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Groundwater ages and mixing in the Piceance Basin natural gas province, Colorado

Reliably identifying the effects of energy development on groundwater quality can be difficult because baseline assessments of water quality completed before the onset of energy development are rare and because interactions between hydrocarbon reservoirs and aquifers can be complex, involving both natural and human processes. Groundwater age and mixing data can strengthen interpretations of monitoring data from those areas by providing better understanding of the groundwater flow systems. Chemical, isotopic, and age tracers were used to characterize groundwater ages and mixing with deeper saline water in three areas of the Piceance Basin natural gas province. The data revealed a complex array of groundwater ages (<10 to >50,000 years) and mixing patterns in the basin that helped explain concentrations and sources of methane in groundwater. Age and mixing data also can strengthen the design of monitoring programs by providing information on time scales at which water quality changes in aquifers might be expected to occur. This information could be used to establish maximum allowable distances of monitoring wells from energy development activity and the appropriate duration of monitoring.

Colorado

Weather and landscape factors affect white-tailed deer neonate survival at ecologically important life stages in the Northern Great Plains

Offspring survival is generally more variable than adult survival and may limit population growth. Although white-tailed deer neonate survival has been intensively investigated, recent work has emphasized how specific cover types influence neonate survival at local scales (single study area). These localized investigations have often led to inconsistences within the literature. Developing specific hypotheses describing the relationships among environmental, habitat, and landscape factors influencing white-tailed deer neonate survival at regional scales may allow for detection of generalized patterns. Therefore, we developed 11 hypotheses representing the various effects of environmental (e.g., winter and spring weather), habitat (e.g., hiding and escape cover types), and landscape factors (e.g., landscape configuration regardless of specific cover type available) on white-tailed deer neonate survival up to one-month and from one- to three-months of age. At one-month, surviving fawns experienced a warmer lowest recorded June temperature and more June precipitation than those that perished. At three-months, patch connectance (percent of patches of the corresponding patch type that are connected within a predefined distance) positively influenced survival. Our results are consistent with white-tailed deer neonate ecology: increased spring temperature and precipitation are likely associated with a flush of nutritional resources available to the mother, promoting increased lactation efficiency and neonate growth early in life. In contrast, reduced spring temperature with increased precipitation place neonates at risk to hypothermia. Increased patch connectance likely reflects increased escape cover available within a neonate’s home range after they are able to flee from predators. If suitable escape cover is available on the landscape, then managers could focus efforts towards manipulating landscape configuration (patch connectance) to promote increased neonate survival while monitoring spring weather to assess potential influences on current year survival.

Minnesota, North Dakota, South Dakota

Cryptic invasion of Northern Leopard Frogs ( Rana pipiens ) across phylogeographic boundaries and a dilemma for conservation of a declining amphibian

Anthropogenic introduction of species is a major contributor to loss of biodiversity. Translocations within the range of a species are less frequently recognized, but have the potential for negative effects as well. Genetic mixing may lead to loss of local adaptations or further decline through outbreeding depression. These cryptic invasions may be quite difficult to recognize, but genetic tools can be used to recognize and monitor such intraspecific introductions. Conversely, translocations within species can be an important conservation tool to reduce inbreeding depression and replace lost genetic diversity. Thus, cryptic invasions can be either an aid or a hindrance to conservation efforts. We tested for the presence of non-native genotypes and assessed the extent and nature of introgression in populations of Northern Leopard Frog ( Rana pipiens ) in the southwestern US, where populations have declined to a few remnant populations. The most abundant and diverse complex of populations in the region contained a mitochondrial haplotype that was not native to the western US, probably resulting from the introduction of released pets, laboratory animals, or release during fish stocking. These non-native haplotypes were well integrated into a large complex of ponds and lakes, contributing to high genetic diversity in this area. Logistically, the geographic extent of non-native genetic influence within this population precludes eliminating or controlling the non-native component of this population. We recommend assessing the progress and fate of the introgression over time—along with population fitness parameters—to determine whether this introduction is beneficial or detrimental to population persistence. Meanwhile, translocations from nearby locations with similar environmental conditions have the best prospects for avoiding problems with outbreeding depression in other declining populations and will also most effectively preserve regional genetic diversity.

Biological Invasions

Modulators of mercury risk to wildlife and humans in the context of rapid global change

Environmental mercury (Hg) contamination is an urgent global health threat. The complexity of Hg in the environment can hinder accurate determination of ecological and human health risks, particularly within the context of the rapid global changes that are altering many ecological processes, socioeconomic patterns, and other factors like infectious disease incidence, which can affect Hg exposures and health outcomes. However, the success of global Hg-reduction efforts depends on accurate assessments of their effectiveness in reducing health risks. In this paper, we examine the role that key extrinsic and intrinsic drivers play on several aspects of Hg risk to humans and organisms in the environment. We do so within three key domains of ecological and human health risk. First, we examine how extrinsic global change drivers influence pathways of Hg bioaccumulation and biomagnification through food webs. Next, we describe how extrinsic socioeconomic drivers at a global scale, and intrinsic individual-level drivers, influence human Hg exposure. Finally, we address how the adverse health effects of Hg in humans and wildlife are modulated by a range of extrinsic and intrinsic drivers within the context of rapid global change. Incorporating components of these three domains into research and monitoring will facilitate a more holistic understanding of how ecological and societal drivers interact to influence Hg health risks.

Ambio

Constraints on mechanisms for the growth of gully alcoves in Gasa crater, Mars, from two-dimensional stability assessments of rock slopes

The value of slope stability analyses for gaining insight into the geologic conditions that would facilitate the growth of gully alcoves on Mars is demonstrated in Gasa crater. Two-dimensional limit equilibrium methods are used in conjunction with high-resolution topography derived from stereo High Resolution Imaging Science Experiment (HiRISE) imagery. These analyses reveal three conditions that may produce observed alcove morphologies through slope failure: (1) a ca. >10 m thick surface layer that is either saturated with H 2 O ground ice or contains no groundwater/ice at all, above a zone of melting H 2 O ice or groundwater and under dynamic loading (i.e., seismicity), (2) a 1–10 m thick surface layer that is saturated with either melting H 2 O ice or groundwater and under dynamic loading, or (3) a >100 m thick surface layer that is saturated with either melting H 2 O ice or groundwater and under static loading. This finding of three plausible scenarios for slope failure demonstrates how the triggering mechanisms and characteristics of future alcove growth would be affected by prevailing environmental conditions. HiRISE images also reveal normal faults and other fractures tangential to the crowns of some gully alcoves that are interpreted to be the result of slope instability, which may facilitate future slope movement. Stability analyses show that the most failure-prone slopes in this area are found in alcoves that are adjacent to crown fractures. Accordingly, crown fractures appear to be a useful indicator of those alcoves that should be monitored for future landslide activity.

Icarus

Burn severity controls on postfire Araucaria‐Nothofagus regeneration in the Andean Cordillera

Aim The aim of the study was to investigate postfire regeneration patterns of Araucaria‐Nothofagus forests on the west slope of the Andes; to evaluate the relationship between remotely sensed burn severity and forest mortality; and to assess controls of burn severity on forest response at local spatio‐temporal scales. Location Araucanía region in the western Andean Range of south‐central Chile where fire occurred during the 2001–2002 season. Methods Sampling of prefire stand structure and postfire vegetation response was performed along a burn severity gradient a decade after the fire. We evaluated the relationship between field‐measured tree mortality and satellite‐derived burn severity using a generalized linear model. We fit zero‐inflated mixture models to regeneration data of each genus to assess the importance of abiotic variables, stand characteristics, and biotic interactions. Results The relative version of the delta Normalized Burn Ratio explained 85% of the variability in canopy mortality. Nearly 12,000 hectares burned; the majority at high severity (67%). Regeneration densities of both genera were lower at higher levels of burn severity and higher with greater total basal area (live, dead, and down trees). The relative effect size of burn severity on regeneration was nearly twice as large for Nothofagus , which suggests information legacies of Araucaria have cascading effects on postdisturbance material legacies. Main conclusions Araucaria‐Nothofagus mortality from wildfire can be readily mapped using satellite‐derived burn severity. Although environmental site characteristics and biotic interactions mediate regeneration, basal area, and burn severity are the main mechanisms controlling regeneration. Forest refugia and postfire regeneration are vulnerable to recurrent fire. Therefore, we expect future fire (either increased severity or frequency), driven by landscape level changes, as a potential mechanism that can reduce local resilience of these forests as initial postfire material legacies (e.g., refugia and regeneration) are removed from the landscape. Our findings highlight an approach to quantify important attributes of forest disturbance and refugia, and identify areas for monitoring postdisturbance regeneration as the forests throughout south‐central Chile and Argentina face a multitude of potential change agents.

Journal of Biogeography

The 3D Elevation Program and energy for the Nation

High-resolution light detection and ranging (lidar) data are used in energy infrastructure siting, design, permitting, construction, and monitoring to promote public safety through the reduction of risks. For example, lidar data are used to identify safe locations for energy infrastructure by analyzing terrain parameters and identifying and evaluating geologic hazards (for example, landslide and fault locations) and their potential public safety effects on the location or design of infrastructure. Increasingly, engineering companies and regulatory agencies are using lidar and other remote sensing techniques as an efficient method to collect accurate, comprehensive data while reducing risks to field personnel. The U.S. Geological Survey (USGS) 3D Elevation Program (3DEP) is collecting lidar data nationwide (interferometric synthetic aperture radar [IfSAR] data in Alaska) to support a wide range of applications, including projects related to energy infrastructure construction and safety. Renewable energy resources, resource mining, and oil and gas resources were identified by the National Enhanced Elevation Assessment as business uses requiring three-dimensional (3D) elevation data. Elevation data are critical in assessing potential sites for energy infrastructure, such as pipelines, refineries and other facilities, to mitigate risks from natural hazards. For example, the Federal Energy Regulatory Commission (FERC), an independent agency that regulates the interstate transmission of electricity, natural gas, and oil, uses enhanced elevation data to conduct National Environmental Policy Act (NEPA) compliance assessments. The acquisition of high-resolution lidar data by the USGS 3DEP initiative helps the FERC and NEPA permit applicants by providing accurate and consistent data for hazards analysis. The use of these data accelerates the application and review process and avoids the much higher costs of acquiring elevation data along proposed energy facility locations and pipeline corridors.

Fact Sheet

Energetic status and bioelectrical impedance modeling of Arctic grayling Thymallus arcticus in interior Alaska Rivers

The energetic status of fishes represents energy stored as protein and lipids and reflects the ability of an individual to reproduce, migrate, and transition through life stages, ultimately influencing survival. However, traditional measurement methods, while highly accurate, are time consuming, expensive, and lethal, and nonlethal methods such as condition factor may not adequately characterize energetic status. We collected 161 Arctic grayling ( Thymallus arcticus ) from four interior Alaska river basins with varying hydrologic regimes during early summer and autumn seasons, and used multiple regression and model selection to evaluate the efficacy of bioelectrical impedance analysis (BIA), a nonlethal condition assessment method, to predict percent dry mass and percent lipid content estimated from proximate analysis. We found that Arctic grayling energetic status varied across seasons, by sex, and fish from sites with spawning runs of Pacific salmon had higher energy content than those from sites without salmon, potentially due to the influence of salmon-derived food subsidies. Electrical measurements explained 82% and 80% of the variability in percent dry mass and percent total lipids, respectively, and top models showed high predictive performance (observed vs. predicted root mean squared error ≤2.2%). Overall, we found the BIA approach to provide rapid, precise, and non-lethal estimates of Arctic grayling body condition. Such an approach may be useful for future work to characterize Arctic grayling bioenergetics and monitor fish condition under a rapidly changing Arctic environment.

Alaska

Occurrence and removal of pharmaceutically active compounds in sewage treatment plants with different technologies

Occurrence of eight selected pharmaceutically active compounds (PhACs; caffeine, carbamazepine, triclosan, gemfibrozil, diclofenac, ibuprofen, ketoprofen and naproxen) were investigated in effluents from fifteen sewage treatment plants (STPs) across South Australia. In addition, a detailed investigation into the removal of these compounds was also carried out in four STPs with different technologies (Plant A: conventional activated sludge; plant B: two oxidation ditches; plant C: three bioreactors; and plant D: ten lagoons in series). The concentrations of these compounds in the effluents from the fifteen STPs showed substantial variations among the STPs, with their median concentrations ranging from 26 ng/L for caffeine to 710 ng/L for carbamazepine. Risk assessment based on the "worst case scenario" of the monitoring data from the present study suggested potential toxic risks to aquatic organisms posed by carbamazepine, triclosan and diclofenac associated with such effluent discharge. With the exception of carbamazepine and gemfibrozil, significant concentration decreases between influent and effluent were observed in the four STPs studied in more detail. Biodegradation was found to be the main mechanism for removing concentrations from the liquid waste stream for the PhACs within the four STPs, while adsorption onto sludge appeared to be a minor process for all target PhACs except for triclosan. Some compounds ( e.g. gemfibrozil) exhibited variable removal efficiencies within the four STPs. Plant D (10 lagoons in series) was least efficient in the removal of the target PhACs; significant biodegradation of these compounds only occurred from the sixth or seventh lagoon.

Journal of Environmental Monitoring

Water quality and ecological condition of urban streams in Independence, Missouri, June 2005 through December 2008

To identify the sources of selected constituents in urban streams and better understand processes affecting water quality and their effects on the ecological condition of urban streams and the Little Blue River in Independence, Missouri the U.S. Geological Survey in cooperation with the City of Independence Water Pollution Control Department initiated a study in June 2005 to characterize water quality and evaluate the ecological condition of streams within Independence. Base-flow and stormflow samples collected from five sites within Independence, from June 2005 to December 2008, were used to characterize the physical, chemical, and biologic effects of storm runoff on the water quality in Independence streams and the Little Blue River. The streams draining Independence-Rock Creek, Sugar Creek, Mill Creek, Fire Prairie Creek, and the Little Blue River-drain to the north and the Missouri River. Two small predominantly urban streams, Crackerneck Creek [12.9-square kilometer (km2) basin] and Spring Branch Creek (25.4-km2 basin), were monitored that enter into the Little Blue River between upstream and downstream monitoring sites. The Little Blue River above the upstream site is regulated by several reservoirs, but streamflow is largely uncontrolled. The Little Blue River Basin encompasses 585 km2 with about 168 km2 or 29 percent of the basin lying within the city limits of Independence. Water-quality samples also were collected for Rock Creek (24.1-km2 basin) that drains the western part of Independence. Data collection included streamflow, physical properties, dissolved oxygen, chloride, metals, nutrients, common organic micro-constituents, and fecal indicator bacteria. Benthic macroinvertebrate community surveys and habitat assessments were conducted to establish a baseline for evaluating the ecological condition and health of streams within Independence. Additional dry-weather screenings during base flow of all streams draining Independence were conducted to identify point-source discharges and other sources of potential contamination. Regression models were used to estimate continuous and annual flow-weighted concentrations, loadings, and yields for chloride, total nitrogen, total phosphorus, suspended sediment, and Escherichia coli bacteria densities. Base-flow and stormflow water-quality samples were collected at five sites within Independence. Base-flow samples for Rock Creek and two tributary streams to the Little Blue River exceeded recommended U.S. Environmental Protection Agency standards for the protection of aquatic life for total nitrogen and total phosphorus in about 90 percent of samples, whereas samples collected at two Little Blue River sites exceeded both the total nitrogen and total phosphorus standards less often, about 30 percent of the time. Dry-weather screening identified a relatively small number (14.0 percent of all analyses) of potential point-source discharges for total chlorine, phenols, and anionic surfactants. Stormflow had larger median measured concentrations of total common organic micro-constituents than base flow. The four categories of common organic micro-constituents with the most total detections in stormflow were pesticides (100 percent), polyaromatic hydrocarbons and combustion by-products (99 percent), plastics (93 percent), and stimulants (91 percent). Most detections of common organic micro-constituents were less than 2 micrograms per liter. Median instantaneous Escherichia coli densities for stormflow samples showed a 21 percent increase measured at the downstream site on the Little Blue River from the sampled upstream site. Using microbial source-tracking methods, less than 30 percent of Escherichia coli bacteria in samples were identified as having human sources. Base-flow and stormflow data were used to develop regression equations with streamflow and continuous water-quality data to estimate daily concentrations, loads, and yields of various water-quality contaminants.

Scientific Investigations Report

Concentration data for anthropogenic organic compounds in groundwater, surface water, and finished water of selected community water systems in the United States, 2002-10

The National Water-Quality Assessment Program of the U.S. Geological Survey began implementing Source Water-Quality Assessments (SWQAs) in 2001 that focus on characterizing the quality of source water and finished water of aquifers and major rivers used by some of the larger community water systems in the United States. As used in SWQA studies, source water is the raw (ambient) water collected at the supply well before water treatment (for groundwater) or the raw (ambient) water collected from the river near the intake (for surface water), and finished water is the water that has been treated and is ready to be delivered to consumers. Finished-water samples are collected before the water enters the distribution system. The primary objective of SWQAs is to determine the occurrence of more than 250 anthropogenic organic compounds in source water used by community water systems, many of which currently are unregulated in drinking water by the U.S. Environmental Protection Agency. A secondary objective is to understand recurrence patterns in source water and determine if these patterns also occur in finished water before distribution. SWQA studies were conducted in two phases for most studies completed by 2005, and in one phase for most studies completed since 2005. Analytical results are reported for a total of 295 different anthropogenic organic compounds monitored in source-water and finished-water samples collected during 2002-10. The 295 compounds were classified according to the following 13 primary use or source groups: (1) disinfection by-products; (2) fumigant-related compounds; (3) fungicides; (4) gasoline hydrocarbons, oxygenates, and oxygenate degradates; (5) herbicides and herbicide degradates; (6) insecticides and insecticide degradates; (7) manufacturing additives; (8) organic synthesis compounds; (9) pavement- and combustion-derived compounds; (10) personal-care and domestic-use products; (11) plant- or animal-derived biochemicals; (12) refrigerants and propellants; and (13) solvents. This report presents the analytical results of source- water samples from 448 community water system wells and 21 surface-water sites. This report also presents the analytical results of finished-water samples from 285 wells and 20 surface-water sites from community water systems. Results of quality-assurance/quality-control samples also are presented including data for equipment blanks, field blanks, source solution blanks, and replicate samples.

Data Series

Vascular Plant and Vertebrate Inventory of Saguaro National Park, Tucson Mountain District

This report summarizes the results of the first comprehensive inventory of plants and vertebrates at the Tucson Mountain District (TMD) of Saguaro National Park, Arizona. From 2001 to 2003 we surveyed for vascular plants and vertebrates (amphibians, reptiles, birds, and mammals) at the district to document the presence of species within its boundaries. Park staff also carried out extensive infrared-triggered camera work for medium and large mammals from 2002-2005 and results from that effort are reported here. Our spatial sampling design for all taxa employed a combination of random and nonrandom survey sites. Survey effort was greatest for medium and large mammals and herpetofauna. Because we used repeatable study designs and standardized field methods, these inventories can serve as the first step in a biological monitoring program for the district. We also provide an overview of previous survey efforts in the district. We use data from our inventory and other surveys to compile species lists and to assess inventory completeness. The survey effort for herpetofauna, birds, and medium and large mammals was the most comprehensive ever undertaken in the district. We recorded a total of 320 plant and vertebrate species, including 21 species not previously found in the district (Table 1). Based on a review of our inventory and past research at the district, there have been a total of 723 species of plants and vertebrates found there. We believe inventories for most taxonomic groups are nearly complete. Based on our surveys, we believe the native plant and vertebrate community compositions of the district are relatively intact, though some species loss has occurred and threats are increasing, particularly to herpetofauna and larger mammals. Of particular note is the relatively small number of non-native species and their low abundance in the district, which is in contrast to many nearby natural areas. Rapidly expanding development on the west, north, and east sides of the district is cause for concern that the park continue its commitment to environmental restoration, which is largely responsible for reducing the threats posed by non-native plants. With continued maintenance of natural processes and the ecological structure of the park's biodiversity, the park will become an increasingly important place to both the general public and the scientific community. This report supersedes results reported in Powell et al. (2002, 2003).

Open-File Report

Escherichia coli monitoring and assessment in 2022 and 2023 after beach restoration at Lake St. Clair Metropark Beach, Macomb County, Michigan

Lake St. Clair Metropark Beach in Michigan has a history of closures because of elevated Escherichia coli ( E. coli ) concentrations in its recreational waters. To reduce closures, restoration projects were implemented in 2021 to deter waterfowl from congregating on the beach. In this study, the U.S. Geological Survey, in cooperation with the Michigan Department of the Environment, Great Lakes, and Energy and in collaboration with Huron-Clinton Metroparks and the Macomb County Health Department, monitored E. coli from 2022–23 in surface water, shallow groundwater, and sediment at Lake St. Clair Metropark Beach. Results were compared to data from a prerestoration (2018–19) study. A significant decrease in daily geometric mean E. coli concentrations in surface water was observed postrestoration, but the number of high concentration events increased. This resulted in more frequent beach closures postrestoration. Surface-sediment E. coli concentrations significantly decreased after restoration, and waterfowl populations generally decreased from 2021 to 2023, suggesting that the deterrence measures could be influencing E. coli concentrations in surface sediments and surface water. Groundwater E. coli concentrations were orders of magnitude higher than those in surface water and revealed no change correlated with restoration. Seepage measurements indicated that groundwater occasionally discharges into surface water, potentially providing a transport mechanism for E. coli to reach the lake. Continued monitoring and consideration of environmental factors could help to better understand the beach system.

Michigan

A foundation for future assessment and management of groundwater resources

Sequence stratigraphic models for the Pleistocene to Holocene sediments of the Los Angeles (LA) Basin will provide better understanding of regional groundwater flow and have helped identify seawater intrusion pathways into important groundwater aquifers. Because groundwater provides more than one-third of the municipal water supply for the coastal LA Basin, the aquifer architecture of this system is a high priority for groundwater managers. Seismic and sequence stratigraphy are now incorporated into groundwater resource assessments and environmental investigations. By evaluating subsurface data using sequence stratigraphy, the geometry and distribution of aquifer and aquitard sediments are defined, thus groundwater contaminant plumes and sea water intrusion pathways are better understood. The U. S. Geological Survey (USGS), in cooperation with Los Angeles County Department of Public Works and the Water Replenishment District of Southern California undertook an investigation of the groundwater stratigraphy of the Wilmington – Long Beach area of the LA Basin. Sequence stratigraphic methods were used to integrate preexisting groundwater well data with: (1) new borehole observations, (2) structural and physical properties data derived from geophysical measurements, (3) hi-resolution seismic reflection data obtained offshore of the present shoreline, and (4) vintage oil company exploration seismic reflection data from both onshore and offshore of the shoreline. These data were used to construct a series of Pleistocene to Holocene environment of deposition maps that show the overall progradation of sequences seaward over time. In addition, seawater intrusion pathways into coastal groundwater aquifers were identified and mapped. On a more regional scale, a vintage Texaco seismic reflection data set from the greater LA Basin was interpreted and integrated with a regional network of multi-level ground-water monitoring wells. The sequence stratigraphic correlation shows that many of the defined groundwater aquifers are not correlative. For example, one of the major groundwater supply aquifers, the Silverado Aquifer, when tied to the seismic reflection data has different ages depending on location. This new understanding demonstrates the need for a re-evaluation of the Pleistocene to Holocene stratigraphy using existing seismic reflection data integrated with well data from the LA Basin in order to understand the regional distribution of groundwater aquifers.

Conference Paper

Restoration is a partial but not complete solution for long-term declines in oyster populations—A case history from the northeastern Gulf of America

Objective We sought to evaluate whether oyster reef restoration is associated with sustained increases in intertidal eastern oyster Crassostrea virginica density in Suwannee Sound, Florida, and to examine how commercial fishing activity and freshwater discharge may modify those patterns. Methods We monitored intertidal oyster reefs for 14 years, including 9 years prior to large-scale restoration (completed in 2018) and 5 years of standardized postrestoration monitoring beginning in 2019 at Lone Cabbage Reef, an offshore intertidal reef complex that was rebuilt to target elevation using dolomite limestone. A Bayesian negative-binomial generalized linear mixed model framework estimated oyster densities while accounting for spatial differences among inshore, nearshore, and offshore reefs; variation in transect length; and temporal variability. We assessed restoration effectiveness via repeated-measures monitoring of fixed restored sites and landscape-scale comparisons of restored versus unrestored reefs. We evaluated covariates of management interest—commercial fishing activity and river discharge—using model comparison and posterior predictions of oyster density at observed covariate values. Results Restoration produced large per-area gains in live-oyster density on offshore reefs. At four fixed restored offshore stations, mean densities rose from near 0 to 91 oysters/m 2 (95% credible interval [CrI] = 43–185) within 6 months and reached 244 oysters/m 2 (95% CrI = 134–433) by year 5 at fixed restoration stations. At the broader landscape scale, restored offshore reefs averaged about 83 oysters/m 2 (95% CrI = 26–157) across sites and postrestoration periods, whereas model-based estimates for restored offshore reefs reached 218 oysters/m 2 (95% CrI = 128–366) in the final sampling period. Conclusions Restoring reef substrate rebuilt the physical capacity for oysters to persist and grow at Lone Cabbage Reef, yielding sustained density gains that degraded sites did not achieve on their own. Harvest status and river discharge showed weak, inconsistent associations once restoration was included, consistent with the interpretation that oyster cultch provides structural capacity, while environmental and fishing conditions modulate around it. Rebuilding and conserving oyster cultch constitute the essential first step to repair and sustain degraded oyster reefs; fishing regulations or favorable environmental conditions alone are unlikely to replace the need for reef structure.

Florida

Anthropogenic organic compounds in source water of selected community water systems that use groundwater, 2002-05

Source water, defined as groundwater collected from a community water system well prior to water treatment, was sampled from 221 wells during October 2002 to July 2005 and analyzed for 258 anthropogenic organic compounds. Most of these compounds are unregulated in drinking water and include pesticides and pesticide degradates, gasoline hydrocarbons, personal-care and domestic-use products, and solvents. The laboratory analytical methods used in the study have detection levels that commonly are 100 to 1,000 times lower than State and Federal standards and guidelines for protecting water quality. Detections of anthropogenic organic compounds do not necessarily indicate a concern to human health but rather help to identify emerging issues and track changes in occurrence and concentrations over time. Less than one-half (120) of the 258 compounds were detected in at least one source-water sample. Chloroform, in 36 percent of samples, was the most commonly detected of the 12 compounds that were in about 10 percent or more of source-water samples. The herbicides atrazine, metolachlor, prometon, and simazine also were among the commonly detected compounds. The commonly detected degradates of atrazine - deethylatrazine and deisopropylatrazine - as well as degradates of acetochlor and alachlor, generally were detected at concentrations similar to or greater than concentrations of the parent herbicide. The compounds perchloroethene, trichloroethene, 1,1,1-trichloroethane, methyl tert-butyl ether, and cis-1,2-dichloroethene also were detected commonly. The most commonly detected compounds in source-water samples generally were among those detected commonly across the country and reported in previous studies by the U.S. Geological Survey's National Water-Quality Assessment Program. Relatively few compounds were detected at concentrations greater than human-health benchmarks, and 84 percent of the concentrations were two or more orders of magnitude less than benchmarks. Five compounds (perchloroethene, trichloroethene, 1,2-dibromoethane, acrylonitrile, and dieldrin) were detected at concentrations greater than their human-health benchmark. The human-health benchmarks used for comparison were U.S. Environmental Protection Agency Maximum Contaminant Levels (MCLs) for regulated compounds and Health-Based Screening Levels developed by the U.S. Geological Survey in collaboration with the U.S. Environmental Protection Agency and other agencies for unregulated compounds. About one-half of all detected compounds do not have human-health benchmarks or adequate toxicity information to evaluate results in a human-health context. Ninety-four source-water and finished-water (water that has passed through all the treatment processes but prior to distribution) sites were sampled at selected community water systems during June 2004 to September 2005. Most of the samples were analyzed for compounds that were detected commonly or at relatively high concentrations during the initial source-water sampling. The majority of the finished-water samples represented water blended with water from one or more other wells. Thirty-four samples were from water systems that did not blend water from sampled wells with water from other wells prior to distribution. The comparison of source- and finished-water samples represents an initial assessment of whether compounds present in source water also are present in finished water and is not intended as an evaluation of water-treatment efficacy. The treatment used at the majority of the community water systems sampled is disinfection, which, in general, is not designed to remove the compounds monitored in this study. Concentrations of all compounds detected in finished water were less than their human-health benchmarks. Two detections of perchloroethene and one detection of trichloroethene in finished water had concentrations within an order of magnitude of the MCL. Concentrations of disinfection by-products were

Scientific Investigations Report

Nutrient and suspended-sediment concentrations and loads and benthic-invertebrate data for tributaries to the St. Croix River, Wisconsin and Minnesota, 1997-99

Nutrient and suspended-sediment data were collected on major tributaries to the St. Croix River during 1997-99 as part of three studies. The first study, done in 1997 as part of the U.S. Geological Survey?s National Water-Quality Assessment Program Upper Mississippi Study Unit, was a widespread synoptic survey of nutrient and suspended-sediment concentrations, loads, and yields during snowmelt. Runoff from snowmelt in agricultural areas and other areas with low permeability soils had significantly greater nutrient concentrations than forested areas, whereas differences in suspended-sediment loading were not detected. In 1998, synoptic samplings of 11 tributaries were done during snowmelt, base-flow, and storm-runoff periods. These studies showed that the Apple, Willow, and Kinnickinnic Rivers were major contributors of suspended sediments and nutrients to the St. Croix River during base flow and storm-runoff events. Nitrate concentrations were high during base flow in the agricultural tributaries?specifically, the Kinnickinnic (4.83 mg/L), Willow (1.53 mg/L), and Apple (0.79 mg/L) Rivers?possibly from ground-water recharge or point-source contributions. Extensive water-quality sampling was done monthly and during high-flow events in water year 1999 (October 1, 1998 to September 30, 1999) in coordination with continuous streamflow monitoring at 12 sites in the St. Croix River Basin. These data were used to compute annual nutrient and suspended-sediment loads and yields at the monitored sites for water year 1999. Relations among environmental characteristics and calculated annual nutrient and suspended-sediment yields were used to estimate loading from unmonitored parts of the basin. The environmental characteristics found to best estimate annual yields were soil characteristics (clay, permeability of soil, and erodibility), basin slope and area, and the percentages of wetland and urban areas in the basins. Variability in 1999 rainfall intensity resulted in annual yields from several northern, forested basins being higher than those from the southern, agricultural basins. The Sunrise River had the highest annual suspended-sediment and nutrient yields in the basin in 1999. Concentrations and instantaneous loading rates varied as much among various flow conditions at individual sites as among sites during the three years of study. Benthic invertebrates were sampled and indices of water quality were calculated at 16 tributaries in fall 1999. Benthic invertebrate indices indicated excellent to good water quality at all tributaries except Valley Creek, Willow River, and Kettle River. No relations were found between benthic invertebrate indices and the calculated and estimated 1999 annual tributary loads and yields.

Minnesota, Wisconsin

Estimating concentrations of fine-grained and total suspended sediment from close-range remote sensing imagery

Fluvial sediment, a vital surface water resource, is hazardous in excess. Suspended sediment, the most prevalent source of impairment of river systems, can adversely affect flood control, navigation, fisheries and aquatic ecosystems, recreation, and water supply (e.g., Rasmussen et al., 2009; Qu, 2014). Monitoring programs typically focus on suspended-sediment concentration (SSC) and discharge (SSQ). These time-series data are used to study changes to basin hydrology, geomorphology, and ecology caused by disturbances. The U.S. Geological Survey (USGS) has traditionally used physical sediment sample-based methods (Edwards and Glysson, 1999; Nolan et al., 2005; Gray et al., 2008) to compute SSC and SSQ from continuous streamflow data using a sediment transport-curve (e.g., Walling, 1977) or hydrologic interpretation (Porterfield, 1972). Accuracy of these data is typically constrained by the resources required to collect and analyze intermittent physical samples. Quantifying SSC using continuous instream turbidity is rapidly becoming common practice among sediment monitoring programs. Estimations of SSC and SSQ are modeled from linear regression analysis of concurrent turbidity and physical samples. Sediment-surrogate technologies such as turbidity promise near real-time information, increased accuracy, and reduced cost compared to traditional physical sample-based methods (Walling, 1977; Uhrich and Bragg, 2003; Gray and Gartner, 2009; Rasmussen et al., 2009; Landers et al., 2012; Landers and Sturm, 2013; Uhrich et al., 2014). Statistical comparisons among SSQ computation methods show that turbidity-SSC regression models can have much less uncertainty than streamflow-based sediment transport-curves or hydrologic interpretation (Walling, 1977; Lewis, 1996; Glysson et al., 2001; Lee et al., 2008). However, computation of SSC and SSQ records from continuous instream turbidity data is not without challenges; some of these include environmental fouling, calibration, and data range among sensors. Of greatest interest to many programs is a hysteresis in the relationship between turbidity and SSC, attributed to temporal variation of particle size distribution (Landers and Sturm, 2013; Uhrich et al., 2014). This phenomenon causes increased uncertainty in regression-estimated values of SSC, due to changes in nephelometric reflectance off the varying grain sizes in suspension (Uhrich et al., 2014). Here, we assess the feasibility and application of close-range remote sensing to quantify SSC and particle size distribution of a disturbed, and highly-turbid, river system. We use a consumer-grade digital camera to acquire imagery of the river surface and a depth-integrating sampler to collect concurrent suspended-sediment samples. We then develop two empirical linear regression models to relate image spectral information to concentrations of fine sediment (clay to silt) and total suspended sediment. Before presenting our regression model development, we briefly summarize each data-acquisition method.

Conference Paper