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At least 109 records · Page 6Linked to original sources

Efficient modeling of wave generation and propagation in a semi-enclosed estuary

Accurate, and high-resolution wave statistics are critical for regional hazard mapping and planning. However, long-term simulations at high spatial resolution are often computationally prohibitive. Here, multiple rapid frameworks including fetch-limited, look-up-table (LUT), and linear propagation are combined and tested in a large estuary exposed to both remotely (swell) and locally generated waves. Predictions are compared with observations and a traditional SWAN implementation coupled to a regional hydrodynamic model. Fetch-limited and LUT approaches both perform well where local winds dominate with errors about 10%–20% larger than traditional SWAN predictions. Combinations of these rapid approaches with linear propagation methods where remotely generated energy is present also perform well with errors 0%–20% larger than traditional SWAN predictions. Model–model comparisons exhibit lower variance than comparisons to observations suggesting that, while model implementation impacts prediction skill, model boundary conditions (winds, offshore waves) may be a dominant source of error. Overall results suggest that with a relatively small loss in prediction accuracy, simulations computation cost can be significantly reduced (by 2–4 orders of magnitude) allowing for high resolution and long-term predictions to adequately define regional wave statistics.

British Columbia, Washington↗

Smoothed Particle Hydrodynamics simulations of reef surf zone processes driven by plunging irregular waves

As waves interact with the slopes of coral reefs and other steep bathymetry profiles, plunging breaking usually occurs where the free surface overturns and violent water motion is triggered. Resolving these surf zone processes pose significant challenges for conventional mesh-based hydrodynamic models, due to the rapidly-deforming nature of the free surface and associated flows. Yet the accurate prediction of these surf zone hydrodynamics is critical for predicting a wide range of nearshore processes driven by wave breaking (e.g., wave dissipation and energy transfers; mean water levels and currents; and wave runup). In this study we assess the ability of the mesh-free, Lagrangian particle-based numerical modelling approach Smoothed Particle Hydrodynamics (SPH) based on DualSPHysics, to simulate the fine-scale hydrodynamic processes driven by irregular wave transformation over a fringing reef profile, by comparing results against detailed experimental observations from a physical modelling study. To greatly improve the computational efficiency, the SPH model was coupled to the mesh-based multi-layer nonhydrostatic wave-flow model SWASH. With this coupled approach, SWASH was used to efficiently simulate the evolution of non-breaking waves from the wavemaker up to the fore reef slope, with the SPH model then used to simulate the detailed hydrodynamic processes over the reef from just offshore of the breakpoint to the shoreline . The SPH model was able to accurately reproduce the complex free surface deformations during plunging breaking, the spectral evolution of waves across the reef flat (including nonlinear wave shape), the mean water levels and currents, and wave runup at the shoreline. Using the long duration simulations (>400 wave periods), the model was able to reproduce the full range of wave motions over the reef (from sea-swell to infragravity frequencies), including the increasing dominance of low frequency waves towards the shoreline and the large cross-reef standing wave motions excited by the reef geometry.

Ocean Modelling↗

Continental extension, magmatism and elevation; formal relations and rules of thumb

To investigate simplified relations between elevation and the extensional, magmatic and thermal processes that influence lithosphere buoyancy, we assume that the lithosphere floats on an asthenosphere of uniform density and has no flexural strength. A simple graph relating elevation to lithosphere density and thickness provides an overview of expectable conditions around the earth and a simple test for consistency of continental and oceanic lithosphere models. The mass-balance relations yield simple general rules for estimating elevation changes caused by various tectonic, magmatic and thermal processes without referring to detailed models. The rules are general because they depend principally on buoyancy, which under our assumptions is specified by elevation, a known quantity; they do not generally require a knowledge of lithosphere thickness and density. The elevation of an extended terrain contains important information on its tectonic and magmatic history. In the Great Basin where Cenozoic extension is estimated to be 100%, the present high mean elevation ( ~ 1.75 km) probably requires substantial low-density magmatic contributions to the extending lithosphere. The elevation cannot be reasonably explained solely as the buoyant residue of a very high initial terrane, or of a lithosphere that was initially very thick and subsequently delaminated and heated. Even models with a high initial elevation typically call for 10 km or so of accumulated magmatic material of near-crustal density. To understand the evolution of the Great Basin, it is important to determine whether such intruded material is present; some could replenish the stretching crust by underplating and crustal intrusion and some might reside in the upper mantle. The elevation maintained or approached by an intruded extending lithosphere depends on the ratio B of how fast magma is supplied from the asthenosphere ( b km/Ma) to how fast the lithosphere spreads the magma out by extension (γ Ma −1 ). For a surface maintained 212km below sea level (e.g., an ocean ridge) B is about 5 km; for continental extension the ratio may be much greater. The frequent association of volcanism with continental extension, the high elevation (and buoyancy) of some appreciably extended terrains, and the oceanic spreading analog all suggest that magmatism may play an important role in continental extension. Better estimates of total extension and elevation change in extended regions can help to identify that role.

Tectonophysics↗

Modeling at-sea density of marine birds to support renewable energy planning on the Pacific outer continental shelf of the contiguous United States

This report describes the at-sea spatial distributions of marine birds in Pacific OCS waters off the contiguous U.S. (Figure 1.1) to inform marine spatial planning in the region. The goal was to estimate long-term average spatial distributions for marine bird species using all available science-quality transect survey data and numerous bathymetric, oceanographic, and atmospheric predictor variables. We developed seasonal habitat-based spatial models of the at-sea distribution for 33 individual species and 13 taxonomic groups of marine birds throughout the study region. A statistical modeling framework was used to estimate numerical relationships between bird sighting data (i.e., standardized counts) and a range of temporal (e.g., Pacific Decadal Oscillation [PDO] index), spatially static (e.g., depth), and spatially dynamic (e.g., sea surface chlorophyll-a concentration) environmental variables. The estimated relationships were then used to predict spatially explicit long-term average density (individuals per km 2 ) throughout the study area for each species/group in each of four seasons. Bird sighting data came from multiple scientific survey programs and consisted of at-sea counts of birds collected between 1980 and 2017 using boat-based and fixed-wing aerial transect survey methods. Spatial environmental variables were derived from remote sensing satellite data and an ocean dynamics model.

California, Oregon, Washington↗

Seasonal-to-interannual fluctuations in surface temperature over the Pacific: effects of monthly winds and heat fluxes

Monthly heat fluxes and wind stresses are used to force the Oberhuber isopycnic ocean general-circulation (OPYC) model of the Pacific basin over a two-decade period from 1970 to 1988. The surface forcings are constructed from COADS marine observations via bulk formulae. Monthly anomalies of the fluxes and stresses are superimposed upon model climatological means of these variables, which were saved from a long spin-up. Two aspects of this work are highlighted, both aimed at a better understanding of the atmosphere-ocean variability and exchanges and at diagnosing the performance of the OPYC model in simulating monthly to decadal-scale variability. The first is the evaluation of the data used to force the model ocean, along with its relationship to other observed data. The second is the diagnosis of the processes revealed in the model that are associated with sea surface temperature (SST) variability, including their seasonal and geographic structure. Although both random and systematic errors arise from the marine data and the bulk formulations, large signals in the air-sea fluxes are nonetheless consistent with the large-scale atmospheric circulation anomalies over the Pacific. This signal is large in a composite prepared from months with similar circulation modes. Also, latent and sensible heat-flux anomaly patterns correspond well to those of SST anomaly tendencies. Considering short-period variations, SST anomaly tendencies have typical magnitudes of 0.3°C mo -1 . These are associated with monthly mean flux anomalies having typical magnitudes of 50 W m -2 and are consistent with observed mixed-layer depths. Decadal anomalies have much smaller magnitudes, perhaps reduced by two orders of magnitude, and it is here that the signal-to-noise problem is more severe. The forcing terms are generally products of variables, so realistic means and fluctuations of these variables are crucial for a successful simulation. The 19-year simulation of the Pacific basin by the monthly marine data-forced OPYC model displays good skill in reproducing SST variability. These results represent the first hindcast of which we are aware that uses both observed total heat-flux and wind-stress anomalies as forcing for such a long time interval. There is close agreement between the model SSTs and those observed in many regions of the Pacific, including the tropics and the northern extratropics. Besides performing credibly on the monthly time scale, the model captures the essence of low-frequency variability over the North Pacific, including aspects of a marked basin-wide change that occurred in 1976-1977. In the model's detailed heat budget, the anomalous air-sea heat fluxes, entrainment, and to a lesser extent horizontal advection, force thermal-anomaly changes in the mixed layer. Each of these components was apparently involved in the 1976-1977 decadal SST shift.

Book chapter↗

Inundation processes, barrier island breaching, and structure impacts during Hurricane Michael (2018)

We demonstrate the increased ability to forecast hurricane impacts with a coupled numerical modeling system by simulating ocean waves, water levels, currents, sediment transport, and structural damage to predict inundation, coastal morphological change, and residential building impacts. The Coupled-Ocean-Atmosphere-Waves-Sediment-Transport (COAWST) modeling system is applied to simulate Hurricane Michael (category 5, 2018) that made landfall near Tyndall Air Force Base, FL, in the northern Gulf of America, causing severe devastation and flooding. Atmospheric forcings from the Coupled Ocean/Atmosphere Mesoscale Prediction System for Tropical Cyclones (COAMPS-TC) are used to drive the ocean and wave models on a series of nested grids. Results identify that coastal inundation at Mexico Beach is due to surge from winds and waves, supplemented by pulses of infragravity wave motions that propagate landward into the inundation region. Seed lines observed on interior building walls also demonstrate variable changes in water level. In addition, a machine learning model was applied to hindcast structure damages, caused mostly by waves and winds, with a 72% accuracy estimate of substantial damage in proximity of landfall. The storm also created a breach across Cape San Blas, the adjacent barrier spit, due to large surge and low dune elevations. Dune locations with vegetated land cover are shown to reduce wave-energy dissipation and reduce erosion, whereas locations without land cover had increased breaching potential. The breach occurred during the maximum ocean-side water level, and the delayed high water on the bay side allowed a pressure gradient to drive flow seaward and promote breach development.

Florida↗

HyWaves: Hybrid downscaling of multimodal wave spectra to nearshore areas

Long-term and accurate wave hindcast databases are often required in different coastal engineering projects. The assessment of the nearshore wave climate is often accomplished by using downscaling techniques to translate offshore waves to coastal areas. However, dynamical downscaling approaches may incur huge computational cost. Additionally, the common use of bulk parameterizations are often not accurate for multidimensional waves. To overcome these limitations, we present a hybrid downscaling approach that combines mathematical algorithms (statistical downscaling) and numerical modeling (dynamical downscaling) over the individual spectral partitions. Every wave partition is downscaled and aggregated afterward by using principles of wave linear theory. By assuming linearity in the propagation of the wave celerity, the application of the method is limited from offshore to intermediate water depths. In addition, the method proposed uses a technique to simplify the spectral boundary conditions in complex domains. The methodology has been applied and validated in the island states of Samoa, American Samoa, Majuro, and Kwajalein, showing good skill at reproducing the spectral hourly time series of significant wave height, peak period, and peak direction. Moreover, an accurate representation of the observed energy spectrum was achieved. This study provides insight into the numerical approximation of the combined sea-swell states while improving the quality of fast spectral forecasting and early warning systems.

Ocean Modeling↗

Crustal structure interpreted from magnetic anomalies

In this review, we discuss publications during the last quadrennium (1987–1990) that used aeromagnetic data, marine magnetic data, satellite magnetic data, and rock magnetic and petrologic data to provide information on the sources of magnetic anomalies. Abstracts and papers by non‐U.S. authors are not described. The publications reviewed reflect increased integration of rock magnetic property and petrologic studies with magnetic anomaly interpretation studies, particularly in deep crustal magnetization, exploration for hydrocarbons, and inversion of marine magnetic anomalies. Interpretations of aeromagnetic data featuring image display techniques and using the horizontal gradient method for locating magnetization boundaries became standard. The magnetic anomaly map of North America appeared, the first such map of an entire continent. MAGSAT data contributed to the development of a new model for the magnetization of the oceanic crust. Forward modeling of sources of magnetic anomalies contributed to a wide range of geologic investigations on land, and inverse magnetic modeling techniques became popular for marine geologic investigations.

Reviews of Geophysics↗

Cretaceous Arctic silicoflagellates

Cretaceous silicoflagellate assemblages from Arctic Ocean USGS Core 437 show Vallacerta siderea the most abundant species; most species of Lyramula disappear halfway up the core; only L. burchardae, n. sp., persists into the upper sections. These occurrences are untypical of the few documented Cretaceous assemblages from other areas. A Campanian or Maestrichtian age is suggested by correlation, but the uniquely high abundance of V. siderea and lack of Corbisema suggests that a difference in both age and general environment could be involved. If Core 437 is latest Maestrichtian, then the evidence from this core would constrain the timing of the ocean-freshening model for the Cretaceous-Tertiary boundary extinctions. ?? 1981 A.M. Dowden, Inc.

Geo-Marine Letters↗

A numerical investigation of the mechanisms controlling salt intrusion in the Delaware Bay Estuary

Salinity intrusion in coastal systems is mainly controlled by freshwater inflows. However, extreme events like drought, low-pressure storms, and longer-term sea level rise can exacerbate the landward salt migration and threaten economic infrastructure and ecological health. Along the eastern seaboard of the United States, approximately 13 million people rely on the water resources of the Delaware River basin. Salinity intrusion is actively managed through river discharge targets to suppress the propagation of the salt front (∼0.52 daily averaged psu line). The purpose of this study is to examine the mechanisms controlling the location of the salt front in the Delaware Bay estuary using a calibrated three-dimensional hydrodynamic model, the Coupled Ocean Atmosphere Wave and Sediment Transport modeling system. This study explored how river discharge, tidal motions, interactions with bathymetric and topographic features, and meteorological events affected the location of the salt front. The model was forced with tides, subtidal water levels, bulk atmospheric conditions, and waves. Compared with the observationally derived location of the salt front line, the model captured the major dynamics throughout the year and performed particularly well during times of low discharge, when salinity intruded up estuary at a constant rate of 0.4 km /day . The daily average salt front moved almost 16 km (10 mi) within a neap-spring tidal cycle, and low-pressure storm systems were found to move the daily averaged salt front by 13–16 km in one event.

Delaware, New Jersey, Pennsylvania↗

Holocene coastal dune fields used as indicators of net littoral transport: West Coast, USA

Between Point Grenville, Washington, and Point Conception, California (1500 km distance) 21 dune fields record longshore transport in 20 littoral cells during the late Holocene. The direction of predominant littoral transport is established by relative positions of dune fields (north, central, or south) in 17 representative littoral cells. Dune field position is north of cell midpoints in northernmost Oregon and Washington, but is south of cell midpoints in southern Oregon and California. Downdrift sand trapping occurs at significant changes in shoreline angle and/or at bounding headlands that project at least 2.5 km seaward from the general coastal trend. Sand bypassing occurs around small headlands of less than 0.5 km in projection distance. A northward shift of the winter low-pressure center in the northeast Pacific Ocean is modeled from 11 ka to 0 ka. Nearshore current forcing in southern Oregon and northern California switched from northward in earliest Holocene time to southward in late Holocene time. The late Holocene (5-0 ka) is generally characterized by net northward littoral drift in northernmost Oregon and Washington and by net southward littoral drift in southernmost Oregon and California. A regional divergence of net transport direction in central Oregon, i.e. no net drift, is consistent with modeled wind and wave forcing at the present time (0 ka). ?? 2009 Elsevier B.V.

Geomorphology↗

Characterizing storm-induced coastal change hazards along the United States West Coast

Traditional methods to assess the probability of storm-induced erosion and flooding from extreme water levels have limited use along the U.S. West Coast where swell dominates erosion and storm surge is limited. This effort presents methodology to assess the probability of erosion and flooding for the U.S. West Coast from extreme total water levels (TWLs), but the approach is applicable to coastal settings worldwide. TWLs were derived from 61 years of wave and water level data at shore-perpendicular transects every 100-m along open coast shorelines. At each location, wave data from the Global Ocean Waves model were downscaled to the nearshore and used to empirically calculate wave run-up. Tides were simulated using the Oregon State University’s tidal data inversion model and non-tidal residuals were calculated from sea-surface temperature and pressure anomalies. Wave run-up was combined with still water levels to generate hourly TWL estimates and extreme TWLs for multiple return periods. Extremes were compared to onshore morphology to determine erosion hazards and define the probability of collision, overwash, and inundation.

California, Oregon, Washington↗

Are there pre-Quaternary geological analogues for a future greenhouse warming?

Given the inherent uncertainties in predicting how climate and environments will respond to anthropogenic emissions of greenhouse gases, it would be beneficial to society if science could identify geological analogues to the human race’s current grand climate experiment . This has been a focus of the geological and palaeoclimate communities over the last 30 years, with many scientific papers claiming that intervals in Earth history can be used as an analogue for future climate change. Using a coupled ocean–atmosphere modelling approach, we test this assertion for the most probable pre-Quaternary candidates of the last 100 million years: the Mid- and Late Cretaceous, the Palaeocene–Eocene Thermal Maximum (PETM), the Early Eocene, as well as warm intervals within the Miocene and Pliocene epochs. These intervals fail as true direct analogues since they either represent equilibrium climate states to a long-term CO 2 forcing—whereas anthropogenic emissions of greenhouse gases provide a progressive (transient) forcing on climate—or the sensitivity of the climate system itself to CO 2 was different. While no close geological analogue exists, past warm intervals in Earth history provide a unique opportunity to investigate processes that operated during warm (high CO 2 ) climate states. Palaeoclimate and environmental reconstruction/modelling are facilitating the assessment and calculation of the response of global temperatures to increasing CO 2 concentrations in the longer term (multiple centuries); this is now referred to as the Earth System Sensitivity, which is critical in identifying CO 2 thresholds in the atmosphere that must not be crossed to avoid dangerous levels of climate change in the long term. Palaeoclimatology also provides a unique and independent way to evaluate the qualities of climate and Earth system models used to predict future climate.

Philosophical Transactions of the Royal Society A:↗

SHRIMP U-Pb zircon ages for Big Creek gneiss, Wyoming and Boulder Creek batholith, Colorado: Implications for timing of Paleoproterozoic accretion of the northern Colorado province

Sensitive, high-resolution, ion microprobe (SHRIMP) U-Pb zircon ages from a sample of the high-grade, hornblende-feldspathic Big Creek gneiss of the southeastern Sierra Madre, along with samples of a quartz monzonitic phase of the Boulder Creek batholith, help define timing of three major Paleoproterozoic thermo-tectonic events within the northern Colorado province at approximately 1810, 1710, and 1610 Ma. Previous ages determined for these key rock units were problematic; they hindered regional tectonic interpretations of the Paleoproterozoic crustal accretion history of the Colorado province that extends from the Cheyenne belt of southern Wyoming to north-central New Mexico. The Colorado province has been popularly modelled as a series of accreted oceanic volcano-plutonic arc systems and associated sediments, although alternative interpretations suggest that the series represents continental-margin arc rocks. The Big Creek gneiss has been interpreted as a high-grade basement equivalent of the oldest arc volcanic rocks exposed within the Green Mountain arc terrane, but it also has been suspected of being either an older block of pre-arc basement or perhaps an allochthonous piece of crust from slightly older orogens to the east and north. Previous ID-TIMS work on mg-size zircon fractions yielded U-Pb concordia upper-intercept ages of 1618 ± 22 and 1684 ± 5 Ma as well as negative lower-intercept ages, indicating complex U-Pb isotopic systematics involving at least two ages of zircon growth overprinted by at least one episode of Pb-loss. Zircons from this gneiss were analyzed using the SHRIMP, and a total of 32 spot analyses on both centers and rims produced a range of different 207 Pb/ 206 Pb ages between ∼1840 and ∼1560 Ma. The weighted mean of the oldest 207 Pb/ 206 Pb ages is 1812 ± 12 Ma and is interpreted to estimate the age of the protolith that appears to be slightly older than lower-grade metabasalts and associated plutons at ∼1790–1775 Ma. This protolith age of 1812 Ma further implies that significantly older crust (> 1820 Ma; e.g., Penokean orogeny) is not found in the Green Mountain magmatic arc. The youngest 207 Pb/ 206 Pb ages of ∼1610 Ma are interpreted to represent a time of new zircon growth during highly localized high-grade metamorphism—an event that also produced local granitic magmatism at ∼1625 Ma. The Boulder Creek batholith had been dated previously using the ID-TIMS, U-Pb zircon technique that yielded ages at ∼1670 and ∼1714 Ma, a 45-m.y. discrepancy that left the true age of the batholith in doubt. Zircons from two samples, previously dated using the ID-TIMS method, were analyzed using SHRIMP, and yielded concordia upper-intercept ages of 1713 ± 10 and 1721 ± 15 Ma. These results, combined with two earlier U-Pb zircon determinations, help to establish the age of the Boulder Creek batholith at 1714.4 ± 4.6 Ma (weighted mean), an age more compatible with those for the other large, tonalitic to quartz monzonitic, syntectonic plutons within the northern Colorado province. The new Boulder Creek age helps to establish a discrete period of plutonism (∼1735–1705 Ma) that is syn- to post-tectonic with respect to major regional structures of deformation and metamorphism in the northern Colorado province. Assuming the multiple oceanic arc accretion model, the new age for the mid-crustal emplacement of this batholith into a deforming composite back-arc basin may date the closure of that basin during crustal shortening.

Colorado, Wyoming↗

Development and application of an Infragravity Wave (InWave) driver to simulate nearshore processes

Infragravity waves are key components of the hydro-sedimentary processes in coastal areas, especially during extreme storms. Accurate modeling of coastal erosion and breaching requires consideration of the effects of infragravity waves. Here, we present InWave, a new infragravity wave driver of the Coupled Ocean-Atmopshere-Waves-Sediment Transport (COAWST) modeling system. InWave computes the spatial and temporal variation of wave energy at the wave group scale and the associated incoming bound infragravity wave. Wave group-varying forces drive free infragravity wave growth and propagation within the hydrodynamic model of the coupled modeling system, which is the Regional Ocean Modeling System (ROMS) in this work. Since ROMS is a three-dimensional model, this coupling allows for the combined formation of undertow currents and infragravity waves. We verified the coupled InWave-ROMS with one idealized test case, one laboratory experiment, and one field experiment. The coupled modeling system correctly reproduced the propagation of gravity wave energy with acceptable numerical dissipation. It also captured the transfer of energy from the gravity band to the infragravity band, and within the different infragravity bands in the surf zone, the measured three-dimensional flow structure, and dune morphological evolution satisfactorily. The idealized case demonstrated that the infragravity wave variance depends on the directional resolution and horizontal grid resolution, which are known challenges with the approach taken here. The addition of InWave to COAWST enables novel investigation of nearshore hydro-sedimentary dynamics driven by infragravity waves using the strengths of the other modeling components, namely the three-dimensional nature of ROMS and the sediment transport routines.

Journal of Advances in Modeling Earth Systems↗

Landfalling Tropical Cyclones: Forecast Problems and Associated Research Opportunities

The Fifth Prospectus Development Team of the U.S. Weather Research Program was charged to identify and delineate emerging research opportunities relevant to the prediction of local weather, flooding, and coastal ocean currents associated with landfalling U.S. hurricanes specifically, and tropical cyclones in general. Central to this theme are basic and applied research topics, including rapid intensity change, initialization of and parameterization in dynamical models, coupling of atmospheric and oceanic models, quantitative use of satellite information, and mobile observing strategies to acquire observations to evaluate and validate predictive models. To improve the necessary understanding of physical processes and provide the initial conditions for realistic predictions, a focused, comprehensive mobile observing system in a translating storm-coordinate system is required. Given the development of proven instrumentation and improvement of existing systems, three-dimensional atmospheric and oceanic datasets need to be acquired whenever major hurricanes threaten the United States. The spatial context of these focused three-dimensional datasets over the storm scales is provided by satellites, aircraft, expendable probes released from aircraft, and coastal (both fixed and mobile), moored, and drifting surface platforms. To take full advantage of these new observations, techniques need to be developed to objectively analyze these observations, and initialize models aimed at improving prediction of hurricane track and intensity from global-scale to mesoscale dynamical models. Multinested models allow prediction of all scales from the global, which determine long- term hurricane motion to the convective scale, which affect intensity. Development of an integrated analysis and model forecast system optimizing the use of three-dimensional observations and providing the necessary forecast skill on all relevant spatial scales is required. Detailed diagnostic analyses of these datasets will lead to improved understanding of the physical processes of hurricane motion, intensity change, the atmospheric and oceanic boundary layers, and the air- sea coupling mechanisms. The ultimate aim of this effort is the construction of real-time analyses of storm surge, winds, and rain, prior to and during landfall, to improve warnings and provide local officials with the comprehensive information required for recovery efforts in the hardest hit areas as quickly as possible.

Bulletin of the American Meteorological Society↗

Suboxic deep seawater in the late Paleoproterozoic: Evidence from hematitic chert and iron formation related to seafloor-hydrothermal sulfide deposits, central Arizona, USA

A current model for the evolution of Proterozoic deep seawater composition involves a change from anoxic sulfide-free to sulfidic conditions 1.8??Ga. In an earlier model the deep ocean became oxic at that time. Both models are based on the secular distribution of banded iron formation (BIF) in shallow marine sequences. We here present a new model based on rare earth elements, especially redox-sensitive Ce, in hydrothermal silica-iron oxide sediments from deeper-water, open-marine settings related to volcanogenic massive sulfide (VMS) deposits. In contrast to Archean, Paleozoic, and modern hydrothermal iron oxide sediments, 1.74 to 1.71??Ga hematitic chert (jasper) and iron formation in central Arizona, USA, show moderate positive to small negative Ce anomalies, suggesting that the redox state of the deep ocean then was at a transitional, suboxic state with low concentrations of dissolved O2 but no H2S. The presence of jasper and/or iron formation related to VMS deposits in other volcanosedimentary sequences ca. 1.79-1.69??Ga, 1.40??Ga, and 1.24??Ga also reflects oxygenated and not sulfidic deep ocean waters during these time periods. Suboxic conditions in the deep ocean are consistent with the lack of shallow-marine BIF ??? 1.8 to 0.8??Ga, and likely limited nutrient concentrations in seawater and, consequently, may have constrained biological evolution. ?? 2006 Elsevier B.V. All rights reserved.

Earth and Planetary Science Letters↗