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At least 109 records · Page 6Linked to original sources
USGS2021

Organo-facies and mineral effects on sorption capacity of low-maturity Permian Barakar shales from the Auranga Basin, Jharkhand, India

Shales associated with the Lower Permian (Barakar Formation) sediments of the Auranga Coalfield, India, occur in the immature–early mature stage. The sorption capacity of Barakar shale samples has been studied through high-pressure methane (CH 4 ) adsorption and low-pressure N 2 gas adsorption (LPN 2 GA) methods, supported with proximate analyses, programmed pyrolysis, optical petrography, and with energy-dispersive spectroscopy, X-ray diffraction, and inductively coupled plasma mass spectrometry. The sorption capacity is a function of the organic and inorganic constituents present in the shale samples. The methane sorption capacity (MSC) and Langmuir volume of the shale samples vary from 0.217 to 0.314 and 0.315 to 0.429 mmol/g rock, respectively. The BET-calculated surface area of the studied shales varies from 8.12 to 30.36 m 2 /g. The sorption capacities show the importance of the total organic content (TOC) through weak but positive correlations with MSC ( r 2 = 0.45) and S 1 values (mg hydrocarbons/g rock from programmed pyrolysis; r 2 = 0.40). Moreover, apparent inverse relationships were observed between MSC and clay mineral abundances, suggesting that individual clay mineral types may influence MSC, although more work is needed. The TOC-normalized MSC (MSC*) of shale samples shows a positive trend with quartz plus clay mineral content and ash yield of r 2 = 0.64 for both. In addition, MSC* shows a negative logarithmic relationship with S 1 + S 2 ( r 2 = 0.63) and a positive linear relationship with TOC-normalized total organic matter (TOM*) ( r 2 = 0.88, when 5 low TOM* samples are excluded) indicating complex relationships possibly including bitumen retention in the sample pore spaces. The micropore study of the samples through LPN 2 GA, applying Dubinin–Radushkevich, Dubinin–Astakhov, and density functional theory models, shows the dominance of micro-mesopore concentrations in the shale matrix of ∼2 nm pore diameter. However, these pores might be present as blind or closed pores. The presence of thorium and zirconium is reflective of terrigenous detrital matter, i.e., moderately to strongly recycled sediments. The fluviatile facies of deposited shales in the Auranga Coalfield are noted by the significant presence of kaolinite (32.5–78.3%), which suggests the importance of its effect on the sorption capacity of proximal terrigenous shales.

Jharkhand↗
USGS1990

Geology of crystalline rocks of northern Fiordland: details of the granulite facies Western Fiordland Orthogneiss and associated rock units

A c. 700 km2 area of northern Fiordland (South Island, New Zealand) is described in which Early Cretaceous high-pressure metamorphic rocks and virtually unmetamorphosed plutonic rocks occur. The dominant rocks are orthogneisses developed from synmetamorphic basic-intermediate intrusive complexes, the youngest and most widespread of which is the Early Cretaceous Western Fiordland Orthogneiss (WFO). The latter has undergone granulite facies metamorphism and occurs throughout much of western Fiordland. WFO was emplaced synkinematically in a subduction-related magmatic arc. A collisional event during or immediately following magma emplacement resulted in crustal thickening equivalent to onloading of a 20 km thick section over rocks already buried at mid-crustal depths. This event was responsible for peak load pressures of c. 12-13 kbar. The steeply dipping Surprise Creek Fault juxtaposes high-pressure metamorphic rocks of western and central Fiordland against virtually unmetamorphosed gabbroic rocks of the Early Cretaceous Darran Complex. -from Author

New Zealand Journal of Geology and Geophysics↗
USGS1969

Coexisting amphiboles from blueschist facies metamorphic rocks

Four pairs of associated calcic and sodic amphiboles from blueschist facies metamorphic rocks were analyzed with the electron microprobe and studied by single-crystal X-ray diffraction techniques. Except for ranges in the ratios Mg/(Mg+Fe) and Fe 3+ /(Fe 3+ +Al+Ti), the sodic amphiboles are similar in chemical composition. The amount of calcium in the M(4)-site ranges only from 0·18 to 0·21 ion per formula unit. The calcic amphiboles, in addition to a range in Mg/(Mg+Fe), vary in Na/(Na+Ca) ratio (0·29–0·48). Three of the calcic amphiboles contain less than 1·5 calcium ions per formula unit, indicating a significant solid solution of sodic amphibole components in the calcic amphibole phase. The a and b unit-cell parameters of the calcic amphiboles decrease with increased content of the sodic component.

Journal of Petrology↗
USGS2007

Multi-frequency ground-penetrating radar method for revealing complex sedimentary facies

We attempted to resolve deltaic facies in Taylor Valley, Antarctica by using pulses centered near 120, 300 and 880 MHz, the latter of which has not yet been tried in this setting, The 120 MHz profiles clearly defined gross material changes, while the 300 MHz profiles added significant resolution to the top set, foreset and bottomset beds. The additional, higher frequency provided only about 2.5 m penetration however, the 10-15 cm pulse length revealed and defined multiple, fine-scale features that were not observed with the lower frequencies. The dip of these features is, in some instances, opposite to that of larger features profiled with the lower frequencies. Profiling with 880 MHz not only confirmed the greater complexity of the sedimentary architecture, but also allowed more robust interpretation of depositional processes. Generally, we recommend pulses centered near 300-400 MHz for detailed sedimentary profiling to about 6m depth. ?? 2007 IEEE.

Conference Paper↗
USGS2008

100 Myr record of sequences, sedimentary facies and sea level change from Ocean Drilling Program onshore coreholes, US Mid-Atlantic coastal plain

We analyzed the latest Early Cretaceous to Miocene sections (???110-7Ma) in 11 New Jersey and Delaware onshore coreholes (Ocean Drilling Program Legs 150X and 174AX). Fifteen to seventeen Late Cretaceous and 39-40 Cenozoic sequence boundaries were identified on the basis of physical and temporal breaks. Within-sequence changes follow predictable patterns with thin transgressive and thick regressive highstand systems tracts. The few lowstands encountered provide critical constraints on the range of sea-level fall. We estimated paleowater depths by integrating lithofacies and biofacies analyses and determined ages using integrated biostratigraphy and strontium isotopic stratigraphy. These datasets were backstripped to provide a sea-level estimate for the past ???100 Myr. Large river systems affected New Jersey during the Cretaceous and latest Oligocene-Miocene. Facies evolved through eight depositional phases controlled by changes in accommodation, long-term sea level, and sediment supply: (1) the Barremian-earliest Cenomanian consisted of anastomosing riverine environments associated with warm climates, high sediment supply, and high accommodation; (2) the Cenomanian-early Turonian was dominated by marine sediments with minor deltaic influence associated with long-term (107 year) sea-level rise; (3) the late Turonian through Coniacian was dominated by alluvial and delta plain systems associated with long-term sea-level fall; (4) the Santonian-Campanian consisted of marine deposition under the influence of a wave-dominated delta associated with a long-term sea-level rise and increased sediment supply; (5) Maastrichtian-Eocene deposition consisted primarily of starved siliciclastic, carbonate ramp shelf environments associated with very high long-term sea level and low sediment supply; (6) the late Eocene-Oligocene was a starved siliciclastic shelf associated with moderately high sea-level and low sediment supply; (7) late early-middle Miocene consisted of a prograding shelf under a strong wave-dominated deltaic influence associated with major increase in sediment supply and accommodation due to local sediment loading; and (8) over the past 10 Myr, low accommodation and eroded coastal systems were associated with low long-term sea level and low rates of sediment supply due to bypassing. ?? 2008 The Authors. Journal compilation ?? 2008 Blackwell Publishing.

Basin Research↗
USGS2007

High-pressure amphibolite facies dynamic metamorphism and the Mesozoic tectonic evolution of an ancient continental margin, east- central Alaska

Ductilely deformed amphibolite facies tectonites comprise two adjacent terranes in east-central Alaska: the northern, structurally higher Taylor Mountain terrane and the southern, structurally lower Lake George subterrane of the Yukon-Tanana terrane. The pressure, temperature, kinematic and age data are interpreted to indicate that the metamorphism of the Taylor Mountain terrane and Lake George subterrane took place during different phases of a latest Palaeozoic through early Mesozoic shortening episode resulting from closure of an ocean basin now represented by klippen of the Seventymile-Slide Mountain terrane. High- to intermediate-pressure metamorphism of the Taylor Mountain terrane took place within a SW-dipping (present-day coordinates) subduction system. High- to intermediate-pressure metamorphism of the Lake George subterrane and the structural contact zone occurred during NW-directed overthrusting of the Taylor Mountain, Seventymile-Slide Mountain and Nisutlin terranes, and imbrication of the continental margin in Jurassic time. -from Authors

Alaska↗
USGS2009

The timing of eclogite facies metamorphism and migmatization in the Orlica–Śnieżnik complex, Bohemian Massif: Constraints from a multimethod geochronological study

The Orlica–Śnieżnik complex (OSC) is a key geological element of the eastern Variscides and mainly consists of amphibolite facies orthogneisses and metasedimentary rocks. Sporadic occurrences of eclogites and granulites record high-pressure (HP) to ultrahigh-pressure (UHP) metamorphic conditions. A multimethod geochronological approach ( 40 Ar– 39 Ar, Rb–Sr, Sm–Nd, U–Pb) has been used to gain further insights into the polymetamorphic evolution of eclogites and associated country rocks. Special attention was given to the unresolved significance of a 370- to 360 Ma age group that was repeatedly described in previous studies. Efforts to verify the accuracy of c. 370 Ma K–Ar phengite and biotite dates reported for an eclogite and associated country-rock gneiss from the location Nowa Wieś suggest that these dates are meaningless, due to contamination with extraneous Ar. Extraneous Ar is also considered to be responsible for a significantly older 40 Ar– 39 Ar phengite date of c. 455 Ma for an eclogite from the location Wojtowka. Attempts to further substantiate the importance of 370–360 Ma zircon dates as an indicator for a melt-forming high-temperature (HT) episode did not provide evidence in support of anatectic processes at this time. Instead, SHRIMP U–Pb zircon dating of leucosomes and leucocratic veins within both orthogneisses and (U)HP granulites revealed two age populations (490–450 and 345–330 Ma respectively) that correspond to protolith ages of the magmatic precursors and late Variscan anatexis. The results of this study further underline the importance of Late Carboniferous metamorphic processes for the evolution of the OSC that comprise the waning stages of HP metamorphism and lower pressure HT overprinting with partial melting. Eclogites and their country rocks provided no chronometric evidence for an UHP and ultrahigh-temperature episode at 387–360 Ma, as recently suggested for granulites from the OSC, based on Lu–Hf garnet ages ( Anczkiewicz et al. , 2007 ).

Orlica-Snieznik complex↗
USGS2009

40Ar/39Ar dating of Silurian and late Devonian cleavages in lower greenschist-facies rocks in the Westminster terrane, Maryland, USA

40 Ar/ 39 Ar dating of muscovite, biotite, and K-feldspar combined with microstructural analysis of lower greenschist-facies, polymetamorphic, phyllitic rocks, and marbles were successfully used to decipher the thermal and tectonic histories of the Westminster and adjacent terranes in western Maryland. The presence of unreset detrital muscovite in some samples demonstrates that temperatures in these rocks never exceeded the closure temperature for argon diffusion in muscovite, ∼350 ± 50 °C. Minor biotite in some arkoses constrains the minimum metamorphic temperatures to ≥∼320 °C. These data show an Early Silurian (ca. 430 Ma) cleavage in the western part of the Westminster terrane and a Late Devonian event (ca. 370 Ma) in the eastern Westminster and adjacent Potomac terranes. These two cleavage domains are separated by the NE-trending, newly identified Parrs Ridge fault zone. We propose that the sinistral transpressive collision of the Carolina terrane with Laurentia emplaced the western portion of the Westminster terrane in the Pennsylvania embayment along the Martic fault where it was folded and cleaved at ca. 430 Ma but otherwise largely sheltered from later deformation. The later Late Devonian dextral transpressive accretion of the outboard Potomac terrane thrust rocks of the eastern Westminster and Potomac terranes to the west, causing Late Devonian (360–370 Ma) S 2 cleavage in these rocks, but only minimal discrete overprinting S 3 cleavages in rocks farther west. Final juxtaposition and thermal convergence of these terranes occurred along reactivated dextral strike-slip faults in the Alleghanian at ca. 300 Ma.

Maryland↗
USGS2011

Pennsylvanian coniferopsid forests in sabkha facies reveal the nature of seasonal tropical biome

Pennsylvanian fossil forests are known from hundreds of sites across tropical Pangea, but nearly all comprise remains of humid Coal Forests. Here we report a unique occurrence of seasonally dry vegetation, preserved in growth position along >5 km of strike, in the Pennsylvanian (early Kasimovian, Missourian) of New Mexico (United States). Analyses of stump anatomy, diameter, and spatial density, coupled with observations of vascular traces and associated megaflora, show that this was a deciduous, mixed-age, coniferopsid woodland (∼100 trees per hectare) with an open canopy. The coniferopsids colonized coastal sabkha facies and show tree rings, confirming growth under seasonally dry conditions. Such woodlands probably served as the source of coniferopsids that replaced Coal Forests farther east in central Pangea during drier climate phases. Thus, the newly discovered woodland helps unravel biome-scale vegetation dynamics and allows calibration of climate models.

New Mexico↗
USGS1999

Depositional facies and sequence stratigraphy of a Lower Carboniferous bryozoan-crinoidal carbonate ramp in the Illinois Basin, mid-continent USA

The Lower Carboniferous Fort Payne and Ullin Formations in the Illinois Basin form the transgressive and highstand systems tracts that were deposited in a carbonate ramp setting. During deposition of the Ullin Limestone, biotic communities dominated by fenestrate bryozoans and echinoderms (primarily crinoids) proliferated, possibly in response to global tectonic, biological, and oceanographic events that affected bathymetry and nutrient supply. The Fort Payne Formation consists of a dark grey-brown, siliceous and argillaceous lime mudstone in the lower part (transgressive systems tract) and a very fine-grained wackestone to packstone with rare mud mounds in the upper part (early highstand), and was deposited in an outer ramp to basinal environment. During deposition of the lower Ullin Limestone (mostly early highstand), bryozoan-crinoidal build-ups accreted both laterally and vertically into several relatively large carbonate banks, which were partly surrounded by siliceous Fort Payne sea. Bryozoans (primarily fenestrates) were especially prevalent during the late stage of bank development and formed mud-free bioherms up to 120 m thick. In places, carbonate mud mounds also formed during the early stage of bank deposition. Bioherm development declined during deposition of the upper Ullin Limestone (late highstand), and a broad, storm-dominated carbonate ramp was established that became the site for widespread deposition of bryozoan-crinoidal sandwaves. Gradual shallowing led to ooid formation at the end of Ullin deposition. This sequence was terminated by a relative rise in sea level that resulted in deposition of the transgressive facies of the lower part of the overlying Salem Limestone. The depositional style and the nature of skeletal material of the Fort Payne and Ullin Formations are similar to those of cool-water carbonates. A deep-water setting along with upwelling of cool, nutrient-rich oceanic waters may have been responsible for the proliferation of bryozoans and crinoids at this time. The deep-water setting and abundant nutrient supply also may have restricted the formation of ooids and proliferation of shallow-water calcareous organisms.

Geological Society Special Publication↗
USGS1999

Late Neogene sedimentary facies and sequences in the Pannonian Basin, Hungary

This paper is part of the special publication No.156, The Mediterranean basins: Tertiary extension within the Alpine Orogen. (eds B.Durand, L. Jolivet, F.Horvath and M.Seranne). Detailed sedimentological, facies and numerical cycle analysis, combined with magnetostratigraphy, have been made in a number of boreholes in the Pannonian Basin, in order to study the causes of relative water-level changes and the history of the basin subsidence. Subsidence and infilling of the Pannonian Basin, which was an isolated lake at that time occurred mainly during the Late Miocene and Pliocene. The subsidence history was remarkably different in the individual sub-basins: early thermal subsidence was interrupted in the southern part of the basin, while high sedimentation rate and continuous subsidence was detected in the northeastern sub-basin. Three regional unconformities were detected in the Late Neogene Pannonian Basin fill, which represent 0.5 and 7.5 Ma time spans corresponding to single and composite unconformities. Consequently two main sequences build up the Late Neogene Pannonian Basin fill: a Late Miocene and a Pliocene one. Within the Late Miocene sequence there are smaller sedimentary cycles most probably corresponding to climatically driven relative lake-level changes in the Milankovitch frequency band. Considering the periods, the estimated values for precession and eccentricity in this study (19 and 370 ka) are close to the usually cited ones. In the case of obliquity the calculated period (71 ka) slightly deviates from the generally accepted number. Based on the relative amplitudes of oscillations, precession (sixth order) and obliquity (fifth order) cycles had the most significant impact on the sedimentation. Eccentricity caused cycles (fourth order) are poorly detectable in the sediments. The longer term (third order) cycles had very slight influence on the sedimentation pattern. Progradation, recorded in the Late Miocene sequence, correlates poorly in time within the basin. The dominant controls of this process probably were changes of basin subsidence rate and the very high sedimentation rate. The slow, upward trend of silt and sand bed thickness as well as that of the grain size also reflects the local progradation.

Geological Society Special Publication↗
USGS2014

Towards the definition of AMS facies in the deposits of pyroclastic density currents

Anisotropy of magnetic susceptibility (AMS) provides a statistically robust technique to characterize the fabrics of deposits of pyroclastic density currents (PDCs). AMS fabrics in two types of pyroclastic deposits (small-volume phreatomagmatic currents in the Hopi Buttes volcanic field, Arizona, USA, and large-volume caldera-forming currents, Caviahue Caldera, Neuquén, Argentina) show similar patterns. Near the vent and in areas of high topographical roughness, AMS depositional fabrics are poorly grouped, with weak lineations and foliations. In a densely welded proximal ignimbrite, this fabric is overprinted by a foliation formed as the rock compacted and deformed. Medial deposits have moderate–strong AMS lineations and foliations. The most distal deposits have strong foliations but weak lineations. Based on these facies and existing models for pyroclastic density currents, deposition in the medial areas occurs from the strongly sheared, high-particle-concentration base of a density-stratified current. In proximal areas and where topography mixes this denser base upwards into the current, deposition occurs rapidly from a current with little uniformity to the shear, in which particles fall and collide in a chaotic fashion. Distal deposits are emplaced by a slowing or stalled current so that the dominant particle motion is vertical, leading to weak lineation and strong foliation.

Arizona;Neuqu�n↗
USGS2018

Chevkinite-group minerals from granulite-facies metamorphic rocks and associated pegmatites of East Antarctica and South India

Electron microprobe data are presented for chevkinite-group minerals from granulite-facies rocks and associated pegmatites of the Napier Complex and Mawson Station charnockite in East Antarctica and from the Eastern Ghats, South India. Their compositions conform to the general formula for this group, viz . A 4 BC 2 D 2 Si 4 O 22 where, in the analysed specimens A = (rare-earth elements ( REE ), Ca, Y, Th), B = Fe 2+ , Mg, C = (Al, Mg, Ti, Fe 2+ , Fe 3+ , Zr) and D = Ti and plot within the perrierite field of the total Fe (as FeO) (wt.%) vs . CaO (wt.%) discriminator diagram of Macdonald and Belkin (2002). In contrast to most chevkinite-group minerals, the A site shows unusual enrichment in the MREE and HREE relative to the LREE and Ca. In one sample from the Napier Complex, Y is the dominant cation among the total REE + Y in the A site, the first reported case of Y-dominance in the chevkinite group. The minerals include the most Al-rich yet reported in the chevkinite group (≤9.15 wt.% Al 2 O 3 ), sufficient to fill the C site in two samples. Conversely, the amount of Ti in these samples does not fill the D site, and, thus, some of the Al could be making up the deficiency at D , a situation not previously reported in the chevkinite group. Fe abundances are low, requiring Mg to occupy up to 45% of the B site. The chevkinite-group minerals analysed originated from three distinct parageneses: (1) pegmatites containing hornblende and orthopyroxene or garnet; (2) orthopyroxene-bearing gneiss and granulite; (3) highly aluminous paragneisses in which the associated minerals are relatively magnesian or aluminous. Chevkinite-group minerals from the first two parageneses have relatively high FeO content and low MgO and Al 2 O 3 contents; their compositions plot in the field for mafic and intermediate igneous rocks. In contrast, chevkinite-group minerals from the third paragenesis are notably more aluminous and have greater Mg/Fe ratios

Antactica↗
USGS2016

Nonmarine facies in the Late Triassic(?) to Early Jurassic Horn Mountain Tuff member of the Talkeetna Formation, Horn Mountain, lower Cook Inlet basin, Alaska

The Talkeetna Formation is a prominent lithostratigraphic unit in south-central Alaska. In the Iniskin–Tuxedni area, Detterman and Hartsock (1966) divided the formation into three mappable units including, from oldest to youngest, the Marsh Creek Breccia, the Portage Creek Agglomerate, and the Horn Mountain Tuff Members. The Horn Mountain Tuff Member was thought to include rocks deposited in a nonmarine setting based on the presence of “tree stumps in an upright position” (Detterman and Hartsock, 1966, p. 19) near the top of the type section at Horn Mountain. Bull (2015) recognized possible nonmarine volcaniclastic rocks in the member during the 2014 field season in a saddle on the north side of Horn Mountain (figs. 2-1 and 2-2). The authors visited this location in 2015 and measured a short stratigraphic section to document facies, interpret depositional setting, and constrain age. This report summarizes our field observations and presents preliminary interpretations.

Alaska↗
USGS2000

Facies patterns and conodont biogeography in Arctic Alaska and the Canadian Arctic Islands: Evidence against juxtaposition of these areas during early Paleozoic time

Differences in lithofacies and biofacies suggest that lower Paleozoic rocks now exposed in Arctic Alaska and the Canadian Arctic Islands did not form as part of a single depositional system. Lithologic contrasts are noted in shallow- and deep-water strata and are especially marked in Ordovician and Silurian rocks. A widespread intraplatform basin of Early and Middle Ordovician age in northern Alaska has no counterpart in the Canadian Arctic, and the regional drowning and backstepping of the Silurian shelf margin in Canada has no known parallel in northern Alaska. Lower Paleozoic basinal facies in northern Alaska are chiefly siliciclastic, whereas resedimented carbonates are volumetrically important in Canada. Micro- and macrofossil assemblages from northern Alaska contain elements typical of both Siberian and Laurentian biotic provinces; coeval Canadian Arctic assemblages contain Laurentian forms but lack Siberian species. Siberian affinities in northern Alaskan biotas persist from at least Middle Cambrian through Mississippian time and appear to decrease in intensity from present-day west to east. Our lithologic and biogeographic data are most compatible with the hypothesis that northern Alaska-Chukotka formed a discrete tectonic block situated between Siberia and Laurentia in early Paleozoic time. If Arctic Alaska was juxtaposed with the Canadian Arctic prior to opening of the Canada basin, biotic constraints suggest that such juxtaposition took place no earlier than late Paleozoic time.

Alaska↗
USGS2013

Oceanographic controls on sedimentary and geochemical facies on the Peru outer shelf and upper slope

Concentrations and characteristics of organic matter in surface sediments deposited under an intense oxygen-minimum zone (OMZ) on the Peru margin were mapped and studied in samples from deck-deployed box cores and push cores acquired by submersible on two east-west transects spanning depths of 75 to 1,000 meters (m) at 12°S and 13.5°S. On the basis of sampling and analyses of the top 1–2 centimeters (cm) of available cores, three main belts of sediments were identified on each transect with increasing depth: (1) muds rich in organic carbon (OC); (2) authigenic phosphatic mineral crusts and pavements; and (3) glaucony facies. Sediments rich in OC on the 12°S transect were mainly located on the outer shelf and upper slope (150–350 m), but they occurred in much shallower water (approximately 100 m) on the 13.5°S transect. The organic matter is almost entirely marine as confirmed by Rock-Eval pyrolysis and isotopic composition of OC. Concentrations of OC are highest (up to 18 percent) in sediments within the OMZ where dissolved oxygen (DO) concentrations are <5 micromoles per kilogram (μM). Even at these low concentrations of DO, however, the surface sediments from within the OMZ are dominantly unlaminated. Concentrations of DO may have the dominant effect on organic matter characteristics, but reworking of fine-grained sediment and organic matter by strong bottom currents with velocities as high as 30 centimeters per second (cm/s) on the slope between 150 and 300 m and redeposition on the seafloor in areas of lower energy and higher DO concentration also exert important controls on OC concentration and degree of oxidation in this region. Phosphate-rich sediments and crusts occurred at depths of about 300 to 550 m on both transects. Nodular crusts of sediment cemented by carbonate-fluorapatite (CFA; phosphorite) or dolomite form within the OMZ. These phosphorite crusts evolve through cementation from light olive-green, stiff but friable, phosphatized claystone “protocrusts” through dense, dark phosphorite crusts, cemented breccias, and pavements. The degree of phosphatization and thickness of the crusts depend on the rates of sediment supply and on the strength and frequency of currents that re-expose crusts on the seafloor. Phosphorite crusts and pavements on the Peru margin can only become buried and incorporated into the geologic record once bottom currents slacken sufficiently to allow fine-grained sediment to accumulate. Glaucony-rich surface sediments, relatively undiluted by other components, were found mainly in deeper water on the 13.5°S transect (750 m to at least 1,067 m). These sediments consist almost entirely of sand-size glaucony pellets. These widespread glaucony sands formed in place and were then concentrated and reworked by strong currents that winnowed away the fine-grained matrix. Although the glaucony occurs in sand-size pellets, the pellets are made up of aggregates of authigenic, platy, micaceous clay minerals. Glaucony is predominantly a potassium (K), sodium (Na), iron (Fe), magnesium (Mg) aluminosilicate with an approximate formula of (K,Na)(Fe 3+ ,Al,Mg) 2 (Si,Al) 4 O 10 (OH) 2 . The glaucony on the 13.5°S transect forms by alteration of one or more original “framework” minerals (carbonate and [or] aluminosilicates) to form pellital aggregates of Fe-, K-, and Mg-rich clay minerals. Because Fe, K, and Mg are derived from seawater, sedimentation rates must be extremely slow in order for the original framework minerals to remain in contact with seawater. The close association of glaucony and phosphorite indicates a delicate balance between the slightly oxidizing conditions at the base of the OMZ that form glaucony and the slightly reducing conditions that mobilize iron and phosphate to form phosphorite.

Open-File Report↗
USGS1974

Nahcolite analyses of seven drill cores from the saline facies of the Green River Formation in Northwest Colorado

This report presents the results of about 3,060 quantitative analyses for nahcolite in cores from seven holes drilled in the saline facies of the Green River Formation (Eocene) in Rio Blanco County, Colorado. Nahcolite analyses of three additional drill cores from the same area were reported earlier by Dyni, Beck, and Mountjoy (1971). The analyses of these 10 drill cores were made during a detailed stratigraphic and resource study of the nahcolite that is found in association with the oil-shale deposits of the Green River Formation in the Piceance Creek basin (Dyni, 1973). The locations of the drill holes are shown on figure 1 and are described in the table headings.

Colorado↗
USGS1974

Stratigraphy and nahcolite resources of the saline facies of the Green River Formation, Rio Blanco County, Colorado

Based on a study of 10 drill cores, a sequence of oil shale and associated nahcolite, nearly 2,000 feet thick, in the lacustrine Green River Formation (Eocene) in the Piceance Creek basin, Rio Blanco County, Colo., was divided in ascending order into zones 1 to 13, B-groove, Mahogany zone (with lower, middle, and upper parts), and A-groove at the top. The odd-numbered zones and the Mahogany zone are mappable subsurface units of relatively thick oil shale and are distinguished from the even-numbered zones and A- and B-grooves which are thinner units of oil shale of lower grade. Large amounts of nahcolite found in zones 5 to 12 occur in (1) coarse-grained crystalline aggregates scattered through oil shale, (2) laterally continuous units of fine-grained crystals disseminated in oil shale, (3) brown microcrystalline beds, and (4) white coarse-grained beds that grade laterally into halitic rocks toward basin center. The original .upper limit of the nahcolite and halitic rocks is not yet completely known, but the present top is marked by a dissolution surface. Above this surface the rocks, extending from zones 11 or 12 upward into the Mahogany zone, form a water-saturated 'leached zone,' a geohydrologic unit in which large amounts of water-soluble minerals probably mostly nahcolite, and halite, were removed by ground-water dissolution. Rocks in the leached zone, mostly oil shale, are commonly broken and fractured and contain crystal cavities and solution breccias. Several solution breccias can be traced laterally into unleached beds of nahcolite and halite. Although evidence of salines is found in rocks above A-groove, the original saline facies that includes most of the bedded deposits extends from zone 5 upward into A-groove. Potentially ruinable beds of white nahcolite as much as 12 feet thick are found at depths of 1,560 or more feet below the surface. Some thicker beds of high-grade nahcolite are believed to be too close to the dissolution surface for safe room-and-pillar mining. Probably the most economical method of mining nahcolite would be as a coproduct of a shale-oil industry. Removal of nahcolite prior to retorting increases significantly the grade of oil shale by as much as 1.6 times, Several zones are more than 300 feet thick and average 30 or more weight percent nahcolite. Resources of nahcolite per square mile range as high as 489 million short tons. The total nahcolite resource in the basin is conservatively estimated at 32 billion short tons, which makes it the secondlargest deposit of sodium carbonate known .in the world.

Open-File Report↗