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Statistical guidelines for assessing marine avian hotspots and coldspots: A case study on wind energy development in the U.S. Atlantic Ocean

Estimating patterns of habitat use is challenging for marine avian species because seabirds tend to aggregate in large groups and it can be difficult to locate both individuals and groups in vast marine environments. We developed an approach to estimate the statistical power of discrete survey events to identify species-specific hotspots and coldspots of long-term seabird abundance in marine environments. We illustrate our approach using historical seabird data from survey transects in the U.S. Atlantic Ocean Outer Continental Shelf (OCS), an area that has been divided into “lease blocks” for proposed offshore wind energy development. For our power analysis, we examined whether discrete lease blocks within the region could be defined as hotspots (3 × mean abundance in the OCS) or coldspots (1/3 ×) for individual species within a given season. For each of 74 species/season combinations, we determined which of eight candidate statistical distributions (ranging in their degree of skewedness) best fit the count data. We then used the selected distribution and estimates of regional prevalence to calculate and map statistical power to detect hotspots and coldspots, and estimate the p -value from Monte Carlo significance tests that specific lease blocks are in fact hotspots or coldspots relative to regional average abundance. The power to detect species-specific hotspots was higher than that of coldspots for most species because species-specific prevalence was relatively low (mean: 0.111; SD: 0.110). The number of surveys required for adequate power (> 0.6) was large for most species (tens to hundreds) using this hotspot definition. Regulators may need to accept higher proportional effect sizes, combine species into groups, and/or broaden the spatial scale by combining lease blocks in order to determine optimal placement of wind farms. Our power analysis approach provides a general framework for both retrospective analyses and future avian survey design and is applicable to a broad range of research and conservation problems.

U.S. Atlantic Ocean Outer Continental Shelf

Gulf of Alaska and Lower Cook Inlet summary report 3: Second revision of Outer Continental Shelf oil and gas activities in the Gulf of Alaska (including Lower Cook Inlet) and their onshore impacts: A summary report, September 1980

Five Outer Continental Shelf (OCS) lease sales have been held in the Gulf of Alaska subregion of Alaska. Lease Sale 39, in the northern Gulf of Alaska, was held on April 13, 1976, and it resulted in the leasing of 76 tracts. Lease Sale CI, held on October 27, 1977, resulted in the leasing of 87 tracts in Lower Cook Inlet. Lease Sale 55 in the eastern Gulf of Alaska, held on October 21, 1980, leased 35 tracts. The first Reoffering Sale (RS-1), held on June 30, 1981, resulted in the leasing of one tract in the eastern Gulf of Alaska. Lease Sale 60, the most recent sale in the subregion, was held on September 29, 1981. It resulted in the leasing of 13 tracts in the Lower Cook Inlet and the Shelikof Strait. Exploratory drilling has been conducted on tracts leased in Lease Sales 39 and CI. No commercial discoveries were made, and no further exploratory drilling is anticipated on tracts leased in either sale. ARCO has plans to explore a tract leased in Lease Sale 55 in January 1983. Chevron has conducted geohazard studies on tracts leased in Lease Sale 60. The results of these studies will determine if exploratory wells will be drilled. Exploratory drilling, if it does take place, is not anticipated before the summer of 1983. In March 1982, the Department of the Interior prepared new resource estimates for the Gulf of Alaska subregion. The risked mean resource estimates for tracts leased in Lease Sale 55 and Lease Sale RS-1 are 12.1 million barrels of oil and 46.2 billion cubic feet of gas. The risked mean resource estimates for tracts leased in Lease Sale 60 are 5.6 million barrels of oil and 5 billion cubic feet of gas. The onshore impacts from previous OCS exploration in the Gulf of Alaska and the Lower Cook Inlet were minimal. Yakutat will be used to support exploratory drilling on any Lease Sale 55 or Lease Sale RS-1 tracts. If exploratory drilling takes place on Lease Sale 60 tracts, support facilities are expected to be located in Kenai or on Kodiak Island.

Gulf of Alaska, Outer Continental Shelf

The lacustrine carbon cycle as illuminated by the waters and sediments of two hydrologically distinct headwater lakes in north-central Minnesota, U.S.A

The accumulation rates of CaCO 3 and organic carbon (OC) in lake sediments are delicately balanced between production in the epilimnion and destruction in the hypolimnion. The cycling of these two forms of carbon makes a "carbon pump" that greatly affects the biogeochemical cycles of other elements. To further understand these biogeochemical dynamics, the lakes, streams, and wetlands of the Shingobee River headwater area of north-central Minnesota have been subjected to intensive hydrologic and biogeochemical studies. Williams Lake, situated close to the highest point in the regional flow system, is hydrologically closed, with no surface inlet or outlet, and ground water and precipitation as the only sources of water. Shingobee Lake, situated at the lowest point in the regional flow system, has the Shingobee River as an inlet and outlet. The surface waters of both lakes are oversaturated, and the bottom waters undersaturated, with respect to CaCO 3 during the summer. The small amount of CaCO 3 that is precipitated in the epilimnion of Williams Lake during the summer is dissolved in the undersaturated hypolimnion and sediments with the result that no CaCO 3 is incorporated into the profundal surface sediments. Because of the high phytoplankton productivity of Shingobee Lake, sufficient CaCO 3 is produced in the epilimnion that large amounts survive the corrosive hypolimnion and sediments, and an average of 46 wt. % accumulates in surface sediments. Another consequence of higher phytoplankton productivity in Shingobee Lake is that the hypolimnion becomes oxygen deficient within a month after overturn in both the spring and fall. Because of reducing conditions that develop in the hypolimnion of Shingobee Lake, high concentrations of dissolved Fe and Mn accumulate there during summer stratification. Precipitation of Fe and Mn oxyhydroxides during periods of fall and spring overturn results in high concentrations of Fe and Mn in surface sediments. In Williams Lake, high concentrations of Fe and Mn do not build up in the hypolimnion. The concentration of CaCO 3 is about 80 wt. % in lower Holocene sediments of both lakes. The lower Holocene sediments in both lakes also contain high concentrations of Fe and Mn, and the lower Holocene sediments of Shingobee are laminated. The waters of both lakes had identical values of δ 13 C and δ 18 O during the early Holocene, but the waters of Williams Lake "evolved" during the early Holocene, increasing about 10‰ in both δ 13 C and δ 18 O. Deposits of lacustrine marl occur as much as seven meters above the present elevation of Williams Lake, the highest of the two lakes. Taken together, these observations suggest that the lakes were once connected to form a larger lake called Lake Willobee with a hypolimnion that was anoxic, at least seasonally.

Minnesota

Oceanographic controls on sedimentary and geochemical facies on the Peru outer shelf and upper slope

Concentrations and characteristics of organic matter in surface sediments deposited under an intense oxygen-minimum zone (OMZ) on the Peru margin were mapped and studied in samples from deck-deployed box cores and push cores acquired by submersible on two east-west transects spanning depths of 75 to 1,000 meters (m) at 12°S and 13.5°S. On the basis of sampling and analyses of the top 1–2 centimeters (cm) of available cores, three main belts of sediments were identified on each transect with increasing depth: (1) muds rich in organic carbon (OC); (2) authigenic phosphatic mineral crusts and pavements; and (3) glaucony facies. Sediments rich in OC on the 12°S transect were mainly located on the outer shelf and upper slope (150–350 m), but they occurred in much shallower water (approximately 100 m) on the 13.5°S transect. The organic matter is almost entirely marine as confirmed by Rock-Eval pyrolysis and isotopic composition of OC. Concentrations of OC are highest (up to 18 percent) in sediments within the OMZ where dissolved oxygen (DO) concentrations are <5 micromoles per kilogram (μM). Even at these low concentrations of DO, however, the surface sediments from within the OMZ are dominantly unlaminated. Concentrations of DO may have the dominant effect on organic matter characteristics, but reworking of fine-grained sediment and organic matter by strong bottom currents with velocities as high as 30 centimeters per second (cm/s) on the slope between 150 and 300 m and redeposition on the seafloor in areas of lower energy and higher DO concentration also exert important controls on OC concentration and degree of oxidation in this region. Phosphate-rich sediments and crusts occurred at depths of about 300 to 550 m on both transects. Nodular crusts of sediment cemented by carbonate-fluorapatite (CFA; phosphorite) or dolomite form within the OMZ. These phosphorite crusts evolve through cementation from light olive-green, stiff but friable, phosphatized claystone “protocrusts” through dense, dark phosphorite crusts, cemented breccias, and pavements. The degree of phosphatization and thickness of the crusts depend on the rates of sediment supply and on the strength and frequency of currents that re-expose crusts on the seafloor. Phosphorite crusts and pavements on the Peru margin can only become buried and incorporated into the geologic record once bottom currents slacken sufficiently to allow fine-grained sediment to accumulate. Glaucony-rich surface sediments, relatively undiluted by other components, were found mainly in deeper water on the 13.5°S transect (750 m to at least 1,067 m). These sediments consist almost entirely of sand-size glaucony pellets. These widespread glaucony sands formed in place and were then concentrated and reworked by strong currents that winnowed away the fine-grained matrix. Although the glaucony occurs in sand-size pellets, the pellets are made up of aggregates of authigenic, platy, micaceous clay minerals. Glaucony is predominantly a potassium (K), sodium (Na), iron (Fe), magnesium (Mg) aluminosilicate with an approximate formula of (K,Na)(Fe 3+ ,Al,Mg) 2 (Si,Al) 4 O 10 (OH) 2 . The glaucony on the 13.5°S transect forms by alteration of one or more original “framework” minerals (carbonate and [or] aluminosilicates) to form pellital aggregates of Fe-, K-, and Mg-rich clay minerals. Because Fe, K, and Mg are derived from seawater, sedimentation rates must be extremely slow in order for the original framework minerals to remain in contact with seawater. The close association of glaucony and phosphorite indicates a delicate balance between the slightly oxidizing conditions at the base of the OMZ that form glaucony and the slightly reducing conditions that mobilize iron and phosphate to form phosphorite.

Open-File Report

The use of synthetic jarosite as an analog for natural jarosite

The presence of jarosite in soil or mining waste is an indicator of acidic sulfate-rich conditions. Physical and chemical properties of synthetic jarosites are commonly used as analogs in laboratory studies to determine solubility and acid-generation of naturally occurring jarosites. In our work we have mineralogically and chemically characterized both natural and synthetic jarosites. Analysis of 32 natural hydrothermal and supergene K- and Na-jarosites indicates no (< 5 mole %) solid solution between K and Na end members. Instead, our detailed study of cell dimensions and composition reveals discrete mixtures of K and Na end members. Hydronium-bearing jarosite was detected in only one natural sample, and it appears that hydronium-bearing jarosites are metastable. Although the presence of hydronium in jarosite cannot be directly measured, we found that when synthetic hydronium-bearing jarosites are heated at 120°C for 78 days or 240°C for 24 hours, Fe(OH)SO4 is formed. The Fe(OH)SO4 is easily detected by X-ray diffraction and, hence, can be used as a post-mortem indicator of the presence of hydronium jarosite. Results from our synthetic jarosite studies indicate that natural metastable hydronium-bearing jarosite or iron-deficient forms of natural jarosite likely play an important role in acid generation in some mining wastes, but are not accurately represented by synthetic jarosite prepared by commonly used methods. The widespread practice of heating to at least 110°C after jarosite synthesis appears to drive off structural waters from protonated hydroxyl sites, which changes the properties of the jarosite. Therefore, synthetic jarosite should not be heated above 95 oC if it is to be used as an analog for low-temperature natural jarosite in mining wastes.

Conference Paper

Integrated thermal infrared imaging and Structure-from-Motion photogrametry to map apparent temperature and radiant hydrothermal heat flux at Mammoth Mountain, CA USA

This work presents a method to create high-resolution (cm-scale) orthorectified and georeferenced maps of apparent surface temperature and radiant hydrothermal heat flux and estimate the radiant hydrothermal heat emission rate from a study area. A ground-based thermal infrared (TIR) camera was used to collect (1) a set of overlapping and offset visible imagery around the study area during the daytime and (2) time series of co-located visible and TIR imagery at one or more sites within the study area from pre-dawn to daytime. Daytime visible imagery was processed using the Structure-from-Motion photogrammetric method to create a digital elevation model onto which pre-dawn TIR imagery was orthorectified and georeferenced. Three-dimensional maps of apparent surface temperature and radiant hydrothermal heat flux were then visualized and analyzed from various computer platforms (e.g., Google Earth, ArcGIS). We demonstrate this method at the Mammoth Mountain fumarole area on Mammoth Mountain, CA. Time-averaged apparent surface temperatures and radiant hydrothermal heat fluxes were observed up to 73.7 oC and 450 W m-2, respectively, while the estimated radiant hydrothermal heat emission rate from the area was 1.54 kW. Results should provide a basis for monitoring potential volcanic unrest and mitigating hydrothermal heat-related hazards on the volcano.

California

Ancient low–molecular-weight organic acids in permafrost fuel rapid carbon dioxide production upon thaw

Northern permafrost soils store a vast reservoir of carbon, nearly twice that of the present atmosphere. Current and projected climate warming threatens widespread thaw of these frozen, organic carbon (OC)-rich soils. Upon thaw, mobilized permafrost OC in dissolved and particulate forms can enter streams and rivers, which are important processors of OC and conduits for carbon dioxide (CO 2 ) to the atmosphere. Here, we demonstrate that ancient dissolved organic carbon (DOC) leached from 35,800 y B.P. permafrost soils is rapidly mineralized to CO 2 . During 200-h experiments in a novel high–temporal-resolution bioreactor, DOC concentration decreased by an average of 53%, fueling a more than sevenfold increase in dissolved inorganic carbon (DIC) concentration. Eighty-seven percent of the DOC loss to microbial uptake was derived from the low–molecular-weight (LMW) organic acids acetate and butyrate. To our knowledge, our study is the first to directly quantify high CO 2 production rates from permafrost-derived LMW DOC mineralization. The observed DOC loss rates are among the highest reported for permafrost carbon and demonstrate the potential importance of LMW DOC in driving the rapid metabolism of Pleistocene-age permafrost carbon upon thaw and the outgassing of CO 2 to the atmosphere by soils and nearby inland waters.

PNAS

Using bottom trawls to monitor subsurface water clarity in marine ecosystems

Biophysical processes that affect subsurface water clarity play a key role in ecosystem function. However, subsurface water clarity is poorly monitored in marine ecosystems because doing so requires in-situ sampling that is logistically difficult to conduct and sustain. Novel solutions are thus needed to improve monitoring of subsurface water clarity. To that end, we developed a sampling method and data processing algorithm that enable the use of bottom trawl fishing gear as a platform for conducting subsurface water clarity monitoring using trawl-mounted irradiance sensors without disruption to fishing operations. The algorithm applies quality control checks to irradiance measurements and calculates the downwelling diffuse attenuation coefficient, K d , and optical depth, ζ – apparent optical properties (AOPs) that characterize the rate of decrease in downwelling irradiance and relative irradiance transmission to depth, respectively. We applied our algorithm to irradiance measurements, obtained using bottom-trawl-mounted archival tags equipped with a photodiode collected during NOAA’s Alaska Fisheries Science Center annual summer bottom trawl surveys of the eastern Bering Sea continental shelf from 2004 to 2018. We validated our AOPs by quantitatively comparing surface-weighted K d from tags to the multi-sensor K d (490) product from the Ocean Colour Climate Change Initiative project (OC-CCI) and qualitatively evaluating whether tag K d was consistent with patterns of subsurface chlorophyll-a concentrations predicted by a coupled regional physical-biological model (Bering10K-BESTNPZ). We additionally examined patterns and trends in water clarity in the eastern Bering Sea. Key findings are: 1) water clarity decreased significantly from 2004 to 2018; 2) a recurrent, pycnocline-associated, maximum in K d occurred over much of the northwestern shelf, putatively due to a subsurface chlorophyll maximum; and 3) a turbid bottom layer (nepheloid layer) was present over a large portion of the eastern Bering Sea shelf. Our study demonstrates that bottom trawls can provide a useful platform for monitoring water clarity, especially when trawling is conducted as part of a systematic stock assessment survey.

Alaska

Estimating water temperatures in small streams in western Oregon using neural network models

Artificial neural network models were developed to estimate water temperatures in small streams using data collected at 148 sites throughout western Oregon from June to September 1999. The sites were located on 1st-, 2nd-, or 3rd-order streams having undisturbed or minimally disturbed conditions. Data collected at each site for model development included continuous hourly water temperature and description of riparian habitat. Additional data pertaining to the landscape characteristics of the basins upstream of the sites were assembled using geographic information system (GIS) techniques. Hourly meteorological time series data collected at 25 locations within the study region also were assembled. Clustering analysis was used to partition 142 sites into 3 groups. Separate models were developed for each group. The riparian habitat, basin characteristic, and meteorological time series data were independent variables and water temperature time series were dependent variables to the models, respectively. Approximately one-third of the data vectors were used for model training, and the remaining two-thirds were used for model testing. Critical input variables included riparian shade, site elevation, and percentage of forested area of the basin. Coefficient of determination and root mean square error for the models ranged from 0.88 to 0.99 and 0.05 to 0.59 oC, respectively. The models also were tested and validated using temperature time series, habitat, and basin landscape data from 6 sites that were separate from the 142 sites that were used to develop the models. The models are capable of estimating water temperatures at locations along 1st-, 2nd-, and 3rd-order streams in western Oregon. The model user must assemble riparian habitat and basin landscape characteristics data for a site of interest. These data, in addition to meteorological data, are model inputs. Output from the models include simulated hourly water temperatures for the June to September period. Adjustments can be made to the shade input data to simulate the effects of minimum or maximum shade on water temperatures.

Water-Resources Investigations Report

Determination of bioavailable contaminants in the lower Missouri River following the flood of 1993

The semipermeable membrane device (SPMD) technology was employed to determine the presence of bioavailable organochlorine pesticides (OCs), polychlorinated biphenyls (PCBs), and polyaromatic hydrocarbons (PAHs)in the water of the main stem of the lower Missouri River and three of its tributaries. The SPMDs were deployed in 1994 following the extensive flood of 1993. Specifically, the SPMDs were deployed for 28 days at Wilson State Park, IA; Nebraska City, NE; Parkville, MO; the Kansas River in Kansas City, KS; Napoleon, MO; the Grand River; Glasgow, MO; the Missouri River upstream from the confluence of the Gasconade River; the Gasconade River, and Hermann, MO. Contaminant residues were found at all sites and at higher concentrations than found in the earlier pre-flood sampling. For example, in the present study, dieldrin was found to range from a low of 110 ng/sample in the Gasconade River to a high of 2000 ng/sample at Glasgow, while in the pre- flood sampling, dieldrin ranged from a low of 64 ng/sample at Sioux City to a high of 800 ng/sample at Glasgow. In contrast to the 1992 sampling, residues of PCBs were found at all 1994 sampling sites except the Gasconade River. Samples from Wilson State Park and the Grand River had 3100 and 2700 ng of PCBs/sample, respectively. These two concentrations are about an order of magnitude higher than the older sites and are likely indicative of point source inputs. PAHs were present in SPMD samples from three sites near Kansas City. The contaminant residues sequestered by the SPMDs represent an estimation of the bioavailable (via respiration) contaminants present in the main stem of the lower Missouri River and three of its major tributaries following an extensive flood event.The semipermeable membrane device (SPMD) technology was employed to determine the presence of bioavailable organochlorine pesticides, polychlorinated biphenyls, and polyaromatic hydrocarbons in the water of the main stem of the lower Missouri River and three of its tributaries. The SPMD were deployed in 1994 following an extensive flood in 1993. Contaminants residues were found at all sites and at higher concentrations than found in the earlier pre-flood sampling.

Environmental Science & Technology

Formation and transport of the sulfonic acid metabolites of alachlor and metolachlor in soil

Alachlor and metolachlor are dechlorinated and transformed into their corresponding ethane sulfonic acid (ESA) metabolites in soil. In a field-disappearance study, it was shown that alachlor ESA was formed at a faster rate and at concentrations 2−4 times higher than metolachlor ESA, conforming with the observed longer disappearance half-life of metolachlor (15.5 d) in the field as compared to alachlor (8 d). Runoff data also showed higher concentrations of alachlor ESA as compared to metolachlor ESA, even though they were applied at the same levels. Data from soil cores showed transport of the ESA compounds in soil to as far down as 75−90 cm below the surface, at concentrations ranging from less than 0.5 μg/L to about 50 μg/L. In contrast, no parent herbicide was detected at these depths. This observation correlates with the higher log K oc values for alachlor (3.33) and metolachlor (3.01) relative to their corresponding ESA metabolites, alachlor ESA (2.26), and metolachlor ESA (2.29).

Environmental Science & Technology

Landscape scale controls on the vascular plant component of dissolved organic carbon across a freshwater delta

Lignin phenol concentrations and compositions were determined on dissolved organic carbon (DOC) extracts (XAD resins) within the Sacramento-San Joaquin River Delta (the Delta), the tidal freshwater portion of the San Francisco Bay Estuary, located in central California, USA. Fourteen stations were sampled, including the following habitats and land-use types: wetland, riverine, channelized waterway, open water, and island drains. Stations were sampled approximately seasonally from December, 1999 through May, 2001. DOC concentrations ranged from 1.3 mg L -1 within the Sacramento River to 39.9 mg L -1 at the outfall from an island drain (median 3.0 mg L -1 ), while lignin concentrations ranged from 3.0 &mu;L -1 within the Sacramento River to 111 &mu;L -1 at the outfall from an island drain (median 11.6 &mu;L -1 ). Both DOC and lignin concentrations varied significantly among habitat/land-use types and among sampling stations. Carbon-normalized lignin yields ranged from 0.07 mg (100 mg OC) -1 at an island drain to 0.84 mg (100 mg OC) -1 for a wetland (median 0.36 mg (100 mg OC) -1 ), and also varied significantly among habitat/land-use types. A simple mass balance model indicated that the Delta acted as a source of lignin during late autumn through spring (10-83% increase) and a sink for lignin during summer and autumn (13-39% decrease). Endmember mixing models using S:V and C:V signatures of landscape scale features indicated strong temporal variation in sources of DOC export from the Delta, with riverine source signatures responsible for 50% of DOC in summer and winter, wetland signatures responsible for 40% of DOC in summer, winter, and late autumn, and island drains responsible for 40% of exported DOC in late autumn. A significant negative correlation was observed between carbon-normalized lignin yields and DOC bioavailability in two of the 14 sampling stations. This study is, to our knowledge, the first to describe organic vascular plant DOC sources at the level of localized landscape features, and is also the first to indicate a significant negative correlation between lignin and DOC bioavailability within environmental samples. Based upon observed trends: (1) Delta features exhibit significant spatial variability in organic chemical composition, and (2) localized Delta features appear to exert strong controls on terrigenous DOC as it passes through the Delta and is exported into the Pacific Ocean.

California

Shock effects in certain rock-forming minerals

Shock effects in quartz, plagioclase, biotite, amphibole, and some accessory minerals have been observed in rocks subjected to various degrees of meta morphism by meteoritic impact. The shock features described are unique; they are never observed in rocks from normal geologic environments. Such features are described: 1) Multiple sets of closely spaced planar microstructures occur in quartz, plagioclase, and other rock-forming minerals. Those characteristic of shock consist of alternating platelets, with a range of reduced mean index of re fraction and birefringence; they con sist of platelets that have been partially or completely transformed to an amor phous phase. 2) Quartz and plagioclase are selec tively and completely transformed to silica glass and plagioclase glass in the solid state, whereas the associated mafic minerals remained crystalline. There is no reaction between adjacent minerals. 3) High-pressure polymorphs occur, such as coesite or stishovite. Coesite oc Curs exclusively within silica glass; it has not been observed as a reaction or breakdown product. 4) Nickel-iron spherules occur in the fused glass or impactites. 5) The occurrence of droplets of ilmenite, rutile, pseudobrookite, and baddaleyite in impactites indicates a temperature of formation exceeding 150°C. 6) Dense glass occurs, similar in composition to bulk rock, in which iron oxide, such as fine particles of mag netite, is completely dissolved. All these features are characteristic of a process involving the rapid rise and fall of extremiiely high pressures and temperatures. Minerals and mineral as semblages experiencing such high strain rates and sudden changes of pressures and temperatures react and change in dependently to the bulk chemical com position, under nonequilibrium condi tions. Many aspects of shock features re quire careful study. Kink bands in biotite and deformation lamellae in quartz occur in tectonically deformed rocks. These features should be studied with great care in order to determine whether reduction in mean index of refraction and total birefringence along the planar structures have resulted from vitrification or phase transition; their presence is additional evidence in favor of a shock mechanism. Vitreous phases or glasses formed by shock also have many unique prop erties; they have not been studied by such methods as thermoluminescence, electron spin resonance, low-angle x ray diffraction, or infrared spectroscopy. Shock-fused glass of high density needs to be studied in detail in carefully con trolled laboratory conditions. Experimental shock-wave studies of the equation-of-state of single minerals and mineral assemblages, under care fully controlled conditions, must pre cede estimates of peak pressures and peak and residual temperatures of shocked natural mineral assemblages. Detailed petrographic and mineralogic studies, however, have provided useful and definitive criteria for characteriza tion of impact events. Such data should be of paramount importance in the study of samples brought back from Moon.

Science

Strontium isotope record of seasonal scale variations in sediment sources and accumulation in low-energy, subtidal areas of the lower Hudson River estuary

Strontium isotope ( 87 Sr/ 86 Sr) profiles in sediment cores collected from two subtidal harbor slips in the lower Hudson River estuary in October 2001 exhibit regular patterns of variability with depth. Using additional evidence from sediment Ca/Sr ratios, 137 Cs activity and Al, carbonate (CaCO 3 ), and organic carbon (OC sed ) concentration profiles, it can be shown that the observed variability reflects differences in the relative input and trapping of fine-grained sediment from seaward sources vs. landward sources linked to seasonal-scale changes in freshwater flow. During high flow conditions, the geochemical data indicate that most of the fine-grained sediments trapped in the estuary are newly eroded basin materials. During lower (base) flow conditions, a higher fraction of mature materials from seaward sources with higher carbonate content is trapped in the lower estuary. Results show that high-resolution, multi-geochemical tracer approaches utilizing strontium isotope ratios ( 87 Sr/ 86 Sr) can distinguish sediment sources and constrain seasonal scale variations in sediment trapping and accumulation in dynamic estuarine environments. Low-energy, subtidal areas such as those in this study are important sinks for metastable, short-to-medium time scale sediment accumulation. These results also show that these same areas can serve as natural recorders of physical, chemical, and biological processes that affect particle and particle-associated material dynamics over seasonal-to-yearly time scales. ?? 2009.

Chemical Geology

Catalog of earthquakes in southern Alaska: January-March 1978

The National Center for Earthquake Research of the U.S. Geological Survey (USGS) began a program of telemetered seismic recording in south-central Alaska in 1971. The principal objectives of this program have been to use data recorded by this network to precisely locate earthquakes in the active seismic zones of southern Alaska, to delineate seismically active faults, to assess seismic risk, to document potential premonitory earthquake phenomena, to investigate current tectonic deformation, and to study the structure and physical properties of the crust and upper mantle. A task fundamental to all of these goals is the routine cataloging of earthquake parameters for earthquakes located within and adjacent to the seismograph network. The initial network of 10 stations, 7 around Cook Inlet and 3 near Valdez, was installed in 1971. Each summer since then additions or modifications to the network have been made. By the Fall of 1973, 26 stations extended from western Cook Inlet to eastern Prince William Sound, and 4 stations were located between Cordova and Yakutat. A year later 20 additional stations were installed. Thirteen of these were placed along the eastern Gulf of Alaska with support from the National Oceanic and Atmospheric Administration (NOAA) under the Outer Continental Shelf Environmental Program to investigate the seismicity of the outer continental shelf (OCS) region of interest for oil exploration. During the subsequent years the region covered by the network has remained relatively fixed while effort has been made to improve the instrumentation and installation of the stations in order to make them more reliable. This earthquake catalog presents origin times, focal coordinates and magnitudes for 384 shocks occurring in the first quarter of 1978. Readings from a total of 62 stations were used to locate the shocks, including 11 stations operated by the NOAA Alaska Tsunami Warning Center (formerly Palmer Observatory), and 5 stations operated by the Geophysical Institute of the University of Alaska (U. of A.). Earthquakes in south-central Alaska as small as magnitude 3.0 have been routinely located by the National Earthquake Information Service of the USGS and its predecessor since the great Alaska earthquake of 1964 and published in the reports "Preliminary Determination of Epicenters" (PDE). In contrast the shocks included in this catalog are as small as magnitude 1.0 and most are smaller than magnitude 3.0. Data for the larger historic earthquakes in south-central Alaska have been tabulated by Meyers (1976). The locations of the stations of the USGS seismograph network are plotted in Figure 1 and listed in Table 1 along with the additional stations from which readings were obtained. The USGS stations have single, vertical-component seismometers except for GLB, PNL, RDT, SKN, and VLZ which also have two horizontal seismometers.

Alaska

Occurrence and accumulation of pesticides and organic contaminants in river sediment, water and clam tissues from the San Joaquin River and tributaries, California

A study was conducted in 1992 to assess the effects of anthropogenic activities and land use on the water quality of the San Joaquin River and its major tributaries. This study focused on pesticides and organic contaminants, looking at distributions of contaminants in water, bed and suspended sediment, and the bivalve Corbicula fluminea. Results indicated that this river system is affected by agricultural practices and urban runoff. Sediments from Dry Creek contained elevated concentrations of polycyclic aromatic hydrocarbons (PAHs), possibly derived from urban runoff from the city of Modesto; suspended sediments contained elevated amounts of chlordane. Trace levels of triazine herbicides atrazine and simazine were present in water at most sites. Sediments, water, and bivalves from Orestimba Creek, a westside tributary draining agricultural areas, contained the greatest levels of DDT (1,1,1-trichloro-2-2-bis[p-chlorophenyl]ethane), and its degradates DDD (1,1-dichloro-2,2-bis[p-chlorophenyl]ethane), and DDE (1,1-dichloro-2,2- bis[p-chlorophenyl]ethylene). Sediment adsorption co efficients (K(oc)), and bioconcentration factors (BCF) in Corbicula of DDT, DDD, and DDE at Orestimba Creek were greater than predicted values. Streams of the western San Joaquin Valley can potentially transport significant amounts of chlorinated pesticides to the San Joaquin River, the delta, and San Francisco Bay. Organochlorine compounds accumulate in bivalves and sediment and may pose a problem to other biotic species in this watershed.

California

An evaluation of the science needs to inform decisions on Outer Continental Shelf energy development in the Chukchi and Beaufort Seas, Alaska

The U. S. Geological Survey (USGS) was asked to conduct an initial, independent evaluation of the science needs that would inform the Administration's consideration of the right places and the right ways in which to develop oil and gas resources in the Arctic Outer Continental Shelf (OCS), particularly focused on the Beaufort and Chukchi Seas. Oil and gas potential is significant in Arctic Alaska. Beyond petroleum potential, this region supports unique fish and wildlife resources and ecosystems, and indigenous people who rely on these resources for subsistence. This report summarizes key existing scientific information and provides initial guidance of what new and (or) continued research could inform decision making. This report is presented in a series of topical chapters and various appendixes each written by a subset of the USGS OCS Team based on their areas of expertise. Three chapters (Chapters 2, 3, and 4) provide foundational information on geology; ecology and subsistence; and climate settings important to understanding the conditions pertinent to development in the Arctic OCS. These chapters are followed by three chapters that examine the scientific understanding, science gaps, and science sufficiency questions regarding oil-spill risk, response, and impact (Chapter 5), marine mammals and anthropogenic noise (Chapter 6), and cumulative impacts (Chapter 7). Lessons learned from the 1989 Exxon Valdez Oil Spill are included to identify valuable "pre-positioned" science and scientific approaches to improved response and reduced uncertainty in damage assessment and restoration efforts (appendix D). An appendix on Structured Decision Making (appendix C) is included to illustrate the value of such tools that go beyond, but incorporate, science in looking at what can/should be done about policy and implementation of Arctic development. The report provides a series of findings and recommendations for consideration developed during the independent examination of science gaps and sufficiency. These recommendations are important for understanding what the USGS discovered in the course of this study and to help inform and improve decision making.

Circular

The oilspill risk analysis model of the U. S. Geological Survey

The U.S. Geological Survey has developed an oilspill risk analysis model to aid in estimating the environmental hazards of developing oil resources in Outer Continental Shelf (OCS) lease areas. The large, computerized model analyzes the probability of spill occurrence, as well as the likely paths or trajectories of spills in relation to the locations of recreational and biological resources which may be vulnerable. The analytical methodology can easily incorporate estimates of weathering rates , slick dispersion, and possible mitigating effects of cleanup. The probability of spill occurrence is estimated from information on the anticipated level of oil production and method and route of transport. Spill movement is modeled in Monte Carlo fashion with a sample of 500 spills per season, each transported by monthly surface current vectors and wind velocities sampled from 3-hour wind transition matrices. Transition matrices are based on historic wind records grouped in 41 wind velocity classes, and are constructed seasonally for up to six wind stations. Locations and monthly vulnerabilities of up to 31 categories of environmental resources are digitized within an 800,000 square kilometer study area. Model output includes tables of conditional impact probabilities (that is, the probability of hitting a target, given that a spill has occurred), as well as probability distributions for oilspills occurring and contacting environmental resources within preselected vulnerability time horizons. (USGS)

Open-File Report