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Distribution and transport of trace substances in the Schuylkill River basin from Berne to Philadelphia, Pennsylvania

During the period from October 1978 to March 1981, the U.S. Geological Survey assessed the river quality of the Schuylkill River basin in Pennsylvania from the headwaters to the Fairmount Dam at Philadelphia (river mile 8.4). The assessment focused on the distribution and transport of trace metals and organic substances (trace substances). Trace metals included were arsenic, beryllium, cadmium, copper, lead, mercury, nickel, and zinc; trace organic substances included organochlorine insecticides and polychlorinated biphenyls. In general, concentrations of trace substances in the streambed sediments were greater in the main stem of the Schuylkill River than in its tributaries and exceeded the background concentrations in the study area. Concentrations of most trace metals in the sediments were lowest in the Berne area (river mile 95) and highest in the urban-industrial area of Reading (river mile 76). Concentrations generally decreased from Reading downstream to Philadelphia (river mile 10.2). Concentrations of the organochlorine insecticides chlordane, DDT and its metabolites, and dieldrin generally increased gradually from Berne to Philadelphia. Average concentrations of trace metals in the main stem of the Schuylkill River in the sediment-sized fraction, less than 0.063 millimeters, were: zinc, 603 ?g/g (micrograms per gram); lead, 284 ?g/g; copper, 252 ?g/g; nickel, 119 ?g/g; chromium, 96 ?g/g; beryllium, 8.2 ?g/g; arsenic, 0.64 ?g/g; and mercury, 0.002 ?g/g. Average concentrations of trace organic substances in sediments of the main stem of the river were: polychlorinated biphenyls, 152 ?g/kg (micrograms per kilogram); chlordane, 24 ?g/kg; DDT and its metabolites, 18 ?g/kg; and dieldrin, 1.8 ?g/kg. The average annual transport of trace substances by the river was computed for chromium, copper, lead, nickel, and zinc. Concentrations of other trace substances in the sediment-water mixtures were generally undetectable. Of the trace metals, average annual transport of zinc was the greatest, and that of nickel was the least. Transport of trace metals in the river is closely associated with and related to suspended-sediment transport. About 71 percent of the average annual total metal transport is particulate material. Yields, in tons per square mile per year, of copper, lead, zinc, and total organic carbon in the Schuylkill River basin were compared with yields in the Chattahoochee River basin (Georgia). The comparison indicates that yields, by constituent, were of the same order of magnitude. Both basins lie in the Piedmont province, and both have about the same percentage of urban land use. The frequency of occurrence of concentrations of copper, lead, and zinc in the sediment-water mixture at Manayunk in Philadelphia were compared with domestic water-supply criteria of the U.S. Environmental Protection Agency. The criteria are exceeded less than 1 percent of the time, or about 4 days per year.

Schuylkill River basin↗

Effect of spatial resolution of satellite images on estimating the greenness and evapotranspiration of urban green spaces

Urban green spaces (UGS), like most managed land covers, are getting progressively affected by water scarcity and drought. Preserving, restoring and expanding UGS require sustainable management of green and blue water resources to fulfil evapotranspiration (ET) demand for green plant cover. The heterogeneity of UGS with high variation in their microclimates and irrigation practices builds up the complexity of ET estimation. In oversized UGS, areas too large to be measured with in situ ET methods, remote sensing (RS) approaches of ET measurement have the potential to estimate the actual ET. Often in situ approaches are not feasible or too expensive. We studied the effects of spatial resolution using different satellite images, with high‐, medium‐ and coarse‐spatial resolutions, on the greenness and ET of UGS using Vegetation Indices (VIs) and VI‐based ET, over a 780‐ha urban park in Adelaide, Australia. We validated ET with the ground‐based ET method of Soil Water Balance. Three sets of imagery from WorldView2, Landsat and MODIS, and three VIs including the Normalized Difference Vegetation Index (NDVI), Enhanced Vegetation Index (EVI) and Enhanced Vegetation Index 2 (EVI2), were used to assess long‐term changes of VIs and ET calculated from the different imagery acquired for this study (2011–2018). We found high correspondence between ET‐MODIS and ET‐Landsat (R2 > 0.99 for all VIs). Landsat‐VIs captured the seasonal changes of greenness better than MODIS‐VIs. We used artificial neural network (ANN) to relate the RS‐ET and ground data, and ET‐MODIS (EVI2) showed the highest correlation (R2 = 0.95 and MSE =0.01 for validation). We found a strong relationship between RS‐ET and in situ measurements, even though it was not explicable by simple regressions; black box models helped us to explore their correlation. The methodology used in this research makes a strong case for the value of remote sensing in estimating and managing ET of green spaces in water‐limited cities.

Adelaide↗

Level II scour analysis for Bridge 7H (HUNTTH0001007H) on Town Highway 1, crossing Cobb Brook, Huntington, Vermont

This report provides the results of a detailed Level II analysis of scour potential at structure HUNTTH001007H on Town Highway 1 crossing the Cobb Brook, Huntington, Vermont (figures 1–10). A Level II study is a basic engineering analysis of the site, including a quantitative analysis of stream stability and scour (U.S. Department of Transportation, 1993). Results of a Level I scour investigation also are included in Appendix E of this report. A Level I investigation provides a qualitative geomorphic characterization of the study site. Information on the bridge, gleaned from Vermont Agency of Transportation (VTAOT) files, was compiled prior to conducting Level I and Level II analyses and is found in Appendix D. In August 1976, Hurricane Belle caused flooding at this site which resulted in road and bridge damage (figures 7-8). This was approximately a 25-year flood event (U.S. Department of Housing and Urban Development, 1978). The site is in the Green Mountain section of the New England physiographic province in central Vermont. The 4.20-mi 2 drainage area is in a predominantly rural and forested basin. In the vicinity of the study site, the surface cover is forest upstream of the bridge. Downstream of the bridge is brushland and pasture. In the study area, the Cobb Brook has an incised, straight channel with a slope of approximately 0.03 ft/ft, an average channel top width of 43 ft and an average bank height of 6 ft. The channel bed material ranges from sand to boulders with a median grain size (D 50 ) of 65.5 mm (0.215 ft). The geomorphic assessment at the time of the Level I and Level II site visit on June 24, 1996, indicated that the reach was stable. The Town Highway 1 crossing of the Cobb Brook is a 23-ft-long, two-lane bridge consisting of one 20-foot concrete slab span (Vermont Agency of Transportation, written communication, June 21, 1996). The bridge is supported by vertical, concrete abutments with wingwalls. The channel is skewed approximately 15 degrees to the opening while the opening-skew-to-roadway is zero degrees. A scour hole 2.8 ft deeper than the mean thalweg depth was observed along the left abutment during the Level I assessment. Protection measures at the site include type-1 stone fill (less than 12 inches diameter) at the downstream right wingwall, type-2 stone fill (less than 36 inches diameter) at the upstream right wingwall and the downstream end of the downstream left wingwall, and type-3 stone fill (less than 48 inches diameter) at the upstream left wingwall. Additional details describing conditions at the site are included in the Level II Summary and Appendices D and E. Scour depths and recommended rock rip-rap sizes were computed using the general guidelines described in Hydraulic Engineering Circular 18 (Richardson and others, 1995). Total scour at a highway crossing is comprised of three components: 1) long-term streambed degradation; 2) contraction scour (due to accelerated flow caused by a reduction in flow area at a bridge) and; 3) local scour (caused by accelerated flow around piers and abutments). Total scour is the sum of the three components. Equations are available to compute depths for contraction and local scour and a summary of the results of these computations follows. Contraction scour for all modelled flows ranged from 0.2 to 1.3 ft. The worst-case contraction scour occurred at the incipient-overtopping discharge. Abutment scour ranged from 4.0 to 8.7 ft. The worst-case abutment scour occurred at the 500-year discharge. Additional information on scour depths and depths to armoring are included in the section titled “Scour Results”. Scoured-streambed elevations, based on the calculated scour depths, are presented in tables 1 and 2. A cross-section of the scour computed at the bridge is presented in figure 10. Scour depths were calculated assuming an infinite depth of erosive material and a homogeneous particle-size distribution. It is generally accepted that the Froehlich equation (abutment scour) gives “excessively conservative estimates of scour depths” (Richardson and others, 1995, p. 47). Usually, computed scour depths are evaluated in combination with other information including (but not limited to) historical performance during flood events, the geomorphic stability assessment, existing scour protection measures, and the results of the hydraulic analyses. Therefore, scour depths adopted by VTAOT may differ from the computed values documented herein.

Vermont↗

Comparing forest fragmentation and its drivers in China and the USA with Globcover v2.2

Forest loss and fragmentation are of major concern to the international community, in large part because they impact so many important environmental processes. The main objective of this study was to assess the differences in forest fragmentation patterns and drivers between China and the conterminous United States (USA). Using the latest 300-m resolution global land cover product, Globcover v2.2, a comparative analysis of forest fragmentation patterns and drivers was made. The fragmentation patterns were characterized by using a forest fragmentation model built on the sliding window analysis technique in association with landscape indices. Results showed that China’s forests were substantially more fragmented than those of the USA. This was evidenced by a large difference in the amount of interior forest area share, with China having 48% interior forest versus the 66% for the USA. China’s forest fragmentation was primarily attributed to anthropogenic disturbances, driven particularly by agricultural expansion from an increasing and large population, as well as poor forest management practices. In contrast, USA forests were principally fragmented by natural land cover types. However, USA urban sprawl contributed more to forest fragmentation than in China. This is closely tied to the USA’s economy, lifestyle and institutional processes. Fragmentation maps were generated from this study, which provide valuable insights and implications regarding habitat planning for rare and endangered species. Such maps enable development of strategic plans for sustainable forest management by identifying areas with high amounts of human-induced fragmentation, which improve risk assessments and enable better targeting for protection and remediation efforts. Because forest fragmentation is a long-term, complex process that is highly related to political, institutional, economic and philosophical arenas, both nations need to take effective and comprehensive measures to mitigate the negative effects of forest loss and fragmentation on the existing forest ecosystems.

Journal of Environmental Management↗

Microbial and dissolved organic carbon characterization of stormflow in the Santa Ana River at Imperial Highway, Southern California, 1999-2002

The Santa Ana River drains about 2,670 square miles of densely populated coastal southern California, near Los Angeles. Almost all the flow in the river, more than 200,000 acre-feet annually, is diverted to ponds where it infiltrates and recharges underlying aquifers pumped to supply water for more than 2 million people. Base flow in the river is almost entirely treated municipal wastewater discharged from upstream treatment plants and, in the past, stormflow was considered a source of high-quality water suitable for use as a source of ground-water recharge that would dilute poorer quality water recharged during base flow. Stormflow in the Santa Ana River at the Imperial Highway diversion contains total coliform bacteria concentrations as high as 3,400,000 colonies per 100 mL (milliliters). Fecal indicator bacteria concentrations, including fecal coliforms, Escherichia coli, and enterococci, were as high as 310,000, 84,000, and 102,000 colonies per 100 mL, respectively. Although concentrations were high owing to urban runoff during the first stormflow of the rainy season, the highest concentrations occurred during the recessional flows of the first stormflow of the rainy season after streamflow returned to pre-storm conditions. Molecular indicators of microbiological organisms in stormflow, including phospholipid fatty acid (PLFA) and genetic data, show that the diversity of the total microbial population decreases during stormflow while fecal indicator bacteria concentrations increase. This suggests that the source of the bacteria must be poorly diverse and dominated by only a few types of bacteria. Although direct runoff of fecal indicator bacteria from urban areas occurs, this process cannot explain the very high concentrations of fecal indicator bacteria in runoff from upstream parts of the basin characterized by urban, agricultural (including more than 300,000 head of dairy cattle), and other land uses. Although other explanations are possible, fecal indicator bacteria concentrations and molecular microbiological data indicate accumulation and extended survival of bacteria in streambed sediments, and subsequent mobilization of those sediments and associated bacteria during stormflow. Both PLFA and genetic data indicate that water from dairy-waste storage ponds was not present during sampled stormflows. This is consistent with the relatively dry conditions and the absence of large stormflows during the study. Dissolved organic carbon (DOC) concentrations in stormflow ranged from 3 to 15.3 mg/L. In general, concentrations increased during stormflow and were distributed across the stormflow hydrograph in a manner similar to that of fecal indicator bacteria. DOC concentrations typically remained high for several days after flow returned to pre-storm conditions. Ultraviolet absorbance, excitation emission spectroscopy, and sequential fractionation of DOC using XAD-8 and XAD-4 resins showed that the composition of DOC changed rapidly during stormflow. Hydrophobic and hydrophilic acids were the largest fraction of DOC composing between 27 and 45 percent and between 24 and 37 percent of the DOC, respectively. The fraction of DOC composed of hydrophobic acids decreased due to urban runoff and increased during the recession of the first stormflow of the rainy season; the hydrophilic-acid fraction generally decreased throughout the stormflow hydrograph; the transhydrophilic-acid fraction did not vary greatly during stormflow; and the hydrophobic-neutral fraction increased from low values in base flow to almost 30 percent of the DOC after more soluble and more mobile hydrophobic and hydrophilic acids were washed from urban areas. Comparison of ultraviolet absorbance data with data collected during previous studies shows that the optical properties and, presumably, the composition of the DOC were different in this study than DOC collected during wetter periods. Samples of shallow ground water collec

California↗

A landscape indicator approach to the identification and articulation of the consequences of land-cover change in the Mid-Atlantic Region, 1973-2001

Landscape indicators, derived from land-use and land-cover data, hydrology, nitrate deposition, and elevation data, were used by Jones and others (2001a) to calculate the ecological consequences of land-cover change. Nitrate loading and physical bird habitat were modeled from 1973 and 1992 land-cover and other spatial data for the Mid-Atlantic region. Utilizing the same methods, this study extends the analysis another decade with the use of the 2001 National Land Cover Dataset. Land-cover statistics and trends are calculated for three time periods: 1973-1992, 1992-2001 and 1973-2001. In addition, high-resolution aerial photographs (1 meter or better ground-sample distance) were acquired and analyzed for thirteen pairs of adjacent USGS 7.5 minute quadrangle maps in areas where distinct positive or negative changes to nitrogen loading and bird habitat were previously calculated. During the entire 30 year period, the data show that there was extensive loss of agriculture and forest area and a major increase in urban land-cover classes. However, the majority of the conversion of other classes to urban occurred during the 1992-2001 period. During the 1973-1992 period, there was only moderate increase in urban area, while there was an inverse relationship between agricultural change and forest change. In general, forest gain and agricultural loss was found in areas of improving landscape indicators, and forest loss and agricultural gain was found to occur in areas of declining indicators related to habitat and nitrogen loadings, which was generally confirmed by the aerial photographic analysis. In terms of the specific model results, bird habitat, which is mainly related to the extent of forest cover, declined overall with forest extent, but was also affected more in the decline of habitat quality. Nitrate loading, which is mainly related to agricultural land cover actually improved from 1992-2001, and in the overall study, mainly due to the conversion of agriculture to forests and urban. The high-resolution imagery analysis was significant in that it confirmed, at a very local level, the specific land-cover changes that were driving the landscape metrics and model results that were calculated from moderate resolution land-cover data and models. These were generally subtle changes in patch size of agriculture, forest, and urban areas, but had substantial effects on bird habitat and nitrogen loadings. This analysis of high-resolution imagery demonstrates and confirms the important ability of moderate-resolution land-cover data to capture significant landscape-level activity that is directly related to specific metrics of ecological significance. It also demonstrates consistent landscape-scale relationships between data derived from high-resolution, moderate-resolution and landscape-model sources. Finally, many of the areas of improvement and decline in bird habitat and nitrogen loadings appear to be potentially regional in nature and likely reflect some local trend in landscape activity. Although the use of ecoregions as sampling units has been criticized in recent years, these results show that basic changes in Level 1 land-cover categories, such as forest and agriculture, may still reflect ecoregional patterns and considerations at some scale of mapping and analysis. This is a potentially important area for future landscape-indicator research. This and other follow-on research opportunities are discussed.

Open-File Report↗

Pharmaceuticals, hormones, and other organic wastewater contaminants in U.S. streams

A recent study by the Toxic Substances Hydrology Program of the U.S. Geological Survey (USGS) shows that a broad range of chemicals found in residential, industrial, and agricultural wastewaters commonly occurs in mixtures at low concentrations downstream from areas of intense urbanization and animal production. The chemicals include human and veterinary drugs (including antibiotics), natural and synthetic hormones, detergent metabolites, plasticizers, insecticides, and fire retardants. One or more of these chemicals were found in 80 percent of the streams sampled. Half of the streams contained 7 or more of these chemicals, and about one-third of the streams contained 10 or more of these chemicals. This study is the first national-scale examination of these organic wastewater contaminants in streams and supports the USGS mission to assess the quantity and quality of the Nation's water resources. A more complete analysis of these and other emerging water-quality issues is ongoing.

Fact Sheet↗

Water quality in alluvial aquifers of the southern Rocky Mountains Physiographic Province, upper Colorado River basin, Colorado, 1997

Water-quality samples were collected in the summer of 1997 from 45 sites (43 wells and 2 springs) in selected alluvial aquifers throughout the Southern Rocky Mountains physiographic province of the Upper Colorado River Basin study unit as part of the U.S. Geological Survey National Water-Quality Assessment Program. The objective of this study was to assess the water-quality conditions in selected alluvial aquifers in the Southern Rocky Mountains physiographic province. Alluvial aquifers are productive aquifers in the Southern Rocky Mountains physiographic province and provide for easily developed wells. Water-quality samples were collected from areas where ground water is used predominantly for domestic or public water supply. Twenty-three of the 45 sites sampled were located in or near mining districts. No statistical differences were observed between the mining sites and sites not associated with mining activities for the majority of the constituents analyzed. Water samples were analyzed for major ions, nutrients, dissolved organic carbon, trace elements, radon-222, pesticides, volatile organic compounds, bacteria, and methylene blue active substances. In addition, field parameters consisting of water temperature, specific conductance, dissolved oxygen, pH, turbidity, and alkalinity were measured at all sites. Specific conductance for the ground-water sites ranged from 57 to 6,650 microsiemens per centimeter and had higher concentrations measured in areas such as the northwestern part of the study unit. Dissolved oxygen ranged from 0.1 to 6.0 mg/L (milligrams per liter) and had a median concentration of 2.9 mg/L. The pH field values ranged from 6.1 to 8.1; about 4 percent of the sites (2 of 45) had pH values outside the range of 6.5 to 8.5 and so did not meet the U.S. Environmental Protection Agency secondary maximum contaminant level standard for drinking water. About 5 percent (2 of 43) of the samples exceeded the U.S. Environmental Protection Agency recommended turbidity value of 5 nephelometric turbidity units; one of these samples was from a monitoring well. The U.S. Environmental Protection Agency secondary maximum contaminant levels for dissolved solids, sulfate, iron, and manganese were exceeded at some of the sites. Higher dissolved-solids concentrations were detected where sedimentary rocks are exposed, such as in the northwestern part of the Southern Rocky Mountains physiographic province. The dominant water compositions for the sites sampled are calcium, magnesium, and bicarbonate. However, sites in areas where sedimentary rocks are exposed and sites located in or near mining areas show more sulfate-dominated waters. Nutrient concentrations were less than the U.S. Environmental Protection Agency drinking-water standards. Only one site had a nitrate concentration greater than 3.0 mg/L, a level indicating possible influence from human activities. No significant differences among land-use/land-cover classifications (forest, rangeland, and urban) for drinking-water wells (42 sites) were identified for dissolved-solids, sulfate, nitrate, iron or manganese concentrations. Radon concentrations were higher in parts of the study unit where Precambrian rocks are exposed. All radon concentrations in ground water exceeded the previous U.S. Environmental Protection Agency proposed maximum contaminant level for drinking water, which has been withdrawn pending further review. Pesticide detections were at concentrations below the reporting limits and were too few to allow for comparison of the data. Eight volatile organic compounds were detected at six sites; all concentrations complied with U.S. Environmental Protection Agency drinking-water standards. Total coliform bacteria were detected at six sites, but no Escherichia coli ( E. coli ) was detected. Methylene blue active substances were detected at three sites at concentrations just above the reporting limit. Overall, the water quality in the Southern Rocky Mountains physiographic province is suitable for most uses, but natural and human factors affect the water quality.

Colorado↗

An integrated statistical and deterministic hydrologic model for analyzing trace organic contaminants in commercial and high-density residential stormwater runoff

Urbanization can dramatically alter stormwater, both the quantity and quality, by engendering larger peak flows and through the introduction of contaminants into runoff. The current study builds on previous research that developed relationships between a suite of nonpoint source contaminants, known as trace organic contaminants (TOrCs), and hydrologic measurements for a series of storms (one site had 15 storms and the other had 19 storms) in Madison, WI, by creating statistical and deterministic models. Correlations and regressions were calculated between TOrC loads and hydrologic measurements for a series of storms for both a commercial site and a high-density residential site. From the regressions, it became evident that loading responses to precipitation were not the same between the two land covers for some TOrCs, indicating varying load responses for TOrCs depending on land cover. The regressions were utilized in the Source Loading and Management Model for Windows (WinSLAMM), an event-based hydrologic and water-quality model, to demonstrate that it can be used to model novel contaminants. The regressions were also used to estimate mean annual loads of TOrCs from all commercial and high-density residential areas in Madison, WI, for the watersheds to which Madison discharges its stormwater. The mean annual loads varied between grams per year to tens of thousands of grams per year depending on the TOrC and watershed. This work will ultimately allow managers to simulate the presence of, establish total maximum daily loads for, and mitigate the loads of TOrCs through stormwater best management practices.

Wisconsin↗

Persistence of a declining anuran species across its distribution

Information on a species’ population dynamics, such as changes in abundance and distribution, can be used to identify declining populations and initiate conservation efforts and protections. For the Ornate Chorus Frog ( Pseudacris ornata ), anecdotal observations of local extirpation and population declines have been noted, but trends in its range-wide population status are generally unknown. We used 2227 verified records of Ornate Chorus Frog presence from across the species’ distribution, grouped into 407 populations, and a modified Cormack-Jolly-Seber survival analysis to estimate the probability that historical Ornate Chorus Frog populations persist in the year 2024. Our results suggested that > 36% of historical Ornate Chorus Frog populations are possibly extirpated (probability of persistence < 0.5) and that 33% of populations had a probability of persistence > 0.9. Many of these extant populations occurred in northwestern Florida, southeastern Alabama, and southern Georgia, USA. The probability of persistence was positively influenced by habitat suitability and mean winter precipitation and negatively influenced by urban imperviousness. Ornate Chorus Frogs in protected areas had a higher average probability of persistence compared to populations that were not in protected areas. Our study fills a knowledge gap by identifying regions where Ornate Chorus Frog populations are likely thriving and regions where they may be extinct.

Alabama, Florida, Georgia, Louisiana, Mississippi,↗

Water-quality monitoring of Sweetwater Reservoir

Sweetwater Authority is concerned with the quality of water it provides to its customers. Results from the water-quality monitoring study that the USGS is conducting in the Sweetwater watershed show that the contaminant concentrations in bed sediments, water, and air are reflected in increased urbanization. The bed sediments show the most dramatic evidence of this impact with a sharp increase of persistent organic chemical concentrations over the past 65 years. Water quality is also affected by urbanization in the form of chemicals in the runoff water and deposition of airborne chemicals. The concentrations of the detected organic chemicals in Sweetwater and Loveland Reservoirs are all well below the guidance limits set by State and Federal agencies to protect human health. Many of these compounds are detected only because of the sensitive analytical methods used. This monitoring program provides the Sweetwater Authority with information on what monitored chemicals are present in the reservoirs, and at what concentrations. With this information, the Authority can assess the associated risks, and consider future water treatment and remediation. These results also help focus and support future efforts by Sweetwater Authority to protect the watershed.

Fact Sheet↗

Trace metals related to historical iron smelting at Hopewell Furnace National Historic Site, Berks and Chester Counties, Pennsylvania

Iron ore containing elevated concentrations of trace metals was smelted at Hopewell Furnace during its 113 years of operation (1771-1883). The ore used at Hopewell Furnace was obtained from iron mines within 5 miles of the furnace. The iron-ore deposits were formed about 200 million years ago and contain abundant magnetite, the primary iron mineral, and accessory minerals enriched in arsenic, cobalt, copper, lead, and other metals. Hopewell Furnace, built by Mark Bird during 1770-71, was one of the last of the charcoal-burning, cold-blast iron furnaces operated in Pennsylvania. The most productive years for Hopewell Furnace were from 1830 to 1837. Castings were the most profitable product, especially the popular Hopewell Stove. More than 80,000 stoves were cast at Hopewell, which produced as many as 23 types and sizes of cooking and heating stoves. Beginning in the 1840s, the iron industry shifted to large-scale, steam-driven coke and anthracite furnaces. Independent rural enterprises like Hopewell could no longer compete when the iron and steel industries consolidated in urban manufacturing centers. The furnace ceased operation in 1883 (Kurjack, 1954). The U.S. Geological Survey (USGS), in cooperation with the National Park Service, completed a study at Hopewell Furnace National Historic Site (NHS) in Berks and Chester Counties, Pennsylvania, to determine the fate of toxic trace metals, such as arsenic, cobalt, and lead, released into the environment during historical iron-smelting operations. The results of the study, conducted during 2008-10, are presented in this fact sheet.

Pennsylvania↗

The U.S. Geological Survey's water resources program in New York

The U.S. Geological Survey performs hydrologic investigations throughout the United States to appraise the Nation's water resources. The Geological Survey began its water-resources investigations in New York in 1895. To meet the objectives of assessing New York's water resources, the Geological Survey (1) monitors the quantity and quality of surface and ground water, (2) conducts investigations of the occurrence, availability, and chemical quality of water in specific areas of the State, (3) develops methods and techniques of data-collection and interpretation, (4) provides scientific guidance to the research community, to Federal, State, and local governments, and to the public, and (5) disseminates data and results of research through reports, maps, news releases, conferences, and workshops. Many of the joint hydrologic investigations are performed by the Geological Survey in cooperation with State, county, and nonprofit organizations. The data collection network in New York includes nearly 200 gaging stations and 250 observation wells; chemical quality of water is measured at 260 sites. Data collected at these sites are published annually and are filed in the WATSTORE computer system. Some of the interpretive studies performed by the Geological Survey in New York include (1) determining the suitability of ground-water reservoirs for public-water supply in urban areas, (2) assessing geohydrologic impacts of leachate from hazardous waste sites on stream and ground-water quality, (3) evaluating the effects of precipitation quality and basin characteristics on streams and lakes, and (4) developing digital models of the hydrology of aquifers to simulate ground-water flow and the interaction between ground water and streams.

Open-File Report↗

Use of real-time monitoring to predict concentrations of select constituents in the Menomonee River drainage basin, Southeast Wisconsin, 2008-9

The Menomonee River drainage basin in southeast Wisconsin is undergoing changes that may affect water quality. Several rehabilitation and flood-management projects are underway, including removal of concrete channels and the construction of floodwater retention basins. The city of Waukesha may begin discharging treated wastewater into Underwood Creek, thus approximately doubling the current base-flow discharge. In addition, the headwater basins, historically dominated by agriculture and natural areas, are becoming increasingly urbanized. In an effort to monitor these and future changes to the basin, the U.S. Geological Survey and the Milwaukee Metropolitan Sewerage District initiated a study in 2008 to develop regression models to estimate real-time concentrations and loads of selected water-quality constituents. Water-quality sensors and automated samplers were installed at five sites in the Menomonee River drainage basin. The sensors continuously measured four explanatory variables: water temperature, specific conductance, dissolved oxygen, and turbidity. Discrete water-quality samples were collected and analyzed for five response variables: chloride, total suspended solids, total phosphorus, Escherichia coli bacteria, and fecal coliform bacteria. Regression models were developed to continuously estimate the response variables on the basis of the explanatory variables. The models to estimate chloride concentrations all used specific conductance as the explanatory variable, except for the model for the Little Menomonee River near Freistadt, which used both specific conductance and turbidity as explanatory variables. Adjusted R 2 values for the chloride models ranged from 0.74 to 0.97. Models to estimate total suspended solids and total phosphorus used turbidity as the only explanatory variable. Adjusted R 2 values ranged from 0.77 to 0.94 for the total suspended solids models and from 0.55 to 0.75 for the total phosphorus models. Models to estimate indicator bacteria used water temperature and turbidity as the explanatory variables, with adjusted R 2 values from 0.54 to 0.69 for Escherichia coli bacteria models and from 0.54 to 0.74 for fecal coliform bacteria models. Dissolved oxygen was not used in any of the final models. These models may help managers measure the effects of land-use changes and improvement projects, establish total maximum daily loads, estimate important water-quality indicators such as bacteria concentrations, and enable informed decision making in the future.

Wisconsin↗

Occurrence, trends, and sources in particle-associated contaminants in selected streams and lakes in Fort Worth, Texas

Several lakes and stream segments in Fort Worth, Texas, have fish consumption bans because of elevated levels of chlordane, dieldrin, DDE, and polychlorinated biphenyls (PCBs). This study was undertaken to evaluate current loading, trends, and sources in these long-banned contaminants and other particle-associated contaminants commonly found in urban areas. Sampling included suspended sediments at 11 sites in streams and bottom-sediment cores in three lakes. Samples were analyzed for chlorinated hydrocarbons, major and trace elements, and polycyclic aromatic hydrocarbons (PAHs). All four legacy pollutants responsible for fish consumption bans were detected frequently. Concentrations of chlordane, lead, and PAHs most frequently exceeded sediment-quality guidelines. Trends in DDE and PCBs since the 1960s generally are decreasing; and trends in chlordane are mixed with a decreasing trend in Lake Como, no trend in Echo Lake, and an increasing trend in Fosdic Lake. All significant trends in trace elements are decreasing, and most significant trends in PAHs are increasing. Sedimentation surveys were conducted on each of the three lakes and used in combination with sediment core data to compute sediment mass balances for the lakes, to estimate long-term-average loads and yields of sediment, and to estimate recent loads and yields of selected contaminants. Concentrations of most trace elements in suspended sediments were similar to those at the tops of cores, but concentrations of many hydrophobic organic contaminants were two to three times larger. As a result, for these fluvial systems, sediment cores probably provide a historical record of trace element contamination but could underestimate historical concentrations of organic contaminants. However, down-core profiles suggest that relative concentration histories are preserved in these sediment cores for many organic contaminants (such as chlordane and total DDT) but not for all (such as dieldrin). Percent urban land use correlates strongly with selected contaminant concentrations in sediments. Organochlorine pesticides had significant correlations to residential land use, whereas PCBs, cadmium, lead, zinc, and PAHs more often correlate significantly with commercial and industrial land uses, which suggests different urban sources for different contaminants. The amount of enrichment in these contaminants associated with urban land use predicted from regression equations, expressed as the ratio of concentrations predicted for 100 percent urban to 30 percent urban, ranges from 3.6 to 6.9 for PCBs and heavy metals to about 15 for chlordane, total DDT, and PAHs. These data indicate that urbanization is having a substantial negative effect on sediment and water quality and that legacy pollutants are being actively transported to streams and lakes 13 to 30 years after their use was restricted or banned. They further suggest that fish in the lakes and these water bodies will continue to be exposed to legacy pollutants in sediment for many years to come.

Texas↗

Impact of discharges from point and nonpoint sources on water quality of the upper Reedy River near Greenville, South Carolina

Impacts of discharge from nonpoint sources in the urban area of Greenville, South Carolina and from the point source, the Mauldin Road Wastewater Treatment Plant, on water quality of the Reedy River were studied from October 1979 through September 1980. Streamflow and water-quality data were collected before and during two storms. The pH and concentrations of organic nitrogen, ammonium, nitrate plus nitrate, ultimate carbonaceous biochemical oxygen demand, dissolved oxygen, and orthophosphate were determined. Streamflow and concentrations of dissolved oxygen were measured continuously at three stations from May through September 1980. Discharge from the point source resulted in average daily concentrations of dissolved oxygen less than 5 milligrams per liter in the Reedy River on 34 days during low streamflow in the summer of 1980. During periods of high streamflow that resulted from the two storms. Dissolved oxygen remained at about 5 milligrams per liter in the Reedy River because increased dilution of loads of oxygen-demanding materials reduced the impacts of these loads on the quality of the Reedy River. (USGS)

South Carolina↗

Hydrology and water quality of the Edwards Aquifer associated with Barton Springs in the Austin area, Texas

Urban development over the Edwards aquifer in the Austin, Texas, area has caused concerns about the availability and quality of water in the aquifer. The study area, the Edwards aquifer that discharges to Barton Springs, includes parts of Travis and Hays Counties and extends from the city of Kyle to the Colorado River. A large part of the aquifer lies within the Austin metropolitan area one of the fastest growing areas in the Nation. As of 1985, only about 30,000 people used water from the aquifer, however, according to recent official city of Austin population projections, about 86,000 more people will be living in the study area by the year 2000, many of whom will depend upon the aquifer for water. Barton Springs, which discharges from the aquifer, serves as a supplemental source of drinking water for Austin and as a major recreational attraction. The aquifer is a karst system composed of limestone and dolomite of Cretaceous age. The water occurs in solution channels in the Edwards and Georgetown Limestones. Yields of adjacent wells often differ by as much as four orders of magnitude. Storage within the aquifer is about 306,000 acre-feet, of which about 31,000 acre-feet is within the "transient" part of storage the change in volume occurring between high flow and the lowest known flow of Barton Springs. The average specific yield of the aquifer is 0.017. Within the study area, the Edwards aquifer covers 155 square miles, of which about 151 square miles discharge to Barton Springs, and the remaining 4 square miles discharge to Cold and Deep Eddy Springs. The westernmost 79 percent of the aquifer is under water-table conditions, and the remaining 21 percent is under confined conditions. Three geologic sections are presented in the report, as well as maps showing the altitudes of the base and the top of the Edwards aquifer. Recharge occurs predominantly along faults and fractures crossing six creeks in the recharge area, which covers the westernmost 90 square miles of the aquifer. Leakage probably occurs into the Edwards aquifer from the underlying upper Trinity aquifer. A small amount of subsurface recharge also occurs as "bad-water" encroachment during lovnflow periods. Monthly values for water levels, total surface-water recharge, and total discharge (springflow and pumpage) for the aquifer are available for 4 years. Water-budget analyses show that surface recharge and ground-water discharge (springflow and pumpage) are reasonably balanced, suggesting that the ground-water system is in dynamic equilibrium. Based on 65 years of measurements, Barton Springs has a long-term mean discharge of 50 cubic feet per second and a minimum and maximum discharge of 10 and 166 cubic feet per second. As of 1982, the estimated total ground-water pumpage of about 3,800 acre-feet per year represented just over 10 percent of the average annual discharge of 36,000 acre-feet to Barton Springs. Increased pumpage associated with future ground-water development could reduce the discharge at Barton Springs and reduce ground-water availability. Substantial pumpage increases could cause increased subsurface flow into the aquifer in the form of "bad-water" encroachment, leakage from underlying aquifers, or both. Water-quality data for 1979-83 are available for each creek that recharges the aquifer, from Barton Springs, and for 38 wells. Water quality from Barton Springs and the wells is better than the creeks providing surface recharge, which have fecal-bacteria values as high as 100,000 colonies per 100 milliliters. Significant densities of fecal bacteria have been found in water from Barton Springs. Significant concentrations of nitrate nitrogen, fecal-group bacteria, and fluoride have been identified in samples from wells. Fluoride originates in the aquifers that underlie the Edwards aquifer. Nitrate nitrogen and fecal-group bacteria originate in residential developments and cattle ranches located in the area.

Texas↗

Variation in the relation of rainfall to runoff from residential lawns in Madison, Wisconsin, July and August 1995

The quality of runoff from residential lawns is a concern for municipal stormwater management programs. Land-use based computer models are increasingly being used to assess the impact of lawn runoff on urban watersheds. To accurately model the runoff for residential lawns, the variation in the relation of rainfall to runoff from lawns must be understood. The study described in this report measures the runoff parameters from 20 residential lawns in Madison, Wisconsin, using a rainfall simulator. It was determined that the saturated hydraulic conductivity does not vary significantly within a single residential lawn, but does vary significantly from one lawn to another. This variation is recognized in the entire rainfall-runoff relation from one lawn to another. The age of a lawn, or the years since development and turf establishment, is used as a surrogate of several lawn and soil characteristics to describe the variability in lawn runoff volumes. Runoff volumes from newly developed lawns are significantly greater than runoff from older lawns. This is an important consideration when modeling runoff for new developments. For older lawns, the date since lawn establishment does not explain the variation in the rainfall-runoff relation. In order for simple land-use based computer models to adequately account for the volume of runoff from pervious landscapes, field data from individual lawns would be necessary. A more realistic, alternative method may be to consider a basin-scale analysis of runoff from pervious landscapes.

Wisconsin↗