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At least 109 records · Page 6Linked to original sources

Adsorption of SO 2 on bituminous coal char and activated carbon fiber

The SO 2 adsorption behaviors of activated carbons produced from Illinois coal and of commercially prepared activated carbon fibers (ACFs) were compared. There was no relation between surface area of coal-based carbons and SO 2 adsorption, whereas adsorption of SO 2 on the series of ACFs was inversely proportional to N 2 BET surface area. Higher surface area ACFs had wider pores and adsorbed less SO 2 ; thus, pore size distribution is thought to play a significant role in SO 2 adsorption for these materials. Oxidation with HNO 3 and/or H 2 SO 4 , followed by heat treatment at 700−925°C to remove carbon−oxygen complexes, resulted in increased SO 2 adsorption for both coal chars and ACFs. This behavior was explained by an increase in the available number of free sites, previously occupied by oxygen and now available for SO 2 adsorption. The use of nitrogen-containing functional groups on ACFs of proper pore size shows promise for further increasing SO 2 adsorption capacities. Knowledge of the relationship among the number of free sites, pore size, and surface chemistry on corresponding SO 2 adsorption should lead to the development of more efficient adsorbents prepared from either coal or ACFs.

Energy and Fuels

Adsorbed natural gas storage with activated carbons made from Illinois coals and scrap tires

Activated carbons for natural gas storage were produced from Illinois bituminous coals (IBC-102 and IBC-106) and scrap tires by physical activation with steam or CO 2 and by chemical activation with KOH, H 3 PO 4 , or ZnCl 2 . The products were characterized for N 2 -BET area, micropore volume, bulk density, pore size distribution, and volumetric methane storage capacity ( V m / V s ). V m / V s values for Illinois coal-derived carbons ranged from 54 to 83 cm 3 /cm 3 , which are 35−55% of a target value of 150 cm 3 /cm 3 . Both granular and pelletized carbons made with preoxidized Illinois coal gave higher micropore volumes and larger V m / V s values than those made without preoxidation. This confirmed that preoxidation is a desirable step in the production of carbons from caking materials. Pelletization of preoxidized IBC-106 coal, followed by steam activation, resulted in the highest V m / V s value. With roughly the same micropore volume, pelletization alone increased V m / V s of coal carbon by 10%. Tire-derived carbons had V m / V s values ranging from 44 to 53 cm 3 /cm 3 , lower than those of coal carbons due to their lower bulk densities. Pelletization of the tire carbons increased bulk density up to 160%. However, this increase was offset by a decrease in micropore volume of the pelletized materials, presumably due to the pellet binder. As a result, V m / V s values were about the same for granular and pelletized tire carbons. Compared with coal carbons, tire carbons had a higher percentage of mesopores and macropores.

Energy and Fuels

Preparation and evaluation of coal-derived activated carbons for removal of mercury vapor from simulated coal combustion flue fases

Coal-derived activated carbons (CDACs) were tested for their suitability in removing trace amounts of vapor-phase mercury from simulated flue gases generated by coal combustion. CDACs were prepared in bench-scale and pilot-scale fluidized-bed reactors with a three-step process, including coal preoxidation, carbonization, and then steam activation. CDACs from high-organicsulfur Illinois coals had a greater equilibrium Hg0 adsorption capacity than activated carbons prepared from a low-organic-sulfur Illinois coal. When a low-organic-sulfur CDAC was impregnated with elemental sulfur at 600 ??C, its equilibrium Hg0 adsorption capacity was comparable to the adsorption capacity of the activated carbon prepared from the high-organicsulfur coal. X-ray diffraction and sulfur K-edge X-ray absorption near-edge structure examinations showed that the sulfur in the CDACs was mainly in organic forms. These results suggested that a portion of the inherent organic sulfur in the starting coal, which remained in the CDACs, played an important role in adsorption of Hg0. Besides organic sulfur, the BET surface area and micropore area of the CDACs also influenced Hg0 adsorption capacity. The HgCl2 adsorption capacity was not as dependent on the surface area and concentration of sulfur in the CDACs as was adsorption of Hg0. The properties and mercury adsorption capacities of the CDACs were compared with those obtained for commercial Darco FGD carbon.

Energy and Fuels

Front Range Infrastructure Resources Project; energy resources activities

Oil, natural gas, and coal (energy resources) have been produced from rocks in the Front Range of Colorado and Wyoming for more than a century, and significant quantities of oil and gas continue to be developed in the study area of the U.S. Geological Survey (USGS) Front Range Infrastructure Resources Project (fig. 1). As an infrastructure resource, energy resources helped to fuel past development of (1) urban areas in the Front Range as well as (2) some of the manufacturing and mining upon which the urban centers were built and thrived. At present, much of the oil and gas extracted from rocks beneath the Front Range urban corridor is used locally; the people living in the urban area provide a need and viable marketplace for these commodities.

Colorado, Wyoming

Impacts to wildlife of wind energy siting and operation in the United States

Electricity from wind energy is a major contributor to the strategy to reduce greenhouse gas emissions from fossil fuel use and thus reduce the negative impacts of climate change. Wind energy, like all power sources, can have adverse impacts on wildlife. After nearly 25 years of focused research, these impacts are much better understood, although uncertainty remains. In this report, we summarize positive impacts of replacing fossil fuels with wind energy, while describing what we have learned and what remains uncertain about negative ecological impacts of the construction and operation of land-based and offshore wind energy on wildlife and wildlife habitat in the U.S. Finally, we propose research on ways to minimize these impacts. TO SUMMARIZE: 1 Environmental and other benefits of wind energy include near-zero greenhouse gas emissions, reductions of other common air pollutants, and little or no water use associated with producing electricity from wind energy. Various scenarios for meeting U.S. carbon emission reduction goals indicate that a four- to five-fold expansion of land-based wind energy from the current 97 gigawatts (GW) by the year 2050 is needed to minimize temperature increases and reduce the risk of climate change to people and wildlife. 2 Collision fatalities of birds and bats are the most visible and measurable impacts of wind energy production. Current estimates suggest most bird species, especially songbirds, are at low risk of population-level impacts. Raptors as a group appear more vulnerable to collisions. Population-level impacts on migratory tree bats are a concern, and better information on population sizes is needed to evaluate potential impacts to these species. Although recorded fatalities of cave-dwelling bat species are typically low at most wind energy facilities, additional mortality from collisions is a concern given major declines in these species due to white-nose syndrome (WNS). Assessments of regional and cumulative fatality impacts for birds and bats have been hampered by the lack of data from areas with a high proportion of the nation’s installed wind energy capacity. Efforts to expand data accessibility from all regions are underway, and this greater access to data along with improvements in statistical estimators should lead to improved impact assessments. 3 Habitat impacts of wind energy development are difficult to assess. An individual wind energy facility may encompass thousands of acres, but only a small percentage of the landscape within the project area is directly transformed. If a project is sited in previously undisturbed habitat, there is concern for indirect impacts, such as displacement of sensitive species. Studies to date indicate displacement of some species, but the long-term population impacts are unknown. 4 Offshore wind energy development in the U.S. is just beginning. Studies at offshore wind facilities in Europe indicate some bird and marine mammal species are displaced from project areas, but substantial uncertainty exists regarding the individual or population-level impacts of this displacement. Bird and bat collisions with offshore turbines are thought to be less common than at terrestrial facilities, but currently the tools to measure fatalities at offshore wind energy facilities are not available. The wind energy industry, state and federal agencies, conservation groups, academia, and scientific organizations have collaborated for nearly 25 years to conduct the research needed to improve our understanding of risk to wildlife and to avoid and minimize that risk. Efforts to reduce the uncertainty about wildlife risk must keep up withthe pace and scale of the need to reduce carbon emissions. This will require focusing our research priorities and increasing the rate at which we incorporate research results into the development and validation of best practices for siting and operating wind energy facilities.

Issues in Ecology

From Projectile Points to Microprocessors - The Influence of Some Industrial Minerals

In the language of economic geology, Earth materials are classified as metallic ores, fuel minerals, gemstones, and industrial minerals. Most people know that metallic ores yield shiny, conductive, ductile elements such as copper, iron, or gold. Most understand that energy-producing coals constitute a fuel mineral. Likewise, dazzling rubies and rare sapphires are universally recognized as gemstones. The fourth group, industrial minerals, is largely unknown to the general public, even though industrial minerals are as essential to daily life as metals and fuel minerals. This report examines the occurrence and practical uses of nine important industrial minerals - constituting just a few of the more than 50 industrial minerals that shape human culture.

Circular

The Global food‐energy‐water nexus

Water availability is a major factor constraining humanity's ability to meet the future food and energy needs of a growing and increasingly affluent human population. Water plays an important role in the production of energy, including renewable energy sources and the extraction of unconventional fossil fuels that are expected to become important players in future energy security. The emergent competition for water between the food and energy systems is increasingly recognized in the concept of the “food‐energy‐water nexus.” The nexus between food and water is made even more complex by the globalization of agriculture and rapid growth in food trade, which results in a massive virtual transfer of water among regions and plays an important role in the food and water security of some regions. This review explores multiple components of the food‐energy‐water nexus and highlights possible approaches that could be used to meet food and energy security with the limited renewable water resources of the planet. Despite clear tensions inherent in meeting the growing and changing demand for food and energy in the 21st century, the inherent linkages among food, water, and energy systems can offer an opportunity for synergistic strategies aimed at resilient food, water, and energy security, such as the circular economy.

Reviews of Geophysics

Fundamental challenges to methane recovery from gas hydrates

The fundamental challenges, the location, magnitude, and feasibility of recovery, which must be addressed to recover methane from dispersed hydrate sources, are presented. To induce dissociation of gas hydrate prior to methane recovery, two potential methods are typically considered. Because thermal stimulation requires a large energy input, it is less economically feasible than depressurization. The new data will allow the study of the effect of pressure, temperature, diffusion, porosity, tortuosity, composition of gas and water, and porous media on gas-hydrate production. These data also will allow one to improve existing models related to the stability and dissociation of sea floor hydrates. The reproducible kinetic data from the planned runs together with sediment properties will aid in developing a process to economically recover methane from a potential untapped hydrate source. The availability of plentiful methane will allow economical and large-scale production of methane-derived clean fuels to help avert future energy crises.

Topics in Catalysis

Land status and federal mineral ownership in the Powder River basin, Wyoming and Montana; a digital data set for geographic information systems

As the Nation's energy resources continue to be examined for development, it is critical that a digital database exist that contains location data for all Federal land and mineral resources. The U.S. Geological Survey (USGS), in cooperation with the Bureau of Land Management (BLM), is collecting these ownership files and compiling them in Environmental Systems Research Institute, Inc. (ESRI) ARC/INFO coverages, to form a standardized data library. A coverage is a digital version of a map in the form of vector data storage. These coverages are combined with models of coal deposits from the USGS National Coal Resource Assessment project, a five-year effort to identify and characterize the coal beds and coal zones that will provide fuel for the Nation’s energy needs during the first quarter of the twenty-first century. Geographic and geologic data layers are integrated in a Geographic Information System (GIS) to answer complex geo-spatial questions concerning coal resource occurrence.

Montana, Wyoming

The history and development of FETAX (ASTM standard guide, E-1439 on conducting the frog embryo teratogenesis Assay-Xenopus)

The energy crisis of the 1970's and 1980's prompted the search for alternative sources of fuel. With development of alternate sources of energy, concerns for biological resources potentially adversely impacted by these alternative technologies also heightened. For example, few biological tests were available at the time to study toxic effects of effluents on surface waters likely to serve as receiving streams for energy-production facilities; hence, we began to use Xenopus laevis embryos as test organisms to examine potential toxic effects associated with these effluents upon entering aquatic systems. As studies focused on potential adverse effects on aquatic systems continued, a test procedure was developed that led to the initial standardization of FETAX. Other .than a limited number of aquatic toxicity tests that used fathead minnows and cold-water fishes such as rainbow trout, X. laevis represented the only other aquatic vertebrate test system readily available to evaluate complex effluents. With numerous laboratories collaborating, the test with X. laevis was refined, improved, and developed as ASTM E-1439, Standard Guide for the Conducting Frog Embryo Teratogenesis Assay-Xenopus (FETAX). Collabrative work in the 1990s yielded procedural enhancements, for example, development of standard test solutions and exposure methods to handle volatile organics and hydrophobic compounds. As part of the ASTM process, a collaborative interlaboratory study was performed to determine the repeatability and reliability of FETAX. Parallel to these efforts, methods were also developed to test sediments and soils, and in situ test methods were developed to address "lab-to-field extrapolation errors" that could influence the method's use in ecological risk assessments. Additionally, a metabolic activation system composed of rat liver microsomes was developed which made FETAX more relevant to mammalian studies.

Conference Paper

Variation in foraging patterns as reflected by floral resources used by male vs female bees of selected species at Badlands National Park, SD

Female and male bees forage for different reasons: females provision nests with pollen appropriate for larval development and consume nectar for energy while males need only fuel their own energetic requirements. The expectation, therefore, is that females should visit fewer floral resource species than males, due to females’ focus on host plant species and their tie to the nest location. We used pollen collected from bees’ bodies and the flowers they were collected on to infer floral resource use in 2010-2012 at Badlands National Park, SD, USA. We collected bees on 24 1-ha plots centered on particular plant species. We compared number of floral species and families (1) associated with individual female and male bees (via generalized linear mixed models) and (2) accumulated by each sex (using rarefaction); and (3) effect of variation between sexes in plant-bee interactions via modularity analyses. Analyses were restricted to bee species with > 5 individuals per sex. Contrary to expectation, female and male bees differed infrequently in the number of floral resources they had visited, both on single foraging bouts and collectively when accumulated across all males and females of a species. When males and females did differ, males visited fewer floral species than females. Generalist and specialist bee species did not differ markedly in floral resource use by females and males. When separated by sex, seven of eleven species occupied different modules than they did when analyzed as a species; most of the bee species were connectors, thus important for stability of the network during perturbations.

South Dakota

Geology, coal quality, and resources of the Antaramut-Kurtan-Dzoragukh coal field, north-central Armenia

The Antaramut-Kurta-Dzoragukh (AKD) coal deposit is a previously unrecognized coal field in north-central Armenia. Coal has been known to exist in the general vicinity since the turn of the century, but coal was thought to be restricted to a small (1 km2) area only near the village of Antaramut. However, through detailed field work and exploratory drilling, this coal deposit has been expanded to at least 20 km2, and thus renamed the Antaramut-Kurtan-Dzoragukh coal field, for the three villages that the coal field encompasses. The entire coal-bearing horizon, a series of tuffaceous sandstones, siltstones, and claystones, is approximately 50 m thick. The AKD coal field contains two coal beds, each greater than 1 m thick, and numerous small rider beds, with a total resource of approximately 31,000,000 metric tonnes. The coals are late Eocene in age, high volatile bituminous in rank, relatively high in ash yield (approximately 40%, as-determined basis) and moderate in sulfur content (approximately 3%, as-determined basis). The two coal beds (No. 1 and No. 2), on a moist, mineral-matter-free basis, have high calorific values of 32.6 MJ/kg (7796 cal/g) and 36.0 MJ/kg (8599 cal/g), respectively. Coal is one of the few indigenous fossil fuel resources occurring in Armenia and thus, the AKD coal field could potentially provide fuel for heating and possibly energy generation in the Armenian energy budget. Published by Elsevier Science B.V.

International Journal of Coal Geology

Identifying alternate pathways for climate change to impact inland recreational fishers

Fisheries and human dimensions literature suggests that climate change influences inland recreational fishers in North America through three major pathways. The most widely recognized pathway suggests that climate change impacts habitat and fish populations (e.g., water temperature impacting fish survival) and cascades to impact fishers. Climate change also impacts recreational fishers by influencing environmental conditions that directly affect fishers (e.g., increased temperatures in northern climates resulting in extended open water fishing seasons and increased fishing effort). The final pathway occurs from climate change mitigation and adaptation efforts (e.g., refined energy policies result in higher fuel costs, making distant trips more expensive). To address limitations of past research (e.g., assessing climate change impacts for only one pathway at a time and not accounting for climate variability, extreme weather events, or heterogeneity among fishers), we encourage researchers to refocus their efforts to understand and document climate change impacts to inland fishers.

Fisheries

Determining fine-scale use and movement patterns of diving bird species in federal waters of the Mid-Atlantic United States using satellite telemetry

Offshore wind energy development in the United States is projected to expand in the upcoming decades to meet growing energy demands and reduce fossil fuel emissions. There is particular interest in commercial offshore wind development within Federal waters (i.e., > 3 nautical miles from shore) of the mid-Atlantic. In order to understand the potential for adverse effects on marine birds in this area, information on distribution and behavior (e.g., flight pathways, timing, etc.) is required for a broad suite of species. In areas where offshore wind development is likely to occur, such information can be used to identify high use areas during critical life stages, which can inform the siting of offshore facilities. It can also be used to provide baseline data for understanding broad changes in distributions that occur after offshore wind developments are constructed in a specific area.

Report

International Organizations and Programs for Wildlife Conservation

Historically, private non-governmental entities in the developed world took interest in wildlife in developing nations. Nineteenth and early twentieth century explorers of Africa, Asia, and South America reported fascinating encounters with magnificent species that were previously cryptic or unknown (Robinson et al. 2017). Organizations such as the Royal Geographical Society in the United Kingdom, a sponsor of Charles Darwin’s expedition, the Boone and Crockett Club in North America, and numerous museums in the United States and Europe, sponsored chronicled expeditions to remote places under the goal of discovery and collection. Concurrent with the quest for discovery of wild places and species new to science was the drive to find and secure timber, mineral, energy, and other resources to fuel the growing demands of development brought on by the Industrial Revolution (Lucas 2009, Stearns 2013). This led to exploitation, and overexploitation, which led to growing concerns over the loss of species, including species not yet known to western science. During the latter half of the twentieth century, in response to these concerns, private non-governmental organizations formed to promote conservation through science, advocacy, and technical assistance. These organizations vary from working independently, to forming collaborations across the public and private sphere. Our objective in this chapter is to outline some of the major conventions, major organizations, and programs that promote engagement in wildlife conservation and management at the international level.

Book chapter

Spring migration of waterfowl in the Northern Hemisphere: a management and conservation perspective

Spring migration is a key part of the annual cycle for waterfowl populations in the northern hemisphere, due to its temporal proximity to the breeding season and because resources may be limited at one or more staging sites. Research based on field observations during spring lags behind other periods of the year, despite the potential for fitness consequences through diminished survival or cross-seasonal effects of conditions experienced during migration. Consequently, conservation strategies for waterfowl on spring migration are often only refined versions of practices used during autumn and winter. Here we discuss the current state of knowledge of habitat requirements for waterfowl at their spring migratory sites and the intrinsic and extrinsic factors that lead to variability in those requirements. The provision of plant foods has become the main conservation strategy during spring because of the birds’ energy requirements at this time, not only to fuel migration but to facilitate early clutch formation on arrival at the breeding grounds. Although energy sources are important to migrants, there is little evidence on the extent to which the availability of carbohydrate-based food is limiting for many migratory waterfowl populations. Such limitation is relatively unlikely among populations that exploit agricultural grain during migration (e.g. arctic-nesting geese), suggesting that conservation strategies for these populations may be misplaced. In general, however, we found few cases in which an ecological understanding of spring-migrating waterfowl was sufficient to indicate true resource limitation during migration, and still fewer cases where conservation efforts ameliorated these limitations. We propose a framework that aims to address knowledge gaps and apply empirical research results to conservation strategies based on documented limitations and associated fitness impacts on migrating waterfowl. Such a strategy would improve allocation of scarce conservation resources during spring migration and greatly improve ecological understanding of migratory waterfowl and their habitats in the northern hemisphere.

Wildfowl

Entropy, materials, and posterity

Materials and energy are the interdependent feedstocks of economic systems, and thermodynamics is their moderator. It costs energy to transform the dispersed minerals of Earth's crust into ordered materials and structures. And it costs materials to collect and focus the energy to perform work - be it from solar, fossil fuel, nuclear, or other sources. The greater the dispersal of minerals sought, the more energy is required to collect them into ordered states. But available energy can be used once only. And the ordered materials of industrial economies become disordered with time. They may be partially reordered and recycled, but only at further costs in energy. Available energy everywhere degrades to bound states and order to disorder - for though entropy may be juggled it always increases. Yet industry is utterly dependent on low entropy states of matter and energy, while decreasing grades of ore require ever higher inputs of energy to convert them to metals, with ever increasing growth both of entropy and environmental hazard. Except as we may prize a thing for its intrinsic qualities - beauty, leisure, love, or gold - low-entropy is the only thing of real value. It is worth whatever the market will bear, and it becomes more valuable as entropy increases. It would be foolish of suppliers to sell it more cheaply or in larger amounts than their own enjoyment of life requires, whatever form it may take. For this reason, and because of physical constraints on the availability of all low-entropy states, the recent energy crises is only the first of a sequence of crises to be expected in energy and materials as long as current trends continue. The apportioning of low-entropy states in a modern industrial society is achieved more or less according to the theory of competitive markets. But the rational powers of this theory suffer as the world grows increasingly polarized into rich, over-industrialized nations with diminishing resource bases and poor, supplier nations with little industry. The theory also discounts posterity, the more so as population density and percapita rates of consumption continue to grow. A new social, economic, and ecologic norm that leads to population control, conservation, and an apportionment of low-entropy states across the generations is needed to assure to posterity the options that properly belong to it as an important but voiceless constituency of the collectivity we call mankind. ?? 1977 Ferdinand Enke Verlag Stuttgart.

Geologische Rundschau