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At least 1,009 records · Page 56Linked to original sources

Development of a geodatabase and conceptual model of the hydrogeologic units beneath air force plant 4 and Naval Air Station-Joint Reserve Base Carswell Field, Fort Worth, Texas

Air Force Plant 4 and adjacent Naval Air Station-Joint Reserve Base Carswell Field at Fort Worth, Texas, constitute a government-owned, contractor-operated facility that has been in operation since 1942. Contaminants from AFP4, primarily volatile organic compounds and metals, have entered the ground-water-flow system through leakage from waste-disposal sites and from manufacturing processes. The U.S. Geological Survey developed a comprehensive geodatabase of temporal and spatial environmental information associated with the hydrogeologic units (alluvial aquifer, Goodland-Walnut confining unit, and Paluxy aquifer) beneath the facility and a three-dimensional conceptual model of the hydrogeologic units integrally linked to the geodatabase. The geodatabase design uses a thematic layer approach to create layers of feature data using a geographic information system. The various features are separated into relational tables in the geodatabase on the basis of how they interact and correspond to one another. Using the geodatabase, geographic data at the site are manipulated to produce maps, allow interactive queries, and perform spatial analyses. The conceptual model for the study area comprises computer-generated, three-dimensional block diagrams of the hydrogeologic units. The conceptual model provides a platform for visualization of hydrogeologic-unit sections and surfaces and for subsurface environmental analyses. The conceptual model is based on three structural surfaces and two thickness configurations of the study area. The three structural surfaces depict the altitudes of the tops of the three hydrogeologic units. The two thickness configurations are those of the alluvial aquifer and the Goodland-Walnut confining unit. The surface of the alluvial aquifer was created using a U.S. Geological Survey 10-meter digital elevation model. The 2,130 point altitudes of the top of the Goodland-Walnut unit were compiled from lithologic logs from existing wells, available soil-boring logs, and previous studies. Data from 120 wells, primarily from existing reports, were used to create a map of the approximate altitude of the Paluxy aquifer.

Texas↗

Geology and mineral resources of the Lake Valley area, Sierra County, New Mexico

At the request of the Bureau of Land Management, the U.S. Geological Survey assessed the Lake Valley Area of Critical Environmental Concern (ACEC), which includes the historic Lake Valley townsite and silver-manganese mining district, for undiscovered mineral resources. The Lake Valley ACEC is along the southeastern margin of the Black Range of western Sierra County, New Mexico. The Black Range contains eleven mining districts from which silver, lead, zinc, manganese, copper, gold, and tin have been recovered. As part of the study, an area of over 75 square mi (195 square km) in the area of the Lake Valley ACEC was mapped to understand ore controls and to assess mineral-resource potential. Lake Valley mining district is in Mississippian Lake Valley Formation carbonate rocks, but much of the surrounding terrane consists of volcanic rocks on the southeastern edge of the Emory cauldron which formed about 34.9 Ma. Volcanic rocks are part of the Mogollon-Datil volcanic province which include flows, breccias, ash-flow tuffs, and intrusive rhyolites. The Lake Valley mining district is located about 20 mi (32 km) south of the Late Cretaceous Laramide copper-gold porphyry intrusion at Hillsboro. It is also located at the western boundary of the Rio Grande rift basin.The Lake Valey fault is the major structural feature of the study area. Geological and geophysical data suggest the fault is composed of two segments: a southern, northwest-striking segment that may have a pre-Tertiary history and a northerly-striking segment that is part of the Emory cauldron ring fracture. The mining district is bounded by the southern, northwest-striking segment of the fault which may have up to 800 ft (240m) of normal offset. Deposit types identified in the Black Range, and for which we assess mineral potential, are Laramide porphyry, Laramide skarns, Laramide veins, gold placer, carbonate-hosted, volcanic-epithermal, and rhyolite tin; no Rio Grande Rift baritefluorite-galena deposits are known, but they are included in the assessment. The most likely deposits to be discovered in the Lake Valley district are carbonate-hosted silver-manganese deposits. These deposits could be deposited by hydrothermal fluids or be related to intrusion of Oligocene rhyolite or Laramide porphyry. An aeromagnetic high south of the district probably reflects a small felsic intrusion of unknown age. We assess the Lake Valley ACEC as having low to moderate potential for undiscovered carbonate-hosted deposits associated with volcanic rocks or Laramide porphyry plutons, and low potential for gold placer and rhyolite tin deposits.

New Mexico↗

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of ammonium plus organic nitrogen by a Kjeldahl digestion method and an automated photometric finish that includes digest cleanup by gas diffusion

The National Water Quality Laboratory (NWQL) determined ammonium plus organic nitrogen (Kjeldahl nitrogen) by using semiautomated, block digester methods for filtered and whole-water samples from 1986 until October 1, 1991. During that time, phosphorus was determined by a persulfate digestion method. In 1991, projected increases in demand for both tests by the U.S. Geological Survey?s National Water-Quality Assessment Program led the NWQL to develop and validate methods for determining both analytes in a common digest. This report describes a rapid and accurate method to determine Kjeldahl nitrogen. The batch, high-temperature (block digester), Hg (II)-catalyzed digestion step used in the new methods I-2515-91/4515-91 is similar to U.S. Geological Survey methods I-2552-85/4552-85 and U.S. Environmental Protection Agency method 351.2 except that sample and reagent volumes are halved. Prepared digests are desolvated at 220 degrees Celsius (oC) and digested at 370oC in separate block digesters set at these temperatures, rather than in a single, temperatureprogrammed block digester. This approach permits 40 calibrants, reference materials, and samples to be digested and resolvated in about an hour. Ammonium ions originally present in samples, along with those released during the digestion step, are determined photometrically by an automated, salicylatehypochlorite Berthelot reaction procedure at a rate of 90 tests per hour. About 100 microliters of digest are required per determination. The upper concentration level is 10 milligrams per liter (mg/L) with a method detection level of 0.05 mg/L. Repeatability for a sample containing about 4.1 mg/L of Kjeldahl nitrogen in a high suspended-solids matrix is 3.1 percent. Between-day precision for the same sample is 4.8 percent. A gas diffusion cell in the air-segmented continuous flow analyzer eliminates particulates and ions that otherwise would interfere in the photometric finish. A singlechannel analyzer can process the resolvated digests from two pairs of block digesters each hour. Statistical analysis of paired data for about 1,500 samples determined by U.S. Geological Survey methods I-2552-85/4552- 85 and I-2515-91/4515-91 during method validation revealed a median concentration difference between the former and the latter methods of about 0.1 mg-N/L. This result was expected because digestion blank concentrations (nearly equal to 0.1 mg/L) were not subtracted from concentrations reported by methods I-2552-85/4552-85. A 10-year record of National Water Quality Laboratory Kjeldahl nitrogen blind blank concentration data also supports a step-change decrease in Kjeldahl nitrogen concentrations of about 0.1 mg/L after methods I-2552-85/4552-85 were replaced by methods I-2515-91/4515-91 on October 1, 1991. Somewhat larger concentration differences between the two methods were observed for a subset of about 350 samples with nitrate plus nitrite concentrations greater than 1 mg-N/L.

Open-File Report↗

Water-Quality Characteristics for Sites in the Tongue, Powder, Cheyenne, and Belle Fourche River Drainage Basins, Wyoming and Montana, Water Years 2001-05, with Temporal Patterns of Selected Long-Term Water-Quality Data

Water-quality sampling was conducted regularly at stream sites within or near the Powder River structural basin in northeastern Wyoming and southeastern Montana during water years 2001-05 (October 1, 2000, to September 30, 2005) to characterize water quality in an area of coalbed natural gas development. The U.S. Geological Survey, in cooperation with the Wyoming Department of Environmental Quality, characterized the water quality at 22 sampling sites in the Tongue, Powder, Cheyenne, and Belle Fourche River drainage basins. Data for general hydrology, field measurements, major-ion chemistry, and selected trace elements were summarized, and specific conductance and sodium-adsorption ratios were evaluated for relations with streamflow and seasonal variability. Trend analysis for water years 1991-2005 was conducted for selected sites and constituents to assess change through time. Average annual runoff was highly variable among the stream sites. Generally, streams that have headwaters in the Bighorn Mountains had more runoff as a result of higher average annual precipitation than streams that have headwaters in the plains. The Powder River at Moorhead, Mont., had the largest average annual runoff (319,000 acre-feet) of all the sites; however, streams in the Tongue River drainage basin had the highest runoff per unit area of the four major drainage basins. Annual runoff in all major drainage basins was less than average during 2001-05 because of drought conditions. Consequently, water-quality samples collected during the study period may not represent long-term water-quality con-ditions for all sites. Water-quality characteristics were highly variable generally because of streamflow variability, geologic controls, and potential land-use effects. The range of median specific-conductance values among sites was smallest in the Tongue River drainage basin. Median values in that basin ranged from 643 microsiemens per centimeter at 25 degrees Celsius (?S/cm at 25?C) on the Tongue River to 1,460 ?S/cm at 25?C on Prairie Dog Creek. The Tongue River drainage basin has the largest percentage of area underlain by Mesozoic-age and older rocks and by more resistant rocks. In addition, the higher annual precipitation and a steeper gradient in this basin compared to basins in the plains produce relatively fast stream velocities, which result in a short contact time between stream waters and basin materials. The Powder River drainage basin, which has the largest drainage area and most diverse site conditions, had the largest range of median specific-conductance values among the four major drainage basins. Median values in that basin ranged from 680 ?S/cm at 25?C on Clear Creek to 5,950 ?S/cm at 25?C on Salt Creek. Median specific-conductance values among sites in the Cheyenne River drainage basin ranged from 1,850 ?S/cm at 25?C on Black Thunder Creek to 4,680 ?S/cm at 25?C on the Cheyenne River. The entire Cheyenne River drainage basin is in the plains, which have low precipitation, soluble geologic materials, and relatively low gradients that produce slow stream velocities and long contact times. Median specific-conductance values among sites in the Belle Fourche River drainage basin ranged from 1,740 ?S/cm at 25?C on Caballo Creek to 2,800 ?S/cm at 25?C on Donkey Creek. Water in the study area ranged from a magnesium-calcium-bicarbonate type for some sites in the Tongue River drainage basin to a sodium-sulfate type at many sites in the Powder, Cheyenne, and Belle Fourche River drainage basins. Little Goose Creek, Goose Creek, and the Tongue River in the Tongue River drainage basin, and Clear Creek in the Powder River drainage basin, which have headwaters in the Bighorn Mountains, consistently had the smallest median dissolved-sodium concentrations, sodium-adsorption ratios, dissolved-sulfate concentrations, and dissolved-solids concentrations. Salt Creek, Wild Horse Creek, Little Powder River, and the Cheyenne River, which have headwat

Scientific Investigations Report↗

Development of a global land cover characteristics database and IGBP DISCover from 1 km AVHRR data

Researchers from the U.S. Geological Survey, University of Nebraska-Lincoln and the European Commission's Joint Research Centre, Ispra, Italy produced a 1 km resolution global land cover characteristics database for use in a wide range of continental-to global-scale environmental studies. This database provides a unique view of the broad patterns of the biogeographical and ecoclimatic diversity of the global land surface, and presents a detailed interpretation of the extent of human development. The project was carried out as an International Geosphere-Biosphere Programme, Data and Information Systems (IGBP-DIS) initiative. The IGBP DISCover global land cover product is an integral component of the global land cover database. DISCover includes 17 general land cover classes defined to meet the needs of IGBP core science projects. A formal accuracy assessment of the DISCover data layer will be completed in 1998. The 1 km global land cover database was developed through a continent-by-continent unsupervised classification of 1 km monthly Advanced Very High Resolution Radiometer (AVHRR) Normalized Difference Vegetation Index (NDVI) composites covering 1992-1993. Extensive post-classification stratification was necessary to resolve spectral/temporal confusion between disparate land cover types. The complete global database consists of 961 seasonal land cover regions that capture patterns of land cover, seasonality and relative primary productivity. The seasonal land cover regions were aggregated to produce seven separate land cover data sets used for global environmental modelling and assessment. The data sets include IGBP DISCover, U.S. Geological Survey Anderson System, Simple Biosphere Model, Simple Biosphere Model 2, Biosphere-Atmosphere Transfer Scheme, Olson Ecosystems and Running Global Remote Sensing Land Cover. The database also includes all digital sources that were used in the classification. The complete database can be sourced from the website: http://edcwww.cr.usgs.gov/landdaac/glcc/glcc.html.

International Journal of Remote Sensing↗

The Connecticut Streamflow and Sustainable Water Use Estimator—A decision-support tool to estimate water availability at ungaged stream locations in Connecticut

Freshwater streams in Connecticut are subject to many competing demands, including public water supply; agricultural, commercial, and industrial water use; and ecosystem and habitat needs. In recent years, drought has further stressed Connecticut’s water resources. To sustainably allocate and manage water resources among these competing uses, Federal, State, and local water-resource managers require data and modeling tools to estimate the water availability at a variety of temporal and spatial scales for planning purposes. The Connecticut Streamflow and Sustainable Water Use Estimator (CT SSWUE), developed by the U.S. Geological Survey in cooperation with the Connecticut Department of Energy and Environmental Protection, is a decision-support tool for estimating daily unaltered streamflow and sustainable water use at ungaged sites in Connecticut. The CT SSWUE estimates unaltered daily mean streamflow and water-use-adjusted streamflow for the period from October 1, 1960, to September 30, 2015, and the monthly sustainable net withdrawal at ungaged sites in Connecticut. Unaltered streamflow is the estimated daily mean streamflow in a drainage basin in the absence of any water withdrawals or wastewater discharges and with minimal human development. Sustainable net withdrawal is the maximum net withdrawal (withdrawal minus wastewater discharges) that can be drawn from a basin without critically depleting the water available through natural streamflow patterns. Sustainable net withdrawal is defined for this study as the difference between the unaltered daily mean streamflow and a user-defined target minimum streamflow. Weighted least squares and Tobit regression techniques were used to develop equations for estimating streamflow at ungaged sites at 19 streamflow quantiles with exceedance probabilities ranging from 0.005 to 99.995 percent. Regressions were based on streamflow quantiles and basin characteristics from 36 reference streamgages in and around Connecticut. Four basin characteristics—drainage area, mean of the soil permeability, mean of the average annual precipitation, and ratio of the length of streams that overlay sand and gravel deposits to the total length of streams in the basin—are used as explanatory variables in the equations. At an ungaged site, interpolation between the streamflow quantiles estimated from the regression equations produces a continuous flow-duration curve. A time series of daily mean streamflow at an ungaged site is then estimated by assuming that for each day, the streamflow quantile occurs on the same date at both a reference streamgage and the ungaged site. In a remove-one cross validation, estimated unaltered daily mean streamflow agreed well with observed values at reference streamgages, with a few exceptions. Nash Sutcliffe efficiency ranged from −0.43 to 0.97 with a median value of 0.88. The normalized root-mean-square error ranged from 16.6 to 120.4 percent with a median value of 34.5 percent. An empirical method for estimating 95-percent prediction intervals for unaltered daily and monthly mean streamflow was developed and tested by using the cross-validation data. Prediction intervals for unaltered daily mean streamflow at the cross-validation reference streamgages performed well in most cases. Gaged streamflow values from the cross-validation data fell within the prediction intervals a median 96.6 percent of the time for daily mean time series and 93.9 percent of the time for monthly mean time series. The CT SSWUE computes water-use-adjusted streamflow using spatially referenced water-use information provided by the Connecticut Department of Energy and Environmental Protection. Available water-use information included permitted and registered water withdrawals and permitted wastewater discharges during 1998 to 2015 for the Thames River Basin and central coastal drainage basins. Water-use information was incorporated into the U.S. Geological Survey StreamStats web application for Connecticut and can be used for computing water-use-adjusted streamflow and sustainable net withdrawal at selected points of interest. Altered daily streamflow is computed by applying average daily withdrawals and wastewater discharges to the water balance equation. Average daily surface water withdrawals and wastewater discharges are applied directly to the daily water balance equation. Time-lagged alterations on streamflow from groundwater withdrawals or wastewater discharges are estimated by using a response-coefficient method developed from results of previously published, calibrated groundwater models.

Connecticut↗

Environmental conditions and resources of southwestern Mississippi

The impending phase-out of Saturn V testing by the National Aeronautics and Space Administration at the Mississippi Test Facility (MTF) necessitates consideration of possible alternative uses for the Facility and surrounding region. To make a rapid and up-to-date study of pertinent environmental factors in that region, remote sensing techniques and data were used by discipline specialists in the U. S. Geological Survey, scientists in other Bureaus of the Department of the Interior and other agencies, and the Project Coordinator. Full cooperation was received from officials, planners, and business executives in Mississippi, as well as timely assistance from NASA Headquarters, the Manned Spacecraft Center/Houston, and the MTF staff. Results from a multi-sensor equipped RB-57F high altitude overflight on February 17, 1970, and a simultaneous helicopter overflight were compared with existing photographs, maps, reports, and locally collected field data to complete this report rapidly as a Geographic Applications Project of the EROS Program, U. S. Department of the Interior. Pertinent background materials, including a comprehensive, annotated bibliography of existing studies of the area, are attached. This report considers 19 potential uses of the MTF equipment, staff, and property in relation to 16 environmental factors.

Mississippi↗

An environmental assessment of hydrocarbons in mid-Atlantic shelf sediments: 1975-1976 USGS-BLM program

During 1975-1976, the U.S. Geological Survey (U.S.G.S.), in conjunction with the Bureau of Land Management and the Virginia Institute of Marine Sciences, carried out an environmental assessment program to establish baseline concentration levels of hydrocarbons in the surface sediments of the Mid-Atlantic Shelf where leasing for petroleum exploration is anticipated. Reported here are the results of the individual hydrocarbon analyses for 150 composite surfacesediment samples.

Open-File Report↗

Geophysical bed sediment characterization of the Androscoggin River from the former Chlor-Alkali Facility Superfund Site, Berlin, New Hampshire, to the state border with Maine, August 2009

The former Chlor-Alkali Facility in Berlin, New Hampshire, was listed on the U.S. Environmental Protection Agency National Priorities List in 2005 as a Superfund site. The Chlor-Alkali Facility lies on the east bank of the Androscoggin River. Elemental mercury currently discharges from that bank into the Androscoggin River. The nature, extent, and the speciation of mercury and the production of methyl mercury contamination in the adjacent Androscoggin River is the subject of continuing investigations. The U.S. Geological Survey, in cooperation with Region I of the U.S. Environmental Protection Agency, used geophysical methods to determine the distribution, thickness, and physical properties of sediments in the Androscoggin River channel at a small area of an upstream reference reach and downstream from the site to the New Hampshire–Maine State border. Separate reaches of the Androscoggin River in the study area were surveyed with surface geophysical methods including ground-penetrating radar and step-frequency electromagnetics. Results were processed to assess sediment characteristics including grain size, electrical conductivity, and pore-water specific conductance. Specific conductance measured during surface- and pore-water sampling was used to help interpret the results of the geophysical surveys. The electrical resistivity of sediment samples was measured in the laboratory with intact pore water for comparison with survey results. In some instances, anthropogenic features and land uses, such as roads and power lines affected the detection of riverbed properties using geophysical methods; when this occurred, the data were removed. Through combining results, detailed riverbed sediment characterizations were made. Results from ground-penetrating radar surveys were used to image and measure the depth to the riverbed, depth to buried riverbeds, riverbed thickness and to interpret material-type variations in terms of relative grain size. Fifty two percent of the riverbed in the study area was covered with gravel and finer sediments. The electrically resistive river water and sediment in this study area were conducive to the penetration of the ground-penetrating radar and step-frequency electromagnetic signals and allowed for effective sediment characterization by geophysical methods. The reach between the former Chlor-Alkali Facility and the Riverside Dam, had small areas of fine sediment (estimated 11 percent of riverbed area), found on the upstream left bank and the downstream right bank, with an electromagnetic conductivity (31.4 millisiemens per meter (mS/m) maximum) that was higher than the upstream reference reach. The greatest electromagnetic conductivity (195 mS/m), pore-water specific conductance (324 mS/m) and lab measured sediment conductivity of (76.8 mS/m, measured with a direct-current resistivity test box) in the study were measured approximately 1 mile (mi) downstream of the site from a sandbar on the left bank. Reaches adjacent to and within 2 mi downstream from the site had elevated electromagnetic conductivity despite having lower estimated percentages of riverbed area covered in sediment (11, 25, and 61 percent, respectively) than the reference reach (97). Typically finer grained sediment with similar mineralogy will be more conductive. The Shelburne Reservoir is approximately 8 mi downstream from the site had the second greatest pore-water specific conductance measured, 45.8 mS/m. Many of the locations with the largest step-frequency electromagnetic values have not been sampled for pore water and sediment.

New Hampshire↗

Water-quality distributions in the East Branch Black River near the Chemical Recovery Systems site in Elyria, Ohio, 2021

Autonomous underwater vehicles are uniquely designed to provide spatially dense water-quality data along with bathymetry and velocimetry. The U.S. Environmental Protection Agency Region 5 requested technical assistance from the U.S. Geological Survey in support of ongoing investigations at the Chemical Recovery Systems site to collect spatially dense water-quality and bathymetry data in the East Branch Black River in Elyria, Ohio. This report was prepared in cooperation with the U.S. Environmental Protection Agency to present the results of the autonomous underwater vehicle survey near the Chemical Recovery Systems site on March 22, 2021. Plots of distributions of water temperature, specific conductance, pH, and dissolved oxygen are presented that may help guide and focus future U.S. Environmental Protection Agency efforts at the site to determine the degree of groundwater/surface-water interaction.

Ohio↗

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of the total phosphorus by a Kjeldahl digestion method and an automated colorimetric finish that includes dialysis

A method to determine total phosphorus (TP) in the same digests prepared for total Kjeldahl nitrogen (TKN) determinations is desribed. The batch, high-temperature (block digester), HG(II)-catalyzed digestion step is similar to U.S. Geological Survey methods I-2552-85/I-4552-85 and U.S. Environmental Protection Agency method 365.4 except that sample and reagent volumes are halved. Prepared digests are desolvated at 220 degrees Celsius and digested at 370 degrees Celsius in separate block digesters set at these temperatures, rather than in a single, temperature-programmed block digester. This approach is used in the method escribed here, which permits 40 calibrants, reference waters, and smaples to be digested and resolvated in about an hour. Orthophosphate ions originally present in samples, along with those released during the digestion step, are determined colorimetrically at a rate of 90 tests per hour by an automated version of the phosphoantimonylmolybdenum blue procedure. About 100 microliters of digest are required per determination. The upper concentration limit is 2 milligrams per liter (mg/L) with a method detection limt of 0.01 mg/L. Repeatability for a sample containing approximately 1.6 mg/L of TP in a high suspended-solids matrix is 0.7 percent. Between-day precision for the same sample is 5.0 percent. A dialyzer in the air-segmented continuous flow analyzer provides on-line digest cleanup, eliminated particulates that otherwise would interfere in the colorimetric finish. An single-channel analyzer can process the resolvated digests from two pairs of block digesters each hour. Paired t-test analysis of TP concentrations for approximately 1,600 samples determined by the new method (U.S. Geologial Survey methods I-2610-91 and I-4610-91) and the old method (U.S. Geological Survey methods I-2600-85 and I-4600-85) revealed positive bias in the former of 0.02 to 0.04 mg/L for surface-water samples in agreement with previous studies. Concentrations of total phosphorus detemrined for ground-water samples by both methods were statistically equivalent.

Open-File Report↗

Marine geophysical data collected in a shallow back-barrier estuary, Barnegat Bay, New Jersey

In 2011, the U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection, began a multidisciplinary research project to better understand the water quality in Barnegat Bay, New Jersey. This back-barrier estuary is experiencing degraded water quality, algal blooms, loss of seagrass, and increases in oxygen stress, macroalgae, stinging nettles, and brown tide. The spatial scale of the estuary and the scope of challenges within it necessitate a multidisciplinary approach that includes establishing the regional geology and the estuary’s physical characteristics and modeling how the estuary’s morphology interacts to affect its water quality. This report presents the data collected during this project for use in understanding the morphology and the distribution of sea-floor and sub-sea-floor sediments within Barnegat Bay, describes the methods used to collect and process those data, and includes links to the final processed datasets. These data can be used by scientists to understand the links between geomorphology, geologic framework, sediment transport, and estuarine water quality and circulation.

New Jersey↗

Geologic Map of the House Rock Valley Area, Coconino County, Northern Arizona

This geologic map is a cooperative effort of the U.S. Geological Survey (USGS), the Bureau of Land Management, the National Park Service, and the U.S. Forest Service to provide a geologic database for resource management officials and visitor information services. This map was produced in response to information needs related to a proposed withdrawal of three segregated land areas near Grand Canyon National Park, Arizona, from new hard rock mining activity. House Rock Valley was designated as the east parcel of the segregated lands near the Grand Canyon. This map was needed to provide connectivity for the geologic framework of the Grand Canyon segregated land areas. This geologic map of the House Rock Valley area encompasses approximately 280 mi2 (85.4 km2) within Coconino County, northern Arizona, and is bounded by longitude 111 degrees 37'30' to 112 degrees 05' W. and latitude 36 degrees 30' to 36 degrees 50' N. The map area is in the eastern part of the Arizona Strip, which lies within the southern Colorado Plateaus geologic province (herein Colorado Plateau). The Arizona Strip is the part of Arizona lying north of the Colorado River. The map is bound on the east by the Colorado River in Marble Canyon within Grand Canyon National Park and Glen Canyon National Recreation Area, on the south and west by the Kaibab National Forest and Grand Canyon National Game Preserve, and on the north by the Vermilion Cliffs Natural Area, the Paria Canyon Vermilion Cliffs Wilderness Area, and the Vermilion Cliffs National Monument. House Rock State Buffalo Ranch also bounds the southern edge of the map area. The Bureau of Land Management Arizona Field Office in St. George, Utah, manages public lands of the Vermilion Cliffs Natural Area, Paria Canyon - Vermilion Cliffs Wilderness and Vermilion Cliffs National Monument. The North Kaibab Ranger District in Fredonia, Arizona, manages U.S. Forest Service land along the west edge of the map area and House Rock State Buffalo Ranch. Other lands include about 13 sections of Arizona State land, about ? of a section of private land along House Rock Wash, and about 1? sections of private land at Cliff Dwellers Lodge, Vermilion Cliffs Lodge, and Marble Canyon, Arizona. Landmark features within the map area include the Vermilion Cliffs, Paria Plateau, Marble Canyon, and House Rock Valley. Surface drainage in House Rock Valley is to the east toward the Colorado River in Marble Canyon. Large tributaries of Marble Canyon from north to south include Badger Canyon, Soap Creek, Rider Canyon, North Canyon, Bedrock Canyon, and South Canyon. Elevations range from about 2,875 ft (876 m) at the Colorado River in the southeast corner of the map to approximately 7,355 ft (2,224 m) on the east rim of Paria Plateau along the north-central edge of the map area. Three small settlements are in the map area along U.S. Highway 89A, Cliff Dwellers Lodge, Vermilion Cliffs Lodge, and Marble Canyon, Arizona. The community of Jacob Lake is about 9 mi (14.5 km) west of House Rock Valley on the Kaibab Plateau. Lees Ferry is 5 mi (8 km) north of Marble Canyon and marks the confluence of the Paria and Colorado Rivers and the beginning of Marble Canyon. U.S. Highway 89A provides access to the northern part of the map area. Dirt roads lead south into House Rock Valley from U.S. Highway 89A and are collectively maintained by the Bureau of Land Management, the U.S. National Forest Service, and the Grand Canyon Trust. House Rock Valley is one of the few remaining areas where uniform geologic mapping is needed for connectivity to the regional Grand Canyon geologic framework. This information is useful to Federal and State resource managers who direct environmental and land management programs that encompass such issues as range management, biological studies, flood control, water, and mineral-resource investigations. The geologic information will support future and ongoing geologic investigations and scientific studies

Scientific Investigations Map↗

Water quality in the upper Anacostia River, Maryland: Continuous and discrete monitoring with simulations to estimate concentrations and yields, 2003-05

From 2003 through 2005, continuous and discrete waterquality data were collected at two stations on the Anacostia River in Maryland: Northeast Branch at Riverdale, Maryland (U.S. Geological Survey Station 01649500) and Northwest Branch near Hyattsville, Maryland (Station 01651000). Both stations are above the heads of tide for the river, and measurements approximately represent contributions of chemicals from the nontidal watersheds in the Anacostia River. This study was a cooperative effort between the U.S. Geological Survey, the Prince George’s County Department of Environmental Resources, the Maryland Department of the Environment, the U.S. Environmental Protection Agency, and George Mason University. Samples were collected for suspended sediment, nutrients, and trace metals; data were used to calculate loads of selected chemical parameters, and to evaluate the sources and transport processes of contaminants. Enrichment factors were calculated for some trace metals and used to interpret patterns of occurrence over different flow regimes. Some metals, such as cadmium, lead, and zinc, were slightly enriched as compared to global averages for shales; overall, median values of enrichment factors for all metals were approximately 15 to 35. Stepwise linear regression models were developed on log-transformed concentrations to estimate the concentrations of suspended sediment, total nitrogen, and total phosphorus from continuous data of discharge and turbidity. The use of multiple explanatory variables improved the predictions over traditional rating curves that use only streamflow as the explanatory variable, because other variables such as turbidity measure the hysteretic effects of fine-grained suspended sediment over storm hydrographs. Estimates of the concentrations of suspended sediment from continuous discharge and turbidity showed coefficients of determination for the predictions (multiple R2) of 0.95 and biases of less than 4 percent. Models to estimate the concentrations of total phosphorus and total nitrogen had lower values of multiple R2 than suspended sediment, but the estimated bias for all the models was similar. The models for total nitrogen and total phosphorus tended to under-predict high concentrations and to over-predict low concentrations as compared to measured values. Annual yields (loads per square area in kilograms per year per square kilometer) were estimated for suspended sediment, total nitrogen, and total phosphorus using the U.S. Geological Survey models ESTIMATOR and LOADEST. The model LOADEST used hourly time steps and allowed the use of turbidity, which is strongly correlated to concentrations of suspended sediment, as a predictor variable. Annual yields for total nitrogen and total phosphorus were slightly higher but similar to previous estimates for other watersheds of the Chesapeake Bay, but annual yields for suspended sediment were higher by an order of magnitude for the two Anacostia River stations. Annual yields of suspended sediment at the two Anacostia River stations ranged from 131,000 to 248,000 kilograms per year per square kilometer for 2004 and 2005. LOADEST estimates were similar to those determined with ESTIMATOR, but had reduced errors associated with the estimates.

Maryland↗

Methods for estimating streamflow characteristics at ungaged sites in western Montana based on data through water year 2009: Chapter G in Montana StreamStats

The U.S. Geological Survey, in cooperation with the Montana Department of Environmental Quality and the Montana Department of Natural Resources and Conservation, developed regional regression equations based on basin and streamflow characteristics for streamflow-gaging stations through water year 2009 that can be used to estimate streamflow characteristics for ungaged sites in western Montana. The regression equations allow estimation of low-flow frequencies; mean annual and mean monthly streamflows; and the 20-, 50-, and 80-percent durations for annual and monthly duration streamflows for ungaged sites in western Montana that are unaffected by regulation. Regression equations were developed for 54 streamflow characteristics in each of the 4 hydrologic regions generally located in western Montana. Exploratory data analyses determined that of the 40 basin characteristics used as explanatory variables, only 3 were significant in the final equations. These three basin characteristics are contributing drainage area, mean annual precipitation of the drainage basin, and percentage of basin with slopes greater than 50 percent. Low-flow frequency data and daily mean streamflow data from 152 streamflow-gaging stations were used to develop the regression equations. These 152 streamflow-gaging stations were considered to be unregulated (or only the unregulated period of record for regulated streamflow-gaging stations were used). For this study, a streamflow-gaging station is considered to be unregulated if cumulative drainage area upstream from all upstream dams is less than 20 percent of the drainage basin for the streamflow-gaging station, and if no large diversion canals are upstream from the streamflow-gaging station. In addition to the regional regression equations, two methods for estimating streamflow characteristics based on drainage areas of a nearby streamflow-gaging station are provided. Also, spreadsheet tools are provided for calculating streamflow characteristics based on regression equations or the drainage-area ratio method. All of the data used to calculate basin characteristics were derived from publicly available data sources and are available through the U.S. Geological Survey Streamstats program ( http://water.usgs.gov/osw/streamstats/ ) for Montana. The primary purpose of the Montana StreamStats application is to provide estimates of basin characteristics and streamflow characteristics for user-selected ungaged sites on Montana streams. The regional regression equations presented in this report have been loaded to the Montana StreamStats application and can be used to derive streamflow characteristics for ungaged sites.

Montana↗

Simulation of Surface-Water Conditions in the Nontidal Passaic River Basin, New Jersey

The Passaic River Basin, the third largest drainage basin in New Jersey, encompasses 950 mi2 (square miles) in the highly urbanized area outside New York City, with a population of 2 million. Water quality in the basin is affected by many natural and anthropogenic factors. Nutrient loading to the Wanaque Reservoir in the northern part of the basin is of particular concern and is caused partly by the diversion of water at two downstream intakes that is transferred back upstream to refill the reservoir. The larger of these diversions, Wanaque South intake, is on the lower Pompton River near Two Bridges, New Jersey. To support the development of a Total Maximum Daily Load (TMDL) for nutrients in the nontidal part of the basin (805 mi2), a water-quality transport model was needed. The U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection and New Jersey EcoComplex, developed a flow-routing model to provide the hydraulic inputs to the water-quality model. The Diffusion Analogy Flow model (DAFLOW) described herein was designed for integration with the Water Quality Analysis Simulation Program (WASP) watershed water-quality model. The flow routing model was used to simulate flow in 108 miles of the Passaic River and major tributaries. Flow data from U.S. Geological Survey streamflow-gaging stations represent most of the model's upstream boundaries. Other model inputs include estimated flows for ungaged tributaries and unchanneled drainage along the mainstem, and reported flows for major point-source discharges and diversions. The former flows were calibrated using the drainage-area ratio method. The simulation extended over a 4+ year period representing a range in flow conditions. Simulated channel cross-sectional geometry in the DAFLOW model was calibrated using several different approaches by adjusting area and top width parameters. The model also was calibrated to observed flows for water year 2001 (low flow) at five mainstem gaging stations and one station at which flow was estimated. The model's target range was medium to low flows--the range of typical intake operations. Simulated flow mass balance, hydrographs (flood-wave speed, attenuation, and spread), flow-duration curves, and velocity and depth values were compared to observed counterparts. Mass balance and hydrograph fit were evaluated quantitatively. Simulation results generally were within the accuracy of the flow data at the measurement stations. The model was validated to observed flows for water years 2000 (average flow), 2002 (extreme low flow), and 2003 (high flow). Results for 19 of 20 comparisons indicate average mass-balance and model-fit errors of 6.6 and 15.7 percent, respectively, indicating that the model reasonably represents the time variation of streamflow in the nontidal Passaic River Basin. An algorithm (subroutine) also was developed for DAFLOW to simulate the hydraulic mixing that occurs near the Wanaque South intake upstream from the confluence of the Pompton and Passaic Rivers. The intake draws water from multiple sources, including effluent from a nearby wastewater-treatment plant, all of which have different phosphorus loads. The algorithm determines the proportion of flow from each source and operates within a narrow flow range. The equations used in the algorithm are based on the theory of diffusion and lateral mixing in rivers. Parameters used in the equations were estimated from limited available local flow and water-quality data. As expected, simulation results for water years 2000, 2001, and 2003 indicate that most of the water drawn to the intake comes from the Pompton River; however, during many short periods of low flow and high diversion, particularly in water year 2002, entrainment of the other flow sources compensated for the insufficient flow in the Pompton River. As additional verification of the flow model used in the water-quality model, a Branched Lagrangian Transport Model (B

Scientific Investigations Report↗

Herbicides and their transformation products in source-water aquifers tapped by public-supply wells in Illinois, 2001-02

During 2001-02, ground-water samples were collected from 117 public-supply wells distributed throughout Illinois to evaluate the occurrence of herbicides and their transformation products in the State?s source-water aquifers. Wells were selected using a stratified-random method to ensure representation of the major types of source-water aquifers in the State. Samples were analyzed for 18 herbicides and 18 transformation products, including 3 triazine and 14 chloroacetanilide products. Herbicide compounds (field-applied parent herbicides and their transformation products) were detected in 34 percent of samples. A subset of samples was collected unfiltered to determine if analytical results for herbicides in unfiltered samples are similar to those in paired filtered samples and, thus, can be considered equally representative of herbicide concentrations in ground water supplied to the public. The study by the U.S. Geological Survey was done in cooperation with the Illinois Environmental Protection Agency. Parent herbicides were detected in only 4 percent of all samples. The six most frequently detected herbicide compounds (from 5 to 28 percent of samples) were chloroacetanilide transformation products. The frequent occurrence of transformation products and their higher concentrations relative to those of most parent herbicides confirm the importance of obtaining information on transformation products to understand the mobility and fate of herbicides in ground-water systems. No sample concentrations determined during this study exceeded current (2003) Federal or State drinking-water standards; however, standards are established for only seven parent herbicides. Factors related to the occurrence of herbicide compounds in the State?s source-water aquifers include unconsolidated and unconfined conditions, various hydrogeologic characteristics and well-construction aspects at shallow depths, and proximity to streams. Generally, the closer an aquifer (or well location) is to a recharge area and (or) the stronger the hydraulic connection between an aquifer and a recharge area, the younger the ground water and the more vulnerable the aquifer will be to contamination by herbicide compounds. The weak relation between current (2001) statewide application rates of herbicides and current (2001-02) occurrence of herbicide compounds in source-water aquifers indicates that additional factors must be considered when relating herbicide-application rates to occurrence. These factors include historical application rates and the mobility and persistence of the various herbicide compounds in ground-water systems. Frequency of detection and concentrations of herbicides compounds in the State?s source-water aquifers are indicated to be highest during the spring, when crops are planted and herbicides primarily are applied. Excess nitrate (concentrations of nitrate, as nitrogen, higher than 3 milligrams per liter) in ground water strongly indicates the co-occurrence of herbicide compounds. However, nitrate concentrations are not a reliable indicator of herbicide-compound concentrations. The inverse relation found between current use of land for corn and soybean production and current occurrence of herbicide compounds in underlying aquifers indicates that various factors, along with current agricultural land use, contribute to herbicide occurrence. These factors include, among others, land-use history, ground-water age, ground-water-flow patterns, geology, soil microbiology, and chemistry and persistence of the herbicide compounds. Detection of agriculture-specific herbicide compounds in 71 percent of samples from urban areas with no current or recent agricultural land use near the sampled wells indicates that recharge to certain high-capacity supply wells may originate at considerable distances (up to about 10 miles) from the wells. Essentially no difference was found between the analytical results for herbicides in paired unfiltered and filtered samples,

Water-Resources Investigations Report↗

Water-quality data analysis of the upper Gunnison River watershed, Colorado, 1989-99

Water-quality data from October 1969 to December 1999 for both surface water and ground water in the upper Gunnison River watershed were retrieved and compiled from the U.S. Geological Survey National Water Information System and the U.S. Environmental Protection Agency Storage and Retrieval databases. Analyses focused primarily on a subset of these data from October 1989 to December 1999. The upper Gunnison River watershed is located west of the Continental Divide in the Southern Rocky Mountains physiographic province. Surface-water-quality data were compiled for 482 sites in the upper Gunnison River watershed. Most values of surface-water temperature, dissolved oxygen, and pH were within Colorado Department of Public Health and Environment (CDPHE) in-stream standards. Calcium bicarbonate type water was the most spatially dominant water type in the basin. Nutrients were most commonly sampled along the Slate River and East River near Crested Butte and along the Gunnison River from the confluence of the East and Taylor Rivers to the western edge of the watershed. Median ammonia concentrations were low, with many concentrations less than laboratory reporting levels. All nitrate concentrations met the CDPHE in-stream standard of 10 milligrams per liter. More than 30 percent of stream sites with total phosphorus data (23 of 61 sites) had concentrations greater than the U.S. Environmental Protection Agency (USEPA) recommendation for controlling eutrophication. Ammonia concentrations at a site on the Slate River near Crested Butte had a statistically significant upward trend for the 1995–99 period. The Slate River near Crested Butte site is located immediately downstream from the towns of Crested Butte and Mount Crested Butte and may reflect recent population growth or other land-use changes. However, the rate of change of the trend is small (0.017 milligram per liter per year). Although a multiple comparison test showed nitrate concentrations were statistically different between agriculture and forest sites and between agriculture and urban land-use classified sites, median concentrations were low among all land-use settings. Median concentrations of total phosphorus were greatest in rangeland areas and least in urban areas. No significant differences were identified for median concentrations of total phosphorus in agriculture and forest land-use areas. Median concentrations of arsenic, lead, mercury, selenium, and silver were low or below reporting levels throughout the watershed. Aluminum, cadmium, copper, lead, manganese, and zinc concentrations were elevated near the town of Crested Butte and on Henson Creek upstream from Lake City, which may be explained by upstream areas of historical mining. Samples for six trace elements exceeded standards: cadmium, copper, lead, manganese, silver, and zinc. A downward trend (3 micrograms per liter per year) was identified for the dissolved iron concentration at a site on the Gunnison River at County Road 32 downstream from the city of Gunnison. Streambed-sediment samples from areas affected by historical mining also had elevated concentrations of some trace elements. Chlorophyll- a concentrations in samples from Blue Mesa Reservoir and streams in the Crested Butte and Gunnison areas were typical of unenriched to moderately enriched conditions. Median concentrations of 5-day biochemical oxygen demand concentrations for sites between Crested Butte and Blue Mesa Reservoir were less than 2 milligrams per liter. Occasional high (greater than 200 counts per 100 milliliters) concentrations for fecal coliform were determined at selected sites within the study area. However, median concentrations were less than 100 counts per 100 milliliters except for the Squaw Creek and Cimarron River areas in the western part of the watershed. Ground-water-quality data have been collected by the U.S. Geological Survey from 99 wells. Many wells were completed in aquifers composed of Holocene-age valley fill and alluvium. Most field properties were within the USEPA Secondary Drinking Water Regulations (SDWR) range for treated drinking water, except for 2 (of 40) pH samples. Calcium bicarbonate was the predominant water type in nearly all aquifers except for the aquifers composed of volcanic rock, which had more sodium and sulfate mixed water types. Wells with sulfate concentrations exceeding the SDWR of 250 milligrams per liter were completed in aquifers composed of volcanic rock near Lake City. Dissolution and oxidation of sulfide minerals in these aquifers may explain the elevated sulfate concentrations in ground water at these locations. Nutrient concentrations in ground water were generally low, and median concentrations for ammonia, nitrite, and dissolved phosphorus were below reporting levels. All nitrate concentrations in the samples were below the USEPA drinking-water maximum contaminant level of 10 mg/L. No statistical difference was found in nitrate concentrations among the four land-use classifications (agriculture, forest, rangeland, and urban). Trace elements in ground water were generally below the USEPA SDWR. Three iron samples exceeded the USEPA SDWR of 300 micrograms per liter at two wells located near the city of Gunnison and at a well south of the town of Powderhorn near the Cebolla River. Nine of 39 manganese samples exceeded the USEPA SDWR of 50 micrograms per liter and were collected from aquifers composed of Holocene-age valley fill and alluvium near Gunnison and Crested Butte and in one well near the Cebolla River. Radon gas is a natural radioactive decay product of uranium. All 39 radon samples collected from ground water in the watershed exceeded the proposed USEPA drinking-water maximum contaminant level of 300 picocuries per liter and ranged from 426 to 3,830 picocuries per liter.

Colorado↗