and shale and crystalline bedrock also provide large amounts of nitrate to the river. The large amount of nitrate in the water from these areas cause a significant increase in nitrate loads transported by the Susquehanna River to the Chesapeake Bay. Urban areas underlain by carbonate bedrock had a high yield of nitrate but comprise such a small part of the basin that the nitrate load from these areas was small. In contrast, forested areas underlain by sandstone and shale bedrock had low base-flow nitrate yields, but these areas comprise a large percentage of the basin, making the overall nitrate load from these areas high.

Maryland, Pennsylvania↗
USGS1988

Concurrent mobile on-site and in situ striped bass contaminant and water quality studies in the Choptank River and upper Chesapeake Bay

In situ and mobile on-site striped bass prolarval and yearling survival studies were conducted in the Choptank River and in the Chesapeake and Delaware (C & D) Canal area of the Upper Chesapeake Bay. Extensive chemical analyses of both organic and inorganic contaminants in the habitat water were performed and water quality parameters were monitored during these experiments. Surviving yearling striped bass were subjected to histological examination. Prolarval survival data from both the in situ and mobile on-site studies were similar for each spawning area. Prolarval survival ranged from 30 to 45% after 96 h of exposure to Choptank River water in four separate experiments (two in situ , two on-site); control survival was greater than 74%. Based on a comparison of laboratory toxicity data and reported field concentrations in the Choptank River for various water quality and contaminant conditions, the following combination of conditions was potentially stressful to striped bass prolarvae: low hardness (36 to 48 mg/L CaCO 3 ), monomeric aluminum (0.150 mg/L), cadmium (0.003 mg/L) and copper (0.040 mg/L). Yearling survival in both in situ and on-site tests ranged from 93 to 100% in both the control and Choptank River water after 9 d of exposure. Survival of striped bass prolarvae in C & D Canal water ranged from 52.5 to 70% after 96 h of exposure in four separate experiments. Control survival of prolarvae was not significantly different. Survival of yearling striped bass in on-site and in situ tests was 95% or greater in C & D Canal water and control water. Acute contaminant effects were not verified in the C & D Canal area.

Environmental Toxicology and Chemistry↗
USGS2018

Preliminary assessment of stable nitrogen and oxygen isotopic composition of USGS51 and USGS52 nitrous oxide reference gases and perspectives on calibration needs

Rationale Despite a long history and growing interest in isotopic analyses of N 2 O, there is a lack of isotopically characterized N 2 O isotopic reference materials (standards) to enable normalization and reporting of isotope‐delta values. Here we report the isotopic characterization of two pure N 2 O gas reference materials, USGS51 and USGS52, which are now available for laboratory calibration ( https://isotopes.usgs.gov/lab/referencematerials.html ). Methods A total of 400 sealed borosilicate glass tubes of each N 2 O reference gas were prepared from a single gas filling of a high vacuum line. We demonstrated isotopic homogeneity via dual‐inlet isotope‐ratio mass spectrometry. Isotopic analyses of these reference materials were obtained from eight laboratories to evaluate interlaboratory variation and provide preliminary isotopic characterization of their δ 15 N, δ 18 O, δ 15 N α , δ 15 N β and site preference ( S P ) values. Results The isotopic homogeneity of both USGS51 and USGS52 was demonstrated by one‐sigma standard deviations associated with the determinations of their δ 15 N, δ 18 O, δ 15 N α , δ 15 N β and S P values of 0.12 mUr or better. The one‐sigma standard deviations of S P measurements of USGS51 and USGS52 reported by eight laboratories participating in the interlaboratory comparison were 1.27 and 1.78 mUr, respectively. Conclusions The agreement of isotope‐delta values obtained in the interlaboratory comparison was not sufficient to provide reliable accurate isotope measurement values for USGS51 and USGS52. We propose that provisional values for the isotopic composition of USGS51 and USGS52 determined at the Tokyo Institute of Technology can be adopted for normalizing and reporting sample data until further refinements are achieved through additional calibration efforts.

Rapid Communications in Mass Spectrometry↗
USGS2023

Turbulence near a sandbar island in the lower Missouri River

River turbulence is spatially variable due to interactions between morphology of rivers and physical mechanics of flowing water. Understanding the variation of turbulence in rivers is important for characterizing transport processes of soluble and particulate materials in these systems. We present an exploratory effort to understand ecologically relevant flow patterns using measurements of mean flow and turbulence in a highly engineered river channel around an island in the lower Missouri River. Specifically, the profiles of mean river velocities were investigated to examine the logarithmic relation and associated parameters, including shear velocity and bed roughness. Turbulence intensity and Reynolds shear stress were compared with classic open-channel profiles and previously reported river data in the hydraulics literature. With the capability of pulse-to-pulse coherent Doppler velocity profiling in high spatial resolution, we estimated the profiles of turbulence dissipation rate using resolved one-dimensional velocity spectra. These measurement data allow us to examine the validity of turbulence production-dissipation balance and the classic open-channel profiles of turbulence statistics, including turbulence intensity, Reynolds shear stress, dissipation rate, and eddy viscosity. The field data show a strong variation of turbulence profiles in close vicinity of the river island. In shallow water depths close to the island, turbulence is substantially enhanced in comparison with classic open-channel profiles. Such turbulence enhancement is likely attributed to non-uniformity of the flow structures.

Missouri↗