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At least 109 records · Page 6Linked to original sources

Surface complexation of carboxylate adheres Cryptosporidium parvum öocysts to the hematite-water interface

The interaction of viable Cryptosporidium parvum öocysts at the hematite (α-Fe 2 O 3 )−water interface was examined over a wide range in solution chemistry using in situ attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy. Spectra for hematite-sorbed öocysts showed distinct changes in carboxylate group vibrations relative to spectra obtained in the absence of hematite, indicative of direct chemical bonding between carboxylate groups and Fe metal centers of the hematite surface. The data also indicate that complexation modes vary with solution chemistry. In NaCl solution, öocysts are bound to hematite via monodentate and binuclear bidentate complexes. The former predominates at low pH, whereas the latter becomes increasingly prevalent with increasing pH. In a CaCl 2 solution, only binuclear bidentate complexes are observed. When solution pH is above the point of zero net proton charge (PZNPC) of hematite, öocyst surface carboxylate groups are bound to the mineral surface via outer-sphere complexes in both electrolyte solutions.

Environmental Science & Technology

Complex earthquake rupture and local tsunamis

In contrast to far-field tsunami amplitudes that are fairly well predicted by the seismic moment of subduction zone earthquakes, there exists significant variation in the scaling of local tsunami amplitude with respect to seismic moment. From a global catalog of tsunami runup observations this variability is greatest for the most frequently occurring tsunamigenic subduction zone earthquakes in the magnitude range of 7 < M w < 8.5. Variability in local tsunami runup scaling can be ascribed to tsunami source parameters that are independent of seismic moment: variations in the water depth in the source region, the combination of higher slip and lower shear modulus at shallow depth, and rupture complexity in the form of heterogeneous slip distribution patterns. The focus of this study is on the effect that rupture complexity has on the local tsunami wave field. A wide range of slip distribution patterns are generated using a stochastic, self-affine source model that is consistent with the falloff of far-field seismic displacement spectra at high frequencies. The synthetic slip distributions generated by the stochastic source model are discretized and the vertical displacement fields from point source elastic dislocation expressions are superimposed to compute the coseismic vertical displacement field. For shallow subduction zone earthquakes it is demonstrated that self-affine irregularities of the slip distribution result in significant variations in local tsunami amplitude. The effects of rupture complexity are less pronounced for earthquakes at greater depth or along faults with steep dip angles. For a test region along the Pacific coast of central Mexico, peak nearshore tsunami amplitude is calculated for a large number ( N = 100) of synthetic slip distribution patterns, all with identical seismic moment ( M w = 8.1). Analysis of the results indicates that for earthquakes of a fixed location, geometry, and seismic moment, peak nearshore tsunami amplitude can vary by a factor of 3 or more. These results indicate that there is substantially more variation in the local tsunami wave field derived from the inherent complexity subduction zone earthquakes than predicted by a simple elastic dislocation model. Probabilistic methods that take into account variability in earthquake rupture processes are likely to yield more accurate assessments of tsunami hazards.

Journal of Geophysical Research B: Solid Earth

Exhumation of the Coyote Mountains metamorphic core complex (Arizona): Implications for orogenic collapse of the southern North American Cordillera.

A microstructural and thermochronometric analysis of the Coyote Mountains detachment shear zone provides new insight into the collapse of the southern North American Cordillera. The Coyote Mountains is a metamorphic core complex that makes up the northern end of the Baboquivari Mountains in southern Arizona. The Baboquivari Mountains records several episodes of crustal shortening and thickening and regional metamorphism, including the Late Cretaceous‐early Paleogene Laramide orogeny which is locally expressed by the Baboquivari thrust fault. Thrusting and shortening were accompanied by magmatic activity recorded by intrusion of Paleocene muscovite‐biotite‐garnet peraluminous granites such as the ~58 Ma Pan Tak Granite, interpreted as anatectic melts representing the culmination of the Laramide orogeny. Following Laramide crustal shortening, the northern end of the Baboquivari Mountains was exhumed along a top‐to‐the‐north detachment shear zone, which resulted in the formation of the Coyote Mountains metamorphic core complex. Structural and microstructural analysis show that the detachment shear zone evolved under a strong component of noncoaxial (simple shear) deformation, at deformation conditions of ~450 ± 50°C, under a differential stress of ~60 MPa, and a strain rate of 1.5 × 10 −11 to 5.0 × 10 −13 s −1 at depth of ~11–14 km. Detailed 40 Ar/ 39 Ar geochronology of biotite and muscovite, in the context of the deformation conditions determined by quartz microstructures, suggests that the mylonitization associated with the formation of the Coyote Mountains metamorphic core complex started at ~29 Ma (early Oligocene). Apatite fission track ages indicate that the footwall of the Coyote Mountains metamorphic core complex experienced rapid exhumation to the upper crust by ~24 Ma. The fact that mylonitization and rapid extensional exhumation postdates Laramide thickening by ~30 Myr indicates that crustal thickness alone was insufficient to initiate extensional tectonic and required an additional driving force. The timing of mylonitization and rapid exhumation documented here and in other MCCs are consistent with the hypothesis that slab rollback and the effect of a slab window trailing the Mendocino Triple Junction have been critical in driving the development of the MCCs of the southwest.

British Columbia, Washington, Oregon, California,

Precise U‐Pb ages of Duluth Complex and related mafic intrusions, northeastern Minnesota: Geochronological insights to physical, petrogenetic, paleomagnetic, and tectonomagmatic processes associated with the 1.1 Ga Midcontinent Rift System

Precise resolution of the timing of igneous activity is crucial to understanding the dynamic processes associated with continental rifting. Mafic intrusive rocks constitute a major portion of the exposed 1100 Ma (Keweenawan) Midcontinent Rift system in northeastern Minnesota; however, prior to this study, geochronological data were insufficient to allow rigorous interpretation of intrusive histories and their relationships to extrusive suites. Eight anorthositic and gabbroic intrusives were chosen to represent both the temporal and spatial ranges of plutonic activity that formed the Duluth Complex and related mafic intrusions. U‐Pb isotopic analyses from zircons and baddeleyites result in U‐Pb concordant ages with little or no ambiguity introduced by inherited components, Pb loss or common Pb. The earliest Keweenawan plutonism exposed in Minnesota occurs along the northeastern flank of the Duluth Complex as a series of layered gabbros (Nathan's layered series) emplaced at 1106.9 ± 0.6 Ma. This sequence of gabbro sheets shares temporal, spatial, and compositional similarities with the nearby Logan sills in Ontario. Four Duluth Complex anorthositic and troctolitic series samples from widely separated areas have unresolvable ages between 1099.3 ± 0.3 and 1098.6 ± 0.5 Ma, indicating a very short duration for peak intrusive activity (0.5–1 m.y.). The unresolvable ages between anorthositic and troctolitic plutons suggest that these two magma series are more closely related than previously modeled and argue strongly for the need to reexamine their fundamental petrogenetic relationships. These dates also imply that the major reverse‐to‐normal magnetic polarity switch, used throughout the rift system as an important correlation tool, occurred prior to 1099 Ma. This date is several million years earlier than previously suspected and emphasizes the need for further paleomagnetic and geochronological data from the overlying volcanics. Much of the hypabyssal intrusive suite within the volcanic pile overlying Duluth Complex plutons may be significantly younger than the main pulse of plutonic activity. Two hypabyssal bodies, the Sonju Lake intrusion and gabbro at Silver Bay, were emplaced at 1096.1 ± 0.8 Ma and 1095.8 ± 1.2 Ma, respectively. Dates reported here and in previous studies support the concept of episodic tectonomagmatic rift development where magmatism was apparently concentrated in episodes of short duration (<1–3 m.y.) interspersed with longer hiatuses (2–8 m.y.).

Michigan, Minnesota, Ontario, Wisconsin

The complex frequencies of long-period seismic events as probes of fluid composition beneath volcanoes

Long-period (LP) events have been widely observed in relation to magmatic and hydrothermal activities in volcanic areas. LP waveforms characterized by their harmonic signature have been interpreted as oscillations of a fluid-filled resonator, and mixtures of liquid and gas in the form of bubbly liquids have been mainly assumed for the fluid. To investigate the characteristic properties of the resonator system, we analyse waveforms of LP events observed at four different volcanoes in Hawaii, Alaska, Colombia and Japan using a newly developed spectral method. This method allows an estimation of the complex frequencies of decaying sinusoids based on an autoregressive model. The results of our analysis show a wide variety of Q factors, ranging from tens to several hundred. We compare these complex frequencies with those predicted by the fluid-filled crack model for various mixtures of liquid, gas and ash. Although the oscillations of LP events with Q smaller than 50 can be explained by various combinations of liquids and gases, we find that ash-laden gases are required to explain long-lasting oscillations with Q larger than 100. The complex frequencies of LP events yield useful information on the types of fluids. Temporal and spatial variations of the complex frequencies can be used as probes of fluid composition beneath volcanoes.

Geophysical Journal International

Kelp-forest dynamics controlled by substrate complexity

The factors that determine why ecosystems exhibit abrupt shifts in state are of paramount importance for management, conservation, and restoration efforts. Kelp forests are emblematic of such abruptly shifting ecosystems, transitioning from kelp-dominated to urchin-dominated states around the world with increasing frequency, yet the underlying processes and mechanisms that control their dynamics remain unclear. Here, we analyze four decades of data from biannual monitoring around San Nicolas Island, CA, to show that substrate complexity controls both the number of possible (alternative) states and the velocity with which shifts between states occur. The superposition of community dynamics with reconstructions of system stability landscapes reveals that shifts between alternative states at low-complexity sites reflect abrupt, high-velocity events initiated by pulse perturbations that rapidly propel species across dynamically unstable state–space. In contrast, high-complexity sites exhibit a single state of resilient kelp–urchin coexistence. Our analyses suggest that substrate complexity influences both top-down and bottom-up regulatory processes in kelp forests, highlight its influence on kelp-forest stability at both large (island-wide) and small (<10 m) spatial scales, and could be valuable for holistic kelp-forest management.

PNAS

Eruptive stratigraphy of the Tatara-San Pedro complex, 36°S, sourthern volcanic zone, Chilean Andes: Reconstruction method and implications for magma evolution at long-lived arc volcanic centers

The Quaternary Tatara–San Pedro volcanic complex (36°S, Chilean Andes) comprises eight or more unconformity-bound volcanic sequences, representing variably preserved erosional remnants of volcanic centers generated during ∼930 ky of activity. The internal eruptive histories of several dominantly mafic to intermediate sequences have been reconstructed, on the basis of correlations of whole-rock major and trace element chemistry of flows between multiple sampled sections, but with critical contributions from photogrammetric, geochronologic, and paleomagnetic data. Many groups of flows representing discrete eruptive events define internal variation trends that reflect extrusion of heterogeneous or rapidly evolving magma batches from conduit–reservoir systems in which open-system processes typically played a large role. Long-term progressive evolution trends are extremely rare and the magma compositions of successive eruptive events rarely lie on precisely the same differentiation trend, even where they have evolved from similar parent magmas by similar processes. These observations are not consistent with magma differentiation in large long-lived reservoirs, but they may be accommodated by diverse interactions between newly arrived magma inputs and multiple resident pockets of evolved magma and/or crystal mush residing in conduit-dominated subvolcanic reservoirs. Without constraints provided by the reconstructed stratigraphic relations, the framework for petrologic modeling would be far different. A well-established eruptive stratigraphy may provide independent constraints on the petrologic processes involved in magma evolution—simply on the basis of the specific order in which diverse, broadly cogenetic magmas have been erupted. The Tatara–San Pedro complex includes lavas ranging from primitive basalt to high-SiO 2 rhyolite, and although the dominant erupted magma type was basaltic andesite (∼52–55 wt % SiO 2 ) each sequence is characterized by unique proportions of mafic, intermediate, and silicic eruptive products. Intermediate lava compositions also record different evolution paths, both within and between sequences. No systematic long-term pattern is evident from comparisons at the level of sequences. The considerable diversity of mafic and evolved magmas of the Tatara–San Pedro complex bears on interpretations of regional geochemical trends. The variable role of open-system processes in shaping the compositions of evolved Tatara–San Pedro complex magmas, and even some basaltic magmas, leads to the conclusion that addressing problems such as arc magma genesis and elemental fluxes through subduction zones on the basis of averaged or regressed reconnaissance geochemical datasets is a tenuous exercise. Such compositional indices are highly instructive for identifying broad regional trends and first-order problems, but they should be used with extreme caution in attempts to quantify processes and magma sources, including crustal components, implicated in these trends.

Andes Mountains, Tatara-San Pedro Volcanic Complex

Low-complexity floodplain inundation model performs well for ecological and management applications in a large river ecosystem

Flooding is a dominant physical process that drives the form and function of river-floodplain ecosystems. Efficiently characterizing flooding dynamics can be challenging, especially over geographically broad areas or at spatial and temporal scales relevant for ecosystem management activities. Here, we empirically evaluated a low-complexity geospatial model of floodplain inundation in six study segments of the Upper Mississippi River System (UMRS) by pairing spatially extensive, temporally limited and spatially limited, temporally extensive sampling designs. We found little evidence of systematic bias in model performance although discrepancies between model predictions and empirical data did occur locally. Assessments of model predictions revealed low segment-wide discrepancies of wetted extent under contrasting flow conditions and agreement for inundation event detection and duration. Model performance for predicting event frequency and duration was similar among sites expected to exhibit contrasting patterns of hydrologic connectivity with the main channel. Our results suggest that low-complexity models can efficiently characterize a critical physical process across geographically broad, complex river-floodplain ecosystems. Such tools have the potential for advancing scientific understanding of landscape-scale ecological patterns and for prioritizing management actions in large, complex river-floodplain ecosystems like the UMRS.

Illinois, Iowa, Minnesota, Missouri, Wisconsin

Complexity versus certainty in understanding species’ declines

Aim Our understanding of and ability to predict species declines is limited, despite decades of study. We sought to expand our understanding of species declines within a regional landscape by testing models using both traditional hypotheses and those derived from a complex adaptive systems approach. Location Our study area was the dry mixed grassland of south-eastern Alberta, Canada, one of the largest remnants of native grassland in North America, and the adjacent grassland in Saskatchewan. Methods We used the breeding birds of the grassland to test the relationship between species declines and a suite of traits associated with decline (such as size, specialization and rarity, as well as distance to edge of a discontinuity, and edge of geographic range) in a stepwise regression with AICc values and bootstrapping via model averaging, followed by a refit procedure to obtain model-averaged parameter estimates. We used both provincial government and Breeding Bird Survey (BBS) classifications of decline. We also modelled degree of decline in the Alberta and Saskatchewan grasslands, which differ in amount of habitat remaining, to test whether severity of decline was explained by the same traits as species decline/not- decline. Results We found that the model for government-defined decline fulfilled government expectations that species' extinction risk is a function of being large, specialized, rare and carnivorous, whereas the model for BBS-defined decline suggested that the biological reality of decline is more complex, requiring the need to explicitly model scale-specific patterns. Furthermore, species decline/not- decline was explained by different traits than those that fit degree of decline, though complex systems- derived traits featured in both sets of models. Main conclusions Traditional approaches to predict species declines (e.g. government processes or IUCN Red Lists), may be too simplistic and may therefore misguide management and conservation. Using complex systems approaches that account for scale-specific patterns and processes have the potential to overcome these limitations.

Diversity and Distributions

Time-lapse three-dimensional inversion of complex conductivity data using an active time constrained (ATC) approach

Induced polarization (more precisely the magnitude and phase of impedance of the subsurface) is measured using a network of electrodes located at the ground surface or in boreholes. This method yields important information related to the distribution of permeability and contaminants in the shallow subsurface. We propose a new time-lapse 3-D modelling and inversion algorithm to image the evolution of complex conductivity over time. We discretize the subsurface using hexahedron cells. Each cell is assigned a complex resistivity or conductivity value. Using the finite-element approach, we model the in-phase and out-of-phase (quadrature) electrical potentials on the 3-D grid, which are then transformed into apparent complex resistivity. Inhomogeneous Dirichlet boundary conditions are used at the boundary of the domain. The calculation of the Jacobian matrix is based on the principles of reciprocity. The goal of time-lapse inversion is to determine the change in the complex resistivity of each cell of the spatial grid as a function of time. Each model along the time axis is called a ‘reference space model’. This approach can be simplified into an inverse problem looking for the optimum of several reference space models using the approximation that the material properties vary linearly in time between two subsequent reference models. Regularizations in both space domain and time domain reduce inversion artefacts and improve the stability of the inversion problem. In addition, the use of the time-lapse equations allows the simultaneous inversion of data obtained at different times in just one inversion step (4-D inversion). The advantages of this new inversion algorithm are demonstrated on synthetic time-lapse data resulting from the simulation of a salt tracer test in a heterogeneous random material described by an anisotropic semi-variogram.

Geophysical Journal International

Paleozoic subduction complex and Paleozoic-Mesozoic island-arc volcano-plutonic assemblages in the northern Sierra terrane

This field trip provides an overview of the stratigraphic and structural evolution of the northern Sierra terrane, which forms a significant part of the wall rocks on the western side of the later Mesozoic Sierra Nevada batholith in California. The terrane consists of a pre-Late Devonian subduction complex (Shoo Fly Complex) overlain by submarine arc-related deposits that record the evolution of three separate island-arc systems in the Late Sevonian-Early Mississippian, Permian, and Late Triassic-Jurassic. The two Paleozoic are packages and the underlying Shoo Fly Complex have an important bearing on plate-tectonic processes affecting the convergent margin outboard of the Paleozoic Cordilleran miogeocline, although their original paleogeographic relations to North America are controversial. The third arc package represents an overlap assemblage that ties the terrane to North America by the Late Triassic and helps constrain the nature and timing of Mesozoic orogenesis. Several of the field-trip stops examine the record of pre-Late Devonian subduction contained in the Shoo Fly Complex, as well as the paleovolcanology of the overlying Devonian to Jurassic arc rocks. Excellent glaciated exposures provide the opportunity to study a cross section through a tilted Devonian volcano-plutonic association. Additional stops focus on plutonic rocks emplaced during the Middle Jurassic arc magmatism in the terrane, and during the main pulse of Cretaceous magmatism in the Sierra Nevada batholith to the east.

California

Peridotite-gabbro complexes as keys to petrology of mid-oceanic ridges

Two suites of olivine-rich ultramafic and feldspathic rocks appear to be present in the Mid-Atlantic Ridge: one which seems to have alkalic affinities, and one similar to the chromitite- bearing alpine peridotite-gabbro complexes. The similarities of rocks in the two environments—continental and oceanic—imply that much about the petrology of mid-oceanic ridges may be learned from studies of continental complexes, and that silicic rocks have been formed in the mantle. Although gabbros in St. Paul Rocks and similar rocks at Tinaquillo, Venezuela, and Lizard, England, have been interpreted as not comagmatic with intimately associated peridotite by some petrologists, evidence to the contrary at Lizard is discussed. Association of fresh gneissic gabbro, some containing quartz, with talcose serpentinite, amphibole schist, quartz diorite and epidotic but unsheared basalts along the Mid-Atlantic Ridge is believed to indicate presence of alpine-type rocks that occur normally in eugeosynclinal belts. Gabbro, described as partly interlayered with peridotite by gravitational differentiation, forms major parts of three widely separated ultramafic complexes which have been interpreted as slices of oceanic crust and upper mantle: the Troodos massif in Cyprus, the Bowutu Mountains in Papua, and the Camagiiey complex in central Cuba. If, as Dietz has suggested, peridotite and related rocks in eugeosynclines represent fragments of ocean rind formed along mid-oceanic ridges and moved laterally by ocean-floor spreading, gabbro must be an essential constituent of the upper mantle. This could account for many geophysical anomalies, but would complicate some postulated mechanisms involved in ocean-floor spreading.

England

Possible origin and significance of extension-parallel drainages in Arizona's metamophic core complexes

The corrugated form of the Harcuvar, South Mountains, and Catalina metamorphic core complexes in Arizona reflects the shape of the middle Tertiary extensional detachment fault that projects over each complex. Corrugation axes are approximately parallel to the fault-displacement direction and to the footwall mylonitic lineation. The core complexes are locally incised by enigmatic, linear drainages that parallel corrugation axes and the inferred extension direction and are especially conspicuous on the crests of antiformal corrugations. These drainages have been attributed to erosional incision on a freshly denuded, planar, inclined fault ramp followed by folding that elevated and preserved some drainages on the crests of rising antiforms. According to this hypothesis, corrugations were produced by folding after subacrial exposure of detachment-fault foot-walls. An alternative hypothesis, proposed here, is as follows. In a setting where preexisting drainages cross an active normal fault, each fault-slip event will cut each drainage into two segments separated by a freshly denuded fault ramp. The upper and lower drainage segments will remain hydraulically linked after each fault-slip event if the drainage in the hanging-wall block is incised, even if the stream is on the flank of an antiformal corrugation and there is a large component of strike-slip fault movement. Maintenance of hydraulic linkage during sequential fault-slip events will guide the lengthening stream down the fault ramp as the ramp is uncovered, and stream incision will form a progressively lengthening, extension-parallel, linear drainage segment. This mechanism for linear drainage genesis is compatible with corrugations as original irregularities of the detachment fault, and does not require folding after early to middle Miocene footwall exhumations. This is desirable because many drainages are incised into nonmylonitic crystalline footwall rocks that were probably not folded under low-temperature, surface conditions. An alternative hypothesis, that drainages were localized by small fault grooves as footwalls were uncovered, is not supported by analysis of a down-plunge fault projection for the southern Rincon Mountains that shows a linear drainage aligned with the crest of a small antiformal groove on the detachment fault, but this process could have been effective elsewhere. Lineation-parallel drainages now plunge gently southwestward on the southwest ends of antiformal corrugations in the South and Buckskin Mountains, but these drainages must have originally plunged northeastward if they formed by either of the two alternative processes proposed here. Footwall exhumation and incision by northeast-flowing streams was apparently followed by core-complex arching and drainage reversal.

Arizona

Reconstruction of an early Paleozoic continental margin based on the nature of protoliths in the Nome Complex, Seward Peninsula, Alaska

The Nome Complex is a large metamorphic unit that sits along the southern boundary of the Arctic Alaska–Chukotka terrane, the largest of several micro continental fragments of uncertain origin located between the Siberian and Laurentian cratons. The Arctic Alaska–Chukotka terrane moved into its present position during the Mesozoic; its Mesozoic and older movements are central to reconstruction of Arctic tectonic history. Accurate representation of the Arctic Alaska–Chukotka terrane in reconstructions of Late Proterozoic and early Paleozoic paleogeography is hampered by the paucity of information available. Most of the Late Proterozoic to Paleozoic rocks in the Alaska–Chukotka terrane were penetratively deformed and recrystallized during the Mesozoic deformational events; primary features and relationships have been obliterated, and age control is sparse. We use a variety of geochemical, geochronologic, paleontologic, and geologic tools to read through penetrative deformation and reconstruct the protolith sequence of part of the Arctic Alaska–Chukotka terrane, the Nome Complex. We confirm that the protoliths of the Nome Complex were part of the same Late Proterozoic to Devonian continental margin as weakly deformed rocks in the southern and central part of the terrane, the Brooks Range. We show that the protoliths of the Nome Complex represent a carbonate platform (and related rocks) that underwent incipient rifting, probably during the Ordovician, and that the carbonate platform was overrun by an influx of siliciclastic detritus during the Devonian. During early phases of the transition to siliciclastic deposition, restricted basins formed that were the site of sedimentary exhalative base-metal sulfide deposition. Finally, we propose that most of the basement on which the largely Paleozoic sedimentary protolith was deposited was subducted during the Mesozoic.

Alaska

U-Pb detrital zircon geochronology as evidence for the origin of the Nome Complex, northern Alaska, and implications for regional and trans-Arctic correlations

Detrital zircons from the Nome Complex, a metamorphic terrane in northern Alaska, reveal important constraints on the early Paleozoic history of the Arctic Alaska–Chukotka terrane, a microcontinental block with an origin exotic to Laurentia. Twenty-two samples (17 in this study, five previously published) produce three detrital zircon population patterns (called themes), indicating that at least three distinguishable source areas contributed to the metamorphic protolith. Detrital zircon populations from metamorphosed rift-related mafic volcaniclastic rocks, a lithologic subunit of the Nome Complex, contain a dominant population of 740–550 Ma zircons. Samples from three other lithologic units yielded populations dominated by early Paleozoic zircons and characterized by a large population of 450–420 Ma zircons. A few samples, taken from two different lithologic units, yielded populations dominated by Mesoproterozoic zircons (most around 1.25–0.9 Ga) and lacked zircons younger than 900 Ma. None of the 22 samples contained more than a few Archean zircons. The ages of the youngest detrital zircon populations indicate that little of the protolith for the Nome Complex can be as old as Proterozoic, as previously thought. Further, a significant part of the protolith sequence is Devonian or younger; these rocks are likely correlative with Devonian or Mississippian units in the Brooks Range, specifically marine parts of the Endicott or Lisburne Groups. Based on detrital zircon data, limiting factors can be placed on the paleogeographic history of the Nome Complex and associated parts of the Arctic Alaska–Chukotka terrane: (1) 740–550 Ma zircons were deposited in a rift-related basin formed on a continental margin in the early Paleozoic; at least some of those zircons may have been sourced from local basement; (2) a transition to new sediment sources is reflected in Devonian or younger protoliths with the appearance of 450–420 Ma and 1.25–0.9 Ga detrital zircons; and (3) 450–420 Ma and 1.25–0.9 Ga zircons may have been supplied from sources outside the Arctic Alaska–Chukotka terrane.

Alaska

Oxygen isotopic investigation of silicic magmatism in the Stillwater caldera complex, Nevada: Generation of large-volume, low-δ18O rhyolitic tuffs and assessment of their regional context in the Great Basin of the western United States

Successive caldera-forming eruptions from ca. 30 to 25 Ma generated a large nested caldera complex in western Nevada that was subsequently dissected by Basin and Range extension, providing extraordinary cross-sectional views through diverse volcanic and plutonic rocks. A high-resolution oxygen isotopic study was conducted on units that represent all major parts of the Job Canyon, Louderback Mountains, Poco Canyon, and Elevenmile Canyon caldera cycles (29.2−25.1 Ma), and several Cretaceous plutons that flank the Stillwater caldera complex. We provide new oxygen and strontium isotope data for 12 additional caldera centers in the Great Basin, which are synthesized with >150 published oxygen and strontium isotope analyses for regional Mesozoic basement rocks. Stillwater zircons span a large isotopic range (δ 18 O zircon of 3.6‰−8.2‰), and all caldera cycles possess low-δ 18 O zircons. In some cases, they are a small proportion of the total populations, and in others, they dominate, such as in the low-δ 18 O rhyolitic tuffs of Job Canyon and Poco Canyon (δ 18 O zircon = 4.0‰−4.3‰; δ 18 O magma = 5.5‰−6‰). These are the first low-δ 18 O rhyolites documented in middle Cenozoic calderas of the Great Basin, adding to the global occurrence of these important magma types that fingerprint recycling of shallow crust altered by low-δ 18 O meteoric waters. The appearance of low-δ 18 O rhyolites in the Stillwater caldera complex is overprinted on a Great Basin−wide trend of miogeoclinal sediment contribution to silicic magmas that elevates δ 18 O compositions, making identification of 18 O depletions difficult. Though not a nominally low-δ 18 O rhyolite, the tuff of Elevenmile Canyon possesses both low-δ 18 O and high-δ 18 O zircon cores that are overgrown by homogenized zircon rims that approximate the bulk zircon average, pointing to batch assembly of isotopically diverse upper crustal melts to generate one of the most voluminous (2500−5000 km 3 ) tuff eruptions in the Great Basin. Despite overlapping in space and time, each caldera-forming cycle of the Stillwater complex has a unique oxygen isotope record as retained in single zircons. Most plutons that were spatially and temporally coincident with calderas have isotopic compositions that diverge from the caldera-forming tuffs and cannot be their cogenetic remnants.

Nevada

Postcaldera intrusive magmatism at the Platoro caldera complex, Southern Rocky Mountain volcanic field, Colorado, USA

The Oligocene Platoro caldera complex of the San Juan volcanic locus in Colorado (USA) features numerous exposed plutons both within the caldera and outside its margins, enabling investigation of the timing and evolution of postcaldera magmatism. Intrusion whole-rock geochemistry and phenocryst and/or mineral trace element compositions coupled with new zircon U-Pb geo-chronology and zircon in situ Lu-Hf isotopes document distinct pulses of magma from beneath the caldera complex. Fourteen intrusions, the Chiquito Peak Tuff, and the dacite of Fisher Gulch were dated, showing intrusive magmatism began after the 28.8 Ma eruption of the Chiquito Peak Tuff and continued to 24 Ma. Additionally, magmatic-hydrothermal mineralization is associated with the intrusive magmatism within and around the margins of the Platoro caldera complex. After caldera collapse, three plutons were emplaced within the subsided block between ca. 28.8 and 28.6 Ma. These have broadly similar modal miner-alogy and whole-rock geochemistry. Despite close temporal relations between the tuff and the intrusions, mineral textures and compositions indicate that the larger two intracaldera intrusions are discrete later pulses of magma. Intrusions outside the caldera are younger, ca. 28–26.3 Ma, and smaller in exposed area. They contain abundant glomerocrysts and show evidence of open-system processes such as magma mixing and crystal entrainment. The protracted magmatic history at the Platoro caldera complex documents the diversity of the multiple discrete magma pulses needed to generate large composite volcanic fields.

Colorado

Paleogene mid-crustal intrusions in the Ruby Mountains–East Humboldt Range metamorphic core complex, northeastern Nevada, USA

Middle Eocene to early Oligocene intrusions, widespread in the Ruby Mountains–East Humboldt Range metamorphic core complex, Nevada, USA, provide insights into a major Paleogene magmatic episode and its relation to tectonism in the northeastern Great Basin. These intrusions, well-exposed in upper Lamoille Canyon, range in composition from gabbro to leucomonzogranite. They form small plutons, sheets, and dikes that intrude the metamorphic and granitic infrastructure of the core complex. Two types of Paleogene monzogranite were recognized. The first is exemplified by two of the larger intrusive bodies, the Snow Lake Peak and Castle Lake intrusions, which occur as sheet-like bodies near and at the structural base of metamorphosed Neoproterozoic and Cambrian Prospect Mountain Quartzite where it is inverted above Cambrian and Ordovician marble of Verdi Peak in the Lamoille Canyon nappe. Swarms of dikes are associated with these intrusions. U-Pb (zircon) ages range ca. 40–33 Ma and typically display relatively simple and minor inheritance. The rocks have the lowest ε Hf (zircon) and ε Nd (whole rock) of any of the middle Cenozoic granites. The second type of monzogranite, Overlook type, typically occurs as thin, isolated dikes and leucosome-like bodies in Late Cretaceous granites of the infrastructure, with no obvious relationship to the large monzogranite bodies. Overlook-type monzogranite displays complex zircon inheritance, yields igneous ages ca. 37–32 Ma, and has ε Hf (zircon) and ε Nd (whole rock) identical to those of Late Cretaceous granites in the core complex. These isotopic and field data indicate that Overlook-type monzogranite formed in situ through anatexis of host Cretaceous granites. A pervasive thermal event was required to stimulate this crustal melting.

Nevada