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USGS2009

Comparison of Hydrologic and Water-Quality Characteristics of Two Native Tallgrass Prairie Streams with Agricultural Streams in Missouri and Kansas

This report presents the results of a study by the U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, to analyze and compare hydrologic and water-quality characteristics of tallgrass prairie and agricultural basins located within the historical distribution of tallgrass prairie in Missouri and Kansas. Streamflow and water-quality data from two remnant, tallgrass prairie basins (East Drywood Creek at Prairie State Park, Missouri, and Kings Creek near Manhattan, Kansas) were compared to similar data from agricultural basins in Missouri and Kansas. Prairie streams, especially Kings Creek in eastern Kansas, received a higher percentage of base flow and a lower percentage of direct runoff than similar-sized agricultural streams in the region. A larger contribution of direct runoff from the agricultural streams made them much flashier than prairie streams. During 22 years of record, the Kings Creek base-flow component averaged 66 percent of total flow, but base flow was only 16 to 26 percent of flows at agricultural sites of various record periods. The large base-flow component likely is the result of greater infiltration of precipitation in prairie soils and the resulting greater contribution of groundwater to streamflow. The 1- and 3-day annual maximum flows were significantly greater at three agricultural sites than at Kings Creek. The effects of flashier agricultural streams on native aquatic biota are unknown, but may be an important factor in the sustainability of some native aquatic species. There were no significant differences in the distribution of dissolved-oxygen concentrations at prairie and agricultural sites, and some samples from most sites fell below the 5 milligrams per liter Missouri and Kansas standard for the protection of aquatic life. More than 10 percent of samples from the East Drywood Creek prairie stream were less than this standard. These data indicate low dissolved-oxygen concentrations during summer low-flow periods may be a natural phenomenon for small prairie streams in the Osage Plains. Nutrient concentrations including total nitrogen, ammonia, nitrate, and total phosphorus were significantly less in base-flow and runoff samples from prairie streams than from agricultural streams. The total nitrogen concentration at all sites other than one of two prairie sampling sites were, on occasion, above the U.S. Environmental Protection Agency recommended criterion for total nitrogen for the prevention of nutrient enrichment, and typically were above this recommended criterion in runoff samples at all sites. Nitrate and total phosphorus concentrations in samples from the prairie streams generally were below the U.S. Environmental Protection Agency recommended nutrient criteria in base-flow and runoff samples, whereas samples from agricultural sites generally were below the criteria in base-flow samples and generally above in runoff samples. The lower concentrations of nutrient species in prairie streams is likely because prairies are not fertilized like agricultural basins and prairie basins are able to retain nutrients better than agricultural basins. This retention is enhanced by increased infiltration of precipitation into the prairie soils, decreased surface runoff, and likely less erosion than in agricultural basins. Streamflow in the small native prairie streams had more days of zero flow and lower streamflow yields than similar-sized agricultural streams. The prairie streams were at zero flow about 50 percent of the time, and the agricultural streams were at zero flow 25 to 35 percent of the time. Characteristics of the prairie basins that could account for the greater periods of zero flow and lower yields when compared to agricultural streams include greater infiltration, greater interception and evapotranspiration, shallower soils, and possible greater seepage losses in the prairie basins. Another difference between the prairie and agricultural strea

Scientific Investigations Report↗
USGS2005

Hydrology and simulation of ground-water flow in Cedar Valley, Iron County, Utah

Cedar Valley, located in the eastern part of Iron County in southwestern Utah, is experiencing rapid population growth. Cedar Valley traditionally has supported agriculture, but the growing population needs a larger share of the available water resources. Water withdrawn from the unconsolidated basin fill is the primary source for public supply and is a major source of water for irrigation. Water managers are concerned about increasing demands on the water supply and need hydrologic information to manage this limited water resource and minimize flow of water unsuitable for domestic use toward present and future public-supply sources. Surface water in the study area is derived primarily from snowmelt at higher altitudes east of the study area or from occasional large thunderstorms during the summer. Coal Creek, a perennial stream with an average annual discharge of 24,200 acre-feet per year, is the largest stream in Cedar Valley. Typically, all of the water in Coal Creek is diverted for irrigation during the summer months. All surface water is consumed within the basin by irrigated crops, evapotranspiration, or recharge to the ground-water system. Ground water in Cedar Valley generally moves from primary recharge areas along the eastern margin of the basin where Coal Creek enters, to areas of discharge or subsurface outflow. Recharge to the unconsolidated basin-fill aquifer is by seepage of unconsumed irrigation water, streams, direct precipitation on the unconsolidated basin fill, and subsurface inflow from consolidated rock and Parowan Valley and is estimated to be about 42,000 acre-feet per year. Stable-isotope data indicate that recharge is primarily from winter precipitation. The chloride mass-balance method indicates that recharge may be less than 42,000 acre-feet per year, but is considered a rough approximation because of limited chloride concentration data for precipitation and Coal Creek. Continued declining water levels indicate that recharge is not sufficient to meet demand. Water levels in many areas are at or close to historic lows. In 2000, withdrawal from wells was estimated to be 36,000 acre-feet per year. About 4,000 acre-feet per year are estimated to discharge to evapotranspiration or as subsurface outflow. Prior to large-scale ground-water development, ground-water discharge by evapotranspiration and discharge to springs was much larger. Ground water along the eastern margin of the valley between Cedar City and Enoch is unsuitable for domestic use because of high dissolved-solids and nitrate concentrations. The predominant ions of Ca and SO4 in this area indicate dissolution of gypsum in the Markagunt Plateau to the east. Data collected during this study were compared to historic data; there is no evidence to indicate deterioration in ground-water quality. The spatial distribution of ground water with high nitrate concentration does not appear to be migrating beyond its previously known extent. No single source can be identified as the cause for elevated nitrate concentrations in ground water. Low nitrogen-15 values north of Cedar City indicate a natural geologic source. Higher nitrogen-15 values toward the center of the basin and associated hydrologic data indicate probable recharge from waste-water effluent. Excess dissolved nitrogen gas and low nitrate concentrations in shallow ground water indicate that denitrification is occurring in some areas. A computer ground-water flow model was developed to simulate flow in the unconsolidated basin fill. The method of determining recharge from irrigation was changed during the calibration process to incorporate more areal and temporal variability. In general, the model accurately simulates water levels and water-level fluctuations and can be considered an adequate tool to help determine the valley-wide effects on water levels of additional ground-water withdrawals and changes in water use. The model was used to simulated water-level changes caused by projecting current withdrawal rates, increased withdrawal rates, and a 10-year drought. Water levels declined 20 to 275 feet in the southern and central parts of the valley and less than 20 feet north of Enoch

Utah↗
USGS2009

Regional regression equations for estimation of natural streamflow statistics in Colorado

The U.S. Geological Survey (USGS), in cooperation with the Colorado Water Conservation Board and the Colorado Department of Transportation, developed regional regression equations for estimation of various streamflow statistics that are representative of natural streamflow conditions at ungaged sites in Colorado. The equations define the statistical relations between streamflow statistics (response variables) and basin and climatic characteristics (predictor variables). The equations were developed using generalized least-squares and weighted least-squares multilinear regression reliant on logarithmic variable transformation. Streamflow statistics were derived from at least 10 years of streamflow data through about 2007 from selected USGS streamflow-gaging stations in the study area that are representative of natural-flow conditions. Basin and climatic characteristics used for equation development are drainage area, mean watershed elevation, mean watershed slope, percentage of drainage area above 7,500 feet of elevation, mean annual precipitation, and 6-hour, 100-year precipitation. For each of five hydrologic regions in Colorado, peak-streamflow equations that are based on peak-streamflow data from selected stations are presented for the 2-, 5-, 10-, 25-, 50-, 100-, 200-, and 500-year instantaneous-peak streamflows. For four of the five hydrologic regions, equations based on daily-mean streamflow data from selected stations are presented for 7-day minimum 2-, 10-, and 50-year streamflows and for 7-day maximum 2-, 10-, and 50-year streamflows. Other equations presented for the same four hydrologic regions include those for estimation of annual- and monthly-mean streamflow and streamflow-duration statistics for exceedances of 10, 25, 50, 75, and 90 percent. All equations are reported along with salient diagnostic statistics, ranges of basin and climatic characteristics on which each equation is based, and commentary of potential bias, which is not otherwise removed by log-transformation of the variables of the equations from interpretation of residual plots. The predictor-variable ranges can be used to assess equation applicability for ungaged sites in Colorado.

Colorado↗
USGS2009

Occurrence of Pesticides in Ground Water of Wyoming, 1995-2006

Little existing information was available describing pesticide occurrence in ground water of Wyoming, so the U.S. Geological Survey, in cooperation with the Wyoming Department of Agriculture and the Wyoming Department of Environmental Quality on behalf of the Wyoming Ground-water and Pesticides Strategy Committee, collected ground-water samples twice (during late summer/early fall and spring) from 296 wells during 1995-2006 to characterize pesticide occurrence. Sampling focused on the State's ground water that was mapped as the most vulnerable to pesticide contamination because of either inherent hydrogeologic sensitivity (for example, shallow water table or highly permeable aquifer materials) or a combination of sensitivity and associated land use. Because of variations in reporting limits among different compounds and for the same compound during this study, pesticide detections were recensored to two different assessment levels to facilitate qualitative and quantitative examination of pesticide detection frequencies - a common assessment level (CAL) of 0.07 microgram per liter and an assessment level that differed by compound, referred to herein as a compound-specific assessment level (CSAL). Because of severe data censoring (fewer than 50 percent of the data are greater than laboratory reporting limits), categorical statistical methods were used exclusively for quantitative comparisons of pesticide detection frequencies between seasons and among various natural and anthropogenic (human-related) characteristics. One or more pesticides were detected at concentrations greater than the CAL in water from about 23 percent of wells sampled in the fall and from about 22 percent of wells sampled in the spring. Mixtures of two or more pesticides occurred at concentrations greater than the CAL in about 9 percent of wells sampled in the fall and in about 10 percent of wells sampled in the spring. At least 74 percent of pesticides detected were classified as herbicides. Considering only detections using the CAL, triazine pesticides were detected much more frequently than all other pesticide classes, and the number of different pesticides classified as triazines was the largest of all classes. More pesticides were detected at concentrations greater than the CSALs in water from wells sampled in the fall (28 different pesticides) than in the spring (21 different pesticides). Many pesticides were detected infrequently as nearly one-half of pesticides detected in the fall and spring at concentrations greater than the CSALs were detected only in one well. Using the CSALs for pesticides analyzed for in 11 or more wells, only five pesticides (atrazine, prometon, tebuthiuron, picloram, and 3,4-dichloroaniline, listed in order of decreasing detection frequency) were each detected in water from more than 5 percent of sampled wells. Atrazine was the pesticide detected most frequently at concentrations greater than the CSAL. Concentrations of detected pesticides generally were small (less than 1 microgram per liter), although many infrequent detections at larger concentrations were noted. All detected pesticide concentrations were smaller than U.S. Environmental Protection Agency (USEPA) drinking-water standards or applicable health advisories. Most concentrations were at least an order of magnitude smaller; however, many pesticides did not have standards or advisories. The largest percentage of pesticide detections and the largest number of different pesticides detected were in samples from wells located in the Bighorn Basin and High Plains/ Casper Arch geographic areas of north-central and southeastern Wyoming. Prometon was the only pesticide detected in all eight geographic areas of the State. Pesticides were detected much more frequently in samples from wells located in predominantly urban areas than in samples from wells located in predominantly agricultural or mixed areas. Pesticides were detected distinctly less often in sa

Scientific Investigations Report↗
USGS2015

Potentiometric surface of the Catahoula aquifer in central Louisiana, 2013

The Catahoula aquifer is an important source of fresh groundwater in central Louisiana. In 2010, about 3.96 million gallons per day (Mgal/d) were withdrawn from the Catahoula aquifer in Louisiana. In 2012, the U.S. Geological Survey in cooperation with the Louisiana Department of Natural Resources began a study to document current water levels in selected aquifers in Louisiana. This report presents water-level data and a map that illustrates the potentiometric surface of the Catahoula aquifer in 2013. The Catahoula aquifer crops out in a narrow band across north-central Louisiana. This band is broken by alluvial deposits in the valleys of the Red, Little, and Ouachita Rivers that have incised into the aquifer. Saltwater ridges under the Red, Little, and Tensas River Valleys divide the freshwater extents of the Catahoula aquifer and limit the flow of freshwater between these areas. The Catahoula aquifer generally ranges in thickness from about 50 feet (ft) in the outcrop area to about 450 ft in southern Vernon Parish. Sand beds in the aquifer are generally discontinuous, lenticular, and interbedded with silts and clays. The potentiometric surface of the Catahoula aquifer was constructed by using the altitude of water levels measured at 29 wells during the period May through September 2013. The altitude of water levels ranged from 0.02 ft above the National Geodetic Vertical Datum of 1929 (NGVD 29) in well Co-51 to 238 ft above NGVD 29 in well Na-317. Groundwater movement in the Catahoula aquifer is generally to the southeast and towards discharge areas beneath the Sabine, Red, Little, and Tensas River Valleys.

Louisiana↗
USGS2005

Hydrology and water quality of lakes and streams in Orange County, Florida

Orange County, Florida, is continuing to experience a large growth in population. In 1920, the population of Orange County was less than 20,000; in 2000, the population was about 896,000. The amount of urban area around Orlando has increased considerably, especially in the northwest part of the County. The eastern one-third of the County, however, had relatively little increase in urbanization from 1977-97. The increase of population, tourism, and industry in Orange County and nearby areas changed land use; land that was once agricultural has become urban, industrial, and major recreation areas. These changes could impact surface-water resources that are important for wildlife habitat, for esthetic reasons, and potentially for public supply. Streamflow characteristics and water quality could be affected in various ways. As a result of changing land use, changes in the hydrology and water quality of Orange County's lakes and streams could occur. Median runoff in 10 selected Orange County streams ranges from about 20 inches per year (in/yr) in the Wekiva River to about 1.1 in/yr in Cypress Creek. The runoff for the Wekiva River is significantly higher than other river basins because of the relatively constant spring discharge that sustains streamflow, even during drought conditions. The low runoff for the Cypress Creek basin results from a lack of sustained inflow from ground water and a relatively large area of lakes within the drainage basin. Streamflow characteristics for 13 stations were computed on an annual basis and examined for temporal trends. Results of the trend testing indicate changes in annual mean streamflow, 1-day high streamflow, or 7-day low streamflow at 8 of the 13 stations. However, changes in 7-day low streamflow are more common than changes in annual mean or 1-day high streamflow. There is probably no single reason for the changes in 7-day low streamflows, and for most streams, it is difficult to determine definite reasons for the flow increases. Low flows in the Econlockhatchee River at Chuluota have increased because of discharge of treated wastewater since 1982. However, trends in increasing 7-day low streamflow are evident before 1982, which cannot be attributed to wastewater discharge. Some of the increases in 7-day low flows may be related to drainage changes resulting from increased development in Orange County. Development for most purposes, including those as diverse as cattle grazing and residential construction, may involve modification of surface drainage through stream channelization and construction of canals. These changes in land drainage can lower the water table, resulting in reductions of regional evapotranspiration rates and increased streamflow. Another possible cause of increasing low flows in streams is use of water from the Floridan aquifer system for irrigation. Runoff of irrigation water or increased seepage from irrigated areas to streams could increase base streamflow compared to natural conditions. Water-level data were analyzed to determine temporal trends from 83 lakes that had more than 15 years of record. There were significant temporal trends in 33 of the 83 lakes (40 percent) over the entire period of record. Of these 33 lakes, 14 had increasing water levels and 19 lakes had decreasing water levels. The downward trends in long-term lake levels could in part be due to high rainfall accumulation in 1960-1961, which included precipitation from Hurricane Donna (September 1960). The high rainfall resulted in historical high-water levels in many lakes in 1960 or 1961. A large range of water-quality conditions exists in lakes and streams of Orange County (2000-01). Specific conductance in lake samples ranged from 57 to 1,185 microsiemens per centimeter. Values of pH ranged from 3.2 to 8.7 in stream samples and 4.6 to 9.6 in lake samples. Total nitrogen concentrations ranged from less than 0.2 to 7.1 milligrams per liter (mg/L) as nitrogen in stream samples, and

Scientific Investigations Report↗
USGS2015

Chloride concentrations, loads, and yields in four watersheds along Interstate 95, southeastern Connecticut, 2008-11: factors that affect peak chloride concentrations during winter storms

Chloride (Cl - ) concentrations and loads and other water chemistry characteristics were assessed to evaluate potential effects of road-deicer applications on streamwater quality in four watersheds along Interstate 95 (I–95) in southeastern Connecticut from November 1, 2008, through September 30, 2011. Streamflow and water quality were studied in the Four Mile River, Oil Mill Brook, Stony Brook, and Jordan Brook watersheds, where developed land ranged from 9 to 32 percent. Water-quality samples were collected and specific conductance was measured continuously at paired water-quality monitoring sites, upstream and downstream from I–95. Specific conductance values were related to Cl - concentrations to assist in determining the effects of road-deicing operations on the levels of Cl - in the streams. Streamflow and water-quality data were compared with weather data and with the timing, amount, and composition of deicers applied to State highways. Grab samples were collected during winter stormwater-runoff events, such as winter storms or periods of rain or warm temperatures in which melting takes place. Grab samples were also collected periodically during the spring and summer and during base-flow conditions. The estimated Cl - concentrations at the eight water-quality monitoring sites during winter storms peaked as high as 270 milligrams per liter (mg/L) and were well below the U.S. Environmental Protection Agency (EPA) recommended acute chloride toxicity criterion of 860 mg/L and the chronic 4-day average toxicity criterion of 230 mg/L. Cl - concentrations in streams, particularly at sites downstream from I–95, peaked during increased streamflow in the winter and early spring as a result of deicers applied to roads and washed off by stormwater or meltwater. Cl - concentrations during most of the nonwinter seasons decreased during increases in streamflow because storm runoff was more dilute than base flow. However, peaks in specific conductance and estimated chloride concentrations at streams in more urbanized watersheds corresponded to peaks in streamflow well after winter snow or ice events; these delayed peaks in Cl - concentration likely resulted from deicer residue that remained in melting snow piles and on roadsides and (or) that were flushed from soils and shallow groundwater, then discharged downstream. Estimated peak Cl - concentrations varied with the type of winter storm event and were highest during or after winter storms of frozen precipitation and rain, in which the rain or meltwater effectively washed off the deicers. Estimated peak Cl - concentrations correlated positively with the duration of deicer application but generally not with streamflow. Estimated peak Cl - concentrations during the winter season were highest during low streamflow at most sites. Chloride concentrations varied considerably in shallow groundwater as a result of land-use differences. Cl - concentrations were very high (as high as 800 mg/L) in shallow groundwater downstream from I–95 at the Four Mile River site. Chloride/bromide mass concentration ratios and the proximity of a former landfill and sewage lagoon upstream indicate a likely source of Cl - is landfill leachate and possibly sewage leachate. Cl - loads in streams generally were highest in the winter and early spring. The estimated daily Cl - yield for the four monitoring sites downstream from I–95 ranged from 0.0004 ton per day per square mile for one of the least developed watersheds to 0.052 ton per day per square mile for the watershed with the highest percentage of urban development and impervious area. The estimated median contribution of Cl - load from atmospheric deposition was small and ranged from 0.07 percent of Cl - load at the Jordan Brook watershed to 0.57 percent at the Oil Mill Brook watershed. The Cl - loads in streams (outputs) were compared with Cl - load inputs, which include atmospheric deposition and deicer applications; Cl - load inputs were slightly larger than the Cl - load outputs at most of the sites during most years but do not account for the Cl - load in groundwater leaving the watersheds. A multiple linear regression model was developed to describe the variability of the natural log of peak specific conductance, as well as estimated Cl - concentrations. Five significant variables best explained the variability in the natural log of the peak specific conductance after deicing events: (1) snow on ground before deicing event; (2) winter precipitation with rain; (3) specific conductance in base flow; (4) State-operated road lane miles divided by watershed area; and (5) amount of Cl - from deicers applied to State-operated roads per lane mile. In this report, winter precipitation is defined as any type of precipitation, including frozen precipitation and rain, that occurs during the active deicing season, typically November through March. Frozen precipitation is defined here as snow, sleet, freezing rain, or any winter precipitation except rain. The addition of a lane mile in both directions on I–95 would result in an estimate of approximately 2 to 11 percent increase in Cl - input from deicers applied to I–95 and other roads maintained by Connecticut Department of Transportation. The largest estimated increase in Cl - load was in the watersheds with the greatest number miles of I–95 corridor relative to the total lane miles maintained by Connecticut Department of Transportation. On the basis of these estimates and the estimated peak Cl - concentrations during the study period, it is unlikely that the increased use of deicers on the additional lanes would lead to Cl - concentrations that exceed the aquatic habitat criteria.

Connecticut↗
USGS2024

Distribution of ancient carbon in groundwater and soil gas from degradation of petroleum near the Red Hill Bulk Fuel Storage Facility, O‘ahu, Hawai‘i

The groundwater below the Red Hill Bulk Fuel Storage Facility (the facility) in Oʻahu, Hawaiʻi, contains fuel compounds from past spills. This study used carbon-14 analyses to distinguish fuel-derived carbon from background carbon, along with other biodegradation indicators, to address two goals: (1) determine the extent and migration direction of groundwater affected by residual fuel below the facility and (2) determine if residual fuel locations in the subsurface could be identified by analyzing soil gas at the surface above the facility. Groundwater from 19 wells was sampled between September 2022 and April 2023. Nonvolatile dissolved organic carbon (NVDOC) from a well presumed to be unaffected by past spills contained 38 percent ancient carbon indicating a natural source of ancient carbon in the subsurface. The NVDOC concentrations and ancient carbon percentages indicate fuel biodegradation products are likely present on the north and south of Red Hill with the greatest effects at well RHMW02 near the 2014 spill site. The NVDOC concentrations are almost three times higher than diesel range organic (DRO) concentrations in groundwater from the same sites. Major ion data indicate that iron reduction is an important biodegradation process. Soil probe samples and soil carbon traps were used to determine the carbon-14 content of soil carbon dioxide. Ancient carbon from fuel biodegradation was not detected at any soil probe or carbon trap site in contrast to a 2017 study which reported ancient carbon detections. A reanalysis of the 2017 results using a range of local values for background carbon-14 indicates that ancient carbon from fuel biodegradation was probably only detected in lower tunnel exhaust system samples and not in any soil carbon trap samples. Measurements of carbon dioxide efflux with a dynamic closed chamber were highly variable. The soil gas results indicate that soil gas measurements at land surface were not useful for detecting residual fuel at the facility.

Hawaii↗
USGS2010

Mapping watershed potential to contribute phosphorus from geologic materials to receiving streams, southeastern United States

As part of the southeastern United States SPARROW (SPAtially Referenced Regressions On Watershed attributes) water-quality model implementation, the U.S. Geological Survey created a dataset to characterize the contribution of phosphorus to streams from weathering and erosion of surficial geologic materials. SPARROW provides estimates of total nitrogen and phosphorus loads in surface waters from point and nonpoint sources. The characterization of the contribution of phosphorus from geologic materials is important to help separate the effects of natural or background sources of phosphorus from anthropogenic sources of phosphorus, such as municipal wastewater or agricultural practices. The potential of a watershed to contribute phosphorus from naturally occurring geologic materials to streams was characterized by using geochemical data from bed-sediment samples collected from first-order streams in relatively undisturbed watersheds as part of the multiyear U.S. Geological Survey National Geochemical Survey. The spatial pattern of bed-sediment phosphorus concentration is offered as a tool to represent the best available information at the regional scale. One issue may weaken the use of bed-sediment phosphorus concentration as a surrogate for the potential for geologic materials in the watershed to contribute to instream levels of phosphorus-an unknown part of the variability in bed-sediment phosphorus concentration may be due to the rates of net deposition and processing of phosphorus in the streambed rather than to variability in the potential of the watershed's geologic materials to contribute phosphorus to the stream. Two additional datasets were created to represent the potential of a watershed to contribute phosphorus from geologic materials disturbed by mining activities from active mines and inactive mines.

Alabama, Florida, Georgia, Kentucky, Mississippi, ↗
USGS2023

Groundwater quality near the Montebello Oil Field, Los Angeles County, California

Groundwater quality and potential sources and migration pathways of chemical constituents associated with hydrocarbon-bearing formations were assessed by the U.S. Geological Survey for the California State Water Resources Control Board Oil and Gas Regional Monitoring Program (RMP). Groundwater samples were collected as part of the RMP from 21 preexisting wells used for public supply, monitoring, or irrigation in and near the Montebello Oil Field and analyzed for constituents associated with hydrocarbon-bearing formations and constituents used to identify recently recharged groundwater and older groundwater. The newly collected RMP data were supplemented with historical sample data from 849 groundwater wells and analyzed with respect to explanatory factors that have the potential to influence water quality. Potential sources and migration pathways of fluids (water, gas, or oil) from hydrocarbon-bearing formations that could affect groundwater quality in the Montebello Oil Field include large volumes of recycled produced water (water withdrawn from an oil well and brought to the surface that may include oil, water, and gas from the geologic formation and water or gas injected for enhanced recovery) that have been reinjected since the 1960s to enhance oil production, oil and gas wells with well-integrity issues, and oil and gas wells with an uncemented annulus that intersects groundwater resource zones. Trace amounts of dissolved petroleum hydrocarbons, thermogenic gas (propane through pentane range), or both, were detected in seven groundwater samples collected in 2014 and 2018 as part of the RMP. Five of those samples also contained manufactured volatile organic compounds and at least some modern-age groundwater (recharged during or after 1953), indicating that the hydrocarbons could have originated from surficial, or shallow, sources unrelated to oil and gas development. Two samples contained low concentrations of petroleum hydrocarbons (less than 0.1 microgram per liter) and did not contain detections of manufactured volatile organic compounds in pre-modern groundwater. These samples were collected from relatively deep wells (greater than 140 meters below land surface) with perforations completed in marine sediments that may contain water with similar compositions to produced water. The RMP sample results and available historical data in and near the Montebello Oil Field did not provide conclusive evidence that oil and gas development has adversely affected groundwater resources. All samples with detectable petroleum hydrocarbons, thermogenic gases, or both, were collected from sites that also are within 500 meters of anthropogenic hydrocarbon sources not associated with oil and gas development or sources. In addition, naturally occurring sources of hydrocarbons that exist at intervals shallower than, or are in areas outside of, economically productive oil- and gas-producing zones could affect groundwater quality. A definitive analysis of relations of groundwater quality to potential anthropogenic and natural explanatory factors was not possible because of the low density of new and historical sampling data, particularly in parts of the Montebello Oil Field where the largest relative risks to groundwater from hydrocarbon-bearing formations exist. Areas to consider for more detailed monitoring and analysis in the future that may present the largest relative potential risks to groundwater quality include (1) areas downgradient from historical surface ponds and sumps and (2) areas with co-located high net injection (oil reservoir injection exceeds production), old oil and gas wells that may be more likely to develop well-integrity issues than newer wells, and oil and gas wells with uncemented boreholes intersecting groundwater zones. To help fill gaps resulting from sparse groundwater wells, temperature and resistivity borehole log data could be analyzed to locate anomalies that identify potential areas where relatively warm or saline water from deeper hydrocarbon-bearing formations is present in groundwater.

California↗
USGS2010

Logs and Geologic Data from a Paleoseismic Investigation of the Susitna Glacier fault, Central Alaska Range, Alaska

This report contains field and laboratory data from a paleoseismic study of the Susitna Glacier fault, Alaska. The initial M 7.2 subevent of the November 3, 2002, M 7.9 Denali fault earthquake sequence produced a 48-km-long set of complex fault scarps, folds, and aligned landslides on the previously unknown, north-dipping Susitna Glacier thrust fault along the southern margin of the Alaska Range in central Alaska. Most of the 2002 folds and fault scarps are 1-3 m high, implying dip-slip thrust offsets (assuming a near-surface fault dip of approximately 20 degrees)of 3-5 m. Locally, some of the 2002 ruptures were superimposed on preexisting scarps that have as much as 5-10 m of vertical separation and are evidence of previous surface-rupturing earthquakes on the Susitna Glacier fault. In 2003-2005, we focused follow-up studies on several of the large scarps at the 'Wet fan' site in the central part of the 2002 rupture to determine the pre-2002 history of large surface-rupturing earthquakes on the fault. We chose this site for several reasons: (1) the presence of pre-2002 thrust- and normal-fault scarps on a gently sloping, post-glacial alluvial fan; (2) nearby natural exposures of underlying fan sediments revealed fine-grained fluvial silts with peat layers and volcanic ash beds useful for chronological control; and (3) a lack of permafrost to a depth of more than 1 m. Our studies included detailed mapping, fault-scarp profiling, and logging of three hand-excavated trenches. We were forced to restrict our excavations to 1- to 2-m-high splay faults and folds because the primary 2002 ruptures mostly were superimposed on such large scarps that it was impossible to hand dig through the hanging wall to expose the fault plane. Additional complications are the pervasive effects of cryogenic processes (mainly solifluction) that can mask or mimic tectonic deformation. The purpose of this report is to present photomosaics, trench logs, scarp profiles, and fault slip, radiocarbon, tephrochronologic, and unit description data obtained during this investigation. We do not attempt to use the data presented herein to construct a paleoseismic history of the Susitna Glacier fault; that history will be the subject of a future report. When completed, our results will be used to compare the Susitna Glacier fault paleoseismic record with results of similar studies on the nearby Denali fault to determine if the simultaneous rupture of these two faults during the 2002 Denali fault earthquake sequence is typical or atypical of their long-term interaction.

Scientific Investigations Map↗
USGS2022

Linear regression model documentation for computing water-quality constituent concentrations using continuous real-time water-quality data for the Republican River, Clay Center, Kansas, July 2018 through March 2021

The Republican River is the primary inflow to Milford Lake and drains areas of Kansas, Nebraska, and Colorado. Milford Lake has been listed as impaired and designated hypereutrophic by the Kansas Department of Health and Environment because of excessive nutrient loading. Milford Lake had confirmed harmful algal blooms every summer from 2011 through 2017 and in 2020 and 2021. In the lower Republican River drainage basin, the Regional Conservation Partnership Program, administered by the Natural Resources Conservation Service, provides reimbursement to agricultural producers that implement best management practices intended to decrease sediment and nutrient runoff and loading into Milford Lake. Sediment and nutrient loads could potentially be driving factors in the development of harmful algal blooms in the reservoir. Since July 2018, the U.S. Geological Survey, in cooperation with the Kansas Water Office, has collected continuous and discrete water-quality data at the Republican River at Clay Center, Kansas, streamgage (U.S. Geological Survey station 06856600), which is about 15 river miles upstream from Milford Lake. This report documents site-specific regression models for the computation of continuous concentrations of suspended sediment, total nitrogen, total phosphorus, and total carbon developed using continuous and discrete data collected from July 24, 2018, the date of continuous water-quality monitor installation, through March 31, 2021. The objective of this study is to characterize sediment and nutrient transport in the Milford Lake drainage basin before, during, and after best management practice implementation using the models described in this report. The explanatory variable turbidity explained a high amount (72–96 percent) of the variance in suspended-sediment, total nitrogen, total phosphorus, and total carbon concentrations. Statistical plots for the four selected models showed the desired normality and homoscedasticity in residuals, and model standard error ratios indicated that recomputing each selected model after removing a randomly selected 10 percent of the data did not substantially change model coefficients.

Kansas↗
USGS2007

Processes Affecting Phosphorus and Copper Concentrations and Their Relation to Algal Growth in Two Supply Reservoirs in the Lower Coastal Plain of Virginia, 2002-2003, and Implications for Alternative Management Strategies

Elevated phosphorus concentrations commonly promote excessive growth of algae in waters nationwide. When such waters are used for public supply, the algae can plug filters during treatment and impart tastes and odors to the finished water. This increases treatment costs and results in finished water that may not be of the quality desired for public supply. Consequently, copper sulfate is routinely applied to many reservoirs to control algal growth but only is a 'temporary fix' and must be reapplied at intervals that can range from more than 30 days in the winter to less than 7 days in the summer. Because copper has a maximum allowable concentration in public drinking water and can be toxic to aquatic life, water suppliers commonly seek to develop alternative, long-term strategies for managing reservoirs. Because these are nationwide issues and part of the mission of the U.S. Geological Survey (USGS) is to define and protect the quality of the Nation's water resources and better understand the physical, chemical, and biological processes in wetlands, lakes, reservoirs, and estuaries, investigations into these issues are important to the fulfillment of the mission of the USGS. The City of Newport News, Virginia, provides 50 million gallons per day of treated water for public supply from Lee Hall and Harwoods Mill Reservoirs (terminal reservoirs) to communities on the lower York-James Peninsula. About 3,500 pounds of copper sulfate are applied to each reservoir at 3- to 99-day intervals to control algal growth. Consequently, the USGS, in cooperation with the City of Newport News, investigated the effects of management practices and natural processes on phosphorus (the apparent growth-limiting nutrient), copper, and algal concentrations in the terminal reservoirs to provide information that can be used to develop alternative management strategies for the terminal reservoirs. Initial parts of the research evaluated circulation and stratification in the reservoirs because these factors affect phosphorus availability to algae. Results indicate that (1) water flows through both reservoirs in a 'plug-flow' manner; (2) little water in the lower part of Lee Hall Reservoir, into which pumped water enters, flows into the upper part of the reservoir and mixes with that water; (3) Lee Hall Reservoir generally does not stratify; and (4) Harwoods Mill Reservoir stratifies from April to June through September or October into an upper epilimnion that does not mix with water in the lower hypolimnion. The ratio of dissolved nitrogen to phosphorus concentrations (N:P) for sites in both reservoirs generally was greater than 20:1, indicating that phosphorus likely is the growth-limiting nutrient in both reservoirs. Phosphorus was present predominantly as suspended, rather than dissolved, species except in the hypolimnion of Harwoods Mill Reservoir and the natural inflow represented by Baptist Run. Because Harwoods Mill Reservoir stratified, field-measured physical and chemical characteristics and concentrations of nitrogen and phosphorus species changed sharply over short depth intervals in this reservoir. Dissolved phosphorus concentration increased from 0.015 to 0.057 milligrams per liter between a depth of 15 feet (ft) and the bottom (depth of 18 ft), indicating the release of phosphorus by the decomposition of organic material and(or) the reduction of iron oxides in bed sediment and the lower water column. Because the mixing boundary between the epilimnion and the hypolimnion likely was between depths of 6 and 10 ft, such sources in the hypolimnion would not contribute phosphorus to the growth of algae in the epilimnion from which water is withdrawn for supply until the breakdown of stratification in the fall. Furthermore, laboratory studies of samples from both reservoirs indicated that dissolved phosphorus was released from suspended particles at rates of 0.0007 to 0.0019 milligrams per liter per day. At these rates of release, particl

Scientific Investigations Report↗
USGS2009

Groundwater-Quality Survey of the South Coast Aquifer of Puerto Rico, April 2 through May 30, 2007

The increased potential for variability of groundwater quality in the South Coast aquifer of Puerto Rico due to saline water encroachment from the Caribbean Sea and from deep parts of the aquifer has become a major concern of water planners and managers. In an effort to determine the extent and sources of this encroachment, the U.S. Geological Survey (USGS) and the Puerto Rico Department of Natural and Environmental Resources conducted a synoptic groundwater-quality survey from April 2 through May 30, 2007, for the South Coast aquifer between Ponce and Arroyo (fig. 1). Groundwater resources in this aquifer extend 150 square miles in south-central Puerto Rico and provide an estimated 44.2 million gallons per day (Mgal/d) or about 61 percent of the total water needs. This amount includes: 15.3 Mgal/d for irrigation, 27.4 Mgal/d for public supply, and 1.5 Mgal/d for industrial and other uses (W.L. Molina-Rivera, U.S. Geological Survey, written commun., 2007). Since 1980 when most of the south coastal plain was intensively cultivated for sugarcane, total groundwater withdrawals have declined about 32 Mgal/d with the greatest decline occurring in irrigation (37.2 Mgal/d) and the greatest increase occurring in public supply (5.5 Mgal/d). Although withdrawals have declined substantially, a major concern is that aquifer recharge provided by irrigation return flow from surface-water irrigation canals has essentially dropped to zero because of the large-scale implementation of groundwater drip irrigation systems.

Scientific Investigations Map↗
USGS2017

Geologic map of the Beacon Rock quadrangle, Skamania County, Washington

The Beacon Rock 7.5′ quadrangle is located approximately 50 km east of Portland, Oregon, on the north side of the Columbia River Gorge, a scenic canyon carved through the axis of the Cascade Range by the Columbia River. Although approximately 75,000 people live within the gorge, much of the region remains little developed and is encompassed by the 292,500-acre Columbia River Gorge National Scenic Area, managed by a consortium of government agencies “to pro­tect and provide for the enhancement of the scenic, cultural, recreational and natural resources of the Gorge and to protect and support the economy of the Columbia River Gorge area.” As the only low-elevation corridor through the Cascade Range, the gorge is a critical regional transportation and utilities corridor (Wang and Chaker, 2004). Major state and national highways and rail lines run along both shores of the Columbia River, which also provides important water access to ports in the agricultural interior of the Pacific Northwest. Transmission lines carry power from hydroelectric facilities in the gorge and farther east to the growing urban areas of western Oregon and Washington, and natural-gas pipelines transect the corridor (Wang and Chaker, 2004). These lifelines are highly vulnerable to disruption by earthquakes, landslides, and floods. A major purpose of the work described here is to identify and map geologic hazards, such as faults and landslide-prone areas, to provide more accurate assessments of the risks associated with these features. The steep canyon walls of the map area reveal exten­sive outcrops of Miocene flood-basalt flows of the Columbia River Basalt Group capped by fluvial deposits of the ances­tral Columbia River, Pliocene lavas erupted from the axis of the Cascade arc to the east, and volcanic rocks erupted from numerous local vents. The Columbia River Basalt Group unconformably rests on a sequence of late Oligocene and early Miocene rocks of the ancestral Cascade volcanic arc, which underlies most of the map area. The resistant flood-basalt flows form some of the famous landforms in the map area, such as Hamilton Mountain. Extensive landslide complexes have devel­oped where the basalt flows were emplaced on weak volcani­clastic rocks.

Washington↗
USGS2010

Application of AFINCH as a tool for evaluating the effects of streamflow-gaging-network size and composition on the accuracy and precision of streamflow estimates at ungaged locations in the southeast Lake Michigan hydrologic subregion

Bootstrapping techniques employing random subsampling were used with the AFINCH (Analysis of Flows In Networks of CHannels) model to gain insights into the effects of variation in streamflow-gaging-network size and composition on the accuracy and precision of streamflow estimates at ungaged locations in the 0405 (Southeast Lake Michigan) hydrologic subregion. AFINCH uses stepwise-regression techniques to estimate monthly water yields from catchments based on geospatial-climate and land-cover data in combination with available streamflow and water-use data. Calculations are performed on a hydrologic-subregion scale for each catchment and stream reach contained in a National Hydrography Dataset Plus (NHDPlus) subregion. Water yields from contributing catchments are multiplied by catchment areas and resulting flow values are accumulated to compute streamflows in stream reaches which are referred to as flow lines. AFINCH imposes constraints on water yields to ensure that observed streamflows are conserved at gaged locations. Data from the 0405 hydrologic subregion (referred to as Southeast Lake Michigan) were used for the analyses. Daily streamflow data were measured in the subregion for 1 or more years at a total of 75 streamflow-gaging stations during the analysis period which spanned water years 1971–2003. The number of streamflow gages in operation each year during the analysis period ranged from 42 to 56 and averaged 47. Six sets (one set for each censoring level), each composed of 30 random subsets of the 75 streamflow gages, were created by censoring (removing) approximately 10, 20, 30, 40, 50, and 75 percent of the streamflow gages (the actual percentage of operating streamflow gages censored for each set varied from year to year, and within the year from subset to subset, but averaged approximately the indicated percentages). Streamflow estimates for six flow lines each were aggregated by censoring level, and results were analyzed to assess (a) how the size and composition of the streamflow-gaging network affected the average apparent errors and variability of the estimated flows and (b) whether results for certain months were more variable than for others. The six flow lines were categorized into one of three types depending upon their network topology and position relative to operating streamflow-gaging stations. Statistical analysis of the model results indicates that (1) less precise (that is, more variable) estimates resulted from smaller streamflow-gaging networks as compared to larger streamflow-gaging networks, (2) precision of AFINCH flow estimates at an ungaged flow line is improved by operation of one or more streamflow gages upstream and (or) downstream in the enclosing basin, (3) no consistent seasonal trend in estimate variability was evident, and (4) flow lines from ungaged basins appeared to exhibit the smallest absolute apparent percent errors (APEs) and smallest changes in average APE as a function of increasing censoring level. The counterintuitive results described in item (4) above likely reflect both the nature of the base-streamflow estimate from which the errors were computed and insensitivity in the average model-derived estimates to changes in the streamflow-gaging-network size and composition. Another analysis demonstrated that errors for flow lines in ungaged basins have the potential to be much larger than indicated by their APEs if measured relative to their true (but unknown) flows. “Missing gage” analyses, based on examination of censoring subset results where the streamflow gage of interest was omitted from the calibration data set, were done to better understand the true error characteristics for ungaged flow lines as a function of network size. Results examined for 2 water years indicated that the probability of computing a monthly streamflow estimate within 10 percent of the true value with AFINCH decreased from greater than 0.9 at about a 10-percent network-censoring level to less than 0.6 as the censoring level approached 75 percent. In addition, estimates for typically dry months tended to be characterized by larger percent errors than typically wetter months.

Indiana, Michigan↗
USGS2012

Preliminary assessment of sources of nitrogen in groundwater at a biosolids-application area near Deer Trail

Concentrations of dissolved nitrite plus nitrate increased fairly steadily in samples from four shallow groundwater monitoring wells after biosolids applications to nonirrigated farmland began in 1993. The U.S. Geological Survey began a preliminary assessment of sources of nitrogen in shallow groundwater at part of the biosolids-application area near Deer Trail, Colorado, in 2005 in cooperation with the Metro Wastewater Reclamation District. Possible nitrogen sources in the area include biosolids, animal manure, inorganic fertilizer, atmospheric deposition, and geologic materials (bedrock and soil). Biosolids from the Metro Wastewater Reclamation District plant in Denver and biosolids, cow manure, geologic materials (bedrock and soil), and groundwater from the study area were sampled to measure nitrogen content and nitrogen isotopic compositions of nitrate or total nitrogen. Biosolids also were leached, and the leachates were analyzed for nitrogen content and other concentrations. Geologic materials from the study area also were sampled to determine mineralogy. Estimates of nitrogen contributed from inorganic fertilizer and atmospheric deposition were calculated from other published reports. The nitrogen information from the study indicates that each of the sources contain sufficient nitrogen to potentially affect groundwater nitrate concentrations. Natural processes can transform the nitrogen in any of the sources to nitrate in the groundwater. Load calculations indicate that animal manure, inorganic fertilizer, or atmospheric deposition could have contributed the largest nitrogen load to the study area in the 13 years before biosolids applications began, but biosolids likely contributed the largest nitrogen load to the study area in the 13 years after biosolids applications began. Various approaches provided insights into sources of nitrate in the groundwater samples from 2005. The isotopic data indicate that, of the source materials considered, biosolids and (or) animal manure were the most likely sources of nitrate in the wells at the time of sampling (2005), and that inorganic fertilizer, atmospheric deposition, and geologic materials were not substantial sources of nitrate in the wells in 2005. The large total nitrogen content of the biosolids and animal-manure samples and biosolids leachates also indicates that the biosolids and animal manure had potential to leach nitrogen and produce large dissolved nitrate concentrations in groundwater. The available data, however, could not be used to distinguish between biosolids or manure as the dominant source of nitrate in the groundwater because the nitrogen isotopic composition of the two materials is similar. Major-ion data also could not be used to distinguish between biosolids or manure as the dominant source of nitrate in the groundwater because the major-ion composition (as well as the isotopic composition) of the two materials is similar. Without additional data, chloride/bromide mass ratios do not necessarily support or refute the hypothesis that biosolids and (or) animal manure were the primary sources of nitrate in water from the study-area wells in 2005. Concentrations of water-extractable nitrate in the soil indicate that biosolids could be an important source of nitrate in the groundwater recharge. Nitrogen inventories in the soil beneath biosolids-application areas and the nitrogen-input estimates for the study area both support the comparisons of isotopic composition, which indicate that some type of human waste (such as biosolids) and (or) animal manure was the source of nitrate in groundwater sampled from the wells in 2005. The nitrogen-load estimates considered with the nitrogen isotopic data and the soil-nitrogen inventories indicate that biosolids applications likely are a major source of nitrogen to the shallow groundwater at these monitoring wells.

Colorado↗
USGS2002

Reducing predation by common ravens on desert tortoises in the Mojave and Colorado Deserts

Conflicts between humans and natural populations often result from habitat fragmentation and degradation that accompanies human activities. Common raven populations in the Mojave Desert have benefited by human-provided resources; they've expanded precipitously in recent years. Because ravens prey on juveniles of the threatened desert tortoise, they have become the focus of management concerns to help recover dwindling tortoise populations. I have outlined herein a series of management recommendations designed to reduce raven predation on desert tortoises thereby facilitating juvenile tortoise recruitment into the population of reproductive adults. The recommendations are based on the best available scientific information and are intended to provide a basis for a long-term reduction in raven impacts. The recommendations fall into four basic categories. (1) Modify anthropogenic sources of food, water, and nesting substrates to reduce their use by ravens. This includes modifying landfill operations, septage containment practices, livestock management, and other commercial and private practices that help facilitate raven survival and dispersal by providing food and water. Most of these measures are long-term actions deigned to reduce the carrying capacity of the desert for ravens. This action is critical and must be done over very large areas. (2)Lethal removal of ravens by shooting or euthanizing following live trapping. Specific ravens known to prey on tortoises would be targeted as well as all ravens found foraging within specific high-priority desert tortoise management zones (e.g., Desert Tortoise Natural Areas, DTNA). These actions would primarily be deployed on a short-term emergency basis to give specific tortoise populations a necessary boost until other measures become fully implemented and achieve their goals. (3) Conduct research on raven ecology, raven behavior, and methods to reduce raven predation on tortoises. Results of these studies would be used to design future phases of the raven management program. (4) All actions should be approached within an adaptive management framework. As such monitor, actions should be designed as experiments so that monitoring of actions will yield reliable and scientifically sound results. Coordinating and oversight teams should be convened to facilitate cooperation and coordination among agencies and to ensure that the actions are being implemented effectively. Recommendations made herein were developed to help recover tortoise populations by reducing raven predation on juvenile tortoises. If the recommendations made are implemented in concert with actions reducing other causes of mortality, ill health, and lowered reproductive output, they should aid in the long-term recovery of desert tortoise populations. Many important aspects of raven population dynamics, raven predation on tortoises, and how to manage raven populations and behavior are as yet unknown. Because of this, any raven management program must be implemented within an adaptive management framework. Doing so would allow for sufficient flexibility to modify the program as new information is gained.

Report↗