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At least 991 records · Page 55Linked to original sources

Field trials of an autonomous eDNA sampler in lotic waters

Environmental DNA (eDNA) analysis has become a transformative technology, but sample collection methods lack standardization and sampling at effective frequencies requires considerable field effort. Autonomous eDNA samplers that can sample water at high frequencies offer potential solutions to these problems. We present results from four case studies using a prototype autonomous eDNA sampler as part of the U.S. Geological Survey’s Rapid Environmental eDNA Assessment and Deployment Initiative & Network (READI-Net) project. These case studies involved short-term deployments of an eDNA autosampler (Smith-Root) across a range of riverine habitats with the objectives of (a) identifying what insights could be gained from high-frequency autosampling and (b) benchmarking these autosamples against manually collected samples. The high frequency autosampling revealed high temporal variability of eDNA concentrations and provided valuable insights about eDNA associations with environmental covariates, such as discharge and turbidity. Benchmarking assessments indicated autosamples had similar detection rates to manual samples and obtained similar or greater eDNA quantities. We did find minimal carryover contamination in autosampler field controls. We conclude that eDNA autosamplers have potential to improve freshwater biosurveillance by reducing logistical sampling barriers, standardizing collection methods, and clarifying the influence of environmental covariates on eDNA results.

Idaho, Missouri, Montana, New York↗

Investigation of bioaerosols released from swine farms using conventional and alternative waste treatment and management technologies

Microbial air pollution from concentrated animal feeding operations (CAFOs) has raised concerns about potential public health and environmental impacts. We investigated the levels of bioaerosols released from two swine farms using conventional lagoon-sprayfield technology and ten farms using alternative waste treatment and management technologies in the United States. In total, 424 microbial air samples taken at the 12 CAFOs were analyzed for several indicator and pathogenic microorganisms, including culturable bacteria and fungi, fecal coliform, Escherichia coli, Clostridium perfringens, bacteriophage, and Salmonella. At all of the investigated farms, bacterial concentrations at the downwind boundary were higher than those at the upwind boundary, suggesting that the farms are sources of microbial air contamination. In addition, fecal indicator microorganisms were found more frequently near barns and treatment technology sites than upwind or downwind of the farms. Approximately 4.5% (19/424), 1.2% (5/424), 22.2% (94/424), and 12.3% (53/424) of samples were positive for fecal coliform, E. coli, Clostridium, and total coliphage, respectively. Based on statistical comparison of airborne fecal indicator concentrations at alternative treatment technology farms compared to control farms with conventional technology, three alternative waste treatment technologies appear to perform better at reducing the airborne release of fecal indicator microorganisms during on-farm treatment and management processes. These results demonstrate that airborne microbial contaminants are released from swine farms and pose possible exposure risks to farm workers and nearby neighbors. However, the release of airborne microorganisms appears to decrease significantly through the use of certain alternative waste management and treatment technologies. ?? 2008 American Chemical Society.

Environmental Science & Technology↗

Accumulation of metals in fish from lead-zinc mining areas of southeastern Missouri, USA

The potential effects of proposed lead-zinc mining in an ecologically sensitive area were assessed by studying a nearby mining district that has been exploited for about 30 yr under contemporary environmental regulations and with modern technology. Blood and liver samples representing fish of three species (largescale stoneroller, Campostoma oligolepis, n=91; longear sunfish, Lepomis megalotis, n=105; and northern hog sucker, Hypentelium nigricans, n=20) were collected from 16 sites representing a range of conditions relative to lead-zinc mining and ore beneficiation in southeastern Missouri. Samples were analyzed for lead, zinc, and cadmium, and for a suite of biomarkers (reported in a companion paper). A subset of the hog sucker (n=9) representing three sites were also analyzed for nickel and cobalt. Blood and liver lead concentrations were highly correlated (r=0.84-0.85, P < 0.01) in all three species and were significantly (ANOVA, P < 0.01) greater at sites < 10 km downstream of active lead-zinc mines and mills and in a historical lead-zinc mining area than at reference sites, including a site in the area proposed for new mining. Correlations between blood and liver cadmium concentrations were less evident than for lead but were nevertheless statistically significant (r=0.26-0.69, P < 0.01-0.07). Although blood and liver cadmium concentrations were highest in all three species at sites near mines, within-site variability was greater and mining-related trends were less evident than for lead. Blood and liver zinc concentrations were significantly correlated only in stoneroller (r=0.46, P < 0.01) and mining-related trends were not evident. Concentrations of cobalt and nickel in blood and liver were significantly higher (ANOVA, P < 0.01) at a site near an active mine than at a reference site and a site in the historical lead-zinc mining area. These findings confirm previous studies indicating that lead and other metals are released to streams from active lead-zinc mines and are available for uptake by aquatic organisms. ?? 2006 Elsevier Inc. All rights reserved.

Ecotoxicology and Environmental Safety↗

The role of behavioral ecotoxicology in environmental protection

For decades, we have known that chemicals affect human and wildlife behavior. Moreover, due to recent technological and computational advances, scientists are now increasingly aware that a wide variety of contaminants and other environmental stressors adversely affect organismal behavior and subsequent ecological outcomes in terrestrial and aquatic ecosystems. There is also a groundswell of concern that regulatory ecotoxicology does not adequately consider behavior, primarily due to a lack of standardized toxicity methods. This has, in turn, led to the exclusion of many behavioral ecotoxicology studies from chemical risk assessments. To improve understanding of the challenges and opportunities for behavioral ecotoxicology within regulatory toxicology/risk assessment, a unique workshop with international representatives from the fields of behavioral ecology, ecotoxicology, regulatory (eco)toxicology, neurotoxicology, test standardization, and risk assessment resulted in the formation of consensus perspectives and recommendations, which promise to serve as a roadmap to advance interfaces among the basic and translational sciences, and regulatory practices.

Environmental Science & Technology↗

To reduce the global burden of human schistosomiasis, use ‘old fashioned’ snail control

Control strategies to reduce human schistosomiasis have evolved from ‘snail picking’ campaigns, a century ago, to modern wide-scale human treatment campaigns, or preventive chemotherapy. Unfortunately, despite the rise in preventive chemotherapy campaigns, just as many people suffer from schistosomiasis today as they did 50 years ago. Snail control can complement preventive chemotherapy by reducing the risk of transmission from snails to humans. Here, we present ideas for modernizing and scaling up snail control, including spatiotemporal targeting, environmental diagnostics, better molluscicides, new technologies (e.g., gene drive), and ‘outside the box’ strategies such as natural enemies, traps, and repellants. We conclude that, to achieve the World Health Assembly’s stated goal to eliminate schistosomiasis, it is time to give snail control another look.

Trends in Parasitology↗

To the National Map and beyond

Scientific understanding, technology, and social, economic, and environmental conditions have driven a rapidly changing demand for geographic information, both digital and analog. For more than a decade, the U.S. Geological Survey (USGS) has been developing innovative partnerships with other government agencies and private industry to produce and distribute geographic information efficiently; increase activities in remote sensing to ensure ongoing monitoring of the land surface; and develop new understanding of the causes and consequences of land surface change. These activities are now contributing to a more robust set of geographic information called The National Map (TNM). The National Map is designed to provide an up-to-date, seamless, horizontally and vertically integrated set of basic digital geographic data, a frequent monitoring of changes on the land surface, and an understanding of the condition of the Earth's surface and many of the processes that shape it. The USGS has reorganized its National Mapping Program into three programs to address the continuum of scientific activities-describing (mapping), monitoring, understanding, modeling, and predicting. The Cooperative Topographic Mapping Program focuses primarily on the mapping and revision aspects of TNM. The National Map also includes results from the Land Remote Sensing and Geographic Analysis and Monitoring Programs that provide continual updates, new insights, and analytical tools. The National Map is valuable as a framework for current research, management, and operational activities. It also provides a critical framework for the development of distributed, spatially enabled decision support systems.

Cartography and Geographic Information Science↗

Resource report for proposed OCS lease sale 57: Norton Basin, Alaska

This report is a summary of information about an area of the northern Bering Sea continental shelf that is bounded by the Seward Peninsula on the north, by the line of the United States-Russia Convention of 1867 on the west, and by St. Lawrence Island and the coastline that rims Norton Sound on the south and east. Scholl and Hopkins (1969) report that a sedimentary basin underlies the offshore area. More recent data, which form the basis of part of this report, show the basin is deepest beneath Norton Sound; also, the basin has sufficient depth and areal extent that the basin may be a target for development of hydrocarbon resources after Outer Continental Shelf (OCS) Lease Sale 57. The informal, but widely used, name for the basin is Norton Basin. The following discussion includes regional geology, geologic history, and offshore structure and stratigraphy as background data to discussion of the hydrocarbon potential and resource appraisal of the offshore area. Sections on environmental geology and on the technology and manpower needed and available for development of offshore resources are also included.

Alaska↗

Preliminary investigation of the distribution and resources of coal in the Kaiparowits Plateau, southern Utah

This report on the coal resources of the Kaiparowits Plateau, Utah is a contribution to the U.S. Geological Survey's (USGS) 'National Coal Resource Assessment' (NCRA), a five year effort to identify and characterize the coal beds and coal zones that could potentially provide the fuel for the Nation's coal-derived energy during the first quarter of the twenty-first century. For purposes of the NCRA study, the Nation is divided into regions. Teams of geoscientists, knowledgeable about each region, are developing the data bases and assessing the coal within each region. The five major coal-producing regions of the United States under investigation are: (1) the Appalachian Basin; (2) the Illinois Basin; (3) the Gulf of Mexico Coastal Plain; (4) the Powder River Basin and the Northern Great Plains; and (5) the Rocky Mountains and the Colorado Plateau. Six areas containing coal deposits in the Rocky Mountain and Colorado Plateau Region have been designated as high priority because of their potential for development. This report on the coal resources of the Kaiparowits Plateau is the first of the six to be completed. The coal quantities reported in this study are entirely 'resources' and represent, as accurately as the data allow, all the coal in the ground in beds greater than one foot thick. These resources are qualified and subdivided by thickness of coal beds, depth to the coal, distance from known data points, and inclination (dip) of the beds. The USGS has not attempted to estimate coal 'reserves' for this region. Reserves are that subset of the resource that could be economically produced at the present time. The coal resources are differentiated into 'identified' and 'hypothetical' following the standard classification system of the USGS (Wood and others, 1983). Identified resources are those within three miles of a measured thickness value, and hypothetical resources are further than three miles from a data point. Coal beds in the Kaiparowits Plateau are laterally discontinuous relative to many other coal bearing regions of the United States. That is, they end more abruptly and are more likely to fragment or split into thinner beds. Because of these characteristics, the data from approximately 160 drill holes and 40 measured sections available for use in this study are not sufficient to determine what proportion of the resources is technologically and economically recoverable. The Kaiparowits Plateau contains an original resource of 62 billion short tons of coal in the ground. Original resource is defined to include all coal beds greater than one foot thick in the area studied. None of the resource is recoverable by surface mining. However, the total resource figure must be regarded with caution because it does not reflect geologic, technological, land-use, and environmental restrictions that may affect the availability and the recoverability of the coal. At least 32 billion tons of coal are unlikely to be mined in the foreseeable future because the coal beds are either too deep, too thin to mine, inclined at more than 12?, or in beds that are too thick to be completely recovered in underground mining. The estimated balance of 30 billion tons of coal resources does not reflect land use or environmental restrictions, does not account for coal that would be bypassed due to mining of adjacent coal beds, does not consider the amount of coal that must remain in the ground for roof support, and does not take into consideration the continuity of beds for mining. Although all of these factors will reduce the amount of coal that could be recovered, there is not sufficient data available to estimate recoverable coal resources. For purposes of comparison, studies of coal resources in the eastern United States have determined that less than 10 percent of the original coal resource, in the areas studied, could be mined economically at today's prices (Rohrbacher and others, 1994).

Open-File Report↗

Cell penetrating peptide-mediated delivery of gene-silencing nucleic acids to the invasive common reed Phragmites australis via foliar application

As a popular tool for gene function characterization and gene therapy, RNA interference (RNAi)-based gene silencing has been increasingly explored for potential applications to control invasive species. At least two major hurdles exist when applying this approach to invasive plants: (1) the design and screening of species- and gene-specific biomacromolecules (i.e., gene-silencing agents or GSAs) made of DNA, RNA, or peptides that can suppress the expression of target genes efficiently, and (2) the delivery vehicle needed to penetrate plant cell walls and other physical barriers (e.g., leaf cuticles). In this study, we investigated the cell-penetrating peptide (CPP)-mediated delivery of multiple types of GSAs (e.g., double-stranded RNA (dsRNA), artificial microRNA (amiRNA), and antisense oligonucleotide (ASO)) to knock down a putative phytoene desaturase ( PDS ) gene in the invasive common reed ( Phragmites australis spp. australis ). Both microscopic and quantitative gene expression evidence demonstrated the CPP-mediated internalization of GSA cargos and transient suppression of PDS expression in both treated and systemic leaves up to 7 days post foliar application. Although various GSA combinations and application rates and frequencies were tested, we observed limitations, including low gene-silencing efficiency and a lack of physiological trait alteration, likely owing to low CPP payload capacity and the incomplete characterization of the PDS-coding genes (e.g., the recent discovery of two PDS paralogs) in P. australis . Our work lays a foundation to support further research toward the development of convenient, cost-effective, field-deployable, and environmentally benign gene-silencing technologies for invasive P. australis management.

Mississippi, Ohio↗

The World Coal Quality Inventory: South America

Executive Summary-Introduction: The concepts of a global environment and economy are strongly and irrevocably linked to global energy issues. Worldwide coal production and international coal trade are projected to increase during the next several decades in an international energy mix that is still strongly dependent on fossil fuels. Therefore, worldwide coal use will play an increasingly visible role in global environmental, economic, and energy forums. Policy makers require information on coal, including coal quality data, to make informed decisions regarding domestic coal resource allocation, import needs and export opportunities, foreign policy objectives, technology transfer policies, foreign investment prospects, environmental and health assessments, and byproduct use and disposal issues. The development of a worldwide, reliable, coal quality database would help ensure the most economically and environmentally efficient global use of coal. The U.S. Geological Survey (USGS), in cooperation with many agencies and scientists from the world's coal producing countries, originally undertook a project to obtain representative samples of coal from most of the world's producing coal provinces during a limited period of time (roughly 1998-2005), which is called the World Coal Quality Inventory (WoCQI). The multitude of producing coal mines, coal occurrences, or limited accessibility to sites in some countries can preclude collecting more than a single sample from a mine. In some areas, a single sample may represent an entire coal mining region or basin. Despite these limitations in sampling and uneven distribution of sample collection, the analytical results can still provide a general overview of world coal quality. The USGS intends to present the WoCQI data in reports and, when possible, in Geographic Information System (GIS) products that cover important coal bearing and producing regions.

Open-File Report↗

Real-time kinematic surveying at the Osage-Skiatook Petroleum Environmental Research sites, Osage County, Oklahoma

Highly accurate survey-grade Global Positioning System (GPS) technology was used at the two Osage-Skiatook petroleum environmental research sites to document the locations of observation wells, geoprobe holes, and other sampling sites of 15 research scientists. Real-time kinematic (RTK) GPS was the method used, because it is stable, fast, and accurate. Initially three survey monuments were installed one at each research site and one at the U.S. Army Corps of Engineers headquarters for Skiatook Lake. The monument locations were established by static GPS surveys that occupied each of the sites for four hours. The data were submitted to the NOAA-National Geodetic Survey (NGS) Online Positioning User Service (OPUS) for processing. OPUS processes the data relative to three sites on the NGS continuously operating reference station network (CORS). CORS provides GPS carrier phase and code range measurements in support of three-dimensional positioning activities throughout the United States. OPUS enables positioning accuracies, both horizontally and vertically, that approach a few centimeters relative to the National Spatial Reference System and electronically mails the results to the sender. The usual turnaround time for a data set is 2-3 minutes, depending upon the file size. Static GPS surveys are highly accurate, but require post processing the data and longer occupation time. The RTK surveys require a GPS base station positioned over a known monument, a GPS rover, and a radio link between the base station and the rover. The radio link transmits the base station correction data to the rover. The rover combines the base station data with the rover GPS data to produce real-time coordinates. The rover must maintain lock on at least four of the same satellites that the base station is tracking. Each survey location is occupied for 3 minutes. Setup time at each location is less than a minute, if the rover maintains lock on the satellites and the radio link to the base station. Accuracy in the horizontal component is 1 centimeter (cm) plus 2 parts per million (ppm) times the baseline distance and in the vertical component is 2 cm plus 2 ppm times the baseline distance. The calculated accuracy for the initial static GPS surveys that occupied the survey monuments ranged from 1.2 to 1.4 cm for the horizontal component and 2.2 to 2.4 cm for the vertical component. Calculated accuracy for the RTK surveys at the research sites are about 2.2 to 2.4 cm for the horizontal component and 4.2 to 4.4 cm for the vertical component.

Oklahoma↗

Effects of environmental clutter on synthesized chiropteran echolocation signals in an anechoic chamber

Ultrasonic bat detectors are useful for research and monitoring purposes to assess occupancy and relative activity of bat communities. Environmental “clutter” such as tree boles and foliage can affect the recording quality and identification of bat echolocation calls collected using ultrasonic detectors. It can also affect the transmission of calls and recognition by bats when using acoustic lure devices to attract bats to mist-nets. Bat detectors are often placed in forests, yet automatic identification programs are trained on call libraries using echolocation passes recorded largely from open spaces. Research indicates that using clutter-recorded calls can increase classification accuracy for some bat species and decrease accuracy for others, but a detailed understanding of how clutter impacts the recording and identification of echolocation calls remains elusive. To clarify this, we experimentally investigated how two measures of clutter (i.e., total basal area and number of stems of simulated woody growth, as well as recording angle) affected the recording and classification of a synthesized echolocation signal under controlled conditions in an anechoic chamber. Recording angle (i.e., receiver position relative to emitter) significantly influenced the probability of correct classification and differed significantly for many of the call parameters measured. The probability of recording echo pulses was also a function of clutter but only for the detector angle at 0° from the emitter that could receive deflected pulses. Overall, the two clutter metrics were overshadowed by proximity and angle of the receiver to the sound source but some deviations from the synthesized call in terms of maximum, minimum, and mean frequency parameters were observed. Results from our work may aid efforts to better understand underlying environmental conditions that produce false-positive and -negative identifications for bat species of interest and how this could be used to adjust survey accuracy estimates. Our results also help pave the way for future research into the development of acoustic lure technology by exploring the effects of environmental clutter on ultrasound transmission.

Acoustics↗

Mineral resources, environmental issues, and land use

Contrary to predictions from the 1950s through the mid-1980s, persistent shortages of nonfuel minerals have not occurred, despite prodigious consumption, and world reserves have increased. Global availability of raw materials is relevant to policy decisions regarding mineral development and land use. Justification for environmental protection may exceed that for mining a specific ore body. Demand for environmental accountability is rising worldwide, and new technologies are enabling internalization of costs. Mineral-rich developing nations plagued by inefficient state-owned mining enterprises, high population growth rates, and environmental degradation could realize substantial benefit by reforming government policies to encourage foreign investment in resources and by appropriate allocation of mineral rents.

Science↗

The interaction between biology and the management of aquatic macrophytes

‘Management’ refers to controlling nuisance aquatic species and to restoring or restructing aquatic plant communities. Producing stable, diverse, aquatic plant communities containing a high percentage of desirable species is a primary management goal. There are a variety of techniques including harvesting, herbicides, water-level fluctuation, sediment alteration, nutrient limitation, light alteration, and biological controls which can be used for managing macrophytes. These techniques are briefly reviewed along with discussions of biological considerations important to the efficacy of the technique and the environmental impacts of the technique. There is a growing interest in restoring and restructing aquatic plant communities. Techniques for community restoration are discussed as are emerging management technologies using growth regulators and bioengineering. New management technologies will probably be limited by costs and environmental impacts. In the near future, better macrophyte management will come through better planning and more effective use of present technology. The challenge is to make current planning and management techniques more effective through increased biological inputs. The potential for biological input ranges from subcellular biology to species biology, to community and ecosystem biology. Some information needs are identified.

Aquatic Botany↗

Market value of asteroidal precious metals in an age of diminishing terrestrial resources

In the next century Mankind may have to choose from two options for our supply and usage of some nonrenewable natural resources, such as gold, platinum metals, and fossil fuels: learn to live with diminishing supplies of these materials obtained at ever increasing economic and environmental cost, or reach into difficult places and develop new technologies to give us what we need to sustain economic growth. Either prospect faces formidable technological and economic challenges. Exploitation of asteroids for precious and strategic metals is a possible environmentally friendly remedy for impending shortages of some resources. Certain types of asteroids could completely replace terrestrial sources of platinum metals. Asteroid metal mining may become a 21st-century space industry worth ten to fifty billion dollars annually (1995 dollars). Asteroids could make the United States and other countries self sufficient in many strategic metals, and it could usher new technologies and increase our applications of existing technologies that depend on these metals.

Conference Paper↗

Water withdrawal and consumption trends for thermoelectric-power plants in the conterminous United States, 2008-2020

Freshwater-using utility-scale thermoelectric (TE) plant water-use estimates were evaluated for annual trends from 2008 to 2020 across the conterminous United States (CONUS) and within hydrologic regions. Overall, TE water withdrawal and consumption trends declined across CONUS by 14,335 and 278 million liters/day, respectively. Decreasing water withdrawal and consumption trends for TE plants are driven largely by switching from coal-fired plants to other generation technologies. TE plant cooling system technology has also changed, with large declining trends for TE plants using once-through cooling systems and small increasing consumption trends for TE plants using recirculating tower cooling systems. Fifteen hydrologic regions have decreasing trends in withdrawals and consumption. The largest decreases are for coal-fired plants using once-through freshwater cooling systems in the Great Lakes and Ohio hydrologic regions. Natural gas combined cycle plants with recirculating tower cooling systems have increased water consumption trends across most of the CONUS hydrologic regions. Some TE plants with recirculating tower or once-through cooling systems withdraw water volumes that on average are close to or exceed average simulated streamflows. Most of these situations occur in the central and eastern U.S., potentially leading to water availability issues among competing water needs, ecosystem impacts from thermal pollution, and power generation constraints.

conterminous United States↗

Partnership of Environmental Education and Research-A compilation of student research, 1999-2008

The U.S. Geological Survey (USGS) Tennessee Water Science Center and the College of Engineering and Technology at Tennessee State University developed a Partnership in Environmental Education and Research (PEER) to support environmental research at TSU and to expand the environmental research capabilities of the USGS in Tennessee. The PEER program is driven by the research needs to better define the occurrence, fate, and transport of contaminants in groundwater and surface water. Research in the PEER program has primarily focused on the transport and remediation of organic contamination in karst settings. Research conducted through the program has also expanded to a variety of media and settings. Research areas include contaminant occurrence and transport, natural and enhanced bioremediation, geochemical conditions in karst aquifers, mathematical modeling for contaminant transport and degradation, new methods to evaluate groundwater contamination, the resuspension of bacteria from sediment in streams, the use of bioluminescence and chemiluminescence to identify the presence of contaminants, and contaminant remediation in wetlands. The PEER program has increased research and education opportunities for students in the College of Engineering, Technology, and Computer Science and has provided students with experience in presenting the results of their research. Students in the program have participated in state, regional, national and international conferences with more than 140 presentations since 1998 and more than 40 student awards. The PEER program also supports TSU outreach activities and efforts to increase minority participation in environmental and earth science programs at the undergraduate and graduate levels. TSU students and USGS staff participate in the TSU summer programs for elementary and high school students to promote earth sciences. The 2007 summer camps included more than 130 students from 20 different States and Washington DC.

Tennessee↗

XANES evidence for rapid arsenic(III) oxidation at magnetite and ferrihydrite surfaces by dissolved O2 via Fe2+-mediated reactions

To reduce the adverse effects of arsenic on humans, various technologies are used to remove arsenic from groundwater, most relying on As adsorption on Fe-(oxyhydr)oxides and concomitant oxidation of As(III) by dissolved O 2 . This reaction can be catalyzed by microbial activity or by strongly oxidizing radical species known to form upon oxidation of Fe(II) by dissolved O 2 . Such catalyzed oxidation reactions have been invoked to explain the enhanced kinetics of As(III) oxidation in aerated water, in the presence of zerovalent iron or dissolved Fe(II). In the present study, we used arsenic K-edge X-ray absorption near edge structure (XANES) spectroscopy to investigate the role of Fe(II) in the oxidation of As(III) at the surface of magnetite and ferrihydrite under oxygenated conditions. Our results show rapid oxidation of As(III) to As(V) upon sorption onto magnetite under oxic conditions at neutral pH. Moreover, under similar oxic conditions, As(III) oxidized upon sorption onto ferrihydrite only after addition of Fe(II) aq within the investigated time frame of 24 h. These results confirm that Fe(II) is able to catalyze As(III) oxidation in the presence of dissolved O 2 and suggest that oxidation of As(III) upon sorption on magnetite under oxic conditions can be explained by an Fe 2+ -mediated Fenton-like reactions. Thus, the present study shows that magnetite might be an efficient alternative to the current use of oxidants and Fe(II) to remove As from aerated water. In addition, this study emphasizes that special care is needed to preserve arsenic oxidation state during laboratory sorption experiments as well as in collecting As-bearing samples from natural environments.

Environmental Science and Technology↗