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Water-Quality Constituents, Dissolved-Organic-Carbon Fractions, and Disinfection By-Product Formation in Water from Community Water-Supply Wells in New Jersey, 1998-99

Water samples were collected from 20 community water-supply wells in New Jersey to assess the chemical quality of the water before and after chlorination, to characterize the types of organic carbon present, and to determine the disinfection by-product formation potential. Water from the selected wells previously had been shown to contain concentrations of dissolved organic carbon (DOC) that were greater than 0.2 mg/L. Of the selected wells, five are completed in unconfined (or semi-confined) glacial-sediment aquifers of the Piedmont and Highlands (New England) Physiographic Provinces, five are completed in unconfined bedrock aquifers of the Piedmont Physiographic Province, and ten are completed in unconsolidated sediments of the Coastal Plain Physiographic Province. Four of the ten wells in the Coastal Plain are completed in confined parts of the aquifers; the other six are in unconfined aquifers. One or more volatile organic compounds (VOCs) were detected in untreated water from all of the 16 wells in unconfined aquifers, some at concentrations greater than maximum contaminant levels. Those compounds detected included aliphatic compounds such as trichloroethylene and 1,1,1-trichloroethane, aromatic compounds such as benzene, the trihalomethane compound, chloroform, and the gasoline additive methyl tert-butyl ether (MTBE). Concentrations of sodium and chloride in water from one well in a bedrock aquifer and sulfate in water from another exceeded New Jersey secondary standards for drinking water. The source of the sulfate was geologic materials, but the sodium and chloride probably were derived from human inputs. DOC fractions were separated by passing water samples through XAD resin columns to determine hydrophobic fractions from hydrophilic fractions. Concentrations of hydrophobic acids were slightly lower than those of combined hydrophilic acids, neutral compounds, and low molecular weight compounds in most samples. Water samples from the 20 wells were adjusted to a pH of 7, dosed with sodium hypochlorite, and incubated for 168 hours (seven days) at 25 ?C to form disinfection by-products (DBPs). Concentrations of the DBPs-trihalomethanes, haloacetic acids, haloacetonitriles, and chlorate-were measured. Concentrations of these compounds, with few exceptions, were higher in water from Coastal Plain wells than from wells in glacial and bedrock aquifers. The organic-carbon fractions were dosed with sodium hypochlorite, incubated for 168 hours at 25 ?C, and analyzed for trihalomethanes, haloacetic acids, haloacetonitriles, and chlorate. Concentrations of trihalomethanes and haloacetic acids were higher in most of the hydrophobic organic-acid fractions than in the hydrophilic fractions, with the highest concentrations in samples from Coastal Plain aquifers. Traces of haloacetonitriles were measured, mostly in the hydrophilic fraction. The aromaticity of the precursor DOC, as estimated by measurements of the absorbance of ultraviolet light at 254 nanometers, apparently is a factor in the DBP formation potentials determined, as aromaticity was greater in the samples that developed high concentrations of DBPs. VOCs may have contributed to the organic carbon present in some of the samples, but much of the DOC present in water from the 20 wells appeared to be natural in origin. The sediments of the Coastal Plain aquifers, in particular, contain substantial amounts of organic matter, which contribute ammonia, organic nitrogen, and aromatic DOC compounds to the ground water. Thus, the geologic characteristics of the aquifers appear to be a major factor in the potential for ground water to form DBPs when chlorinated.

Scientific Investigations Report↗

Wetland and water supply

The Geological Survey has received numerous inquiries about the effects of proposed changes in the wetland environment. The nature of the inquiries suggests a general confusion in the public mind as to wetland values and an increasing concern by the public with the need for facts as a basis for sound decisions when public action is required. Perhaps the largest gap in our knowledge is in regard to the role played by the wetland in the natural water scheme. Specialists in such fields as agriculture and conservation have studied the wetland in relation to its special uses and values for farming and as a habitat for fish and wildlife. However, except as studied incidentally by these specialists, the role of the wetland with respect to water has been largely neglected. This facet of the wetland problem is of direct concern to the Geological Survey. We commonly speak of water in terms of its place in the hydrologic environment---as, for example, surface water or ground water. These terms imply that water can be neatly pigeonholed. With respect to the wetland environment nothing can be further from the truth. In fact, one objective of this discussion is to demonstrate that for the wetland environment surface water, ground water, and soil water cannot be separated realistically, but are closely interrelated and must be studied together. It should be noted that this statement holds true for the hydrologic environment in general, and that the wetland environment is by no means unique in this respect. Our second and principal objective is to identify some of the problems that must be studied in order to clarify the role of the wetland in relation to water supply. We have chosen to approach these objectives by briefly describing one area for which we have some information, and by using this example to point out some of the problems that need study. First, however, let us define what we, as geohydrologists, mean by wetland and briefly consider wetland classifications. For our purpose wetlands are land areas that are covered with shallow water or subjected to intermittent flooding and subsequent slow drainage, and which generally are characterized by an accumulation of organic matter hereafter termed swamp deposits.' These wetlands may be classified in a number of different ways depending on the purpose of the classifier. For example, the Fish and Wildlife Service classifies wetlands into 20 different types based on water quality (fresh or salty), drainage, and vegetation. At the risk of some oversimplification we might consider 4 types of wetland from the standpoint of hydrology: (1) fresh-water swamps in which the swamp deposits are underlain by glacial till or bedrock; (2)fresh-water swamps in which the swamp deposits are underlain by marine or lacustrine clay and silt; (3) fresh-water swamps in which the swamp deposits are underlain by glacial outwash or alluvium consisting mostly of sand or sand and gravel; and (4) salt .marshes and salt meadows. The three fresh-water types of wetland are of interest with respect to water supply, and of these, the type in which swamp deposits are underlain by glacial outwash is of particular interest in New England. In the Ipswich River basin above the Geological Survey gaging station at South Middleton, Mass., is an area of 44 square miles which forms the headwaters section of the basin. The relief of the area is low. About half the area consists of hills mostly underlain by bedrock but mantled by a thin layer of glacial till. The other half consists Of lowlands---including swamps, low terraces and plains---underlain by glacial outwash, Swampland, used hereafter as a synonym for wetland, forms about a fourth of the area. Some of the swamps occupy depressions in the till blanket and are situated at somewhat higher levels than the lowlands. The largest swamps, however, border the Ipswich River and its tributaries. Here the swamp deposits, which consist of muck and peat mixed with s

Circular↗

Northeast

The distinct seasonality of the Northeast’s climate supports a diverse natural landscape adapted to the extremes of cold, snowy winters and warm to hot, humid summers. This natural landscape provides the economic and cultural foundation for many rural communities, which are largely supported by a diverse range of agricultural, tourism, and natural resource-dependent industries (see Ch. 10: Ag & Rural, Key Message 4) . The recent dominant trend in precipitation throughout the Northeast has been towards increases in rainfall intensity, with increases in intensity exceeding those in other regions of the contiguous United States. Further increases in rainfall intensity are expected, with increases in total precipitation expected during the winter and spring but with little change in the summer. Monthly precipitation in the Northeast is projected to be about 1 inch greater for December through April by end of century (2070–2100) under the higher scenario (RCP8.5). Ocean and coastal ecosystems are being affected by large changes in a variety of climate-related environmental conditions. These ecosystems support fishing and aquaculture, tourism and recreation, and coastal communities. Observed and projected increases in temperature, acidification, storm frequency and intensity, and sea levels are of particular concern for coastal and ocean ecosystems, as well as local communities and their interconnected social and economic systems. Increasing temperatures and changing seasonality on the Northeast Continental Shelf have affected marine organisms and the ecosystem in various ways. The warming trend experienced in the Northeast Continental Shelf has been associated with many fish and invertebrate species moving northward and to greater depths. Because of the diversity of the Northeast’s coastal landscape, the impacts from storms and sea level rise will vary at different locations along the coast. Northeastern cities, with their abundance of concrete and asphalt and relative lack of vegetation, tend to have higher temperatures than surrounding regions due to the urban heat island effect. During extreme heat events, nighttime temperatures in the region’s big cities are generally several degrees higher than surrounding regions, leading to higher risk of heat-related death. Urban areas are at risk for large numbers of evacuated and displaced populations and damaged infrastructure due to both extreme precipitation events and recurrent flooding, potentially requiring significant emergency response efforts and consideration of a long-term commitment to rebuilding and adaptation, and/or support for relocation where needed. Much of the infrastructure in the Northeast, including drainage and sewer systems, flood and storm protection assets, transportation systems, and power supply, is nearing the end of its planned life expectancy. Climate-related disruptions will only exacerbate existing issues with aging infrastructure. Sea level rise has amplified storm impacts in the Northeast (Key Message 2), contributing to higher surges that extend farther inland, as demonstrated in New York City in the aftermath of Superstorm Sandy in 2012. Service and resource supply infrastructure in the Northeast is at increasing risk of disruption, resulting in lower quality of life, economic declines, and increased social inequality. Loss of public services affects the capacity of communities to function as administrative and economic centers and triggers disruptions of interconnected supply chains (Ch. 16: International, Key Message 1) . Increases in annual average temperatures across the Northeast range from less than 1°F (0.6°C) in West Virginia to about 3°F (1.7°C) or more in New England since 1901. Although the relative risk of death on very hot days is lower today than it was a few decades ago, heat-related illness and death remain significant public health problems in the Northeast. For example, a study in New York City estimated that in 2013 there were 133 excess deaths due to extreme heat. These projected increases in temperature are expected to lead to substantially more premature deaths, hospital admissions, and emergency department visits across the Northeast. For example, in the Northeast we can expect approximately 650 additional premature deaths per year from extreme heat by the year 2050 under either a lower (RCP4.5) or higher (RCP8.5) scenario and from 960 (under RCP4.5) to 2,300 (under RCP8.5) more premature deaths per year by 2090. Communities, towns, cities, counties, states, and tribes across the Northeast are engaged in efforts to build resilience to environmental challenges and adapt to a changing climate. Developing and implementing climate adaptation strategies in daily practice often occur in collaboration with state and federal agencies (e.g., New Jersey Climate Adaptation Alliance 2017, New York Climate Clearinghouse 2017, Rhode Island STORMTOOLS 2017, EPA 2017, CDC 2015 ). Advances in rural towns, cities, and suburban areas include low-cost adjustments of existing building codes and standards. In coastal areas, partnerships among local communities and federal and state agencies leverage federal adaptation tools and decision support frameworks (for example, NOAA’s Digital Coast, USGS’s Coastal Change Hazards Portal, and New Jersey’s Getting to Resilience). Increasingly, cities and towns across the Northeast are developing or implementing plans for adaptation and resilience in the face of changing climate (e.g., EPA 2017 ). The approaches are designed to maintain and enhance the everyday lives of residents and promote economic development. In some cities, adaptation planning has been used to respond to present and future challenges in the built environment. Regional efforts have recommended changes in design standards when building, replacing, or retrofitting infrastructure to account for a changing climate.

Report↗

Water resources inventory of Connecticut Part 5: lower Housatonic River basin

The 557 square miles of the lower Housatonic River basin in western Connecticut include the basins of two major tributaries, the Pomperaug and Naugatuck Rivers. Nearly all water is derived from precipitation, which averaged 47 inches per year during 1931-60, In this period an additional 570 billion gallons of water per year entered the basin in the main stem of the Housatonic River at Lake Lillinonah, and some water was imported by water-supply systems from outside the basin. Almost half the precipitation--21.6 inches--was lost from the basin by evapotranspiration. Except for small amounts exported, the remainder discharged as runoff and underflow into Long Island Sound. Variations in streamflow at 6 long-term continuous-record gaging stations are summarized in standardized graphs and tables that can be used to estimate streamflow characteristics at other sites. For example, mean flow and two low-flow characteristics, the 7-day annual minimum flow for 2-year and 10-year recurrence intervals, have been determined for many partial-record stations throughout the basin. Of the 37 principal lakes, ponds, and reservoirs in the basin, 6 have usable storage of more than 1 billion gallons. The “maximum safe draft rate” (described in: “Storage of Water in Lakes and Reservoirs”) of the largest of these, Thomaston Reservoir near Thomaston, is 75.6 million gallons per day for the 10-year and 20-year recurrence intervals of annual lowest mean flow. Floods have occurred during every month, at one time or another. The two greatest floods on the Naugatuck River in historical time occurred 2 months apart in 1955. The larger, in August, had a peak of 106,000 cfs (cubic feet per second) at Beacon Falls. Since then, the likelihood of major floods has been considerably reduced by a program of flood control in the basin. Water can be obtained from three aquifers under-lying the basin-stratified drift, till, and bedrock. Stratified drift covers about 16 percent of the basin, mostly in valleys and lowlands, and its saturated part generally ranges in thickness from 10 feet in small valleys to 200 feet in the Housatonic River valley. Its transmissivity ranges from 0 to 47,000 ft 2 /day (feet shared per day). Till, deposited directly by glacial ice, forms a widespread but discontinuous mantle over bedrock in most upland areas and extends beneath stratified drift in lowlands; it ranges in thickness from 0 to 200 feet. The median value of 31 published determinations of hydraulic conductivity of till in southern New England is 0.67 ft/day and ranges from 0.013 to 29 ft/day. Crystalline bedrock underlies most of the basin and is composed principally of granite, gneiss, and schist. Sedimentary volcanic bedrock underlies only the Pomperaug River basin. Regardless of rock type, water is obtained mostly from fractures. Streambed deposits are significant features of the hydrogeologic system because they affect the amount of water from streams and lakes that can be induced to infiltrate aquifers. Based on field tests, characteristic values of vertical hydraulic conductivity of streambed deposits are 0.40 ft/day for fine-grained deposits and 14 ft/day for gravelly deposits. Ground-water supplies generally range in yield from several millions of gallons per day from large well fields to 1 gpm (gallons per minute) from single wells. Large supplies, with yields of 100 gpm or more from individual wells, are most commonly obtained from stratified drift. Yields to be expected from screened wells tapping this aquifer can be calculated by use of a series of graphs in conjunction with estimates of transmissivity and aquifer thickness. The yields of 14 principal ground-water reservoirs are estimated from aquifer characteristics and also from the amount of water that can be obtained from aquifer storage, from interception or runoff, and from infiltration of streamflow at low-flow conditions, using a hypothetical well-field arrangement for each reservoir. It is assumed that induced infiltration is restricted to an amount equal to the 7-day annual minimum stream-flow for a 2-year recurrence interval. Yields range from 1.4 to 15 mgd (million gallons per day) during periods of no recharge, and from 2.0 to 17 mgd during recharge periods. Small to moderate water supplies can be obtained from any of the aquifers under suitable conditions. For example, data from 294 wells in the basin indicate that yields of a few gallons per minute can be obtained from bedrock at most sites. The likelihood of obtaining an adequate domestic supply is slightly greater in granite than in schist and also is greater where the overburden is stratified drift rather than till. Chemical analyses of precipitation samples collected monthly from five stations in the basin during a 9-month period in 1966 show that rainfall is acidic and that sulfate is the dominant anion, probably because of industrial fumes and smoke within and near the basin. Where unaffected by man’s activities, water in the basin is generally low in dissolved-solids concentration, is of the calcium magnesium bicarbonate type, and is soft to moderately hard. In general, streamflow is less mineralized than ground water, particularly when it consists largely of direct runoff. However, streamflow becomes more highly mineralized during low-flow conditions, when most of it consists of more highly mineralized water discharged from aquifers. The median value of dissolved-solids concentration of water at 22 stream sites was 51 mg/1 (milligrams per liter) during high flow, and 68 mg/1 during low flow within the study period. Iron and manganese occur naturally in objectionable concentrations in parts of the basin, particularly in streams draining swamps and in water from bedrock containing iron and manganese-bearing minerals. Man’s activities have degraded the quality of water in streams in much of the basin, except in the Pomperaug subbasin. In the Naugatuck River basin, the degradation in quality is shown by wide and erratic changes in dissolved-solids concentration, excessive amounts of certain trace elements, a low dissolved oxygen content, and abnormally high temperatures. Ground water is degraded principally by induced infiltration of stream water containing chemical wastes, by wastes stored on the ground and by effluents from septic tanks. Below its confluence with the Naugatuck River, much of the Housatonic River and adjoining marshes, wetlands, and aquifers contain salt water. Measurements of specific conductance during low-flow conditions in 1969 indicate that the dissolved-solids concentration of water in the estuary ranged from 210 mg/1 near Twomile Island to 20,000 mg/1 near Long Island Sound. The quantity and quality of water in the basin are satisfactory for a wide variety of uses, and, with suitable treatment, the water may be used for most purposes. In 1967, the total amount of water used in the basin was about 194 billion gallons. About 90 percent of this was used for industrial purposes, and 95 percent of the industrial water was obtained from surface-water sources. In the same year, 17 municipal and private water-supply systems supplied water of satisfactory quality to about three-fourths of the population.

Connecticut↗

Quality of water from crystalline rock aquifers in New England, New Jersey, and New York, 1995-2007

Crystalline bedrock aquifers in New England and parts of New Jersey and New York (NECR aquifers) are a major source of drinking water. Because the quality of water in these aquifers is highly variable, the U.S. Geological Survey (USGS) statistically analyzed chemical data on samples of untreated groundwater collected from 117 domestic bedrock wells in New England, New York, and New Jersey, and from 4,775 public-supply bedrock wells in New England to characterize the quality of the groundwater. The domestic-well data were from samples collected by the USGS National Water-Quality Assessment (NAWQA) Program from 1995 through 2007. The public-supply-well data were from samples collected for the U.S. Environmental Protection Agency (USEPA) Safe Drinking Water Act (SDWA) Program from 1997 through 2007. Chemical data compiled from the domestic wells include pH, specific conductance, dissolved oxygen, alkalinity, and turbidity; 6 nitrogen and phosphorus compounds, 14 major ions, 23 trace elements, 222 radon gas (radon), 48 pesticide compounds, and 82 volatile organic compounds (VOCs). Additional samples were collected from the domestic wells for the analysis of gross alpha- and gross beta-particle radioactivity, radium isotopes, chlorofluorocarbon isotopes, and the dissolved gases methane, carbon dioxide, nitrogen, and argon. Chemical data compiled from the public-supply wells include pH, specific conductance, nitrate, iron, manganese, sodium, chloride, fluoride, arsenic, uranium, radon, combined radium ( 226 radium plus 228 radium), gross alpha-particle radioactivity, and methyl tert -butyl ether (M t BE). Patterns in fluoride, arsenic, uranium, and radon distributions were discernable when the data were compared to lithology groupings of the bedrock, indicating that the type of bedrock has an effect on the quality of groundwater from NECR aquifers. Fluoride concentrations were significantly higher in groundwater samples from the alkali granite, peraluminous granite, and metaluminous granite lithology groups than from samples in the other lithology groups. Water samples from 1.4 percent of 2,167 studied wells had fluoride concentrations that were equal to or greater than the maximum contaminant level (MCL) of 4 milligrams per liter (mg/L) and 7.5 percent of the wells had fluoride concentrations that were equal to or greater than the secondary MCL of 2 mg/L. For arsenic, groundwater samples from the calcareous metasedimentary rocks in the New Hampshire-Maine geologic province, peraluminous granite, and pelitic rocks lithology groups had higher concentrations than did samples from the other lithology groups. Water samples from 13.3 percent of 2,054 studied wells had arsenic concentrations that were equal to or greater than the MCL of 10 micrograms per liter (μg/L), about double the national rate of occurrence in community-supply systems and in domestic wells of the United States. Uranium concentrations were significantly higher in groundwater samples from the peraluminous granite, alkali granite, and calcareous metasedimentary rocks in the New Hampshire-Maine geologic province lithology groups than from samples in the other lithology groups. Water samples from 14.2 percent of 556 studied wells had uranium concentrations equal to or greater than the MCL of 30 μg/L. Radon activities were equal to or greater than the proposed MCL of 300 picocuries per liter (pCi/L) in 95 percent of 943 studied wells, and 33 percent of the wells had radon activities were equal to or greater than the proposed alternative maximum contaminant level (AMCL) of 4,000 pCi/L. Radon activities exceeded the proposed AMCL in 20 percent or more of groundwater samples in each of the studied lithology groups with a minimum of 9 samples, but radon activities were significantly higher in groundwater samples from the alkali granite, peraluminous granite, and Narragansett basin metasedimentary rocks lithology groups. Water samples from 3.2 percent of 564 studied wells had combined radium activities equal to or greater than the MCL of 5 pCi/L; however, combined radium activities were not significantly different among the studied lithology groups. Land use and population density also were evaluated to explain patterns in water quality. Concentrations of nitrate, sodium, chloride, and MtBE from the studied wells were significantly greater in areas of high population density (≥50 persons per square kilometer) than in areas of low population density (<50 persons per square kilometer). Concentrations of sodium, chloride, and M t BE from the studied wells were significantly greater in areas classified as developed (urban lands) than in areas classified as undeveloped (forested), agricultural, or mixed (no dominant land use). Nitrate concentrations from the public-supply wells were not significantly different among the four land use categories, but nitrate concentrations from the domestic wells were significantly greater in areas classified as developed than in areas classified as undeveloped, agricultural, or mixed. Chloride to bromide mass ratios in the domestic well samples indicate that the groundwater was probably affected by at least three halogen sources: local precipitation and recharge waters, remnant seawater and connate waters evolved from seawater, and recharge waters affected by road salt. The groundwater in the NECR aquifers generally contained low concentrations of nitrate, VOCs, and pesticides. Less than 1 percent of water samples from 4,781 studied wells had concentrations of nitrate greater than the MCL of 10 mg/L. Less than 1 percent of water samples from 1,299 studied wells exceeded the USEPA advisory level of 20 to 40 μg/L for M t BE. None of the other studied VOCs exceeded a human health benchmark. M t BE (36 percent frequency detection) and chloroform (32.9 percent frequency detection) were the most frequently detected (>0.02 μg/L) VOCs in the domestic wells. M t BE was detected more often in water samples with apparent ages of less than 25 years than in water samples with apparent ages greater than 25 years. This finding is consistent with the time period of high M t BE use in areas in the United States where reformulated gasoline was mandated. The largest pesticide concentration was an estimated concentration of 0.06 μg/L for the herbicide metolachlor. Deethylatrazine, a degradate of atrazine, (18 percent frequency detection) and atrazine (8 percent frequency detection) were the only pesticide compounds detected (>0.001 μg/L) in more than 3 percent of the domestic wells. None of the detected pesticide compounds exceeded human health benchmarks. Concentrations of nitrate and gross alpha-particle activities were significantly greater in the water samples from the domestic wells than in samples from the public-supply wells. Concentrations of sodium, chloride, iron, manganese, and uranium were significantly greater in the water samples from the public-supply wells than in the samples from the domestic wells. One possible explanation may be related to differences in field processing (filtered samples from the domestic wells compared to unfiltered samples from the public-supply wells). The high frequency of detections for a wide variety of manmade and naturally occurring contaminants in both domestic and public-supply wells shows the vulnerability of NECR aquifers to contamination. The highly variable water quality and the association with highly variable lithology of crystalline bedrock underscores the importance of testing individual wells to determine if concentrations for the most commonly detected contaminants exceed human health benchmarks.

Connecticut, Maine, Massachusetts, New Hampshire, ↗