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Typing mineral deposits using their grades and tonnages in an artificial neural network

A test of the ability of a probabilistic neural network to classify deposits into types on the basis of deposit tonnage and average Cu, Mo, Ag, Au, Zn, and Pb grades is conducted. The purpose is to examine whether this type of system might serve as a basis for integrating geoscience information available in large mineral databases to classify sites by deposit type. Benefits of proper classification of many sites in large regions are relatively rapid identification of terranes permissive for deposit types and recognition of specific sites perhaps worthy of exploring further. Total tonnages and average grades of 1,137 well-explored deposits identified in published grade and tonnage models representing 13 deposit types were used to train and test the network. Tonnages were transformed by logarithms and grades by square roots to reduce effects of skewness. All values were scaled by subtracting the variable's mean and dividing by its standard deviation. Half of the deposits were selected randomly to be used in training the probabilistic neural network and the other half were used for independent testing. Tests were performed with a probabilistic neural network employing a Gaussian kernel and separate sigma weights for each class (type) and each variable (grade or tonnage). Deposit types were selected to challenge the neural network. For many types, tonnages or average grades are significantly different from other types, but individual deposits may plot in the grade and tonnage space of more than one type. Porphyry Cu, porphyry Cu-Au, and porphyry Cu-Mo types have similar tonnages and relatively small differences in grades. Redbed Cu deposits typically have tonnages that could be confused with porphyry Cu deposits, also contain Cu and, in some situations, Ag. Cyprus and kuroko massive sulfide types have about the same tonnages. Cu, Zn, Ag, and Au grades. Polymetallic vein, sedimentary exhalative Zn-Pb, and Zn-Pb skarn types contain many of the same metals. Sediment-hosted Au, Comstock Au-Ag, and low-sulfide Au-quartz vein types are principally Au deposits with differing amounts of Ag. Given the intent to test the neural network under the most difficult conditions, an overall 75% agreement between the experts and the neural network is considered excellent. Among the largestclassification errors are skarn Zn-Pb and Cyprus massive sulfide deposits classed by the neuralnetwork as kuroko massive sulfides—24 and 63% error respectively. Other large errors are the classification of 92% of porphyry Cu-Mo as porphyry Cu deposits. Most of the larger classification errors involve 25 or fewer training deposits, suggesting that some errors might be the result of small sample size. About 91% of the gold deposit types were classed properly and 98% of porphyry Cu deposits were classes as some type of porphyry Cu deposit. An experienced economic geologist would not make many of the classification errors that were made by the neural network because the geologic settings of deposits would be used to reduce errors. In a separate test, the probabilistic neural network correctly classed 93% of 336 deposits in eight deposit types when trained with presence or absence of 58 minerals and six generalized rock types. The overall success rate of the probabilistic neural network when trained on tonnage and average grades would probably be more than 90% with additional information on the presence of a few rock types.

Natural Resources Research↗

The chemostratigraphy of the Murray formation and role of diagenesis at Vera Rubin ridge in Gale crater, Mars, as observed by the ChemCam instrument

Geochemical results are presented from Curiosity’s exploration of the Vera Rubin ridge (VRR), in addition to the full chemostratigraphy of the predominantly lacustrine mudstone Murray formation up to and including VRR. VRR is a prominent ridge flanking Aeolis Mons (informally Mt. Sharp), the central mound in Gale crater, Mars, and was a key area of interest for the Mars Science Laboratory mission. ChemCam data show that VRR is overall geochemically similar to lower-lying members of the Murray formation, even though the top of VRR is characterized by strong hematite spectral signatures as observed from orbit. While overall geochemically similar, VRR is characterized by a prominent decrease in Li abundance and Chemical Index of Alteration across the ridge. This decrease follows the morphology of the ridge rather than elevation and is inferred to reflect a non-depositionally controlled decrease in clay mineral abundance in VRR rocks. Additionally, a notable enrichment in Mn above baseline levels is observed on VRR. While not supporting a single model, the results suggest that VRR rocks were likely affected by multiple episodes of post-depositional groundwater interactions that made them more erosionally resistant than surrounding Murray rocks – thus resulting in the modern-day ridge after subsequent erosion.

Journal of Geophysical Research: Planets↗

Implications of the Surveyor 7 results

The chemical and television data from the Surveyor 7 mission are discussed. The significance of the α-scattering analysis is found to depend on whether the flow unit underlying the spacecraft was laid down by mass flow at the time of the Tycho-forming impact. The chemical composition of the site is significantly lower in Fe than the composition of the previously analyzed mare sites; no other resolvable distinctions can be made. The higher albedo of the highlands is attributed to the lower iron content in the silicate minerals. By assigning the atomic composition to minerals common in basaltic rocks, we estimate-the highland rock density to be 3.0 and the mare density to be 3.2. The densities may be incorporated into a discussion of recent information on the gravitational field of the moon, yielding estimates of crustal thickness in the highlands around 30 to 50 km. A number of television pictures of rocks and fragments are shown, and we offer some suggestions about the type and origin of these objects. They compose a heterogeneous population in which the brighter rocks seem to be more resistant to mechanical breakdown than the dark rocks. The characteristics of the fine-grained component of the surface mantle are found to be similar to those at earlier Surveyor sites. The process of eroding exposed rocks and covering them with a blanket of fine particles appears to be relatively less advanced than at the sites previously studied; A bright line of light was seen on the western horizon after sunset, as was observed during Surveyor 5 and 6; this rather puzzling phenomenon is discussed again.

Journal of Geophysical Research↗

Sr isotopic tracer study of the Samail ophiolite, Oman

We have measured Rb and Sr concentrations and Sr isotopic compositions in 41 whole-rock samples and 12 mineral separates from units of the Samail ophiolite, including peridotite, gabbro, plagiogranite, diabase dikes, and gabbro and websterite dikes within the metamorphic peridotite. Ten samples of cumulate gabbro from the Wadir Kadir section and nine samples from the Wadi Khafifah section have mean 87 Sr/ 86 Sr ratios and standard deviations of 0.70314 ± 0.00030 and 0.70306 ± 0.00034, respectively. The dispersion in Sr isotopic composition may reflect real heterogeneities in the magma source region. The average Sr isotopic composition of cumulate gabbro falls in the range of isotopic compositions of modern midocean ridge basalt. The 87 Sr/ 86 Sr ratios of noncumulate gabbro, plagiogranite, and diabase dikes range from 0.7034 to 0.7047, 0.7038 to 0.7046, and 0.7037 to 0.7061, respectively. These higher 87 Sr/ 86 Sr ratios are due to alteration of initial magmatic compositions by hydrothermal exchange with seawater. Mineral separates from dikes that cut harzburgite tectonite have Sr isotopic compositions which agree with that of cumulate gabbro. These data indicate that the cumulate gabbro and the different dikes were derived from partial melting of source regions that had similar long-term histories and chemical compositions.

Journal of Geophysical Research Solid Earth↗

Recharge and discharge of the ground‐water reservoirs on the High Plains in Texas

The High Plains in Texas occupy an area of about 35,000 square miles extending from the northern boundary of the Panhandle southward about 300 miles, and from the New Mexico line eastward an average distance of about 120 miles to a boundary which in most places is sharply defined by a bold escarpment several hundred feet in height. The region is noted for its abundant supply of ground‐water, most of which is found in the Ogallala formation, a sandy deposit lying at or near the surface throughout most of the region, and reaching a depth of between 200 and 300 feet. The Ogallala formerly extended over a much greater area, but it has been removed by erosion from much of the territory it once occupied. The areas in which it remains are the High Plains, which are bounded by prominent escarpments both on the east and on the west, and are traversed in Texas by the Canadian River, which is deeply entrenched in the older rocks. The water‐bearing sands of the Ogallala in both segments are cut off in all directions from any underground connection, except through the underlying older rocks which contain highly mineralized water unlike the fresh water in the Ogallala. The source of the fresh water, therefore, is within the High Plains themselves, and is from the rain and snow that falls on the surface of the Plains.

Eos, Transactions, American Geophysical Union↗

Salinity variations in submarine hydrothermal systems by layered double-diffusive convection

Various mechanisms have been proposed to explain the salinity variations in vent fluids of seafloor geothermal systems. New experiments reacting diabase and evolved seawater were carried out to reproduce earlier published observations of Cl depletions attributed to formation of an ephemeral Cl-bearing mineral. The absence of any Cl depletions in the present study suggests that the formation of Cl-bearing minerals is not sufficiently widespread to account for the observed salinity variations in the vent fluids. A re-evaluation of both field and laboratory evidence has led to a new model for subseafloor circulation that accounts for salinity variations as well as other chemical and mineralogic observations. In place of a simple single-pass convection system, we propose that the seafloor systems consist of two vertically nested convection cells in which a brine layer at depth heats and drives an overlying seawater cell. Such layering of salinities, a process known in fluid mechanics as double-diffusive convection, is an expected result when convection is induced in saline fluids. The process provides for stable high-temperature heat transfer upward from the cracking front adjacent to the magma, and for limited chemical exchange of the brine with the overlying seawater to explain salinity variations and high metal contents in the vent fluids. The brine also provides an effective medium to produce the secondary mineral assemblages observed in rocks from the mid-ocean ridges and ophiolites unsuccessfully produced in laboratory studies using seawater. The brine originates from the two-phase separation of seawater during magmatic/tectonic events and accumulates and remains relatively stable in the region immediately above the magma chamber.

Journal of Geology↗

Isotopic age of the Nevadan Orogeny and older Plutonic and metamorphic events in the Klamath Mountains, California

Several metamorphic and plutonic events have been recognized in the Klamath Mountains utilizing potassium-argon and rubidium-strontium mineral and whole-rock ages. The oldest known metamorphic event in the region produced the Abrams Mica Schist and the co-extensive Salmon Hornblende Schist. Strontium evolution diagrams indicate that the age of primary metamorphism of the Abrams Mica Schist is approximately 380 m.y. (Devonian). The Stuart Fork Formation of Davis and Lipman (1962), the schists of Condrey Mountain, and related schists were produced during a Middle and Late Jurassic metamorphic event. Granitic plutonic rocks are divided into four groups that are different in age and somewhat different in chemical characteristics. The oldest pluton, the Pit River stock, has a minimum age of 246 m.y. (Permian) and is grouped with the Castle Crags pluton. The other three plutonic groups are Middle and Late Jurassic and are characterized by the following ranges in isotopic age: 165 to 167 m.y., 145 to 155 m.y., and 127 to 140 m.y. The principal lode gold deposits in the California part of the Klamath Mountains seem to be related to the youngest group of plutons. If the Nevadan orogeny in this area is restricted to a Middle and Late Jurassic deformational, metamorphic, and plutonic event, the orogeny includes the emplacement of plutons of the three younger groups and the metamorphic development of the Stuart Fork Formation, schists of Condrey Mountain, and related schists.

California↗

40Ar/39Ar and K-Ar data bearing on the metamorphic and tectonic history of western New England

40 Ar/ 39 Ar ages of coexisting biotite and hornblende from Proterozoic Y gneisses of the Berkshire and Green Mountain massifs, as well as 40 Ar/ 39 Ar and K-Ar mineral and whole-rock ages from Paleozoic metamorphic rocks, suggest that the thermal peak for the dominant metamorphic recrystallization in western New England occurred 465 ± 5 m.y. ago (Taconian). Although textural data indicate a complex metamorphic-tectonic history for Paleozoic rocks, no evidence in rocks at least as high as kyanite grade dictates an Acadian age for the Barrovian metamorphism. Available 40 Ar/ 39 Ar and K-Ar data suggest that the low-grade metamorphism and cleavage formation in Taconic allochthons and the higher-grade metamorphism and emplacement of the Berkshire massif allochthon are Taconian. 40 Ar/ 39 Ar age data from a poorly defined terrane beginning near the east margin of the Green Mountain massif and extending along the eastern one-third of the Berkshire massif as far south as Otis, Massachusetts, suggest that the area has been retrograded during a metamorphism that peaked at least 376 ± 5 m.y. ago (Acadian). Available age and petrologic data from western New England indicate the presence of at least three separate metamorphic-structural domains of Taconian age: (1) a small area of relict high-pressure and low-temperature metamorphism in northern Vermont (T-1 domain), (2) a broad area in Vermont and eastern New York of normal Barrovian metamorphism from chlorite to garnet grade and characterized by a gentle metamorphic gradient (T-2 domain), and (3) a rather narrow belt of steep-gradient, Barrovian series metamorphic rocks extending from near the Cortlandt Complex northeastward through Dutchess County, New York, to the Berkshire massif in western Massachusetts (T-3 domain). Areas of maximum metamorphic intensity within the T-3 domain coincide with areas of maximum crustal thickening resulting from imbricate thrusting (Berkshire massif) or from recumbent folding (Manhattan Prong) of remobilized North American continental crust in the later stages of the Taconic orogeny.

Geological Society of America Bulletin↗

40 Ar/ 39 Ar dating of Quaternary feldspar: Examples from the Taupo Volcanic Zone, New Zealand

Using a continuous laser and resistance furnace, we have measured ages on Quaternary plagioclase with an absolute precision of about ±30 ka and on Quaternary sanidine with a relative precision of better than 1%. Such precision was achieved by using low-temperature heating steps to remove much of the nonradiogenic argon contamination. Plagioclase is one of the most common mineral phases in volcanic rocks; thus, these procedures will be widely applicable to many problems for which precise radiometric age control has not been available. We studied plagioclase and plagioclase-sanidine concentrates from the oldest and the three largest silicic ash-flow deposits of the Taupo Volcanic Zone, New Zealand, one of the world's largest and most active volcanic systems. The results are in close agreement with new magnetostratigraphic data, suggest that existing fission-track age determinations significantly underestimate the age of older units, and shift the inception of Taupo Volcanic Zone volcanism back to at least 1600 ka. The improved precision has permitted the first correlations between proximal and distal units; previous correlations with deep-sea ash flows in the western Pacific require major revision.

Geology↗

Geology and mineral evaluation of the Wadi Bidah district, southern Hijaz quadrangle, Kingdom of Saudi Arabia

The Wadi Bidah district in southwest Saudi Arabia contains several ancient mines and mineral-prospects. The Precambian rocks of the district are steeply dipping and highly folded and faulted. They are divided into three major units: (1) older metavolcanic rocks, (2) metasedimentary rocks, and (3) younger metavolcanic rocks. Massive sulfide-type deposits show stratigraphic control and are found in metasedimentary rocks and in the younger metavolcanic rocks. There appears to be a close genetic relationship between the sulfide deposits and volcanism. Deposits containing copper, zinc, gold, and silver are indicated by geologic mapping and by shallow diamond drill holes in two of the ancient mine localities. The ore estimate for the district is 2.55 million short tons computed to depths that range from 79 to 150 meters. It seems probable that deeper drilling of the indicated deposits and drilling of other outlined target areas would add substantially to the ore reserves.

Open-File Report↗

Strata-bound, silver-bearing iron, lead, and zinc sulfide deposits in Silurian and Ordovician rocks of allochthonous terranes, Nevada and northern Mexico

Allochthonous terranes in northern Nevada contain strata-bound sulfide deposits at two horizons in Silurian and Ordovician siliceous sedimentary rocks. The most intensively mineralized horizon and most extensive deposit is at the base of the Silurian. Another less extensive deposit is in the lower Middle Ordovician. Spectrographic analyses of gossan from the basal Silurian horizon indicate anomalously high values of lead and zinc; and in about 40 percent of the samples, silver values are anomalously high. Suhsurface samples contain the primary minerals pyrite, galena, and sphalerite. The basal Silurian deposits are in thick-bedded chert that is overlain by micaceous siltstone. They are underlain by a thick-bedded black chert unit of Late Ordovician age. The basal Silurian gossan has been identified also in southwestern Nevada and in northern Mexico in stratigraphic sequences very similar to that of northern Nevada.

Open-File Report↗

Geologic map of the Bodie Hills, California and Nevada

The Bodie Hills covers about 1,200 km 2 straddling the California-Nevada state boundary just north of Mono Lake in the western part of the Basin and Range Province, about 20 km east of the central Sierra Nevada. The area is mostly underlain by the partly overlapping, middle to late Miocene Bodie Hills volcanic field and Pliocene to late Pleistocene Aurora volcanic field (John and others, 2012). Upper Miocene to Pliocene sedimentary deposits, mostly basin-filling sediments, gravel deposits, and fanglomerates, lap onto the west, north, and east sides of the Bodie Hills, where they cover older Miocene volcanic rocks. Quaternary surficial deposits, including extensive colluvial, fluvial, glacial, and lacustrine deposits, locally cover all older rocks. Miocene and younger rocks are tilted ≤30° in variable directions. These rocks are cut by several sets of high-angle faults that exhibit a temporal change from conjugate northeast-striking left-lateral and north-striking right-lateral oblique-slip faults in rocks older than about 9 Ma to north- and northwest-striking dip-slip faults in late Miocene rocks. The youngest faults are north-striking normal and northeast-striking left-lateral oblique-slip faults that cut Pliocene-Pleistocene rocks. Numerous hydrothermal systems were active during Miocene magmatism and formed extensive zones of hydrothermally altered rocks and several large mineral deposits, including gold- and silver-rich veins in the Bodie and Aurora mining districts (Vikre and others, in press).

California, Nevada↗

Potential for formation of disinfection by-products from storage of chlorinated surface water in the Basalt aquifer near Fallon, Nevada

Increased pumpage from a basalt aquifer near Fallon, Nevada, has caused its water levels to decline and has induced changes in the quality of water pumped from the basalt. The aquifer is the sole source of water for municipal supply to the city of Fallon, the Naval Air Station Fallon, and the Fallon Paiute-Shoshone Tribe. These changes may be mitigated by storage of surface water in the basalt for subsequent use. Because chlorination of the surface water may be required for storage, the U.S. Geological Survey, in cooperation with the Fallon Paiute-Shoshone Tribe, made laboratory tests using laboratory carbon-organic-free water, surface-water, ground-water, and basaltic-rock samples to determine the potential for formation of disinfection by-products. Experiments with water samples only (no rock and no chlorine) indicated no change in dissolved-organic-carbon (DOC) concentrations over a 20-day reaction period; whereas, all experiments using rock, water, and no chlorine indicated an increase in DOC concentrations. The greatest increase in DOC concentrations for all three water samples occurred in experiments with the rock samples from outcrops on Rattlesnake Hill. Experiments with water only and chlorine yielded a total trihalomethane (THM) concentration of 97.4 ?g/L for the ground-water sample and 347 ?g/L for the surface-water sample. Experiments with mixtures of water, rocks, and chlorine indicated that reactions with the rock consumed chlorine and released significant amounts of organic carbon from the rock, increasing the DOC concentration in the water. The organic carbon in the rocks likely is associated with the secondary clay minerals that line vesicles and fractures in the rocks. THM concentrations were greatest, from 335 to 909 ?g/L, for surface water equilibrated with rock samples from Rattlesnake Hill. However, the concentration of chlorine required to produce these high THM concentrations ranged from 18 to 84 mg/L. The results of the experiments suggest that the amount of organic carbon released from the rocks during successive cycles of recharge, storage, and recovery of chlorinated surface water may be relatively small. The chlorine demand of the rocks is so large that all of the free chlorine in the entire volume of recharged water likely would be consumed by only a very small volume of the aquifer surrounding an injection well, or beneath an infiltration bed. The majority of the volume of the aquifer filled by the stored water likely would never come in contact with free chlorine, and the increases in concentration of DOC observed in these experiments likely would occur in a very small volume of the stored water. For this reason, increases in concentration of THMs for the entire volume of water stored also likely would be considerably less than those measured in these experiments. To test this hypothesis, additional laboratory experiments using varying levels of chlorination, varying lengths of reaction periods, and repeated cycles of chlorination would be useful. A field experiment made at a small scale in an isolated part of the basalt aquifer would aid in the design of an operational system.

Scientific Investigations Report↗

Reconnaissance for uranium and thorium in Alaska, 1954

During 1954 reconnaissance investigations to locate minable deposits of uranium and thorium in Alaska were unsuccessful. Areas examined, from which prospectors had submitted radioactive samples, include Cap Yakataga, Kodiak Island, and Shirley Lake. Unconcentrated gravels from the beach at Cape Yakataga average about 0.001 percent equivalent uranium. Uranothorianite has been identified by X-ray diffraction data and is the principal source of radioactivity in the Cape Yakataga beach sands studied; but the zircon, monazite, and uranothorite are also radioactive. The black, opaque uranothorianite generally occurs as minute euhedral cubs, the majority of which will pass through a 100-mesh screen. The bedrock source of the radioactive samples from Kodiak Island was not found; the maximum radioactivity of samples from the Shirley Lake area was equivalent to about 0.02 percent uranium. Radiometric traverses of the 460-foot level of the Garnet shaft of the Nixon Fork mine in the Nixon Fork mining district indicated a maximum of 0.15 mr/hr. In the Hot Springs district, drill hole concentrates of gravels examined contained a maximum of 0.03 percent equivalent uranium. A radioactivity anomaly noted during the Survey's airborne reconnaissance of portions of the Territory during 1954 is located in the Fairhaven district. A ground check disclosed that the radioactivity was due to accessory minerals in the granitic rock.

Alaska↗

Summary of reconnaissance for uranium in Alaska, 1955

Reconnaissance for uranium in Alaska during 1955 included airborne radiometric traverses, examination of radioactivity anomalies found during the airborne traverses, examination of prospector leads, and examination of areas that seems geologically favorable for the occurrence of uranium. The airborne radiometric traverses in central Alaska revealed 33 anomalies considered worth examining. The ground examinations of a few of these anomalies indicated that they were due to radiation of from accessory minerals in intrusive granitic rocks. The examination of prospector leads revealed several radioactivity anomalies of interest and one, near Bokan Mountain on prince of Wales Island, of possible commercial importance.

Alaska↗

Mineral intergrowths replaced by "elbow-twinned" rutile in altered rocks

Some aggregates of rutile, classically considered to be "elbow" twinned, instead are topotactic replacements of ilmenite or other hexagonal titaniferous precursors. Twinned rutile can be differentiated from the reticulated rutile of topotactic replacements by the angle of prism intersections, junction morphology, and the overall form of the aggregate. In a special case of topotactic replacement of ilmenite, rutile forms pseudomorphs of "trellis"-textured ilmenite lamellae in {111} of precursor magnetite. We trace the progress of rutile formation through the alteration of fine-grained magnetite-bearing host rocks. The sequential two-step topotaxy from magnetite through ilmenite to rutile requires rutile prisms to parallel the intersections of {111} planes in precursor magnetite. Some coarse reticulated rutile may result from the same paragenetic sequence.

Canadian Mineralogist↗