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Solute geochemistry of the Snake River plain regional aquifer system, Idaho and eastern Oregon

Four geochemical approaches were used to determine chemical reactions controlling solute concentrations in the Snake River Plain regional aquifer system: (1) calculation of a solute balance within the aquifer, (2) identification of weathered products in the aquifer frame- work, (3) comparison of thermodynamic mineral saturation indices with plausible solute reactions, and (4) comparison of stable-isotope ratios of the solutes with those in the aquifer framework. Solutes in the geo- thermal groundwater system underlying the main aquifer were examined by calculating thermodynamic mineral saturation indices, stable-isotope ratios, geothermometry, and radiocarbon dating. Water budgets, hydrologic arguments, and isotopic analyses for the eastern Snake River Plain aquifer system demonstrate that most, if not all, water is of local meteoric and not juvenile or formation origin. Thus, the solutes must also originate within the basin. Solute balance, isotopic, mineralogic, and thermodynamic arguments suggest that about 20 per- cent of the solutes leaving the basin are derived from reactions with rocks forming the aquifer framework. Most of the remaining solutes are introduced from tributary drainage basins. Mass-balance calculations, thermodynamic arguments, and petro- graphic observations indicate that calcite and silica are precipitated in the aquifer. Petrographic evidence and thermodynamic arguments sug- gest that olivine, pyroxene, plagioclase, pyrite, and anhydrite are being weathered from the aquifer framework. Large amounts of sodium, chloride, and sulfate, relative to their concentration in the igneous rock, are being removed from the aquifer. Release of fluids from inclusions in the igneous rocks and initial flushing of grain boundaries and pores of detrital marine sediments in interbeds are believed to be a major source of these solutes. Identification and quantification of reactions controlling solute concentrations in ground water in the eastern plain indicate that the aquifer is not a large mixing vessel that simply stores and transmits water and solutes but is undergoing diagenesis and is both a source and a sink for solutes. Evaluation of solute concentrations and stable-isotope ratios of hydrogen, oxygen, carbon, and sulfur along groundwater flowpaths that transect irrigated areas suggests that irrigation water may have altered solute concentrations and isotope ratios in the eastern Snake River Plain aquifer system. The changes, however, have been small because of the similarity of solute concentrations and ratios in applied irrigation water and in native ground water, and because of rapid movement and large dispersivity of the aquifer. Reactions controlling solutes in the western Snake River basin are believed to be similar to those in the eastern basin but, because of dif- ferent hydrologic conditions, a definitive analysis could not be made. The regional geothermal system that underlies the Snake River Plain contains total dissolved solids similar to those in the overlying Snake River Plain aquifer system but contains higher concentrations of sodium, bicarbonate, silica, fluoride, sulfate, chloride, arsenic, boron, and lithium, and lower concentrations of calcium, magnesium, and hydrogen. These solutes are believed to be derived from reactions similar to those in the Snake River Plain aquifer system, except that ion exchange and hydrol- ysis play a role in controlling solute concentrations in the geothermal system. Geothermometry calculations of selected ground-water samples from known geothermal areas throughout the basin suggest that the geother- mal system is large in areal extent but has relatively low temperatures. Approximately half of the silica-quartz calculated water temperatures are greater than 90 °C. Radiocarbon dating of geothermal water in the Salmon Falls and Bruneau-Grand View areas in the south central part of the Snake River basin suggests that residence time of the geother- mal water is about 17,700 years.

Idaho;Oregon↗

Groundwater-flow model of the Treasure Valley, southwestern Idaho, 1986–2015

Most of the population of the Treasure Valley and the surrounding area of southwestern Idaho and easternmost Oregon depends on groundwater for domestic supply, either from domestic or municipal-supply wells. Current and projected rapid population growth in the area has caused concern about the long-term sustainability of the groundwater resource. In 2016, the U.S. Geological Survey, in cooperation with the Idaho Water Resource Board and the Idaho Department of Water Resources, began a project to construct a numerical groundwater-flow model of the westernmost portion of the western Snake River Plain aquifer system, called the Treasure Valley. The development of the model was guided by several objectives, including: to improve the understanding of groundwater and surface water interactions; to facilitate conjunctive water management; to provide a tool for water resources planning; and to provide a tool for water allocation. The model was constructed with a spatial scale and level of detail that aimed to meet these objectives while balancing the sometimes-competing goals of fast runtimes, numerical stability, usability, and parsimony. The Treasure Valley Groundwater Flow Model (TVGWFM) is a three-dimensional finite-difference numerical model constructed using MODFLOW 6 (Langevin and others, 2017, Documentation for the MODFLOW 6 Groundwater Flow Model: U.S. Geological Survey Techniques and Methods, book 6, chap. A55, 197 p., https://doi.org/10.3133/tm6A55 ). The model covers the westernmost portion of the western Snake River Plain and is discretized into a regular grid of 64 by 65 cells with a side length of 1 mile and 6 layers of varying depth and active area. A historical model period was developed consisting of 360 month-long stress periods for 1986–2015. The model builds upon previous modeling efforts by adding a transient period, incorporating new head and discharge observations to constrain parameters, incorporating information from the hydrogeologic framework model (HFM) of Bartolino (2019, Hydrogeologic framework of the Treasure Valley and surrounding area, Idaho and Oregon: U.S. Geological Survey Scientific Investigations Report 2019–5138, https://doi.org/10.3133/sir20195138 ) and incorporating refined estimates of evapotranspiration and irrigation classification of lands in the study area. The TVGWFM includes all significant components of recharge to and discharge from the aquifer. Inflows include canal seepage, irrigation and precipitation recharge, mountain-front recharge, rivers and stream seepage, and seepage from Lake Lowell. Outflows include discharge to agricultural drainage ditches, discharge to rivers and streams, pumping, and discharge to Lake Lowell. Each recharge or discharge component is represented separately using individual MODFLOW 6 packages. Parameter values were derived with a combination of trial-and-error steps and automated parameter estimation using PEST software (Doherty, J.E., 2005, PEST, model-independent parameter estimation–User manual: Watermark Numerical Computing, https://pesthomepage.org/documentation ). Parameter estimates were constrained with several types of observation data, including water levels, water level changes, vertical water level differences, drain discharges, change in drain discharges, river seepage, seepage from Lake Lowell, and change in seepage from Lake Lowell. Material properties from the hydrogeologic framework were also used to assign the minimum and maximum values of some parameters. A final parameter realization was reached that minimized residuals between the observed and modelled values for the various observation groups. Mean residuals for the observation groups were 15.4 feet (ft) for water levels, 0.2 ft for water level changes, 19.4 ft for vertical water level differences, −3.9 cubic feet per second (ft 3 /s) for drain discharges, 0.0 ft 3 /s for changes in drain discharge, 45.0 ft 3 /s for river seepage, −40.1 ft 3 /s for Lake Lowell seepage, and 126.3 ft 3 /s for changes in Lake Lowell seepage. The quality of the model’s fit to observations varied spatially, with notable areas of under- or over-simulation of water levels present to the northwest and southwest of Lake Lowell, in the foothills along the eastern model boundary, and near the City of Eagle. Trends were observed in the residuals of many of the observation groups, indicating that the model is missing or not fully reproducing some phenomena that are observed in the system. The TVGWFM can be used as a tool for water resource planning, for understanding the interactions of groundwater and surface water at a basin scale, and for facilitating conjunctive management, but may lack the precision needed for water rights administration at a local scale. Additional sources of uncertainty or limitations of the model are noted. The quantity and spatial distribution of canal seepage and infiltration of irrigation water recharge, the largest sources of recharge to the system, are unknown and approximated indirectly. There is poor understanding of how canal seepage and incidental recharge change as land is converted from agricultural (irrigated) to suburban (semi-irrigated). These uncertainties will affect any scenarios that investigate changes to land use or irrigation practices. Finally, the model has relatively high water-level residuals around and to the southwest of Lake Lowell and should not be used to estimate water level effects in that region. The model was built with multiple, broadly expressed objectives and did not optimize performance for specific uses. However, the model and the tools included in an associated data release provide ample flexibility to improve the model for future uses. Adjustments and improvements could be made by refining the model in an area of interest, collecting additional calibration data, applying more rigorous boundary conditions, or re-estimating model parameters to optimize model performance for a specific model forecast.

Idaho↗

Technical Analysis of In-Valley Drainage Management Strategies for the Western San Joaquin Valley, California

The western San Joaquin Valley is one of the most productive farming areas in the United States, but salt-buildup in soils and shallow groundwater aquifers threatens this area?s productivity. Elevated selenium concentrations in soils and groundwater complicate drainage management and salt disposal. In this document, we evaluate constraints on drainage management and implications of various approaches to management considered in: *the San Luis Drainage Feature Re-Evaluation (SLDFRE) Environmental Impact Statement (EIS) (about 5,000 pages of documentation, including supporting technical reports and appendices); *recent conceptual plans put forward by the San Luis Unit (SLU) contractors (i.e., the SLU Plans) (about 6 pages of documentation); *approaches recommended by the San Joaquin Valley Drainage Program (SJVDP) (1990a); and *other U.S. Geological Survey (USGS) models and analysis relevant to the western San Joaquin Valley. The alternatives developed in the SLDFRE EIS and other recently proposed drainage plans (refer to appendix A for details) differ from the strategies proposed by the San Joaquin Valley Drainage Program (1990a). The Bureau of Reclamation (USBR) in March 2007 signed a record of decision for an in-valley disposal option that would retire 194,000 acres of land, build 1,900 acres of evaporation ponds, and develop a treatment system to remove salt and selenium from drainwater. The recently proposed SLU Plans emphasize pumping drainage to the surface, storing approximately 33% in agricultural water re-use areas, treating selenium through biotechnology, enhancing the evaporation of water to concentrate salt, and identifying ultimate storage facilities for the remaining approximately 67% of waste selenium and salt. The treatment sequence of reuse, reverse osmosis, selenium bio-treatment, and enhanced solar evaporation is unprecedented and untested at the scale needed to meet plan requirements. All drainage management strategies that have been proposed seek to reduce the amount of drainage water produced. One approach is to reduce the amount of drainage per irrigated acre. From modeling simulations performed for the SLDFRE EIS of the Westlands Area of the SLU, theoretical minimums that can be achieved range from approximately 0.16 to 0.25 acre-feet per acre per year (AF/acre/year). Minimum production rates from the Northerly Area of the SLU are theorized as being much higher, approximately 0. 42 to 0.28 AF/acre/year. Rates shown in the SLU Plans for drained acres from the two areas combined are 0.5 AF/acre/year at the subsurface drain stage and 0.37 AF/acre/year after a series of on-farm and regional measures are instituted. Land retirement is a key strategy to reduce drainage because it can effectively reduce drainage to zero if all drainage-impaired lands are retired. Land retirement alternatives considered in the SLDFRE EIS differ for the two areas analyzed in the SLU. The Northerly Area is to retire a nominal 10,000 acres and Westlands is to retire up to 300,000 acres. The initial land retirement option recently put forth in the SLU Plans predicted drainage volume reductions that are consistent with 200,000 acres of land retirement, but only 100,000 acres of land retirement was proposed. Within the proposed area of drainage there are, for all practical purposes, unlimited reservoirs of selenium and salt stored within the aquifers and soils of the valley and upslope in the Coast Ranges. Salt imported in irrigation water is estimated to be at least 1.5 million tons per year for the Westlands and Northerly Areas (SJVDIP, 1998). Analysis of the land retirement alternatives presented in the SLDFRE EIS indicates that land retirement of a minimum of only 100,000 acres results in the annual pumping to the surface of 20,142 pounds of selenium or about a million pounds of selenium over a 50 year period. Retiring 200,000 acres results in an annual pumping of 14,750 pounds of selenium; and reti

Open-File Report↗

Ground-water exploration in Al Marj area, Cyrenaica, United Kingdom of Libya

The present report, based largely on fieldwork during 1959-61, describes the results of reconnaissance hydrogeologic studies and exploratory drilling to evaluate the general water-bearing properties of the rocks and the availability of groundwater supplies for irrigation, stock, and village uses in Al Marj area. These studies and the drilling were conducted under the auspices of the U.S. Operations Mission of the International Cooperation Administration. Al Marj area, located in the Province of Cyrenaica on the southern coast of the Mediterranean Sea, contains a land area of about 6,770 square kilometers. Along the Mediterranean shore is a narrow coastal plain that rises evenly to the base of an escarpment that forms the seaward front of an undulating plateau known as. Al Jabal al Akhgiar. The climate is semiarid; seasonal rainfall occurs during the winter months. Owing to orographic effects, the rainfall is somewhat higher in the Jabal than in the coastal plain. The average annual rainfall ranges from about 250 millimeters in the coastal plain to 450 millimeters on the Jabal. All the streams (wadis) of the area are ephemeral and flow only in response to heavy rains of the winter season. From a drainage divide on the Jabal some streams flow north and northwest toward the sea and the others, south and southeast to the interior desert. Solution features, such as limestone sink holes, are common in the coastal plain and a large solution depression occurs near Al Marj. The rocks of A1 Marj area consist predominantly of limestone and some sandstone and shale; they range from Cretaceous to Miocene age. On the coastal plain Miocene limestone is locally mantled by Quaternary alluvial, beach and lagoonal deposits. The Miocene and older beds have a regional southerly dip. These rocks are broken by northeast-trending normal faults in the coastal and inland escarpments. The ground-water reservoir is contained chiefly in fractures, bedding planes, and solution openings in the limestone country rock. The upper limit of this reservoir is marked by a water table which generally lies within 40 meters of the land surface in the coastal plain but is 100 meters or more below the surface of most of the Jabal and the interior desert. The ground-water reservoir is replenished chiefly by infiltration from surface-water runoff in wadis and to less extent by direct infiltration of rainfall. Ground water moves north and northwest toward the Mediterranean Sea and south toward the interior desert from a ground-water divide near the crest of A1 Jabal al Akhgiar. Discharge of ground water takes place by submarine outflow, spring flow, evapotranspiration, and withdrawals from wells. Wells, springs, and cisterns furnish almost all water supplies for municipal, village, stock and irrigation purposes. Bengasi, A1 Marj, and A1 Abyar are the only centers of population with municipal distribution systems. Drafts from individual dug wells used for irrigation in the coastal plain generally are no more than 10 to 15 cubic meters per day. In the Jabal and the interior desert drafts from individual stock and village wells are generally less than 10 cubic meters per day and from most wells only a few thousand liters per day. Some 21 test wells were put down during the present investigation to depths ranging from 30 to 309 meters. The yields obtained by test pump and bailer ranged from 45 to 0.6 cubic meters per hour. With few exceptions, well yields sufficient for stock and village requirements were obtained. Well yields sufficient for irrigation even on a moderate scale, however, are not everywhere available. In the Jabal and the interior desert the ground water is generally of good to fair chemical quality and suitable for most purposes. In the coastal plain, however, the ground water is in places moderately to highly mineralized, and consequently for irrigation use it must be applied to the land under optimum crop soil, and drainage conditions.

Water Supply Paper↗

Summary of the Snake River plain Regional Aquifer-System Analysis in Idaho and eastern Oregon

Regional aquifers underlying the 15,600-square-mile Snake River Plain in southern Idaho and eastern Oregon was studied as part of the U.S. Geological Survey's Regional Aquifer-System Analysis program. The largest and most productive aquifers in the Snake River Plain are composed of Quaternary basalt of the Snake River Group, which underlies most of the 10,8000-square-mile eastern plain. Aquifer tests and simulation indicate that transmissivity of the upper 200 feet of the basalt aquifer in the eastern plain commonly ranges from about 100,000 to 1,000,000 feet squared per day. However, transmissivity of the total aquifer thickness may be as much as 10 million feet squared per day. Specific yield of the upper 200 feet of the aquifer ranges from about 0.01 to 0.20. Average horizontal hydraulic conductivity of the upper 200 feet of the basalt aquifer ranges from less than 100 to 9,000 feet per day. Values may be one to several orders of magnitude higher in parts in individual flows, such as flow tops. Vertical hydraulic conductivity is probably several orders of magnitude lower than horizontal hydraulic conductivity and is generally related to the number of joints. Pillow lava in ancestral Snake River channels has the highest hydraulic conductivity of all rock types. Hydraulic conductivity of the basalt decreases with depth because of secondary filling of voids with calcite and silica. An estimated 80 to 120 million acre-feet of water is believed to be stored in the upper 200 feet of the basalt aquifer in the eastern plain. The most productive aquifers in the 4,800-square-mile western plain are alluvial sand and gravel in the Boise River valley. Although aquifer tests indicate that transmissivity of alluvium in the Boise River valley ranges from 5,000 to 160,000 feet squared per day, simulation suggests that average transmissivity of the upper 500 feet is generally less than 20,000 feet squared per day. Vertically averaged horizontal hydraulic conductivity of the upper 500 feet of alluvium ranges from about 4 to 40 feet per day; higher values can be expected in individual sand and gravel zones. Vertical hydraulic conductivity is considerably lower because of the presence of clay layers. Hydraulic heads measured in piezometers, interpreted from diagrams showing ground-water flow and equipotential lines and estimated by computer simulation, demonstrate that water movement is three dimensional through the rock framework. Natural recharge takes place along the margins of the plain where head decreases with depth; discharge takes place near some reaches of the Snake River and the Boise River where head increases with depth. Geothermal water in rhyolitic rocks in the western plain and western part of the eastern plain has higher hydraulic head than the overlying cold water. Geothermal water, therefore, moves upward and merges into the cold-water system. Basin water-budget analyses indicate that the volume of cold water. Carbon-14 age determinations, which indicate that residence time of geothermal water is 17,700 to 20,300 years, plus or minus 4,000 years, imply slow movement of water through the geothermal system. Along much of its length, the Snake River gains large quantities of ground water. On the eastern plain, the river gained about 1.9 million acre-feet of water between Blackfoot and Neeley, Idaho, in 1980. Between Milner and King Hill, Idaho, the river gained 4.7 million acre-feet, mostly as spring flow from the north side. Upstream from Blackfoot and in the vicinity of Lake Walcott, the rover loses flow to ground water during parts or all of the year. On the western plain, river gains from ground water are small relative to those on the eastern plain; most are from seepage. Streams in tributary drainage basins supply calcium/bicarbonate type and calcium/magnesium/bicarbonate type water to the plain. Water type is a reflection of the chemical composition of rocks in the drainage basin, Concentrations of dissolved solids are smallest, about 50 milligrams per liter, in streams such as the Boise River that drain areas of granitic rocks; concentrations are greatest, about 400 milligrams per liter, in streams such as the Owyhee and Raft Rivers that drain area of sedimentary rocks. Water chemistry reflects the interaction of surface water and ground water. The chemical composition of ground water in the plain is essentially the same as that in streamflow and groundwater discharge from tributary drainage basins. Tributary drainage basins supplied 85 percent of the ground-water recharge in the eastern plain during 1980 and a nearly equivalent percentage of the solute load in ground water; human activities and dissolution of minerals supplied the other solutes. Dissolved-solids concentrations in ground water were generally less than 400 milligrams per liter. Water from the lower geothermal system is chemically different from water from the upper cold-water system. Geothermal water typically has greater concentrations of sodium, bicarbonate, sulfate, chloride, fluoride, silica, arsenic, boron, and lithium and smaller concentrations of calcium, magnesium, and hydrogen. Difference are attributed to ion exchange as geothermal moves through the rock framework. Irrigation, mostly on the Snake River Plain, accounted for about 96 percent of consumptive water use in Idaho during 1980. The use of surface water for irrigation for more than 100 years has caused major changes in the hydrologic system on the plain. Construction of dams, reservoirs, and diversifications effected planned changes in the surface-water system but resulted in largely unplanned changes in the ground-water system. During those years of irrigation, annual recharge in the main part of the eastern plain increased to about 6.7 million acre-feet in 1980, or by about 70 percent. Most of the increase was from percolation of surface water diverted for irrigation. From preirrigation to 1952, groundwater storage increased about 24 million acre-feet, and storage decreased from 1952 to 1964 and from 1976 to 1980 because of below-normal precipitation and increased withdrawals of ground water for irrigation. Annual ground-water discharge increased to about 7.1 million acre-feet in 1980, or about 80 percent since the start of irrigation. About 10 percent of the 1980 total discharge was ground-water pumpage. About 3.1 million acres, or almost one-third of the plain, was irrigated during 1980: 2.0 million acres with surface water, 1.0 million acres with ground water, and 0.1 million acres with combined surface and ground water. About 8.9 million acre-feet of Snake River water was diverted for irrigation during 1980 and 2.3 million acre-feet of ground water was pumped from 5,300 wells. Most irrigation wells on the eastern plain are open to basalt. About two-thirds of them yield more than 1,500 gallons per minute with a reported maximum of 7,240 gallons per minute; drawdown is less than 20 feet in two-thirds of the wells. Most irrigation wells on the western plain are open to sedimentary rocks. About one-third of them yield more than 1,00 gallons per minute with a reported maximum of 3,850 gallons per minute; drawndown is less than 20 feet in about one-fifth of the wells. The major instream use of water on the Snake River Plain is hydroelectric power generation. Fifty-two million acre-feet of water generated 2.6 million megawatthours of electricity during 1980. Digital computer ground-water flows models of the eastern and western plain reasonably simulated regional changes in water levels and ground-water discharges from 1880 (preirrigation) to 1980. Model results support the concept of three-dimensional flow and the hypotheses of no underflow between the eastern and western plain. Simulation of the regional aquifer system in the eastern plain indicates that is 1980 hydrologic conditions, including pumpage, were to remain the same for another 30 years, moderate declines in ground-water levels and decreases in spring discharges would continue. Increased ground-water pumpage to irrigate an additional 1 million acres could cause ground-water levels to decline a few tens of feet in the central part of the plain and could cause corresponding decreases in ground-water discharge. A combination of actions such as increased ground-water pumpage and decreased use of surface water for irrigation (resulting in reduced recharge) would accentuate the changes.

Idaho;Oregon↗

Selenium hazards in the Salton Sea environment—Summary of current knowledge to inform future wetland management

Quaternary marine and continental shales in the western United States are sources of selenium that can be loaded into the aquatic environment through mining, agricultural, and energy production processes. The mobilization of selenium from shales through agricultural irrigation has been recognized since the 1930s; however, discovery of deformities in birds and other wildlife using agricultural habitats during the 1980s spurred studies to determine the extent and effects of the contamination. Through these early studies, researchers determined that biota in the Salton Sea drainage basin was at risk from legacy selenium contamination in the Colorado River watershed. The Salton Sea and its surrounding managed and unmanaged wetlands provide vital inland habitat and trophic support for diverse assemblages of resident and migratory wildlife, and understanding regional selenium hazards for these trust species is a priority for many Federal and State agencies. The modern Salton Sea is a shallow, landlocked saline lake in Riverside and Imperial Counties (not shown) of California that is sustained by irrigation return and perennial river inflow. Changes in water transfer agreements under the 2003 Quantification Settlement Agreement (QSA) have resulted in reduced irrigation flow, declining lake levels, and the evolution of unmanaged wetlands in areas where drains and rivers no longer reach the Salton Sea. These wetlands provide additional habitat for some species of concern, but their potential to increase selenium hazards for trust species is largely unknown. From the 1980s to 2020, efforts to document selenium contamination and effects throughout the region have resulted in a considerable amount of selenium data from the Salton Sea and its surrounding drainage basin; however, no long-term (greater than 20 years), consistent sampling program has been established, and all data have been collected by different entities using a variety of protocols and analytical techniques. This lack of coordination has been previously documented in regional management plans and has led to difficulty in reliably assessing selenium hazards in the Salton Sea environment. This report provides a summary of the available disparate selenium information collected from water, sediment, and biota in the Salton Sea region since the 1980s and to identify data gaps that need to be filled to understand the potential effects of selenium on species of concern, including federally endangered desert pupfish ( Cyprinodon macularius ) and Yuma Ridgway’s Rail ( Rallus obsoletus yumanensis; formerly Yuma Clapper Rail, Rallus longirostris yumanensis ). Available data from the Salton Sea drainage basin show that water from the Colorado River has the lowest selenium concentration of all surface water sources. All other surface water flowing into the Salton Sea has elevated selenium concentrations due to evaporation and evapotranspiration that occurs in agricultural fields and associated water delivery infrastructure or leaching of selenium from irrigated farmland soils. The Salton Sea has lower selenium concentrations because of various biogeochemical processes that recycle selenium into the sediment or volatilize it to the atmosphere; however, these mechanisms are not well defined, and it is not clear if selenium cycling will change in response to possible changes in the oxidation state of the Salton Sea bottom waters as water levels decline. Agricultural drains have the highest average selenium concentrations, but few drains have been sampled since changes in irrigation practices have occurred (due to the 2003 QSA). Groundwater selenium concentrations are variable; some wells south of the Salton Sea have selenium concentrations as high as 300 micrograms per liter (µg/L), whereas selenium concentrations are below detection in other wells. Groundwater and surface-water geothermal discharge zones around the margins of the Salton Sea and in unmanaged wetlands have not been studied in detail, and published selenium measurements are not available for these surface features. Selenium concentrations in the sediment of the Salton Sea drainage basin are highest in wetland particulate organic matter and the Salton Sea lakebed, indicating that removal of selenium from the water to the sediment has been a primary mechanism for keeping selenium concentrations low in the water column. Sediment selenium concentrations in wetlands are lower than in the Salton Sea but higher than inflowing drains and rivers, indicating the lentic wetland sites also may be important sinks for selenium because of biogeochemical processes. Sediment selenium data have not been collected in agricultural drains since changes in irrigation practices occurred (due to the 2003 QSA), and it is unknown if selenium sequestration from the water column has changed in these systems. We divided biological data into broad taxonomic categories, including primary producers, invertebrates, herpetofauna, mammals, fishes, and birds to facilitate evaluation of selenium concentrations and spatiotemporal trends observed in the Salton Sea. Overall, selenium concentrations were substantially greater in algae samples compared to all vascular plant samples combined. Median selenium concentrations in several invertebrate taxa (Chironomidae, Formicidae, Corixidae, Corbiculidae and Nereididae, and Decapoda) exceeded the maximum suggested dietary threshold of 3.0–4.0 micrograms per gram (µg/g) dry weight (dw) for predators consuming invertebrates in aquatic food webs. The greatest number of samples were collected from fish, and selenium distributions among species and locations showed that the range for most samples was lower than the U.S. Environmental Protection Agency selenium criterion for aquatic life (8.5 µg/g dw whole body, 11.3 µg/g dw fillets). The median selenium concentrations for whole body fish were below the selenium criterion in most locations, except for bairdiella ( Bairdiella icistia ) from the Salton Sea and irrigation drains, a few individual tilapia spp. (family Cichlidae, including genera Tilapia, Oreochromis , and their hybrids) from the river and river outlets, and several western mosquitofish ( Gambusia affinis ) and sailfin molly ( Poecilia latipinna ) from irrigation drain outlets. For avian samples combined among years and locations, median selenium concentrations in livers from all families except waders and Ibis (family Threskiornithidae) were higher than levels expected to cause selenium toxicosis (10–20 µg/g dw), and all median egg concentrations were above or near 6.0 μg/g dw, which is a conservative threshold value for reproductive impairment. Most knowledge gaps we identified for water, sediment, and biota were interrelated, and the use of integrated approaches to address knowledge gaps can provide greater insight into the drivers behind selenium hazards. Integrated water, sediment, and biota studies could help identify cost-effective management solutions that serve multiple purposes. A comprehensive analysis of the hydrology, biogeochemistry, and food-web processes in wetlands and other habitats can inform predictive models to identify drivers of selenium bioavailability, uptake from the environment and subsequent trophic transfer, ultimately forming the basis for experimental habitat management manipulations to minimize selenium hazards to wildlife. Furthermore, a comprehensive, long-term sampling and analytical laboratory plan would enable comparison of data among different entities that are sampling at the Salton Sea. Such efforts are well suited to help fill knowledge gaps that preclude understanding of selenium hazards and future management options for biota using Salton Sea habitats, including newly formed wetlands throughout the region. All data compiled for this report are available in two U.S. Geological Survey data releases: Groover and others (2022) for water and sediment samples and De La Cruz and others (2022) for biological samples. The data releases include all publicly available data for selenium concentrations in water, sediment, and biological samples collected in and around the Salton Sea, including the Coachella and Imperial Valleys. The data releases also include previously unpublished data.

California↗

Evaluation of long-term water-level declines in basalt aquifers near Mosier, Oregon

The Mosier area lies along the Columbia River in northwestern Wasco County between the cities of Hood River and The Dalles, Oregon. Major water uses in the area are irrigation, municipal supply for the city of Mosier, and domestic supply for rural residents. The primary source of water is groundwater from the Columbia River Basalt Group (CRBG) aquifers that underlie the area. Concerns regarding this supply of water arose in the mid-1970s, when groundwater levels in the orchard tract area began to steadily decline. In the 1980s, the Oregon Water Resources Department (OWRD) conducted a study of the aquifer system, which resulted in delineation of an administrative area where parts of the Pomona and Priest Rapids aquifers were withdrawn from further appropriations for any use other than domestic supply. Despite this action, water levels continued to drop at approximately the same, nearly constant annual rate of about 4 feet per year, resulting in a current total decline of between 150 and 200 feet in many wells with continued downward trends. In 2005, the Mosier Watershed Council and the Wasco Soil and Water Conservation District began a cooperative investigation of the groundwater system with the U.S. Geological Survey. The objectives of the study were to advance the scientific understanding of the hydrology of the basin, to assess the sustainability of the water supply, to evaluate the causes of persistent groundwater-level declines, and to evaluate potential management strategies. An additional U.S. Geological Survey objective was to advance the understanding of CRBG aquifers, which are the primary source of water across a large part of Oregon, Washington, and Idaho. In many areas, significant groundwater level declines have resulted as these aquifers were heavily developed for agricultural, municipal, and domestic water supplies. Three major factors were identified as possible contributors to the water-level declines in the study area: (1) pumping at rates that are not sustainable, (2) well construction practices that have resulted in leakage from aquifers into springs and streams, and (3) reduction in aquifer recharge resulting from long-term climate variations. Historical well construction practices, specifically open, unlined, uncased boreholes that result in cross-connecting (or commingling) multiple aquifers, allow water to flow between these aquifers. Water flowing along the path of least resistance, through commingled boreholes, allows the drainage of aquifers that previously stored water more efficiently. The study area is in the eastern foothills of the Cascade Range in north central Oregon in a transitional zone between the High Cascades to the west and the Columbia Plateau to the east. The 78-square mile (mi 2 ) area is defined by the drainages of three streams - Mosier Creek (51.8 mi 2 ), Rock Creek (13.9 mi 2 ), and Rowena Creek (6.9 mi 2 ) - plus a small area that drains directly to the Columbia River.The three major components of the study are: (1) a 2-year intensive data collection period to augment previous streamflow and groundwater-level measurements, (2) precipitation-runoff modeling of the watersheds to determine the amount of recharge to the aquifer system, and (3) groundwater-flow modeling and analysis to evaluate the cause of groundwater-level declines and to evaluate possible water resource management strategies. Data collection included the following: 1. Water-level measurements were made in 37 wells. Bi-monthly or quarterly measurements were made in 30 wells, and continuous water-level monitoring instruments were installed in 7 wells. The measurements principally were made to capture the seasonal patterns in the groundwater system, and to augment the available long-term record. 2. Groundwater pumping was measured, reported, or estimated from irrigation, municipal and domestic wells. Flowmeters were installed on 74 percent of all high-capacity irrigation wells in the study area. 3. Borehole geophysical data were collected from a known commingling well. These data measured geologic properties and vertical flow through the well. 4. Streamflow measurements were made in Rock, Rowena, and Mosier Creeks. A long-term recording stream-gaging station was reestablished on Mosier Creek to provide a continuous record of streamflow. Streamflow measurements also were made along the creeks periodically to evaluate seasonal patterns of exchange between streams and the groundwater system. Major findings from the study include: 1. Annual average precipitation ranges from 20 to 54 inches across the study area with an average value of about 30 inches. Based on rainfall-runoff modeling, about one-third of this water infiltrates into the aquifer system. 2. Currently, about 3 percent of the water infiltrated into the groundwater system is extracted for municipal, agricultural, and rural residential use. The remainder of the water flows through the aquifer system, discharging into local streams and the Columbia River. About 80 percent of recent pumping supports crop production. The city of Mosier public supply wells account for about 10 percent of total pumping, with the remaining 10 percent being pumped from the private wells of rural residents. 3. Groundwater-flow simulation results indicate that leakage through commingling wells is a significant and likely the dominant cause of water level declines. Leakage patterns can be complex, but most of the leaked water likely flows out the CRBG aquifer system through very permeable sediments into Mosier Creek and its tributary streams in the OWRD administrative area. Model-derived estimates attribute 80-90 percent of the declines to commingling, with pumping accounting for the remaining 10-20 percent. Although decadal trends in precipitation have occurred, associated changes in aquifer recharge are likely not a significant contributor to the current water level declines. 4. As many as 150 wells might be commingling. To evaluate whether or not the local combination of geology and well construction have resulted in aquifer commingling at a particular well, the well needs to be tested by measuring intraborehole flow. During geophysical testing of one known commingling well, the flow rate through the well between aquifers ranged between 70 and 135 gallons per minute (11-22 percent of total annual pumping in the study area). Historically, when aquifer water levels were 150-200 feet higher, this flow rate would have been correspondingly higher. 5. Because aquifer commingling through well boreholes is likely the dominant cause of aquifer declines, flow simulations were conducted to evaluate the benefit of repairing wells in specified locations and the benefit of recharging aquifers using diverted flow from study area creeks. As part of this analysis, maps were generated that show which areas are more vulnerable to commingling. These maps indicate that the value of repairing wells in the area generally coincident with the OWRD administrative area is higher than in areas farther upstream in the watershed. Simulation results also indicate that artificial recharge of the aquifers using diverted creek water will not significantly improve water levels in the aquifer system unless at least some commingling wells are repaired first. Repairs would entail construction of wells in a manner that prevents commingling of multiple aquifers. The value of artificially recharging the aquifers improves as more wells are repaired because the aquifer system more efficiently stores water.

Oregon↗

Ground-water hydrology of the Willamette basin, Oregon

The Willamette Basin encompasses a drainage of 12,000 square miles and is home to approximately 70 percent of Oregon's population. Agriculture and population are concentrated in the lowland, a broad, relatively flat area between the Coast and Cascade Ranges. Annual rainfall is high, with about 80 percent of precipitation falling from October through March and less than 5 percent falling in July and August, the peak growing season. Population growth and an increase in cultivation of crops needing irrigation have produced a growing seasonal demand for water. Because many streams are administratively closed to new appropriations in summer, ground water is the most likely source for meeting future water demand. This report describes the current understanding of the regional ground-water flow system, and addresses the effects of ground-water development. This study defines seven regional hydrogeologic units in the Willamette Basin. The highly permeable High Cascade unit consists of young volcanic material found at the surface along the crest of the Cascade Range. Four sedimentary hydrogeologic units fill the lowland between the Cascade and Coast Ranges. Young, highly permeable coarse-grained sediments of the upper sedimentary unit have a limited extent in the floodplains of the major streams and in part of the Portland Basin. Extending over much of the lowland where the upper sedimentary unit does not occur, silts and clays of the Willamette silt unit act as a confining unit. The middle sedimentary unit, consisting of permeable coarse-grained material, occurs beneath the Willamette silt and upper sedimentary units and at the surface as terraces in the lowland. Beneath these units is the lower sedimentary unit, which consists of predominantly fine-grained sediments. In the northern part of the basin, lavas of the Columbia River basalt unit occur at the surface in uplands and beneath the basin-fill sedimentary units. The Columbia River basalt unit contains multiple productive water-bearing zones. A basement confining unit of older marine and volcanic rocks of low permeability underlies the basin and occurs at land surface in the Coast Range and western part of the Cascade Range. Most recharge in the basin is from infiltration of precipitation, and the spatial distribution of recharge mimics the distribution of precipitation, which increases with elevation. Basinwide annual mean recharge is estimated to be 22 inches. Rain and snowmelt easily recharge into the permeable High Cascade unit and discharge within the High Cascade area. Most recharge in the Coast Range and western part of the Cascade Range follows short flowpaths through the upper part of the low permeability material and discharges to streams within the mountains. Consequently, recharge in the Coast and Ranges is not available as lateral ground-water flow into the lowland, where most ground-water use occurs. Within the lowland, annual mean recharge is 16 inches and most recharge occurs from November to April, when rainfall is large and evapotranspiration is small. From May to October recharge is negligible because precipitation is small and evapotranspiration is large. Discharge of ground water is mainly to streams. Ground-water discharge is a relatively large component of flow in streams that drain the High Cascade unit and parts of the Portland Basin where permeable units are at the surface. In streams that do not head in the High Cascade area, streamflow is generally dominated by runoff of precipitation. Ground-water in the permeable units in the lowland discharges to the major streams where there is a good hydraulic connection between aquifers and streams. Ground-water discharge to smaller streams, which flow on the less permeable Willamette silt unit, is small and mostly from the Willamette silt unit. Most ground-water withdrawals occur within the lowland. Irrigation is the largest use of ground water, accounting for 240,000 acre feet of withdrawals, or 81 p

Scientific Investigations Report↗

Estimation of a water budget for 1972-2000 for the Grasslands Area, central part of the Western San Joaquin Valley, California

Equitable implementation of regulations restricting discharges from agricultural drains into the San Joaquin River requires a greater understanding of the influence of extreme precipitation events on the ground-water flow system. As part of a larger investigation, this study estimated ground-water recharge and ground-water pumpage, two important components of the water budget in the Grasslands drainage area in the central part of the western San Joaquin Valley, California, for the water years 1972 through 2000. These estimates will be used as inputs to a numerical simulation model of the regional ground-water flow system in the continuing investigation. Crop-acreage and surface-water delivery data were compiled for 14 water districts and 6 other areas comprising approximately 97 percent of the 600-square-mile study area. Little ground-water pumpage data exists for the study area. A climate-based approach was employed to estimate annual water-table recharge flux and ground-water pumpage for 11 water-budget areas. Ground-water pumpage was estimated from the residual irrigation demand after crop consumption of surface water. Estimated recharge flux to the water table for the entire study area averaged 0.8 ft/yr, and estimated ground-water pumpage per unit area for the entire study area averaged 0.5 ft/yr. Increased discharges from agricultural drains in the late 1990s may have been due partly to 4 years of high recharge from precipitation over the 6-year period from 1993 to 1998. Knowledge of the ratio of annual crop water demand to annual potential evapotranspiration, expressed as an aggregate crop coefficient, Kd, will facilitate estimation of annual water-budget components in future studies. Annual aggregate crop coefficients, calculated each year for the entire study area, were nearly constant at 0.59 from 1983 to 2000, and reasonably constant at 0.53 prior to 1983. The overall trend suggests continuous reductions in recharge from irrigation over time. This reduction is most likely due to gradual improvements in irrigation management. The recharge and pumpage estimates are both sensitive to the consumption-distribution ratio, and the pumpage estimate is sensitive to the cropped acreage.

Scientific Investigations Report↗

Water resources of the White Earth Indian Reservation, northwestern Minnesota

Water resources in the White Earth Indian Reservation meet the present (1988) needs for potable supply and other household uses and provide valuable ecological, recreational, and aesthetic benefits. Total annual water use in the Reservation is about 460 million gallons per year. Domestic supply from privately owned wells and municipal systems accounts for roughly three-fourths of the water use, and irrigation of croplands and nurseries accounts for approximately one-fourth, depending on rainfall. Glacial-drift aquifers are the source of ground water in the Reservation. Unconfined-drift aquifers consist of two surficial outwash deposits that extend over approximately one-fifth of the Reservation. One deposit trends along a north-south strip through the central part of the Reservation, and the other occupies the southeastern corner. Confined-drift aquifers are the most significant source of ground-water supply. These aquifers are discontinuous lenses of sand and gravel that hydraulically are poorly connected to each other. The aquifers are 50 to 300 feet below land surface and 5 to 25 feet thick. Yields from these aquifers typically range from 10 to 100 gallons per minute. Surface water in the Reservation consist of numerous lakes, wetlands, prairie potholes, and streams. The larger, deeper lakes in the eastern and southern parts of the Reservation support walleye and northern pike and provide recreational opportunities for swimming and boating. The shallower lakes and prairie potholes are used to produce wild rice and also are managed to provide waterfowl habitat. Most of the streams in the Reservation drain the headwater areas of basins that are part of the Red River of the North watershed; however, several small streams in the southeastern part drain to the Crow Wing River, which is part of the Mississippi River drainage system. The Wild Rice River drains the largest basin in the Reservation. Ground water is mostly a calcium magnesium bicarbonate type. Dissolvedsolids concentration of the ground water generally is greater in the deeper confined-drift aquifers than in the shallower unconfined-drift aquifers. The concentrations of sodium and sulfate in water from the confined-drift aquifers are higher in the northwestern part of the Reservation than in the rest of the aquifer. Except for elevated concentrations of iron and manganese, the quality of the ground water meets the criteria established by the U.S. Environmental Protection Agency (USEPA) for drinking water. Surface water also is a calcium magnesium bicarbonate type. Lake waters are hard and alkaline and are mesotrophic to eutrophic in productivity. Quality of the lake and stream water is suitable for native forms of freshwater biota, although the concentration of total recoverable mercury exceeds the 0.012 micrograms per liter maximum contaminant level; that level, established by USEPA for the organic form of dissolved mercury, is intended to protect against chronic effects on freshwater life. Available information, however, indicates that the amount of mercury in edible tissue from fish in alkaline lakes of northwestern Minnesota is within safe limits. The concentrations of phosphorus and nitrate in the streams are below levels that indicate pollution problems.

Minnesota↗

Simulation of groundwater flow and the interaction of groundwater and surface water in the Willamette Basin and Central Willamette subbasin, Oregon

Full appropriation of tributary streamflow during summer, a growing population, and agricultural needs are increasing the demand for groundwater in the Willamette Basin. Greater groundwater use could diminish streamflow and create seasonal and long-term declines in groundwater levels. The U.S. Geological Survey (USGS) and the Oregon Water Resources Department (OWRD) cooperated in a study to develop a conceptual and quantitative understanding of the groundwater-flow system of the Willamette Basin with an emphasis on the Central Willamette subbasin. This final report from the cooperative study describes numerical models of the regional and local groundwater-flow systems and evaluates the effects of pumping on groundwater and surface‑water resources. The models described in this report can be used to evaluate spatial and temporal effects of pumping on groundwater, base flow, and stream capture. The regional model covers about 6,700 square miles of the 12,000-square mile Willamette and Sandy River drainage basins in northwestern Oregon—referred to as the Willamette Basin in this report. The Willamette Basin is a topographic and structural trough that lies between the Coast Range and the Cascade Range and is divided into five sedimentary subbasins underlain and separated by basalts of the Columbia River Basalt Group (Columbia River basalt) that crop out as local uplands. From north to south, these five subbasins are the Portland subbasin, the Tualatin subbasin, the Central Willamette subbasin, the Stayton subbasin, and the Southern Willamette subbasin. Recharge in the Willamette Basin is primarily from precipitation in the uplands of the Cascade Range, Coast Range, and western Cascades areas. Groundwater moves downward and laterally through sedimentary or basalt units until it discharges locally to wells, evapotranspiration, or streams. Mean annual groundwater withdrawal for water years 1995 and 1996 was about 400 cubic feet per second; irrigation withdrawals accounted for about 80 percent of that total. The upper 180 feet of productive aquifers in the Central Willamette and Southern Willamette subbasins produced about 70 percent of the total pumped volume. In this study, the USGS constructed a three-dimensional numerical finite-difference groundwater-flow model of the Willamette Basin representing the six hydrogeologic units, defined in previous investigations, as six model layers. From youngest to oldest, and [generally] uppermost to lowermost they are the: upper sedimentary unit, Willamette silt unit, middle sedimentary unit, lower sedimentary unit, Columbia River basalt unit, and basement confining unit. The high Cascade unit is not included in the groundwater-flow model because it is not present within the model boundaries. Geographic boundaries are simulated as no-flow (no water flowing in or out of the model), except where the Columbia River is simulated as a constant hydraulic head boundary. Streams are designated as head-dependent-flux boundaries, in which the flux depends on the elevation of the stream surface. Groundwater recharge from precipitation was estimated using the Precipitation-Runoff Modeling System (PRMS), a watershed model that accounts for evapotranspiration from the unsaturated zone. Evapotranspiration from the saturated zone was not considered an important component of groundwater discharge. Well pumping was simulated as specified flux and included public supply, irrigation, and industrial pumping. Hydraulic conductivity values were estimated from previous studies through aquifer slug and permeameter tests, specific capacity data, core analysis, and modeling. Upper, middle and lower sedimentary unit horizontal hydraulic conductivity values were differentiated between the Portland subbasin and the Tualatin, Central Willamette, and Southern Willamette subbasins based on preliminary model results.

Oregon↗

Detailed study of water quality, bottom sediment, and biota associated with irrigation drainage in the Klamath Basin, California and Oregon, 1990-92

The effect of irrigation drainage on the water quality and wildlife of the Klamath Basin in California and Oregon was evaluated during 1990-92 as part of the National Irrigation Water Quality Program of the U.S. Department of the Interior. The study focused on land serviced by the Bureau of Reclamation Klamath Project, which supplies irrigation water to agricultural land in the Klamath Basin and the Lost River Basin. The Tule Lake and Lower Klamath National Wildlife Refuges, managed by the U.S. Fish and Wildlife Service, are in the study area. These refuges provide critical resting and breeding habitat for waterfowl on the Pacific flyway and are dependent on irrigation drainwater from upstream agriculture for most of their water supply. Water-quality characteristics throughout the study area were typical of highly eutrophic systems during the summer months of 1991 and 1992. Dissolved-oxygen concentrations and pH tended to fluctuate each day in response to diurnal patterns of photosynthesis, and frequently exceeded criteria for protection of aquatic organisms. Nitrogen and phosphorus concentrations were generally at or above threshold levels characteristic of eutrophic lakes and streams. At most sites the bulk of dissolved nitrogen was organically bound. Elevated ammonia concentrations were common in the study area, especially downstream of drain inputs. High pH of water increased the toxicity of ammonia, and concentrations exceeded criteria at sites upstream and downstream of irrigated land. Concentrations of ammonia in samples from small drains on the Tule Lake refuge leaseland were higher than those measured in the larger, integrating drains at primary monitoring sites. The mean ammonia concentration in leaseland drains [1.21 milligrams per liter (mg/L)] was significantly higher than the mean concentration in canals delivering water to the leaseland fields (0.065 mg/L) and higher than concentrations reported to be lethal to Daphnia magna (median lethal concentration of 0.66 mg/L). Dissolved-oxygen concentrations also were lower, and Daphnia survivability measured during in situ bioassays was correspondingly lower in the leaseland drains than in water delivery canals. In static laboratory bioassays, water samples collected at the primary monitoring sites caused toxicity in up to 78 percent of Lemna minor tests, in up to 49 percent of Xenopus laevis tests, in 17 percent and 8 percent of Hyalella azteca and Pimephales promelas tests, respectively, and 0 percent in Daphnia magna tests. In situ exposure at the sites caused mortality in more than 83 percent of Pimephales tests and in more than 41 percent of Daphnia and Hyalella tests. Much of the observed toxicity appears to have been caused by low dissolved oxygen, high pH, and ammonia. Although water in the study area was toxic to a variety of organisms, no statistically significant differences in the degree of toxicity between sites were observed above or below irrigated agricultural land in any of the bioassays. Pesticides were frequently detected in water samples collected at the monitoring sites during the 1991 and 1992 irrigation seasons. Among the most frequently detected compounds were the herbicides simazine, metribuzin, EPTC, and metolachlor and the insecticide terbufos. All the insecticides detected were at concentrations substantially below acute toxicity values reported for aquatic organisms. The herbicide acrolein has been used extensively in the basin to manage aquatic plant growth in irrigation canals and drains. The concentration of acrolein was monitored in a canal near Tule Lake after an application in order to evaluate the potential for the pesticide to be transported to refuge waters. Although acrolein concentrations were toxic to fish in the channels adjacent to Tule Lake, very little of the canal water entered the refuge during the monitoring period. Organochlorine pesticide concentrations in 25 surficial sediment samples collected in 1990 were below baseline levels commonly found in soils and sediment. Seventeen sediment samples were analyzed for chlorophenoxy acid herbicides and two samples were analyzed for organophosphorus and carbamate insecticides in 1992. No pesticides were detected in any of these samples. Residues of the trace elements selenium, mercury, and arsenic in algae, invertebrates, fish, and avian eggs revealed no bioaccumulation problems. Concentrations of organochlorine compounds, especially of p,p' DDE, were associated with a mean 11-percent eggshell thinning in white-faced ibis. However, ibis populations appear to be increasing, and some eggs of ibis were relatively low in DDE concentration. DDE concentrations in eggs of western grebes were not as high as in the eggs of ibis. Concentrations and types of organochlorine compounds detected in grebe and ibis eggs were highly variable, indicating that the birds were exposed to these compounds outside the basin. Fish and invertebrates inhabiting drainwater were representative of pollution-tolerant species assemblages. The aquatic communities retained little of their historic ecological structure. Extensive hydrologic modifications and hypereutrophic conditions in Klamath Basin waterways have degraded the quality of aquatic habitat and altered aquatic communities.

California, Oregon↗

Selenium source identification and biogeochemical processes controlling selenium in surface water and biota, Kendrick Reclamation Project, Wyoming, U.S.A.

The major tributaries draining the Kendrick Reclamation Project (KRP) account for an average of 52% of the total Se load measured in the North Platte River downstream from Casper, Wyoming. The Casper Creek drainage basin contributed the largest Se load of the five tributary sites to the North Platte River. The 4-d average Se concentration in water samples from one site in the part of the North Platte River that receives irrigation return flows exceeded the 5 μg/l U.S. Environmental Protection Agency's aquatic life criterion five time during a 50-d monitoring period in 1989. In agreement with the water-quality data, muscle and liver tissue rom rainbow trout collected from the same part of the North Platte River had Se concentrations exceeding levels known to cause reproductive failure and chronic Se poisoning. On the basis of Se: Cl, 18 O/ 16 O and D/H ratios in water from Goose and Rasmus Lee Lakes (closed-basin systems), the large Se concentrations in those lakes were derived by natural evaporation of irrigation water without leaching of soluble forms of Se from soil or rocks. Water samples from Thirtythree Mile Reservoir and Illco Pond (flow-through systems) showed considerable enrichment in Se over evaporative concentration, presumably due to leaching and desorption of Se from soil and rock. The Se: Cl ratios of irrigation drain water collected from the KRP indicate that leaching and desorption of soluble forms of Se from soils and rocks are the dominant processes in drain water. Results of a Wilcoxon matched-pairs test for 43 paired drain-water samples collected during June and August 1988, indicated there is a statistically larger concentration of Se (0.01 significance level) during the June sampling period. The larger concentrations of Se and other chemical constitutents during the early part of the irrigation season probably were due to dissolution of seleniferous salts that have accumulated in soils within the KRP since the last irrigation season. The large Se concentrations in water samples from wetland sites in the KRP were reflected in the aquatic-bird food chain. Most waterfowl and shorebirds nesting at the KRP showed Se concentrations in livers and eggs greater than levels suspected of causing adverse reproductive effects.

Wyoming↗

A preliminary evaluation of the geohydrology and water quality of the Greenacres Landfill area, Spokane County, Washington

The Greenacres Landfill, located about 11 mi east of the city of Spokane, Washington, was used for the disposal of waste from 1951 to 1972. Materials in the landfill include household and industrial waste materials, and various hazardous wastes. In 1983 the landfill was designated by the U.S. EPA as a ' Superfund ' site. The purposes of this investigation were to gather, describe, and interpret all the existing data concerning the hydrology and groundwater quality of the area surrounding the landfill, and to identify any additional data needed to describe the hydrology of the area. The quantity of water flow through the landfill as a result of precipitation on the landfill and in the drainage basin above the landfill probably ranges from 21,000 to 85,000 gal/day. This water movement may be creating a leachate and transporting some of the wastes out of the landfill. The plume would encompass an area where groundwater provides most of the water used for municipal, industrial, irrigation, and domestic purposes. Water quality analyses of water from numerous wells in the area which are open to the Spokane aquifer are available, but well 25/45-16K1 is the only well where groundwater contamination was consistently apparent. This well is only 500 ft from the landfill. Contamination of water in this well was indicated by high concentrations of dissolved mineral constituents and several organic compounds, including trans-dichloroethene (115 to 392 micrograms/L). Available data are insufficient to completely interpret the groundwater flow system near this well and the source of the contamination cannot be determined conclusively. While the existing data are adequate to provide background information, more data are needed to: (1) determine the source of contamination in well 25/45-16K1; (2) determine groundwater flow in the Spokane aquifer near well 25/45-16K1; and (3) determine the extent of contamination in the Spokane aquifer. The degree of the influence of the landfill on the Spokane aquifer cannot be determined with existing data. (Author 's abstract)

Open-File Report↗

Groundwater-flow model for the Wood River Valley aquifer system, south-central Idaho

A three-dimensional numerical model of groundwater flow was developed for the Wood River Valley (WRV) aquifer system, Idaho, to evaluate groundwater and surface-water availability at the regional scale. This mountain valley is located in Blaine County and has a drainage area of about 2,300 square kilometers (888 square miles). The model described in this report can serve as a tool for water-rights administration and water-resource management and planning. The model was completed with support from the Idaho Department of Water Resources, and is part of an ongoing U.S. Geological Survey effort to characterize the groundwater resources of the WRV. A highly reproducible approach was taken for constructing the WRV groundwater-flow model. The collection of datasets, source code, and processing instructions used to construct and analyze the model was distributed as an R statistical-computing and graphics package. Flow in the WRV aquifer was simulated using the MODFLOW-USG groundwater flow model. The transient flow model simulates groundwater flow between 1995 and 2010. The model uses a 100-meter (328-feet) uniform grid spacing with 54,922 active model cells distributed over three model layers. A confining unit in the south-central part of the Bellevue fan necessitated the use of a multi-layer model. Specified-flow boundaries were used to simulate the groundwater inflows from each of the major tributary basins (also known as tributary basin underflow) and the areal recharge of precipitation and applied irrigation. Head‑dependent flow boundaries were used to simulate the stream-aquifer flow exchange in river reaches and the groundwater discharge at the outlet boundaries of Stanton Crossing and Silver Creek. The model was calibrated by adjusting aquifer hydraulic properties to match simulated and measured water levels and stream-aquifer flow exchange, using the parameter-estimation program PEST. The model reasonably simulated the measured water-table elevation, orientation, and gradients. Stream-aquifer flow exchange along river reaches also was reasonably simulated by the model. Inflow into the WRV aquifer system originates from three sources (from largest to smallest): Streamflow loss from the Big Wood River and Silver Creek, Areal recharge of precipitation and applied irrigation, and Tributary basin underflow. Outflow from the WRV aquifer system originates from five sources (from largest to smallest): Aquifer discharge into the Big Wood River and Silver Creek, Production-well pumping, Discharge across the water table into the vadose zone, Subsurface outflow beneath Silver Creek near Picabo, and Subsurface outflow beneath the Big Wood River near Stanton Crossing. Temporal changes in aquifer storage are most affected by areal recharge and groundwater pumping, and also contribute to changes in streamflow gains.

Idaho↗

Assessing potential effects of changes in water use with a numerical groundwater-flow model of Carson Valley, Douglas County, Nevada, and Alpine County, California

Rapid growth and development within Carson Valley in Douglas County, Nevada, and Alpine County, California, has caused concern over the continued availability of groundwater, and whether the increased municipal demand could either impact the availability of water or result in decreased flow in the Carson River. Annual pumpage of groundwater has increased from less than 10,000 acre feet per year (acre-ft/yr) in the 1970s to about 31,000 acre-ft/yr in 2004, with most of the water used in agriculture. Municipal use of groundwater totaled about 10,000 acre-feet in 2000. In comparison, average streamflow entering the valley from 1940 to 2006 was 344,100 acre-ft/yr, while average flow exiting the valley was 297,400 acre-ft/yr. Carson Valley is underlain by semi-consolidated Tertiary sediments that are exposed on the eastern side and dip westward. Quaternary fluvial and alluvial deposits overlie the Tertiary sediments in the center and western side of the valley. The hydrology of Carson Valley is dominated by the Carson River, which supplies irrigation water for about 39,000 acres of farmland and maintains the water table less than 5 feet (ft) beneath much of the valley floor. Perennial and ephemeral watersheds drain the Carson Range and the Pine Nut Mountains, and mountain-front recharge to the groundwater system from these watersheds is estimated to average 36,000 acre-ft/yr. Groundwater in Carson Valley flows toward the Carson River and north toward the outlet of the Carson Valley. An upward hydraulic gradient exists over much of the valley, and artesian wells flow at land surface in some areas. Water levels declined as much as 15 ft since 1980 in some areas on the eastern side of the valley. Median estimated transmissivities of Quaternary alluvial-fan and fluvial sediments, and Tertiary sediments are 316; 3,120; and 110 feet squared per day (ft 2 /d), respectively, with larger transmissivity values in the central part of the valley and smaller values near the valley margins. A groundwater-flow model of Quaternary and Tertiary sediments in Carson Valley was developed using MODFLOW and calibrated to simulate historical conditions from water years 1971 through 2005. The 35-year transient simulation represented quarterly changes in precipitation, streamflow, pumping and irrigation. Inflows to the groundwater system simulated in the model include mountain-front recharge from watersheds in the Carson Range and Pine Nut Mountains, valley recharge from precipitation and land application of wastewater, agricultural recharge from irrigation, and septic-tank discharge. Outflows from the groundwater system simulated in the model include evapotranspiration from the water table and groundwater withdrawals for municipal, domestic, irrigation and other water supplies. The exchange of water between groundwater, the Carson River, and the irrigation system was represented with a version of the Streamflow Routing (SFR) package that was modified to apply diversions from the irrigation network to irrigated areas as recharge. The groundwater-flow model was calibrated through nonlinear regression with UCODE to measured water levels and streamflow to estimate values of hydraulic conductivity, recharge and streambed hydraulic-conductivity that were represented by 18 optimized parameters. The aquifer system was simulated as confined to facilitate numerical convergence, and the hydraulic conductivity of the top active model layers that intersect the water table was multiplied by a factor to account for partial saturation. Storage values representative of specific yield were specified in parts of model layers where unconfined conditions are assumed to occur. The median transmissivity ( T ) values (11,000 and 800 ft 2 /d for the fluvial and alluvial-fan sediments, respectively) are both within the third quartile of T values estimated from specific-capacity data, but T values for Tertiary sediments are larger than the third quartile estimated from specific-capacity data. The estimated vertical anisotropy for the Quaternary fluvial sediments (9,000) is comparable to the value estimated for a previous model of Carson Valley. The estimated total volume of mountain-front recharge is equivalent to a previous estimate from the Precipitation-Runoff Modeling System (PRMS) watershed models, but less recharge is estimated for the Carson Range and more recharge is estimated for the Pine Nut Mountains than the previous estimate. Simulated flow paths indicate that groundwater flows faster through the center of Carson Valley and slower through the lower hydraulic-conductivity Tertiary sediments to the east. Shallow flow in the center of the valley is towards drainage channels, but deeper flow is generally directed toward the basin outlet to the north. The aquifer system is in a dynamic equilibrium with large inflows from storage in dry years and large outflows to storage in wet years. Pumping has historically been less than 10 percent of outflows from the groundwater system, and agricultural recharge has been less than 10 percent of inflows to the groundwater system. Three principal sources of uncertainty that affect model results are: (1) the hydraulic characteristics of the Tertiary sediments on the eastern side of the basin, (2) the composition of sediments beneath the alluvial fans and (3) the extent of the confining unit represented within fluvial sediments in the center of the basin. The groundwater-flow model was used in five 55-year predictive simulations to evaluate the long-term effects of different water-use scenarios on water-budget components, groundwater levels, and streamflow in the Carson River. The predictive simulations represented water years 2006 through 2060 using quarterly stress periods with boundary conditions that varied cyclically to represent the transition from wet to dry conditions observed from water years 1995 through 2004. The five scenarios included a base scenario with 2005 pumping rates held constant throughout the simulation period and four other scenarios using: (1) pumping rates increased by 70 percent, including an additional 1,340 domestic wells, (2A) pumping rates more than doubled with municipal pumping increased by a factor of four over the base scenario, (2B) pumping rates of 2A with 2,040 fewer domestic wells, and (3) pumping rates of 2A with 3,700 acres removed from irrigation. The 55-year predictive simulations indicate that increasing groundwater withdrawals under the scenarios considered would result in as much as 40 ft and 60 ft of water-table decline on the west and east sides of Carson Valley, respectively. The water table in the central part of the valley would remain essentially unchanged, but water-level declines of as much as 30 ft are predicted for the deeper, confined aquifer. The increased withdrawals would reduce the volume of groundwater storage and decrease the mean downstream flow in the Carson River by as much as 16,500 acre-ft/yr. If, in addition, 3,700 acres were removed from irrigation, the reduction in mean downstream flow in the Carson River would be only 6,500 acre-ft/yr. The actual amount of flow reduction is uncertain because of potential changes in irrigation practices that may not be accounted for in the model. The projections of the predictive simulations are sensitive to rates of mountain-front recharge specified for the Carson Range and the Pine Nut Mountains. The model provides a tool that can be used to aid water managers and planners in making informed decisions. A prudent management approach would include continued monitoring of water levels on both the east and west sides of Carson Valley to either verify the predictions of the groundwater-flow model or to provide additional data for recalibration of the model if the predictions prove inaccurate.

California;Nevada↗

Water required, water used, and potential water sources for rice irrigation, north coast of Puerto Rico

A 3-yr investigation was conducted to determine the water required and used (both consumed and applied) for irrigation in the rice-growing areas of Vega Baja, Manati, and Arecibo along the north coast. In addition, the investigation evaluated the water resources of each area with regard to the full development of rice farming areas. Based on experiments conducted at selected test farms, water required ranged from 3.13 to 5.25 acre-ft/acre/crop. The amount of water required varies with the wet and dry seasons. Rainfall was capable of supplying from 31 to 70% of the water required for the measured crop cycles. Statistical analyses demonstrated that as much as 95% of rainfall is potentially usable for rice irrigation. The amount of water consumed differed from the quantity required at selected test farms. The difference between the amount of water consumed and that required was due to unaccounted losses or gains, seepage to and from the irrigation and drainage canals, and lateral leakage through levees. Due to poor water-management practices, the amount of water applied to the farms was considerably larger than the sum of the water requirement and the unaccounted losses or gains. Rivers within the rice growing areas constitute the major water supply for rice irrigation. Full development of these areas will require more water than the rivers can supply. Efficient use of rainfall can significantly reduce the water demand from streamflow. The resulting water demand, however, would still be in excess of the amount available from streamflow. Groundwater development in the area is limited because of seawater intrusion in the aquifers underlying the rice-growing areas. Capture of seepage to the aquifers using wells located near streams, artificial recharge, and development of the deep artesian system can provide additional water for rice irrigation.

Puerto Rico↗

Groundwater quality in the Owens Valley, California

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. Owens Valley is one of the study areas being evaluated. The Owens study area is approximately 1,030 square miles (2,668 square kilometers) and includes the Owens Valley groundwater basin (California Department of Water Resources, 2003). Owens Valley has a semiarid to arid climate, with average annual rainfall of about 6 inches (15 centimeters). The study area has internal drainage, with runoff primarily from the Sierra Nevada draining east to the Owens River, which flows south to Owens Lake dry lakebed at the southern end of the valley. Beginning in the early 1900s, the City of Los Angeles began diverting the flow of the Owens River to the Los Angeles Aqueduct, resulting in the evaporation of Owens Lake and the formation of the current Owens Lake dry lakebed. Land use in the study area is approximately 94 percent (%) natural, 5% agricultural, and 1% urban. The primary natural land cover is shrubland. The largest urban area is the city of Bishop (2010 population of 4,000). Groundwater in this basin is used for public and domestic water supply and for irrigation. The main water-bearing units are gravel, sand, silt, and clay derived from surrounding mountains. Recharge to the groundwater system is primarily runoff from the Sierra Nevada, and by direct infiltration of irrigation. The primary sources of discharge are pumping wells, evapotranspiration, and underflow to the Owens Lake dry lakebed. The primary aquifers in Owens Valley are defined as those parts of the aquifers corresponding to the perforated intervals of wells listed in the California Department of Public Health database. Public-supply wells in Owens Valley are completed to depths between 210 and 480 feet (64 to 146 meters), consist of solid casing from the land surface to a depth of 50 to 80 feet (15 to 24 meters), and are screened or perforated below the solid casing.

California↗