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At least 1,063 records · Page 59Linked to original sources
USGS2020

Missouri StreamStats—St. Louis County and the City of St. Louis urban application

To address a major limitation of the functionality of the Missouri statewide StreamStats application in the urban areas of St. Louis County and the City of St. Louis, Missouri, the U.S. Geological Survey, in cooperation with the Metropolitan St. Louis Sewer District, defined watershed boundaries and hydrography for the study area using high-resolution 3-meter digital elevation data derived from light detection and ranging sources, high-resolution 6-inch imagery, and storm sewer network geospatial data. The combined sanitary sewers, a part of the storm sewer network, were integrated into the open channel hydrography and elevation data using a new Arc Hydro stormwater tool developed to facilitate the incorporation of the combined sanitary sewer network into the StreamStats application. The combined sanitary sewer network was edited for connectivity and flow direction before integration into the Missouri-St. Louis StreamStats application. Inlet structures in the geospatial data were defined as HydroJunction features that allow for stormwater runoff to enter the combined sanitary sewer network. An Arc Hydro stormwater processing workflow and a sewershed delineation tool were developed to integrate the combined sanitary sewer network with the hydrographic dataset and digital elevation model in the study area. The StreamStats application developed for the study area provides various data exploration tools that can be used to examine the spatial data and to obtain general descriptive information and flow statistics at streamgages in the study area. Watersheds and sewersheds can be delineated and basin characteristics can be determined at any point on the open channel network or the combined sanitary sewer network in the study area. Peak-flow statistics can be computed at any point on the open channel network. A report summarizing the results is generated by the StreamStats application and can be downloaded and used in other software. The Missouri-St. Louis StreamStats application is limited to the area inside St. Louis County and the City of St. Louis and excludes locations on the main stem of the Mississippi, Missouri, and Meramec Rivers. The limitations of the Missouri-St. Louis StreamStats application include possible inaccuracies using regression equations for peak-flow statistics developed assuming natural flow conditions and topographically derived watersheds determined from a coarser resolution of data than is used in this application. Additionally, published regression equations for peak-flow statistics did not incorporate any pipe flow or sewershed delineations when they were developed, which limits the applicability of peak-flow statistics to basins based on primarily topographic delineation. Inaccuracies in resolution, completeness, location, or attribution of geospatial elevation data, hydrographic data, derived stream lines, derived watershed boundaries, and combined sanitary sewer data can limit the accuracy and functionality of the Missouri-St. Louis StreamStats application.

Missouri↗
USGS2015

Results from laboratory and field testing of nitrate measuring spectrophotometers

Five ultraviolet (UV) spectrophotometer nitrate analyzers were evaluated by the U.S. Geological Survey (USGS) Hydrologic Instrumentation Facility (HIF) during a two-phase evaluation. In Phase I, the TriOS ProPs (10-millimeter (mm) path length), Hach NITRATAX plus sc (5-mm path length), Satlantic Submersible UV Nitrate Analyzer (SUNA, 10-mm path length), and S::CAN Spectro::lyser (5-mm path length) were evaluated in the HIF Water-Quality Servicing Laboratory to determine the validity of the manufacturer's technical specifications for accuracy, limit of linearity (LOL), drift, and range of operating temperature. Accuracy specifications were met in the TriOS, Hach, and SUNA. The stock calibration of the S::CAN required two offset adjustments before the analyzer met the manufacturer's accuracy specification. Instrument drift was observed only in the S::CAN and was the result of leaching from the optical path insert seals. All tested models, except for the Hach, met their specified LOL in the laboratory testing. The Hach's range was found to be approximately 18 milligrams nitrogen per liter (mg-N/L) and not the manufacturer-specified 25 mg-N/L. Measurements by all of the tested analyzers showed signs of hysteresis in the operating temperature tests. Only the SUNA measurements demonstrated excessive noise and instability in temperatures above 20 degrees Celsius (°C). The SUNA analyzer was returned to the manufacturer at the completion of the Phase II field deployment evaluation for repair and recalibration, and the performance of the sensor improved significantly. In Phase II, the analyzers were deployed in field conditions at three diferent USGS sites. The measured nitrate concentrations were compared to discrete (reference) samples analyzed by the Direct UV method on a Shimadzu UV1800 bench top spectrophotometer, and by the National Environmental Methods Index (NEMI) method I-2548-11 at the USGS National Water Quality Laboratory. The first deployment at USGS site 0249620 on the East Pearl River in Hancock County, Mississippi, tested the ability of the TriOs ProPs (10-mm path length), Hach NITRATAX (5 mm), Satlantic SUNA (10 mm), and the S::CAN Spectro::lyser (5 mm) to accurately measure low-level (less than 2 mg-N/L) nitrate concentrations while observing the effect turbidity and colored dissolved organic matter (CDOM) would have on the analyzers' measurements. The second deployment at USGS site 01389005 Passaic River below Pompton River at Two Bridges, New Jersey, tested the analyzer's accuracy in mid-level (2-8 mg-N/L) nitrate concentrations. This site provided the means to test the analyzers' performance in two distinct matrices—the Passaic and the Pompton Rivers. In this deployment, three instruments tested in Phase I (TriOS, Hach, and SUNA) were deployed with the S::CAN Spectro::lyser (35 mm) already placed by the New Jersey Water Science Center (WSC). The third deployment at USGS site 05579610 Kickapoo Creek at 2100E Road near Bloomington, Illinois, tested the ability of the analyzers to measure high nitrate concentrations (greater than 8 mg-N/L) in turbid waters. For Kickapoo Creek, the HIF provided the TriOS (10 mm) and S::CAN (5 mm) from Phase I, and a SUNA V2 (5 mm) to be deployed adjacent to the Illinois WSC-owned Hach (2 mm). A total of 40 discrete samples were collected from the three deployment sites and analyzed. The nitrate concentration of the samples ranged from 0.3–22.2 mg-N/L. The average absolute difference between the TriOS measurements and discrete samples was 0.46 mg-N/L. For the combined data from the Hach 5-mm and 2-mm analyzers, the average absolute difference between the Hach samples and the discrete samples was 0.13 mg-N/L. For the SUNA and SUNA V2 combined data, the average absolute difference between the SUNA samples and the discrete samples was 0.66 mg-N/L. The average absolute difference between the S::CAN samples and the discrete samples was 0.63 mg-N/L.

Open-File Report↗
USGS1973

Changes in floodflow characteristics of a rectified channel caused by vegetation, Jackson, Mississippi

Extreme changes in velocity, stage, and Manning's roughness coefficient, n , were observed during the first year after canalization of Hanging Moss Creek at Jackson, Miss. Additional changes were observed during the following 8 years. The channel, constructed during the summer of 1963, had a 50-foot-wide bottom, 2:1 side slopes, and 12-foot depth. In March 1964, average velocities of 7.8 feet per second were measured at a 5 1/2-foot depth in the clean channel and Manning's n was computed to be 0.022. In October 1964 the average velocity was 3.2 fps at a 5 1/2-foot depth and Manning's n was 0.045. The channel was then lined with fairly thick vegetation consisting of small willows, weeds, and grass. In October 1970 (summer foliage existing) the average velocity was 2.0 fps at a 5 1/2-foot depth and Manning's n was 0.07. Willow trees, 8 to 10 feet high, then lined the channel. In March 1971 (barren foliage), Manning's n was 0.05. In March 1972 (barren foliage), Manning's n was increased to 0.07. These observations indicate that the commonly used values of Manning's n for channel rectification (0.02-0.03) are low and that the carrying capacity of earthen channels may be reduced 50 percent as a result of only 1 year's growth of vegetation and 70 percent as a result of 8 year's growth. The carrying capacity during summer foliage is approximately two-thirds the carrying capacity during barren winter foliage.

Mississippi↗
USGS2004

Multistage hydrothermal silicification and Fe-Tl-As-Sb-Ge-REE enrichment in the Red Dog Zn-Pb-Ag district, northern Alaska: Geochemistry, origin, and exploration applications

Geochemical analyses of major, trace, and rare earth elements (REE) in more than 200 samples of variably silicified and altered wall rocks, massive and banded sulfide, silica rock, and sulfide-rich and unmineralized barite were obtained from the Main, Aqqaluk, and Anarraaq deposits in the Red Dog Zn-Pb-Ag district of northern Alaska. Detailed lithogeochemical profiles for two drill cores at Aqqaluk display an antithetic relationship between SiO2/Al2O3 and TiO2/Zr which, together with textural information, suggest preferential silicification of carbonate-bearing sediments. Data for both drill cores also show generally high Tl, Sb, As, and Ge and uniformly positive Eu anomalies (Eu/Eu* > 1.0). Similar high Tl, Sb, As, Ge, and Eu/Eu* values are present in the footwall and shallow hanging wall of Zn-Pb-Ag sulfide intervals at Anarraaq but are not as widely dispersed. Net chemical changes for altered wall rocks in the district, on the basis of average Al-normalized data relative to unaltered black shales of the host Kuna Formation, include large enrichments (>50%) of Fe, Ba, Eu, V, S, Co, Zn, Pb, Tl, As, Sb, and Ge at both Red Dog and Anarraaq, Si at Red Dog, and Sr, U, and Se at Anarraaq. Large depletions (>50%) are evident for Ca at both Red Dog and Anarraaq, for Mg, P, and Y at Red Dog, and for Na at Anarraaq. At both Red Dog and Anarraaq, wall-rock alteration removed calcite and minor dolomite during hydrothermal decarbonation reactions and introduced Si, Eu, and Ge during silicification. Sulfidation reactions deposited Fe, S, Co, Zn, Pb, Tl, As, and Sb; barite mineralization introduced Ba, S, and Sr. Light REE and U were mobilized locally. This alteration and mineralization occurred during Mississippi an hydrothermal events that predated the Middle Jurassic-Cretaceous Brookian orogeny. Early hydrothermal silicification at Red Dog took place prior to or during massive sulfide mineralization, on the basis of the dominantly planar nature of Zn-Pb veins, which suggests filling of fractures that developed in previously lithified rock. Uniformly low Ca and Mg and uniformly negative Ce anomalies in highly siliceous Red Dog wall rocks reflect hydrothermal decarbonation reactions and pervasive silicification owing to conductive cooling of oxidized metalliferous fluids. Similar Ca and Mg depletions are evident at Anarraaq but generally lack associated silicification, possibly because temperatures of the hydrothermal fluids were too low (<180??C) or because the thermal contrast between the fluids and wall rocks was smaller owing to the greater depth of alteration and mineralization there, compared with Red Dog. Chalcophile element anomalies (Fe, Zn, Pb, Tl, As, Sb) in wall rocks at both Red Dog and Anarraq are attributed to sulfidation reactions, coeval with subsurface Zn-Pb-Ag mineralization, during the mixing of oxidized metalliferous fluids with H2S-rich fluids derived locally within the Kuna Formation. Sedimentary wall rocks in the Red Dog district are characterized by a distinctive suite of geochemical anomalies, especially for Zn, Pb, Tl, As, Sb, Ge, and Eu/Eu*. At the Aqqaluk deposit, wall rocks without visible sphalerite or galena (<300 ppm Zn + Pb) have anomalous Eu/Eu*, Tl, Sb, and As for up to ???100 m stratigraphically below Zn-rich silica rock. At Anarraaq, the Tl anomaly is most extensively developed, and enrichment relative to unaltered black shale of the Kuna Formation is present up to 62 m above the highest Zn-Pb sulfide zones. The magnitude of the enrichment and systematic behavior of Tl in the district make Tl a promising geochemical exploration guide for Red Dog-type Zn-Pb-Ag deposits elsewhere. ?? 2004 by Economic Geology.

Economic Geology↗
USGS2007

Seismotectonic implications of sand blows in the southern Mississippi Embayment

We explore seismically-induced sand blows from the southern Mississippi Embayment and their implications in resolving the question of near or distal epicentral source region. This was accomplished using aerial photography, field excavations, and cone penetration tests. Our analysis shows that three sand blow fields exhibit a distinct chronology of strong ground motion for the southern embayment: (1) The Ashley County, Arkansas sand blow field, near the Arkansas/Louisiana state border, experienced four Holocene sand venting episodes; (2) to the north, the Desha County field experienced at least three episodes of liquefaction; and (3) the Lincoln–Jefferson Counties field experienced at least one episode. Cone penetration tests (CPT) conducted in and between the sand blow fields suggest that the fields may not be distal liquefaction associated with New Madrid seismic zone earthquakes but rather are likely associated with strong earthquakes on local faults. This conclusion is consistent with the differences in timing of the southern embayment sand venting episodes and those in the New Madrid seismic zone. These results suggest that active tectonism and strong seismicity in intraplate North America may not be localized at isolated weak spots, but rather widespread on fault systems that are favorably oriented for slip in the contemporary stress field.

Engineering Geology↗
USGS2008

A photographic and acoustic transect across two deep-water seafloor mounds, Mississippi Canyon, northern Gulf of Mexico

In the northern Gulf of Mexico, a series of seafloor mounds lie along the floor of the Mississippi Canyon in Atwater Valley lease blocks 13 and 14. The mounds, one of which was drilled by the Chevron Joint Industry Project on Methane Hydrates in 2005, are interpreted to be vent-related features that may contain significant accumulations of gas hydrate adjacent to gas and fluid migration pathways. The mounds are located ???150 km south of Louisiana at ???1300 m water depth. New side-scan sonar data, multibeam bathymetry, and near-bottom photography along a 4 km northwest-southeast transect crossing two of the mounds (labeled D and F) reveal the mounds' detailed morphology and surficial characteristics. Mound D, ???250 m in diameter and 7-10 m in height, has exposures of authigenic carbonates and appears to result from a seafloor vent of slow-to-moderate flux. Mound F, which is ???400 m in diameter and 10-15 m high, is covered on its southwest flank by extruded mud flows, a characteristic associated with moderate-to-rapid flux. Chemosynthetic communities visible on the bottom photographs are restricted to bacterial mats on both mounds and mussels at Mound D. No indications of surficial gas hydrates are evident on the bottom photographs.

Marine and Petroleum Geology↗
USGS2001

Seismic-reflection imaging of Tertiary faulting and related post-Eocene deformation 20 km North of Memphis, Tennessee

Other than the Crittenden County fault zone (CCFZ), little is known about the seismic hazard from earthquake faults within 50 km of Memphis, Tennessee, a city that contains a large inventory of older buildings that are vulnerable to moderate and strong earthquake ground shaking. To address this lack of knowledge about faulting near Memphis, we acquired a 4.5 km long Mini-Sosie seismic-reflection profile across the boundary between the loess-covered bluffs and modern Mississippi River flood plain in Meeman-Shelby Forest State Park north of Memphis. We imaged a previously unknown reverse/thrust fault that displaces Paleozoic and Cretaceous rocks and upwarps Tertiary deposits on the floodplain portion of the profile about 25 km north of downtown Memphis. The Paleozoic and Cretaceous rocks are vertically faulted about 70 and 40 m, respectively, in an up-to-the-west sense of displacement. The fault displacement apparently terminates in the basal portion of the Paleocene section and causes only an upwarping of the overlying deposits. The overlying Paleocene and Eocene deposits, which are probably the youngest deposits imaged, are upwarped about 50-60 m with the same sense of displacement as the underlying older units. The sense of displacement, amplitude, and appearance of the fault in the seismic data are very similar to that observed in the seismic reflection images of the CCFZ 15 km west of this profile. Although we have imaged this new fault in only one location, its proximity to Memphis and similarities to the CCFZ, leads us to speculate that it may be a parallel structure to the CCFZ and thus warrants further study. ?? 2001 Elsevier Science B.V. All rights reserved.

Engineering Geology↗
USGS2002

Sand wave fields beneath the Loop Current, Gulf of Mexico: Reworking of fan sands

Extensive fields of large barchan-like sand waves and longitudinal sand ribbons have been mapped by deep-towed SeaMARC IA sidescan sonar on part of the middle and lower Mississippi Fan that lies in about 3200 m of water. The area is beneath the strongly flowing Loop Current. The bedforms have not been adequately sampled but probably consist of winnowed siliciclastic-foraminiferal sands. The size (about 200 m from wingtip to wingtip) and shape of the large barchans is consistent with a previously observed peak current speed of 30 cm/s, measured 25 m above the seabed. The types of small-scale bedforms and the scoured surfaces of chemical crusts, seen on nearby bottom photographs, indicate that near-bed currents in excess of 30 cm/s may sometimes occur. At the time of the survey the sand transport direction was to the northwest, in the opposite direction to the Loop Current but consistent with there being a deep boundary current along the foot of the Florida Escarpment. Some reworking of the underlying sandy turbidites and debris flow deposits is apparent on the sidescan sonar records. Reworking by deep-sea currents, resulting in erosion and in deposits characterised by coarsening upwards structures and cross-bedding, is a process that has been proposed for sand found in cores in shallower parts of the Gulf of Mexico. This process is more widespread than hitherto supposed.

Marine Geology↗
USGS1990

A dolomitized shelfedge hardground in the northern Gulf of Mexico

An elongated calcareous hardground occurs on the shelfedge northeast of the Mississippi Trough. High-resolution seismic reflection profiles show that the hardground is in 90-110 m of water, is 70-250 m wide, at least 2.3 km long, and of low relief (5-10 m). The hardground is composed of dolostone and coquinoid limestone, and exhibits a dead biofacies of nodular and encrusting calcium carbonate-secreting organisms that are significantly different from those forms living in the adjacent unconsolidated sediments. Cementation of the hardground substrate by primary dolomite was initiated during early diagenesis close to the sea floor and progressed by concretionary growth under an interstitial environment partially open to marine molecular fluxes. The bicarbonate necessary to form the dolomite came from an admixture of isotopically light thermogenic and sedimentary organic carbon sources and an isotopically heavier marine source. Exposed surfaces of the dolostone, which have been heavily bioeroded, are covered by an oxidized, goethite-rich, reddish-brown rind. The coquina is primarily composed of whole and fragmented mollusk shells and was deposited in a higher-energy environment than the precursor sediments of the dolostone. The hardground was preserved during the Holocene transgression because of its lithified nature and the top has been intermittently swept free of finer detritus by current action.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS1997

Massive sediment bypassing on the lower shoreface offshore of a wide tidal inlet: Cat Island Pass, Louisiana

Analysis of a series of historical bathymetric and shoreline surveys along the Louisiana coast west of the Mississippi River mouth detected a large area of deposition in water depths of 2.0–8.5 m offshore of a 9-km-wide tidal inlet, the Cat Island Pass/Wine Island Pass system. A 59.9 · 106 m 3 sandy deposit formed from the 1930s–1980s, spanning 27 km in the alongshore direction, delineating the transport pathway for sediment bypassing offshore of the inlet on the shoreface. Bypassing connected the shorefaces of two barrier island systems, the Isles Dernieres and the Bayou Lafourche. The processes responsible for formation of this deposit are not well understood, but sediment-transport modeling suggests that sediment is transported primarily by wind-driven coastal currents during large storms and hurricanes. Deposition appears to be related to changes in shoreline orientation, closing of transport pathways into a large bay to the east and the presence of tidal inlets. This newly documented type of bypassing, an offshore bypassing of the inlet system, naturally nourished the immediate downdrift area, the eastern Isles Dernieres, where shoreface and shoreline erosion rates are about half of pre-bypassing rates. Erosion rates remained the same farther downdrift, where bypassing has not yet reached. As this offshore bypassing continues, the destruction of the Isles Dernieres will be slowed.

Louisiana↗
USGS2006

Estimate of ground water in storage in the Great Lakes basin, United States, 2006

Hydrogeologic data from Regional Aquifer System Analyses (RASA) studies by the U.S. Geological Survey in the Great Lakes Basin, United States, during 1978-95, were compiled and used to estimate the total volume of water that is stored in the many aquifers of the basin. These studies focused on six regional aquifer systems: the Cambrian-Ordovician aquifer system in Wisconsin, Illinois, and Indiana; the Silurian- Devonian aquifers in Wisconsin, Michigan, Illinois, Indiana, and Ohio; the surficial aquifer system (aquifers of alluvial and glacial origin) found throughout the Great Lakes Basin; and the Pennsylvanian sandstone and carbonate-rock aquifers and the Mississippian sandstone aquifer in Michigan. Except for the surficial aquifers, all of these aquifer systems are capable of yielding substantial quantities of water and are not small aquifers with only local importance. Individual surficial aquifers, although small in comparison to the bedrock aquifers, collectively represent large potential sources of ground water and therefore have been treated as a regional system. Summation of ground-water volumes in the many regional aquifers of the basin indicates that about 1,340 cubic miles of water is in storage; of this, about 984 cubic miles is considered freshwater (that is, water with dissolved-solids concentration less than 1,000 mg/L). These volumes should not be interpreted as available in their entirety to meet water-supply needs; complete dewatering of any aquifer is environmentally undesirable. The amount of water that is considered available on the basis of water quality and environmental, economic, and legal constraints has not been determined. The effect of heavy pumping in the Chicago, Ill., and Milwaukee, Wis., areas, which has caused the regional ground-water divide in the Cambrian-Ordovician aquifer system to shift westward, has been included in the above estimates. This shift in the ground-water divide has increased the amount of water in storage in the deep-bedrock aquifers of the Great Lakes Basin by about 36 cubic miles; however, this water is removed by wells and, after use, is mostly discharged to the Mississippi River Basin rather than to the Great Lakes Basin. The corresponding decrease in ground-water storage that has resulted from lowering of the potentiometric surface due to this heavy pumping (0.059 cubic miles) is negligible compared to the total estimated storage.

Scientific Investigations Report↗
USGS2020

Characterization of the unconventional Tuscaloosa marine shale reservoir in southwestern Mississippi, USA: Insights from optical and SEM petrography

This study presents new optical petrography and electron microscopy data, interpreted in the context of previously published petrophysical, geochemical, and mineralogical data, to further characterize the Tuscaloosa marine shale (TMS) as an unconventional reservoir in southwestern Mississippi. The basal high resistivity zone has a higher proportion of Type II sedimentary organic matter than the overlying TMS, indicating it is more prone to oil generation. Optical petrography and electron microscopy reveal a heterogeneous clay matrix with ubiquitous pyrite grains, quartz, feldspar, glaucony, foraminifera, shell fragments, and rarer occurrences of apatite and crinoid fragments as well as liptinite, alginite, inertinite, and vitrinite. Our petrographic observations suggest that higher abundances of detrital quartz grains coupled with minimal authigenic cements result in higher porosity and permeability. However, the TMS is also more clay-rich than other unconventional shale oil and gas plays, which can impair the effectiveness of hydraulic fracture stimulation. Thin section observations reveal alternating clay and calcium carbonate laminae that are interpreted to reflect changes in sediment flux. Planktonic foraminifera indicate an overlying oxygenated water column while benthic inoceramid fragments and pervasive authigenic pyrite suggest anoxic or dysoxic bottom water conditions. Apatite fragments in thin section suggest mixing events and an influx of nutrient-rich sediments. Overall, these observations suggest that a variety of paleodepositional environments occurred in the TMS and the lithofacies diversity resulting from these small-scale depositional cycles makes it difficult to determinatively identify areas conducive to enhanced economic hydrocarbon recovery.

Mississippi, Lousianna↗
USGS1984

Shoreface translation and the Holocene stratigraphic record: Examples from Nova Scotia, the Mississippi Delta and eastern Australia

Classic descriptive models of barrier sedimentation have been developed with data from the Atlantic and Gulf coasts of the United States. These models are dominated by low to moderate rates of relative sea level (RSL) rise and wave energy. Barriers respond by landward recycling of sediment through the mechanism of shoreface retreat. Sedimentation processes on the central coast of New South Wales (N.S.W.), Australia, consist of rapid RSL rise in early Holocene times followed by a stillstand since 6500 B.P. Wave energy is relatively high year-round and sand sources for barrier formation are only found on the inner shelf. Barrier sedimentation on the central coast of N.S.W. exhibits a thick, composite sequence composed of a basal marine transgressive sand overlain by regressive beach and dune facies. The Louisiana coast surrounding the Mississippi delta is underlain by compacting deltaic muds which generate very rapid rates of RSL rise. The Louisiana coast experiences low wave energy punctuated by high-energy tropical and extra-tropical storm events. Barrier sediments accumulate from the erosion of deltaic headlands and undergo a transformation from subaerial barrier island systems to subaqueous shoals located on the inner shelf. Drumlins experience coastal erosion on the Eastern Shore of Nova Scotia and provide a sediment source for compartmented estuary mouth barriers. An ongoing, moderate rise of RSL results from the passage of a glacial forebulge. Wave energy is intermediate between Louisiana and N.S.W. and displays a seasonal pattern dominated by frequent winter storms. Coastal barrier sedimentation is episodic, consisting of a period of beach ridge progradation followed by barrier destruction and re-establishment further landward. The three contrasting sedimentary sequences found in examples from Louisiana, N.S.W. and Nova Scotia indicate that presently available sedimentation models from locations such as the middle Atlantic or Texas coasts of the United States may only represent well-documented regional case studies. A true generalised coastal sedimentation model is required which can identify the parameters controlling vertical and horizontal translation of the depositional surface and provide relationships between these parameters which quantitatively predict the genesis, distribution and geometry of coastal sedimentary facies.

Marine Geology↗
USGS2011

Trace and minor element variations and sulfur isotopes in crystalline and colloform ZnS: Incorporation mechanisms and implications for their genesis

Various models have been proposed to explain the formation mechanism of colloform sphalerite, but the origin is still under debate. In order to decipher influences on trace element incorporation and sulfur isotope composition, crystalline and colloform sphalerite from the carbonate-hosted Mississippi-Valley Type (MVT) deposit near Wiesloch, SW Germany, were investigated and compared to sphalerite samples from 52 hydrothermal vein-type deposits in the Schwarzwald ore district, SW Germany to study the influence of different host rocks, formation mechanisms and fluid origin on trace element incorporation. Trace and minor element incorporation in sphalerite shows some correlation to their host rock and/or origin of fluid, gangue, paragenetic minerals and precipitation mechanisms (e.g., diagenetic processes, fluid cooling or fluid mixing). Furthermore, crystalline sphalerite is generally enriched in elements like Cd, Cu, Sb and Ag compared to colloform sphalerite that mainly incorporates elements like As, Pb and Tl. In addition, sulfur isotopes are characterized by positive values for crystalline and strongly negative values for colloform sphalerite. The combination of trace element contents, typical minerals associated with colloform sphalerite from Wiesloch, sulfur isotopes and thermodynamic considerations helped to evaluate the involvement of sulfate-reducing bacteria in water-filled karst cavities. Sulfate-reducing bacteria cause a sulfide-rich environment that leads in case of a metal-rich fluid supply to a sudden oversaturation of the fluid with respect to galena, sphalerite and pyrite. This, however, exactly coincides with the observed crystallization sequence of samples involving colloform sphalerite from the Wiesloch MVT deposit.

Wiesloch↗
USGS2024

Water-quality trends in the Kansas River, Kansas, since enactment of the Clean Water Act, 1972–2020

The Clean Water Act was passed by Congress in 1972 to regulate pollution within the waters of the United States. The U.S. Geological Survey (USGS), in cooperation with the Kansas Department of Health and Environment (KDHE), the Kansas Water Office, the Nature Conservancy, the City of Lawrence, the City of Manhattan, the City of Olathe, the City of Topeka, WaterOne, and Evergy, compiled and analyzed historical streamflow and water-quality data collected by USGS and KDHE to characterize trends in water-quality constituents of interest because of their relation to water supply, drinking-water treatment, and sediment and nutrient transport, among others (total dissolved solids, chloride, ammonia, dissolved inorganic nitrogen [ammonia and nitrate plus nitrite], total nitrogen, orthophosphate, total phosphorus, total suspended solids, and fecal coliform bacteria) during mean- and low-flow conditions in the Kansas River since the passage of the Clean Water Act in 1972 through 2020. Trends in water-quality concentrations, or densities, and loads were analyzed using the Exploration and Graphics for RivER Trends R package and Weighted Regressions on Time, Discharge, and Season (WRTDS) model at upstream (Kansas River at Wamego, Kansas; USGS station 06887500) and downstream (Kansas River at De Soto, Kansas; USGS station 06892350) locations along the Kansas River using streamflow and water-quality data collected by the USGS and KDHE during 1972 through 2020. The Exploration and Graphics for RivER Trends Confidence Intervals R package and WRTDS bootstrap test estimated direction, uncertainty, and likelihood of trends in concentration and loads for each water-quality constituent of interest. Downward trends in concentration and load were observed for 5 of the 9 water-quality constituents at both sites during mean-flow conditions during the study period. During low-flow conditions, 7 of the 9 constituents exhibited downward trends, possibly reflecting reductions in point-source contributions to the Kansas River. Downward trends in ammonia, dissolved inorganic nitrogen, and total nitrogen during mean- and low-flow conditions were observed at both Kansas River sites, which were similar to patterns observed nationally. Upward trends were generally observed for orthophosphate and total phosphorus, which were similar to patterns observed at sites in the Mississippi River Basin. Downward trends, or no trend, were observed for chloride. Upward and downward trends were observed for total dissolved solids. Downward trends in total suspended solids and fecal coliform bacteria were observed at both sites, which were also similar to patterns observed nationally. The long-term trend analyses in this report are an essential step to understanding how water-quality conditions have changed in the Kansas River since the passage of the Clean Water Act.

Kansas↗
USGS2003

Arsenic in midwestern glacial deposits — Occurrence and relation to selected hydrogeologic and geochemical factors

Ground-water-quality data collected as part of 12 U.S. Geological Survey National Water-Quality Assessment studies during 1996-2001 were analyzed to (1) document arsenic occurrence in four types of gla-cial deposits that occur in large areas of the Midwest, (2) identify hydrogeologic or geochemical factors asso-ciated with elevated arsenic concentrations, and (3) search for clues as to arsenic source(s) or mechanism(s) of mobilization that could be useful for designing future studies. Arsenic and other water-quality constituents were sampled in 342 monitor and domestic wells in parts of Illinois Indiana Ohio Michigan and Wisconsin. Arsenic was detected (at a concentration >1 ?g/L) in one-third of the samples. The maximum concentration was 84 ?g/L, and the median was less than 1 ?g/L. Eight percent of samples had arsenic concentrations that exceeded the U.S. Environmental Protection Agency Maximum Contaminant Level (MCL) of 10?g/L. Samples were from four aquifer types?confined valley fill, unconfined valley fill, outwash plain, and till with sand lenses. Highest arsenic concentrations were found in reducing waters from valley-fill depos-its. In confined valley fill, all waters were reducing and old (recharged before 1953), and almost half of sam-ples had arsenic concentrations greater than the MCL. In unconfined valley fill, redox conditions and ages were varied, and elevated arsenic concentrations were sporadic. In both types of valley fill, elevated arsenic concentrations are linked to the underlying bedrock on the basis of spatial relations and geochemical correla-tions. In shallow (<50 ft) till with sand lenses, arsenic was detected in oxic or mixed waters, but concentra-tions were rarely greater than the MCL. In shallow out-wash-plain deposits, arsenic concentrations greater than the MCL were detected in waters that were reduc-ing and young (recharged after 1953). Although arsenic concentrations were signifi-cantly higher in deep wells (>150 ft), all deep wells were from a distinctive aquifer type (confined valley fill). It is not known whether wells at similar depths in other aquifer types would produce waters with simi-larly high arsenic concentrations. Correlations of arsenic with fluoride, strontium, and barium suggest that arsenic might be related to epi-genetic (Mississippi Valley-type) sulfide deposits in Paleozoic bedrock. Arsenic is typically released from sulfides by oxidation, but in the current study, the highest arsenic concentrations in glacial deposits were detected in reducing waters. Therefore, a link between epigenetic sulfides and elevated arsenic concentrations in glacial deposits would probably require a multi-step process.

Illinois, Indiana, Ohio↗
USGS1984

The Balmat-Edwards zinc-lead deposits; synsedimentary ore from Mississippi Valley-type fluids

Reconstruction of some aspects of the initial environment of ore deposition through detailed S, C, and O isotope studies of the Fowler orebody, and through reconnaissance trace element and S isotope studies of sphalerite concentrates and composite samples of ore from 22 orebodies; and (2) evaluation of the effects of high-grade metamorphism on the stable isotope geochemistry of both the ore and gangue minerals of a massive sulfide orebody. The delta 34 S values of pyrite, sphalerite, and galena in the Fowler orebody range from 11.5 to 17.5 per mil; anhydrite associated with ore ranges from 25.6 to 27.0 per mil. Average equilibration temperatures calculated from the delta 34 S differences between coexisting sulfur-bearing phases are 388 degrees C for pyrite-sphalerite, 338 degrees C for sphalerite-galena, 329 degrees C for pyrite-galena, and 602 degrees C for anhydrite-pyrite; all pairs display narrow temperature distributions. The delta 13 C and delta 18 O values of carbonates from the Fowler orebody range from -1.6 to 1.4 per mil and from 24.8 to 27.0 per mil, respectively; quartz delta 18 O values range from 23.0 to 27.0 per mil. The delta 34 S values of sphalerite concentrated from composite samples of the orebodies range from 12.7 to 14.7 per mil. This narrow range contrasts sharply with the wide variability of associated evaporitic anhydrite lenses, which range from 8 to 28 per mil. A stratigraphic increase in the delta 34 S value of the evaporitic anhydrite at Balmat, and large sulfide iron-formation occurrences near Balmat, imply that bacterial sulfate reduction occurred on an unusually large scale during Balmat sedimentation. The presence of such an increase in a sedimentary section may constitute a valuable exploration guide.

Economic Geology↗
USGS1996

Hydrogeology and ground-water quality of glacial-drift aquifers, Leech Lake Indian Reservation, north-central Minnesota

Among the duties of the water managers of the Leech Lake Indian Reservation in north-central Minnesota are the development and protection of the water resources of the Reservation. The U.S. Geological Survey, in cooperation with the Leech Lake Indian Reservation Business Committee, conducted a three and one half-year study (1988-91) of the ground-water resources of the Leech Lake Indian Reservation. The objectives of this study were to describe the availability and quality of ground water contained in glacial-drift aquifers underlying the Reservation. Aquifers and confining units are present throughout the entire thickness of the glacial drift in the study area, which includes the Leech Lake Indian Reservation and adjacent parts of Beltrami, Hubbard, Itasca, and Cass Counties in north-central Minnesota, an area of approximately 2,145 square miles. An unconfined aquifer underlies most of the central and north-central parts of the study area. The saturated thickness of the aquifer ranges from 0 to about 105 feet. Horizontal hydraulic conductivity, estimated from 19 slug tests, ranges from 0.6 to 31 feet per day. The transmissivity of the aquifer ranges from 19 to more than 20,000 feet squared per day and is greatest in an area from west of Cass Lake to Lake Winnibigoshish. Theoretical maximum well yields range from less than 10 to about 2,000 gallons per minute. The unconfined and uppermost confined aquifers are physically and hydraulically separated by a fine-grained confining unit, consisting of till or lake deposits, that ranges in thickness from 3 to 254 feet. The thickness of the uppermost confined aquifer ranges from 5 to about 53 feet. On the basis of specific-capacity data, the transmissivity of the aquifer ranges from less than 100 feet squared per day in the northeastern and southeastern parts of the study area to about 21,000 feet squared per day near Cass Lake. Theoretical maximum well yields range from less than 10 to about 2,600 gallons per minute. Recharge to the ground-water system is predominantly from precipitation that infiltrates to the saturated zone. An analysis of four hydrographs for observation wells screened in the unconfined aquifer indicated spring recharge amounts during 1989 of 1-4 inches. Discharge from the ground-water system occurs by leakage to streams, lakes, and wetlands, evapotranspiration, withdrawals by wells, and underflow to the southeast within the Mississippi River Valley. Streamflow measurements indicate that ground-water discharge to the Mississippi River is greater in the western part of the study area between Cass Lake and Lake Winnibigoshish than in the eastern part downstream from Lake Winnibigoshish. The general regional direction of ground-water flow in the unconfined and uppermost confined aquifers is to the east and southeast. Ground-water flow is also toward the Mississippi River and the three large lakes in the study area, Lake Winnibigoshish and Cass and Leech Lakes. Water moves through the ground-water system predominantly horizontally in the aquifers, whereas vertical components of flow are significant in confining units. Downward leakage of water occurs in highland areas where ground water flows downward from overlying till to the uppermost confined aquifer. Water moves vertically upward from deep to shallow aquifers in areas of regional discharge, the Mississippi River, Cass Lake, Lake Winnibigoshish. and Leech Lake. Waters from both the unconfined and uppermost confined aquifers generally are suitable for domestic consumption, crop irrigation, and most other uses. Concentrations of iron and manganese in water from both aquifers frequently exceed levels that may impart an undesirable taste or odor to water. Calcium and bicarbonate are the predominant ions in water from both the unconfined and uppermost confined aquifers. Water from both the unconfined and uppermost confined aquifers is hard to very hard, averaging 187 and 247 milligrams per liter as calcium carbonate, respectively. Differences in the mean concentrations of constituents in waters from the unconfined and uppermost confined aquifers vary. The mean concentrations of chloride, manganese, dissolved organic carbon, sulfate, and dissolved iron were greater for water from the unconfined aquifer than for water from the uppermost confined aquifer. Conversely, the mean concentrations of calcium, potassium, silica, sodium, fluoride, and boron were greater for water from the uppermost confined aquifer than for water from the unconfined aquifer. These higher concentrations of naturally occurring constituents in waters from the uppermost confined aquifer may occur because of the longer flow paths and longer residence times of water in the uppermost confined aquifer as compared to the unconfined aquifer. Nutrients include nitrogen and phosphorus species. The mean concentrations of dissolved nitrogen (NO 2 + NO 3 , dissolved) and total phosphorus were about 5 and 1.5 times greater for water from the unconfined aquifer than for water from the uppermost confined aquifer, respectively. None of the water samples had concentrations of dissolved nitrogen greater than the maximum contaminant level established by the U.S. Environmental Protection Agency (10 milligrams per liter) and only one water sample had a concentration greater than 3 milligrams per liter. Water collected from wells completed in the unconfined aquifer in residential and recreational land-use areas had concentrations of arsenic, cadmium, chromium, copper, lead, mercury, and cyanide equal to or less than 6 micrograms per liter. Concentrations of organic-acid herbicides in water from three wells screened in the unconfined aquifer in managed-forest land-use areas were all below detection levels. Concentrations of U.S. Environmental Protection Agency priority pollutants in water from three wells screened in the unconfined aquifer and from one well screened in the uppermost confined aquifer were also all below detection levels.

Minnesota↗