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Fractured-rock aquifers, understanding an increasingly important source of water

Ground water is one of the Nation's most important natural resources. It provides drinking water to communities, supports industry and agriculture, and sustains streams and wetlands. A long record of contributions exists in understanding ground-water movement in sand and gravel aquifers; historically, these aquifers were easily accessible and the first to be investigated. With increased demand for water, communities are looking to fractured-rock aquifers, where water moves through fractures in the rock. Fractures, however, may not always convey or store large quantities of water. Understanding ground-water flow through fractured-rock aquifers is an area of ground-water research that will have increasing importance to our Nation over the coming years. Many areas of the United States rely on fractured-rock aquifers for water supply. In addition, areas experiencing population growth in the Northeast, Southeast, and mountainous regions of the West are likely to rely heavily on water supplies from fractured-rock aquifers. Finding water for thirsty communities, however, is not the only societal issue requiring an understanding of ground-water flow in fractured rock. Land-use practices affect water quality in fractured-rock aquifers, particularly where ground water flows rapidly through fractures. Fractured rock aquifers also are viewed as potential repositories for radioactive and other types of waste, where it is desirable for the ground water to be inaccessible or move at a very slow rate.

Fact Sheet

Use of a ground-water flow model with particle tracking to evaluate ground-water vulnerability, Clark County, Washington

A ground-water flow model was used in conjunction with particle tracking to evaluate ground-water vulnerability in Clark County, Washington. Using the particle-tracking program, particles were placed in every cell of the flow model (about 60,000 particles) and tracked backwards in time and space upgradient along flow paths to their recharge points. A new computer program was developed that interfaces the results from a particle-tracking program with a geographic information system (GIS). The GIS was used to display and analyze the particle-tracking results. Ground-water vulnerability was evaluated by selecting parts of the ground-water flow system and combining the results with ancillary information stored in the GIS to determine recharge areas, characteristics of recharge areas, downgradient impact of land use at recharge areas, and age of ground water. Maps of the recharge areas for each hydrogeologic unit illustrate the presence of local, intermediate, or regional ground-water flow systems and emphasize the three-dimensional nature of the ground-water flow system in Clark County. Maps of the recharge points for each hydrogeologic unit were overlaid with maps depicting aquifer sensitivity as determined by DRASTIC (a measure of the pollution potential of ground water, based on the intrinsic characteristics of the near-surface unsaturated and saturated zones) and recharge from on-site waste-disposal systems. A large number of recharge areas were identified, particularly in southern Clark County, that have a high aquifer sensitivity, coincide with areas of recharge from on-site waste-disposal systems, or both. Using the GIS, the characteristics of the recharge areas were related to the downgradient parts of the ground-water system that will eventually receive flow that has recharged through these areas. The aquifer sensitivity, as indicated by DRASTIC, of the recharge areas for downgradient parts of the flow system was mapped for each hydrogeologic unit. A number of public-supply wells in Clark County may be receiving a component of water that recharged in areas that are more conducive to contaminant entry. The aquifer sensitivity maps illustrate a critical deficiency in the DRASTIC methodology: the failure to account for the dynamics of the ground-water flow system. DRASTIC indices calculated for a particular location thus do not necessarily reflect the conditions of the ground-water resources at the recharge areas to that particular location. Each hydrogeologic unit was also mapped to highlight those areas that will eventually receive flow from recharge areas with on-site waste-disposal systems. Most public-supply wells in southern Clark County may eventually receive a component of water that was recharged from on-site waste-disposal systems.Traveltimes from particle tracking were used to estimate the minimum and maximum age of ground water within each model-grid cell. Chlorofluorocarbon (CFC)-age dating of ground water from 51 wells was used to calibrate effective porosity values used for the particle- tracking program by comparison of ground-water ages determined through the use of the CFC-age dating with those calculated by the particle- tracking program. There was a 76 percent agreement in predicting the presence of modern water in the 51 wells as determined using CFCs and calculated by the particle-tracking program. Maps showing the age of ground water were prepared for all the hydrogeologic units. Areas with the youngest ground-water ages are expected to be at greatest risk for contamination from anthropogenic sources. Comparison of these maps with maps of public- supply wells in Clark County indicates that most of these wells may withdraw ground water that is, in part, less than 100 years old, and in many instances less than 10 years old. Results of the analysis showed that a single particle-tracking analysis simulating advective transport can be used to evaluate ground-water vulnerability for any part of a ground-wate

Open-File Report

Hydraulic and field water-chemistry characteristics of piedmont alluvial deposits in the Middle Tyger River near Lyman, Spartanburg County, South Carolina, 2005

This study explores the possibility of developing a bank-filtration process to improve water quality in which alluvial deposits serve as a natural sand filter to pretreat water to be used as a secondary drinking-water source in a small piedmont reservoir along the Middle Tyger River near Lyman in Spartanburg County, South Carolina. From January 2004 to September 2005, data from 10 auger borings, 2 sediment cores, 29 ground-penetrating radar transects, and 3 temporary observation wells, and field water-chemistry data were collected and analyzed. These data were collected and used to characterize the lithology, geometry, hydraulic properties, yield potential, and water-chemistry characteristics of the alluvial deposits in the channel and on the right bank of the reservoir. The assessment was undertaken to determine if an adequate amount of water could be withdrawn from the alluvial deposits to sustain a bank-filtration process and to characterize the water chemistry of the surface water and pore water. The heterogeneous alluvial and fill material at the study site--clay, silty clay, clayey sand, fine- to coarse-grained sand, and mica--on the right bank of the Middle Tyger River ranges in thickness from 0.6 to 7 meters, has a calculated horizontal hydraulic conductivity of 1 meter per day, and yields approximately 0.07 liter per second of water. The small calculated horizontal hydraulic conductivity and water yield for these deposits restrict the use of the right bank as a potential bank-filtration site. The coarse-grained alluvial sand deposit in the channel of the Middle Tyger River, however, may be used for a limited bank-filtration process. The discharge during pumping of the channel deposit yielded water at the rate of 1.9 liters per second. The coarse-grained channel deposit is approximately 49 meters wide and 3 meters thick near the dam. At approximately 183 meters upstream from the dam, the channel narrows to roughly 9 meters and the channel deposits thin to approximately 0.1 meter. Slug tests conducted in the channel deposits near the dam produced a calculated horizontal hydraulic conductivity of 60 meters per day. The limited thickness and aerial extent of the coarse-grained channel deposits coupled with large horizontal hydraulic conductivity likely would allow rapid transmission of water and may degrade the effectiveness of some water-chemistry improvements typical of a bank-filtration process. Field water-chemistry data were collected for approximately 1 hour and 45 minutes at 10 to 15 minute intervals to compare the surface-water and pore-water quality in and beneath the channel of the Middle Tyger River. The waterchemistry data indicate that (1) the mean water temperature was higher in surface water (22.5 degrees Celsius) than in pore water (18.5 degrees Celsius), (2) the mean specific conductance was less in surface water (56.9 microsiemens per centimeter at 25 degrees Celsius) than in pore water (125.7 microsiemens per centimeter at 25 degrees Celsius), (3) alkalinity was lower in surface water (22.5 milligrams per liter) than in pore water (44.6 milligrams per liter), and (4) recorded pH values ranged between 6.2 and 6.3 in the surface water and pore water during the sampling period. The flow velocity was orders of magnitude slower in the pore water than in the surface water; therefore, the pore water interacts with the alluvial sediment for a longer period of time producing the variation in water-chemistry data between the two waters.

South Carolina

Water-quality assessment of the Rio Grande Valley study unit, Colorado, New Mexico, and Texas -- Analysis of selected nutrient, suspended-sediment, and pesticide data

This report contains a summary of data compiled from sources throughout the Rio Grande Valley study unit of the National Water-Quality Assessment program. Information presented includes the sources and types of water-quality data available, the utility of water-quality data for statistical analysis, and a description of recent water-quality conditions and trends and their relation to natural and human factors. Water-quality data are limited to concentrations of selected nutrient species in surface water and ground water, concentrations of suspended sediment and suspended solids in surface water, and pesticides in surface water, ground water, and biota. The Rio Grande Valley study unit includes about 45,900 square miles in Colorado, New Mexico, and Texas upstream from the streamflow-monitoring station Rio Grande at El Paso, Texas. The area also includes the San Luis Closed Basin and the surface-water closed basins east of the Continental Divide and north of the United States-Mexico international border. The Rio Grande drains about 29,300 square miles in these States; the remainder of the study unit area is in closed basins. Concentrations of all nutrients found in surface-water samples collected from the Rio Grande, with the exception of phosphorus, generally remained nearly constant from the northernmost station in the study unit to Rio Grande near Isleta, where concentrations were larger by an order of magnitude. Total nitrogen and total phosphorus loads increased downstream between Lobatos, Colorado, and Albuquerque, New Mexico. Nutrient concentrations remained elevated with slight variations until downstream from Elephant Butte Reservoir, where nutrient concentrations were lower. Nutrient concentrations then increased downstream from the reservoir, as evidenced by elevated concentrations at Rio Grande at El Paso, Texas. Suspended-sediment concentrations were similar at stations upstream from Otowi Bridge near San Ildefonso, New Mexico. The concentration and estimated load were nearly two orders of magnitude larger at this station relative to upstream stations. Cochiti Lake allows suspended sediment to settle, thus the resulting concentration is substantially lower downstream from the reservoir. Downstream from Cochiti Lake, concentrations again increased due to inflow from tributaries, other ephemeral streams and arroyos, and agricultural and urban areas. Two ephemeral tributaries (Rio Puerco and Rio Salado, which are south of Albuquerque) contribute substantial amounts of suspended sediment to the Rio Grande. Suspended-sediment concentrations in the Rio Grande just downstream from Elephant Butte Dam decreased by nearly three orders of magnitude due to settling in the reservoir. Concentrations then increased due to agricultural and urban impacts downstream from the reservoir. Nutrients in ground water in the study unit do not appear to be a widespread problem. However, localized areas that have elevated nitrate concentrations have been documented. The largest median nitrate concentration was found in water from wells located in the Basin and Range-mountains-urban data stratum (3.0 milligrams per liter) and the smallest median nitrate concentration was found in water from wells located in the Southern Rocky Mountainsmountains-forest data stratum (0.08 milligram per liter). Few (3 percent) nitrate concentrations in water from wells in all data strata were greater than 10 milligrams per liter, and most (82 percent) were less than 2 milligrams per liter. Comparison of nitrate concentrations in water from wells located in specific land-use settings across all hydrogeologic settings, with the exception of the Colorado Plateau, indicated that the largest median nitrate concentration was associated with rangeland land use and that larger nitrate concentrations were found in water from shallow wells. Water from wells located in areas of rangeland land use consistently had larger median nutrient concentrations than water from wells in areas of other land uses. The largest median ammonia concentration was in water from wells located in the Colorado Plateau-San Juan Basin-rangeland data stratum (0.27 milligram per liter). Most median ammonia concentrations were less than 0.03 milligram per liter, indicating that elevated ammonia concentrations are not a major issue in the study unit. The largest median orthophosphate concentration was found in water from wells located in the Southern Rocky Mountains-mountains-forest data stratum (0.15 milligram per liter) and the smallest was found in water from wells located in the Basin and Range-mountains-urban data stratum (0.02 milligram per liter). Most orthophosphate concentrations (85 percent) sampled were less than 0.2 milligram per liter, indicating that elevated orthophosphate concentrations are not a major issue in the study unit. Pesticide analyses were available for only 38 ground-water sampling sites in the Rio Grande Valley study unit. Diazinon, at a concentration of 0.01 microgram per liter, was the only pesticide detected and it was detected at only one site. More study is needed to determine if pesticides are affecting ground-water quality in the Rio Grande Valley study unit. Surface-water biological pesticide data were inadequate for in-depth analysis. The primary sources of data were the U.S. Fish and Wildlife Service and the U.S. Geological Survey. In the U.S. Fish and Wildlife Service study p,p'-DDE, a degradation product of DDT, was detected most frequently; highest concentrations were found at Stahman Farms in carp (6.3 micrograms per gram wet-weight) and at Hatch in Western kingbird (5.1 micrograms per gram wet-weight). In the U.S. Geological Survey study of Bosque del Apache National Wildlife Refuge no detectable organochlorine concentrations were found in plants, but detectable levels of p,p'-DDE were found in coot and carp, with a maximum concentration of 0.12 microgram per gram wet-weight found in coot.

Colorado, New Mexico, Texas

Several methods of studying fluctuations of ground‐water levels

As a result of increased interest in ground‐water conditions in recent years, records of water‐levels in wells are now being collected in many places in the United States for the primary purpose of determining the relation of precipitation and other natural factors to fluctuations in water‐level. In the past, records of ground‐water levels have been collected chiefly in connection with intensive investigations in areas where the water‐levels were affected by artificial withdrawals and it has not been generally possible to correlate water‐level fluctuations closely with natural factors. It now appears probable that certain methods of studying water‐level fluctuations may be utilized advantageously in areas unaffected by heavy artificial withdrawals, but these methods generally do not yield satisfactory results in areas where there is considerable pumping or artesian flow. Three such methods are presented in this paper. The methods have not been given intensive study and their practical use is therefore not yet fully known. It is hoped that their application will be further investigated. Illustrations of the methods have been taken from records of ground‐water levels in the Platte River Valley, Nebraska, collected by the United States Geological Survey in cooperation with the Conservation and Survey Division of the University of Nebraska.

Eos, Transactions, American Geophysical Union

Hydrostratigraphic interpretation of test-hole and borehole geophysical data, Kimball, Cheyenne, and Deuel Counties, Nebraska, 2011-12

Recently (2004) adopted legislation in Nebraska requires a sustainable balance between long-term supplies and uses of surface-water and groundwater and requires Natural Resources Districts to understand the effect of groundwater use on surface-water systems when developing a groundwater-management plan. The South Platte Natural Resources District (SPNRD) is located in the southern Nebraska Panhandle and overlies the nationally important High Plains aquifer. Declines in water levels have been documented, and more stringent regulations have been enacted to ensure the supply of ground-water will be sufficient to meet the needs of future generations. Because an improved understanding of the hydrogeologic characteristics of this aquifer system is needed to ensure sustainability of groundwater withdrawals, the U.S. Geological Survey, in cooperation with the SPNRD, Conservation and Survey Division of the University of Nebraska-Lincoln, and the Nebraska Environmental Trust, began a hydrogeologic study of the SPNRD to describe the lithology and thickness of the High Plains aquifer. This report documents these characteristics at 29 new test holes, 28 of which were drilled to the base of the High Plains aquifer. Herein the High Plains aquifer is considered to include all hydrologically connected units of Tertiary and Quaternary age. The depth to the base of aquifer was interpreted to range from 37 to 610 feet in 28 of the 29 test holes. At some locations, particularly northern Kimball County, the base-of-aquifer surface was difficult to interpret from drill cutting samples and borehole geophysical logs. The depth to the base of aquifer determined for test holes drilled for this report was compared with the base-of-aquifer surface interpreted by previous researchers. In general, there were greater differences between the base-of-aquifer elevation reported herein and those in previous studies for areas north of Lodgepole Creek compared to areas south of Lodgepole Creek. The largest difference was at test hole 5-SP-11, where an Ogallala-filled paleovalley prevously had been interpreted based on relatively sparse test-hole data west of 5-SP-11. The base of aquifer near test hole 5-SP-11 reported herein is approximately 230 ft higher in elevation than previously interpreted. Among other test holes that are likely to have been drilled in Ogallala-filled paleovalleys, the greatest difference in the interpreted base of aquifer was for test hole 7-CC-11, northeast of Potter, Nebraska, where the base of aquifer is 180 feet deeper than previously interpreted. Interpretation of test-hole and borehole geophysical data for 29 additional test holes will improve resource managers’ understanding of the hydrogeologic characteristics, including aquifer thickness. Aquifer thickness, which is related to total water in storage, is not well quantified in the north and south tablelands. The additional hydrostratigraphic interpretations provided in this report will improve the hydrogeologic framework used in current (2014) and future groundwater models, which are the basis for many water-management decisions.

Nebraska

Surface-water/groundwater boundaries affect seasonal PFAS concentrations and PFAA precursor transformations​

Elevated concentrations of per- and polyfluoroalkyl substances (PFAS) in drinking-water supplies are a major concern for human health. It is therefore essential to understand factors that affect PFAS concentrations in surface water and groundwater and the transformation of perfluoroalkyl acid (PFAA) precursors that degrade into terminal compounds. Surface-water/groundwater exchange can occur along the flow path downgradient from PFAS point sources and biogeochemical conditions can change rapidly at these exchange boundaries. Here, we investigate the influence of surface-water/groundwater boundaries on PFAS transport and transformation. To do this, we conducted an extensive field-based analysis of PFAS concentrations in water and sediment from a flow-through lake fed by contaminated groundwater and its downgradient surface-water/groundwater boundary (defined as ≤100 cm below the lake bottom). PFAA precursors comprised 45 ± 4.6% of PFAS (PFAA precursors + 18 targeted PFAA) in the predominantly oxic lake impacted by a former fire-training area and historical wastewater discharges. In shallow porewater downgradient from the lake, this percentage decreased significantly to 25 ± 11%. PFAA precursor concentrations decreased by 85% between the lake and 84–100 cm below the lake bottom. PFAA concentrations increased significantly within the surface-water/groundwater boundary and in downgradient groundwater during the winter months despite lower stable concentrations in the lake water source. These results suggest that natural biogeochemical fluctuations associated with surface-water/groundwater boundaries may lead to PFAA precursor loss and seasonal variations in PFAA concentrations. Results of this work highlight the importance of dynamic biogeochemical conditions along the hydrological flow path from PFAS point sources to potentially affected drinking water supplies.

Massachusetts

Effects of soil temperature and depth to ground water on first-year growth of a dryland riparian phreatophyte, Glycyrrhiza lepidota (American licorice)

We investigated the effects of soil temperature and depth to ground water on first-year growth of a facultative floodplain phreatophyte, Glycyrrhiza lepidota , in a 2-×-2 factorial greenhouse experiment. We grew plants in mesocosms subirrigated with water low in dissolved oxygen, mimicking natural systems, and set depth of ground water at 63 or 100 cm and soil temperature at cold (ambient) or warm (≤2.7°C above ambient). We hypothesized the moister (63 cm) and warmer soil would be most favorable and predicted faster growth of shoots and roots and greater nitrogen-fixation (thus, less uptake of mineral nitrogen) under those conditions. Growth in height was significantly faster in the moister treatment but was not affected by soil temperature. Final biomass of shoots and of roots, total biomass of plants, and root:shoot ratio indicated a significant effect only from depth of ground water. Final levels of soil mineral-nitrogen were as predicted, with level of nitrate in the moister treatment more than twice that in the drier treatment. No effect from soil temperature on level of soil-mineral nitrogen was detected. Our results suggest that establishment of G. lepidota requires strict conditions of soil moisture, which may explain the patchy distribution of the species along southwestern dryland rivers.

Southwestern Naturalist

Organochlorine pesticides and PCBs in stream sediment and aquatic biota—initial results from the National Water-Quality Assessment Program, 1992–1995

One of the goals of the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey is to assess the status and trends in the nation's water quality and to understand the natural and anthropogenic factors that affect water-quality conditions. This report summarizes the occurrence and distribution of 33 organochlorine compounds in fluvial bed sediment and aquatic biota (whole freshwater fish and freshwater bivalves) sampled by NAWQA investigations between 1991 and 1994. These include historically used insecticides (DDT and metabolites, chlordane and its various components, and dieldrin), some currently used pesticides (permethrin and dacthal) and some industrial chemicals and byproducts (PCBs and hexaclorobenzene). Samples were collected at approximately 500 sites in 19 large hydrologic basins throughout the United States. Contaminant levels in bed sediment and aquatic biota are summarized, first on a national basis, and then by land-use classification (for example, urban, cropland, pasture and rangeland, and forest). Nationally, detection frequencies are highest in sediment and biota for the more persistent organochlorine compounds: total DDT, total chlordane, dieldrin, and total PCBs. Organochlorine compounds were detected more frequently in whole fish than in bivalves or bed sediment. Organochlorine pesticide concentrations were relatively high in agricultural regions with histories of high use. The highest organochlorine compound concentrations in both sediment and biota generally were associated with urban areas. Some organochlorine concentrations in sediment exceeded guidelines for the protection of aquatic organisms. A screening-level comparison of measured organochlorine concentrations in whole fish was made with human health guidelines that are applicable to edible fish. This comparison indicates stream sites at which additional sampling of game fish fillets may be warranted, depending on local patterns of fish consumption. A comparison of current national contaminant levels with previous studies of this scope suggests a gradual decrease in organochlorine contaminant levels, at least in fish.

Water-Resources Investigations Report

Water-quality assessment of the New England coastal basins in Maine, Massachusetts, New Hampshire, and Rhode Island: Environmental settings and implications for water quality and aquatic biota

The New England Coastal Basins in Maine, Massachusetts, New Hampshire, and Rhode Island constitute one of 59 study units selected for water-quality assessment as part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program. England Coastal Basins study unit encompasses the fresh surface waters and ground waters in a 23,000 square-mile area that drains to the Atlantic Ocean. Major basins include those of the Kennebec, Androscoggin, Saco, Merrimack, Charles, Blackstone, Taunton, and Pawcatuck Rivers. Defining the environmental setting of the study unit is the first step in designing and conducting a multi-disciplinary regional water-quality assessment. The report describes the natural and human factors that affect water quality in the basins and includes descriptions of the physiography, climate, geology, soils, surface- and ground-water hydrology, land use, and the aquatic ecosystem. Although surface-water quality has greatly improved over the past 30 years as a result of improved wastewater treatment at municipal and industrial wastewater facilities, a number of water-quality problems remain. Industrial and municipal wastewater discharges, combined sewer overflows, hydrologic modifications from dams and water diversions, and runoff from urban land use are the major causes of water-quality degradation in 1998. The most frequently detected contaminants in ground water in the study area are volatile organic compounds, petroleum-related products, nitrates, and chloride and sodium. Sources of these contaminants include leaking storage tanks, accidental spills, landfills, road salting, and septic systems and lagoons. Elevated concentrations of mercury are found in fish tissue from streams and lakes throughout the study area.

Maine, Massachusetts, New Hampshire, Rhode Island

Hydrogeologic data from parts of the Denver basin, Colorado

This report presents hydrogeologic data collected and compiled during 1956-81 as part of a comprehensive hydrogeologic data collected and compiled during 1956-81 as part of a comprehensive hdryogeologic investigation of the Denver basin, Colorado, by the U.S. Geological Survey in cooperation with the Colorado Department of Natural Resources, Division of Water Resources, Office of the State Engineer. The data, in tabular and graphic form, consist of records for 870 wells which include water-level data for 158 wells and water-quality analyses for 561 wells; geophysical logs from three wells which include resistivity, self potential, and natural gamma logs; and gain-and-loss data of streamflow measured at 54 sites.

Colorado

Dissolved arsenic concentrations in surface waters within the upper portions of the Klamath River Basin, Oregon and California

Arsenic toxicity is an environmental health problem. Levels of arsenic in surface waters at some locations in the Klamath River Basin in southern Oregon and northern California can exceed the U.S. Environmental Protection Agency (EPA) standard for drinking water. There are both anthropogenic and natural sources of arsenic. The Klamath River Basin consists primarily of volcanic deposits and contains an underground geothermal system with hot springs and warm water wells, all known natural sources of arsenic. Anthropogenic sources of arsenic are related to the agricultural use of herbicides, fungicides, and insecticides. Surface water arsenic levels can also be affected by fertilizer amendments, evaporative concentration, oxygen-level depletion, and various geochemical transformations that can increase arsenic mobilization. In this study by the U.S. Geological Survey and the Bureau of Reclamation, dissolved concentrations of arsenic, copper, and lead were measured in surface waters at 39 unique sites within the upper portions of the Klamath River Basin between 2018 and 2022. In every year, except 2022, sites were sampled four times between April and November. Surface-water arsenic concentrations varied up to four-orders of magnitude among sites. Median arsenic concentration was lowest at Cherry Creek (0.03 micrograms per liter [μg/L]) and highest at Wood Kimball Spring (36.7 μg/L), two sites located north of Upper Klamath Lake. The highest arsenic concentrations (17.4±4.9 μg/L, n =3) were found in drain sites (defined here as a waterbody returning used irrigation water) while the lowest arsenic concentrations were found in an artesian well (0.8 μg/L, n =1). The elevated arsenic concentrations of the drain sites suggest that arsenic might be concentrated or mobilized by agricultural activities, water re-use practices, and (or) by geochemical processes occurring around water stored in drains (that is, in the water column and across sediment water boundaries). A source of arsenic in drain water in the Klamath Strait Drain area includes water used for irrigation originating from Ady Canal. Other potential sources include groundwater, geothermal water, and local soils and sediments. Seasonal differences in surface-water arsenic concentrations were detected at 13 sites, 10 of which had higher arsenic concentrations in summer than in either spring or fall. The sites sampled around Upper Klamath Lake, the impounded rivers, one of the two canal sites, and 5 of the 14 river sites had higher surface-water arsenic concentrations in the summer than in either spring or fall. Surface-water arsenic concentrations from groundwater sources (that is, springs and in the artesian well) did not vary significantly among seasons (p-values greater than 0.1). Median surface-water concentrations of copper and lead ranged from 0.03 to 3.7 μg/L, and from 0.013 to 0.175 μg/L ( n =2–18), respectively. Dissolved concentrations of both metals were below acute toxicity endpoints reported by the EPA for freshwater animals. Surface-water arsenic concentrations varied independently from corresponding changes in surface-water lead or copper concentrations. However, arsenic concentrations measured in bed-sediment samples collected from a subset of sites located north of Upper Klamath Lake correlated strongly and significantly with the corresponding sedimentary lead concentrations ( p =0.015). Aqueous arsenic speciation measured in a subset of sites in 2019 and 2022 showed that all the arsenic existed as arsenic (V), the most oxidized arsenic species, and presumably, the least toxic. The highest proportions of arsenite (As(III)), the presumably most toxic arsenic species, relative to total arsenic concentrations were found at drain sites. Our assessment of dissolved arsenic concentrations in various surface-water bodies in the Upper Klamath River Basin reveals geographical areas of consistently low (below 2.1 μg/L), moderate (below 10 μg/L) and high (above 10 μg/L) surface-water arsenic concentrations. South of Upper Klamath Lake, surface-water arsenic concentrations were consistently higher than 20 μg/L at two drain sites located in an area of predominant agricultural land use with extensive water re-use practices. North of Upper Klamath Lake, surface-water arsenic concentrations greater than 20 μg/L were consistently measured at sites with limited nearby agricultural activities, suggesting a geogenic source. The consistently high arsenic levels from the Wood River at Jackson F. Kimball State Park, Fort Creek, and Crooked Creek, which are sites located at or near headwater spring sources, suggest a natural background source of arsenic. Water flowing downstream from this area could be a potential source of arsenic to Upper Klamath Lake and the Upper Klamath River.

California, Oregon

Map showing selected surface-water data for the Nephi 30 x 60-minute quadrangle, Utah

This is one of a series of maps that describe the geology and related natural resources of the Nephi 30 x 60 minute quadrangle, Utah. Streamflow records used to compile this map were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Transportation. The principal runoff-producing areas shown on the map were delineated from a work map (scale 1:250,000) compiled to estimate water yields in Utah (Bagley and others, 1964). Sources of information about recorded floods resulting from cloudbursts included Woolley (1946) and Butler and Marsell (1972); sources of information about the chemical quality of streamflow included Hahl and Cabell (1965) Mundorff (1972 and 1974), and Waddell and others (1982).

Utah

Preliminary hydrogeologic appraisal of selected hydrothermal systems in northern and central Nevada

Several hydrothermal systems in northern and central Nevada were explored in a hydrogeologic reconnaissance. The systems studied comprise those at Stillwater and Soda Lakes-Upsal Hogback in the Carson Desert, Gerlach, Fly Ranch-Granite Range, and Double Hot Springs in the Black Rock Desert, Brady's Hot Springs, Leach Hot Springs in Grass Valley, Buffalo Valley Hot Springs, and Sulphur Hot Springs in Ruby Valley. The investigation focused on (1) delineating of areas of high heat flow associated with rising thermal ground water, (2) determining the nature of the discharge parts of the hydrothermal systems, (3) estimating heat discharge from the systems, (4) estimating water discharge from the systems, (5) obtaining rough estimates of, conductive heat flow outside areas of hydrothermal discharge, and (6) evaluating several investigative techniques that would yield the required information quickly and at relatively low cost. The most useful techniques were shallow test drilling to obtain geologic, hydraulic, and thermal data and hydrogeologic mapping of the discharge areas. The systems studied are in the north-central part of the Basin and Range province. Exposed volcanic rocks of latest Tertiary and Quaternary age are chiefly basaltic. Basaltic terranes are generally regarded as less favorable for geothermal resources than terranes that contain large volumes of young volcanic mocks of felsic to intermediate composition. Most of the known hydrothermal systems are associated with Basin and Range faults which are caused by crustal extension across the province. An area of high heat flow centered at Battle Mountain and possibly other areas of high heat flow may be related to crustal heat sources. However, some of the hydrothermal systems studied appear to be related to deep circulation of meteoric water in areas of 'normal' regional heat flow rather than to shallow-crustal heat sources. Discharge temperatures of thermal springs in the region range from slightly above mean annual air temperature (8?-12?C at most places) to boiling or slightly hotter. Geochemical data indicate that, in the major systems, subsurface temperatures at which thermal waters equilibrate with reservoir rocks range from 150? to more than 200?C. These data also indicate that the major systems are of the hot-water type rather than the vapor-dominated type. Depths of thermal-water circulation probably range from 2 to 6 kilometres in areas of 'normal' regional heat flow (~2 heatflow units) and from 1 to 3 kilometres in areas of high heat flow (~3-4 heat-flow units) such as near Battle Mountain. Most of the heat is discharged from the hydrothermal systems studied by (1) conduction through near-surface materials heated as a consequence of thermal-water convection, (2) convection as springflow, and (3) convection as steam discharge from spring pools, vents, fumaroles, and cracks. The mate of heat discharge by radiation from warm ground and by convection as lateral ground-water outflow is believed to be small in most systems and is not estimated. Estimates of net heat discharge from the systems studied range from about 0.8 x 106 calories per second at Buffalo Valley Hot Springs to about 14 x 106 calories per second at Stillwater. These estimates represent the approximate magnitude of the excess heat discharge from the thermal areas that results from the upward convection of hot water from deep sources. Water discharges from the hydrothermal systems by springflow, evapotranspiration, steam discharge, and lateral ground-water outflow. Estimated discharges range from about 0.2 x 106cubic metres per year from the Buffalo Valley Hot Springs system to about 3 x 106 cubic metres per year from the Stillwater system. In most of the hydrothermal systems studied and, by inference, in other similar systems in northern and central Nevada, the scale for potential .commercial development for production of electricity or for other uses may be constrained by the

Open-File Report

Use of environmental tracers to evaluate ground-water age and water-quality trends in a buried-valley aquifer, Dayton area, southwestern Ohio

Chlorofluorocarbons (CFC method) and tritium and helium isotopes (3H-3He method) were used as environmental tracers to estimate ground-water age in conjunction with efforts to develop a regional ground-water flow model of the buried-valley aquifer in the Dayton area, southwestern Ohio. This report describes results of CFC and water-quality sampling, summarizes relevant aspects of previously published work, and describes the use of 3H-3He ages to characterize temporal trends in ground-water quality of the buried-valley aquifer near Dayton, Ohio. Results of CFC sampling indicate that approximately 25 percent of the 137 sampled wells were contaminated with excess CFC's that rendered the ground water unsuitable for age dating. Evaluation of CFC ages obtained for the remaining samples indicated that the CFC compounds used for dating were being affected by microbial degradation. The degradation occurred under anoxic conditions that are found in most parts of the buried-valley aquifer. As a result, ground-water ages derived by the CFC method were too old and were inconsistent with measured tritium concentrations and independently derived 3H-3He ages. Limited data indicate that dissolved methane may play an important role in the degradation of the CFC's. In contrast, the 3H-3He technique was found to yield ground-water ages that were chemically and hydrologically reasonable. Ground-water ages derived by the 3H-3He technique were compared to values for selected water- quality characteristics to evaluate temporal trends in ground-water quality in the buried- valley aquifer. Distinct temporal trends were not identified for pH, alkalinity, or calcium and magnesium because of rapid equilibration of ground-water with calcite and dolomite in aquifer sediments. Temporal trends in which the amount of scatter and the number of outlier concentrations increased as ground-water age decreased were noted for sodium, potassium, boron, bromide, chloride, ammonia, nitrate, phosphate, sulfate, and organic carbon. Elevated concentrations of these constituents in shallow ground water are probably related to human activities. Temporal trends in which concentrations declined as ground-water age increased may reflect natural processes that reduce constituent concentrations to low levels. For example, the absence of nitrate detections in ground water recharged before 1980 may indicate natural removal of nitrate by bacterially mediated denitrification. Temporal trends observed for dissolved oxygen, iron, nitrate and silica indicate that these constituents may help identify recently (post-1990) recharged ground water.

Ohio

Water quality in the vicinity of Mosquito Creek Lake, Trumbull County, Ohio, in relation to the chemistry of locally occurring oil, natural gas, and brine

Environmental samples collected in the Mosquito Creek Lake area were used to characterize water quality in relation to the chemistry of locally occurring oil, natural gas, and brine and to establish baseline water quality. Mosquito Creek Lake (a manmade reservoir) and the shallow bedrock aquifers near the lake are major sources of potable water in central Trumbull County. The city of Warren relies on the lake as a sole source of potable water. Some of the lake bottom may be in direct hydraulic connection with the underlying aquifers. The city of Cortland, along the southeastern shore of the lake, relies on the Cussewago Sandstone aquifer as a sole source of potable water. This aquifer subcrops beneath the glacio-fluvial sediments that underlie the lake. Nearly all residential homes around the lake, with the exception of homes in the city of Cortland, rely on domestic supply wells as a source of potable water. Oil and natural gas exploration and production have been ongoing in the Mosquito Creek Lakearea since the discovery of the historic Mecca Oil Pool in the Mississippian Berea and Cussewago Sandstones in 1860. Since the late 1970' s, the major drilling objective and zone of production is the Lower Silurian Clinton sandstone. The oil and natural gas resources of the Mosquito Creek Lake area, including reservoir pressure, production history, and engineering and abandonment practices are described in this report. The chemical and isotopic characteristics of the historic Mecca oil and natural gas are very different than those of the Clinton sandstone oil and natural gas. Gas chromatograms show that Mecca oil samples are extensively altered by biodegradation, whereas Clinton sandstone oils are not. Extensive alteration of Mecca oil is consistent with their occurrence at very shallow depths (less than 100 ft below land surface) where microbial activity can affect their composition. Also, the carbon-isotope composition of dissolved methane gas from Berea and Cussewago Sandstone water samples indicates that the gas is microbially generated, whereas the Clinton sandstone gases are thermogenically generated. Methane gas, in addition to crude oil, occurs naturally in the shallow Berea and Cussewago Sandstone aquifers in the Mosquito Creek Lake area and concentrations of dissolved methane are significant in the city of Cortland public-supply wells and in the domestic-supply wells near the southern shore of the lake. Water associated with oil and gas in the Clinton sandstone is a brine with high concentrations of chloride. Water from the Berea and Cussewago Sandstones, however, is fresh and potable. The contrasting geochemical characteristics are important for addressing water-quality issues that relate to oil and natural gas development in the Mosquito Creek area. A reexamination of the geologic framework and results of a subsurface-gas survey show that crude oil in the historic Mecca Oil Pool probably does not seep into Mosquito Creek Lake. Environmental samples show no evidence of any measurable release of oil, gas, or brine from the deeper Clinton sandstone oil and gas wells to the shallow aquifers, the lake, or lake tributaries. Brine is not associated with the hydrocarbons in the shallow Berea-Cussewago aquifer system and therefore cannot be a source of brine contamination. A mixing diagram constructed for dissolved bromide and chloride in surface water and water-supply wells shows no demonstrable mixing of these water resources with brine from the Clinton sandstone. There is some notable salinity in surface waters; however, the water is bromide poor, and a mixing diagram indicates that some local ground waters are influenced by halite solutions, presumably derived from leaching of road salt or from septic effluent.

Ohio

Map showing selected surface-water data for the Alton-Kolob coal-fields area, Utah

This is one of a series of maps that describe the geology and related natural resources of the Alton-Kolob coal-fields area, Utah. Streamflow records used to compile the map and the following table were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights, and the Utah Department of Transportation. The principal runoff-producing areas were delineated form a work map (scale 1:250,000) compiled to estimate water yields in Utah (Bagley and others, 1964).

Utah

Correlative estimates of streamflow in the upper Colorado River basin

Most hydrologic analyses, whether for appraisal of the water resource, feasibility of a particular development, design of a system of operation, assessment of gains or losses from acts of man or natural changes, or almost any other use, require the extension in time of some streamflow records. In the Upper Colorado River Basin, streamflow records have been extended by various agencies from time to time to fulfill their individual needs, resulting in different estimates of flow for the same point and time. The purpose of this report is to provide correlative estimates of monthly mean discharge at discontinued streamflow gaging stations so that all users will have access to a single set of data. Estimates of monthly mean discharge for periods other than the period of actual record are given for certain discontinued streamflow gaging stations. The stations selected were discontinued in recent years, but they have a sufficient length of record to permit development of a meaningful correlation with the records for a nearby long-term gaging station. Where possible, estimates of monthly mean discharge are made to provide a complete record, estimated or measured, from 1930 to 1965. However, where the long-term gaging station record encompasses a shorter period, the estimates cover only that shorter period. Estimates for periods prior to 1930 were not made, although these may be computed for a few stations. Lack of a related long-term gaging-station record prevented the extension of records at many discontinued stations. The area covered in this report (fig. 1) is that defined in the Colorado River Compact of 1922, as the Upper Basin "those parts of the States of Arizona, Colorado, New Mexico, Utah, and Wyoming within and from which waters naturally drain into the Colorado River System above Lee Ferry," 1 but excluding "all parts of said States located without the drainage area of the Colorado River System which are now and shall hereafter be beneficially served by waters diverted from the System above Lee Ferry" (Wilbur and Ely, 1948, p. A18).

Colorado River Basin