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Trends in lake chemistry in response to atmospheric deposition and climate in selected Class I wilderness areas in Colorado, Idaho, Utah, and Wyoming, 1993-2009

In 2010, the U.S. Geological Survey, in cooperation with the U.S. Department of Agriculture Forest Service, Air Resource Management, began a study to evaluate long-term trends in lake-water chemistry for 64 high-elevation lakes in selected Class I wilderness areas in Colorado, Idaho, Utah, and Wyoming during 1993 to 2009. The purpose of this report is to describe trends in the chemical composition of these high-elevation lakes. Trends in emissions, atmospheric deposition, and climate variables (air temperature and precipitation amount) are evaluated over a similar period of record to determine likely drivers of changing lake chemistry. Sulfate concentrations in precipitation decreased over the past two decades at high-elevation monitoring stations in the Rocky Mountain region. The trend in deposition chemistry is consistent with regional declines in sulfur dioxide emissions resulting from installation of emission controls at large stationary sources. Trends in nitrogen deposition were not as widespread as those for sulfate. About one-half of monitoring stations showed increases in ammonium concentrations, but few showed significant changes in nitrate concentrations. Trends in nitrogen deposition appear to be inconsistent with available emission inventories, which indicate modest declines in nitrogen emissions in the Rocky Mountain region since the mid-1990s. This discrepancy may reflect uncertainties in emission inventories or changes in atmospheric transformations of nitrogen species that may be affecting deposition processes. Analysis of long-term climate records indicates that average annual mean air temperature minimums have increased from 0.57 to 0.75 °C per decade in mountain areas of the region with warming trends being more pronounced in Colorado. Trends in annual precipitation were not evident over the period 1990 to 2006, although wetter than average years during 1995 to 1997 and drier years during 2001 to 2004 caused a notable decline in precipitation in the middle part of the record.

Colorado;Idaho;Utah;Wyoming

Flood recovery maps for the White River in Bethel, Stockbridge, and Rochester, Vermont, and the Tweed River in Stockbridge and Pittsfield, Vermont, 2014

From August 28 to 29, 2011, Tropical Storm Irene delivered rainfall ranging from about 4 inches to more than 7 inches in the White River Basin. The rainfall resulted in severe flooding throughout the basin and significant damage along the White River and Tweed River. In response to the flooding, the U.S. Geological Survey, in cooperation with the Federal Emergency Management Agency, conducted a new flood study to aid in the flood recovery and restoration. This flood study includes a 20.7-mile reach of the White River from the downstream end at about 2,000 feet downstream from the State Route 107 bridge in the Village of Bethel, Vermont, to the upstream end at about 1,000 feet upstream from the River Brook Drive bridge in the Village of Rochester, Vt., and a 7.9-mile reach of the Tweed River from its mouth in Stockbridge, Vt., to the confluence of the West and South Branches of the Tweed River and continuing upstream on the South Branch Tweed River to the Pittsfield, Vt., town line. This report presents water-surface elevations determined for the study reaches using the U.S. Army Corps of Engineers one-dimensional step-backwater Hydrologic Engineering Center River Analysis System model, also known as HEC– RAS. The water-surface elevations were determined for floods having a 10-, 4-, 2-, 1-, and 0.2-percent annual exceedance probability (AEP) and for the floodway. Eighteen high-water marks from Tropical Storm Irene were available along the studied reaches. The discharges in the Tropical Storm Irene HEC–RAS model were adjusted so that the resulting water-surface elevations matched the high-water mark elevations along the study reaches. This allowed for an estimation of the water-surface profile throughout the study area resulting from Tropical Storm Irene. From a comparison of the estimated water-surface profile of Tropical Storm Irene to the water-surface profiles of the 1- and 0.2-percent AEP floods, it was determined that the high-water elevations resulting from Tropical Storm Irene exceeded the estimated 1-percent AEP flood throughout the White River and Tweed River study reaches and exceeded the estimated 0.2-percent AEP flood in 16.7 of the 28.6 study reach miles. The simulated water-surface profiles were then combined with a geographic information system digital elevation model derived from light detection and ranging (lidar) data having a 18.2-centimeter vertical accuracy at the 95-percent confidence level and 1-meter horizontal resolution to delineate the area flooded for each water-surface profile.

Vermont

Performance of Traditional and Molecular Methods for Detecting Biological Agents in Drinking Water

To reduce the impact from a possible bioterrorist attack on drinking-water supplies, analytical methods are needed to rapidly detect the presence of biological agents in water. To this end, 13 drinking-water samples were collected at 9 water-treatment plants in Ohio to assess the performance of a molecular method in comparison to traditional analytical methods that take longer to perform. Two 100-liter samples were collected at each site during each sampling event; one was seeded in the laboratory with six biological agents - Bacillus anthracis (B. anthracis), Burkholderia cepacia (as a surrogate for Bu. pseudomallei), Francisella tularensis (F. tularensis), Salmonella Typhi (S. Typhi), Vibrio cholerae (V. cholerae), and Cryptospordium parvum (C. parvum). The seeded and unseeded samples were processed by ultrafiltration and analyzed by use of quantiative polymerase chain reaction (qPCR), a molecular method, and culture methods for bacterial agents or the immunomagnetic separation/fluorescent antibody (IMS/FA) method for C. parvum as traditional methods. Six replicate seeded samples were also processed and analyzed. For traditional methods, recoveries were highly variable between samples and even between some replicate samples, ranging from below detection to greater than 100 percent. Recoveries were significantly related to water pH, specific conductance, and dissolved organic carbon (DOC) for all bacteria combined by culture methods, but none of the water-quality characteristics tested were related to recoveries of C. parvum by IMS/FA. Recoveries were not determined by qPCR because of problems in quantifying organisms by qPCR in the composite seed. Instead, qPCR results were reported as detected, not detected (no qPCR signal), or +/- detected (Cycle Threshold or 'Ct' values were greater than 40). Several sample results by qPCR were omitted from the dataset because of possible problems with qPCR reagents, primers, and probes. For the remaining 14 qPCR results (including some replicate samples), F. tularensis and V. cholerae were detected in all samples after ultrafiltration, B. anthracis was detected in 13 and +/- detected in 1 sample, and C. parvum was detected in 9 and +/- detected in 4 samples. Bu. cepacia was detected in nine samples, +/- detected in two samples, and not detected in three samples (for two out of three samples not detected, a different strain was used). The qPCR assay for V. cholerae provided two false positive - but late - signals in one unseeded sample. Numbers found by qPCR after ultrafiltration were significantly or nearly significantly related to those found by traditional methods for B. anthracis, F. tularensis, and V. cholerae but not for Bu. cepacia and C. parvum. A qPCR assay for S. Typhi was not available. The qPCR method can be used to rapidly detect B. anthracis, F. tularensis, and V. cholerae with some certainty in drinking-water samples, but additional work would be needed to optimize and test qPCR for Bu. cepacia and C. parvum and establish relations to traditional methods. The specificity for the V. cholerae assay needs to be further investigated. Evidence is provided that ultrafiltration and qPCR are promising methods to rapidly detect biological agents in the Nation's drinking-water supplies and thus reduce the impact and consequences from intentional bioterrorist events. To our knowledge, this is the first study to compare the use of traditional and qPCR methods to detect biological agents in large-volume drinking-water samples.

Scientific Investigations Report

Geologic and geophysical models for Osage County, Oklahoma, with implications for groundwater resources

This report summarizes a three-dimensional (3-D) geologic model that was constructed to provide a framework to investigate groundwater resources of the Osage Nation in northeastern Oklahoma. This report also presents an analysis of an airborne electromagnetic (AEM) survey that assessed the spatial variation of electrical resistivity to depths as great as 300 meters in the subsurface. The report and model provide support for a countywide assessment of groundwater resources, emphasizing the Upper Pennsylvanian rock units in the shallow subsurface of central and eastern Osage County having electrical resistivity properties that may indicate aquifers. Surface outcrops and subsurface stratigraphic picks on wire-line geophysical logs of Upper Pennsylvanian–Lower Permian sedimentary rock were used to construct a 3-D model of the geologic subsurface as an aid for evaluating groundwater resources in Osage County. Quaternary alluvium and terraces along major streams and the Arkansas River are included in the geologic framework model. Data from the AEM survey were subjected to quality-control procedures, truncated at depth of investigation (DOI), and then used to build a 3-D electrical resistivity model making use of secondary and tertiary interpolation profiles between primary data profiles. The AEM data highlight westward-inclined resistivity gradients that parallel the shallow dip of bedrock strata; bodies have resistivity >30 ohm-meters, and extend as much as 10 kilometers (km) down the dip of host geologic units. Volume analysis and internal imaging of an integrated 3-D geology and electrical resistivity model give a proxy for likely aquifer units with large relative volumes of high resistivity: Quaternary alluvium, Elgin Sandstone Lentil in the upper part of the Vamoosa Group, Tallant Formation, and parts of a combined Wann-Iola-Chanute Formation. Less voluminous, high-resistivity bodies correspond to intervals in the lower part of the Vamoosa Group in the east-central part of the county and probable limestone intervals in the upper part of the Vanoss Group in the northwest part of the county. Northwestern and eastern troughs of potable water previously defined for central Osage County generally correspond to down-dip projections of high-resistivity bodies associated with the Elgin Sandstone Lentil of the Vamoosa Group and Tallant Formation, respectively.

Oklahoma

External quality-assurance project report for the National Atmospheric Deposition Program/National Trends Network and Mercury Deposition Network, 2009-2010

The U.S. Geological Survey operated six distinct programs to provide external quality-assurance monitoring for the National Atmospheric Deposition Program/National Trends Network (NTN) and Mercury Deposition Network (MDN) during 2009–2010. The field-audit program assessed the effects of onsite exposure, sample handling, and shipping on the chemistry of NTN samples; a system-blank program assessed the same effects for MDN. Two interlaboratory-comparison programs assessed the bias and variability of the chemical analysis data from the Central Analytical Laboratory (CAL) and Mercury (Hg) Analytical Laboratory (HAL). The blind-audit program was also implemented for the MDN to evaluate analytical bias in total Hg concentration data produced by the HAL. The co-located-sampler program was used to identify and quantify potential shifts in NADP data resulting from replacement of original network instrumentation with new electronic recording rain gages (E-gages) and precipitation collectors that use optical sensors. The results indicate that NADP data continue to be of sufficient quality for the analysis of spatial distributions and time trends of chemical constituents in wet deposition across the United States. Results also suggest that retrofit of the NADP networks with the new precipitation collectors could cause –8 to +14 percent shifts in NADP annual precipitation-weighted mean concentrations and total deposition values for ammonium, nitrate, sulfate, and hydrogen ion, and larger shifts (+13 to +74 percent) for calcium, magnesium, sodium, potassium, and chloride. The prototype N-CON Systems bucket collector is more efficient in the catch of precipitation in winter than Aerochem Metrics Model 301 collector, especially for light snowfall.

Scientific Investigations Report

Contaminants in stream sediments from seven U.S. metropolitan areas: Data summary of a National Pilot Study

This report presents data collected as a part of a synoptic survey of stream sediment contaminants, associated watershed characteristics and invertebrate responses in laboratory sediment toxicity tests from 98 streams (sites) in seven metropolitan study areas across the continental United States. The report presents methods, data, and sediment-quality guidelines, including the derivation of a new sediment pyrethroid probable effects concentration, for the purposes of relating measured contaminants to land use and toxicity evaluation. The study evaluated sites that ranged in their degree of relative urbanization within the study areas of Atlanta, Boston, Dallas-Fort Worth, Denver, Milwaukee-Green Bay, Salt Lake City, and Seattle-Tacoma. In all, 108 chemical analytes quantified in the study are presented, by class and number of individual compounds, as follows: polyaromatic hydrocarbons (PAHs) (28), organochlorine pesticides (OCs) (18), polychlorinated biphenyls (Aroclors) (3), pyrethroid insecticides (14), fipronil compounds (4), priority trace and other major elements (41). The potential of these sediments to cause toxicity to sediment-dwelling invertebrates was evaluated using two standard sediment toxicity tests: a 28-day growth and survival toxicity test with the amphipod Hyalella azteca, and a 10-day growth and survival toxicity test with the midge Chironomus dilutus. Further, approximately 95 relevant watershed and reach-level characteristics were generated and are presented to aid in interpretation and explanation of contaminant and toxicity patterns. Interpretation of the findings of this study, including the relationships with urbanization and other factors, the relationship between sediment toxicity and sediment chemistry in the seven study areas, and the sources and occurrence of pyrethroid insecticides, are discussed in detail in a forthcoming series of journal articles.

Boston;Atlanta;Milwaukee;Green Bay;Dallas;Fort Wor

Bathymetric and velocimetric surveys at highway bridges crossing the Missouri and Mississippi Rivers near St. Louis, Missouri, August 3–10, 2020

Bathymetric and velocimetric data were collected by the U.S. Geological Survey, in cooperation with the Missouri Department of Transportation, near 15 bridges at 10 highway crossings of the Missouri and Mississippi Rivers near Washington, Louisiana, and St. Louis, Missouri, on August 3–10, 2020. A multibeam echosounder mapping system was used to obtain channel-bed elevations for river reaches about 1,640 to 1,970 feet longitudinally and generally extending laterally across the active channel from bank to bank during moderate flood-flow conditions. These surveys provided channel geometry and hydraulic conditions at the time of the surveys and provided characteristics of scour holes that may be useful in developing predictive guidelines or equations for computing potential scour depth. These data also may be useful to the Missouri Department of Transportation as a low to moderate flood-flow assessment of the bridges for stability and integrity issues with respect to bridge scour during floods. Bathymetric data were collected around every in-channel pier. Scour holes were present at most piers for which bathymetry could be obtained, except those on banks or surrounded by riprap. All the bridge sites in this study were previously surveyed and documented in previous studies, including the two new bridge structures at Louisiana and Washington (structures A8141 and A8504, sites 22 and 32, respectively). Comparisons between bathymetric surfaces from the previous surveys and those of the current (2020) study do not indicate any consistent correlation in channel-bed elevations with streamflow conditions. The comparisons of the 2020 surveys to two previous surveys at the new bridge structure A8141 at Washington (site 22) resulted in net erosion of the channel bed in both comparisons, despite the 2020 streamflow being less than either previous survey. Alternatively, there was a net gain of sediment at new bridge structure A8504 at Louisiana (site 32) between 2014 and 2020, which was the most substantial increase in the surveys detailed in this report; substantially less flow in 2020 than in 2014 or changes to the channel and spur dikes near the bridge may have contributed to the observed sediment gain. Pier size, nose shape, and skew to approach flow had a substantial effect on the size of the scour hole observed at a given pier. Larger and deeper scour holes were present at piers with wide or blunt noses caused by exposed footings, seal courses, or caissons. When a pier was skewed to primary approach flow, the scour hole was generally deeper and larger than at a similar pier without skew; however, the shape of the scour hole near skewed piers in this study generally was longer and deeper on the leeward side, contrary to the general shape of scour holes for skewed piers. However, this phenomenon has been observed historically at these sites, and likely is exacerbated by debris rafts or other turbulence-inducing features near the atypical scour holes. A substantial scour hole was observed near pier 11 of structure A6500 (site 33), which was deeper than in the 2016 survey. The scour holes observed at pier 17 of structure L0561 (site 25) and piers 3 and 4 of structure A1500 (site 34) also were slightly deeper and wider in 2020 than in 2016. At new bridge structures A8141 at Washington (site 22) and A8504 at Louisiana (site 32), the smaller cross-sectional area and configuration of the piers of the new bridges resulted in substantially less scour than with the wider old piers.

Illinois, Missouri

External quality-assurance project report for the National Atmospheric Deposition Program National Trends Network and Mercury Deposition Network, 2021–22

The U.S. Geological Survey Precipitation Chemistry Quality Assurance project (PCQA) operated five distinct programs to provide external quality-assurance monitoring for the National Atmospheric Deposition Program (NADP) National Trends Network (NTN) and Mercury Deposition Network (MDN) during 2021–22. The NTN programs included (1) a field audit program to evaluate sample contamination and stability, (2) an interlaboratory-comparison program to evaluate analytical laboratory performance, and (3) a colocated sampler program to estimate overall variability of NTN wet-deposition measurements, and the MDN programs included the (4) system blank program to evaluate sample contamination and stability and (5) an interlaboratory-comparison program. The results indicated increased levels of sample contamination compared to previous years for NTN samples and decreased contamination in MDN samples. Strong analytical laboratory performance with low overall variability and bias in concentration data was indicated for the NTN Central Analytical Laboratory. Slight perturbations in contamination levels in NTN samples and in analytical performance for MDN are considered inconsequential. The colocated sampler program results indicated overall variability in NTN data to range from 0 to 30.3 percent for cations, 1.6 to 11.4 percent for ammonium, 0.8 to 20.2 percent for anions, 10.3 to 17.2 percent for hydrogen-ion concentration, and 1.5 to 12.2 percent for specific conductance. The PCQA results indicate that NADP data continue to be of sufficient quality for applications in independent research and NADP data products, including spatial interpolations and time trends for chemical constituents in wet deposition. Small shifts in data quality indicated by the 2021–22 PCQA results are included to be used for interpretation of the NADP data products.

Scientific Investigations Report

Environmental baseline study of the Huron River Watershed, Baraga and Marquette Counties, Michigan

This report summarizes results of a study to establish water-quality and geochemical baseline conditions within a small watershed in the Lake Superior region. In 2008, the U.S. Geological Survey (USGS) completed a survey of water-quality parameters and soil and streambed sediment geochemistry of the 83 mi2 Huron River Watershed in the Upper Peninsula of Michigan. Streamflow was measured and water-quality samples collected at a range of flow conditions from six sites on the major tributaries of the Huron River. All water samples were analyzed for a suite of common ions, nutrients, and trace metals. In addition, water samples from each site were analyzed for unfiltered total and methylmercury once during summer low-flow conditions. Soil samples were collected from 31 sites, with up to 4 separate samples collected at each site, delineated by soil horizon. Streambed sediments were collected from 11 sites selected to cover most of the area drained by the Huron River system. USGS data were supplemented with ecological assessments completed in 2006 by the Michigan Department of Environmental Quality using a modified version of their Great Lakes Environmental Assessment Section procedure 51, and again during 2008 using volunteers under supervision of the Michigan Department of Natural Resources. Results from this study define a hydrological, geological, and environmental baseline for the Huron River Watershed prior to any significant mineral exploration or development. Results from the project also serve to refine the design of future regional environmental baseline studies in the Lake Superior Basin.

Scientific Investigations Report

Environmental factors that influence the location of crop agriculture in the conterminous United States

This report presents and describes high-resolution geospatial data identifying the range of environmental conditions that influence the location of cropped agricultural lands in the conterminous United States. Also presented are estimates of the extent of land where environmental constraints limit agricultural production (marginal land) and the extents of land where modifications overcome environmental constraints. The report is the result of the compilation and manipulation of datasets from numerous sources; it consists of an explanatory text and a series of appendixes and associated tables that document the data sources and data-manipulation methods in detail. Environmental factors that influence the extent of crop agriculture are terrain, climate, soil properties, and soil water. It is the combination of these four factors that allow specific crops to be grown in certain areas. Today, in order to maximize production, most of the cultivated croplands and grasslands for commercial agriculture are in areas where crops and livestock are well suited to local conditions. In the United States, cropland (row crops, closely sown crops (except hay), fruits, nuts, vegetables) occupies about 13 percent of the total land area. Grassland and rangeland occupy another 41 percent of the land area. Most crops are grown on land with shallow slope where the temperature, precipitation, and soils are favorable. In areas that are too steep, wet, or dry, landscapes have been modified to allow cultivation. Some of the limitations of the environmental factors that determine the location of agriculture can be overcome through modifications, but others cannot. On a larger-than-field scale, agricultural modifications commonly influence water availability through irrigation and (or) drainage and soil fertility and (or) organic-matter content through amendments such as manure, commercial fertilizer and lime. In general, it is not feasible to modify the other environmental factors, soil texture, soil depth, soil mineralogy, temperature, and terrain at large scales.

Scientific Investigations Report

Water-quality characteristics of urban storm runoff at selected sites in East Baton Rouge Parish, Louisiana, February 2006 through November 2009

Water samples were collected at three watersheds in East Baton Rouge Parish, Louisiana, during February 2006 through November 2009 for continued evaluation of urban storm runoff. The watersheds represented land uses characterized predominantly as established commercial, industrial, and residential. The following water-quality data are reported: physical and chemical-related properties, fecal coliform, nutrients, trace elements, and organic compounds. Results of water-quality analyses enabled calculation of event-mean concentrations and estimated annual contaminant loads and yields of storm runoff from nonpoint sources for 12 water-quality properties and constituents. Lead met or exceeded the U.S. Environmental Protection Agency Maximum Contaminant Level of 15 micrograms per liter for drinking water standards in 4 of 14 samples. Low level concentrations of mercury were detected in all 14 samples, and half were two to four times above the reporting limit of 0.02 micrograms per liter. The average dissolved phosphorus concentrations from each land use were two to four times the U.S. Environmental Protection Agency criterion of 0.05 milligrams per liter. Diazinon was detected in one sample at a concentration of 0.2 micrograms per liter. In the residential watershed, the largest at 216 acres, contaminant loads for 5 of the 12 water-quality properties and constituents were highest, with 4 of these being nutrients. The industrial watershed, 97 acres, had the highest contaminant loads for 6 of the 12 water-quality properties and constituents with 3 of these being metals, which is indicative of the type of land use. Zinc had the highest metal load (155 pounds per year) in the industrial watershed, compared to 36 pounds per year in the residential watershed, and 32 pounds per year in the established commercial watershed. The industrial watershed had the highest yields for 8 of the 12 water-quality properties and constituents, whereas the established commercial watershed had the lowest yield for 5 of the 12. Lower yields from the established commercial and residential watersheds could be from Best Management Practices in place that help control increased runoff from impervious areas and land development. Metal yields from all the watersheds were less than 1 pound per acre per year, except for the zinc from the industrial watershed, which was 2 pounds per acre per year. Nutrient yields in the established commercial watershed were lowest for total nitrogen, ammonia plus organic nitrogen (Kjeldahl nitrogen), and dissolved phosphorus.

Louisiana

Aquifers of Arkansas: protection, management, and hydrologic and geochemical characteristics of groundwater resources in Arkansas

Sixteen aquifers in Arkansas that currently serve or have served as sources of water supply are described with respect to existing groundwater protection and management programs, geology, hydrologic characteristics, water use, water levels, deductive analysis, projections of hydrologic conditions, and water quality. State and Federal protection and management programs are described according to regulatory oversight, management strategies, and ambient groundwater-monitoring programs that currently (2013) are in place for assessing and protecting groundwater resources throughout the State. Physical attributes, groundwater geochemistry, and groundwater quality are described for each of the 16 aquifers of the State. Information in regard to the hydrology and geochemistry of each of the aquifers is summarized from about 550 historical and recent publications. Additionally, more than 8,000 sites with groundwater-quality data were obtained from the U.S. Geological Survey National Water Information System and the Arkansas Department of Environmental Quality databases and entered into a spatial database to investigate distribution and trends in chemical constituents for each of the aquifers. The 16 aquifers of the State were divided into two major physiographic regions of the State: the Coastal Plain Province (referred to as Coastal Plain) of eastern and southern Arkansas, which includes 11 of the 16 aquifers, and the Interior Highlands Division (referred to as Interior Highlands) of western Arkansas, which includes the remaining 5 aquifers. The 11 aquifers in the Coastal Plain consist of various geologic units that are Cenozoic in age and consist primarily of Cretaceous, Tertiary, and Quaternary sands, gravels, silts, and clays. Groundwater in the Coastal Plain represents one of the most valuable natural resources in the State, driving the economic engines of agriculture, while also supplying abundant water for commercial, industrial, and public-supply use. In terms of age from youngest to oldest, the aquifers of the Coastal Plain include Quaternary alluvial aquifers, including the Mississippi River Valley alluvial aquifer (the most important aquifer in Arkansas in terms of volume of use and economic benefits), the Jackson Group (a regional confining unit that served for decades as an important source of domestic supply), and the Cockfield, Sparta, Cane River, Carrizo, Wilcox, Nacatoch, Ozan, Tokio, and Trinity aquifers. The Mississippi River Valley alluvial aquifer accounts for approximately 94 percent of all groundwater used in the State, and the aquifer is used primarily for irrigation purposes. The Sparta aquifer is the second most important aquifer in terms of use, and the aquifer was used in the past dominantly as a source of public and industrial supply, although increasing irrigation use is occurring because of critically declining water levels in the Mississippi River Valley alluvial aquifer. Other aquifers of the Coastal Plain generally are used as important local sources of domestic, industrial, and public supply, in addition to other minor uses. Water quality generally is good for all aquifers of the Coastal Plain, except for elevated iron concentrations and localized areas of high salinity. The high salinity results from intrusion from underlying formations, evapotranspiration processes in areas of low recharge, and inadequate flushing in downgradient areas of residual salinity from deposition in marine environments. Trends in the spatial distribution of individual chemical constituents are related to position along the flow path for most aquifers of the Coastal Plain. These trends include elevated iron and nitrate concentrations with lower pH values and dissolved solids in groundwater from the outcrop areas, transitioning to lower iron and nitrate (related to changes in redox) and higher pH and dissolved solids (dominantly from the dissolution of carbonate minerals) in groundwater downgradient from outcrop areas. Groundwater generally trended from a calcium- to a sodium-bicarbonate water type with increasing cation exchange along the flow path. The Interior Highlands of western Arkansas has less reported groundwater use than other areas of the State, reflecting a combination of factors. These factors include prevalent and increasing use of surface water, less intensive agricultural uses, lower population and industry densities, lesser potential yield of the resource, and lack of detailed reporting. The overall low yields of aquifers of the Interior Highlands result in domestic supply as the dominant use, with minor industrial, public, and commercial-supply use. Where greater volumes are required for growth of population and industry, surface water is the greatest supplier of water needs in the Interior Highlands. The various aquifers of the Interior Highlands generally occur in shallow, fractured, well-indurated, structurally modified bedrock of this mountainous region of the State, as compared to the relatively flat-lying, unconsolidated sediments of the Coastal Plain. In terms of age from youngest to oldest, the aquifers of the Interior Highlands include: the Arkansas River Valley alluvial aquifer, the Ouachita Mountains aquifer, the Western Interior Plains confining system, the Springfield Plateau aquifer, and the Ozark aquifer. Spatial trends in groundwater geochemistry in the Interior Highlands differ greatly from trends noted for aquifers of the Coastal Plain. In the Coastal Plain, the prevalence of long regional flow paths results in regionally predictable and mappable geochemical changes along the flow paths. In the Interior Highlands, short, topographically controlled flow paths (from hilltops to valleys) within small watersheds represent the predominant groundwater-flow system. As such, dense data coverage from numerous wells would be required to effectively characterize these groundwater basins and define small-scale geochemical changes along any given flow path for aquifers of the Interior Highlands. Changes in geochemistry generally were related to rock type and residence time along individual flow paths. Dominant changes in geochemistry for the Ouachita Mountains aquifer and the Western Interior Plains confining system are attributed to rock/water interaction and changes in redox zonation along the flow path. In these areas, groundwater evolves along flow paths from a calcium- to a sodium-bicarbonate water type with increasing reducing conditions resulting in denitrification, elevated iron and manganese concentrations, and production of methane in the more geochemically evolved and strongest reducing conditions. In the Ozark and Springfield Plateau aquifers, rapid influx of surface-derived contaminants, especially nitrogen, coupled with few to no attenuation processes was attributed to the karst landscape developed on Mississippian- and Ordovician-age carbonate rocks of the Ozark Plateaus. Increasing nitrate concentrations are related to increasing agricultural land use, and areas of mature karst development result in higher nitrate concentrations than areas with less karst features.

Arkasas

Groundwater conditions and studies in the Augusta–Richmond County area, Georgia, 2008–2009

Groundwater studies and monitoring efforts conducted during 2008–2009, as part of the U.S. Geological Survey (USGS) Cooperative Water Program with the City of Augusta in Richmond County, Georgia, provided data for the effective management of local water resources. During 2008–2009 the USGS completed: (1) installation of three monitoring wells and the collection of lithologic and geophysical logging data to determine the extent of hydrogeologic units, (2) collection of continuous groundwater-level data from wells near Well Fields 2 and 3, (3) collection of synoptic groundwater-level measurements and construction of potentiometric-surface maps in Richmond County to establish flow gradients and groundwater-flow directions in the Dublin and Midville aquifer systems, (4) completion of a 24-hour aquifer test to determine hydraulic characteristics of the lower Dublin aquifer, and upper and lower Midville aquifers in Well Field 2, and (5) collection of groundwater samples from selected wells in Well Field 2 for laboratory analysis of volatile organic compounds and groundwater tracers to assess groundwater quality and estimate the time of groundwater recharge. Potentiometric-surface maps of the Dublin and Midville aquifer systems for 2008–2009 indicate that the general groundwater flow direction within Richmond County is eastward toward the Savannah River, with the exception of the area around Well Field 2, where pumping interrupts the eastward flow of water toward the Savannah River and causes flow lines to bend toward the center of pumping. Results from a 24-hour aquifer test conducted in 2009 within the upper and lower Midville aquifers at Well Field 2 indicated a transmissivity and storativity for the upper and lower Midville aquifers, combined, of 4,000 feet-squared per day and 2x10 -4 , respectively. The upper and lower Midville aquifers and the middle lower Midville confining unit, which is 85-feet thick in this area, yielded horizontal hydraulic conductivity and specific storage values of about 45 feet per day and 2x10 -6 ft -1 , respectively. Results from the 24-hour aquifer test also indicate a low horizontal hydraulic conductivity for the lower Dublin aquifer of less than 1 foot per day. Of the 35 volatile organic compounds (VOCs) analyzed in 23 groundwater samples during 2008–2009, only six were detected above laboratory reporting limits in samples from eight wells. No concentration in groundwater samples collected during 2008–2009 exceeded drinking water standards. Trichloroethene had the maximum VOC concentration (1.9 micrograms per liter) collected from a water sample during 2008–2009. Water-quality sampling of several wells near Well Field 2 indicate that, while in operation, the northernmost production well might have diverted groundwater, containing low levels of trichloroethene from at least two other production wells. Analysis of sulfur hexafluoride data indicate the average year of recharge ranges between 1981 and 1984 for water samples from five wells open to the upper and lower Midville aquifers, and 1991 for a water sample from one shallow well open to the lower Dublin aquifer. All of these ages suggest a short flow path and nearby source of contamination. The actual source of low levels of VOCs at Well Field 2 remains unknown. Three newly installed monitoring wells indicate that hydrogeologic units beneath Well Fields 2 and 3 are composed of sand and clay layers. Hydrogeologic units, encountered at Well Field 2, in order of increasing depth are the lower Dublin confining unit, lower Dublin aquifer, upper Midville confining unit, upper Midville aquifer, lower Midville confining unit, and lower Midville aquifer. West of Well Field 3, hydrogeologic units, in order of increasing depth are the Upper Three Runs aquifer, Gordon confining unit, Gordon aquifer, lower Dublin confining unit, lower Dublin aquifer, upper Midville confining unit, upper Midville aquifer, lower Midville confining unit, and lower Midville aquifer.

Georgia

Water-quality trends in the nation’s rivers and streams, 1972–2012—Data preparation, statistical methods, and trend results

Since passage of the Clean Water Act in 1972, Federal, State, and local governments have invested billions of dollars to reduce pollution entering rivers and streams. To understand the return on these investments and to effectively manage and protect the Nation’s water resources in the future, we need to know how and why water quality has been changing over time. As part of the National Water-Quality Assessment Project, of the U.S. Geological Survey’s National Water-Quality Program, data from the U.S. Geological Survey, along with multiple other Federal, State, Tribal, regional, and local agencies, have been used to support the most comprehensive assessment conducted to date of surface-water-quality trends in the United States. This report documents the methods used to determine trends in water quality and ecology because these methods are vital to ensuring the quality of the results. Specific objectives are to document (1) the data compilation and processing steps used to identify river and stream sites throughout the Nation suitable for water-quality, pesticide, and ecology trend analysis, (2) the statistical methods used to determine trends in target parameters, (3) considerations for water-quality, pesticide, and ecology data and streamflow data when modeling trends, (4) sensitivity analyses for selecting data and interpreting trend results with the Weighted Regressions on Time, Discharge, and Season method, and (5) the final trend results at each site. The scope of this study includes trends in water-quality concentrations and loads (nutrient, sediment, major ion, salinity, and carbon), pesticide concentrations and loads, and metrics for aquatic ecology (fish, invertebrates, and algae) for four time periods: (1) 1972–2012, (2) 1982–2012, (3) 1992–2012, and (4) 2002–12. In total, nearly 12,000 trends in concentration, load, and ecology metrics were evaluated in this study; there were 11,893 combinations of sites, parameters, and trend periods. The final trend results are presented with examples of how to interpret the results from each trend model. Interpretation of the trend results, such as causal analysis, is not included.

Scientific Investigations Report

Inventory and Statistical Analysis of Sediment Data for Streams in Kentucky, 1950-2008

Suspended sediment is a constituent of water that is monitored because of concerns about accelerated erosion, nonpoint contamination of water resources, and degradation of aquatic environments. Understanding the availability of monitored sediment data for streams in Kentucky is critical to planning future modeling and monitoring efforts. In order to assess the availability of sediment data for Kentucky, long-term records were obtained from the National Water Information System (NWIS) of the U.S. Geological Survey (USGS). Suspended-sediment concentration (SSC), the parameter traditionally measured and reported by the USGS, was statistically compared to turbidity and total suspended solids (TSS), two parameters that are considered surrogate data. Coincident observations of SSC with either turbidity or TSS were available for 42 sites. In combination with instantaneous streamflow, turbidity and TSS both proved to be significant indicators of SSC when data from all sites were used. Because of the perceived link between sediment and nutrient abundance in streams, sediment-parameter data at these sites were correlated to total-nitrogen and total-phosphorus concentrations. A significant relation (p-value < 0.05) was found between monitored nutrient concentrations and coincident sediment abundance, although there were no clear linear relations. This compilation of data showed that SSC was monitored at 118 sites in Kentucky at some time between 1950 and 2008. As of March 2008, 9 sites were monitored for SSC in Kentucky (8 of which are new) down from a high of more than 60 SSC sites during the 1980s. Of these 118 SSC sites, 21 sites were also monitored for TSS; there are coincident records for both SSC and TSS at 6 sites. Forty-seven of these long-term water-quality sites were also monitored for turbidity; there are coincident records for SSC and turbidity at 42 sites, including all of those at which there are coincident data for TSS. The number of sites at which SSC and at least one other sediment parameter (TSS or turbidity) were monitored decreased from a high of 27 in 1987 to zero during the period 2001-2005.

Scientific Investigations Report

Effects of water use and land use on streamflow and aquatic habitat in the Sudbury and Assabet River Basins, Massachusetts

Water withdrawals from surface-water reservoirs and groundwater have affected streamflow in the Sudbury and Assabet River Basins. These effects are particularly evident in the upper Sudbury River Basin, which prompted the need to improve the understanding of water resources and aquatic habitat in these basins. In 2004, the U.S. Geological Survey, in cooperation with the Massachusetts Department of Conservation and Recreation, developed a precipitation-runoff model that uses Hydrologic Simulation Program-FORTRAN (HSPF) to evaluate the effects of water use and projected future water-use and land-use change on streamflow. As part of this study, the aquatic habitat in the basins and the effects of streamflow alteration also were evaluated. Chapter 1 of the report covers the development of the HSPF model that focuses on the upper Sudbury River Basin (106 square miles) but covers the entire Sudbury and Assabet River Basins (339 square miles). The model was calibrated to an 11-year period (1993-2003) using observed or estimated streamflow at four streamgages. The model was then used to simulate long-term (1960-2004) streamflows to evaluate the effects of average 1993-2003 water use and projected 2030 water-use and land-use change over long-term climatic conditions. Simulations indicate that the average 1993-2003 withdrawals most altered streamflow relative to no withdrawals in small headwater subbasins where the ratios of mean annual withdrawals to mean annual streamflow are the highest. The effects of withdrawals are also appreciable in other parts of the upper Sudbury River Basin as a result of the perpetuation of the effects of large withdrawals in upstream reaches or in subbasins that also have a high ratio of withdrawal to streamflow. The simulated effects of potential 2030 water-use and land-use change indicate small decreases in flows as a result of increased water demands, but these flow alterations were offset as a result of decreased evapotranspiration associated with the loss of deep-rooted vegetation. Simulations of reactivating production wells near the north end of Lake Cochituate indicate pumping could substantially affect lake levels and flows at the lake outlet or in nearby reaches in the Sudbury River during periods of low flow, but the effects vary depending on the source of the water to the wells, which is largely unknown. Chapter 2 of the report covers the fish-community assessment and comparison of streamflow-setting standards for protecting aquatic habitat. The fish-community assessment indicates the main stems of the Sudbury and Assabet Rivers are dominated by macrohabitat generalists. Water temperatures recorded in seven free-flowing reaches in the upper Sudbury River Basin at three sites unaffected by withdrawals or impoundments are generally suitable for cold-water fish; however, summer temperatures often rose to a level considered critical to long-term survival of brook trout. At four sites downstream from withdrawals or reservoirs, or both, summer water temperatures were often in the upper critical range for brook trout survival. Physically and statistically based methods for determining streamflows for protecting aquatic habitat were applied at 10 selected riffle sites in the Sudbury and Assabet River Basins. Physically based methods, R2Cross and Wetted-Perimeter, use site-specific physical and hydraulic information and a one-dimensional hydraulics model, HEC-RAS, to determine flows that meet the criteria set forth by the method. The median flow that meets 2-of-3 of the R2Cross hydraulic criteria (percentage of bankfull wetted perimeter, average velocity, and mean depth) ranged from about 0.07 to 0.72 cubic feet per second per square mile (ft3/s/mi2) with an overall median of about 0.24 ft3/s/mi2; the median Wetted-Perimeter target flow ranged from about 0.10 to 0.51 ft3/s/mi2 with an overall median of about 0.25 ft3/s/mi2. Statistically based methods?Tennant, New England Aquatic Base Flow (ABF)

Scientific Investigations Report

Water and nutrient budgets for Vancouver Lake, Vancouver, Washington, October 2010-October 2012

Vancouver Lake, a large shallow lake in Clark County, near Vancouver, Washington, has been undergoing water-quality problems for decades. Recently, the biggest concern for the lake are the almost annual harmful cyanobacteria blooms that cause the lake to close for recreation for several weeks each summer. Despite decades of interest in improving the water quality of the lake, fundamental information on the timing and amount of water and nutrients entering and exiting the lake is lacking. In 2010, the U.S. Geological Survey conducted a 2-year field study to quantify water flows and nutrient loads in order to develop water and nutrient budgets for the lake. This report presents monthly and annual water and nutrient budgets from October 2010&ndash;October 2012 to identify major sources and sinks of nutrients. Lake River, a tidally influenced tributary to the lake, flows into and out of the lake almost daily and composed the greatest proportion of both the water and nutrient budgets for the lake, often at orders of magnitude greater than any other source. From the water budget, we identified precipitation, evaporation and groundwater inflow as minor components of the lake hydrologic cycle, each contributing 1 percent or less to the total water budget. Nutrient budgets were compiled monthly and annually for total nitrogen, total phosphorus, and orthophosphate; and, nitrogen loads were generally an order of magnitude greater than phosphorus loads across all sources. For total nitrogen, flow from Lake River at Felida, Washington, made up 88 percent of all inputs into the lake. For total phosphorus and orthophosphate, Lake River at Felida flowing into the lake was 91 and 76 percent of total inputs, respectively. Nutrient loads from precipitation and groundwater inflow were 1 percent or less of the total budgets. Nutrient inputs from Burnt Bridge Creek and Flushing Channel composed 12 percent of the total nitrogen budget, 8 percent of the total phosphorus budget, and 21 percent of the orthophosphate budget. We identified several data gaps and areas for future research, which include the need for better understanding nutrient inputs to the lake from sediment resuspension and better quantification of indirect nutrient inputs to the lake from Salmon Creek.

Washington

Conceptual models of groundwater flow in the Grand Canyon region, Arizona

The conceptual models of groundwater flow outlined herein synthesize what is known and hypothesized about the groundwater-flow systems that discharge to the Grand Canyon of Arizona. These models interpret the hydrogeologic characteristics and hydrologic dynamics of the physical systems into a framework for understanding key aspects of the physical systems as they relate to groundwater flow and contaminant transport. This report describes five individual groundwater-flow systems draining to the Grand Canyon: Kaibab, Uinkaret-Kanab, Marble-Shinumo, Cataract, and Blue Spring. These systems are present in the saturated parts of the lower Paleozoic carbonate section exposed on the walls of the Grand Canyon; specifically, the Mississippian Redwall Limestone down through the Cambrian Muav Limestone of Tonto Group. Together, the systems described in this report compose the regional groundwater-flow system. Local to subregional flow systems in the sedimentary units of the overlying Permian section could provide transport pathways from the land surface to the regional flow system. Despite the potential importance of the local systems, the focus of this report is on the systems present in the lower Paleozoic section because all major springs in the Grand Canyon discharge from those units. The most important hydrogeologic characteristics include system boundaries imposed by major tectonic structures, and the degree to which karstification influences the magnitude and direction of flow in each system. Important hydrologic dynamics include locations and rates of potential groundwater recharge, vertical pathways to the regional aquifer, and the locations, magnitude, geochemical signature, and hydrostratigraphic setting of groundwater discharge from springs. Unknown properties or conditions that represent the greatest uncertainties in our current understanding of the regional groundwater-flow system are identified for additional consideration. Groundwater data are sparse owing to geographic remoteness and extreme depth to water throughout much of the study area. This paucity of information was diminished with the development of a structural contour map of the top and bottom surfaces of the regional aquifer, and a Soil-Water-Balance model that produces spatial distributions of rates of potential recharge. Investigation of the five groundwater-flow systems reveals important, though mostly qualitative, characteristics controlling the rates and directions of groundwater flow. Karstification has produced dissolution-enhanced conduit flow pathways to various degrees in each of the systems. Parts of each system exhibit relative structural uplift or downdropping of the hydrostratigraphic units of the regional aquifer, with some uplifted sections dipping inward toward the Grand Canyon and others dipping outward. The Kaibab groundwater system is archetypical of an uplifted, inward-dipping karst system, whereas the Blue Spring groundwater system and most of the Cataract groundwater system are representative instances of a downdropped or basin karst system. The Uinkaret-Kanab groundwater-flow system is structurally similar to the basin karst systems but karstification has not progressed to nearly the same degree. The Marble-Shinumo groundwater system does not fall cleanly into either category and its boundaries are the most uncertain of all the groundwater systems.

Arizona