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USGS2008

Assessment of nonpoint source chemical loading potential to watersheds containing uranium waste dumps associated with uranium exploration and mining, San Rafael Swell, Utah

During July and August of 2006, 117 solid-phase samples were collected from abandoned uranium waste dumps, geologic background sites, and adjacent streambeds in the San Rafael Swell, in southeastern Utah. The objective of this sampling program was to assess the nonpoint source chemical loading potential to ephemeral and perennial watersheds from uranium waste dumps on Bureau of Land Management property. Uranium waste dump samples were collected using solid-phase sampling protocols. After collection, solid-phase samples were homogenized and extracted in the laboratory using a field leaching procedure. Filtered (0.45 micron) water samples were obtained from the field leaching procedure and were analyzed for Ag, As, Ba, Be, Cd, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sb, Se, U, V, and Zn at the Inductively Coupled Plasma-Mass Spectrometry Metals Analysis Laboratory at the University of Utah, Salt Lake City, Utah and for Hg at the U.S. Geological Survey National Water Quality Laboratory, Denver, Colorado. For the initial ranking of chemical loading potential of suspect uranium waste dumps, leachate analyses were compared with existing aquatic life and drinking-water-quality standards and the ratio of samples that exceeded standards to the total number of samples was determined for each element having a water-quality standard for aquatic life and drinking-water. Approximately 56 percent (48/85) of the leachate samples extracted from uranium waste dumps had one or more chemical constituents that exceeded aquatic life and drinking-water-quality standards. Most of the uranium waste dump sites with elevated trace-element concentrations in leachates were along Reds Canyon Road between Tomsich Butte and Family Butte. Twelve of the uranium waste dump sites with elevated trace-element concentrations in leachates contained three or more constituents that exceeded drinking-water-quality standards. Eighteen of the uranium waste dump sites had three or more constituents that exceeded trace-element concentrations for aquatic life water-quality standards. The proximity of the uranium waste dumps in the Tomsich Butte area near Muddy Creek, coupled with the elevated concentration of trace elements, increases the offsite impact potential to water resources. Future assessment and remediation priority of these areas may be done by using GIS-based risk-mapping techniques, such as Sensitive Catchment Integrated Mapping and Analysis Project.

Utah↗
USGS1994

Hydrology of, and water quality in, the open burning area and vicinity, Picatinny Arsenal, New Jersey, 1989-90

This report presents the results of a study to determine whether shallow ground water at Picatinny Arsenal Morris County, New Jersey, has been con- taminated as a result of operations at the open burning area, which is used for burning of waste explosives and materials contaminated with explosives. Results of previous investigations indicate that the soil in this area is contaminated with metals and organic compounds. Twenty-seven wells were sampled for analysis for inorganic constituents, nutrients, and explosive compounds. Selected wells also were sampled for analysis for base/neutral- and acid-extractable compounds, pesticides, volatile organic compounds, and dioxin and furan compounds. Surface-water and streambed- material samples were collected at three sites in Green Pond Brook. Water-level measurements indicate that ground-water flow generally is nearly horizontal and toward Green Pond Brook. The average velocity of the ground water is estimated to be 0.03 to 1.8 feet per day. Concentrations of iron and manganese in ground-water samples from the unconfined aquifer were consistently greater than U.S. Environmental Protection Agency secondary drinking-water regulations. Because similarly high concentrations of these constituents have been found in ground-water samples at the arsenal, they are not considered to be a consequence of activities at the open burning area. Contaminants from the open burning area appear to be contributing to elevated concentratons of lead, zinc, and explosive com- pounds found in the streambed material. Other trace element and polynuclear aromatic hydrocarbons probably are derived from both the open burning area and upstream sources. Volatile organic compounds were detected in surface-water samples at low concentrations, although most were found upstream from the open burning area. No inorganic or organic constituents were detected in ground-water or surface-water samples in concentrations that exceeded U.S. Environmental Protection Agency primary drinking-water regulations.

New Jersey↗
USGS2002

Hydrogeology and water quality of the Upper Three Runs aquifer in the vicinity of the Gibson Road Landfill, Fort Gordon, Georgia, June-November 1999

Fort Gordon military installation, a U.S. Department of the Army facility, is located in east-central Georgia southwest of Augusta. The military base operates a three-phase unlined landfill—Gibson Road Landfill— to store a variety of wastes. Phases I and II stored only household wastes, and these phases were discontinued during the mid–1990s. Fort Gordon currently (1999) operates Phase III of the landfill that stores only construction and demolition debris. Water-quality monitoring detected selected trace elements and organic compounds exceeding the maximum contaminant levels of the U.S. Environmental Protection Agency, National Primary Drinking Water Standards. The selected trace elements and organic compounds detected showed that contamination of ground water had occurred in the vicinity of the landfill. In 1999, the U.S. Geological Survey, in cooperation with the Environmental and Natural Resources Management Office of the U.S. Army Signal Center and Fort Gordon, Georgia, began an assessment of the hydrogeology and water quality in shallow ground water in the vicinity of the Gibson Road Landfill to delineate the extent of a ground-water contamination plume in the vicinity of the landfill. Hydrogeologic units in the Augusta area include the Upper Three Runs aquifer, the Gordon aquifer, the Millers Pond aquifer, and the Dublin aquifer. Only the shallowest aquifer, Upper Three Runs, was penetrated during this study. The Upper Three Runs aquifer is composed of sediments of the Barnwell Group. Mostly, these sediments are highly permeable fine to medium, well-sorted sand with lenses of clay. Ground-water flow is from northwest to southeast and generally was unaffected by seasonal variation during the period of study (June–November 1999). Water-table altitudes in the landfill area for the study period ranged from 394 feet (ft) to 445 ft above sea level. Ground-water samples analyzed for organic compounds and selected trace elements by a U. S. Environmental Protection Agency (USEPA) approved statistical test revealed that increases in contaminant concentrations above the detection limits had occurred during March and September 1999 in five wells—one of which is located upgradient. These organic compounds, respective increases in concentration, and the wells in which they were detected are: methylene chloride—wells 28AA29 (24 parts per billion [ppb] and 46 ppb), 28AA30 (86 ppb and 130 ppb), and 28AA31 (240 ppb and 140 ppb); 1,1-dichloroethene—well 28AA31 (10 ppb and 5.7 ppb); 1,1-dichloroethane— wells 28AA30 (81 ppb and 140 ppb) and 28AA31 (200 ppb and 130 ppb); and 1,1,1-trichloroethane—well 28AA31 (61 ppb and 37 ppb). Although in some wells the concentration decreased from March to September, the median concentrations were still higher in certain groups. Trace element compounds, their respective increases in concentration, and the wells in which they were detected are: chromium—well 28AA30 (1,190 ppb), vanadium—well 28AA30 (104 ppb); barium—wells 28AA27 (42.2 ppb) and 28AA32 (140 ppb), and beryllium—well 28AA30 (6.3 ppb). These increases occurred in September, with the exception of chromium in well 28AA30, which occurred in March. Although a statistical test indicated increases in contaminant concentrations had occurred, water from wells 28AA27, 28AA30, 28AA31, and 28AA32 had a decrease in contaminant concentrations from February 1998 to September 1999. U.S. Environmental Protection Agency, National Primary Drinking Water Regulations Maximum Contaminant Levels (PMCLs), formerly (MCLs) were exceeded in water from four wells for organic compounds and in five wells by selected trace elements during the February 1998, March 1999, and September 1999 sampling periods. The concentrations for the following organic compounds and the associated wells are: methylene chloride (PMCL is 5 ppb)—wells 28AA27 (February, 37 ppb; March, 24 ppb; and September, 9.6 ppb), 28AA29 (February, 20 ppb; March, 24 ppb; and September, 46 ppb), 28AA30 (February, 50 ppb; March, 86 ppb; and September, 130 ppb), and 28AA31 (February, 330 ppb; March 240 ppb; and September, 140 ppb); vinyl chloride (PMCL is 2 ppb)—well 28AA29 (March, 3.6 ppb; and September, 4.4 ppb); 1,1-dichloroethene (PMCL is 7 ppb)—wells 28AA30 (March 10 ppb; and September, 17 ppb) and 28AA31 (February, 13 ppb; and March, 10 ppb); and 1,1,2-trichloroethane (PMCL is 5 ppb)—well 28AA30 (March, 33 ppb). Contaminant concentrations decreased in well 28AA31 from March to September 1999; however, concentrations still exceeded the PMCL. The concentrations for the following selected trace elements exceeding PMCL and the associated wells during the sampling periods February 1998, March 1999, and September 1999 are: mercury (PMCL is 2 ppb)—well 28AA24 (September, 2.82 ppb), well 28AA25 (February, 3.1 ppb; March, 2.11 ppb; and September, 2.28 ppb), and well 28AA30 (September, 2.82 ppb); arsenic (PMCL is 50 ppb)—well 28AA30 (February, 90 ppb; and September, 114 ppb); thallium (PMCL is 2 ppb)—wells 28AA27 (March, 2.08 ppb) and 28AA29 (February, 2.56); barium (PMCL is 2,000 ppb)—well 28AA30 (March, 4,490 ppb); chromium (PMCL is 30 ppb)—well 28AA30 (February, 630 ppb; and March, 1,190 ppb); and beryllium (PMCL is 4 ppb)—well 28AA30 (September, 6.3 ppb). Water from seven wells, three of which are upgradient of the landfill, contained organic compounds and/or selected trace elements exceeding PMCLs during the period February 1998 to September 1999 according to private consultants. Contaminants present in upgradient wells most likely were caused by chemical dispersion, leachate migration, incorrectly defined landfill area, or natural ground-water flow beneath the landfill.

Georgia↗
USGS1984

Ground-water quality in Wyoming

This report graphically summarizes ground-water quality from selected chemical-quality data for about 2,300 ground-water sites in Wyoming. Dissolved-solids, nitrate, fluoride, arsenic, barium, cadmium, chromium, lead, mercury, selenium, iron, and manganese concentrations are summarized on a statewide basis. The major chemical-quality problem that limits the use of Wyoming ground-water is excessive dissolved-solids concentrations. The aquifers with the best quality water, based on the lowest median dissolved-solids concentration of water in aquifers with 20 or more sampled sites, are Holocene lacustrine deposits, the upper Testiary Ogallala Formation and Arikaree Formation, and the Mississippian Madison Limestone. The counties with the best quality water, based on the lowest median dissolved-solids concentrations are Teton County and Laramie County. Hot Springs County and Natrona County have the highest median dissolved-solids concentrations. About 3 percent of the nitrate concentrations of ground-water samples exceeded the national primary drinking-water standard of 10 milligrams per liter. Fluoride concentrations exceeded the national primary drinking-water standard in 14 percent of the ground-water samples. Except for selenium, toxic trace elements generally have not been found in concentrations in excess of the drinking-water standards. About 19 percent of the iron and about 30 percent of the manganese concentrations in ground-water samples exceeded the national secondary drinking-water standards. (USGS)

Water-Resources Investigations Report↗
USGS2005

Chemical loading into surface water along a hydrological, biogeochemical, and land use gradient: A holistic watershed approach

Identifying the sources and impacts of organic and inorganic contaminants at the watershed scale is a complex challenge because of the multitude of processes occurring in time and space. Investigation of geochemical transformations requires a systematic evaluation of hydrologic, landscape, and anthropogenic factors. The 1160 km 2 Boulder Creek Watershed in the Colorado Front Range encompasses a gradient of geology, ecotypes, climate, and urbanization. Streamflow originates primarily as snowmelt and shows substantial annual variation. Water samples were collected along a 70-km transect during spring-runoff and base-flow conditions, and analyzed for major elements, trace elements, bulk organics, organic wastewater contaminants (OWCs), and pesticides. Major-element and trace-element concentrations were low in the headwaters, increased through the urban corridor, and had a step increase downstream from the first major wastewater treatment plant (WWTP). Boron, gadolinium, and lithium were useful inorganic tracers of anthropogenic inputs. Effluent from the WWTP accounted for as much as 75% of the flow in Boulder Creek and was the largest chemical input. Under both hydrological conditions, OWCs and pesticides were detected in Boulder Creek downstream from the WWTP outfall as well as in the headwater region, and loads of anthropogenic-derived contaminants increased as basin population density increased. This report documents a suite of potential endocrine-disrupting chemicals in a reach of stream with native fish populations showing indication of endocrine disruption.

Environmental Science & Technology↗
USGS2009

Estimation of sediment sources using selected chemical tracers in the Perry lake basin, Kansas, USA

The ability to achieve meaningful decreases in sediment loads to reservoirs requires a determination of the relative importance of sediment sources within the contributing basins. In an investigation of sources of fine-grained sediment (clay and silt) within the Perry Lake Basin in northeast Kansas, representative samples of channel-bank sources, surface-soil sources (cropland and grassland), and reservoir bottom sediment were collected, chemically analyzed, and compared. The samples were sieved to isolate the <63 ?? m fraction and analyzed for selected nutrients (total nitrogen and total phosphorus), organic and total carbon, 25 trace elements, and the radionuclide cesium-137 ( 137 Cs). On the basis of substantial and consistent compositional differences among the source types, total nitrogen (TN), total phosphorus (TP), total organic carbon (TOC), and 137 Cs were selected for use in the estimation of sediment sources. To further account for differences in particle-size composition between the sources and the reservoir bottom sediment, constituent ratio and clay-normalization techniques were used. Computed ratios included TOC to TN, TOC to TP, and TN to TP. Constituent concentrations (TN, TP, TOC) and activities ( 137 Cs) were normalized by dividing by the percentage of clay. Thus, the sediment-source estimations involved the use of seven sediment-source indicators. Within the Perry Lake Basin, the consensus of the seven indicators was that both channel-bank and surface-soil sources were important in the Atchison County Lake and Banner Creek Reservoir subbasins, whereas channel-bank sources were dominant in the Mission Lake subbasin. On the sole basis of 137 Cs activity, surface-soil sources contributed the most fine-grained sediment to Atchison County Lake, and channel-bank sources contributed the most fine-grained sediment to Banner Creek Reservoir and Mission Lake. Both the seven-indicator consensus and 137 Cs indicated that channel-bank sources were dominant for Perry Lake and that channel-bank sources increased in importance with distance downstream in the basin. ?? 2009 International Research and Training Centre on Erosion and Sedimentation and the World Association for Sedimentation and Erosion Research.

International Journal of Sediment Research↗
USGS2008

Quality of water and sediment in streams affected by historical mining, and quality of Mine Tailings, in the Rio Grande/Rio Bravo Basin, Big Bend Area of the United States and Mexico, August 2002

The U.S. Geological Survey, in cooperation with the International Boundary and Water Commission - U.S. and Mexican Sections, the National Park Service, the Texas Commission on Environmental Quality, the Secretaria de Medio Ambiente y Recursos Naturales in Mexico, the Area de Proteccion de Flora y Fauna Canon de Santa Elena in Mexico, and the Area de Proteccion de Flora y Fauna Maderas del Carmen in Mexico, collected samples of stream water, streambed sediment, and mine tailings during August 2002 for a study to determine whether trace elements from abandoned mines in the area in and around Big Bend National Park have affected the water and sediment quality in the Rio Grande/Rio Bravo Basin of the United States and Mexico. Samples were collected from eight sites on the main stem of the Rio Grande/Rio Bravo, four Rio Grande/Rio Bravo tributary sites downstream from abandoned mines or mine-tailing sites, and 11 mine-tailing sites. Mines in the area were operated to produce fluorite, germanium, iron, lead, mercury, silver, and zinc during the late 1800s through at least the late 1970s. Moderate (relatively neutral) pHs in stream-water samples collected at the 12 Rio Grande/Rio Bravo main-stem and tributary sites indicate that water is well mixed, diluted, and buffered with respect to the solubility of trace elements. The highest sulfate concentrations were in water samples from tributaries draining the Terlingua mining district. Only the sample from the Rough Run Draw site exceeded the Texas Surface Water Quality Standards general-use protection criterion for sulfate. All chloride and dissolved solids concentrations in water samples were less than the general-use protection criteria. Aluminum, copper, mercury, nickel, selenium, and zinc were detected in all water samples for which each element was analyzed. Cadmium, chromium, and lead were detected in samples less frequently, and silver was not detected in any of the samples. None of the sample concentrations of aluminum, cadmium, chromium, nickel, selenium, and zinc exceeded the Texas Surface Water Quality Standards criteria for aquatic life-use protection or human health. The only trace elements detected in the water samples at concentrations exceeding the Texas Surface Water Quality Standards criterion for human health (fish consumption use) was lead at one site and mercury at 10 of 12 sites. Relatively high mercury concentrations distributed throughout the area might indicate sources of mercury in addition to abandoned mining areas. Streambed-sediment samples were collected from 12 sites and analyzed for 44 major and trace elements. In general, the trace elements detected in streambed-sediment samples were low in concentration, interpreted as consistent with background concentrations. Concentrations at two sites, however, were elevated compared to Texas Commission on Environmental Quality criteria. Concentrations of antimony, arsenic, cadmium, lead, silver, and zinc in the sample from San Carlos Creek downstream from La Esperanza (San Carlos) Mine exceeded the Texas Commission on Environmental Quality screening levels for sediment. The sample from Rough Run Draw, downstream from the Study Butte Mine, also showed elevated concentrations of arsenic, cadmium, and lead, but these concentrations were much lower than those in the San Carlos Creek sample and did not exceed screening levels. Elevated concentrations of multiple trace elements in streambed-sediment samples from San Carlos Creek and Rough Run Draw indicate that San Carlos Creek, and probably Rough Run Draw, have been adversely affected by mining activities. Fourteen mine-tailing samples from 11 mines were analyzed for 25 major and trace elements. All trace elements except selenium and thallium were detected in one or more samples. The highest lead concentrations were detected in tailings samples from the Boquillas, Puerto Rico, La Esperanza (San Carlos), and Tres Marias Mines, as might be expected because the tailings ar

Scientific Investigations Report↗
USGS2024

An evaluation of fin ray microchemistry to describe movement of White Sturgeon in the Kootenai River basin: Insights and limitations

Introduction: White Sturgeon Acipenser transmontanus in the Kootenai River basin is listed as endangered in the United States and Canada. Declines have been mainly attributed to poor recruitment exacerbated by the environmental effects of Libby Dam in Montana. Reduced primary production downstream of Libby Dam has been identified as one factor limiting growth of White Sturgeon, thereby limiting natural reproduction through delayed sexual maturity. However, estimating changes in growth over time without knowledge of fish location (i.e., Kootenai River vs. Kootenay Lake) is difficult. The objective of this project was to use microchemistry analysis to describe the movement of White Sturgeon within the Kootenai River basin. Methods: Water samples ( n = 27) and White Sturgeon fin rays ( n = 162) collected in the Kootenai River basin were measured for strontium isotope ( 87 Sr: 86 Sr) ratios using laser ablation multicollector inductively coupled plasma mass spectrometry. All water samples and a subset of fin rays ( n = 8) were also analyzed for trace elements (e.g., Sr, Ba, Mg). Fin ray annuli were measured and tested using knowledge of known age; known locations from physical capture events were assigned to age at capture. Results: Strontium isotope analysis was unable to detect differences in the Kootenai River and Kootenay Lake using water or fin ray samples. The Kootenai River and Kootenay Lake were distinguishable using trace element data from water samples, but not fin rays. The discrepancy with trace elements appears to be associated with the physiology of fin ray growth. Discussion: Although this study did not meet its original objective of describing the movement of White Sturgeon in the Kootenai River basin from fin ray microchemistry, our results provide insight into the potential influence of physiology on microchemistry analysis. In particular, fin ray microchemistry of slow-growing fishes may be possible in freshwater systems with further investigation into the physiological processes associated with growth and the incorporation of elements into calcified structures.

British Columbia, Idaho, Montana↗
USGS1990

Water-resources potential of the freshwater lens at Key West, Florida

The island of Key West lies at the end of the Florida Keys, about 150 miles southwest of Miami. The public-water supply for the island is provided by the Florida Keys Aqueduct Authority Well Field near Miami. However, there are many privately owned wells on the island that tap the local fresh ground-water lens for potable and nonpotable water supply. The number of people who use water from the wells for drinking purposes is unknown. From 1985 to 1988, the U.S. Geological Survey, in cooperation with the South Florida Water Management District, conducted an investigation to characterize the Key West freshwater lens. Observation wells were drilled to determine the extent of the lens and to characterize the water quality. Previous well logs and well-core data collected during the investigation showed the aquifer to be a highly permeable, porous, solution-riddled, oolitic limestone that allows rainfall recharge to quickly seep into the ocean and saltwater to easily intrude the aquifer. The small freshwater lens (250 milligrams per liter of chloride concentration, or less) averages 5 feet in thickness below the center of the western half (Old Town) of the island. The lens contains about 20 million gallons of fresh-water during the dry season and about 30 million gallons during the wet season. Underlying the freshwater lens is a transition zone of freshwater-saltwater mix that extends to the saltwater interface (19,000 milligrams per liter of chloride concentration), which is about 40-feet deep at the center of the lens. The water table fluctuates and the configuration of the lens constantly changes, largely as a result of tidal effects. Other events, such as rainfall, pumping, and evapotranspiration, are masked by the tidal effects. The freshwater lens is a calcium bicarbonate water that grades to a sodium chloride type near the saltwater interface. Elevated concentrations of nitrate nitrogen were found in water samples from wells in the Old Town district. However, concentrations generally were not above the maximum contaminant level of 10 milligrams per liter for drinking water established by the Florida Department of Environmental Regulation. Water samples near an old land-fill in the eastern half of the island had concentrations of iron (600-1,900 micrograms per liter) and lead (40-800 micrograms per liter) that extended maximum contaminant levels of 300 and 50 micrograms per liter. These trace-element concentrations generally decreased with distance from the landfill. Although the freshwater lens is a potential source of water for additional nonpotable water needs in Key West, any large-scale pumping could quickly exhaust the freshwater lens, and saline water could be rapidly drawn though the porous limestone aquifer. Water-quality data indicate that the lens is an unlikely source of potable water.

Florida↗
USGS1979

Water quality of selected streams in the coal area of east-central Montana

In October 1975 the U.S. Geological Survey established a network of nine data-collection stations on eight streams in Montana to monitor water quality in potential coal-mining areas. The report summarizes and evaluates the water-quality data that have been collected during the first 2 years (3 years for 1 station) of network operation. Big Dry Creek, Little Dry Creek, Timber Creek , and Nelson Creek are the principal streams forming the Big Dry Creek basin, which is tributary to the Missouri River. These streams all contain water of the sodium sulfate type. Concentrations were high for dissolved solids (433-4,570 mg/L) and generally low for nutrients and trace elements. Prairie Elk Creek, Sand Creek, and the Redwater River flow directly into the Missouri River. Prairie Elk and Sand Creeks have mainly sodium bicarbonate water, whereas the Redwater River is predominately sodium sulfate water. All three streams contained water of high dissolved-solids concentration (160-3,370 mg/L) and generally low nutrient and trace-element concentrations. Burns Creek is tributary to the Yellowstone River. The water type is generally sodium sulfate during the spring and summer and sodium bicarbonate during the fall and winter. Water from Burns Creek ranged from 382 to 1,420 mg/L dissolved solids. (Woodard-USGS)

Montana↗
USGS2004

Mercury and Methylmercury concentrations and loads in Cache Creek Basin, California, January 2000 through May 2001

Concentrations and mass loads of total mercury and methylmercury in streams draining abandoned mercury mines and near geothermal discharge in Cache Creek Basin, California, were measured during a 17-month period from January 2000 through May 2001. Rainfall and runoff averages during the study period were lower than long-term averages. Mass loads of mercury and methylmercury from upstream sources to downstream receiving waters, such as San Francisco Bay, were generally the highest during or after winter rainfall events. During the study period, mass loads of mercury and methylmercury from geothermal sources tended to be greater than those from abandoned mining areas because of a lack of large precipitation events capable of mobilizing significant amounts of either mercury-laden sediment or dissolved mercury and methylmercury from mine waste. Streambed sediments of Cache Creek are a source of mercury and methylmercury to downstream receiving bodies of water such as the Delta of the San Joaquin and Sacramento Rivers. Much of the mercury in these sediments was deposited over the last 150 years by erosion and stream discharge from abandoned mines or by continuous discharges from geothermal areas. Several geochemical constituents were useful as natural tracers for mining and geothermal areas. These constituents included aqueous concentrations of boron, chloride, lithium, and sulfate, and the stable isotopes of hydrogen and oxygen in water. Stable isotopes of water in areas draining geothermal discharges were enriched with more oxygen-18 relative to oxygen-16 than meteoric waters, whereas the enrichment by stable isotopes of water from much of the runoff from abandoned mines was similar to that of meteoric water. Geochemical signatures from stable isotopes and trace-element concentrations may be useful as tracers of total mercury or methylmercury from specific locations; however, mercury and methylmercury are not conservatively transported. A distinct mixing trend of trace elements and stable isotopes of hydrogen and oxygen from geothermal waters was apparent in Sulphur Creek and lower Bear Creek (tributaries to Cache Creek), but the signals are lost upon mixing with Cache Creek because of dilution.

Scientific Investigations Report↗
USGS2024

Onset and tempo of ignimbrite flare-up volcanism in the eastern and central Mogollon-Datil volcanic field, southern New Mexico, USA

The Cenozoic ignimbrite flare-up (40–18 Ma) generated multiple volcanic fields in the southwestern United States and northern Mexico resulting from asthenospheric mantle upwelling after removal of the Farallon slab. The correlation of tuffs to one another and to source calderas within these volcanic fields is essential for determining spatiotemporal patterns in volcanism and magma geochemistry, which have been used to deduce migration of the Farallon slab at depth and associated mantle melting. However, the correlation of Eocene–Oligocene tuffs in the southwestern U.S. is difficult because of post-emplacement erosion and faulting. This study focuses on spatiotemporal patterns of the initial episode of ignimbrite flare-up activity (ca. 36.5–33.8 Ma) in the Mogollon-Datil volcanic field in south-central New Mexico, USA. We show that alkali feldspar major and trace element geochemistry is an effective tool for correlating tuffs when combined with high-precision, single-crystal 40 Ar/ 39 Ar geochronology and bulk-rock geochemistry. Using these data, we correlate several tuff units and differentiate other tuffs that have the same eruption age but very different geochemistry, and we conclude that there was a broadly northwestward migration in volcanism over time. The new tuff correlations are used to investigate spatiotemporal variations in magma geochemistry, erupted volumes, and recurrence intervals during the initial episode of Mogollon-Datil volcanic field volcanism. Early-erupted tuffs restricted to the eastern Mogollon-Datil volcanic field share similarities with western U.S. topaz rhyolites, which suggests that the silicic magmas were generated by partial melting of mafic lower crustal rocks. We also find differences in the compositions, crystallinities, and mineral assemblages between the early- and late-erupted tuffs. The early-erupted tuffs tend to have single-feldspar mineralogies, lower feldspar Or contents, large negative Eu anomalies, and low-whole–rock Ba concentrations. Conversely, late-erupted tuffs have two feldspar plus quartz assemblages, lesser Eu anomalies, higher whole-rock Ba concentrations, and feldspars have higher Or contents. Thus, we suggest that for some of the early eruptions, after magmas underwent crystal fractionation in the crust, the silicic melt largely separated from the crystalline mush prior to eruption, whereas late-erupted tuff magmas underwent crystal fractionation at near the eutectic minimum and were remobilized and erupted with a larger proportion of their crystalline mush. Using our new ages, correlations, and previously published data, we find that the initial phase of Mogollon-Datil volcanic field volcanism produced at least 15 eruptions between 36.5 Ma and 33.8 Ma, with a minimum total erupted volume of ~1350 km 3 and an average recurrence interval of 170 k.y. However, eruptions were generally smaller in volume (most <15 km 3 ) than in other coeval fields, and most eruptions (n = 11) occurred in the first 1.2 m.y. (ca. 36.5–35.3 Ma) of activity. Altogether, our work sheds new light on variations in the composition, timing, and migration of volcanism during the initial phase of Mogollon-Datil volcanic field activity and highlights the utility of feldspar geochemistry in both “fingerprinting” tuffs and elucidating magma evolution.

New Mexico↗
USGS2002

Chemical data for bottom sediment in Mountain Creek Lake, Dallas, Texas, 1999-2000

Mountain Creek Lake is a reservoir adjacent to the Naval Weapons Industrial Reserve Plant and the former Naval Air Station in Dallas, Texas. The U.S. Geological Survey began studies of water, sediment, and biota in the reservoir in 1994 after a Resource Conservation and Recovery Act Facility Investigation detected concentrations of organic chemicals on both facilities. Additional reservoir bottom sediment samples were collected during December 1999–January 2000 at the request of the Southern Division Naval Facilities Engineering Command to further define the occurrence and distribution of selected constituents and to supplement available data. The U.S. Geological Survey National Water Quality Laboratory analyzed bottom-sediment samples from 16 box cores and 5 gravity cores for major and trace elements, organochlorine pesticides, polychlorinated biphenyls, polycyclic aromatic hydrocarbons, grain size, and cesium-137.

Texas↗
USGS2021

Testing models of Laramide orogenic initiation by investigation of Late Cretaceous magmatic-tectonic evolution of the central Mojave sector of the California arc

The Mojave Desert region is in a critical position for assessing models of Laramide orogenesis, which is hypothesized to have initiated as one or more seamounts subducted beneath the Cretaceous continental margin. Geochronological and geochemical characteristics of Late Cretaceous magmatic products provide the opportunity to test the validity of Laramide orogenic models. Laramide-aged plutons are exposed along a transect across the Cordilleran Mesozoic magmatic system from Joshua Tree National Park in the Eastern Transverse Ranges eastward into the central Mojave Desert. A transect at latitude ∼33.5°N to 34.5°N includes: (1) the large upper-crustal Late Cretaceous Cadiz Valley batholith, (2) a thick section of Proterozoic to Jurassic host rocks, (3) Late Cretaceous stock to pluton-sized bodies at mesozonal depths, and (4) a Jurassic to Late Cretaceous midcrustal sheeted complex emplaced at ∼20 km depth that transitions into a migmatite complex truncated along the San Andreas fault. This magmatic section is structurally correlative with the Big Bear Lake intrusive suite in the San Bernardino Mountains and similar sheeted rocks recovered in the Cajon Pass Deep Scientific Drillhole. Zircon U-Pb geochronology of 12 samples via secondary ionization mass spectrometry (SIMS) (six from the Cadiz Valley batholith and six from the Cajon Pass Deep Scientific Drillhole) indicates that all Cretaceous igneous units investigated were intruded between 83 and 74 Ma, and Cajon Pass samples include a Jurassic age component. A compilation of new and published SIMS geochronological data demonstrates that voluminous magmatism in the Eastern Transverse Ranges and central Mojave Desert was continuous throughout the period suggested for the intersection and flat-slab subduction of the Shatsky Rise conjugate deep into the interior of western North America. Whole-rock major-element, trace-element, and isotope geochemistry data from samples from a suite of 106 igneous rocks represent the breadth of Late Cretaceous units in the transect. Geochemistry indicates an origin in a subduction environment and intrusion into a crust thick enough to generate residual garnet. The lack of significant deflections of compositional characteristics and isotopic ratios in igneous products through space and time argues against a delamination event prior to 74 Ma. We argue that Late Cretaceous plutonism from the Eastern Transverse Ranges to the central Mojave Desert represents subduction zone arc magmatism that persisted until ca. 74 Ma. This interpretation is inconsistent with the proposed timing of the docking of the Shatsky Rise conjugate with the margin of western North America, particularly models in which the leading edge of the Shatsky Rise was beneath Wyoming at 74 Ma. Alternatively, the timing of cessation of plutonism precedes the timing of the passage of the Hess Rise conjugate beneath western North America at ca. 70–65 Ma. The presence, geochemical composition, and age of arc products in the Eastern Transverse Ranges and central Mojave Desert region must be accounted for in any tectonic model of the transition from Sevier to Laramide orogenesis.

California↗
USGS1997

Element distribution patterns in the ordovician Galena group, Southeastern Minnesota: Indicators of fluid flow and provenance of terrigenous material

As part of a regional geochemical investigation of lower Paleozoic strata in the Hollandale embayment of southeastern Minnesota, elemental concentrations in acid-insoluble residues were determined for carbonate rock in the Middle Ordovician Galena Group. Elemental distribution patterns within the insoluble residues, particularly those of Ti, Al, and Zr, show that the Wisconsin dome and the Wisconsin arch, which contributed sediment to the embayment prior to Galena time, continued as weak sources of sediment during this period. In contrast, trace metals commonly associated with Mississippi Valley-type lead-zinc mineralization, including Pb, Zn, Cu, Ag, Ni, Co, As, and Mo, show dispersal patterns that are independent of those associated with primary depositional phenomena. These trace metals are concentrated in southern Minnesota in carbonate rocks near the interface between limestone- and dolostone-dominated strata. Dispersal patterns imply that the metals were carried by a north-flowing regional ground-water system. The results show that the geochemical attributes of insoluble residues can be used to distinguish provenance and transport directions of primary sediments within a depositional basin from effects of subsequent regional ground-water flow systems.

Economic Geology↗
USGS2022

Depth to water and water quality in groundwater wells in the Ogallala aquifer within the North Plains Groundwater Conservation District, Texas Panhandle, 2019–20, and comparison to 2012–13 conditions

The Ogallala aquifer is the primary source of water for agricultural and municipal purposes in the Texas Panhandle. Because most of the groundwater in the Texas Panhandle is withdrawn from the Ogallala aquifer, information on the quality of groundwater in the Ogallala aquifer in this part of Texas is useful for resource characterization. During 2012–13, the U.S. Geological Survey in cooperation with the North Plains Groundwater Conservation District (NPGCD), collected and analyzed water-quality samples from 30 groundwater monitoring wells in the Texas Panhandle. The results of the initial 2012–13 synoptic sampling were published in 2014 to help provide an initial characterization of the spatial and temporal variability of water quality in the NPGCD management area. This report documents the results of a followup synoptic sampling completed between March 2019 and July 2020 by the U.S. Geological Survey, in cooperation with the NPGCD, to further characterize the spatial and temporal characteristics of groundwater in the NPGCD management area; measurements of the depth to water, in feet below land surface, and water-quality samples were obtained from the same 30 monitoring wells that were sampled during 2012–13. The water-quality samples were analyzed for major ions, nutrients, trace elements, and selected organic compounds. Results from the 2019–20 synoptic sampling were compared to drinking-water standards and to the results from the 2012–13 synoptic sampling. Between the 2012–13 and 2019–20 sampling periods, the depth to water increased in 28 of the 30 wells, with a median difference of 18.17 feet. Results from major ion analyses indicate that most of the groundwater samples collected during 2019–20 were classified as magnesium-bicarbonate type, the same water type indicated for most samples during 2012–13. Dissolved-solids concentrations for the wells sampled during 2019–20 ranged from 260 to 774 milligrams per liter (mg/L) with a median dissolved-solids concentration of 316 mg/L, which was slightly higher than the median dissolved-solids concentration of 311 mg/L for the 2012–13 sampling period. Of the four nutrients analyzed, nitrate was the dominant nitrogen species, with a median nitrate concentration of 2.25 mg/L for the 2019–20 sampling period, which was a slight increase relative to the median nitrate concentration of 2.05 mg/L for the 2012–13 sampling period. Accounting for variability in analyses, median major ion concentrations and median concentrations for nutrient species were similar during the 2012–13 and 2019–20 sampling periods. None of the trace element concentrations exceeded any maximum contaminant level or secondary drinking-water standards. Median concentrations of trace elements from the 2012–13 sampling period were compared to those from the 2019–20 sampling period for constituents in cases where at least 50 percent of concentrations measured in the samples were detected at concentrations greater than the highest applicable laboratory reporting level, and variability in analyses was accounted for. Comparison results indicated that that median concentrations of two trace elements (lithium and uranium) increased, whereas median concentrations for two of the other trace elements measured (barium and molybdenum) decreased. Atrazine and deethylatrazine were the only organic compounds detected; both were detected in four of the six samples collected from different wells and analyzed for organic compounds. Concentrations of atrazine and deethylatrazine detections were all less than 0.05 micrograms per liter.

Texas↗
USGS1995

Water-quality assessment of the Kentucky River Basin, Kentucky: Distribution of metals and other trace elements in sediment and water, 1987-90

The U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program is designed to provide a nationally consistent description of the current status of water quality, to define water-quality trends, and to relate past and present water-quality conditions to natural features, uses of land and water, and other water-quality effects from human activities. The Kentucky River Basin is one of four NAWQA pilot projects that focused primarily on the quality of surface water. Water, sediment, and bedrock samples were collected in the Kentucky River Basin during 1987-90 for the purpose of (1) describing the spatial distribution, transport, and temporal variability of metals and other trace elements in streams of the basin; (2) estimating mean annual loads, yields, and trends of constituent concentrations and identifying potential causes (or sources) of spatial patterns; (3) providing baseline information for concentrations of metals in streambed and suspended sediments; (4) identifying stream reaches in the Kentucky River Basin with chronic water-quality problems; and (5) evaluating the merits of the NAWQA pilot study-approach for the assessment of metals and other trace elements in a river system. The spatial distribution of metals and other trace elements in streambed sediments of the Kentucky River Basin is associated with regional differences of geology, land use and cover, and the results of human activities. Median concentrations of constituents differed significantly among physiographic regions of the basin because of relations to bedrock geochemistry and land disturbance. Concentrations of potentially toxic metals were large in urban and industrial areas of the basin. Elevated concentrations of certain metals were also found in streambed sediments of the Knobs Region because of the presence of Devonian shale bedrock. Elevated concentrations of lead and zinc found in streambed sediments of the Bluegrass Region are likely associated with urban stormwater runoff, point-source discharges, and waste-management practices. Concentrations of cadmium, chromium, copper, mercury, and silver were elevated in streambed sediments downstream from wastewater-treatment plant discharges. Streambed-sediment concentrations of barium, chromium, and lithium were elevated in streams that receive brine discharges from oil production. Elevated concentrations of antimony, arsenic, molybdenum, selenium, strontium, uranium, and vanadium in streambed sediments of the Kentucky River Basin were generally associated with natural sources. Concentrations of metals and other trace elements in water samples from fixed stations (stations where water-quality samples were collected for 3.5 years) in the Kentucky River Basin were generally related to stream discharge and the concentration of suspended sediment, whereas constituent concentrations in the suspended-sediment matrix were indicative of natural and human sources. Estimated mean annual loads and yields for most metals and other trace elements were associated with the transport of suspended sediment. Land disturbance, such as surface mining and agriculture, contribute to increased transport of sediment in streams, thereby increasing concentrations of metals in water samples during periods of intense or prolonged rainfall and increased stream discharge. Concentrations of many metals and trace elements were reduced during low streamflow. Although total-recoverable and dissolved concentrations of certain metals and trace elements were large in streams affected by land disturbance, concentrations of constituents in the suspendedsediment matrix were commonly large in streams in the Knobs and Eastern Coal Field Regions (because of relations with bedrock geochemistry) and in streams that receive wastewater or oil-well-brine discharges. Concentrations and mean annual load estimates for aluminum, chromium, copper, iron, lead, manganese, and mercury were larger than those obtained from data collected by a State agency, probably because of differences in sample-collection methodology, the range of discharge associated with water-quality samples, and laboratory analytical procedures. However, concentrations, loads, and yields of arsenic, barium, and zinc were similar to those determined from the State data. Significant upward trends in the concentrations of aluminum, iron, magnesium, manganese, and zinc were indicated at one or more fixed stations in the Kentucky River Basin during the past 10 to 15 years. Upward trends for concentrations of aluminum, iron, and manganese were found at sites that receive drainage from coal mines in the upper Kentucky River Basin, whereas upward trends for zinc may be associated with urban sources. Water-quality criteria established by the U.S. Environmental Protection Agency (USEPA) or the State of Kentucky for concentrations of aluminum, beryllium, cadmium, chromium, copper, iron, manganese, nickel, silver, and zinc were exceeded at one or more fixed stations in the Kentucky River Basin. On a qualitative basis, dissolved concentrations of certain metals and trace elements were large during low streamflow at sites where (1) concentrations of these constituents in underlying streambed sediments were large, or (2) dissolvedoxygen concentrations were small. Concentrations of barium, lithium, and strontium were large during low streamflow, which indicates the influence of ground-water baseflows on the quality of surface water during low flow. The effects of point-source discharges, landfills, and other wastemanagement practices are somewhat localized in the Kentucky River Basin and are best indicated by the spatial distribution of metals and other trace elements in streambed sediments and in the suspended-sediment fraction of water samples at stream locations near the source. It was not possible to quantify the contribution of point sources to the total transport of metals and other trace elements at fixed stations because data were not available for wastewater effluents. Quantification of baseline concentrations of metals and other trace elements in streambed sediments provides a basis for the detection of water-quality changes that may result from improvements in wastewater treatment or the implementation of best-management practices for controlling contamination from nonpoint sources in the Kentucky River Basin.

Kentucky↗
USGS1995

Quality of water and chemistry of bottom sediment in the Rillito Creek basin, Tucson, Arizona, 1992-93

Physical and chemical data were collected from four surface-water sites, six ground-water sites, and two bottom-sediment sites during 1992-93. Specific conductance, hardness, alkalinity, and dissolved- solids concentrations generally were higher in ground water than in surface water. The median concentrations of dissolved major ions, with the exception of potassium, were higher in ground water than in surface water. In surface water and ground water, calcium was the dominant cation, and bicarbonate was the dominant anion. Concentrations of dissolved nitrite and nitrite plus nitrate in surface water and ground water did not exceed the U.S. Environmental Protection Agency maximum contaminant levels of 1 and 10 milligrams per liter for drinking water, respectively. Ammonium plus organic nitrogen in bottom sediment was detected at the highest concentration of any nitrogen species. Median values for most of the dissolved trace elements in surface water and ground water were below the detection levels. Dissolved trace elements in surface water and ground water did not exceed the U.S. Environmental Protection Agency maximum contaminant levels for drinking water. Trace-element concentrations in bottom sediment were similar to trace-element concentrations reported for soils of the western conterminous United States. Several organochlorine pesticides and priority pollutants were detected in surface-water and bottom-sediment samples; however, they did not exceed water-quality standards. Pesticides or priority pollutants were not detected in ground-water samples.

Water-Resources Investigations Report↗