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At least 109 records · Page 6Linked to original sources

Whole-rock and glass major-element geochemistry of Kilauea Volcano, Hawaii, near-vent eruptive products: September 1994 through September 2001

This report presents major-element geochemical data for glasses and whole-rock aliquots among 523 lava samples collected near the vent on Kilauea's east rift zone between September 1994 and October 2001. Information on sample collection, analysis techniques and analytical standard reproducibility are presented as a PDF file, which also includes a detailed explantion of the categories of sample information presented in the database spreadsheet. The sample database is downloadable as a separate Microsoft Excel file.

Hawai'i

Shallow differentiation of primitive arc magmas at the Jurassic Emigrant Gap mafic complex, Sierra Nevada, California

The Emigrant Gap composite pluton exposes ultramafic to silicic intrusive rocks that preserve the chemical evolution of primitive mafic arc magmas and their open-system interactions in the upper crust during mid-Jurassic growth of the Sierra Nevada batholith (California). We present field and petrographic observations and mineral and whole-rock chemistry of the ~35-km 2 ultramafic to dioritic Emigrant Gap mafic complex and an adjacent penecontemporaneous ~90-km 2 granodiorite that together make up the composite pluton. In the Emigrant Gap mafic complex, four roughly central masses of dunite, wehrlite, and olivine clinopyroxenite are surrounded by weakly layered gabbronorite and non-layered diorite. The ultramafic rocks are cumulates formed from near-liquidus minerals of primitive arc magmas that accumulated in steep feeder zones with substantial modification by melt–mush reaction as primitive liquids repeatedly transited the mush-filled conduits. The dominant gabbronoritic rocks are the variably accumulative products of more advanced crystallization–differentiation of arc tholeiitic basalts and basaltic andesites. The adjacent granodiorite intrusion originated separately and preserves field and geochemical evidence for assimilation of metasedimentary rocks. Open-system hybridization between the gabbronoritic mushes and the granodioritic magma produced an intervening body of two-pyroxene diorite. We infer that the ultramafic rocks and gabbronorite of the Emigrant Gap mafic complex crystallized from near-primitive arc basaltic to basaltic andesitic magmas at ~0.15–0.3 GPa, with estimated f O 2 of ≥FMQ +1 and dissolved H 2 O concentrations of only ~0.5–2 wt %. Notably, the Emigrant Gap composite pluton is distinct from other Mesozoic plutons in the Sierra Nevada batholith because of (1) its abundance of mafic and ultramafic rocks that crystallized from relatively primitive mafic melts and (2) the low inferred H 2 O concentrations of its parental magmas, indicated by a near absence of igneous amphibole and by the intermediate rather than calcic compositions of plagioclase. A Jurassic regional extension event probably accounts for the formation of relatively dry primitive arc magmas, as well as for their ascending to the upper crust.

California

Tectonics of the North American Cordillera near the Fortieth Parallel

The North American Cordillera near the Fortieth Parallel consists of the following tectonic units: 1. (A) To the east is a reactivated cratonic area, in the Southern Rocky Mountains and Colorado Plateau, in which the supracrustal rocks (Cambrian to Cretaceous) were broadly deformed during the late Cretaceous-Paleocene Laramide orogeny, and the Precambrian basement was raised in folds of wide amplitude. 2. (B) West of it is a miogeosynclinal belt, in the eastern Great Basin, in which a thick sequence of Paleozoic carbonates and related deposits was thrust eastward along low-angle faults during the middle to late Cretaceous Sevier orogeny. The miogeosyncline is the downwarped western margin of the original North American continent, and its rocks accumulated on Precambrian basement. 3. (C) Beyond is a eugeosynclinal belt, in the western Great Basin, in which Paleozoic graywackes, cherts, and volcanics were thrust easteastward along low-angle faults during several Paleozoic orogenies - the mid-Paleozoic Antler orogeny which produced the Roberts thrust on the east, and the end-Paleozoic Sonoma orogeny which produced the Golconda thrust farther west. The Paleozoic eugeosynclinal rocks accumulated on oceanic basement. They are overlapped from the west by Triassic and Jurassic shelf deposits, which pass westward into eugeosynclinal deposits. 4. (D) A volcanic island-arc belt existed on the sites of the Sierra Nevada in Paleozoic and early Mesozoic time, which produced thick bodies of sediments and volcanics. During the mid-Mesozoic Nevadan orogeny these were steeply deformed and thrust westward over subduction zones, and were intruded by granitic rocks that rose from the upper mantle to form great batholiths. 5. (E) West of the Sierra Nevada, in the Great Valley, is a great sedimentary embankment of later Mesozoic flysch or turbidite, largely younger than the supracrustal rocks of the Sierra Nevada and the Nevadan orogeny. It was formed of the erosional products of the supracrustal and granitic rocks of the Sierra Nevada. 6. (F) This sequence is, in turn, thrust westward over the Mesozoic Franciscan terrane of the Coast Ranges, which forms the westernmost belt of the Cordillera, and which is being treated in other papers in this symposium. The net effect of the prolonged events that produced the Cordillera in this segment has been the addition of successive tectonic belts to the North American continent at the expense of the Pacific Ocean basin during Phanerozoic time.

Tectonophysics

A preliminary evaluation of vertical separation between production intervals of coalbed-methane wells and water-supply wells in the Raton basin, Huerfano and Las Animas Counties, Colorado, 1999-2004

The Raton Basin in southern Colorado and northern New Mexico is undergoing increased development of its coalbed-methane resources. Annual production of methane from coalbeds in the Raton Basin in Huerfano and Las Animas Counties, Colorado, increased from about 28,000,000 thousand cubic feet from 478 wells to about 80,000,000 thousand cubic feet from 1,543 wells, during 1999-2004. Annual ground-water withdrawals for coalbed-methane production increased from about 1.45 billion gallons from 480 wells to about 3.64 billion gallons from 1,568 wells, during 1999-2004. Where the coalbeds are deeply buried near the center of the Raton Basin, water pressure may be reduced as much as 250 to 300 pounds per square inch to produce the methane from the coalbeds, which is equivalent to a 577- to 692-foot lowering of water level. In 2001, the U.S. Geological Survey, in cooperation with the Colorado Water Conservation Board, began an evaluation of the potential effects of coalbed- methane production on the availability and sustainability of ground-water resources. In 2003, there were an estimated 1,370 water-supply wells in the Raton Basin in Colorado, and about 90 percent of these water-supply wells were less than 450 feet deep. The tops of the production (perforated) interval of 90 percent of the coalbed-methane wells in the Raton Basin (for which data were available) are deeper than about 675 feet. The potential for interference of coalbed-methane wells with nearby water-supply wells likely is limited because in most areas their respective production intervals are separated by more than a hundred to a few thousand feet of rock. The estimated vertical separation between production intervals of coalbed-methane and water-supply wells is less than 100 feet in an area about 1 to 6 miles west and southwest of Trinidad Lake and a few other isolated areas. It is assumed that in areas with less than 100 feet of vertical separation, production by coalbed-methane wells has a greater potential for interfering with nearby water-supply wells. More detailed geologic and hydrologic information is needed in these areas to quantify the potential effects of coalbed-methane production on water levels and the availability and sustainability of ground-water resources.

Scientific Investigations Report

Oil–source correlation studies in the shallow Berea Sandstone petroleum system, eastern Kentucky

Shallow production of sweet high-gravity oil from the Upper Devonian Berea Sandstone in northeastern Kentucky has caused the region to become the leading oil producer in the state. Potential nearby source rocks, namely, the overlying Mississippian Sunbury Shale and underlying Ohio Shale, are immature for commercial oil generation according to vitrinite reflectance and programmed pyrolysis analyses. We used organic geochemical measurements from Berea oils and solvent extracts from potential Upper Devonian–Mississippian source rocks to better understand organic matter sources, oil–oil and oil–source rock correlations, and thermal maturity in the shallow Berea oil play. Multiple geochemical proxies suggest Berea oils are from one family and from similar source rocks. Oils and organic matter in the potential source rocks are from a marine source based on pristane-to-phytane (Pr/Ph) and terrestrial-to-aquatic ratios, carbon preference index values, n - alkane maxima, C-isotopic composition, and tricyclic terpane and hopane ratios. Any or all of the Devonian to Mississippian black shale source rocks could be potential source rocks for Berea oils based on similarities in oil and solvent extract Pr/n - C 17 and Ph/n - C 18 ratios, sterane distributions, C-isotopic values, and sterane/hopane and tricyclic terpane ratios. Multiple biomarker ratios suggest Berea oils formed at thermal maturities of approximately 0.7% –0.9% vitrinite reflectance. These data require significant updip lateral migration of 30–50 mi from a downdip Devonian black shale source kitchen to emplace low-sulfur oils in the shallow updip oil-play area and indicate that immature source rocks nearby to Berea oil production are not contributing to produced hydrocarbons.

Kentucky

The Talara Basin province of northwestern Peru: cretaceous-tertiary total petroleum system

More than 1.68 billion barrels of oil (BBO) and 340 billion cubic feet of gas (BCFG) have been produced from the Cretaceous-Tertiary Total Petroleum System in the Talara Basin province, northwestern Peru. Oil and minor gas fields are concentrated in the onshore northern third of the province. Current production is primarily oil, but there is excellent potential for offshore gas resources, which is a mostly untapped resource because of the limited local market for gas and because there are few pipelines. Estimated mean recoverable resources from undiscovered fields in the basin are 1.71 billion barrels of oil (BBO), 4.79 trillion cubic feet of gas (TCFG), and 255 million barrels of natural gas liquids (NGL). Of this total resource, 15 percent has been allocated to onshore and 85 percent to offshore; volumes are 0.26 BBO and 0.72 TCFG onshore, and 1.45 BBO and 4.08 TCFG offshore. The mean estimate of numbers of undiscovered oil and gas fields is 83 and 27, respectively. Minimum size of fields that were used in this analysis is 1 million barrels of oil equivalent and (or) 6 BCFG. The Paleocene Talara forearc basin is superimposed on a larger, Mesozoic and pre-Mesozoic basin. Producing formations, ranging in age from Pennsylvanian to Oligocene, are mainly Upper Cretaceous through Oligocene sandstones of fluvial, deltaic, and nearshore to deep-marine depositional origins. The primary reservoirs and greatest potential for future development are Eocene sandstones that include turbidites of the Talara and Salinas Groups. Additional production and undiscovered resources exist within Upper Cretaceous, Paleocene, and Oligocene formations. Pennsylvanian Amotape quartzites may be productive where fractured. Trap types in this block-faulted basin are mainly structural or a combination of structure and stratigraphy. Primary reservoir seals are interbedded and overlying marine shales. Most fields produce from multiple reservoirs, and production is reported commingled. For this reason, and also because geochemical data on oils and source rocks is very limited, Tertiary and Cretaceous production is grouped into one total petroleum system. The most likely source rocks are Tertiary marine shales, but some of the Cretaceous marine shales are also probable source rocks, and these would represent separate total petroleum systems. Geochemical data on one oil sample from Pennsylvanian rock indicates that it was probably also sourced from Tertiary shales.

Bulletin

Spatiotemporal drivers of water quality and phytoplankton communities in a cyanobacteria-dominated reservoir provide management insights

Reservoirs serve critical roles providing drinking water, irrigation, flood control, hydropower, recreation, fisheries, and aquatic habitat. Yet their physical position, complex shape, and large watersheds make reservoirs especially susceptible to eutrophication and harmful algal bloom (HAB) production. Boysen Reservoir, WY, is a high priority for proactive nutrient management because it is an important source for drinking water and recreation, and has a history of toxic cyanobacterial blooms. We combined four years of comprehensive monitoring efforts by state and federal agencies to characterize the spatiotemporal patterns of nutrient inflow, internal water quality dynamics, and phytoplankton community shifts in Boysen Reservoir. We found nutrient inflow was hydrologically driven, with snowmelt runoff transporting high nutrient loads. Our findings suggest physicochemical and nutrient conditions of the reservoir were strongly different between the furthest reaches of the reservoir, but less variable among the intermediate sites. Space did not play a role in phytoplankton community dynamics, but time was an important factor. Cyanobacteria dominated phytoplankton communities by mid-summer across the reservoir and were driven mainly by temporal physicochemical conditions, like stratification and water temperature. The two most dominant phytoplankton taxa across the four years of sampling were N-fixing, toxin producing cyanobacteria. Extensive monitoring efforts and data analyses can illuminate strategies to safeguard water resources via understanding the drivers of water quality changes and HAB production.

Wyoming

Geology and origin of epigenetic lode gold deposits, Tintina Gold Province, Alaska and Yukon

More than 50 million ounces of lode gold resources have been defined in the previous 15 years throughout accreted terranes of interior Alaska and in adjacent continental margin rocks of Yukon. The major deposits in this so-called Tintina Gold Province formed around 105 to 90 million years ago in east-central Alaska and Yukon, and around 70 million years ago in southwestern Alaska, late in the deformational history of their host rocks. All gold deposits studied to date formed from CO 2 -rich and 18 O-rich crustal fluids, most commonly of low salinity. The older group of ores includes the low-grade intrusion-related gold systems at Fort Knox near Fairbanks and those in Yukon, with fluids exsolved from fractionating melts at depths of 3 to 9 kilometers and forming a zoned sequence of auriferous mineralization styles extending outward to the surrounding metasedimentary country rocks. The causative plutons are products of potassic mafic magmas generated in the subcontinental lithospheric mantle that interacted with overlying lower to middle crust to generate the more felsic ore-related intrusions. In addition, the older ores include spatially associated, high-grade, shear-zonerelated orogenic gold deposits formed at the same depths from upward-migrating metamorphic fluids; the Pogo deposit is a relatively deep-seated example of such. The younger gold ores, restricted to southwestern Alaska, formed in unmetamorphosed sedimentary rocks of the Kuskokwim basin within 1 to 2 kilometers of the surface. Most of these deposits formed via fluid exsolution from shallowly emplaced, highly evolved igneous complexes generated mainly as mantle melts. However, the giant Donlin Creek orogenic gold deposit is a product of either metamorphic devolatilization deep in the basin or of a gold-bearing fluid released from a flysch-melt igneous body.

Alaska, Yukon

Geology and resources of thorium and associated elements in the Wet Mountains area, Fremont and Custer counties, Colorado

Thorium in potentially economic amounts occurs in three types of deposits in the Wet Mountains area of Colorado: (1) quartz-baritethorite veins and fracture zones, (2) carbonatite dikes, and (3) red syenite dikes. The quartz-barite-thorite veins and fracture zones contain the largest resources of thorium; they cut all Precambrian and Paleozoic rock types in the area and tend to strike normal to the foliation in the Proterozoic metasedimentary and metavolcanic rocks. The veins and fracture zones are end products of the episode of Cambrian alkaline magmatism that also produced rocks of the McClure Mountain Complex, the Gem Park Complex, the complex at Democrat Creek, and associated dikes of carbonatite, lamprophyre, and red syenite. The veins and fracture zones contain an average of 0.46 percent ThO2, 0.21 percent SLREE (total light rare-earth elements), 0.14 percent SHREE (total heavy rare-earth elements), and 0.012 percent Nb2O5; They contain reserves of 64,200 tons ThO2, 29,300 tons SLREE, 19,540 tons SHREE, 1,675 tons Nb2O5; they contain probable potential resources of 160,500 tons ThO2, 73,270 tons SLREE, 48,850 tons SHREE, and 4,185 tons Nb2O5. The carbonatite dikes form two distinct groups: replacement carbonatites and primary magmatic carbonatites. The latter group appears to be the better source of potentially economic commodities. The primary magmatic carbonatites contain an average of 0.17 percent ThO2, 0.0097 percent Nb2O5, 0.0031 percent U3O5, and 2.15 percent total rare-earth oxides. The seven largest dikes contain reserves of 131 tons ThO2, 40 tons Nb2O5, 17 tons U3O5, and 2,500 tons SRE203 (total rare-earth oxides), and probable potential resources of 753 tons ThO2, 228 tons Nb2O5, 105 tons U3O5, and 14,300 tons SRE2O3. The red syenite dikes contain anomalous amounts of thorium, uranium, niobium, and rare-earth elements. Although reserves and probable potential resources have not been calculated, they are likely to be small.

Professional Paper

A compilation of whole-rock and glass major-element geochemistry of Kilauea Volcano, Hawai'i, near-vent eruptive products: January 1983 through September 2001

This report presents major-element geochemical data from 652 glasses (~6,520 analyses) and 795 whole-rock aliquots from 1,002 fresh samples of olivine-tholeiitic lava collected throughout the near-continuous eruption of Kïlauea Volcano, Hawai'i, from January 1983 through September 2001. The data presented herein provide a unique temporal compilation of lava geochemistry that best reflects variations of pre-eruptive magma compositions during prolonged rift-zone eruption. This document serves as a repository for geochemical data referred to in U.S. Geological Survey Professional Paper 1676 (Heliker, Swanson, and Takahashi, eds., 2003) which includes multidisciplinary research papers pertaining to the first twenty years of Puu Oo-Kupaianaha eruption activity. Details of eruption characteristics and nomenclature are provided in the introductory chapter of that volume (Heliker and Mattox, 2003). Geochemical relations among all or portions of this data set are depicted and interpreted by Thornber (2003), Thornber and others (2003) and Thornber (2001). Trace element compositions and Nd, Sr and Pb isotopic analyses of representative samples of this select eruption suite will be provided in a separate and complimentary open file report. From 1983 to October 2001, approximately 2,500 eruption samples were collected and archived by the U.S. Geological Survey’s Hawaiian Volcano Observatory (HVO). Geochemical data for 1,002 of these samples are included here. Previous reports present bulk-lava major- element chemistry for eruption samples collected from 1983 to 1986 and from 1990 to 1994 (Neal and others, 1988 and Mangan and others, 1995, respectively). Major element glass chemistry and thermometry data for samples collected from 1983 to 1994 is reported by Helz and Hearn (1998) and whole-rock and glass chemistry for samples collected from September 1994 to October 2001 is provided by Thornber and others (2002). This report is a compilation of previously published data along with unpublished whole-rock data for the 1986–1990 eruptive interval (episode 48, see Heliker and Mattox, 2003). The geochemical data in this report is mostly limited to well-quenched samples collected at or near their respective vents. The samples include tephra and spatter, in addition to lava dipped from lava lakes, lava tubes, and surface lava flows. The details of sample collection techniques as described by Thornber and others (2002) are generally applicable for this entire sampling interval. Specifically excluded from this database are samples of distal surface flows, many of which were collected for topical studies of emplacement dynamics (for example, Cashman and others, 1999). Samples of sluggish or crystal-laden tube flows collected during eruptive pauses were also excluded, because they bear visual, petrographic and geochemical evidence for crystal accumulation during surface-flow stagnation. In addition, the pre-1992 whole-rock major element data reported here has been corrected to compensate for minor analytical discrepancies between pre- and post-1991 XRF analyses. These discrepancies resulted from a change in instrumentation at the USGS Denver analytical laboratories. This select suite of time-constrained geochemical data is suitable for constructing petrologic models of pre-eruptive magmatic processes associated with prolong rift zone eruption of Hawaiian shield volcanoes.

Hawai'i

Hydrous heating experiments at 130°C yield insights into the occurrence of hydrogen sulfide and light alkanes in natural gas reservoirs

Improved understanding of the origin of produced volatiles from conventional reservoirs and unconventional source rocks is critical for petroleum exploration and production. A series of hydrous heating experiments using two immature Type II siliciclastic source rocks, Pennsylvanian Turner Mine shale (TMS) and Devonian New Albany Shale (NAS), at 130 °C over one to two years were conducted to assess gas generation at low temperature. Elemental sulfur (ES) was added to the NAS samples to evaluate the role of sulfur on thermochemical sulfate reduction (TSR). The produced volatile composition was investigated in situ using Raman spectroscopy at the end of the heating experiments. Results show that the two source rocks yield different types and concentrations of volatiles. Only CH 4 and CO 2 were detected following hydrous heating of the TMS source rock in contrast to CH 4 , C 2 H 6 , C 3 H 8 , and CO 2 which were observed in experiments using NAS. Variations in the produced volatiles are likely the result of compositional differences within the respective source rock organic matter. Experiments involving ES show strong H 2 S signals that are likely due to the formation of H 2 S from the reaction of ES with water at 130 °C. H 2 S signals correlate with a greater relative concentration of CH 4 and CO 2 compared to experiments where ES was not added, on a time-normalized basis. The correlation between the presence of H 2 S and an increase in CH 4 and CO 2 concentration could indicate the occurrence of TSR. Here we propose that H 2 S in siliciclastic shale can be generated in the presence of ES at low temperatures via both disproportionation of ES into H 2 S and SO 4 2– , and TSR. Our findings from this study provide experimental evidence that may aid efforts to interpret the origin of H 2 S in low-temperature sedimentary basins.

Pennsylvania

Lead and strontium isotopes and related trace elements as genetic tracers in the Upper Cenozoic rhyolite-basalt association of the Yellowstone Plateau volcanic field

Supported by various field geologic and petrologic data, the contents of Pb, U, Th, Rb, and Sr and the isotopic compositions of Pb and Sr for upper Cenozoic volcanic rocks of the Yellowstone Plateau volcanic field are consistent with the hypothesis of derivation of the basaltic and rhyolitic magmas by partial melting of distinct source regions in the upper mantle and lower crust, respectively. All the basalt samples analyzed but one have systematically lower values of 207 Pb/ 204 Pb and 87 Sr/ 86 Sr than the rhyolites. The values of 206 Pb/ 204 Pb are smaller, and 87 Sr/ 86 Sr are mostly larger than known values in oceanic basalts. In all but one case, the values of 207 Pb/ 204 Pb are higher than expected from an extrapolation of known values in oceanic basalts to less radiogenic values of 206 Pb/ 204 Pb. Because there are no xenoliths, phenocrysts are only moderate to sparse in abundance, REE patterns are low and flat at the radiogenic end of lead isotopic compositions, several values of Rb/Sr are low, and 80% of the basalt samples form a well-developed secondary isochron separate from the rhyolites, we favor an interpretation for basalt genesis wherein isotopic signatures of most mafic magmas were attained in a continental ‘keel’ of mantlelike character about 2.6 b.y. old or somewhat older attached to the crust, and these signatures were unaltered by magma passage through the crust. At the very least, the current data continue to cast serious doubt as to the inevitability of crustal contamination for basaltic magma intruding the continental environment and postulate that much can be learned about the mantle under continents through the study of continental basalts. One basalt unit with an unusually low value of 207 Pb/ 204 Pb and an 87 Ar/ 86 Ar less than 0.704 may represent subcontinental ‘keel’-derived magma that rose unaltered to the surface. Our data also are not consistent with formation of this rhyolite-basalt association primarily by such processes as crystal fractionation, separation of immiscible silicate liquids from a common parental magma, or fractional melting of a homogeneous source. Rather as a conceptual model, we envision large mafic intrusions to have been injected into the lower crust resulting in rhyolite generation through partial anatexis of the adjacent wall rocks which probably had a 206 Pb/ 204 Pb < 17 and 87 Sr/ 86 Sr > 0.709; a model that has much in common with that proposed by Holmes (1931). All the other hypotheses listed have the necessary added complication that either the basalt or the rhyolite or both become contaminated after the two magma types separated, have problems accounting for the lack of igneous rocks of intermediate compositions or production of such large volumes of rhyolitic material (∼5000 km 3 ), and fail to explain why rhyolitic magma is not a more common occurrence in the ocean basin. We appeal to bouyancy of rhyolites to generate a barrier for basalt magma migration and account for the great preponderance of rhyolite relative to basalt at the surface. Furthermore, the complex isotopic picture in the rhyolites indicates that many of these magmas interacted with the upper crustal geologic units that they traversed. The interactions involved diverse processes, probably including reacton with hydrothermal fluids or hydrothermally altered rocks at high levels as well as by contamination with Phanerozoic sedimentary and Precambrian crystalline rocks at deeper levels. At the very least, we feel our study adds a cautionary note to the currently increasingly popular hypothesis that differentiation of basalt or gabbro magmas to rhyolite or granite (as distinct from tonalite or dacite) is a common occurrence and is therefore an important continential building process. Models for formation of rhyolite and granite predominantly by reworking of crust (anatexis) must still be considered. The primitive Archean mantle of the region was characterized by higher Rb/Sr, U/Pb, and Th/U values than are typical of modern suboceanic mantle. The mantle residuum within the continental subcrustal lithosperic ‘keel’ that resulted from the Archean crustal differentiation event probably was depleted in Rb/Sr and U/Pb, and the crust was correspondingly enriched in these ratios. The crust probably was further differentiated by an Archean high-grade metamorphism, during or after the primary event, into a granulitic lower crust depleted in U/Pb and Rb/Sr and a lower-grade upper crust enriched in these ratios.

Journal of Geophysical Research Solid Earth

What's weathering? Mineralogy and field leach studies in mine waste, Leadville and Montezuma mining districts, Colorado

Weathering is important in the development of rock fabrics that control porosity in mine-waste materials, and in turn, porosity affects metal transport through and from mine-waste piles into watersheds. Mine-waste piles are dynamic physical and chemical systems as evidenced by remnant Fe-oxide boxwork structures after sulfide minerals, development of alteration rinds and etch pits on grains, and precipitation of secondary minerals under low temperature conditions. These microscale changes in the mine-waste materials are the result of partial to total dissolution of sulfide and other minerals. Mine-waste materials from the Dinero, Lower Chatauqua, and Saints John sites, Leadville and Montezuma mining districts, Colorado, exhibit rock fabrics that indicate that weathering products, e.g., Fe oxyhydroxides, jarosite, and clays, have been transported in suspension through the waste piles and deposited in voids and as coatings on rock fragments. Microscale characterization of weathered, partially dissolved minerals lends insight into the source of leachable metals in these mine-waste sites. Mineralogic studies show that galena in the Lower Chatauqua waste is enriched in Ag. Qualitative and semiquantitative microanalysis of weathered, altered galena grains from all three sites show that the Ag-bearing galena is more susceptible to dissolution. It is not surprising, then, that solutions experimentally leached from Lower Chatauqua waste are higher in Pb (2310 ppb) compared to leachates from the Dinero (31 ppb) and Saints John (1360 ppb) wastes. The mobility of metals is increased at acidic pH. Using the USGS Field Leach Test protocol, leachate derived from the Dinero waste has a pH of 3 and high concentrations of Al (443 ppb), Fe (441 ppb), and Zn (7970 ppb). Leachate from Sts. John tailings has a pH about 4 and high concentrations of Mn (1520 ppb), Zn (2240 ppb), and Pb (1360 ppb). Leachate from the Lower Chatauqua waste has an intermediate pH of 5, but in addition to the high Pb level already mentioned, it contains high levels of K (1.9 ppm), Mn (6720 ppb), and Zn (1550 ppb). The high concentration of metals, despite the intermediate pH of the leachate, may be explained by acidic microenvironments that exist at the surfaces of sulfide minerals, where sulfur-and iron-oxidizing microbes may flourish. It is at the reactive mineral-oxygen-water interface where metals are released and low-pH sulfate precipitates such as jarosite-beudantite form.

Colorado

Assessment of the petroleum, coal, and geothermal resources of the Economic Community of West African States (ECOWAS) region

Approximately 85 percent of the land area of the ECOWAS (Economic Community of West African States) region is covered by basement rocks (igneous and highly metamorphosed rocks) or relatively thin layers of Paleozoic, Upper Precambrian, and 'Continental Intercalaire? sedimentary rocks. These areas have little or no petroleum potential. Areas of the ECOWAS region that have potential for petroleum production or potential for increased petroleum production include the narrow belt of sedimentary rocks that stretches along the continental margin from Mauritania to Nigeria and the Niger Delta and the Benue depression. The Senegal Basin, located on the continental margin of Mauritania, Senegal, Gambia, Guinea Bissau, and Guinea, has been intensely explored by the oil industry and most of the larger structures onshore and on the shelf probably have been tested by drilling with little or no resulting commercial production. Unless basic ideas pertaining to the petroleum geology of the Senegal Basin are revised, future discoveries are expected to be limited to small fields overlooked by industry at a time when petroleum prices were low. On the continental shelf of Sierra Leone and the continental shelf of northeast and central Liberia, the sedimentary rocks are relatively thin, and industry has shown little interest in the area. On the continental rise of these countries, however, the sedimentary section, deposited in a complex fault-block system, increases in thickness. A renewal of industry interest in this deep-water area will probably follow further development of deep-water production technology. A recent oil discovery on the continental slope off the Ivory Coast is expected to spur further exploration offshore of southeastern Liberia, Ivory Coast, Ghana, Togo, and Benin. This relatively unexplored area in the Gulf of Guinea has good possibilities .for the discovery of giant oil fields. Nigeria's oil development from the Niger Delta may have peaked, as 13 of 14 giant oil fields were discovered prior to 1969 and the greatest number of fields were discovered in the period 1965 through 1967. Like delta regions in other parts of the world, individual oil fields of the Niger Delta are small to medium by world standards and future discoveries, therefore, are likely to reflect this reality. The natural gas resources of the Niger Delta, unlike its oil resources, are comparatively underdeveloped. Parts of the Benue depression in Nigeria and Niger could contain significant deposits of petroleum. The lower Benue depression, immediately north of the Niger Delta, has been extensively explored by drilling. Except for noncommercial discoveries of oil and gas and traces of oil and gas on the ground surface, the results of exploration in the lower Benue depression were negative. However, in the Lake Chad area of Chad and in southern Chad near the Central African Republic boundary, oil and gas discoveries were made just prior to the cessation of all drilling and exploration activity in early 1979. It is rumored that these discoveries may be large although little information is available. The relation between the two areas in Chad and their overall relation to the Benue depression is poorly understood; however, the possibility of thick sedimentary sections containing Cretaceous marine source rock and Tertiary reservoir beds-all contained within grabens in a highly faulted failed-arm system subjected to high heat flow--is attractive. Of the ECOWAS countries, only Nigeria and Niger produce coal commercially. Nigeria produces subbituminous coal from Paleocene-Maestrichtian and Maestrichtian (Late Cretaceous) age rocks of the Niger Delta region; reserves are estimated, on the basis of extensive drilling, to be 350 million tons (standard coal equivalent). In addition, lignite deposits of the Niger Delta appear to be large but have not been developed. Niger produces small amounts of coal used locally by uranium mine and mill operations from C

Open-File Report

Changes in porosity and organic matter phase distribution monitored by NMR relaxometry following hydrous pyrolysis under uniaxial confinement

Artificial maturation methods are used to induce changes in source rock thermal maturity without the uncertainties that arise when comparing natural samples from a particular basin that often represent different levels of maturation and different lithofacies. A novel uniaxial confinement clamp was used on Woodford Shale cores in hydrous pyrolysis experiments to limit sample expansion by simulating the effect of overburden present during thermal maturation in natural systems. These samples were then subjected to X-ray computed tomography (X-CT) imaging and low-field nuclear magnetic resonance (LF-NMR) relaxometry measurements. LF-NMR relaxometry is a noninvasive technique commonly used to measure porosity and pore-size distributions in fluid-filled porous media, but may also measure hydrogen present in hydrogen-bearing organic solids. Standard T 1 and T 2 relaxation distributions were determined and two dimensional T 1 -T 2 correlation measurements were performed on the Woodford Shale cores. The T 1 -T 2 correlations facilitate resolution of organic phases in the system. The changes observed in NMR-relaxation times correspond to bitumen and lighter hydrocarbon production that occur as source rock organic matter matures. The LF-NMR porosities of the core samples at maximum oil generation are significantly higher than porosities measured by other methods. This discrepancy likely arises from the measurement of highly viscous organic constituents in addition to fluid-filled porosity. An unconfined sample showed shorter relaxation times and lower porosity. This difference is attributed to the lack of fractures observed in the unconfined sample by X-CT.

Conference Paper

A borehole test for chlorinated solvent diffusion and degradation rates in sedimentary rock

We present a new field measurement and numerical interpretation method (combined termed ‘test’) to parameterize the diffusion of trichloroethene (TCE) and its biodegradation products (DPs) from the matrix of sedimentary rock. The method uses a dual-packer system to interrogate a low-permeability section of the rock matrix adjacent to a previously contaminated borehole and uses the borehole monitoring history to establish the pre-test condition. TCE and its DPs are removed from the groundwater between the packers at the onset of the testing. The parameters estimated by fitting a radial diffusion model to the concentration history and borehole concentration data, also termed back-diffusion, are the tortuosity factor and sorption coefficients of TCE and DPs in the rock matrix and the TCE and DP biodegradation rate coefficients in the borehole. We demonstrate the equipment design and the interpretive method using a borehole accessing the grey mudstone at a TCE contaminated site in the Newark Basin. In this test, both nonreactive (bromide) and reactive (trichlorofluoroethene) tracers are used to constrain the estimated parameters; however, the bromide tracer was not needed to estimate the parameters in this test. The parameters estimated from the field test are consistent with values measured independently in laboratory experiments using field samples of similar lithology. From the interpretation, we compute the TCE and DP concentration distributions in the rock matrix prior to the test to illustrate how the results can be used to enhance understanding of contaminant distribution in the rock matrix.

Groundwater Monitoring and Remediation

Phosphate rock resources of the United States

In 1980, the United States produced about 54 million tons of phosphate rock, or about 40 percent of the world's production, of which a substantial amount was exported, both as phosphate rock and as chemical fertilizer. During the last decade, predictions have been made that easily ruinable, low-cost reserves of phosphate rock would be exhausted, and that by the end of this century, instead of being a major exporter of phosphate rock, the United States might become a net importer. Most analysts today, however, think that exports will indeed decline in the next one or two decades, but that resources of phosphate are sufficient to supply domestic needs for a long time into the future. What will happen in the future depends on the actual availability of low-cost phosphate rock reserves in the United States and in the world. A realistic understanding of future phosphate rock reserves is dependent on an accurate assessment, now, of national phosphate rock resources. Many different estimates of resources exist; none of them alike. The detailed analysis of past resource estimates presented in this report indicates that the estimates differ more in what is being estimated than in how much is thought to exist. The phosphate rock resource classification used herein is based on the two fundamental aspects of a mineral resource(l) the degree of certainty of existence and (2) the feasibility of economic recovery. The comparison of past estimates (including all available company data), combined with the writers' personal knowledge, indicates that 17 billion metric tons of identified, recoverable phosphate rock exist in the United States, of which about 7 billion metric tons are thought to be economic or marginally economic. The remaining 10 billion metric tons, mostly in the Northwestern phosphate district of Idaho, are considered to be subeconomic, ruinable when some increase in the price of phosphate occurs. More than 16 billion metric tons probably exist in the southeastern Coastal Plain phosphate province, principally in Florida and North Carolina and offshore in the shallow Atlantic Ocean from North Carolina to southern Florida. This resource is considered to be hypothetical because it is based on geologic inference combined with sparse drilling data. Total resources of phosphate rock in the United States are sufficient to supply domestic demands for the foreseeable future, provided that drilling is done to confirm hypothetical resources and the chemistry of the deposits is determined. Mining and beneficiation techniques will have to be modified or improved, and new techniques will have to be developed so that these deposits can be profitably exploited.

Circular

Submarine slides north of Puerto Rico and their tsunami potential

New multibeam bathymetry of the entire Puerto Rico trench reveals numerous retrograde slope failures at various scales at the edge of the carbonate platform north of Puerto Rico and the Virgin Islands. The slumped material comprises carbonate blocks, which fail, at least in initial stages, as a coherent rock mass. This, combined with the fact that the edge of the carbonate platform is steeper than most continental slopes, indicates a higher potential for tsunami run-up than along many other U.S. coasts. The style of slope failure appears to be rock falls, slide blocks and debris avalanches. Secondary failure of the failed carbonate products and of the underlying forearc sediments and rocks may lead to debris flows and turbidity flows. Fissures, discovered in the ocean floor near the edge of the platform, indicate that the process is expected to continue in the future. One of the slope failures, the Arecibo amphitheater, previously thought to represent a single giant slide with a volume of 900-1500 cu. km, appears to comprise smaller failures. The expected maximum tsunami run-up on the northern coast of Puerto Rico from one of these slope failures is <20 m, much lower than previously estimated. A recurrence rate of 100s kyr was calculated for the largest observed failures along the edge of the carbonate platform north of Puerto Rico using simple assumptions. Smaller landslides would presumably occur at a higher recurrence rate. Elsewhere around the island, a 20-km wide failure scarp was discovered in the Upper Mona rift and could be associated with the 1918 tsunami and earthquake that hit northwestern Puerto Rico. Large slope failures were also discovered for the first time on the northern side of the Puerto Rico trench. Because Puerto Rico trench slides occur at large water depths (~6000 m), have large horizontal and vertical dimensions, and the directivity from tsunamis emanating from these slides is toward Puerto Rico, they may be of particular concern and may necessitate further study.

Puerto Rico