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Chapter 3. Tabular data and graphical images in support of the U.S. Geological Survey National Oil and Gas Assessment--East Texas basin and Louisiana-Mississippi salt basins provinces, Jurassic Smackover Interior salt basins total petroleum system (504902), Cotton Valley group

This chapter describes data used in support of the process being applied by the U.S. Geological Survey (USGS) National Oil and Gas Assessment (NOGA) project. Digital tabular data used in this report and archival data that permit the user to perform further analyses are available elsewhere on the CD-ROM. Computers and software may import the data without transcription from the Portable Document Format files (.pdf files) of the text by the reader. Because of the number and variety of platforms and software available, graphical images are provided as .pdf files and tabular data are provided in a raw form as tab-delimited text files (.tab files).

Alabama, Arkansas. Florida, Georgia, Louisiana, Mi↗

Chapter 6. Tabular data and graphical images in support of the U.S. Geological Survey National Oil and Gas Assessment–East Texas basin and Louisiana-Mississippi salt basins provinces, Jurassic Smackover interior salt basins total petroleum system (504902), Travis Peak and Hosston formations

This chapter describes data used in support of the process being applied by the U.S. Geological Survey (USGS) National Oil and Gas Assessment (NOGA) project. Digital tabular data used in this report and archival data that permit the user to perform further analyses are available elsewhere on the CD-ROM. Computers and software may import the data without transcription from the Portable Document Format files (.pdf files) of the text by the reader. Because of the number and variety of platforms and software available, graphical images are provided as .pdf files and tabular data are provided in a raw form as tab-delimited text files (.tab files).

Alabama, Arkansas. Florida, Georgia, Louisiana, Mi↗

Potentiometric map of the Cockfield Aquifer in Mississippi, fall, 1980

This potentiometric map of the Cockfield aquifer is the eleventh in a series of maps, prepared by the U.S. Geological Survey in cooperation with the Mississippi Department of Natural Resources , Bureau of Land and Water Resources, delineating the potentiometric surfaces of the major aquifers in Mississippi. In the outcrop area of the Cockfield quifer the potentiometric surface is strongly affected by recharge from precipitation, by topography, and by drainage of the aquifer by streams. The potentiometric surface slopes downward generally to the west away from the area of outcrop and is strongly affected by large ground-water withdrawals in the Jackson and Greenville areas. Historically, water levels in or near the outcrop of the Cockfield aquifer have shown little or no long-term changes, but in much of the confined part of the aquifer during the past 20 years, water levels have declined from 1 to 2 feet per year.

Mississippi↗

Potentiometric map of the Winona-Tallahatta aquifer in northwestern Mississippi, fall 1979

The potentiometric map of the Winona-Tallahatta aquifer is one of a series of maps, prepared by the U.S. Geological Survey in cooperation with the Mississippi Department of Natural Resources , Bureau of Land and Water Resources, delineating the potentiometric surfaces of the major aquifers in Mississippi. In the outcrop area of the Winona-Tallahatta aquifer the potentiometric surface is strongly affected by recharge from precipitation, by topography, and by drainage of the aquifer by streams. The potentiometric surface slopes downward generally to the west away from the area of outcrop and is strongly affected by recharge from precipitation, by topography, and by drainage of the aquifer by streams. The potentiometric surface slopes downward generally to the west away from the area of outcrop and is strongly affected by pumpage from wells in Leflore, Sunflower , and Bolivar Counties, Historically, water levels in or near the outcrop of the Winona-Tallahatta have shown little or no long-term changes, but the heavy withdrawals in the confined part of the aquifer have caused long-term water-level declines of 1 to 2 feet per year. (USGS)

Mississippi↗

Archive of sediment data from vibracores collected in 2010 offshore of the Mississippi barrier islands

In 2010, scientists from the U.S. Geological Survey St. Petersburg Coastal and Marine Science Center collected sediment cores from coastal waters offshore of the Mississippi barrier islands. With funding support from the Northern Gulf of Mexico (NGOM) Ecosystem Change and Hazard Susceptibility project, 65 subaqueous sediment cores were collected over an area of 480 square kilometers (km 2 ), from Ship Island to Petit Bois Island Pass, Mississippi, within the boundary of Gulf Islands National Seashore. This represents only a fraction of the total area encompassed by the NGOM project, which extends from Sabine Lake, Louisiana, to Perdido Bay, Alabama. The primary objectives of the NGOM project are to understand the evolution of coastal ecosystems on the northern gulf coast, the impact of human activities on these ecosystems, and the vulnerability of ecosystems and human communities to more frequent and intense hurricanes in the future. Selection of the core site locations was based on geophysical surveys conducted around the islands from 2008 to 2010. The surveys, using acoustic systems to image and interpret the nearsurface stratigraphy, were conducted to investigate the geologic controls on island evolution. This data series serves as an archive of sediment data collected from August to September 2010, offshore of the Mississippi barrier islands. Data products, including descriptive core logs, core photographs, results of sediment grain-size analyses, sample location maps, and geographic information system (GIS) data files with accompanying formal Federal Geographic Data Committee (FDGC) metadata can be downloaded from the data products and downloads page.

Mississippi↗

Occurrence, distributions, and transport of herbicides and their degradation products in the lower Mississippi river and its tributaries

The Mississippi River and its tributaries drain extensive agricultural regions of the midcontinental United States, where large amounts of herbicides are applied as weed control agents on crops such as corn and soybeans. Studies being conducted by the U.S. Geological Survey along the lower Mississippi River and its major tributaries, representing a 1930-km river reach, have confirmed that several triazine and chloroacetanilide herbicides and their degradation products are present in this riverine system. These herbicides include atrazine, and its degradation products, desethyl- and desisopropylatrazine; cyanazine; simazine; metolachlor; and alachlor and its degradation products, 2-chloro-2',6'-diethylacetanilide, and 2-hydroxy-2',6'-diethylacetanilide. Loads of these compounds were determined at 17 different sampling stations under various seasonal and hydrologic conditions, during five sampling trips from July 1987 to June 1989. Stream loads of herbicides were relatively small during the drought of 1987 and 1988. Stream loads were much greater during the relatively wet year of 1989. Trace levels of atrazine, cyanazine, and metolachlor also were associated with suspended sediments. Distribution coefficients (Koc) of these compounds varied considerably between sites and were much larger than Koc values reported in the literature. The annual transport of atrazine into the Gulf of Mexico was estimated to be less than 2% of the amount of atrazine applied each year in the midwest.

Lower Mississippi River↗

A preliminary environmental site investigation for a bridge over the Mississippi River at Moline, Illinois

The Illinois State Geological Survey completed a preliminary environmental site assessment along the alignment of Interstate 74 (I-74) and its bridge over the Mississippi River for the Illinois Department of Transportation (IDOT) in 2002. The objective of the study was to determine if any of the parcels proposed for acquisition or on which soil excavation was intended were sufficiently contaminated to require additional investigation by a commercial environmental consultant under contract to IDOT and to identify potential natural hazards that might have an impact on the proposed construction project. VOC were detected at 13 of 37 sites tested for VOC. These sites included an elevator manufacturer, former foundries, former and active machine shops, former and active gasoline stations, and a former automobile dealer. PAH above TACO Tier 1 residential standards were detected on an island in the Mississippi River. PCB was detected at a former foundry and a control box for a railroad. Magnetic anomalies that might indicate the presence of UST were detected in a park that formerly had been the site of a city garage, adjacent to a parking lot that formerly contained an automobile dealer, and at the sites of three former gasoline stations. These studies helped IDOT to save millions of dollars in highway construction projects. This is an abstract of a paper presented in Contaminated Soils, Sediments and Water: Success and Challenges (Massachusetts Fall 2005).

Conference Paper↗

Potentiometric map of the lower Wilcox aquifer in Mississippi, fall 1982

This potentiometric map is the second map of the lower Wilcox aquifer in a series of maps prepared by the U.S. Geological Survey in cooperation with the Mississippi Department of Natural Resources, Bureau of Land and Water Resources, delineating the potentiometric surface of the major aquifers in Mississippi. The potentiometric surface of the lower Wilcox aquifer slopes generally to the west away from the outcrop area and it is marked by a large groundwater cone of depression in the area of Tallahatchie, Quitman, and Panola Counties. Water levels in or near the outcrop of the lower Wilcox aquifer show little longterm change. Heavy withdrawals in the downdip area have caused water level declines of about 1 to 2 feet per year since 1979 in much of the confined part of the aquifer. These water level declines in the area of Tallahatchie, Quitman, and Panola Counties have resulted in a wider cone of depression since 1979. (USGS)

Water-Resources Investigations Report↗

Nutrients in northern Missouri streams

Nutrients, specifically nitrogen and phosphorus, are necessary for healthy aquatic communities to thrive, but if nutrient concentrations are too high, water quality can be degraded and natural aquatic communities may be destroyed. Nutrients consistently have been listed nationally as one of the top five causes of stream and river impairments, and agriculture consistently has been identified as the leading known source. The Mississippi River watershed was identified as a top priority for nutrient reductions because of the predominant agricultural land use, the associated harmful effects of nutrient loading on local water bodies, and the resulting annual midsummer northern Gulf of Mexico hypoxic “dead” zone. In 2010, the Natural Resources Conservation Service started the Mississippi River Basin Healthy Watersheds Initiative, which offers financial and technical assistance for voluntary conservation practices on agricultural lands. The intention is to reduce nutrient and sediment export to waterways within the Mississippi River watershed. The U.S. Geological Survey Missouri Water Science Center and the Missouri Department of Natural Resources began a cooperative study in 2010 to compare temporal changes in total nitrogen and total phosphorus concentrations in the Lower Grand River. Despite increases in conservation practice funding from the Mississippi River Basin Healthy Watersheds Initiative during 2011–15 for the Lower Grand River, decreases in flow-normalized total nitrogen and total phosphorus concentrations during this same period at the Grand River site were less than at the other long-term Missouri River tributary sites that did not receive additional funding. The flow-normalized total nitrogen and total phosphorus concentrations at the three long-term Missouri River tributary sites were related to the amount of agricultural land use within their watersheds and livestock manure may be a substantial source of stream nitrogen. Monthly total nitrogen and total phosphorus concentrations within the Lower Grand River increased with increased streamflow, indicating that the major sources of nitrogen and phosphorus are runoff or nutrients that are stored in soils within the streambank that mobilize during higher streamflows. Programs such as the Mississippi River Basin Healthy Watersheds Initiative are intended to encourage voluntary agricultural conservation practices to enhance soil health and reduce nutrient export to streams.

Missouri↗

Geotechnical description of four Mississippi Delta soil borings

The submerged portion of the Mississippi Delta complex forms an ideal natural laboratory to study the effects of rapid deposition. One of the most obvious of these effects is the mass movements of sediments. Slump and slide signatures, mudflow characteristics, and evidence for creep are all found in abundance on the delta platform. These types of features have been studied by Colemen and Wright (1974) with regard to form and by Garrison (1974) with regard to their spatial distribution. Assembling these authors' findings, it is clear that the entire offshore zone contiguous with the Mississippi River is a myriad of geological action. This situation is indeed stimulating to the sedimentologist, yet it represents a nightmare to the foundation engineer. Emplacing offshore structures in such an environment is a most difficult task, particularly since the high degree of local variability dictates that each case must be handled separately. It is under these circumstances that a marriage between geology and engineering is most fruitful, for determining the relationships between the sedimentological processes and the engineering properties is satisfying to parties from both disciplines. This, then, is the underlying objective of the Mississippi Delta research project. By investigating the instability in a geologic sense, it is hoped that many of the engineering problems will become more soluble and that extrapolation and prediction will become more realistic.

Mississippi Delta↗

A brief history and summary of the effects of river engineering and dams on the Mississippi River system and delta

The U.S. Geological Survey Forecast Mekong project is providing technical assistance and information to aid management decisions and build science capacity of institutions in the Mekong River Basin. A component of this effort is to produce a synthesis of the effects of dams and other engineering structures on large-river hydrology, sediment transport, geomorphology, ecology, water quality, and deltaic systems. The Mississippi River Basin (MRB) of the United States was used as the backdrop and context for this synthesis because it is a continental scale river system with a total annual water discharge proportional to the Mekong River, has been highly engineered over the past two centuries, and the effects of engineering have been widely studied and documented by scientists and engineers. The MRB is controlled and regulated by dams and river-engineering structures. These modifications have resulted in multiple benefits including navigation, flood control, hydropower, bank stabilization, and recreation. Dams and other river-engineering structures in the MRB have afforded the United States substantial socioeconomic benefits; however, these benefits also have transformed the hydrologic, sediment transport, geomorphic, water-quality, and ecologic characteristics of the river and its delta. Large dams on the middle Missouri River have substantially reduced the magnitude of peak floods, increased base discharges, and reduced the overall variability of intraannual discharges. The extensive system of levees and wing dikes throughout the MRB, although providing protection from intermediate magnitude floods, have reduced overall channel capacity and increased flood stage by up to 4 meters for higher magnitude floods. Prior to major river engineering, the estimated average annual sediment yield of the Mississippi River Basin was approximately 400 million metric tons. The construction of large main-channel reservoirs on the Missouri and Arkansas Rivers, sedimentation in dike fields, and protection of channel banks by revetments throughout the basin, have reduced the overall sediment yield of the MRB by more than 60 percent. The primary alterations to channel morphology by dams and other engineering projects have been (1) channel simplification and reduced dynamism; (2) lowering of channel-bed elevation; and (3) disconnection of the river channel from the flood plain, except during extreme flood events. Freshwater discharge from the Mississippi River and its associated sediment and nutrient loads strongly influence the physical and biological components in the northern Gulf of Mexico. Ninety percent of the nitrogen load reaching the Gulf of Mexico is from nonpoint sources with about 60 percent coming from fertilizer and mineralized soil nitrogen. Much of the phosphorus is from animal manure from pasture and rangelands followed by fertilizer applied to corn and soybeans. Increased nutrient enrichment in the northern Gulf of Mexico has resulted in the degradation of water quality as more phytoplankton grow, which increases turbidity and depletes oxygen in the lower depths creating what is known as the "dead zone." In 2002, the dead zone was 22,000 square kilometers (km2), an area similar to the size of the State of Massachusetts. Changes in the flow regime from engineered structures have had direct and indirect effects on the fish communities. The navigation pools in the upper Mississippi River have aged, and these overwintering habitats, which were created when the pools filled, have declined as sedimentation reduces water depth. Reproduction of paddlefish may have been adversely affected by dams, which impede access to suitable spawning habitats. Fishes that inhabit swift-current habitats in the unimpounded lower Mississippi River have not declined as much as in the upper Mississippi River. The decline of the pallid sturgeon may be attributable to channelization of the Missouri River above St. Louis, Missouri. The Missouri River supports a rich fish community and remains relatively intact. Nevertheless, the widespread and long history of human intervention in river discharge has contributed to the declines of about 25 percent of the species. The Mississippi River Delta Plain is built from six delta complexes composed of a massive area of coastal wetlands that support the largest commercial fishery in the conterminous United States. Since the early 20th century, approximately 4,900 km2 of coastal lands have been lost in Louisiana. One of the primary mechanisms of wetland loss on the Plaquemines-Balize complex is believed to be the disconnection of the river distributary network from the delta plain by the massive system of levees on the delta top, which prevent overbank flooding and replenishment of the delta top by sediment and nutrient deliveries. Efforts by Federal and State agencies to conserve and restore the Mississippi River Delta Plain began over three decades ago and have accelerated over the past decade. Regardless of these efforts, however, land losses are expected to continue because the reduced upstream sediment supplies are not sufficient to keep up with the projected depositional space being created by the combined forces of delta plain subsidence and global sea-level rise.

Alabama;Alberta;Arkansas;Colorado;Georgia;Illinois↗

Petroleum systems and geologic assessment of undiscovered oil and gas, Cotton Valley Group and Travis Peak-Hosston Formations, East Texas Basin and Louisiana-Mississippi Salt Basins Provinces of the Northern Gulf Coast Region

The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States. The USGS recently completed an assessment of undiscovered oil and gas potential of the Cotton Valley Group and Travis Peak and Hosston Formations in the East Texas Basin and Louisiana-Mississippi Salt Basins Provinces in the Gulf Coast Region (USGS Provinces 5048 and 5049). The Cotton Valley Group and Travis Peak and Hosston Formations are important because of their potential for natural gas resources. This assessment is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). The USGS used this geologic framework to define one total petroleum system and eight assessment units. Seven assessment units were quantitatively assessed for undiscovered oil and gas resources.

Alabama, Arkansas. Florida, Georgia, Louisiana, Mi↗

Magnitude and frequency of floods in the alluvial plain of the lower Mississippi River, 2017

Annual exceedance probability flows at gaged locations and regional regression equations used to estimate annual exceedance probability flows at ungaged locations were developed by the U.S. Geological Survey, in cooperation with the Mississippi Department of Transportation, to improve flood-frequency estimates at rural streams in the alluvial plain of the lower Mississippi River. These estimates were developed using current geospatial data, analytical methods, and annual peak-flow data through September 2017 at 58 streamgages in the alluvial plain of the lower Mississippi River, including 9 in Mississippi, 35 in Arkansas, 4 in Missouri, and 10 in Louisiana. Annual exceedance probability flows presented in this report incorporate streamflow data through the 2017 water year, 32 additional years of record since the previous study in 1985 of flood magnitude and frequency in the Mississippi portion of the alluvial plain of the lower Mississippi River. Ranges for standard error of prediction, average variance of prediction, and pseudo-R 2 are 45–61 percent, 0.035–0.059 (log cubic feet per second) 2 , and 90–94 percent, respectively.

Arkansas, Illinois, Kentucky, Louisiana, Mississip↗

Water-quality assessment of part of the upper Mississippi River Basin, Minnesota and Wisconsin — Nitrogen and phosphorus in streams, streambed sediment, and ground water, 1971-94

Nitrogen and phosphorus in streams, streambed sediment, and ground water were summarized using data from Federal, state, and local agencies as part of an analysis of historical water-quality data for the Upper Mississippi River Basin study unit of the U.S. Geological Survey's National Water-Quality Assessment Program. The Upper Mississippi River Basin study unit encompasses the drainage of the Mississippi River from the source to the outlet of Lake Pepin. This report focuses on a 19,500-square-mile study area in the eastern part of the study unit. The study area included the part of the Upper Mississippi River Basin from Royalton, Minnesota, to the outlet of Lake Pepin, located near Red Wing, Minnesota; the Minnesota River Basin from Jordan, Minnesota, to the confluence with the Mississippi River; and the entire drainage basins of the St. Croix, Cannon, and Vermillion Rivers. The Twin Cities metropolitan area, with a population of approximately 2.3 million people, is located in the south-central part of the study area. Fertilizers and livestock manure were the greatest sources of nitrogen and phosphorus applied to the land surface of the study unit. Approximately 60 percent of the fertilizer was applied to the Minnesota River Basin, which drains agricultural areas in the southern and western parts of the study unit. Concentrations of total nitrite plus nitrate nitrogen, total nitrogen, and total phosphorus in streams, generally were greatest in the tributaries to the Mississippi River draining agricultural areas in the western and southern part of the study area. Concentrations of these constituents generally were least in tributaries draining forested land. The greatest total nitrite plus nitrate nitrogen concentrations generally occurred during the spring and summer in streams draining agricultural areas and in the winter in streams draining forested areas. Total phosphorus concentrations generally were greatest in the spring and summer for all streams. Total nitrite plus nitrate nitrogen, total nitrogen, and total phosphorus concentrations in the Mississippi River increased substantially downstream from the Minnesota River and downstream from wastewater discharges in the Twin Cities metropolitan area. Total ammonia and dissolved orthophosphate concentrations generally were greatest at sites on the Mississippi and Minnesota Rivers downstream from wastewater discharges from the Twin Cities metropolitan area. Total nitrite plus nitrate nitrogen concentrations in streams generally were less than the Maximum Contaminant Level of 10 mg/L (as nitrogen) established by the U.S. Environmental Protection Agency. Total phosphorus concentrations in streams generally were greater than the 0.1 mg/L concentration recommended by the U.S. Environmental Protection Agency at sites located in agricultural areas and on the Mississippi River downstream from its confluence with the Minnesota River. Phosphorus and nitrogen yields were greatest in watersheds primarily draining agricultural land. The majority of the nitrogen and phosphorus loading to the Mississippi River was from the Minnesota River. In the Minnesota River, the nitrogen load primarily was total nitrite plus nitrate nitrogen. Despite increases in fertilizer usage during 1982-91, most stream sites outside of the Twin Cities metropolitan area had no temporal trends in total nitrite plus nitrate nitrogen, total phosphorus, or dissolved orthophosphate concentrations for water years 1984-93. Most sites had a decrease in total ammonia nitrogen concentrations, possibly a result of improvements in wastewater treatment. In the Twin Cities metropolitan area, decreases in total ammonia concentrations in the Mississippi and Minnesota Rivers coincided with increases in total nitrite plus nitrate nitrogen concentrations, probably a result of wastewater treatment plants initiating nitrification processes. Nitrite plus nitrate nitrogen concentrations in ground water reflect land uses and hydrogeologic settings of major aquifers in the study area. Unconfined sand and gravel, buried sand and gravel, and the Prairie du Chien-Jordan were the aquifers most frequently sampled for nitrite plus nitrate nitrogen because they are the principal sources of ground water in the study area. The greatest nitrite plus nitrate nitrogen concentrations reported by Federal and state agencies, some exceeding the U.S. Environmental Protection Agency's Maximum Contaminant level of 10 mg/L by a factor of four, were in water from shallow wells in agricultural and mixed forested and agricultural areas. Water sampled from buried sand and gravel aquifers, which are more shielded from substances leaching from the land surface by layers of clay or till, generally had lower nitrite plus nitrate nitrogen concentrations than water from unconfined sand and gravel aquifers. Nitrite plus nitrate nitrogen concentrations in water samples from the Prairie du Chien-Jordan aquifer were greatest in the Wisconsin part of the study area and in the vicinity of the Cannon River, where the aquifer is commonly unconfined, exposed at land surface, and overlain by agricultural or by mixed forested and agricultural land covers. Dissolved phosphorus concentrations in ground water in the study area generally were near detection limits of 0.01 mg/L or lower, indicating that surface-water eutrophication from phosphorus may be more likely to occur from overland runoff of phosphorus compounds and from direct discharges of treated wastewater than from ground-water base flow. The greatest concentrations of dissolved phosphorus in ground water generally were detected in water samples from wells in urban portions of the study area.

Minnesota, Wisconsin↗

Geologic control on the evolution of the inner shelf morphology offshore of the Mississippi barrier islands, northern Gulf of Mexico, USA

Between 2008 and 2013, high-resolution geophysical surveys were conducted around the Mississippi barrier islands and offshore. The sonar surveys included swath and single-beam bathymetry, sidescan, and chirp subbottom data collection. The geophysical data were groundtruthed using vibracore sediment collection. The results provide insight into the evolution of the inner shelf and the relationship between the near surface geologic framework and the morphology of the coastal zone. This study focuses on the buried Pleistocene fluvial deposits and late Holocene shore-oblique sand ridges offshore of Petit Bois Island and Petit Bois Pass. Prior to this study, the physical characteristics, evolution, and interrelationship of the ridges between both the shelf geology and the adjacent barrier island platform had not been evaluated. Numerous studies elsewhere along the coastal margin attribute shoal origin and sand-ridge evolution to hydrodynamic processes in shallow water (<20 m). Here we characterize the correlation between the geologic framework and surface morphology and demonstrate that the underlying stratigraphy must also be considered when developing an evolutionary conceptual model. It is important to understand this near surface, nearshore dynamic in order to understand how the stratigraphy influences the long-term response of the coastal zone to sea-level rise. The study also contributes to a growing body of work characterizing shore-oblique sand ridges which, along with the related geology, are recognized as increasingly important components to a nearshore framework whose origins and evolution must be understood and inventoried to effectively manage the coastal zone.

Continental Shelf Research↗

Ammonia in ground water from the Mississippi River alluvium, Fort Madison, Iowa

The U.S. Geological Survey, in cooperation with the City of Fort Madison, conducted a study of the potential sources and possible processes that might produce ammonia in ground water from the Mississippi River alluvium near Fort Madison, Iowa. High ammonia concentrations of 3.0 to 6.4 milligrams per liter were detected in water produced from municipal well Fort Madison #4 from 1992 through 1996. Total organic carbon concentrations of about 5 milligrams per liter were also reported during the same time period. Water-level measurements from two municipal wells and one well at Iowa State Penitentiary were used to determine that the general direction of ground-water flow during the two days of sampling was from northeast to southwest toward wells Fort Madison #4 and Fort Madison #5. Continuous pumping of other nearby wells probably influenced the direction of ground-water flow on these days. Because of a till confining unit separating the Mississippi River and the alluvial aquifer, it is uncertain to what extent induced recharge occurs to the alluvial aquifer from the river. Water samples were collected from three municipal wells, two industrial wells, one watersupply well at the Iowa State Penitentiary, one domestic well, two creeks, and the Mississippi River. Tritium analytical results indicate that the time of recharge was after 1953 for water from the municipal wells (where tritium samples were collected). The ammonia concentration, 5.1 milligrams per liter, was considerably higher in ground water collected from well Fort Madison #4 compared to samples collected from other wells. The dissolved organic carbon concentration was also highest in ground water collected from well Fort Madison #4 (5.5 milligrams per liter) although samples from other wells were also relatively high, 2.6 to 5.3 milligrams per liter. The most likely process producing the high ammonia concentration in ground water in the vicinity of well Fort Madison #4 is decomposition of organic matter (ammonification). Nitrogen isotope values, when compared to nitrogen isotope values found in ground water in the vicinity of some of the other wells, indicate the possibility that a higher percentage of the ammonia found in ground water in the vicinity of well Fort Madison #4 may be from human and(or) other animal wastes. Higher concentrations of dissolved phosphorus, orthophosphate, and a higher chloride-to-sodium mole ratio found in ground water sampled from well Fort Madison #4 could be indicative of a sewage or septic source. Potential sources include existing or abandoned septic systems, leaking sanitary sewer lines, commercial or residential waste-disposal sites, and agricultural runoff upgradient from well Fort Madison #4, or possibly, bed sediments of the Mississippi River.

Iowa↗

Nutrients and suspended sediment in snowmelt runoff from part of the Upper Mississippi River Basin, Minnesota and Wisconsin, 1997

The U.S. Geological Survey sampled snowmelt runoff from 42 stream sites during March and April 1997 in part of the Upper Mississippi River Basin, Minnesota and Wisconsin, to characterize nutrient and suspended-sediment concentrations, yields, and loads. Ancillary data from 12 sites provided data to estimate constituent loads delivered during snowmelt and 1997. The snowmelt period contributed from 1 to 50 percent of 1997 annual loads of total nitrogen, total phosphorus, and suspended sediment at small stream sites, and 17 to 70 percent of annual loads at mainstem river sites. Small streams in agricultural areas transported the greatest proportions of annual loads during snowmelt. Snowmelt from urban streams transported the least proportions of annual loads. Agricultural streams had significantly greater median yields (p < 0.025) of dissolved nitrite, nitrate, phosphorus, orthophosphate, total nitrogen, and total phosphorus than forested sites, and significantly greater median yields (p < 0.025) of dissolved nitrate and orthophosphate than all other land uses. In forested areas, yields of suspended sediment and all nutrient forms were significantly greater (p < 0.05) for streams draining impermeable deposits than permeable deposits.

Minnesota, Wisconsin↗