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Micromorphology and stable-isotope geochemistry of historical pedogenic siderite formed in PAH-contaminated alluvial clay soils, Tennessee, U.S.A

Alluvial clay soil samples from six boreholes advanced to depths of 400-450 cm (top of limestone bedrock) from the Chattanooga Coke Plant (CCP) site were examined micromorphologically and geochemically in order to determine if pedogenic siderite (FeCO3) was present and whether siderite occurrence was related to organic contaminant distribution. Samples from shallow depths were generally more heavily contaminated with polycyclic aromatic hydrocarbons (PAHs) than those at greater depth. The upper 1 m in most boreholes consisted of mixtures of anthropogenically remolded clay soil fill containing coal clinker, cinder grains, and limestone gravel; most layers of coarse fill were impregnated with creosote and coal tar. Most undisturbed soil (below 1 m depth) consisted of highly structured clays exhibiting fine subangular blocky ped structures, as well as redox-related features. Pedogenic siderite was abundant in the upper 2 m of most cores and in demonstrably historical (< 100 years old) soil matrices. Two morphologies were identified: (1) sphaerosiderite crystal spherulites ranging from 10 to 200 um in diameter, and (2) coccoid siderite comprising grape-like "clusters" of crystals 5-20 ??n in diameter. The siderite, formed in both macropores and within fine-grained clay matrices, indicates development of localized anaerobic, low-Eh conditions, possibly due to microbial degradation of organic contaminants. Stable-isotope compositions of the siderite have ??13C values spanning over 25%o (+7 to - 18%o VPDB) indicating fractionation of DIC by multiple microbial metabolic pathways, but with relatively constant ??18O values from (-4.8 ?? 0.66%o VPDB) defining a meteoric sphaerosiderite line (MSL). Calculated isotope equilibrium water ??18O values from pedogenic siderites at the CCP site are from 1 to 5 per mil lighter than the groundwater ??18O values that we estimate for the site. If confirmed by field studies in progress, this observation might call for a reevaluation of low-temperature siderite-water 18O fractionations. Investigations at the CCP site thus provide valuable information on the geochemical conditions under which siderite can form in modern soils, and thus insight on controls on siderite formation in ancient soils. Copyright ?? 2010, SEPM (Society for Sedimentary Geology).

Journal of Sedimentary Research↗

National Water Quality Assessment Program; the Santee Basin and coastal drainage, North Carolina and South Carolina

In 1991, the U.S. Geological Survey (USGS), U.S. Department of the Interior, began a National Water-Quality Assessment Program (NAWQA). The long-term goals of NAWQA are to describe the status of and trends in the quality of a large representative part of the Nation's surface- and ground-water resources and to identify all the major factors that affect the quality of these resources. In addressing these goals, NAWQA produces water-quality information that is useful to policymakers and managers at State, Federal, and local levels. NAWQA emphasis is on regional scale water-quality problems. The program does not diminish the need for smaller scale studies and monitoring designed and conducted by State, Federal, and local agencies. NAWQA, however, provides a large-scale framework for conducting many of these activities and an understanding about regional and national water-quality conditions that cannot be acquired from these other programs and studies. Studies of 60 hydrologic systems that include parts of most major river basins and aquifer systems are the building blocks of the national assessment. The areas of the 60 study units range in size from 1,000 to more than 60,000 square miles (mi 2 ) and represent 60 to 70 percent of the Nation's water use and population served by public water supplies. Twenty investigations were begun in 1991, 20 investigations began in 1994, and 20 are planned to begin in 1997. The assessment activities in the Santee River Basin and Coastal Drainage began in 1994.

North Carolina, South Carolina↗

Results From a Microbial Source-Tracking Study at Villa Angela Beach, Cleveland, Ohio, 2007

During the 2007 recreational season at Villa Angela Beach in Cleveland, Ohio, scientists with the U.S. Geological Survey (USGS) and the Northeast Ohio Regional Sewer District (NEORSD) found high Escherichia coli (E. coli) concentrations that were not easily explained by results obtained to date in ongoing investigations of recreational water quality at the beach. To help understand the sources behind these elevated E. coli concentrations, the USGS and NEORSD sampled beach-area water for Bacteroides DNA markers. Bacteroides are a group of enteric bacteria that are being used in microbial source tracking, in hope that host-associated DNA markers could be used to indicate potential sources of E. coli in the Villa Angela environment. The USGS Ohio Water Microbiology Laboratory analyzed a total of 13 source samples (sewage and waterfowl feces) and 33 beach-area water and sand samples for three Bacteroides DNA markers. This report lists the results of those analyses, along with environmental conditions at Villa Angela on the dates that samples were collected.

Open-File Report↗

Statistical properties of dune profiles

Properties of sand waves formed by subcritical unidirectional water currents are investigated by statistical analyses of records of streambed profiles. Records of bed elevation y as a function of distance x along the channel, y = y(x), and time records at a fixed point of the channel, y = y(t), were collected in three laboratory flumes that were 8 inches, 2 ft and 8 ft wide and in a straight alluvial channel that was 55 ft wide. For all cases, the bed material was fine sand. The continuous analogue records were converted to discrete data points and were analyzed by digital computer. The analyses show that both types of records, y(x) and y(t), can be approximately represented as stationary Gaussian processes. When the data are standardized and the length or distance are expressed as ratios of the mean duration between zero-crossings of y, the statistical properties of all the flume data are similar, with no distinguishing characteristics that can be attributed to size of flume or to whether the bed forms were ripples or dunes. The field data, however, reflect the influence of large alternate bars that were not present in the flumes. The Gaussian assumption, together with the spectral properties of the records as expressed by a dimensionless parameter, 6, permit predicting the distributions of maximum and minimum values of y between successive zeros of y. These distributions represent the probability distributions of the depth of local scour and fill due to the formation and migration of sand waves, and the parameters that specify the distributions relate approximately to flow velocity and depth. Observed values of the number of zero and h-level crossings, the mean duration between zero crossings, and the mean duration of upward excursions of the process y(t) above the fixed level h compared reasonably well with theoretical values for the Gaussian model. The distribution of the duration of upward excursions is the conditional probability distribution of the rest period of a particle, given that it is deposited on the downstream face of a ripple or dune at the level h. Observed distributions of these durations can be approximated by a gamma distribution with parameters that relate to h, where h is measured in units of standard deviation from the mean bed level. These distributions and other probability distributions that enter into stochastic models of sediment transport can be determined either from the theoretical model or empirically from the observed data. The results of the study ,-show that even though the bed elevation deviates somewhat from the postulated normal distribution, reasonable estimates of many properties of the bed profiles can be derived from fairly simple statistical models.

Open-File Report↗

New Mexico district work-effort analysis computer program

The computer program (CAN 2) described in this report is one of several related programs used in the New Mexico District cost-analysis system. The work-effort information used in these programs is accumulated and entered to the nearest hour on forms completed by each employee. Tabulating cards are punched directly from these forms after visual examinations for errors are made. Reports containing detailed work-effort data itemized by employee within each project and account and by account and project for each employee are prepared for both current-month and year-to-date periods by the CAN 2 computer program. An option allowing preparation of reports for a specified 3-month period is provided. The total number of hours worked on each account and project and a grand total of hours worked in the New Mexico District is computed and presented in a summary report for each period. Work effort not chargeable directly to individual projects or accounts is considered as overhead and can be apportioned to the individual accounts and projects on the basis of the ratio of the total hours of work effort for the individual accounts or projects to the total New Mexico District work effort at the option of the user. The hours of work performed by a particular section, such as General Investigations or Surface Water, are prorated and charged to the projects or accounts within the particular section. A number of surveillance or buffer accounts are employed to account for the hours worked on special events or on those parts of large projects or accounts that require a more detailed analysis. Any part of the New Mexico District operation can be separated and analyzed in detail by establishing an appropriate buffer account. With the exception of statements associated with word size, the computer program is written in FORTRAN IV in a relatively low and standard language level to facilitate its use on different digital computers. The program has been run only on a Control Data Corporation 6600 computer system. Central processing computer time has seldom exceeded 5 minutes on the longest year-to-date runs.

Open-File Report↗

Basin characteristics, history of stream gaging, and statistical summary of selected streamflow records for the Rapid Creek basin, western South Dakota

The report presents a summary of basin characteristics affecting streamflow, a history of the U.S. Geological Survey 's stream-gaging program, and a compilation of discharge records and statistical summaries for selected sites within the Rapid Creek basin. It is the first in a series which will investigate surface-water/groundwater relations along Rapid Creek. The summary of basin characteristics includes descriptions of the geology and hydrogeology, physiography and climate, land use and vegetation, reservoirs, and water use within the basin. A recounting of the U.S. Geological Survey 's stream-gaging program and a tabulation of historic stream-gaging stations within the basin are furnished. A compilation of monthly and annual mean discharge values for nine currently operated, long-term, continuous-record, streamflow-gaging stations on Rapid Creek is presented. The statistical summary for each site includes summary statistics on monthly and annual mean values, correlation matrix for monthly values, serial correlation for 1 year lag for monthly values, percentile rankings for monthly and annual mean values, low and high value tables, duration curves, and peak-discharge tables. Records of monthend contents for two reservoirs within the basin also are presented. (USGS)

Open-File Report↗

Geohydrology and potential for upward movement of saline water in the Cocoa well field, East Orange County, Florida

The Floridan aquifer system, an approximately 2,000-foot thick sequence of Eocene-age limestone and dolomite, is the main source of water supply in central Florida. Hydraulic conductivity is different in strata of different lithology and is the basis for separating the aquifer system into the Upper Floridan aquifer, a middle semi-confining unit, and the Lower Floridan aquifer. The coastal city of Cocoa withdraws about 26 million gallons of water per day from the Upper Floridan aquifer from a well field in east Orange County, about 25 miles inland. About 60 million gallons per day are withdrawn from the Upper Floridan aquifer and 56 million gallons per day from the Lower Floridan aquifer in the Orlando area, about 15 miles west of the Cocoa well field. Wells drilled in the Cocoa well field from 1955-61 yielded water with chloride concentrations ranging from 25-55 milligrams per liter. Soon after the wells were put in service, chloride concentrations increased; therefore, new wells were drilled further inland. Chloride concentrations in water from many of the new wells also have increased. Possible sources of saline water are lateral movement of relict seawater in the Upper Floridan aquifer from the east, regional upconing of saline water from the Lower Floridan aquifer or underlying older rocks, or localized upward movement of saline water through fractures. Several test wells were drilled to provide information about chloride concentration changes with depth and to monitor changes with time, including a multi-zone well drilled in 1965 (well C) and two wells drilled in the 1990's (wells R and S). Chloride concentrations have increased in the zone pumped by the supply wells (the upper 500 feet of the aquifer) and in the 1,351 to 1,357-foot deep zone of well C, but not in the two intervening zones. This indicates that the source of saline water is located laterally, rather than vertically, from the pumped zone in the area of well C. The potential for upward movement of saline water depends on the direction of the vertical hydraulic gradient and on the vertical hydraulic conductivity of the aquifer. A series of aquifer tests was run in 1993-94 and existing water-level and water-quality data were analyzed to evaluate the potential for upward movement of saline water in the well field. The transmissivity of the upper 500 feet of the aquifer is about 100,000 feet squared per day (the horizontal hydraulic conductivity is about 200 feet per day) and the storage coefficient is about 2x10-4. Horizontal hydraulic conductivities determined from slug tests of the three deepest zones of well C ranged from 20-50 feet per day. Vertical hydraulic conductivities probably do not exceed 0.05 feet per day. The vertical hydraulic gradient is determined by comparing water levels in the various zones, but because of density differences, unadjusted water levels in the deepest zone investigated cannot be directly compared to water levels in the overlying freshwater zones. The difference between environmental-water heads (adjusted for density differences) in the saline-water zone of well C and the overlying freshwater zone were calculated from measured water levels for the period 1966 to 1994. During most of this time period, the gradient was downward, indicating that saline water did not move upward. Upconing of saline water probably is not taking place in the center and western part of the well field, based on the low vertical hydraulic conductivity values estimated for the middle semi-confining unit, the generally downward vertical hydraulic gradient, and the constant chloride concentrations in the intermediate zones of well C. However, there is no information about the extent of the zone of low vertical hydraulic conductivity or about the direction of the vertical hydraulic gradient in the eastern part of the well field. Thus, increased chloride concentrations in supply wells in the eastern part of the well field could be caused either by lateral movement of saline water from the east, or by upward movement from the Lower Floridan aquifer if the low conductivity zone is thin or breached by fractures, or by a combination of both lateral and vertical movement.

Florida↗

Report of hydrologic investigations in the Three Sisters area of central Oregon, Summer 2001

An ongoing episode of crustal uplift centered in the Separation Creek drainage of the Three Sisters area, central Oregon Cascades, may result from a magmatic intrusion that began in 1998. An investigation of springs in this drainage in summer 2001 revealed slightly elevated water temperatures and chloride (Cl-) concentrations of up to about 5?C and 20 milligrams per liter (mg/L), respectively, above background. The total discharge of anomalous Cl- in Separation Creek was 9.2 grams per second, which in combination with the temperature-Cl- relation in the springs results in a total advective heat discharge of 16 MW (megawatts). Comparison with similar findings obtained a decade earlier suggests that total Cl- and heat discharges in the groundwater drainage are unaffected by the current uplift. However, the isotopic composition of the dissolved inorganic carbon (DIC) in the spring waters (delta carbon-13 (13C) = -9.03 to -11.6?; carbon-14 (14C) <25 pmC) combined with helium-3/helium-4 (3He/4He) ratios near 8 RA and C/3He ratios <1010 in two of the springs are indicative of a magmatic source. The high 3He/4He ratios indicate that the magmatic gas is derived from a relatively recent, if not ongoing, intrusion. The concentration of magmatic carbon is low, a few millimoles per liter (mmol/L) at most, with an average value of 1.53 mmol/L for all the springs sampled in the drainage. Combining this average with the late-summer water flow in Separation Creek suggests a discharge of 21 tonnes/day of magmatic carbon dioxide (CO2). The presence of magmatic carbon in the shallow groundwater system, and the fact that DIC is uncorrelated with Cl-, suggests that some magmatic gas could escape diffusely through the soils.

Water-Resources Investigations Report↗

Effects of agricultural best-management practices on the Brush Run Creek headwaters, Adams County, Pennsylvania, prior to and during nutrient management

The U.S. Geological Survey, in cooperation with the Susquehanna River Basin Commission and the Pennsylvania Department of Environmental Resources, investigated the effects of agricultural best-management practices on surface-water quality as part of the U.S. Environmental Protection Agency's Chesapeake Bay Program. This report characterizes a 0.63-square- mile agricultural watershed underlain by shale, mudstone, and red arkosic sandstone in the Lower Susquehanna River Basin. The water quality of the Brush Run Creek site was studied from October 1985 through September 1991, prior to and during the implementation of nutrient management designed to reduce sediment and nutrient discharges into Conewago Creek, a tributary to the Chesapeake Bay. The original study area was 0.38 square mile and included an area immediately upstream from a manure lagoon. The study area was increased to 0.63 square mile in the fall of 1987 after an extensive tile-drain network was discovered upstream and downstream from the established streamflow gage, and the farm owner made plans to spray irrigate manure to the downstream fields. Land use for about 64 percent of the 0.63 square mile watershed is cropland, 14 percent is pasture, 7 percent is forest, and the remaining 15 percent is yards, buildings, water, or gardens. About 73 percent of the cropland was used to produce corn during the study. The average annual animal population consisted of 57,000 chickens, 1,530 hogs, and 15 sheep during the study. About 59,340 pounds of nitrogen and 13,710 pounds of phosphorus were applied as manure and commercial fertilizer to fields within the subbasin during the 3-year period prior to implementation of nutrient management. During nutrient management, about 14 percent less nitrogen and 57 percent less phosphorus were applied as commercial and manure fertilizer. Precipitation totaled 209 inches, or 13 percent less than the long-term normal, during the 6-year study. Concentrations of total ammonia in precipitation were as high as 2.7 mg/L (milligrams per liter); in dry deposition the concentrations were as high as 5.4 mg/L, probably because of the ammonia that had volatilized from the manure-storage lagoon. Nitrate nitrogen in the upper 4 feet of the soil ranged from 17 to 452 pounds per acre and soluble phosphorus content ranged from 0.29 to 65 pounds per acre. The maximum concentration of total nitrogen was 2,400 mg/L on September 10, 1986, in discharge from the tile drain near the streamflow gage. Median concentrations of total nitrogen and dissolved nitrite plus nitrate in base flow at the water-quality gage were 14 mg/L and 4.4 mg/L, respectively; prior to nutrient management and during nutrient management, median concentrations were 14 mg/L and 6.2 mg/L, respectively. Significant reductions in total phosphorus and suspended-sediment concentrations occurred at the water-quality gage. The maximum concentrations of total phosphorus (160 mg/L) and suspended sediment (3,530 mg/L) were measured at a tile line above the water-quality gage. Concentrations of total nitrogen, dissolved ammonia, and total phosphorus in base flow increased during dry periods when discharges from the tile drain were not diluted. During nutrient management, only base-flow loads of suspended sediment increased. Total streamflow was about 121.8 inches. About 81 percent was storm runoff. Loads of total nitrogen, total phosphorus in stormflow, and suspended sediment increased 14, 44, and 41 percent during nutrient management, respectively. A load of about 787,780 pounds of sediment, 22,418 pounds of nitrogen, and 5,479 pounds of phosphorus was measured during 214 sampled stormflow days that represented 84 percent of the stormflow. About 812,924 pounds of sediment, 38,421 pounds of nitrogen, and 6,377 pounds of phosphorus were discharged during the 6-year study.

Pennsylvania↗

Potential effects of recurrent low oxygen conditions on the Illinois Cave amphipod

The caves of Illinois' sinkhole plain are the sole habitat of the Illinois Cave amphipod (Gammarus acherondytes), a federally endangered species. The sinkhole plain is a hydrologically-connected sequence of karstified limestone that constitutes an extensive karst aquifer which serves as an important source of potable water for area residents. During this investigation, we examined the ground-water quality in caves within two ground-water basins: 1) Illinois Caverns, where the amphipod is now present after previously reported to have been extirpated from the lower reaches, and 2) Stemler Cave, where the amphipod is reported to have been extirpated. The chemical composition of cave streams in Illinois Caverns and Stemler Cave were compared to determine which parameters, if any, could have contributed to the loss of G. acherondytes from Stemler Cave. Stream water in Stemler Cave contained higher concentrations of organic carbon, potassium, silica, chloride, fluoride, sulfate, iron and manganese than Illinois Caverns. Perhaps most importantly, dissolved oxygen (DO) concentrations in Stemler Cave were, during periods of low flow, substantially lower than in Illinois Caverns. Based on land use, there are probably at least eight times more private septic systems in the Stemler Cave ground-water basin than in the Illinois Caverns ground-water basin. Low DO concentrations were likely the result of microbial breakdown of soil organic matter and wastewater treatment system effluent, and the oxidation of pyrite in bedrock. The near-hypoxic DO in Stemler Cave that occurred during low-flow conditions, and, we speculate, a limited range of G. acherondytes within the Stemler Cave ground-water basin due to a metabolic advantage of the stygophilic aquatic invertebrates over the stygobitic G. acherodytes, resulted in the apparent loss of G. acherondytes from Stemler Cave.

Journal of Cave and Karst Studies↗

An integrated feasibility study of reservoir thermal energy storage in Portland, Oregon, USA

In regions with long cold overcast winters and sunny summers, Deep Direct-Use (DDU) can be coupled with Reservoir Thermal Energy Storage (RTES) technology to take advantage of pre-existing subsurface permeability to save summer heat for later use during cold seasons. Many aquifers worldwide are underlain by permeable regions (reservoirs) containing brackish or saline groundwater that has limited beneficial use due to poor water quality. We investigate the utility of these relatively deep, slow flowing reservoirs for RTES by conducting an integrated feasibility study in the Portland Basin, Oregon, USA, developing methods and obtaining results that can be widely applied to groundwater systems elsewhere. As a case study, we have conducted an economic and social cost-benefit analysis for the Oregon Health and Science University (OHSU), a teaching hospital that is recognized as critical infrastructure in the Portland Metropolitan Area. Our investigation covers key factors that influence feasibility including 1) the geologic framework, 2) heat and fluid flow modeling, 3) capital and maintenance costs, 4) the regulatory framework, and 5) operational risks. By pairing a model of building seasonal heat demand with an integrated model of RTES resource supply, we determine that the most important factors that influence RTES efficacy in the study area are operational schedule, well spacing, the amount of summer heat stored (in our model, a function of solar array size), and longevity of the system. Generally, heat recovery efficiency increases as the reservoir and surrounding rocks warm, making RTES more economical with time. Selecting a base-case scenario, we estimate a levelized cost of heat (LCOH) to compare with other sources of heating available to OHSU and find that it is comparable to unsubsidized solar and nuclear, but more expensive than natural gas. Additional benefits of RTES include energy resiliency in the event that conventional energy supplies are disrupted (e.g., natural disaster) and a reduction in fossil fuel consumption resulting in a smaller carbon footprint. Key risks include reservoir heterogeneity and a possible reduction in permeability through time due to scaling (mineral precipitation). Lastly, a map of thermal energy storage capacity for the Portland Basin yields a total of 87,000 GWh, suggesting tremendous potential for RTES in the Portland Metropolitan Area.

Oregon↗

Environmental setting of the Yellowstone River basin, Montana, North Dakota, and Wyoming

Natural and anthropogenic factors influence water-quality conditions in the Yellowstone River Basin. Physiography parallels the structural geologic setting that is generally composed of several uplifts and structural basins. Contrasts in climate and vegetation reflect topographic controls and the midcontinental location of the study unit. Surface-water hydrology reflects water surpluses in mountainous areas that are dominated by snowmelt runoff, and arid to semiarid conditions in the plains that are dissected by typically irrigated valleys in the remainder of the study unit. Principal shallow aquifers are Tertiary sandstones and unconsolidated Quaternary deposits. Human population, though sparsely distributed in general, is growing most rapidly in a few urban centers and resort areas, mostly in the northwestern part of the basin. Land use is areally dominated by grazing in the basins and plains and economically dominated by mineral-extraction activities. Forests are the dominant land cover in mountainous areas. Cropland is a major land use in principal stream valleys. Water use is dominated by irrigated agriculture overall, but mining and public-supply facilities are major users of ground water. Coal and hydrocarbon production and reserves distinguish the Yellowstone River Basin as a principal energy-minerals resources region. Current metallic ore production or reserves are nationally significant for platinum-group elements and chromium. The study unit was subdivided as an initial environmental stratification for use in designing the National Water-Quality Assessment Program investigation that began in 1997. Ecoregions, geologic groups, mineral-resource areas, and general land-cover and land-use categories were used in combination to define 18 environmental settings in the Yellowstone River Basin. It is expected that these different settings will be reflected in differing water-quality or aquatic-ecological characteristics.

Montana, North Dakota, Wyoming↗

Hydrogeology and water quality of the Pepacton Reservoir Watershed in southeastern New York. Part 4. Quantity and quality of ground-water and tributary contributions to stream base flow in selected main-valley reaches

Estimates of the quantity and quality of ground-water discharge from valley-fill deposits were calculated for nine valley reaches within the Pepacton watershed in southeastern New York in July and August of 2001. Streamflow and water quality at the upstream and downstream end of each reach and at intervening tributaries were measured under base-flow conditions and used in mass-balance equations to determine quantity and quality of ground-water discharge. These measurements and estimates define the relative magnitudes of upland (tributary inflow) and valley-fill (ground-water discharge) contributions to the main-valley streams and provide a basis for understanding the effects of hydrogeologic setting on these contributions. Estimates of the water-quality of ground-water discharge also provide an indication of the effects of road salt, manure, and human wastewater from villages on the water quality of streams that feed the Pepacton Reservoir. The most common contaminant in ground-water discharge was chloride from road salt; concentrations were less than 15 mg/L. Investigation of ground-water quality within a large watershed by measurement of stream base-flow quantity and quality followed by mass-balance calculations has benefits and drawbacks in comparison to direct ground-water sampling from wells. First, sampling streams is far less expensive than siting, installing, and sampling a watershed-wide network of wells. Second, base-flow samples represent composite samples of ground-water discharge from the most active part of the ground-water flow system across a drainage area, whereas a well network would only be representative of discrete points within local ground-water flow systems. Drawbacks to this method include limited reach selection because of unfavorable or unrepresentative hydrologic conditions, potential errors associated with a large number of streamflow and water-quality measurements, and limited ability to estimate concentrations of nonconservative constituents such as nutrients. The total gain in streamflow from the upper end to the lower end of each valley reach was positively correlated with the annual-runoff volume calculated for the drainage area of the reach. This correlation was not greatly affected by the proportions of ground-water and tributary contributions, except at two reaches that lost much of their tributary flow after the July survey. In these reaches, the gain in total streamflow showed a negative departure from this correlation. Calculated ground-water discharge exceeded the total tributary inflow in each valley reach in both surveys. Groundwater discharge, as a percentage of streamflow gain, was greatest among reaches in wide valleys (about 1,000-ft wide valley floors) that contain permeable valley fill because tributary flows were seasonally diminished or absent as a result of streambed infiltration. Tributary inflows, as a percentage of streamflow gain, were highest in reaches of narrow valleys (200-500-ft wide valley floors) with little valley fill and high annual runoff. Stream-water and ground-water quality were characterized by major-ion type as either (1) naturally occurring water types, relatively unaffected by road salt, or (2) road-salt-affected water types having elevated concentrations of chloride and sodium. The naturally occurring waters were typically the calcium-bicarbonate type, but some contained magnesium and (or) sulfate as secondary ions. Magnesium concentration in base flow is probably related to the amount of till and its carbonate content, or to the amount of lime used on cultivated fields within a drainage area. Sulfate was a defining ion only in dilute waters (with short or unreactive flow paths) with low concentrations of bicarbonate. Nearly all tributary waters were classified as naturally occurring water types. Ground-water discharge from nearly all valley reaches that contain State or county highways had elevated concentrations of chloride and sodsodium. The mean chloride concentrations of ground-water discharge--from 8 to 13 milligrams per liter--did not exceed Federal or State standards, but were about 5 times higher than naturally occurring levels. Application of road salt along a valley bottom probably affects only the shallow ground water in the area between a road and a stream. The elevated concentrations of chloride and sodium in the base-flow samples from such reaches indicate that the concentrations in the affected ground water were high enough to offset the low concentrations in all unaffected ground water entering the reach. Nutrient (nitrate and orthophosphate) concentrations in base-flow samples collected throughout the valleyreach network could not generally be used to estimate their concentrations in ground-water discharge because these constituents can be transformed or removed from water through biological uptake, transformation, or by adsorption on sediments. Base-flow samples from streams with upgradient manure sources or villages served by septic systems consistently had the highest concentrations of these nutrients.

Scientific Investigations Report↗

Part II—Geophysical investigations in the Hawaiian Islands

During 1938 and 1939, an extensive series of geophysical surveys, employing both resistivity and magnetic methods, have been carried on in the Hawaiian Islands by the Section of Geophysics of the United States Geological Survey in cooperation with the Division of Ground‐Water of the Survey and the Division of Hydrography of the Territorial Government (see Fig. 1). During this time, surveys have been conducted on the islands of Oahu, Molokai, and Maul. Two distinct types of ground‐water occurrence are being investigated: (1) The basal fresh‐water lens floating on underlying salt water in obedience to the Ghyben‐Herzberg principle (Fig. 2); and (2) perched ground‐water (Fig. 3) .

Hawaii↗

Seasonal seepage investigation on an urbanized reach of the lower Boise River, southwestern Idaho, water year 2010

The U.S. Geological Survey in cooperation with the Idaho Department of Water Resources Treasure Valley Comprehensive Aquifer Management Planning effort investigated seasonal groundwater gains and losses on the Boise River, Idaho, starting in November 2009 through August 2010. The investigation was conducted using seepage runs in 11 subreaches over a 14-mile reach from downstream of the inactive streamgage, Boise River below Diversion Dam (U.S. Geological Survey station No. 13203510) to the active Boise River at Glenwood Bridge streamgage (U.S. Geological Survey station No. 13206000). The seepage runs measured mainstem discharge, and significant tributary contributions and diversions along the reach. In addition, an evaluation of the groundwater hydraulic gradient was simultaneously conducted through shallow groundwater mini-piezometers adjacent to the river during February (low stream discharge) and May (high stream discharge) measurement timeframes. November discharge estimates, representative of autumn, had gains and losses that varied by subreach with an overall net gain of 42 &plusmn; 8 cubic feet per second (ft 3 /s). This finding compares favorably to a previous U.S. Geological Survey seepage investigation in November 1996 that found a gaining reach with an estimated gain of 52 ft 3 /s. This finding also is supported by a U.S. Geological Survey investigation in the study reach in November 1971 that estimated a gain of 74 ft 3 /s, which largely came from groundwater. The February discharge estimates, representative of winter conditions, showed variability in the reach with a net gain of 52 ft 3 /s with an uncertainty estimate of &plusmn; 7 ft 3 /s, which is consistent with the low stream discharge findings from November 2009. This finding is further supported by the differential hydraulic head measured at transect sites that qualitatively indicated groundwater to surface-water movement with few exceptions. The May discharge estimates, representative of the spring-time conditions, were gaining or potentially gaining in all but one of the upper subreaches between Boise River below Diversion Dam and Boise River near MK Nature Center sites, with seepage run results supported by hydraulic head differentials indicating a groundwater to surface-water movement. The lower end of the study reach between Boise River near MK Nature Center and Boise River at Glenwood Bridge sites showed more variability with observed hydraulic head differentials that partially supported the potential gains or losses in the reach. Overall, the reach had a calculated net gain of 24 &plusmn; 51 ft 3 /s and, therefore, this estimate may or may not reflect the actual conditions in the reach. The groundwater gains and losses in August, representative of summer conditions, varied in both the upper and lower parts of the reach, with a net loss of -88 &plusmn; 69 ft 3 /s. Overall, the reach experienced a net gain from groundwater at low stream discharges (November and February), a net loss to groundwater at moderately high stream discharge (August), and an ambiguous finding at a higher stream discharge (May). The hydraulic head differentials measured between the groundwater and surface water largely supported the calculated gain and loss estimates in the subreaches, with a potential for groundwater to surface-water movement at low stream discharge in February, and variability during high stream discharge conditions in May.

Scientific Investigations Report↗

Production waters associated with the Ferron coalbed methane fields, central Utah: Chemical and isotopic composition and volumes

This study investigated the composition of water co-produced with coalbed methane (CBM) from the Upper Cretaceous Ferron Sandstone Member of the Mancos Shale in east-central Utah to better understand coalbed methane reservoirs. The Ferron coalbed methane play currently has more than 600 wells producing an average of 240 bbl/day/well water. Water samples collected from 28 wellheads in three fields (Buzzards Bench, Drunkards Wash, and Helper State) of the northeast-southwest trending play were analyzed for chemical and stable isotopic composition.Water produced from coalbed methane wells is a Na-Cl-HCO3 type. Water from the Drunkards Wash field has the lowest total dissolved solids (TDS) (6300 mg/l) increasing in value to the southeast and northeast. In the Helper State field, about 6 miles northeast, water has the highest total dissolved solids (43,000 mg/l), and major ion abundance indicates the possible influence of evaporite dissolution or mixing with a saline brine. In the southern Buzzards Bench field, water has variable total dissolved solids that are not correlated with depth or spatial distance. Significant differences in the relative compositions are present between the three fields implying varying origins of solutes and/or different water-rock interactions along multiple flow paths.Stable isotopic values of water from the Ferron range from +0.9??? to -11.4??? ?? 18O and -32??? to -90??? ?? 2H and plot below the global meteoric water line (GMWL) on a line near, but above values of present-day meteoric water. Isotopic values of Ferron water are consistent with modification of meteoric water along a flow path by mixing with an evolved seawater brine and/or interaction with carbonate minerals. Analysis of isotopic values versus chloride (conservative element) and total dissolved solids concentrations indicates that recharge water in the Buzzards Bench area is distinct from recharge water in Drunkards Wash and is about 3 ??C warmer. These variations in isotopes along with compositional variations imply that the Ferron reservoir is heterogeneous and compartmentalized, and that multiple flow paths may exist. ?? 2003 Published by Elsevier B.V. All rights reserved.

International Journal of Coal Geology↗