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At least 1,063 records · Page 59Linked to original sources
USGS2022

Mars Science Laboratory CheMin data from the Glen Torridon region and the significance of lake-groundwater interactions in interpreting mineralogy and sedimentary history

The Glen Torridon (GT) region is positioned in terrains with strong clay mineral signatures, as inferred from orbital spectroscopy. The GT campaign confirmed orbital distinctions with in situ measurements by the Mars Science Laboratory rover, Curiosity , and the CheMin X-ray diffraction instrument with of some of the highest clay mineral abundances to date. Additionally, GT is unique because of distinct phase identifications for the first time by CheMin, including: (i) Fe-carbonates, and (ii) a novel peak in the XRD patterns of some GT samples, with an interplanar spacing of at 9.2 Å. Fe-carbonates have been previously suggested from other instruments onboard, but this is the first definitive reporting by CheMin of multiple samples with Fe-carbonate. This new phase has never been observed in Gale crater with the CheMin instrument and may be a new mineral for Mars, but discrete identification still remains enigmatic because no single phase on Earth is able to account the mineralogical, geochemical, and sedimentological constraints in the GT region. Here, we modeled XRD profiles and propose an interstratified clay mineral, specifically greenalite-minnesotaite (G-M), as a reasonable candidate. The coexistence of Fe-carbonate and Fe-rich clay minerals in the GT samples, supports a conceptual model of a lacustrine groundwater mixing environment in the ancient Gale crater lake. Groundwater interaction with percolating lake waters in the sediments is common in terrestrial lacustrine settings, and the diffusion of two distinct water bodies within the subsurface can create a geochemical gradient and unique mineral front in the sediments. Ultimately, the proximity to this mixing zone controlled the secondary minerals preserved in the Jura, Knockfarril Hill, and Glasgow members of the Mt. Sharp group exposed in GT.

Journal of Geophysical Research E: Planets↗
USGS2022

Bedrock geochemistry and alteration history of the clay-bearing Glen Torridon region of Gale crater, Mars

Glen Torridon is a topographic trough located on the slope of Aeolis Mons, Gale crater, Mars. It corresponds to what was previously referred to as the “clay-bearing unit”, due to the relatively strong spectral signatures of clay minerals (mainly ferric smectites) detected from orbit. Starting in January 2019, the Curiosity rover explored Glen Torridon for more than 700 sols (Martian days). The objectives of this campaign included acquiring a detailed understanding of the geologic context in which the clay minerals were formed and determining the intensity of aqueous alteration experienced by the sediments. Here, we present the major-element geochemistry of the bedrock as analyzed by the ChemCam instrument. Our results reveal that the two main types of bedrock exposures identified in the lower part of Glen Torridon are associated with distinct chemical compositions (K-rich and Mg-rich), for which we are able to propose mineralogical interpretations. Moreover, the topmost stratigraphic member exposed in the region displays a stronger diagenetic overprint, especially at two locations close to the unconformable contact with the overlying Stimson formation, where the bedrock composition significantly deviates from the rest of Glen Torridon. Overall, the values of the Chemical Index of Alteration determined with ChemCam are elevated by Martian standards, suggesting the formation of clay minerals through open system weathering. However, there is no indication that the alteration was stronger than in some terrains previously visited by Curiosity , which in turn implies that the enhanced orbital signatures are mostly controlled by non-compositional factors.

Journal of Geophysical Research E: Planets↗
USGS2022

New craters on Mars: An updated catalog

We present a catalog of new impacts on Mars. These craters formed in the last few decades, constrained with repeat orbital imaging. Crater diameters range from 58 m down to <1 m. For each impact, we report whether it formed a single crater or a cluster (58% clusters); albedo features of the blast zone (88% halos; 64% linear rays; 10% arcuate rays; majority dark-toned; 4% light-toned; 14% dual-toned); and exposures of ice (4% definite; 2% possible). We find no trends in the occurrences of clusters with latitude, elevation, or impact size. Albedo features do not depend on atmospheric fragmentation. Halos are more prevalent at lower elevations, indicating an atmospheric pressure dependence; and around smaller impacts, which could be an observational bias. Linear rays are more likely to form from larger impacts into more consolidated material and may be enhanced by lower atmospheric pressure at higher elevations. Light- and dual-toned blast zones occur in specific regions and more commonly around larger impacts, indicating excavation of compositionally distinct material. Surfaces covered with bright dust lacking cohesion are favored to form detectable surface features. The slope of the cumulative size frequency distribution for this data set is 2.2 for diameters >8 m (differential slope 2.9), significantly shallower than the slope of new lunar craters. We believe that no systematic biases exist in the Martian data set sufficient to explain the discrepancy. This catalog is complete at the time of writing, although observational biases exist, and new discoveries continue.

Journal of Geophysical Research E: Planets↗
USGS2022

Ancient winds, waves, and atmosphere in Gale Crater, Mars, inferred from sedimentary structures and wave modeling

Wave modeling and analysis of sedimentary structures were used to evaluate whether four examples of symmetrical, reversing, or straight-crested bedforms in Gale crater sandstones are preserved wave ripples; deposition by waves would demonstrate that the lake was not covered by ice at that time. Wave modeling indicates that regardless of atmospheric density, winds that exceeded the threshold of aeolian sand transport could have generated waves capable of producing nearshore wave ripples in most grain sizes of sand. Reversing 3-m-wavelength bedforms in the Kimberley formation are interpreted not as wave ripples but rather as large aeolian ripples that formed in an atmosphere approximately as thin as at present. These exhumed bedforms define many of the ridges at outcrops that appear striated in satellite images. At Kimberley these bedforms demonstrably underlie and therefore predate subaqueous beds, suggesting that a thin atmosphere existed at least temporarily before subaqueous deposition ceased in the crater. The other three candidate wave ripples (Square Top, Hunda, and Voe) are consistent with modeled waves, but other origins cannot be excluded. The predominance of flat-laminated (non-rippled) beds in the lacustrine Murray formation suggests that some aspect of the lake was not conducive to formation or preservation of recognizable wave ripples. Water depths may generally have been too deep, lakebed sediment may have been too fine-grained, the lake may have been smaller than modeled, or the lake may have been covered by ice. Plain Language Summary Wave modeling and analysis of sedimentary structures were used to evaluate whether ancient lake deposits in Gale crater contain ripples formed by waves on the surface of the lake. Deposition by waves would show that the lake was not covered by ice at that time. Modeling shows that regardless of atmospheric density, winds capable of moving sand on land would generally have been strong enough to form waves that would produce ripples near shore. Large bedforms in the Kimberley formation are interpreted as ripples formed by the wind in an atmosphere similar to that of Mars today. These bedforms underlie and are older than other beds deposited in water, thereby showing that a thin atmosphere existed at least temporarily before deposition in water ceased in the crater. Three other candidate wave ripples are consistent with modeled waves, but other origins are possible. Thick sequences of sedimentary rock in Gale crater are flat-laminated rather than rippled, suggesting that some aspect of the lake was not favorable for their formation or preservation. Much of the lake may have been too deep or ice-covered, or the lake may have been smaller than modeled or had sediment too fine to form easily observed ripples.

Journal of Geophysical Research: Planets↗
USGS2021

Postwildfire soil‐hydraulic recovery and the persistence of debris flow hazards

Deadly and destructive debris flows often follow wildfire, but understanding of changes in the hazard potential with time since fire is poor. We develop a simulation‐based framework to quantify changes in the hydrologic triggering conditions for debris flows as postwildfire infiltration properties evolve through time. Our approach produces time‐varying rainfall intensity‐duration thresholds for runoff‐ and infiltration‐generated debris flows with physics‐based hydrologic simulations that are parameterized with widely available hydroclimatic, vegetation reflectance, and soil texture data. When we apply our thresholding protocol to a test case in the San Gabriel Mountains (California, USA), the results are consistent with existing regional empirical thresholds and rainstorms that caused runoff‐ and infiltration‐generated debris flows soon after and three years following a wildfire, respectively. We find that the hydrologic triggering mechanisms for the two observed debris flow types are coupled with the effects of fire on the soil saturated hydraulic conductivity. Specifically, the rainfall intensity needed to generate debris flows via runoff increases with time following wildfire while the rainfall duration needed to produce debris flows via subsurface pore‐water pressures decreases. We also find that variations in soil moisture, rainfall climatology, median grain size, and root reinforcement could impact the median annual probability of postwildfire debris flows. We conclude that a simulation‐based method for calculating rainfall thresholds is a tractable approach to improve situational awareness of debris flow hazard in the years following wildfire. Further development of our framework will be important to quantify postwildfire hazard levels in variable climates, vegetation types, and fire regimes.

Journal of Geophysical Research: Earth Surface↗
USGS2021

Multi-model comparison of computed debris flow runout for the 9 January 2018 Montecito, California post-wildfire event

Hazard assessment for post-wildfire debris flows, which are common in the steep terrain of the western United States, has focused on the susceptibility of upstream basins to generate debris flows. However, reducing public exposure to this hazard also requires an assessment of hazards in downstream areas that might be inundated during debris flow runout. Debris flow runout models are widely available, but their application to hazard assessment for post-wildfire debris flows has not been extensively tested. Necessary inputs to these models include the total volume of the mobilized flow, flow properties (either inherent material properties or calibration coefficients), and site topography. Estimates of volume are possible in post-event (“back calculation”) studies, yet before an event, volume is an uncertain quantity. We simulated debris flow runout for the well-constrained 9 January 2018 Montecito event using three models (RAMMS, FLO2D, and D-Claw) to determine the relative importance of volume and flow properties. We broke the impacted area into three domains, and for each model-domain combination, we performed a numerical sampling study in which volume and flow properties varied within a wide, but plausible range. We assessed model performance based on inundation patterns and peak flow depths. We found all models could simulate the event with comparable results. Simulation performance was most sensitive to flow volume and less sensitive to flow properties. Our results emphasize the importance of reducing uncertainty in pre-event estimates of flow volume for hazard assessment.

California↗
USGS2022

Vadose zone thickness limits pore-fluid pressures and acceleration in a large, slow-moving landslide

The rate and timing of hydrologically forced landslides is a complex function of precipitation patterns, material properties, topography, and groundwater hydrology. In the simplest form, however, slopes fail when subsurface pore pressure grows large enough to exceed the Mohr-Coulomb failure criterion. The capacity for pore pressure rise in a landslide is determined in part by the thickness of the unsaturated zone above the water table, which itself is set by weathering patterns that should have predictable patterns across different lithologies. To investigate how this structure affects landslide behavior, we exploit a multi-year record of precipitation, pore pressure, and velocity from Oak Ridge earthflow, a slow-moving landslide set in Franciscan mélange, northern California, USA. In conjunction with electrical resistivity tomography and hydraulic conductivity measurements, these data show that Oak Ridge has a thin weathered profile that is comparable in thickness to other mélange landslides in California. We propose that due to the inherently thin vadose zone, mélange landscapes experience an unusually high water table that frequently brings them close to movement; however, the capacity to increase stress is limited by the small amount of dynamic storage available. Instead, excess pore pressure is shed via springs and saturation overland flow once the water table reaches the surface. Linkages between weathering patterns, hydrology, and deformation can explain behavior patterns exhibited by Franciscan mélange earthflows across a large precipitation gradient.

California↗
USGS2022

Multi-decadal simulation of marsh topography evolution under sea level rise and episodic sediment loads

Coastal marsh within Mediterranean climate zones is exposed to episodic watershed runoff and sediment loads that occur during storm events. Simulating future marsh accretion under sea level rise calls for attention to: (a) physical processes acting over the time scale of storm events and (b) biophysical processes acting over time scales longer than storm events. Using the upper Newport Bay in Southern California as a case study, we examine the influence of event-scale processes on simulated change in marsh topography by comparing: (a) a biophysical model that integrates with an annual time step and neglects event-scale processes (BP-Annual), (b) a physical model that resolves event-scale processes but neglects biophysical interactions (P-Event), and (c) a biophysical model that resolves event-scale physical processes and biophysical processes at annual and longer time scales (BP-Event). A calibrated BP-Event model shows that large (>20-year return period) episodic storm events are major drivers of marsh accretion, depositing up to 30 cm of sediment in one event. Greater deposition is predicted near fluvial sources and tidal channels and less on marshes further from fluvial sources and tidal channels. In contrast, the BP-Annual model poorly resolves spatial structure in marsh accretion as a consequence of neglecting event-scale processes. Furthermore, the P-Event model significantly overestimates marsh accretion as a consequence of neglecting marsh surface compaction driven by annual scale biophysical processes. Differences between BP-Event and BP-Annual models translate up to 20 cm per century in marsh surface elevation.

California↗
USGS2021

Storm-scale and seasonal dynamics of carbon export from a nested subarctic watershed underlain by permafrost

Subarctic catchments underlain by permafrost sequester a major stock of frozen organic carbon (C), which may be mobilized as the Arctic warms. Warming can impact C export from thawing soils by altering the depth and timing of runoff related to changing storm and fire regimes and altered soil thaw depths. We investigated C export in a first order headwater stream (West Twin Creek) and its receiving third order river (Beaver Creek) in interior Alaska using discrete sampling of dissolved organic and inorganic C (DOC and DIC) and 15-min collection of specific conductance (SC), fluorescent dissolved organic matter (fDOM) and water discharge (Q). Storm SC-Q relationships displayed negative slopes, indicating solute limitation and limited influence of seasonal soil thaw on storm runoff chemistry. Concurrently, fDOM-Q displayed positive slopes that decreased over the summer, indicating flushing of a limited fDOM pool. Baseflow DIC increased over the season concurrent with soil thaw, with higher DIC at the larger scale indicating greater influence of deeper, mineral-rich flow paths. Storm and seasonal trends were generally similar at both scales. The biggest difference was in fDOM, which displayed higher concentrations and slower depletion in the first order stream. Improved process understanding from this study can be used to better predict carbon export and cycling by stream networks as northern forests and arctic regions continue to warm.

Alaska↗
USGS2021

Event scale relationships of DOC and TDN fluxes in throughfall and stemflow diverge from stream exports in a forested catchment

Aquatic fluxes of carbon and nutrients link terrestrial and aquatic ecosystems. Within forests, storm events drive both the delivery of carbon and nitrogen to the forest floor and the export of these solutes from the land via streams. To increase understanding of the relationships between hydrologic event character and the relative fluxes of carbon and nitrogen in throughfall, stemflow and streams, we measured dissolved organic carbon (DOC) and total dissolved nitrogen (TDN) concentrations in each flow path for 23 events in a forested watershed in Vermont, USA. DOC and TDN concentrations increased with streamflow, indicating their export was limited by water transport of catchment stores. DOC and TDN concentrations in throughfall and stemflow decreased exponentially with increasing precipitation, suggesting that precipitation removed a portion of available sources from tree surfaces during the events. DOC and TDN fluxes were estimated for 76 events across a 2-year period. For most events, throughfall and stemflow fluxes greatly exceeded stream fluxes, but the imbalance narrowed for larger storms (>30 mm). The largest 10 stream events exported 40% of all stream event DOC whereas those same 10 events contributed 14% of all throughfall export. Approximately 2–5 times more DOC and TDN was exported from trees during rain events than left the catchment via streams annually. The diverging influence of event size on tree versus stream fluxes has important implications for forested ecosystems as hydrological events increase in intensity and frequency due to climate change.

Vermont↗
USGS2021

Aquatic-terrestrial linkages control metabolism and carbon dynamics in a mid-sized, urban stream influenced by snowmelt

Freshwater streams can exchange nutrients and carbon with the surrounding terrestrial environment through various mechanisms including physical erosion, flooding, leaf drop, and snowmelt. These aquatic-terrestrial interactions are crucial in carbon mobilization, transformation, ecosystem productivity, and have important implications for the role of freshwater ecosystems in the global carbon budget. We utilized high-frequency oxygen, temperature, and carbon dioxide (CO 2 ) data to infer watershed connectivity in Boulder Creek, a mid-sized (1160 km 2 ) watershed located in Colorado, USA. Daily modeled gross primary production (GPP), ecosystem respiration (ER), net ecosystem production (NEP), and reaeration coefficients ( K 600 ) were paired with high-frequency, in-situ dissolved CO 2 data to characterize changes in metabolic regime and carbon flux on a stream influenced by seasonal snowmelt. GPP and ER were correlated ( ρ = −0.72, p ≪ 0.001) during the non-snowmelt period and NEP was frequently negative. Mean F CO2 during the non-snowmelt period was approximately 302 (±171) mmol C m −2 d −1 and was primarily supported by watershed CO 2 inputs. During snowmelt, GPP and ER were not significantly correlated ( ρ = −0.22, p = 0.05), and mean NEP was significantly more negative than during non-snowmelt. Watershed connectivity was higher during snowmelt, as evidenced by significantly higher F CO2 (843 ± 338 mmol C m −2 d −1 ) and greater allochthonous CO 2 inputs than during non-snowmelt periods, emphasizing the effects of seasonal differences in aquatic-terrestrial linkages in this stream. We suggest that our understanding of watershed carbon budgets is subject to temporal dynamics which control the degree of connectivity between terrestrial and aquatic ecosystems.

Colorado↗
USGS2021

Spatiotemporal methane emission from global reservoirs

Inland aquatic systems, such as reservoirs, contribute substantially to global methane (CH 4 ) emissions; yet are among the most uncertain components of the total CH 4 budget. Reservoirs have received recent attention as they may generate high CH 4 fluxes. Improved quantification of these CH 4 fluxes, particularly their spatiotemporal distribution, is key to realistically incorporating them in CH 4 modeling and budget studies. Here we report on a new global, gridded (0.25° lat × 0.25° lon) study of reservoir CH 4 emissions, accounting for new knowledge regarding reservoir areal extent and distribution, and spatiotemporal emission patterns influenced by diurnal variability, temperature-dependent seasonality, satellite-derived freeze-thaw dynamics, and eco-climatic zone. The results of this new data set comprise daily CH 4 emissions throughout the full annual cycle and show that reservoirs cover 297 × 10 3 km 2 globally and emit 10.1 Tg CH 4 yr −1 (1σ uncertainty range of 7.2–12.9 Tg CH 4 yr −1 ) from diffusive (1.2 Tg CH 4 yr −1 ) and ebullitive (8.9 Tg CH 4 yr −1 ) emission pathways. This analysis of reservoir CH 4 emission addresses multiple gaps and uncertainties in previous studies and represents an important contribution to studies of the global CH 4 budget. The new data sets and methodologies from this study provide a framework to better understand and model the current and future role of reservoirs in the global CH 4 budget and to guide efforts to mitigate reservoir-related CH 4 emissions.

Journal of Geophysical Research: Biogeosciences↗
USGS2021

Loss of ice cover, shifting phenology, and more extreme events in Northern Hemisphere lakes

Long-term lake ice phenological records from around the Northern Hemisphere provide unique sensitive indicators of climatic variations, even prior to the existence of physical meteorological measurement stations. Here, we updated ice phenology records for 60 lakes with time-series ranging from 107–204 years to provide the first re-assessment of Northern Hemispheric ice trends since 2004 by adding 15 additional years of ice phenology records and 40 lakes to our study. We found that, on average, ice-on was 11.0 days later, ice-off was 6.8 days earlier, and ice duration was 17.0 days shorter per century over the entire record for each lake. Trends in ice-on and ice duration were six times faster in the last 25-year period (1992–2016) than previous quarter centuries. More extreme events in recent decades, including late ice-on, early ice-off, shorter periods of ice cover, or no ice cover at all, contribute to the increasing rate of lake ice loss. Reductions in greenhouse gas emissions could limit increases in air temperature and abate losses in lake ice cover that would subsequently limit ecological, cultural, and socioeconomic consequences, such as increased evaporation rates, warmer water temperatures, degraded water quality, and the formation of toxic algal blooms.

Journal of Geophysical Research: Biogeosciences↗
USGS2021

Episodic nutrient addition affects water column nutrient processing rates in river-to-lake transitional zones

Storm-driven nutrient loading from tributaries can fuel eutrophication in nearshore and open water areas of lentic ecosystems. However, nutrient processing in river-to-lake transitional zones can substantially alter the amount and composition of nutrients transported to lakes from upstream surface waters. We measured the removal of nutrients and dissolved organic carbon (DOC) from the water column in the Fox rivermouth (Green Bay, Lake Michigan) to evaluate the response of rivermouth plankton to episodic nutrient enrichment. Light and dark water column incubations (8–12 hr) were conducted on four occasions from April through September to measure changes in dissolved nitrogen (N), phosphorus (P), and DOC concentrations in three locations along the Fox rivermouth. Two incubation experiments were conducted on consecutive days, (a) under ambient nutrient concentrations, and (b) under experimentally enriched N and P concentrations. Spatial and temporal variation was observed in nutrient uptake rates, but light incubations consistently had higher nutrient uptake rates than dark incubations. Nutrient enrichment increased total dissolved P and total dissolved N uptake and DOC release in light incubations, but only increased total dissolved P uptake in dark incubations. Moreover, nutrient uptake ratios (N:P) decreased from ambient to nutrient enriched conditions and indicated preferential P uptake by phytoplankton communities in light conditions. Our study substantiates that rivermouths can process nutrients bound for downstream ecosystems and demonstrates the potential of plankton communities to dynamically increase net uptake rates in response to episodic nutrient enrichment.

Wisconsin↗
USGS2021

Lagged wetland CH4 flux response in a historically wet year

While a stimulating effect of plant primary productivity on soil carbon dioxide (CO 2 ) emissions has been well documented, links between gross primary productivity (GPP) and wetland methane (CH 4 ) emissions are less well investigated. Determination of the influence of primary productivity on wetland CH 4 emissions (FCH 4 ) is complicated by confounding influences of water table level and temperature on CH 4 production, which also vary seasonally. Here, we evaluate the link between preceding GPP and subsequent FCH 4 at two fens in Wisconsin using eddy covariance flux towers, Lost Creek (US-Los) and Allequash Creek (US-ALQ). Both wetlands are mosaics of forested and shrub wetlands, with US-Los being larger in scale and having a more open canopy. Co-located sites with multi-year observations of flux, hydrology, and meteorology provide an opportunity to measure and compare lag effects on FCH 4 without interference due to differing climate. Daily average FCH 4 from US-Los reached a maximum of 47.7 ηmol CH 4 m −2 s −1 during the study period, while US-ALQ was more than double at 117.9 ηmol CH 4 m −2 s −1 . The lagged influence of GPP on temperature-normalized FCH 4 ( T air -FCH 4 ) was weaker and more delayed in a year with anomalously high precipitation than a following drier year at both sites. FCH 4 at US-ALQ was lower coincident with higher stream discharge in the wet year (2019), potentially due to soil gas flushing during high precipitation events and lower water temperatures. Better understanding of the lagged influence of GPP on FCH 4 due to this study has implications for climate modeling and more accurate carbon budgeting.

Journal of Geophysical Research: Biogeosciences↗
USGS2021

Climatic controls on soil carbon accumulation and loss in a dryland ecosystems

Arid and semiarid ecosystems drive year-to-year variability in the strength of the terrestrial carbon (C) sink, yet there is uncertainty about how soil C gains and losses contribute to this variation. To address this knowledge gap, we embedded C-depleted soil mesocosms, containing litter or biocrust C inputs, within an in situ dryland ecosystem warming experiment. Over the course of one year, changes in microbial biomass and total soil organic C pools were monitored alongside hourly measurements of soil CO 2 flux. We also developed a biogeochemical model to explore the mechanisms that gave rise to observed soil C dynamics. Field data and model simulations demonstrated that water exerted much stronger control on soil biogeochemistry than temperature, with precipitation events triggering large CO 2 pulses and transport of litter- and biocrust-derived C into the soil profile. We expected leaching of organic matter would result in steady accumulation of C within the mineral soil over time. Instead, the size of the total organic C pool fluctuated throughout the year, largely in response to microbial growth: increases in the size of microbial biomass were negatively correlated with the quantity of C residing in the top 2 cm, where most biogeochemical changes were observed. Our data and models suggest that microbial responses to precipitation events trigger rapid metabolism of dissolved organic C inputs, which strongly limit accumulation of autotroph-derived C belowground. Accordingly, changes in the magnitude and/or frequency of precipitation events in this dryland ecosystem could have profound impacts on the strength of the soil C sink.

Utah↗
USGS2021

Spatiotemporal dynamics of CO2 gas exchange from headwater mountain streams

Mountain streams play an important role in the global carbon cycle by transporting, metabolizing, and exchanging carbon they receive from the terrestrial environment. The rates at which these processes occur remain highly uncertain because of a paucity of observations and the difficulty of measuring gas exchange rates in steep, turbulent mountain streams. This uncertainty is compounded by large temporal and spatial variability in stream carbon dioxide (CO 2 ) concentrations in mountain environments. In this study, we measured diel, seasonal, and annual variations in CO 2 partial pressure ( p CO 2 ) in seven headwater streams and a groundwater spring in the Colorado Rocky Mountains to determine how CO 2 exchange fluxes ( ) vary with time, annual precipitation, and landscape characteristics. Our results show that temporal variability in p CO 2 and in mountain streams is large and is strongly influenced by solar radiation, the accumulation and melting of seasonal snowpacks, and interannual variations in precipitation. Spatial variations in p CO 2 and were related to landscape characteristics, with soil organic matter, wetlands, and likely groundwater discharge zones having a positive influence. Periglacial features, such as ice and rock glaciers, had a negative influence on stream p CO 2 and . Estimated from streams in an alpine/subalpine region of Colorado was 3.4 kg C m −2 yr −1 normalized to stream surface area (95% CI: 2.1–5.0 kg C m −2 yr −1 ), consistent with recent work on CO 2 exchange from mountain streams in the Swiss Alps. Our results highlight the importance of mountain streams as substantial contributors in the global carbon cycle.

Colorado↗
USGS2022

Microbially induced anaerobic oxidation of magnetite to maghemite in a hydrocarbon-contaminated aquifer

Iron mineral transformations occurring in hydrocarbon-contaminated sites are linked to the biodegradation of the hydrocarbons. At a hydrocarbon-contaminated site near Bemidji, Minnesota, USA, measurements of magnetic susceptibility (MS) are useful for monitoring the natural attenuation of hydrocarbons related to iron cycling. However, a transient MS, previously observed at the site, remains poorly understood and the iron mineral phases acting as reactants and products associated with this MS perturbation remain largely unknown. To address these unknowns, we acquired mineral magnetism measurements, including hysteresis loops, backfield curves, and isothermal remanent magnetizations on sediment core samples retrieved from the site and magnetite-filled mineral packets installed within the aquifer. Our data show that the core samples and magnetite packs display decreasing magnetization with time and that this loss in magnetization is accompanied by increasing bulk coercivity consistent with decreased average grain size and/or partial oxidation. Low-temperature magnetometry on all samples displayed behavior consistent with magnetite, but samples within the plume also show evidence of maghemitization. This interpretation is supported by the occurrence of shrinkage cracks on the surface of the grains imaged via scanning electron microscopy. Magnetite transformation to maghemite typically occurs under oxic conditions, here, we propose that maghemitization occurs within the anoxic portions of the plume via microbially mediated anaerobic oxidation. Mineral dissolution also occurs within the plume. Microorganisms capable of such anaerobic oxidation have been identified within other areas at the Bemidji site, but additional microbiological studies are needed to link specific anaerobic iron oxidizers with this loss of magnetization.

Minnesota↗