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At least 973 records · Page 54Linked to original sources
USGS2007

Geochemical characterization of shallow ground water in the Eutaw aquifer, Montgomery, Alabama

Ground water samples were collected from 30 wells located in, or directly down gradient from, recharge areas of the Eutaw aquifer in Montgomery, Alabama. The major ion content of the water evolves from calcium-sodium-chloride- dominated type in the recharge area to calcium-bicarbonate-dominated type in the confined portion of the aquifer. Ground water in the recharge area was undersaturated with respect to aluminosilicate and carbonate minerals. Ground water in the confined portion of the aquifer was at equilibrium levels for calcite and potassium feldspar. Dissolved oxygen and nitrite-plus-nitrate concentrations decreased as ground water age increased; pH, iron, and sulfate concentrations increased as ground water age increased. Aluminum, copper, and zinc concentrations decreased as ground water age and pH increased. These relations indicate that nitrate, aluminum, copper, and zinc are removed from solution as water moves from recharge areas to the confined areas of the Eutaw aquifer. The natural evolution of ground water quality, which typically increases the pH and decreases the dissolved oxygen content, may be an important limiting factor to the migration of nitrogen based compounds and metals.

Alabama↗
USGS1963

Geologic and hydrologic features of the San Bernardino area, California; with special reference to underflow across the San Jacinto fault

This is the second in a series of interpretive reports on subsurface outflow from the ground-water basins of San Bernardino County, Calif., prepared by the U.S. Geological Survey in cooperation with the San Bernardino County Flood Control District. One principal purpose of the study was to estimate the ground-water outflow from the Bunker Hill basin to the Rialto-Colton basin across the San Jacinto fault, which, except locally, forms a nearly impermeable boundary between the two basins. In addition, the report deals qualitatively with the geology, the fault barriers that divide the area into several ground-water basins, the physical nature and degree of imperviousness of the barriers, the occurrence and movement of ground water and fluctuations of water level in the basins, and the chemical quality of surface and ground waters in the San Bernardino area. The report includes a geologic map and sections, water-level-contour maps and profiles, and hydrographs of selected well. The Santa Ana River, the principal stream, flows generally westward across the area. Channels of the river and its tributaries overlie a large irregular structural depression filled with alluvial deposits ranging in age from late Tertiary to Recent and forming a valley bounded on the north by the San Gabriel Mountains, on the east by the San Bernardino Mountains, and on the south by an irregular group of hills. Large alluvial fans underlie most of the area, but its landforms also include alluvial benches and terraces near the mountains, stream channels, and elongate hills, ridges, and scarps along the trace of the San Jacinto fault, which strikes northwestward across the valley about in the center of the area. This fault and others divide the area into ground-water basins, which include the Bunker Hill, Rialto-Colton, upper and lower Lytle and Chino basins. The water-bearing deposits include the following units: the younger alluvium. of Recent age, which occupies principally the backfilled channels beneath the Santa Ana River and its tributaries and through which ground water moves from Bunker Hill basin to Rialto-Colton basin; the older alluvium, of Pleistocene age, which is the principal water-bearing unit of the area and yields water to more than a thousand wells; and continental deposits of Tertiary to Quaternary age, which crop out along the southern margin of the area and locally along the San Gabriel Mountains on the north. The younger alluvium attains a maximum thickness of about 125 feet beneath the Santa Ana River south of San Bernardino. Locally in the Bunker Hill basin it is composed of two members, an upper member of relatively impermeable clay and a lower member of highly permeable material in which water is confined by the upper member. The older alluvium locally has a known thickness greater than 700 feet; elsewhere in the San Bernardino Valley it may exceed 1,400 feet. Locally, where ground water is confined in Bunker Hill basin, the older alluvium is divided into three permeable water-bearing zones separated from each other and from the younger alluvium above by less permeable zones. In parts of Chino and Rialto-Colton basins the alluvium consists of a coarse-grained facies along a former course of a major stream that is interfingered with and overlain by relatively fine-grained deposits. The permeability of the younger alluvium in the area beneath the Santa Ana River downstream from the San Jacinto fault was determined from tests to be about 2,700 gallons per day per square foot. The permeability of the coarse water-yielding materials of the older alluvium several miles downstream was estimated from tests to be about the same magnitude. Rocks that yield practically no water include continental rocks of Tertiary age, which are not exposed in the area but are tapped by wells in Rialto-Colton basin, and crystalline and metamorphic rocks of pre-Tertiary age that form the bedrock of the area.

California↗
USGS1999

Relationships between the structure of natural organic matter and its reactivity towards molecular ozone and hydroxyl radicals

Oxidation reaction rate parameters for molecular ozone (O3) and hydroxyl (HO) radicals with a variety of hydrophobic organic acids (HOAs) isolated from different geographic locations were determined from batch ozonation studies. Rate parameter values, obtained under equivalent dissolved organic carbon concentrations in both the presence and absence of non-NOM HO radical scavengers, varied as a function of NOM structure. First-order rate constants for O3 consumption (k(O3)) averaged 8.8 x 10-3 s-1, ranging from 3.9 x 10-3 s-1 for a groundwater HOA to > 16 x 10-3 s-1 for river HOAs with large terrestrial carbon inputs. The average second-order rate constant (k(HO,DOC) between HO radicals and NOM was 3.6 x 108 l (mol C)-1 s-1; a mass of 12 g C per mole C was used in all calculations. Specific ultraviolet absorbance (SUVA) at 254 or 280 nm of the HOAs correlated well (r > 0.9) with O3 consumption rate parameters, implying that organic ??-electrons strongly and selectively influence oxidative reactivity. HO radical reactions with NOM were less selective, although correlation between k(HO,DOC) and SUVA existed. Other physical-chemical properties of NOM, such as aromatic and aliphatic carbon content from 13C-NMR spectroscopy, proved less sensitive for predicting oxidation reactivity than SUVA. The implication of this study is that the structural nature of NOM varies temporally and spatially in a water source, and both the nature and amount of NOM will influence oxidation rates.

Water Research↗
USGS2012

Methods to characterize environmental settings of stream and groundwater sampling sites for National Water-Quality Assessment

Characterization of natural and anthropogenic features that define the environmental settings of sampling sites for streams and groundwater, including drainage basins and groundwater study areas, is an essential component of water-quality and ecological investigations being conducted as part of the U.S. Geological Survey's National Water-Quality Assessment program. Quantitative characterization of environmental settings, combined with physical, chemical, and biological data collected at sampling sites, contributes to understanding the status of, and influences on, water-quality and ecological conditions. To support studies for the National Water-Quality Assessment program, a geographic information system (GIS) was used to develop a standard set of methods to consistently characterize the sites, drainage basins, and groundwater study areas across the nation. This report describes three methods used for characterization-simple overlay, area-weighted areal interpolation, and land-cover-weighted areal interpolation-and their appropriate applications to geographic analyses that have different objectives and data constraints. In addition, this document records the GIS thematic datasets that are used for the Program's national design and data analyses.

Scientific Investigations Report↗
USGS2010

Design of Cycle 3 of the National Water-Quality Assessment Program, 2013-2022: Part 1: Framework of Water-Quality Issues and Potential Approaches

In 1991, the U.S. Congress established the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program to develop long-term, nationally consistent information on the quality of the Nation's streams and groundwater. Congress recognized the critical need for this information to support scientifically sound management, regulatory, and policy decisions concerning the increasingly stressed water resources of the Nation. The long-term goals of NAWQA are to: (1) assess the status of water-quality conditions in the United States, (2) evaluate long-term trends in water-quality conditions, and (3) link status and trends with an understanding of the natural and human factors that affect water quality. These goals are national in scale, include both surface water and groundwater, and include consideration of water quality in relation to both human uses and aquatic ecosystems. Since 1991, NAWQA assessments and findings have fostered and supported major improvements in the availability and use of unbiased scientific information for decisionmaking, resource management, and planning at all levels of government. These improvements have enabled agencies and stakeholders to cost-effectively address a wide range of water-quality issues related to natural and human influences on the quality of water and potential effects on aquatic ecosystems and human health (http://water.usgs.gov/nawqa/xrel.pdf). NAWQA, like all USGS programs, provides policy relevant information that serves as a scientific basis for decisionmaking related to resource management, protection, and restoration. The information is freely available to all levels of government, nongovernmental organizations, industry, academia, and the public, and is readily accessible on the NAWQA Web site and other diverse formats to serve the needs of the water-resource community at different technical levels. Water-quality conditions in streams and groundwater are described in more than 1,700 publications (available online at http://water.usgs.gov/nawqa/bib/), and are documented by more than 14 million data records representing about 7,600 stream sites, 8,100 wells, and 2,000 water-quality and ecological constituents that are available from the NAWQA data warehouse (http://infotrek.er.usgs.gov/traverse/f?p=NAWQA:HOME:0). The Program promotes collaboration and liaison with government officials, resource managers, industry representatives, and other stakeholders to increase the utility and relevance of NAWQA science to decisionmakers. As part of this effort, NAWQA supports integration of data from other organizations into NAWQA assessments, where appropriate and cost-effective, so that more comprehensive findings are available across geographic and temporal scales.

Open-File Report↗
USGS1978

Remote-sensing methods for monitoring surface coal mining in the northern Great Plains

Recent studies at a large surface coal mine in southern Montana confirm that remote sensing is both feasible and effective for gathering land-use and environmental data (spatial, dynamic, and seasonal) for large-scale surface mines in the northern Great Plains. The Western Energy Co.'s Rosebud mine near Colstrip, Mont., was selected as a test site because it typifies surface operations in the Powder River Basin of Montana and Wyoming and elsewhere in the northern Great Plains. Several basic interpretive and analytical remote-sensing techniques were used to identify and delineate various categories of surface-mining operations and concurrent stages of reclamation that characterize most, if not all, such mining operations. Color infrared and black-and-white aerial photographs and a black-and-white band 5 Landsat image were used to identify (1) high wall and bench areas, (2) ungraded spoils, (3) graded and recontoured areas, (4) revegetated recontoured areas, (5) natural and impounded surface water, and (6) miscellaneous areas. Over the lifespan of an extensive surface mine, cultural and natural processes and cumulative environmental effects can be monitored by capitalizing on the close correlation between enhanced satellite imagery, infrared and (or) black-and-white aerial photography, standard large-scale topographic maps (such as U.S. Geological Survey 7½-minute quadrangle maps), and results of onsite inspection of mining and reclamation by Federal or State agencies.

Montana↗
USGS2018

Forecasting for dry and wet avalanches during mixed rain and snow storm events

Natural wet slab avalanches release when rain or melt water decreases snowpack strength, and natural dry slab avalanches release when an increased load overcomes snowpack strength. This study investigates avalanche activity resulting from mixed rain and snow falling on a faceted snowpack. This scenario produced an extensive slab avalanche cycle in March 2018 in the mountains near Ketchum, Idaho, when a 24 hour storm deposited 50 to 65 mm of water. We investigate the contributions of the pre-existing snowpack structure and weather to avalanching, and suggest possible mechanisms for the observed slab avalanche activity. At upper elevations, expected widespread, 0.5 to 3 m deep, dry slab avalanche activity occurred on many aspects. However, at middle elevations (2300 m to 2700 m) near the fluctuating rain-snow line, a low frequency return period avalanche cycle occurred in a much smaller geographical area, and was concentrated around north-northwest aspects. This differs significantly from avalanches above this elevation that spanned all aspects. This scenario illustrates the challenges forecasting and communicating these events. In our experience, some avalanche cycles exist in a continuum of avalanche types that are not easily sorted into simple “wet” and “dry” categories. We discuss challenges in using current advisory and bulletin communication tools. Furthermore, it is possible that a changing climate will increase the frequency of mixed rain-snow events in areas with traditionally drier and colder climates. We believe the avalanche community will benefit from the refinement and development of tools and techniques to describe and forecast this challenging problem.

Conference Paper↗
USGS1978

Determination of dissolved boron in fresh, estuarine, and geothermal waters by d.c. argon-plasma emission spectrometry

A d.c. argon-plasma emission spectrometer is used to determine dissolved boron in natural (fresh and estuarine) water samples. Concentrations ranged from 0.02 to 250 mg l -1 . The emission—concentration function is linear from 0.02 to 1000 mg l -1 . Achievement of a relative standard deviation of ⩽ 3% requires frequent restandardization to offset sensitivity changes. Dilution may be necessary to overcome high and variable electron density caused by differences in alkali-metal content and to avoid quenching of the plasma by high solute concentrations of sodium and other easily ionized elements. The proposed method was tested against a reference method and found to be more sensitive, equally or more precise and accurate, less subject to interferences, with a wider linear analytical range than the carmine method. Analyses of standard reference samples yielded results in all cases within one standard deviation of the means.

Analytica Chimica Acta↗
USGS1972

Quality of surface water in the Bear River basin, Utah, Wyoming, and Idaho

The United States Geological Survey, in cooperation with the Utah Department of Natural Resources, Division of Water Rights, began a reconnaissance in 1967 to obtain essential water-quality information for the Bear River basin. The reconnaissance was directed toward defining the chemical quality of the basin’s surface waters, including suitability for specific uses, geology, and general basin hydrology. Emphasis was given to those areas where water-development projects are proposed or being considered.

Idaho, Utah, Wyoming↗
USGS2012

Water-quality characteristics and trend analyses for the Tongue, Powder, Cheyenne, and Belle Fourche River drainage basins, Wyoming and Montana, for selected periods, water years 1991 through 2010

The Powder River structural basin in northeastern Wyoming and southeastern Montana is an area of ongoing coalbed natural gas (CBNG) development. Waters produced during CBNG development are managed with a variety of techniques, including surface impoundments and discharges into stream drainages. The interaction of CBNG-produced waters with the atmosphere and the semiarid soils of the Powder River structural basin can affect water chemistry in several ways. Specific conductance and sodium adsorption ratios (SAR) of CBNG-produced waters that are discharged to streams have been of particular concern because they have the potential to affect the use of the water for irrigation. Water-quality monitoring has been conducted since 2001 at main-stem and tributary sites in the Tongue, Powder, Cheyenne, and Belle Fourche River drainage basins in response to concerns about CBNG effects. A study was conducted to summarize characteristics of stream-water quality for water years 2001–10 (October 1, 2000, to September 30, 2010) and examine trends in specific conductance, SAR, and primary constituents that contribute to specific conductance and SAR for changes through time (water years 1991–2010) that may have occurred as a result of CBNG development. Specific conductance and SAR are the focus characteristics of this report. Dissolved calcium, magnesium, and sodium, which are primary contributors to specific conductance and SAR, as well as dissolved alkalinity, chloride, and sulfate, which are other primary contributors to specific conductance, also are described. Stream-water quality in the Tongue, Powder, Cheyenne, and Belle Fourche River drainage basins was variable during water years 2001–10, in part because of variations in streamflow. In general, annual runoff was less than average during water years 2001–06 and near or above average during water years 2007–10. Stream water of the Tongue River had the smallest specific conductance values, sodium adsorption ratios, and major ion concentrations of the main-stem streams. Sites in the Tongue River drainage basin typically had the smallest range of specific conductance and SAR values. The water chemistry of sites in the Powder River drainage basin generally was the most variable as a result of diverse characteristics of that basin. Plains tributaries in the Powder River drainage basin had the largest range of specific conductance and SAR values, in part due to the many tributaries that receive CBNG-produced waters. Trends were analyzed using the seasonal Kendall test with flow-adjusted concentrations to determine changes to water quality through time at sites in the Tongue, Powder, Cheyenne, and Belle Fourche River drainage basins. Trends were evaluated for water years 2001–10 for 17 sites, which generally were on the main-stem streams and primary tributaries. Trends were evaluated for water years 2005–10 for 26 sites to increase the spatial coverage of sites. Trends were evaluated for water years 1991–2010 for eight sites to include water-quality data collected prior to widespread CBNG development and expand the temporal context of trends. Consistent patterns were not observed in trend results for water years 2001–10 for flow-adjusted specific conductance and SAR values in the Tongue, Powder, and Belle Fourche River drainage basins. Significant (p-values less than 0.05) upward trends in flow-adjusted specific conductance values were determined for 3 sites, a downward trend was determined for 1 site, and no significant (p-value greater than 0.05) trends were determined for 13 sites. One of the sites with a significant upward trend was the Tongue River at the Wyoming-Montana State line. No trend in flow-adjusted specific conductance values was determined for the Powder River at Moorhead, Mont. Significant upward trends in flow-adjusted SAR values were determined for 2 sites and no significant trends were determined for 15 sites. No trends in flow-adjusted SAR values were determined for the Tongue River at the Wyoming-Montana State line or for the Powder River at Moorhead, Mont. One of the sites with a significant upward trend in flow-adjusted SAR values was the Powder River at Arvada, Wyo. For water years 2005–10, significant upward trends in flow-adjusted specific conductance values were determined no significant trends were determined for 13 sites. A significant upward trend was determined for flow-adjusted specific conductance values for the Tongue River at the Wyoming-Montana State line. No trend in flow-adjusted specific conductance values was determined for the Powder River at Moorhead, Mont. Significant upward trends in flow-adjusted SAR values were determined for 4 sites, downward trends were determined for 5 sites, and no significant trend was determined for 17 sites. No trends in flow-adjusted SAR values were determined for the Tongue River at the Wyoming-Montana State line or for the Powder River at Moorhead, Mont. Results of the seasonal Kendall test applied to flow-adjusted specific conductance values for water years 1991–2010 indicated no significant trend for eight sites in the Tongue, Powder, and Belle Fourche River drainage basins. No significant trend in flow-adjusted specific conductance was determined for the Tongue River at the Wyoming-Montana State line or the Powder River at Moorhead, Mont. Results of the seasonal Kendall test applied to flow-adjusted SAR values for water years 1991–2010 indicated an upward trend for one site and no significant trend for four sites in the Powder and Belle Fourche River drainage basins. The significant upward trend in flow-adjusted SAR values was determined for the Powder River at Arvada, Wyo., for water years 1991–2010. Results indicate that CBNG development in the Powder River structural basin may have contributed to some trends, such as the upward trend in flow-adjusted SAR for the Powder River at Arvada, Wyo., for water years 1991–2010. An upward trend in flow-adjusted alkalinity concentrations for water years 2001–10 also was determined for the Powder River at Arvada, Wyo. Trend results are consistent with changes that can occur from the addition of sodium and bicarbonate associated with CBNG-produced waters to the Powder River. Upward trends in constituents at other sites, including the Belle Fourche River, may be the result of declining CBNG development, indicating that CBNG-produced waters may have had a dilution effect on some streams. The factors affecting other trends could not be determined because multiple factors could have been affecting the stream-water quality or because trends were observed at sites upstream from CBNG development that may have affected water-quality trends at sites downstream.

Wyoming;Montana↗
USGS2004

Documentation of the Santa Clara Valley regional ground-water/surface-water flow model, Santa Clara Valley, California

The Santa Clara Valley is a long, narrow trough extending about 35 miles southeast from the southern end of San Francisco Bay where the regional alluvial-aquifer system has been a major source of water. Intensive agricultural and urban development throughout the 20th century and related ground-water development resulted in ground-water-level declines of more than 200 feet and land subsidence of as much as 12.7 feet between the early 1900s and the mid-1960s. Since the 1960s, Santa Clara Valley Water District has imported surface water to meet growing demands and reduce dependence on ground-water supplies. This importation of water has resulted in a sustained recovery of the ground-water flow system. To help support effective management of the ground-water resources, a regional ground-water/surface-water flow model was developed. This model simulates the flow of ground water and surface water, changes in ground-water storage, and related effects such as land subsidence. A numerical ground-water/surface-water flow model of the Santa Clara Valley subbasin of the Santa Clara Valley was developed as part of a cooperative investigation with the Santa Clara Valley Water District. The model better defines the geohydrologic framework of the regional flow system and better delineates the supply and demand components that affect the inflows to and outflows from the regional ground-water flow system. Development of the model includes revisions to the previous ground-water flow model that upgraded the temporal and spatial discretization, added source-specific inflows and outflows, simulated additional flow features such as land subsidence and multi-aquifer wellbore flow, and extended the period of simulation through September 1999. The transient-state model was calibrated to historical surface-water and ground-water data for the period 1970–99 and to historical subsidence for the period 1983–99. The regional ground-water flow system consists of multiple aquifers that are grouped into upper- and lower-aquifer systems. Ground-water inflow occurs as natural recharge in the form of streamflow infiltration and areal infiltration of precipitation along stream channels, artificial recharge from infiltration of imported water at recharge ponds and along selected stream channels, and leakage along selected transmission pipelines. Ground-water outflow occurs as evapotranspiration, stream base flow, discharge through pumpage from wells, and subsurface flow to the San Francisco Bay. The geohydrologic framework of the regional ground-water flow system was represented as six model layers. The hydraulic properties were redefined on the basis of cell-based lithologic properties that were delineated in terms of aggregate thicknesses of coarse-grained, fine-grained, and mixed textural categories. The regional aquifer systems also are dissected by several laterally extensive faults that may form at least partial barriers to the lateral flow of ground water. The spatial extent of the ground-water flow model was extended and refined to cover the entire Santa Clara Valley, including the Evergreen subregion. The temporal discretization was refined and the period of simulation was extended to 1970–99. The model was upgraded to MODFLOW-2000 (MF2K) and was calibrated to fit historical ground-water levels, streamflow, and land subsidence for the period 1970–99. The revised model slightly overestimates measured water levels with an root-mean-square error of -7.34 feet. The streamflow generally shows a good match on gaged creeks and rivers for flows greater than 1.2 cubic feet per second. The revised model also fits the measured deformation at the borehole extensometer site located near San Jose within 16 to 27 percent and the extensometer site near Sunnyvale within 3 percent of the maximum measured seasonal deformation for the deepest extensometers. The total ground-water inflow and outflow of about 225,500 acre-feet per year (acre-ft/yr) for the period 1970–89 and of about 205,300 acre-feet per year for the period for the period 1970–99 is comparable with that of the previous model, 207,200 acre-ft/yr for the period 1970–89. Overall the simulated net change in storage increased by about 189,500 acre-ft/yr for the entire period of simulation, which represents about one and a half years of the 1970–99 average pumping. The changes in ground-water flow and storage generally reflect the major climate cycles and the additional importation of water by Santa Clara Valley Water District, with the basin in recovery since the drought of the late 1980s and early 1990s. The average total recharge rate, from natural and artificial recharge and from streamflow infiltration for the revised model for the entire simulation period 1970–99, was about 157,100 acre-ft/yr, which represents about 59 percent of the inflow to the ground-water flow system. The average rate of artificial recharge of about 77,600 acre-ft/yr represents about 30 percent of the inflow to the ground-water flow system. The average pumpage for the entire 29.75-year simulation period is about 133,400 acre-ft/yr and represents about 69 percent of the outflow from the ground-water flow system. Most of the simulated recharge infiltrates and flows through the uppermost layers (i.e. model layers 1 and 3) of the aquifer system. Most of the water that flows to the deeper model layers is occurring through wellbores, with wellbore flow representing 19 percent of the total ground-water inflow between model layers.

California↗
USGS1996

Distribution of oil and natural-gas wells in relation to ground-water flow systems in the Great Basin region of Nevada and Utah, and adjacent states

This map publication is one of several in a series concerning various aspects of the ground-water hydrology of the Great Basin in Nevada, Utah, and adjacent States. One report in the series describes the hydrogeologic framework of the Great Basin (Plume and Carlton, 1988). Another shows the ground-water levels for the aquifer systems of the Great Basin (Thomas and others, 1986). A third report in the series describes the regional ground-water flow patterns in the Great Basin (Harrill and others, 1988).

Nevada, Utah↗
USGS1998

Concepts for monitoring water quality in the Spokane River Basin, northern Idaho and eastern Washington

Numerous environmental studies have been conducted in the Spokane River Basin over the past several decades by government agencies, academic institutions, and environmental engineering firms. Most of these efforts have focused on the environmental effects of more than a century of silver, lead, and zinc mining and oreprocessing activities in the South Fork Coeur d'Alene River valley in northern Idaho. Several studies also have assessed the water quality and potential for eutrophication of Coeur d'Alene and Long Lakes and the Coeur d'Alene, St. Joe, and Spokane Rivers. Because past investigations often were limited in scope and employed different approaches and methods, an integrated understanding of hydrologic, water-quality, and aquatic biological conditions still is lacking for the basin as a whole. Substantial resources are being spent for water-quality and naturalresource management, and for mitigating the adverse environmental effects of past mining activities in the basin. A water-quality monitoring network, integrated with the decision-making processes associated with these efforts, could be of considerable value. The purpose of such a monitoring network is to produce high-quality information on which to base sound water-quality and natural-resource management decisions and to assess the effectiveness of those decisions. A streamflow- and water-quality monitoring infrastructure already exists in the Spokane River Basin. This infrastructure consists of 20 lake-stage and streamflow-gaging stations, representing specific drainages or subdrainages and, in many cases, specific stream reaches or subreaches. These gaging stations are operated by the U.S. Geological Survey (USGS), several of them in cooperation with State and Federal agencies and a private utility company. Extensive streamflow data are available, some dating from the late 1800s. Water-quality data are also available from recent USGS cooperative studies in the Coeur d'Alene Lake watershed. A nutrient load/lake response (eutrophication) model has been developed for Coeur d'Alene Lake. Hydraulic models for estimating streamflow through the low-gradient reaches of the Coeur d'Alene and St. Joe Rivers have been developed. Trace-element concentrations and distributions in sediments in the lower South Fork and main-stem Coeur d'Alene River flood plain and the bed of Coeur d'Alene Lake have been assessed. Trace-element transport models have been developed for the lower Coeur d'Alene River system; estimates of annual load are available from the early 1990's to the present (1998). The USGS is monitoring traceelement concentrations and transport at seven gaging stations in the lower Coeur d'Alene River system and upper Spokane River, in cooperation with the U.S. Environmental Protection Agency. Fish and macroinvertebrate community assessment and tissue contaminant analyses at four Coeur d'Alene and St. Joe River gaging stations will begin in 1998, either as part of the Idaho Surface- Water Quality Ambient Monitoring Network operated by USGS in cooperation with the Idaho Division of Environmental Quality, or for the Northern Rockies Intermontane Basins (NROK) study of the USGS National Water-Quality Assessment (NAWQA) Program. Several gaging stations in the Spokane River Basin are being considered for routine sampling sites for the NROK NAWQA study. Several other sites also will be sampled for contaminants in bed sediment and fish tissue for the NROK study. Combined with appropriate sampling and data interpretation strategies, the existing USGS gaging-station network and data base could provide integrated water-quality information needed for sound environmental and resource-management decisions throughout the Spokane River Basin.

Idaho;Washington↗
USGS1993

National water summary 1990-91: Hydrologic events and stream water quality

National Water Summary 1990-91 Hydrologic Events and Stream Water Quality was planned to complement existing Federal-State water-quality reporting to the U.S. Congress that is required by the Clean Water Act of 1972. This act, formally known as the Federal Water Pollution Control Act Amendments of 1972 (Public Law 92-500), and its amendments in 1977,1979,1980,1981,1983, and 1987, is the principal basis for Federal-State cooperation on maintaining and reporting on water quality in the United States. Under section 305(b) of the Clean Water Act, the States must designate uses for waterbodies, biennially assess whether the waterbodies meet designated uses, and report to the U.S. Environmental Protection Agency (EPA), which in turn summarizes the findings of the State assessments in a biennial National Water Quality Inventory report to the Congress. This volume of the National Water Summary uses a nationally consistent data base and methods of statistical analysis to document stream water quality in the United States, Puerto Rico, and the Western Pacific Islands. As a basis for preparation of this report, the U.S. Geological Survey (uses) created a data base of waterquality data from about 2,900 stream water-quality monitoring stations in the United States (Lanfear, 1993). These data, which were extracted primarily from the uses National Water Information System (NWIS) and supplemented with data from the EPA national data base known as STORET, consisted mostly of water-chemistry and physical-sediment data. About 1,400 of these stations met a criterion, used in this volume for trends analysis of data, of having a period of record that began before water year 1980. (A water year is the period from October 1 through September 30 and is identified by the calendar year at the end of the period.) Inasmuch as the determination of trends requires about 10 years of data, few biological data were suitable for trends analysis because biological indicators of water quality were not being collected extensively by water year 1980. Also, because of the lack of long-term data, an assessment of the water quality of lakes and reservoirs is not included in this National Water Summary . Constituent and waterproperty data were selected from this data base and analyzed with statistical techniques that have been used extensively by the uses to summarize conditions and trends in water quality. (Throughout the remainder of this article, the term "constituent" is used also to represent water properties, such as pH and alkalinity.) Selected results from this analysis are presented graphically, both by State and nationally, in this volume. The data base created for preparation of this volume and the resulting nationally consistent statistical analysis of these data provide a unique opportunity to compare and contrast stream water-quality conditions and trends nationally and State by State. Because of the complexity of water quality and the natural seasonal and diurnal variations in the concentrations of waterquality constituents, the determination of trends in water quality requires a relatively long period of record. Trends in constituent concentrations in the State summaries in this volume were calculated for one or more of four periods water years 1970-89,1975-89,1980- 89, and 1982-89. Unfortunately, few water-quality monitoring stations have periods of record of more than 10 or 15 years, and therefore most analyses in the State summaries were done for 8- or 10-year periods. Although interest in water quality has continued to heighten since passage of the Clean Water Act, funds for support of data-collection programs are limited and data records of many of the constituents now of current concern, especially organic constituents, do not exist or are less than 10-years long; consequently only a modest number of organic constituents are presented in this volume. Discussion of conditions and trends in water quality in this National Water Summary also draw upon information about land use, population, water use, application of agricultural chemicals in rural areas, the siting of industrial facilities, and other ancillary information. Because the results of analysis of a restricted number of constituents are presented in this volume, State 305(b) reports also are cited in the discussion of water quality in each State. The following discussion is an overview of the three parts of this 1990-91 National Water Summary - "Hydrologic Conditions and Water-Related Events, Water Years 1990-91," "Hydrologic Perspectives on Water Issues," and "State Summaries of Stream Water Quality."

Water Supply Paper↗
USGS1997

Assessing hydrogeochemical heterogeneity in natural and constructed wetlands

While 'water quality function' is cited as an important wetland function to design for and preserve, we demonstrate that the scale at which hydrochemical samples are collected can significantly influence interpretations of biogeochemical processes in wetlands. Subsurface, chemical profiles for both nutrients and major ions were determined at a site in southwestern Wisconsin that contained areas of both natural and constructed wetlands. Sampling was conducted on three different scales: (1) a large scale (3 m between sampling points), (2) an intermediate scale (0.15 m between sampling points), and (3) a small scale (1.5 cm between sampling points). In most cases, significant vertical heterogeneity was observed at the 0.15 m scale, which was much larger than previously reported for freshwater wetlands and not detected by sampling water table wells screened over the same interval. However, profiles of ammonia and total phosphorus showed tenfold changes in the upper 0.2 meters of the saturated zone when sampled at the small (1.5 cm) scale, that was not depicted by sampling at the intermediate scale. At the intermediate scale of observation, one constructed wetland site differed geochemically from the natural wetlands and the other constructed wetland site due to application of off-site salvaged marsh surface and downward infiltration of rain. While important differences in dissolved inorganic phosphorus and dissolved inorganic carbon concentrations existed between the constructed wetland and the natural wetlands, we also observed substantial differences between the natural wetland sites for these constituents. A median-polishing analysis of our data showed that temporal variations in constituent concentrations within profiles, although extensively recognized in the literature, were not as important as spatial variability.

Biogeochemistry↗
USGS2018

Methane in groundwater from a leaking gas well, Piceance Basin, Colorado, USA

Site-specific and regional analysis of time-series hydrologic and geochemical data collected from 15 monitoring wells in the Piceance Basin indicated that a leaking gas well contaminated shallow groundwater with thermogenic methane. The gas well was drilled in 1956 and plugged and abandoned in 1990. Chemical and isotopic data showed the thermogenic methane was not from mixing of gas-rich formation water with shallow groundwater or natural migration of a free-gas phase. Water-level and methane-isotopic data, and video logs from a deep monitoring well, indicated that a shale confining layer ~125 m below the zone of contamination was an effective barrier to upward migration of water and gas. The gas well, located 27 m from the contaminated monitoring well, had ~1000 m of uncemented annular space behind production casing that was the likely pathway through which deep gas migrated into the shallow aquifer. Measurements of soil gas near the gas well showed no evidence of methane emissions from the soil to the atmosphere even though methane concentrations in shallow groundwater (16 to 20 mg/L) were above air-saturation levels. Methane degassing from the water table was likely oxidized in the relatively thick unsaturated zone (~18 m), thus rendering the leak undetectable at land surface. Drilling and plugging records for oil and gas wells in Colorado and proxies for depth to groundwater indicated thousands of oil and gas wells were drilled and plugged in the same timeframe as the implicated gas well, and the majority of those wells were in areas with relatively large depths to groundwater. This study represents one of the few detailed subsurface investigations of methane leakage from a plugged and abandoned gas well. As such, it could provide a useful template for prioritizing and assessing potentially leaking wells, particularly in cases where the leakage does not manifest itself at land surface.

Colorado↗
USGS1950

Geochemistry of ground water

The science of geochemistry is the study of the chemical composition of and actual or possible chemical changes in the crust of the earth. The subdivision of geochemistry concerned with ground water includes study of the nature and amounts of dissolved mineral matter in ground waters, the chemical and geologic changes that influence the kinds and amounts of substances carried in solution, and the chemical relationships between dissolved mineral matter in waters and minerals that make up the rocks in which the waters occur. As . thus defined, the field of geochemistry of ground water is very large. Although much work has been done in geochemistry in general, and in some phases of the geochemistry of ground water, the field remains to a large extent unexplored.

Economic Geology↗