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At least 109 records · Page 6Linked to original sources

Combining scanning electron microscopy, X-ray diffraction, and X-ray fluorescence to characterize shear zones at the Pogo gold deposit, Alaska

This study employs a multi-method analytical approach to characterize the mineralogical, geochemical, and textural properties of fault rocks from the Pogo gold mine in the Yukon-Tanana Upland, central Alaska. Specifically, we examine cataclasites, to document the structural and geochemical evolution of shear zones and their associations with gold mineralization. To investigate the shear zone, we integrate portable X-ray fluorescence (pXRF), scanning electron microscopy-based automated mineralogy (SEM-AM), X-ray diffraction (XRD), and high-resolution micro-X-ray fluorescence (micro-XRF) mapping. These methods collectively provide insights into bulk and trace element chemistry, mineralogical composition, and deformation-related textures across multiple scales. Handheld pXRF enables rapid geochemical screening, guiding SEM-AM and XRD analyses to ensure consistent mineralogical interpretation. X-ray diffraction identifies and quantifies crystalline phases, while SEM-AM produces high-resolution mineral maps, revealing mineral abundances, grain-scale textures, and gold associations. Micro-XRF mapping further refines our understanding by showing visual trace element distributions at sub-millimetre resolution. By integrating these techniques, we improve our understanding of the nature and geochemistry of Pogo shear zones, their role in gold mineralization, and support metallurgical processing strategies. This approach enhances exploration models and resource characterization for structurally complex gold deposits.

Alaska

Identifying spawning behavior in Pacific halibut ( Hippoglossus stenolepis ) using electronic tags

Identifying spawning behavior in Pacific halibut, Hippoglossus stenolepis, is particularly challenging because they occupy a deep, remote environment during the spawning season. To identify spawning events, a method is needed in which direct observation by humans is not employed. Spawning behavior of seven other flatfish, species has been directly observed in their natural environment by investigators using SCUBA. All of these flatfish species display almost identical spawning behavior that follows a routine. Therefore, it is reasonable to believe that this spawning behavior occurs in other flatfish species, including Pacific halibut. As part of a larger study, we recaptured two Pacific halibut on which Pop-up Archival Transmitting (PAT) tags had been attached during the winter spawning season. Because the tags were physically retrieved, we were able to collect minute-by-minute depth records for 135 and 155 days. We used these depth data to tentatively identify spawning events. On seven separate occasions between 20 January 2001 and 9 February 2001, one fish displayed a conspicuous routine only seen during the spawning season of Pacific halibut and the routine parallels the actions of other spawning flatfish directly observed by humans using SCUBA. Therefore, we propose this routine represents spawning behavior in Pacific halibut. The second tagged fish did not display the conspicuous routine, thus challenging the assumption that Pacific halibut are annual spawners. PAT tags may prove to be a useful tool for identifying spawning events of Pacific halibut, and that knowledge may be used for improved management in the future.

Environmental Biology of Fishes

Temporal variations in parameters reflecting terminal-electron-accepting processes in an aquifer contaminated with waste fuel and chlorinated solvents

A fundamental issue in aquifer biogeochemistry is the means by which solute transport, geochemical processes, and microbiological activity combine to produce spatial and temporal variations in redox zonation. In this paper, we describe the temporal variability of TEAP conditions in shallow groundwater contaminated with both waste fuel and chlorinated solvents. TEAP parameters (including methane, dissolved iron, and dissolved hydrogen) were measured to characterize the contaminant plume over a 3-year period. We observed that concentrations of TEAP parameters changed on different time scales and appear to be related, in part, to recharge events. Changes in all TEAP parameters were observed on short time scales (months), and over a longer 3-year period. The results indicate that (1) interpretations of TEAP conditions in aquifers contaminated with a variety of organic chemicals, such as those with petroleum hydrocarbons and chlorinated solvents, must consider additional hydrogen-consuming reactions (e.g., dehalogenation); (2) interpretations must consider the roles of both in situ (at the sampling point) biogeochemical and solute transport processes; and (3) determinations of microbial communities are often necessary to confirm the interpretations made from geochemical and hydrogeological measurements on these processes.

Michigan

Formation of ferromanganese crusts on northwest intertropical Pacific seamounts: Electron photomicrography and microprobe chemistry

Seven ferromanganese crusts from the northwest intertropical Pacific seamounts were analyzed for photomicroscopic growth structures, microprobe chemistry, and ages based on Co-chronometer growth rate. The crusts on the Marshall Islands seamounts are thick and ale divided into phosphatized lower older and nonphosphatized upper younger growth generations: the older crust consists of compact laminations and columns impregnated with carbonate fluoapatite (CFA), whereas the younger crust is characterized by porous botryoids and columns of ??-MnO2 and Fe oxyhydroxide. The crusts on the Federated States of Micronesia (FSM) and Palau Islands seamounts are thin and are often incorporated with inorganic opal-A in the uppermost part, comprising the younger generation. Some crusts show scours and fractures. Although the growth of crusts has been often interrupted by mass failure of slope sediments, the crusts on the Marshall Islands seamounts are estimated to have grown at rate of about 3 mm/Ma since the middle Eocene and to have been phosphatized in the late Oligocene during the host seamounts were located beneath the equatorial zone of high productivity. Prolonged infiltration of the oxygen minimum zone (OMZ) water into shallower water older crusts redistributed crust composition by precipitating CFA, enriching subsequent amounts of Mn and Ni, and removing some Co. The younger crust has formed at slower rate (about 2 mm/Ma) under the stronger influence of bottom-water circulation in the north of the equatorial zone, concentrating abundant Co. In the uppermost part of some crusts, siliceous skeletons transform with burial to inorganic opal-A and Si-rich Fe oxyhydroxide, suggesting that biosilica diagenesis can enhance crust growth. (C) 2000 Elsevier Science B.V.

Marine Geology

Transformations of TNT and related aminotoluenes in groundwater aquifer slurries under different electron-accepting conditions

The transport and fate of pollutants is often governed by both their tendency to sorb as well as their susceptibility to biodegradation. We have evaluated these parameters for 2,4,6-trinitrotoluene (TNT) and several biodegradation products. Slurries of aquifer sediment and groundwater depleted TNT at rates of 27, 7.7 and 5.9 μM day −1 under methanogenic, sulfate-reducing and nitrate-reducing conditions, respectively. Abiotic losses of TNT were determined in autoclaved controls. Abiotic TNT loss and subsequent transformation of the products was also observed. These transformations were especially important during the first step in the reduction of TNT. Subsequent abiotic reactions could account for all of the transformations observed in bottles which were initially nitrate-reducing. Other controls removed TNT reduction products at much slower rates than slurries containing live organisms. 2-Amino-4,6-dinitrotoluene was produced in all slurries but disappeared in methanogenic and in sulfate-reducing slurries within several weeks. This compound was converted to 2,4-diamino-6-nitrotoluene in all slurries with subsequent removal of the latter from methanogenic and sulfate-reducing slurries, while it persisted in autoclaved controls and in the nitrate-reducing slurries. Aquifer slurries incubated with either 2,4- or 2,6-diaminotoluene showed losses of these compounds relative to autoclaved controls under nitrate-reducing conditions but not under sulfate-reducing or methanogenic conditions. These latter compounds are important as reduced intermediates in the biodegradation of dinitrotoluenes and as industrial chemicals. In experiments to examine sorption, exposure to landfill sediment resulted in losses of approximately 15% of diaminotoluene isomers and 25% of aminodinitrotoluene isomers from initial solution concentrations within 24 h. Isotherms confirmed that the diaminotoluenes were least strongly sorbed and the amino-dinitrotoluenes most strongly sorbed to this sediment, while TNT sorption capacity was intermediate. In our studies, 2,4,6-triaminotoluene sorption capacity was indeterminate due to its chemical instability. Coupled with biodegradation information, isotherms help describe the likelihood of contaminant removal, persistence, and movement at impacted sites.

Journal of Industrial Microbiology and Biotechnolo

Moving at the speed of flight: Dabbling duck-movement rates and the relationship with electronic tracking interval

Context. Effective wildlife management requires information on habitat and resource needs, which can be estimated with movement information and modelling energetics. One necessary component of avian models is flight speeds at multiple temporal scales. Technology has limited the ability to accurately assess flight speeds, leading to estimates of questionable accuracy, many of which have not been updated in almost a century. Aims. We aimed to update flight speeds of ducks, and differentiate between migratory and non-migratory flight speeds, a detail that was unclear in previous estimates. We also analysed the difference in speeds of migratory and non-migratory flights, and quantified how data collected at different temporal intervals affected estimates of flight speed. Methods. We tracked six California dabbling duck species with high spatio-temporal resolution GPS–GSM transmitters, calculated speeds of different flight types, and modelled how estimates varied by flight and data interval (30 min to 6 h). Key results. Median migratory speeds were faster (but non-significant) for the larger mallard (Anas platyrhynchos; 82.5 km h–1), northern pintail (Anas acuta; 79.0 km h–1) and gadwall (Mareca strepera; 70.6 km h–1), than the smaller-bodied northern shoveler (Spatula clypeata; 65.7 km h–1), cinnamon teal (Spatula cyanoptera; 63.5 km h–1) and American wigeon (Mareca Americana; 52 km h–1). Migratory flights were faster than non-migratory flights for all species and speeds were consistently slower with an increasing data interval. Implications. The need to balance time and energy requirements may drive different speeds for migratory and non-migratory flights. Lower speeds at longer intervals are likely to be due to a greater proportion of ‘loafing’ time included in flighted segments, demonstrating that data acquired at different intervals provide a means to evaluate and estimate behaviours that influence speed estimation. Shorter-interval data should be the most accurate, but longer-interval data may be easier to collect over lengthier timeframes, so it may be expedient to trade-off a degree of accuracy in broad-scale studies for the larger dataset. Our updated flight speeds for dabbling duck species can be used to parameterise and validate energetics models, guide management decisions regarding optimal habitat distribution, and, ultimately, improve conservation management of wetlands for waterfowl.

Wildlife Research

Electronic archival tags provide first glimpse of bathythermal habitat use by free-ranging adult lake sturgeon Acipenser fulvescens

Information on lake sturgeon ( Acipenser fulvescens ) depth and thermal habitat use during non-spawning periods is unavailable due to the difficulty of observing lake sturgeon away from shallow water spawning sites. In 2002 and 2003, lake sturgeon captured in commercial trap nets near Sarnia, Ontario were implanted with archival tags and released back into southern Lake Huron. Five of the 40 tagged individuals were recaptured and were at large for 32, 57, 286, 301, and 880 days. Temperatures and depths recorded by archival tags ranged from 0 to 23.5 ºC and 0.1 to 42.4 m, respectively. For the three lake sturgeon that were at large for over 200 days, temperatures occupied emulated seasonal fluctuations. Two of these fish occupied deeper waters during winter than summer while the other occupied similar depths during non-spawning periods. This study provides important insight into depth and thermal habitat use of lake sturgeon throughout the calendar year along with exploring the feasibility of using archival tags to obtain important physical habitat attributes during non-spawning periods.

Lake Huron

Electronic tags and genetics explore variation in migrating steelhead kelts (oncorhynchus mykiss), Ninilchik river, Alaska

Acoustic and archival tags examined freshwater and marine migrations of postspawn steelhead kelts (Oncorhynchus mykiss) in the Ninilchik River, Alaska, USA. Postspawn steelhead were captured at a weir in 2002-2005. Scale analysis indicated multiple migratory life histories and spawning behaviors. Acoustic tags were implanted in 99 kelts (2002-2003), and an array of acoustic receivers calculated the average speed of outmigration, timing of saltwater entry, and duration of residency in the vicinity of the river mouth. Ocean migration data were recovered from two archival tags implanted in kelts in 2004 (one male and one female). Archival tags documented seasonal differences in maximum depth and behavior with both fish spending 97% of time at sea <6 m depth (day and night). All study fish were double tagged with passive integrated transponder (PIT) tags implanted in the body cavity. Less than 4% of PIT tags were retained in postspawn steelhead. Molecular genetics demonstrated no significant differences in genetic population structure across years or among spawning life history types, suggesting a genetically panmictic population with highly diverse life history characteristics in the Ninilchik River.

Canadian Journal of Fisheries and Aquatic Sciences

Scanning electron microscope observations of sublimates from Merapi Volcano, Indonesia

Sublimates were sampled from high-temperature (up to 800°C) fumaroles at Merapi volcano, Indonesia in January 1984. Sampling is accomplished by inserting silica tubes into high-temperature vents. Volcanic gas flows through the tubes and sublimates precipitate on the inner walls in response to the temperature gradient. With decreasing temperature (800–500°C) in the tubes, there are five sublimate zones: 1) cristobalite, magnetite, and halite; 2) halite, sylvite, K-Ca sulfate (K 2 Ca[SO 4 ] 2 ), acmite, wollastonite, and pyrite; 3) halite, sylvite, galena, Pb-Bi sulfide, aphthitalite, sphalerite, and Cs-K sulfate; 4) halite, sylvite, galena, PbKCl 3 , aphthitalite, and Na-K-Fe sulfate ([Na, K] 2 Fe[SO 4 ]Cl 2 ); and 5) halite, sylvite, galena, PbKCl 3 , and various sulfates of Pb, Cu, and Zn. Texturally, the sublimate phases grade from large, well-formed crystals at their highest-temperature occurrence to more numerous, smaller crystals that are less perfect at lower temperatures. These changes imply that the crystal nucleation and growth rates increase and decrease, respectively, as temperature decreases. Several of the sublimate phases also exhibit highly anisotropic morphologies (whiskers, platelets, spheres), especially below their highest temperature of deposition. Overall, the textural data suggest that the gas is saturated or slightly supersaturated with the phases at their hottest occurrence, but that the gas becomes increasingly supersaturated with the phases at lower temperatures. The anisotropic morphologies probably form because the crystals grow toward more supersaturated conditions in the center of the tube. The gas fails to maintain equilibrium with the precipitating sublimates because the high velocity of the carrier gas prevents complete mass transfer from the gas stream to the tube walls.

Merapi Volcano

Ground-water-quality data in Pennsylvania: A compilation of computerized [electronic] databases, 1979-2004

This study, by the U.S. Geological Survey (USGS) in cooperation with the Pennsylvania Department of Environmental Protection (PADEP), provides a compilation of ground-water-quality data for a 25-year period (January 1, 1979, through August 11, 2004) based on water samples from wells. The data are from eight source agencies唯orough of Carroll Valley, Chester County Health Department, Pennsylvania Department of Environmental Protection-Ambient and Fixed Station Network, Montgomery County Health Department, Pennsylvania Drinking Water Information System, Pennsylvania Department of Agriculture, Susquehanna River Basin Commission, and the U.S. Geological Survey. The ground-water-quality data from the different source agencies varied in type and number of analyses; however, the analyses are represented by 12 major analyte groups:biological (bacteria and viruses), fungicides, herbicides, insecticides, major ions, minor ions (including trace elements), nutrients (dominantly nitrate and nitrite as nitrogen), pesticides, radiochemicals (dominantly radon or radium), volatile organic compounds, wastewater compounds, and water characteristics (dominantly field pH, field specific conductance, and hardness). A summary map shows the areal distribution of wells with ground-water-quality data statewide and by major watersheds and source agency. Maps of 35 watersheds within Pennsylvania are used to display the areal distribution of water-quality information. Additional maps emphasize the areal distribution with respect to 13 major geolithologic units in Pennsylvania and concentration ranges of nitrate (as nitrogen). Summary data tables by source agency provide information on the number of wells and samples collected for each of the 35 watersheds and analyte groups. The number of wells sampled for ground-water-quality data varies considerably across Pennsylvania. Of the 8,012 wells sampled, the greatest concentration of wells are in the southeast (Berks, Bucks, Chester, Delaware, Lancaster, Montgomery, and Philadelphia Counties), in the vicinity of Pittsburgh, and in the northwest (Erie County). The number of wells sampled is relatively sparse in south-central (Adams, Cambria, Cumberland, and Franklin Counties), central (Centre, Indiana, and Snyder Counties), and north-central (Bradford, Potter, and Tioga Counties) Pennsylvania. Little to no data are available for approximately one-third of the state. Water characteristics and nutrients were the most frequently sampled major analyte groups; approximately 21,000 samples were collected for each group. Major and minor ions were the next most-frequently sampled major analyte groups; approximately 17,000 and 12,000 samples were collected, respectively. For the remaining eight major analyte groups, the number of samples collected ranged from a low of 307 samples (wastewater compounds) to a high of approximately 3,000 samples (biological). The number of samples that exceeded a maximum contaminant level (MCL) or secondary maximum contaminant level (SMCL) by major analyte group also varied. Of the 2,988 samples in the biological analyte group, 53 percent had water that exceeded an MCL. Almost 2,500 samples were collected and analyzed for volatile organic compounds; 14 percent exceeded an MCL. Other major analyte groups that frequently exceeded MCLs or SMCLs included major ions (17,465 samples and a 33.9 percent exceedence), minor ions (11,905 samples and a 17.1 percent exceedence), and water characteristics (21,183 samples and a 20.3 percent exceedence). Samples collected and analyzed for fungicides, herbicides, insecticides, and pesticides (4,062 samples), radiochemicals (1,628 samples), wastewater compounds (307 samples), and nutrients (20,822 samples) had the lowest exceedences of 0.3, 8.4, 0.0, and 8.8 percent, respectively.

Pennsylvania