Search USGS⌕ Search

SEARCH · Search USGS

Results for “Geological Journal”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6Linked to original sources

The idea of magma mixing: History of a struggle for acceptance

In 1851, chemist Robert Bunsen suggested that the mixing of two magmas, one mafic and the other felsic, in various proportions might account for the wide range of chemical compositions of igneous rocks. Based on flaws in several of its secondary provisions, the whole hypothesis was rejected by a succession of influential critics and remained in disrepute for a hundred years. Meanwhile, studies of composite dikes and sills indicated that, indeed, mafic and felsic magmas had coexisted at close quarters and had been emplaced in quick succession. This interpretation was also used by some investigators to explain the intimate association of mafic and felsic rock types in the commonly occurring igneous complexes. Others believed that the mafic components of these complexes were derived from geologically older mafic formations. By the early 1900s it had become apparent that mafic magmas crystallized at higher temperatures than felsic magmas. This knowledge was not immediately applied to the problem of magma mixing, however, due in part to the popularity of the newly validated process of fractional crystallization and to the implication that the diversity of igneous rocks could be accounted for by that process alone. Not until the 1950s was the attention of the geological community drawn to the fact that disparate magmas mix in a special manner: they mingle, the mafic magma being quenched to a fracturable solid upon contact with the cooler felsic magma. This explanation set in motion a series of studies of other igneous complexes, confirming the concept and adding other identifying features of the process.

Journal of Geology↗

Geochemical recognition of a captured back-arc basin metabasaltic complex, southwestern Oregon

An extensive fault-bounded amphibolite terrane of Late Jurassic ( ) metamorphic age occurring in the northeastern Klamath Mountains of southern Oregon has been recognized as the remnants of an ancient back-arc basin. In spite of thorough metamorphic recrystallization under amphibolite-facies conditions, the amphibolite locally displays relict igneous textures which suggest that the protoliths included basaltic dikes or sills, shallow diabase intrusions, and gabbros. The major- and minor-element chemistry of the amphibolite indicates that some alteration of original compositions has occurred. Nevertheless, certain elements (e.g. Zr, Ti, Y, Hf, P, Th, Ta, and the REE) were probably immobile and retain their original igneous abundances. Chondrite-normalized REE patterns are similar to those of mid-ocean ridge basalt (MORB): concave-downward and flat or slightly LREE-depleted, with abundances about six to 30 times chondritic values. Patterns are slightly LREE-enriched and HREE-depleted relative to average MORB. Most samples plot in or near MORB fields in tectonomagmatic discrimination diagrams, but relative enrichment in Th and the LREE suggest the involvement of subduction-related fluids in magma genesis. In this regard, the amphibolite is very similar to some back-arc basin basalts. The geochemical data, together with the present-day geologic context, indicate that the tectonic setting of eruption/intrusion was probably within a back-arc basin that existed inboard (east) of a pre-Nevadan volcanic arc. The basalt (now amphibolite) and the overlying sediments (now the May Creek Schist) were metamorphosed and deformed during accretion to North America during the Late Jurassic Nevadan orogeny.

Journal of Geology↗

Geology of crystalline rocks of northern Fiordland: details of the granulite facies Western Fiordland Orthogneiss and associated rock units

A c. 700 km2 area of northern Fiordland (South Island, New Zealand) is described in which Early Cretaceous high-pressure metamorphic rocks and virtually unmetamorphosed plutonic rocks occur. The dominant rocks are orthogneisses developed from synmetamorphic basic-intermediate intrusive complexes, the youngest and most widespread of which is the Early Cretaceous Western Fiordland Orthogneiss (WFO). The latter has undergone granulite facies metamorphism and occurs throughout much of western Fiordland. WFO was emplaced synkinematically in a subduction-related magmatic arc. A collisional event during or immediately following magma emplacement resulted in crustal thickening equivalent to onloading of a 20 km thick section over rocks already buried at mid-crustal depths. This event was responsible for peak load pressures of c. 12-13 kbar. The steeply dipping Surprise Creek Fault juxtaposes high-pressure metamorphic rocks of western and central Fiordland against virtually unmetamorphosed gabbroic rocks of the Early Cretaceous Darran Complex. -from Author

New Zealand Journal of Geology and Geophysics↗

Pedimentation versus debris-flow origin of plateau-side desert terraces in southern Utah

Plateau-side terraces in arid areas around the world are commonly described as pediment remnants, although, in many cases, they may have been formed by debris-flow deposition. Pediments do exist in the area of the Aquarius and Kaiparowits Plateaus of southern Utah; however, many alluvial terraces that were classified by previous workers as pediments are actually formed of thick deposits of sediment released into valleys by episodic landslide events. Pedimentation may have implications of base level stability and aridity that are very different from the implications of landsliding, so that the identification of pediments where none exist, as has occurred for some places in the Aquarius and Kaiparowits areas, may result in erroneous interpretations of geologic history. Although both pediment and debris-flow depositional terraces have smooth, alluvium-covered upper surfaces, the two can be distinguished by the shape of the underlying bedrock surface and the process of formation. The distinction is that pedimentation produces smooth relief through erosion whereas wet debris flow produces smooth relief through deposition, although transitional phases exist. Most terraces on the flanks of the Aquarius and Kaiparowits Plateaus reflect periods of valley filling when wet debris flows rapidly deposited large quantities of sediment. The sources of the wet debris-flow sediment were large lobes of landslide debris that carried down sediment from high on the plateau sides. The relation of younger terraces to landsliding is clear, because the terrace surfaces are graded to the toes of slide lobes, but the origin of older terraces is less obvious, because older lobes of slide debris have generally been removed by erosion.

Journal of Geology↗

Organic geochemical studies of the transformation of gymnospermous xylem during peatification and coalification to subbituminous coal

Organic geochemical investigations of peatified and coalified xylem from gymnosperms have provided useful information on the organic transformational processes collectively known as coalification. The combined use of solid-state 13 C nuclear magnetic resonance (NMR) and pyrolysis/gas chromatography/mass spectrometry (py/gc/ms) has allowed us to examine the organic composition of peatified and coalified xylem on both a bulk (average) compositional basis and on a detailed molecular basis. We conclude from our studies that coalification of gymnospermous xylem involves the following processes1. (1) early selective removal of cellulosic materials so that lignin, a primary constituent of xylem, is transformed to macromolecular aromatic components in coal;2. (2) modification of gymnospermous lignin by demethylation to form catechol-like structures, and by condensation reactions to induce a high level of cross-linking at an early stage of coalification; and (3) dehydroxylation during increasing coalification to subbituminous coal, the resultant xylem becomes more phenolic in character as the catechol-like structures decrease.

International Journal of Coal Geology↗

Fold-to-fault progression of a major thrust zone revealed in horses of the North Mountain fault zone, Virginia and West Virginia, USA

The method of emplacement and sequential deformation of major thrust zones may be deciphered by detailed geologic mapping of these important structures. Thrust fault zones may have added complexity when horse blocks are contained within them. However, these horses can be an important indicator of the fault development holding information on fault-propagation folding or fold-to-fault progression. The North Mountain fault zone of the Central Appalachians, USA, was studied in order to better understand the relationships of horse blocks to hanging wall and footwall structures. The North Mountain fault zone in northwestern Virginia and eastern panhandle of West Virginia is the Late Mississippian to Permian Alleghanian structure that developed after regional-scale folding. Evidence for this deformation sequence is a consistent progression of right-side up to overturned strata in horses within the fault zone. Rocks on the southeast side (hinterland) of the zone are almost exclusively right-side up, whereas rocks on the northwest side (foreland) of the zone are almost exclusively overturned. This suggests that the fault zone developed along the overturned southeast limb of a syncline to the northwest and the adjacent upright limb of a faulted anticline to the southeast.

Virginia;West Virginia↗

The mesoproterozoic Beaverhead impact structure and its tectonic setting, Montana-Idaho: 40Ar/39 and U-Pb isotopic constraints

New 40Ar/39Ar and uranium-lead (U-Pb) zircon data from the Beaverhead impact structure, first identified by extensive shatter coning of Proterozoic quartzite and gneiss from the Beaverhead Mountains near the Montana-Idaho border, indicate that the structure formed at or after 900 Ma. The 40Ar/39Ar age spectra from fine-grained muscovite and biotite from a breccia zone in high-grade gneiss show significant argon loss but yield dates for highest-temperature steps that cluster between 899 and 908 Ma. The dated minerals probably formed by recrystallization of impact glass, so on both geologic and isotopic grounds, the dates probably represent the minimum age of impact. U-Pb data for zircons from the same breccia are strongly discordant and yield an upper intercept apparent age of 2464 ?? 56 Ma and a lower intercept apparent age of 779 ?? 69 Ma. Another brecciated gneiss about 7 km to the northeast that does not contain secondary mica does contain zircons that yield a concordant apparent age of 2455 ?? 9 Ma. Nearby gneiss that neither is brecciated nor contains shatter cones yields an apparent age of 2451 ?? 46 Ma. The 40Ar/39Ar results constrain the age of the shatter-coned quartzite and indicate that it is >900 Ma and possibly correlative with the Gunsight Formation of the Mesoproterozoic Lemhi Group. The upper intercept U-Pb age of ???2450 Ma from all three dated samples also shows that the Paleoproterozoic basement rocks of the area are among the youngest in the mostly Archean Wyoming province of North America. The impact site lies near the margin of the province, along the northeast-trending Great Falls tectonic zone, and the relatively young crustal age may reflect Early Proterozoic marginal accretion.

Journal of Geology↗

Geospatial resources for the geologic community: The USGS National Map

Geospatial data are a key component of investigating, interpreting, and communicating the geological sciences. Locating geospatial data can be time-consuming, which detracts from time spent on a study because these data are not obviously placed in central locations or are served from many disparate databases. The National Map of the US Geological Survey is a publicly available resource for accessing the geospatial base map data needs of the geological community from a central location. The National Map data are available through a viewer and download platform providing access to eight primary data themes, plus the US Topo and scanned historical topographic maps. The eight themes are elevation, orthoimagery, hydrography, geographic names, boundaries, transportation, structures, and land cover, and they are being offered for download as predefined tiles in formats supported by leading geographic information system software. Data tiles are periodically refreshed to capture the most current content and are an efficient method for disseminating and receiving geospatial information. Elevation data, for example, are offered as a download from the National Map as 1° × 1° tiles for the 10- and 30- m products and as 15′ × 15′ tiles for the higher-resolution 3-m product. Vector data sets with smaller file sizes are offered at several tile sizes and formats. Partial tiles are not a download option—any prestaged data that intersect the requesting bounding box will be, in their entirety, part of the download order. While there are many options for accessing geospatial data via the Web, the National Map represents authoritative sources of data that are documented and can be referenced for citation and inclusion in scientific publications. Therefore, National Map products and services should be part of a geologist’s first stop for geospatial information and data.

Journal of Geology↗

Structure of the North American Atlantic Continental Margin

The use of multichannel seismic-reflection profiles to study oceanic areas has advanced our understanding of deep crustal structure and the history of its development. Off eastern North America, where the structure of the continental margin is essentially constructional, seismic profiles have approximated geologic cross sections up to 10–15 km below the sea floor and revealed major structural and stratigraphic features that have regional hydrocarbon potential. These features include (a) a block-faulted basement hinge zone; (b) a deep, broad, rifted basement filled with clastic sediment and salt; and (c) a buried paleoshelf-edge complex that has many forms. The mapping of seismo-stratigraphic units over the continental shelf, slope, and rise has shown that the margin's developmental state included infilling of a rifted margin, buildup of a carbonate platform, and construction of an onlapping continental-rise wedge that was accompanied by eroison of the slope. Correlation of seismic stratigraphy with well-log biostratigraphy reveals that the area experienced a gradual rise in sea level during the Mesozoic and an episodic sea-level fall during the Cenozoic. These long-term changes formed a subdued continental shelf-slope-rise transition in the early Tertiary and a steepened one in the Quaternary. Comparison of seismic and drill-hole data has also shown margin-wide unconformities similar to those shown by the Vail curve of coastal onlap and eustatic sea-level change, i.e., unconformities that provide markers to subdivide the sequences of reflections on the seismic-reflection profiles. Further, the termination of older key reflectors against oceanic basement gives us a corroborative check on the age of oceanic crust as determined from the magnetic anomalies produced by sea-floor-spreading.

Journal of Geological Education↗

River terrace evidence of tectonic processes in the eastern North American plate interior, South Anna River, Virginia

We show that long-recognized seismicity in the central Virginia seismic zone of the eastern North American intraplate setting arises primarily from tectonic processes predicted by new, fully coupled plate tectonic geodynamic models. The study leverages much new geophysical and geologic data following the 2011 Mineral, Virginia, earthquake that ruptured a steeply dipping, northwest-verging reverse fault traversed by the South Anna River. The data are primarily assembled from a flight of six fluvial terrace geomorphic markers identified and correlated on texture, relative weathering, and numeric ages including one terrestrial cosmogenic nuclide (TCN) profile and 30 luminescence dates. Terrace thickness, stratigraphic age models, and incision rates downstream and upstream of the 2011 rupture are different. Long-term river incision rates of ∼25–30 m/My are superimposed on regional TCN-determined erosion rates of ∼8.5 m/My; however, there are at least 10 m of tectonically driven incision in the epicentral region at rates of ∼30–94 m/My. The inferred deformation resembles a hanging wall anticline above a blind reverse fault with a diffuse overlying carapace of minor brittle faults, an interpretation supported by seismology as well as bedrock and saprolite mapped across the epicentral region. These results are further supported by channel metrics that show nonuniform channel steepness ( k sn ) and a predicted steady-state channel elevation different from the actual channel elevation across the epicentral region. If all of the observed deformation is a consequence of the fault that ruptured in 2011, the recurrence interval of Mineral-sized events would be ∼5.5 ky.

Virginia↗

Defining the hafnium isotopic signature of the Appalachian orogen through analysis of detrital zircons from modern fluvial sediments

Fluvial sediments are the product of erosion, weathering, and transport of bedrock within a well-defined catchment area, and their constituent grains may therefore record valuable information about the lithological and geochemical properties of geologic units within the upstream drainage. Analysis of U-Pb ages and Lu/Hf isotopic values in detrital zircon grains from major rivers in the eastern USA characterizes these parameters within broad areas of the Appalachian orogen. In this study, five modern fluvial sediment samples, collected across ~1500 km and representing 216,000 km2 of total catchment area, reveal that the relative proportions of Mesoproterozoic to Paleozoic U-Pb crystallization ages vary widely across the former Laurentian margin. However, εHft values in the same samples are largely consistent regardless of their geographic location. Mesoproterozoic (Grenville orogen) zircons display a more limited range of εHft values (approximately 0 to +10 εHft units) compared to the more negative, more variable values (-15 to +10) found in grains from the Paleozoic orogenies. When compared to other published modern detrital samples from the Gulf Coastal Plain, Appalachian samples show more similarity to each other and to the Pleistocene of Florida than to those from the Mississippi River mouth, likely because the latter also sources sediments from the Cordillera of western North America. More negative εHft values in Paleozoic zircons may be genetically related to older Mesoproterozoic grains, as they are compatible with the continued isotopic evolution of Lu/Hf derived from the mantle between 1.2 and 2.0 Ga. Hafnium geochemistry in detrital grains may therefore have some utility in discerning sediment provenance between the Appalachians and other regions, and may also provide useful information regarding the nature of crustal generation through time.

Journal of Geology↗

Physical geology and eruptive history of the Matahina Ignimbrite, Taupo Volcanic Zone, North Island, New Zealand

The Matahina Ignimbrite is a 280 ka ash‐flow sheet that erupted from Haroharo Caldera in the Okataina Volcanic Centre, northern Taupo Volcanic Zone, North Island, New Zealand. The ignimbrite underlies a 2000 km 2 area mainly east of the caldera, ranges in thickness from 5 to 200 m, and has a outflow volume of c. 120 km 3 , equivalent to c. 75 km 3 of magma. It is a multiple‐flow, compound cooling unit consisting of a basal tephra (fallout) member and three ash‐flow members, designated lower, middle , and upper , that record three eruptive pulses separated by brief time intervals, estimated from cooling and compaction noddling to range from 20 to 60 days. Distribution of coarse lithic clasts, together with local interbedded co‐ignimbrite lag breccias and tephra layers east of the Puhipuhi Easin, confirm Haroharo Caldera as the eruptive source. Over most of its extent on the Kaingaroa Plateau, the outflow s leet thickens eastward away from its source and attains its greatest thickness in the elongate, north‐trending, fault‐a ngle trough formed between the gently east sloping surface of the plateau and the western front of the Ikawhenua Fange. Difference in thickness of the ignimbrite across the fault bounding the west front of the Ikawhenua Range suggests that during the short time interval between emplacement of the lower and middle ash‐flow members, a major tectonic event caused at least 10 m displacement on the fault locally. Circumstantial evidence supporting this early syneruptive tectonic event is found along the Bay of Plenty coast where penecontemporaneous liquefaction structures, possibly seismically induced, occur in the distal subaqueous facies of the lower ash‐flow member. The presence of such 1 quefaction structures in the Matahina and other coastal New Zealand ignimbrites suggests a possible close association between tectonism and major ignimbrite eruptions.

North Island, Taupo Volcanic Zone↗

Bedrock geology of DFDP-2B, central Alpine Fault, New Zealand

During the second phase of the Alpine Fault, Deep Fault Drilling Project (DFDP) in the Whataroa River, South Westland, New Zealand, bedrock was encountered in the DFDP-2B borehole from 238.5–893.2 m Measured Depth (MD). Continuous sampling and meso- to microscale characterisation of whole rock cuttings established that, in sequence, the borehole sampled amphibolite facies, Torlesse Composite Terrane-derived schists, protomylonites and mylonites, terminating 200–400 m above an Alpine Fault Principal Slip Zone (PSZ) with a maximum dip of 62°. The most diagnostic structural features of increasing PSZ proximity were the occurrence of shear bands and reduction in mean quartz grain sizes. A change in composition to greater mica:quartz + feldspar, most markedly below c. 700 m MD, is inferred to result from either heterogeneous sampling or a change in lithology related to alteration. Major oxide variations suggest the fault-proximal Alpine Fault alteration zone, as previously defined in DFDP-1 core, was not sampled.

New Zealand Journal of Geology and Geophysics↗

Pleistocene Brawley and Ocotillo Formations: Evidence for initial strike-slip deformation along the San Felipe and San Jacinto fault zonez, Southern California

We examine the Pleistocene tectonic reorganization of the Pacific-North American plate boundary in the Salton Trough of southern California with an integrated approach that includes basin analysis, magnetostratigraphy, and geologic mapping of upper Pliocene to Pleistocene sedimentary rocks in the San Felipe Hills. These deposits preserve the earliest sedimentary record of movement on the San Felipe and San Jacinto fault zones that replaced and deactivated the late Cenozoic West Salton detachment fault. Sandstone and mudstone of the Brawley Formation accumulated between ???1.1 and ???0.6-0.5 Ma in a delta on the margin of an arid Pleistocene lake, which received sediment from alluvial fans of the Ocotillo Formation to the west-southwest. Our analysis indicates that the Ocotillo and Brawley formations prograded abruptly to the east-northeast across a former mud-dominated perennial lake (Borrego Formation) at ???1.1 Ma in response to initiation of the dextral-oblique San Felipe fault zone. The ???25-km-long San Felipe anticline initiated at about the same time and produced an intrabasinal basement-cored high within the San Felipe-Borrego basin that is recorded by progressive unconformities on its north and south limbs. A disconformity at the base of the Brawley Formation in the eastern San Felipe Hills probably records initiation and early blind slip at the southeast tip of the Clark strand of the San Jacinto fault zone. Our data are consistent with abrupt and nearly synchronous inception of the San Jacinto and San Felipe fault zones southwest of the southern San Andreas fault in the early Pleistocene during a pronounced southwestward broadening of the San Andreas fault zone. The current contractional geometry of the San Jacinto fault zone developed after ???0.5-0.6 Ma during a second, less significant change in structural style. ?? 2007 by The University of Chicago. All rights reserved.

Journal of Geology↗

Sediment fluxes from California Coastal Rivers: the influences of climate, geology, and topography

The influences of geologic and climatic factors on erosion and sedimentation processes in rivers draining the western flank of the California Coast Range are assessed. Annual suspended, bedload, and total sediment fluxes were determined for 16 river basins that have hydrologic records covering all or most of the period from 1950 to 2006 and have been relatively unaffected by flow storage, regulation, and depletion, which alter the downstream movement of water and sediment. The occurrence of relatively large annual sediment fluxes are strongly influenced by the El Nino–Southern Oscillation (ENSO) and the Pacific Decadal Oscillation (PDO). The frequency of relatively large annual sediment fluxes decreases from north to south during La Nina phases and increases from north to south during El Nino phases. The influence of ENSO is modulated over a period of decades by the PDO, such that relatively large annual sediment fluxes are more frequent during a La Nina phase in conjunction with a cool PDO and during an El Nino phase in conjunction with a warm PDO. Values of mean annual sediment flux, , were regressed against basin and climatic characteristics. Basin area, bedrock erodibility, basin relief, and precipitation explain 87% of the variation in from the 16 river basins. Bedrock erodibility is the most significant characteristic influencing . Basin relief is a superior predictor of compared with basin slope. is nearly proportional to basin area and increases with increasing precipitation. For a given percentage change, basin relief has a 2.3-fold greater effect on than a similar change in precipitation. The estimated natural from all California coastal rivers for the period 1950–2006 would have been approximately 85 million tons without flow storage, regulation, and depletion; the actual has been approximately 50 million tons, because of the effects of flow storage, regulation, and depletion.

California↗

Late Cretaceous through Cenozoic strike-slip tectonics of southwestern Alaska

New geologic mapping and geochronology show that margin-parallel strike-slip faults on the western limb of the southern Alaska orocline have experienced multiple episodes of dextral motion since ~100 Ma. These faults are on the upper plate of a subduction zone ~350-450 km inboard of the paleotrench. In southwestern Alaska, dextral displacement is 134 km on the Denali fault, at least 88-94 km on the Iditarod-Nixon Fork fault, and perhaps tens of kilometers on the Dishna River fault. The strike-slip regime coincided with Late Cretaceous sedimentation and then folding in the Kuskokwim basin, and with episodes of magmatism and mineralization at ~70, ~60, and ~30 Ma. No single driving mechanism can explain all of the ~95 million-year history of strike-slip faulting. Since ~40 Ma, the observed dextral sense of strike slip has run contrary to the sense of subduction obliquity. This may be explained by northward motion of the Pacific plate driving continental margin slivers into and/or around the oroclinal bend. From 44 to 66 Ma, oroclinal rotation, perhaps involving large-scale flexural slip, may have been accompanied by westward escape of crustal blocks along strike-slip faults. However, reconstructions of this period involve unproven assumptions about the identity of the subducting plate, the position of subducting ridges, and the exact timing of oroclinal bending, thus obscuring the driving mechanisms of strike slip. Prior to 66 Ma, oblique subduction is the most plausible driving mechanism for dextral strike slip. Cumulative displacement on all faults of the western limb of the orocline is at least 400 km, about half that on the eastern limb; this discrepancy might be explained by a combination of thrusting and unrecognized strike-slip faulting.

Journal of Geology↗

Detecting snow avalanche activity using infrasound: Hooker Valley, New Zealand

Snow avalanches pose considerable hazards to people and infrastructure in alpine environments. Traditional avalanche monitoring relies on meteorological data and visual observations, which can be limited in scope and timeliness. Infrasound offers a promising complementary monitoring tool by detecting the low-frequency sound waves generated by avalanches. Here, we present infrasound and camera observations during a 50-day field campaign in the Hooker Valley of Aoraki/Mount Cook National Park, New Zealand. Our study detected seven avalanches with the cameras, whereas the infrasound system identified only one of these events, which was the largest and occurred under conditions that likely favoured infrasound propagation. The infrasound system recorded numerous other events not captured by the cameras, indicating the benefit of further investigation to determine their sources. These findings highlight the potential of infrasound technology for detecting avalanches and providing broad spatial coverage, capturing events in areas not monitored by cameras, while also showcasing limitations in infrasound capabilities. The limited detection of smaller avalanches underscores the opportunity for further research to enhance detection capabilities and understand environmental influences such as snow cover and wind noise. Overall, this study emphasises the utility of multidisciplinary monitoring techniques to improve avalanche detection in alpine environments.

Hooker Valley↗

High-frequency in situ optical measurements during a storm event: Assessing relationships between dissolved organic matter, sediment concentrations, and hydrologic processes

Dissolved organic matter (DOM) dynamics during storm events has received considerable attention in forested watersheds, but the extent to which storms impart rapid changes in DOM concentration and composition in highly disturbed agricultural watersheds remains poorly understood. In this study, we used identical in situ optical sensors for DOM fluorescence (FDOM) with and without filtration to continuously evaluate surface water DOM dynamics in a 415 km 2 agricultural watershed over a 4 week period containing a short-duration rainfall event. Peak turbidity preceded peak discharge by 4 h and increased by over 2 orders of magnitude, while the peak filtered FDOM lagged behind peak turbidity by 15 h. FDOM values reported using the filtered in situ fluorometer increased nearly fourfold and were highly correlated with dissolved organic carbon (DOC) concentrations (r 2 = 0.97), providing a highly resolved proxy for DOC throughout the study period. Discrete optical properties including specific UV absorbance (SUVA 254 ), spectral slope (S 290–350 ), and fluorescence index (FI) were also strongly correlated with in situ FDOM and indicate a shift toward aromatic, high molecular weight DOM from terrestrially derived sources during the storm. The lag of the peak in FDOM behind peak discharge presumably reflects the draining of watershed soils from natural and agricultural landscapes. Field and experimental evidence showed that unfiltered FDOM measurements underestimated filtered FDOM concentrations by up to ∼60% at particle concentrations typical of many riverine systems during hydrologic events. Together, laboratory and in situ data provide insights into the timing and magnitude of changes in DOM quantity and quality during storm events in an agricultural watershed, and indicate the need for sample filtration in systems with moderate to high suspended sediment loads.

Journal of Geological Research↗