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At least 1,045 records · Page 58Linked to original sources

Chlorine-36 as a tracer of perchlorate origin

Perchlorate (ClO 4 − ) is ubiquitous in the environment. It is produced naturally by atmospheric photochemical reactions, and also is synthesized in large quantities for military, aerospace, and industrial applications. Nitrate-enriched salt deposits of the Atacama Desert (Chile) contain high concentrations of natural ClO 4 − , and have been exported worldwide since the mid-1800s for use in agriculture. The widespread introduction of synthetic and agricultural ClO 4 − into the environment has contaminated numerous municipal water supplies. Stable isotope ratio measurements of Cl and O have been applied for discrimination of different ClO 4 − sources in the environment. This study explores the potential of 36 Cl measurements for further improving the discrimination of ClO 4 − sources. Groundwater and desert soil samples from the southwestern United States (U.S.) contain ClO 4 − having high 36 Cl abundances ( 36 Cl/Cl = 3100 × 10 −15 to 28,800 × 10 −15 ), compared with those from the Atacama Desert ( 36 Cl/Cl = 0.9 × 10 −15 to 590 × 10 −15 ) and synthetic ClO 4 − reagents and products ( 36 Cl/Cl = 0.0 × 10 −15 to 40 × 10 −15 ). In conjunction with stable Cl and O isotope ratios, 36 Cl data provide a clear distinction among three principal ClO 4 − source types in the environment of the southwestern U.S.

Environmental Science & Technology↗

Radioisotopic data of sediment collected in Mobile and Bon Secour Bays, Alabama

The focus of this study was to determine the extent of natural and (or) anthropogenic impacts on the sedimentary records of Mobile and Bon Secour Bays, Alabama during the last 150 years. These bays are unique in that anthropogenic activities are generally widespread and span both the eastern and western shorelines. However, there is a clear distinction in the types of human development and infrastructure between the western and eastern shorelines. These activities and the differences in land-use and -change influence the overall supply and remobilization of sediment to and within the bay. These factors could subsequently threaten the health and integrity of these environments and their ability to mitigate against long-term processes associated with climate change. In an attempt to characterize long-term accretion rates within the Mobile Bay Estuarine System (MBES), seven box cores were collected and analyzed for excess lead-210 ( 210 Pb xs , the difference between total and supported 210 Pb) and cesium-137 ( 137 Cs) activities. The MBES receives sediment and water from the Alabama and Tombigbee River watersheds, which converge into the Mobile-Tensaw River (MTR) system just prior to discharging into Mobile Bay. Riverine discharge from the MTR system to the bay is second only to the Mississippi River discharge to the Gulf of Mexico for the conterminous United States.

Alabama↗

Optical satellite data volcano monitoring: a multi-sensor rapid response system

In this chapter, the use of satellite remote sensing to monitor active geological processes is described. Specifically, threats posed by volcanic eruptions are briefly outlined, and essential monitoring requirements are discussed. As an application example, a collaborative, multi-agency operational volcano monitoring system in the north Pacific is highlighted with a focus on the 2007 eruption of Kliuchevskoi volcano, Russia. The data from this system have been used since 2004 to detect the onset of volcanic activity, support the emergency response to large eruptions, and assess the volcanic products produced following the eruption. The overall utility of such integrative assessments is also summarized. The work described in this chapter was originally funded through two National Aeronautics and Space Administration (NASA) Earth System Science research grants that focused on the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) instrument. A skilled team of volcanologists, geologists, satellite tasking experts, satellite ground system experts, system engineers and software developers collaborated to accomplish the objectives. The first project, Automation of the ASTER Emergency Data Acquisition Protocol for Scientific Analysis, Disaster Monitoring, and Preparedness , established the original collaborative research and monitoring program between the University of Pittsburgh (UP), the Alaska Volcano Observatory (AVO), the NASA Land Processes Distributed Active Archive Center (LP DAAC) at the U.S. Geological Survey (USGS) Earth Resources Observation and Science (EROS) Center, and affiliates on the ASTER Science Team at the Jet Propulsion Laboratory (JPL) as well as associates at the Earth Remote Sensing Data Analysis Center (ERSDAC) in Japan. This grant, completed in 2008, also allowed for detailed volcanic analyses and data validation during three separate summer field campaigns to Kamchatka Russia. The second project, Expansion and synergistic use of the ASTER Urgent Request Protocol (URP) for natural disaster monitoring and scientific analysis , has expanded the project to other volcanoes around the world and is in progress through 2011. The focus on ASTER data is due to the suitability of the sensor for natural disaster monitoring and the availability of data. The instrument has several unique facets that make it especially attractive for volcanic observations (Ramsey and Dehn, 2004). Specifically, ASTER routinely collects data at night, it has the ability to generate digital elevation models using stereo imaging, it can collect data in various gain states to minimize data saturation, it has a cross-track pointing capability for faster targeting, and it collects data up to ±85° latitude for better global coverage. As with any optical imaging-based remote sensing, the viewing conditions can negatively impact the data quality. This impact varies across the optical and thermal infrared wavelengths as well as being a function of the specific atmospheric window within a given wavelength region. Water vapor and cloud formation can obscure surface data in the visible and near infrared (VNIR)/shortwave infrared (SWIR) region due mainly to non-selective scattering of the incident photons. In the longer wavelengths of the thermal infrared (TIR), scattering is less of an issue, but heavy cloud cover can still obscure the ground due to atmospheric absorption. Thin clouds can be optically-transparent in the VNIR and TIR regions, but can cause errors in the extracted surface reflectance or derived surface temperatures. In regions prone to heavy cloud cover, optical remote sensing can be improved through increased temporal resolution. As more images are acquired in a given time period the chances of a clear image improve dramatically. The Advanced Very High Resolution Radiometer (AVHRR) routine monitoring, which commonly collects 4-6 images per day of any north Pacific volcano, takes advantage of this fact. The rapid response program described in this chapter also improves the temporal resolution of the ASTER instrument. ASTER has been acquiring images of volcanic eruptions since soon after its launch in December 1999. An early example included the observations of the large pyroclastic flow deposit emplaced at Bezymianny volcano in Kamchatka, Russia. The first images in March 2000, just weeks after the eruption, revealed the extent, composition, and cooling history of this large deposit and of the active lava dome (Ramsey and Dehn, 2004). The initial results from these early datasets spurred interest in using ASTER data for expanded volcano monitoring in the north Pacific. It also gave rise to the multi-year NASA-funded programs of rapid response scheduling and imaging throughout the Aleutian, Kamchatka and Kurile arcs. Since the formal establishment of the programs, the data have provided detailed descriptions of the eruptions of Augustine, Bezymianny, Kliuchevskoi and Sheveluch volcanoes over the past nine years (Wessels et al., in press; Carter et al., 2007, 2008; Ramsey et al., 2008; Rose and Ramsey, 2009). The initial research focus of this rapid response program was specifically on automating the ASTER sensor’s ability for targeted observational scheduling using the expedited data system. This urgent request protocol is one of the unique characteristics of ASTER. It provides a limited number of emergency observations, typically at a much-improved temporal resolution and quicker turnaround with data processing in the United States rather than in Japan. This can speed the reception of the processed data by several days to a week. The ongoing multi-agency research and operational collaboration has been highly successful. AVO serves as the primary source for status information on volcanic activity, working closely with the National Weather Service (NWS), Federal Aviation Administration (FAA), military and other state and federal emergency services. Collaboration with the Russian Institute of Volcanology and Seismology (IVS)/Kamchatka Volcanic Eruption Response Team (KVERT) is also maintained. Once a volcano is identified as having increased thermal output, ASTER is automatically tasked and the volcano is targeted at the next available opportunity. After the data are acquired, scientists at all the agencies have access to the images, with the primary science analysis carried out at the University of Pittsburgh and AVO. Results are disseminated to the responsible monitoring agencies and the global community through e-mail mailing lists.

Book chapter↗

Long-term trends in the St. Marys River open water fish community

We examined trends in species composition and abundance of the St. Marys River fish community. Abundance data were available approximately once every six years from 1975 through 2006, and size and age data were available from 1995 through 2006. We also compared survey data in 2006 with results of a concurrent creel survey that year, as well as data from prior surveys spanning a 69 year time frame. The St. Marys River fish community was best characterized as a coolwater fish community with apparent little variation in species composition, and only slight variation in overall fish abundance since 1975. However, we did find recent trends in abundance among target species sought by anglers: centrarchids increased, percids appeared stable, and both northern pike Esox lucius and cisco Coregonus artedii declined. Survey results suggested that walleye ( Sander vitreus ) and yellow perch ( Perca flavescens ) experienced moderate exploitation but benefited from recent strong recruitment and faster growth. Mechanisms underlying declines of northern pike and cisco were not clear; reduced abundance could have resulted from high exploitation, variation in recruitment, or a combination of both factors. Despite these challenges, the St. Marys River fish community appears remarkably stable. We suggest that managers insure that creel surveys occur simultaneously with assessments, but periodic gill net surveys may no longer provide adequate data in support of recent, more complex management objectives. While additional surveys would add costs, more frequent data might ensure sustainability of a unique fish community that supports a large proportion of angler effort on Lake Huron.

Michigan;Ontario↗

Fate and Transport Modeling of Selected Chlorinated Organic Compounds at Operable Unit 1, U.S. Naval Air Station, Jacksonville, Florida

The U.S. Naval Air Station occupies 3,800 acres adjacent to the St. Johns River in Jacksonville, Florida. The Station was placed on the U.S. Environmental Protection Agency's National Priorities List in December 1989 and is participating in the U.S. Department of Defense Installation Restoration Program, which serves to identify and remediate environmental contamination. One contaminated site, the old landfill, was designated as Operable Unit 1 (OU1) in 1989. The major source of ground-water contamination was from the disposal of waste oil and solvents into open pits, which began in the 1940s. Several remedial measures were implemented at this site to prevent the spread of contamination. Recovery trenches were installed in 1995 to collect free product. In 1998, some of the contamination was consolidated to the center of the old landfill and covered by an impermeable cap. Currently, Operable Unit 1 is being reevaluated as part of a 5-year review process to determine if the remedial actions were effective. Solute transport modeling indicated that the concentration of contaminants would have reached its maximum extent by the 1970s, after which the concentration levels would have generally declined because the pits would have ceased releasing high levels of contaminants. In the southern part of the site, monitoring well MW-19, which had some of the highest levels of contamination, showed decreases for measured and simulated concentrations of trichloroethene (TCE) and dichloroethene (DCE) from 1992 to present. Two upgradient disposal pits were simulated to have ceased releasing high levels of contamination in 1979, which consequently caused a drop in simulated concentrations. Monitoring well MW-100 had the highest levels of contamination of any well directly adjacent to a creek. Solute transport modeling substantially overestimated the concentrations of TCE, DCE, and vinyl chloride (VC) in this well. The reason for this overestimation is not clear, however, it indicates that the model will be conservative when used to predict concentration levels and the time required for the contamination to move through the system. Monitoring well MW-97 had the highest levels of contamination in the central part of the site. The levels decreased for both the measured and simulated values of TCE, DCE, and VC from 1999 to present. Simulating the source area as ceasing to release high levels of contamination in 1979 caused the drop in concentration, which began in the 1990s at this well. Monitoring well MW-89 had the highest levels of contamination in the northern part of the site. In order to match the low levels of contamination in wells MW-12 and MW-93, the pit was simulated as ceasing to release contamination in 1970; however, the installation of a trench in 1995 could have caused the source area to release additional contamination from 1995 to 1998. The effect of the additional dissolution was a spike in contamination at MW-89, beginning in about 1996 and continuing until the present time. Results from the last several sampling events indicate that the TCE and DCE levels could be decreasing, but VC shows no apparent trend. Several more years of sampling are needed to determine if these trends are continuing. Based on the solute transport modeling predictions, TCE, DCE, and VC will have migrated to the vicinity of creeks that drain ground water from the aquifer by 2010, and only relatively low levels will remain in the aquifer by 2015. Because the creeks represent the point where the contaminated ground water comes into contact with the environment, future contamination levels are a concern. The concentration of chlorinated solvents in the creek water has always been relatively low. Because the model shows that concentrations of TCE, DCE, and VC are declining in the aquifer, contamination levels in the creeks also are anticipated to decline.

Scientific Investigations Report↗

Satellite tracking of hawksbill turtles nesting at Buck Island Reef National Monument, US Virgin Islands: Inter-nesting and foraging period movements and migrations

To conserve imperiled marine species, an understanding of high-density use zones is necessary prior to designing and evaluating management strategies that improve their survival. We satellite-tracked turtles captured after nesting at Buck Island ReefNational Monument (BIRNM), St. Croix, US Virgin Islands to determine habitat-use patterns of endangered adult female hawksbills ( Eretmochelys imbricata ). For 31 turtles captured between 2011 and 2014, switching state-space modeling and home range analyses showed that inter-nesting (IN) core-use areas (i.e., 50% kernel density estimates [KDEs]) were 9.6 to 77.7 km 2 in area, occupied for 21 to 85 days, and in shallow water(21 of 26 centroids > −10 m). The IN zones overlapped with areas both within the protected borders of BIRNM, and outside BIRNM (32% of turtle-tracking days outside during IN). Turtles migrated to their foraging grounds between July and October with path lengths ranging from 52 to 3524 km; foraging areas included 14 countries. Core-use foraging areas (50% KDEs) where turtles took up residence were 6.3 to 95.4 km 2 , occupied for 22 to 490 days, with mean centroid depth − 66 m. Our results show previously unknown habitat-use patterns and highlight concentrated areas of use both within and adjacent to a US protected area during the breeding season. Further, our results clearly demonstrate the need for international conservation to protect hawksbills, as migrating turtles crossed between two and eight different jurisdictions. Our results provide critical spatial and temporal information for managers charged with designing strategies to minimize human impact to and maximize survival for this globally imperiled species.

Virgin Islands↗

Holocene alluvial stratigraphy and response to climate change in the Roaring River valley, Front Range, Colorado, USA

Stratigraphic analyses and radiocarbon geochronology of alluvial deposits exposed along the Roaring River, Colorado, lead to three principal conclusions: (1) the opinion that stream channels in the higher parts of the Front Range are relics of the Pleistocene and nonalluvial under the present climate, as argued in a water-rights trial USA v. Colorado, is untenable, (2) beds of clast-supported gravel alternate in vertical succession with beds of fine-grained sediment (sand, mud, and peat) in response to centennial-scale changes in snowmelt-driven peak discharges, and (3) alluvial strata provide information about Holocene climate history that complements the history provided by cirque moraines, periglacial deposits, and paleontological data. Most alluvial strata are of late Holocene age and record, among other things, that: (1) the largest peak flows since the end of the Pleistocene occurred during the late Holocene; (2) the occurrence of a mid- to late Holocene interval (~2450–1630(?) cal yr BP) of warmer climate, which is not clearly identified in palynological records; and (3) the Little Ice Age climate seems to have had little impact on stream channels, except perhaps for minor (~1 m) incision. Published

Colorado↗

Geoelectric monitoring of the electric potential field of the Lower Rio Grande before, during, and after Intermittent Streamflow, May–October, 2022

Understanding the intermittent hydraulic connectivity between ephemeral streams and alluvial aquifers is a key challenge for managing water resources in arid environments. The lower Rio Grande flows for short, discontinuous periods during the irrigation season through the Mesilla Basin in southeastern New Mexico and southwestern Texas. Hydraulic connections between the Rio Grande and the Rio Grande alluvial aquifer in the Mesilla Basin vary spatially and temporally and are not well understood. Self-potential (SP) monitoring and time-lapse electric resistivity tomography (ERT) were therefore performed along linear cross-sections spanning the riverbed and flood plain for more than 4 months to monitor the transient hydraulic connection between the river and the alluvial aquifer by measuring time-lapse changes in the electric potential field in the riverbed and flood plain. The monitoring period began on 21 May 2022, when the riverbed was completely dry, continued through the irrigation season while streamflow was provided by reservoir releases from upstream dams, and ended on 4 October 2022, when the riverbed was again dry. SP monitoring data show (1) a background condition in the dry riverbed consisting of (a) a positive electric potential anomaly with a maximum amplitude of about +100 mV attributed predominantly to a subsurface vertical salt concentration gradient and (b) diurnal electric potential fluctuations with amplitudes of 40,000–90,000 mV attributed to near-surface heat conduction driven by weather variability, in addition to (2) a streaming potential anomaly during the irrigation season with a maximum amplitude of about −3500 mV whose transient behavior clearly exhibited a change from the background anomaly to depict exclusively losing streamflow conditions that persisted through the irrigation season. Time-lapse ERT monitoring results depict rapid infiltration of streamflow into the subsurface and imply the river and Rio Grande alluvial aquifer established a full hydraulic connection within a few hours after streamflow arrival at the monitoring site. SP monitoring data show an apparent transition from hydraulic connection to disconnection at the end of the irrigation season and indicate that the transitional phase between connection and disconnection may last substantially longer than the transition from disconnection to connection. The combination of SP and ERT monitoring demonstrated herein shows the potential for broader applications of time-lapse monitoring of hydraulic intermittency and near-surface heat fluxes in different rivers.

New Mexico, Texas↗

Quantifying form resistance is essential for estimating summer low and bankfull flow from stream survey channel morphology

Reliable estimates of low flow and flood discharge at ungaged locations are required for evaluating stream flow alteration, designing culverts and stream crossings, and interpreting regional surveys of habitat and biotic condition. Very few stream gaging stations are located on small, remote streams, which typically have complex channel morphology. Adequate gaging is also lacking on larger streams that are remote, smaller than those typically gaged, or have channel morphology not conducive to installation of gages. Complex channels typically contain large scale hydraulic roughness elements that dominate flow patterns (i.e., form roughness), making it difficult to measure channel cross-section area and water velocity, or to measure channel volume even where discharge is known. In channels with large channel form roughness, it is equally difficult to estimate discharge using commonly applied equations based on slope and channel dimensions or basin area. We employed a novel approach that explicitly accounts for hydraulic resistance from large wood and riffle-pool morphology (form roughness) in calculating low flow and bankfull discharge from stream and river physical habitat data collected from 4229 stream and river sites in the conterminous US (CONUS) sampled in 2008–9 and 2013–14 as part of the US Environmental Protection Agency's N ational R ivers and S treams A ssessment (NRSA). Hydraulic resistance derived from form roughness clearly dominated resistance derived from bed particles (particle resistance) during summer low flows in wadeable streams across the spectrum of channel slopes and substrate sizes smaller than boulders. Under bankfull conditions, the influence of form resistance relative to particle resistance was diminished, but form resistance still dominated except in large low gradient rivers lacking complex channels, and in streams or rivers with boulder-size bed particles. We validated our hydraulic resistance estimates by comparing measured discharges with calculated discharges that used those hydraulic resistance estimates along with measured NRSA channel morphology data. Morphology-based summer discharge (low flow) estimates and direct field measurements of discharge in 2333 wadeable CONUS streams showed reasonable agreement (median difference < 2.5×) for discharges ranging from 3.6 × 10 −5 to 123 m 3 /s and drainage areas of 0.12 to 171,000 km 2 . In a subset of 759 of NRSA's larger wadeable stream and non-wadeable river sites where nearby U.S. Geological Survey (USGS) gage data were available and adequate, our morphology-based summer discharge estimates agreed fairly well (median difference < 2.0×) with USGS 20-yr average August mean flows ranging from 0.003 to 16,000 m 3 /s. Similarly, morphology-based estimates of bankfull flow ranging from 0.3 to 100,000 m 3 /s agreed reasonably well with the 1.5-yr recurrence interval flood in these gaged sites (median deviation <2.2×). These findings demonstrate the importance of quantifying flow resistance from large-scale form roughness features in natural channels and provide a novel approach for estimating discharge from widely available survey data. This will allow examination of discharge and its ecological influence across the full range of stream and river sizes sampled by NRSA or other synoptic surveys where comprehensive measures of biota, physical habitat, and chemistry are also made. Although these morphology-based estimates exhibit some variability, they are adequate for examining regional patterns in discharge and flow alteration and their association with instream biota and anthropogenic disturbances, providing summer low and bankfull flow information where reliable estimates are lacking.

Geomorphology↗

Vegetation affects timing and location of wetland methane emissions

Common assumptions about how vegetation affects wetland methane (CH) flux include acting as conduits for CH release, providing carbon substrates for growth and activity of methanogenic organisms, and supplying oxygen to support CH oxidation. However, these effects may change through time, especially in seasonal wetlands that experience drying and re-wetting, or change across space, dependent on proximity to vegetation. In a mesocosm study, we assessed the impacts of on CH flux using clear flux-chamber measurements directly over plants (&lsquo;whole-plant&rsquo;), adjacent to plants (where roots were present but no stems; &lsquo;plant-adjacent&rsquo;), and plant-free soils (&lsquo;control&rsquo;). During the establishment phase of the study (first 30-days), the whole-plant treatment had ~5-times higher CH flux rates (51.78&plusmn;8.16 mg-C md) than plant-adjacent or control treatments, which was primarily due to plant-mediated transport, with little contribution from diffusive-only flux. However, high fluxes from whole-plants depleted porewater CH concentrations both directly below whole-plant and in neighboring plant-adjacent treatments, while controls accumulated a highly concentrated reservoir of porewater CH. When the water table was drawn down to simulate seasonal drying, reserve porewater CH from control soil was released as a pulse, equaling the earlier higher CH emissions from whole-plants. Plant-adjacent treatments, which had neither plant-mediated CH transport nor a concentrated reservoir of porewater CH, had low CH flux throughout the study. Our findings indicate that in seasonal wetlands, vegetation affects the timing and location of CH emissions. These results have important mechanistic and methodological implications for understanding the role of vegetation on wetland CH flux.

Journal of Geophysical Research: Biogeosciences↗

Planning riparian restoration in the context of tamarix control in Western North America

Throughout the world, the condition of many riparian ecosystems has declined due to numerous factors, including encroachment of non-native species. In the western United States, millions of dollars are spent annually to control invasions of Tamarix spp., introduced small trees or shrubs from Eurasia that have colonized bottomland ecosystems along many rivers. Resource managers seek to control Tamarix in attempts to meet various objectives, such as increasing water yield and improving wildlife habitat. Often, riparian restoration is an implicit goal, but there has been little emphasis on a process or principles to effectively plan restoration activities, and many Tamarix removal projects are unsuccessful at restoring native vegetation. We propose and summarize the key steps in a planning process aimed at developing effective restoration projects in Tamarix-dominated areas. We discuss in greater detail the biotic and abiotic factors central to the evaluation of potential restoration sites and summarize information about plant communities likely to replace Tamarix under various conditions. Although many projects begin with implementation, which includes the actual removal of Tamarix, we stress the importance of pre-project planning that includes: (1) clearly identifying project goals; (2) developing realistic project objectives based on a detailed evaluation of site conditions; (3) prioritizing and selecting Tamarix control sites with the best chance of ecological recovery; and (4) developing a detailed tactical plan before Tamarix is removed. After removal, monitoring and maintenance as part of an adaptive management approach are crucial for evaluating project success and determining the most effective methods for restoring these challenging sites. ?? 2008 Society for Ecological Restoration International.

Restoration Ecology↗

Coastal ocean transport patterns in the central Southern California Bight

In the past decade, several large programs that monitor currents and transport patterns for periods from a few months to a few years were conducted by a consortium of university, federal, state, and municipal agencies in the central Southern California Bight, a heavily urbanized section of the coastal ocean off the west coast of the United States encompassing Santa Monica Bay, San Pedro Bay, and the Palos Verdes shelf. These programs were designed in part to determine how alongshelf and cross-shelf currents move sediments, pollutants, and suspended material through the region. Analysis of the data sets showed that the current patterns in this portion of the Bight have distinct changes in frequency and amplitude with location, in part because the topography of the shelf and upper slope varies rapidly over small spatial scales. However, because the mean, subtidal, and tidal-current patterns in any particular location were reasonably stable with time, one could determine a regional pattern for these current fields in the central Southern California Bight even though measurements at the various locations were obtained at different times. In particular, because the mean near-surface flows over the San Pedro and Palos Verdes shelves are divergent, near-surface waters from the upper slope tend to carry suspended material onto the shelf in the northwestern portion of San Pedro Bay. Water and suspended material are also carried off the shelf by the mean and subtidal flow fields in places where the orientation of the shelf break changes abruptly. The barotropic tidal currents in the central Southern California Bight flow primarily alongshore, but they have pronounced amplitude variations over relatively small changes in alongshelf location that are not totally predicted by numerical tidal models. Nonlinear internal tides and internal bores at tidal frequencies are oriented more across the shelf. They do not have a uniform transport direction, since they move fine sediment from the shelf to the slope in Santa Monica Bay, but carry suspended material from the mid-shelf to the beach in San Pedro Bay. It is clear that there are a large variety of processes that transport sediments and contaminants along and across the shelf in the central Southern California Bight. However, because these processes have a variety of frequencies and relatively small spatial scales, the dominant transport processes tend to be localized and have dissimilar characteristics even in adjacent regions of this small part of the coastal ocean. ?? 2009 The Geological Society of America.

Special Paper of the Geological Society of America↗

Depletion of isoeugenol residues from the fillet tissue of AQUI-S™ exposed rainbow trout ( Oncorhynchus mykiss )

There is a critical need in U.S. public aquaculture and fishery management for an approved sedative that allows for the immediate release of fish after sedation. AQUI-S TM is a fish anesthetic/sedative approved for use in several countries and until recently was being developed in the U.S. as a sedative for immediate release of fish after sedation. The U.S. National Toxicology Program reported that isoeugenol (the active ingredient in AQUI-S TM ) exposed male mice showed clear evidence of carcinogenicity, therefore efforts within the U.S. Department of Interior to develop AQUI-S TM as a sedative that allows for immediate release ceased. Despite the ruling, AQUI-S TM still has the potential to be approved as an anesthetic with a short withdrawal time. Among the data required to gain approval for use in the U.S. are data describing the composition and depletion of all AQUI-S TM residues from fish fillet tissue. A total residue depletion study for AQUI-S TM was conducted by exposing market-sized rainbow trout, Oncorhynchus mykiss (mean weight, 502.7 &plusmn; 54 g; s.d.) to 8.9 mg/L of 14 C-[URL]-isoeugenol for 60 min in 17 &deg;C water. The 14 C-[URL]-isoeugenol was mixed with a surfactant resulting in a mixture that mimicked AQUI-S TM . Groups of fish ( n = 6) were sampled immediately after the exposure (0-h sample group) and at 0.5, 1, 2, and 4 h thereafter. Total isoeugenol-equivalent residue concentrations in the fillet tissue were determined by oxidizing triplicate subsamples of homogenized skin-on fillet tissue from each fish to 14 CO 2 and enumerating the radioactivity by static liquid scintillation counting. Isoeugenol concentrations in fillet tissue were determined by extracting homogenized fillet tissue with solvents and determining the isoeugenol concentrations in the extracts with high performance liquid chromatography techniques. The mean total isoeugenol-equivalent residue concentrations in the 0, 0.5, 1, 2, and 4-h sample groups were 55.4, 32.0, 19.8, 11.3, and 4.9 &micro;g/g, respectively. The primary chemical residue in fillet tissue from all exposed fish was isoeugenol. The mean isoeugenol concentrations in the 0, 0.5, 1, 2, and 4-h sample groups were 48.9, 26.5, 15.3, 7.2, and 2.2 &micro;g/g, respectively. The percents of the total radioactivity classified as isoeugenol in the 0, 0.5, 1, 2, and 4-h tissue extracts were 95, 73, 73, 64, and 48%, respectively.

Aquaculture↗

Development of a Fluvial Egg Drift Simulator to evaluate the transport and dispersion of Asian carp eggs in rivers

Asian carp are migrating towards the Great Lakes and are threatening to invade this ecosystem, hence there is an immediate need to control their population. The transport of Asian carp eggs in potential spawning rivers is an important factor in its life history and recruitment success. An understanding of the transport, development, and fate of Asian carp eggs has the potential to create prevention, management, and control strategies before the eggs hatch and develop the ability to swim. However, there is not a clear understanding of the hydrodynamic conditions at which the eggs are transported and kept in suspension. This knowledge is imperative because of the current assumption that suspension is required for the eggs to survive. Herein, FluEgg (Fluvial Egg Drift Simulator), a three-dimensional Lagrangian model capable of evaluating the influence of flow velocity, shear dispersion and turbulent diffusion on the transport and dispersal patterns of Asian carp eggs is presented. The model's variables include not only biological behavior (growth rate, density changes) but also the physical characteristics of the flow field, such as mean velocities and eddy diffusivities. The performance of the FluEgg model was evaluated using observed data from published flume experiments conducted in China with water-hardened Asian carp eggs as subjects. FluEgg simulations show a good agreement with the experimental data. The model was also run with observed data from the Sandusky River in Ohio to provide a real-world demonstration case. This research will support the identification of critical hydrodynamic conditions (e.g., flow velocity, depth, and shear velocity) to maintain eggs in suspension, assist in the evaluation of suitable spawning rivers for Asian carp populations and facilitate the development of prevention, control and management strategies for Asian carp species in rivers and water bodies.

Ecological Modelling↗

Guide for benthic invertebrate studies in support of Natural Resource Damage Assessment and Restoration

This guide is intended to assist with characterizing injury to freshwater benthic macroinvertebrates (BMIs) in Natural Resource Damage Assessment and Restoration (NRDAR) cases. The contents are narrowly focused on insects, crustaceans, snails, and other invertebrate fauna that are typically considered part of BMI communities and are not intended to address studies of injury to larger benthic taxa such as freshwater mussels, crayfish, or benthic fishes or amphibians. Although some percentage of the community functions as predators, BMIs are predominantly primary consumers (for example, scrapers, shredders, and filterer/gatherer feeding groups) that play an essential role in converting carbon and nitrogen from plant tissues into animal biomass for higher-order consumers, especially in flowing waters. Aquatic contaminants can disrupt the quantity and quality of energy transferred (ecosystem function) by reducing invertebrate biomass and diversity. Additionally, the accumulation of toxic residues in invertebrate tissues may be a source of exposure leading to adverse effects in higher trophic levels. The goal of NRDAR BMI assessments is to establish direct linkages of contaminant exposure to injuries reflected by changes in community structure (for example, reduced density and taxa richness) or by effects at the individual population level (for example, survival, growth, and reproduction). BMIs are infrequently the U.S. Department of Interior (DOI)-managed resource in a NRDAR case, with managed resources more frequently including migratory birds, fish, or other insectivorous vertebrates. Therefore, it is critical to have clearly defined objectives for evaluating BMIs and an understanding of how invertebrate data relate to the quantification of injuries to the DOI-managed resource. This guide is intended to assist decisions on whether or not to proceed with BMI studies, use of existing information and data for screening purposes, and what types of studies can support a BMI-injury determination. This document is intended to provide general considerations and best practices for assessing BMIs. Relevant guidance and references are listed throughout the report as sources for specific methods and analysis.

Open-File Report↗

Defining the limits of spectrally based bathymetric mapping on a large river

Remote sensing has emerged as a powerful method of characterizing river systems but is subject to several important limitations. This study focused on defining the limits of spectrally based mapping in a large river. We used multibeam echosounder (MBES) surveys and hyperspectral images from a deep, clear-flowing channel to develop techniques for inferring the maximum detectable depth, d m a x "> d m a x , directly from an image and identifying optically deep areas that exceed d m a x "> d m a x . Optimal Band Ratio Analysis (OBRA) of progressively truncated subsets of the calibration data provided an estimate of d m a x "> d m a x by indicating when depth retrieval performance began to deteriorate due to the presence of depths greater than the sensor could detect. We then partitioned the calibration data into shallow and optically deep ( d &gt; d m a x "> d > d m a x ) classes and fit a logistic regression model to estimate the probability of optically deep water, P r ( O D ) "> P r ( O D ) . Applying a P r ( O D ) "> P r ( O D ) threshold value allowed us to delineate optically deep areas and thus only attempt depth retrieval in relatively shallow locations. For the Kootenai River, d m a x "> d m a x reached as high as 9.5 m at one site, with accurate depth retrieval ( R 2 = 0.94 "> R 2 = 0.94 ) in areas with d &lt; d m a x "> d < d m a x . As a first step toward scaling up from short reaches to long river segments, we evaluated the portability of depth-reflectance relations calibrated at one site to other sites along the river. This analysis highlighted the importance of calibration data spanning a broad range of depths. Due to the inherent limitations of passive optical depth retrieval in large rivers, a hybrid field- and remote sensing-based approach would be required to obtain complete bathymetric coverage.

Idaho↗

Results and Interpretations of U.S. Geological Survey Data Collected In and Around the Tuba City Open Dump, Arizona

This Open-File Report was originally an Administrative Report presentation to the Bureau of Indian Affairs based on U.S. Geological Survey data that has been collected and presented in four previous reports (Open-File Reports 2009-1020, 2008-1380, and 2008-1374, and an Administrative Report on geophysical data). This presentation was given at a technical meeting requested by the BIA on March 3 and 4, 2009, in Phoenix, Arizona. The idea for this meeting was for all the technical people working on issues related to the Tuba City Open Dump site to come together and share their data collection procedures, results, interpretations, and working hypotheses. The meeting goal was to have a clear record of each party's interpretations and a summary of additional data that would be needed to solve differences of opinion. The intention of this presentation is not to provide an exhaustive summary of U.S. Geological Survey efforts at the Tuba City Open Dump site given in the four previously published Open-File Reports listed above, since these reports have already been made available. This presentation briefly summarizes the data collected for those reports and provides results, interpretations, and working hypotheses relating to the data available in these reports. The major questions about the Tuba City Open Dump addressed by the U.S. Geological Survey are (1) what are the sources for uranium and other constituents found in the ground water in and around the Tuba City Open Dump, (2) what is the current distribution of ground water contaminants away from the Tuba City Open Dump (can plume limits be delineated), and (3) what controls the mobility of uranium and other constituents in and around the Tuba City Open Dump? Data collection, results, and interpretations by the U.S. Geological Survey that address these questions are presented herein.

Open-File Report↗

Organochlorine compounds in fish tissue and bed sediment in the upper Snake River basin, Idaho and western Wyoming, 1992-94

Fish-tissue and bed-sediment samples were collected from 20 sites in the upper Snake River Basin in Idaho and western Wyoming as part of the National Water-Quality Assessment Program to determine the occurrence and distribution of organochlorine compounds. During 1992-94, 41 samples were analyzed for 28 different organochlorine compounds in whole-fish tissue and 32 compounds in bed sediment. Sites sampled were third- through seventh-order streams that represented three environmental settings: reference conditions, agricultural land use, and mixed (agricultural and urban) land use. Fourteen organochlorine compounds were detected in fish tissue and nine in bed sediment. All compounds detected in bed sediment also were detected in fish tissue. Fish-tissue and bed- sediment samples from agricultural and mixed land-use sites contained one or more organochlorine compounds. The most frequently detected compound at all sites was p,p'DDE, which was present in 80 percent of the fish-tissue and 30 percent of the bed-sediment samples. A maximum of three compounds were detected, all in fish-tissue samples from reference (forest and rangeland) sites. The highest number of compounds was detected in fish-tissue (nine) and bed-sediment (eight) samples from mixed land-use sites. No clear relation was apparent between the occurrence of external anomalies and fish-tissue contaminant concentrations or land use. The distribution of organochlorine compounds in the basin was related to land use. Total DDT was detected at sites in all land uses; total PCB was detected at only agricultural and mixed land-use sites. Total chlordane was detected in fish- tissue samples from primarily mixed land-use sites; samples from six of the eight sites contained detectable concentrations. Median concentrations of p,p'DDE in fish-tissue samples from mixed land- use sites were significantly higher (p<0.05) than from reference and agricultural sites. Significant positive relations between percent agricultural land and concentrations of total DDT (r 2 = 0.41) and lipid-normalized total DDT (r 2 =0.48) were observed. Concentrations of p,p'DDE, total PCB, total DDT, and toxaphene in fish-tissue samples from three mixed land-use sites equaled or exceeded national guidelines established for protection of fish-eating wildlife: Portneuf River at Pocatello, total PCB; Rock Creek at Twin Falls, p,p'DDE, total DDT, and toxaphene; and Snake River near Buhl, p,p'DDE and total DDT. Concentrations of total DDT and p,p'DDE in 32 and 34 percent of fish-tissue samples, respectively, analyzed during this study exceeded the 1980-81 U.S. Fish and Wildlife Service/National Contaminant Biomonitoring Program (USFWS/NCBP) geometric mean concentrations. Concentrations of total PCB in samples from the Portneuf River at Pocatello and concentrations of toxaphene in samples from Rock Creek at Twin Falls also exceeded the USFWS/NCBP geometric mean concentrations. Comparisons of 1970-84 USFWS/NCBP concentrations of total DDT and total PCB in fish-tissue samples from the Snake River near Hagerman with concentrations measured during this study indicated a decreasing trend. Concentrations of p,p'DDE in all sediment samples from Rock Creek at Twin Falls exceeded the Canadian Probable Effect Level guideline. Total PCB was detected in sediment from only one site, Portneuf River at Pocatello, which was also the only site where concentrations of total PCB in fish tissue were elevated. Because organochlorine compounds are lipophilic and tend to bioaccumulate in tissue, fish are a better indicator of organochlorine contaminant occurrence and distribution than are bed sediment or water in the upper Snake River Basin. Some of the highest concentrations of organochlorine contaminants in tissue and sediment in the basin were detected at sites receiving irrigation- return flows. Results of this study support the importance of controlling sediment erosion on irrigated land to reduce the quantity of contaminants entering streams that receive irrigation-return flows.

Idaho;Wyoming↗